China, People’s Republic
Optimal Dispatch Model for Hybrid Energy Storage in Low-Carbon Integrated Energy Systems
Nov 2025
Publication
Integrated Energy Systems (IESs) which leverage the synergistic coordination of electricity heat and gas networks serve as crucial enablers for a low-carbon transition. Current research predominantly treats energy storage as a subordinate resource in dispatch schemes failing to simultaneously optimise IES economic efficiency and storage operators’ profit maximisation thereby overlooking their potential value as independent market entities. To address these limitations this study establishes an operator-autonomous management framework incorporating electrical thermal and hydrogen storage in IESs. We propose a joint optimal dispatch model for hybrid energy storage systems in low-carbon IES operation. The upper-level model minimises total system operation costs for IES operators while the lower-level model maximises net profits for independent storage operators managing various storage assets. These two levels are interconnected through power price and carbon signals. The effectiveness of the proposed model is verified by setting up multiple scenarios for example analysis.
Heat Transfer Enhancement in Regenerative Cooling Channels: Numerical Analysis of Single- and Double-row Cylindrical Ribs with Supercritical Hydrogen
Nov 2025
Publication
The thermal protection of rocket engine combustion chambers presents a critical challenge in supersonic flight applications. This study numerically investigates the enhancement of heat transfer and coolant flow characteristics in regenerative cooling channels through cylindrical rib integration employing ANSYS Fluent with SST k-ω turbulence modeling to evaluate single- and double-row configurations (0.75–1.25 mm diameter) under supercritical hydrogen conditions (3 MPa 300 K inlet). Results demonstrate that rib-induced turbulence disrupts thermal boundary layers with a 1.25 mm single-row design achieving a 13.67 % reduction in peak wall temperature compared to smooth channels while double-row arrangements show diminishing returns due to increased flow resistance. The thermal performance factor (η = (Nu/Nu₀)/(f/f₀) 1/3) reveals Case 3′s superiority (21.88 % improvement over the smooth channel configuration) in balancing heat transfer enhancement against pressure drop penalties (9.23–20.93 % for single-row 8.26–18.7 % for double-row). Notably density-driven flow acceleration near heated walls mitigates pressure losses through localized viscosity reduction. Furthermore cylindrical ribs reduce thermal stratification by up to 30 % in single-row configurations with double-row designs providing additional temperature homogenization at the cost of increased flow resistance. These findings offer critical insights for optimizing rib-enhanced cooling systems in high-performance rocket engines achieving simultaneous thermal efficiency and hydraulic performance improvements.
In-situ CO2 Capture by DFMs to Enhance Hydrogen Production and Regeneration Performance of Biomass-H2O Gasification
Nov 2025
Publication
Developing green hydrogen energy can alleviate the problem of CO2 emissions caused by excessive use of fossil fuels. In-situ capture of CO2 for enhanced H2 production in zero-carbon energy biomass-H2O gasification can achieve the dual effects of green H2 production and negative carbon. The study used red mud (RM) to modify CaO and prepare dual-functional materials (DFMs). And the in-situ CO2 capture enhanced H2 production and regeneration cycle performance of DFMs in biomass-H2O gasification were studied and the influence of biomass ash on the H2 production and low-temperature (650 ◦C) regeneration performance of DFMs in the cycle was analyzed. The results are as follows: In DFMs catalyzed biomass-H2O gasification due to the continuous deposition of alkali and alkaline earth metals (AAEMs) in biomass ash with increasing cycle times its catalytic effect increased H2 production by 27 % after twenty cycles and the pore structure degradation and cycle stability of DFMs decreased by 44.71 %. DFMs have demonstrated excellent catalytic performance and cycling stability in the catalytic removal of ash from biomass. After twenty cycles the production of H2 only decreased by 20.59 % and the performance of CaO decreased by 26.67 % demonstrating the enormous potential of DFMs for in-situ CO2 capture and enhanced H2 production.
Thermal Energy Integration and Optimization in a Biomass-fueled Multi-generation System for Power, Hydrogen, and Freshwater Production
Nov 2025
Publication
This work investigates a biomass-driven multi-generation system designed for simultaneous power freshwater and hydrogen production addressing the interlinked energy-waterenvironment nexus. The configuration integrates Brayton supercritical carbon dioxide (SCO2) organic Rankine cycle (ORC) and thermoelectric generator (TEG) subsystems to maximize utilization of biomass-derived syngas. The recovered energy drives a reverse osmosis (RO) desalination unit for freshwater production and an alkaline electrolyzer for hydrogen generation followed by two-stage compression for storage. Under baseline conditions the system generates 1.99 MW of electricity 9.38 kg/h of hydrogen and 88.6 m3 /h of freshwater with an overall exergetic efficiency of 20.25 % emissions intensity of 0.85 kg/kWh and a payback period of 5.87 years. The Brayton cycle accounts for 49.3 % of the total cost rate while the gasifier exhibits the highest exergy destruction at 46 %. Sensitivity analyses show that varying biomass moisture content (10–30 %) and operating temperatures (700–900 ◦C) significantly influence system performance. Using a data-driven optimization framework that combines artificial neural networks (ANN) and a genetic algorithm (GA) the system’s exergetic efficiency improves to 21.76 % freshwater output rises to 90.96 m3 /h and emissions intensity decreases to 0.877 kg/kWh. Additionally optimization reduces the total cost rate by 2.71 % leading to a payback period of 5.4 years and enhances the system’s overall performance by 12.64 %.
Optimal Sizing and Energy Management for Fuel Cell Electric Vehicles with 3D-ordered MEAs: A Pareto Frontier Study
Oct 2025
Publication
Fuel cell electric vehicles (FCEVs) are zero-emission but face cost and power density challenges. To mitigate these limitations a novel 3D-ordered nano-structured self-supporting membrane electrode assembly (MEA) has been developed. This paper investigates the optimal component sizing of the battery and fuel cell in FCEVs equipped with 3D-ordered MEAs integrating the energy management. To explore the trade-offs between component cost operational cost and fuel cell degradation the sizing and energy management problem is formulated into a multi-objective optimisation problem. A Pareto frontier (PF) study is conducted using the decomposed multi-objective evolutionary algorithm (MOEA/D) for a more diverse distribution of feasible solutions. The modular design of fuel cells is derived from a scaled and stressed experiment. After executing MOEA/D across the three aggressive driving cycles power source configurations are selected from the corresponding PFs based on objective trade-offs ensuring robustness of the overall system. The optimisation performance of the MOEA/D is compared with that of the multi-objective Particle Swarm Optimisation. In addition the selected powertrain configurations are evaluated and compared through standard and realworld driving cycles in a simulation environment. This paper also performs a sensitivity analysis to reveal the influence of diverse component unit costs and hydrogen price. The results indicate that the mediumsized configuration consisting of a 63.31 kW fuel cell stack and a 52.15 kWh battery pack delivers the best overall performance. It achieves a 26.71% reduction in component cost and up to 12.76% savings in hydrogen consumption across various driving conditions. These findings provide valuable insights into the design and optimisation of fuel cell systems for FCEVs.
Design of Hydrogen-Powered Mobile Emergency Power Vehicle with Soft Open Point and Appropriate Energy Management Strategy
Oct 2025
Publication
Zhigang Liu,
Wen Chen,
Shi Liu,
Yu Cao and
Yitao Li
Mobile emergency power supply vehicles (MEPSVs) powered by diesel engines or lithiumion batteries (LIBs) have become a viable tool for emergency power supply. However diesel-powered MEPSVs generate noise and environmental pollution while LIB-powered vehicles suffer from limited power supply duration. To overcome these limitations a hydrogen-powered MEPSV incorporating a soft open point (SOP) was developed in this study. We analyzed widely used operating scenarios for the SOP-equipped MEPSV and determined important parameters including vehicle body structure load capacity driving speed and power generation capability for the driving motor hydrogen fuel cell (FC) module auxiliary LIB module and SOP equipment. Subsequently we constructed an energy management strategy for the model for MEPSV which uses multiple energy sources of hydrogen fuel cells and lithium-ion batteries. Through simulations an optimal hydrogen consumption rate in various control strategies was validated using a predefined load curve to optimize the energy consumption minimization strategy and achieve the highest efficiency.
Hydrogen-involved Renewable Energy Base Planning in Desert and Gobi Regions under Electricity-carbon-hydrogen Markets
Nov 2025
Publication
China is developing renewable energy bases (REBs) in the desert and Gobi regions. However the intermittency of renewable energy and the temporal mismatch between peak renewable generation and peak load demand severely disrupt the power supply reliability of these REBs. Hydrogen storage technology characterized by high energy density and long-term storage capability is an effective method for enhancing the power supply reliability. Therefore this paper proposes a REB planning model in the desert and Gobi regions considering seasonal hydrogen storage introduction as well as electricity-carbon-hydrogen markets trading. Furthermore a combination scenario generation method considering extreme scenario optimization is proposed. Among which the extreme scenarios selected through an iterative selection method based on maximizing scenario divergence contain more incremental information providing data support for the proposed model. Finally the simulation was conducted in the desert and Gobi regions of Yinchuan Ningxia Province China primarily verifying that (1) the REB incorporating hydrogen storage can fully leverage hydrogen storage to achieve seasonal and long-term electricity transfer and utilization. The project has a payback period of 10 years with an internal rate of return of 13.30% and a return on investment of 16.34% thus showing significant development potential. (2) Compared to the typical battery-involved REB the hydrogen-involved energy storage facility achieved a 59.39% annual profit a 10.98% internal rate of return a 14.93% return on investment and a 1.51% improvement in power supply reliability by sacrificing a 52.49% increase in construction cost. (3) Compared to REB planning based only on typical scenarios the power supply reliability of REBs based on the proposed combination scenario generation method improved by 8.58%.
A Two-Stage Optimal Dispatch Strategy for Electric-ThermalHydrogen Integrated Energy System Based on IGDT and Fuzzy Chance-Constrained Programming
Nov 2025
Publication
Na Sun,
Hongxu He and
Haiying Dong
To address the economic and reliability challenges of high-penetration renewable energy integration in electricity-heat-hydrogen integrated energy systems and support the dualcarbon strategy this paper proposes an optimal dispatch method integrating Information Gap Decision Theory (IGDT) and Fuzzy Chance-Constrained Programming (FCCP). An IES model coupling multiple energy components was constructed to exploit multi-energy complementarity. A stepped carbon trading mechanism was introduced to quantify emission costs. For interval uncertainties in renewable generation IGDT-based robust and opportunistic dispatch models were established; for fuzzy load uncertainties FCCP transformed them into deterministic equivalents forming a dual-layer “IGDT-FCCP” uncertainty handling framework. Simulation using CPLEX demonstrated that the proposed model dynamically adjusts uncertainty tolerance and confidence levels effectively balancing economy robustness and low-carbon performance under complex uncertainties: reducing total costs by 12.7% cutting carbon emissions by 28.1% and lowering renewable curtailment to 1.8%. This study provides an advanced decision-making paradigm for low-carbon resilient IES.
Joint Optimization Scheduling of Electric Vehicles and Electro–Olefin–Hydrogen Electromagnetic Energy Supply Device for Wind–Solar Integration
Nov 2025
Publication
In northern China the long winter heating period is accompanied by severe wind curtailment. To address this issue a joint optimization scheduling strategy of electric vehicles (EVs) and electro–olefin–hydrogen electromagnetic energy supply device (EHED) is proposed to promote deep wind–solar integration. Firstly the feasibility analysis of EVs participating in scheduling is conducted and the operation models of dispatchable EVs and thermal energy storage EHEDs within the scheduling period are established. Secondly a control strategy for the joint optimization scheduling of wind–solar farms EVs EHEDs and power grid is constructed. Then an economic dispatch model for joint optimization of EVs and EHEDs is established to minimize the system operation cost within the scheduling period and the deep wind–solar integration of the joint optimization model is studied by considering EVs under different demand responses. Finally the proposed model is solved by CPLEX solver. The simulation results show that the established joint optimization economic dispatch model of EV-EHEDs can improve the enthusiasm of dispatchable EVs to participate in deep wind–solar integration reduce wind curtailment power and decrease the overall system operation cost.
An Explainable Fault Diagnosis Algorithm for Proton Exchange Membrane Fuel Cells Integrating Gramian Angular Fields and Gradient-Weighted Class Activation Mapping
Nov 2025
Publication
Reliable operation of proton exchange membrane fuel cells (PEMFCs) is crucial for their widespread commercialization and accurate fault diagnosis is the key to ensuring their long-term stable operation. However traditional fault diagnosis methods not only lack sufficient interpretability making it difficult for users to trust their diagnostic decisions but also one-dimensional (1D) feature extraction methods highly rely on manual experience to design and extract features which are easily affected by noise. This paper proposes a new interpretable fault diagnosis algorithm that integrates Gramian angular field (GAF) transform convolutional neural network (CNN) and gradient-weighted class activation mapping (Grad-CAM) for enhanced fault diagnosis and analysis of proton exchange membrane fuel cells. The algorithm is systematically validated using experimental data to classify three critical health states: normal operation membrane drying and hydrogen leakage. The method first converts the 1D sensor signal into a two-dimensional GAF image to capture the temporal dependency and converts the diagnostic problem into an image recognition task. Then the customized CNN architecture extracts hierarchical spatiotemporal features for fault classification while Grad-CAM provides visual explanations by highlighting the most influential regions in the input signal. The results show that the diagnostic accuracy of the proposed model reaches 99.8% which is 4.18% 9.43% and 2.46% higher than other baseline models (SVM LSTM and CNN) respectively. Furthermore the explainability analysis using Grad-CAM effectively mitigates the “black box” problem by generating visual heatmaps that pinpoint the key feature regions the model relies on to distinguish different health states. This validates the model’s decision-making rationality and significantly enhances the transparency and trustworthiness of the diagnostic process.
Dispersion of High-Pressure Hydrogen Jets in Open-Top and Indoor Environments: Effects of Leak Geometry and Pressure
Nov 2025
Publication
Yang Li,
Shourui Zhang,
Meng Yu,
Yang Wu,
Jiake Wu and
Long Jiang
Hydrogen leakage is a critical safety concern for high-pressure storage systems where orifice geometry significantly influences dispersion and risk. Previous studies on leakage and diffusion have mostly focused on closed or semi-closed environments while thorough exploration has been conducted on open and unshielded environments. This work compares three typical orifice types—circular slit and Y-type—through controlled experiments. Results show that circular orifices generate directional jets with steep gradients but relatively low concentrations with a 1 mm case reaching only 0.725% at the jet core. Slit orifices exhibit more uniform diffusion; at 1 mm concentrations ranged from 2.125% to 2.625%. Y-type orifices presented the highest hazard with 0.5 mm leaks producing 2.9% and 1 mm cases approaching the 4% lower flammability limit within 375 s. Equilibrium times increased with orifice size from 400–800 s for circular and slit leaks to up to 900 s for Y-type leaks some of which failed to stabilize. Response behavior also varied: Y-type leaks achieved rapid multi-point responses (as short as 10 s) while circular and slit leaks responded more slowly away from the jet core. Overall risk ranking was circular < slit < Y-type underscoring the urgent need for geometry-specific monitoring strategies sensor layouts and emergency thresholds to ensure safe hydrogen storage.
Marine Hydrogen Pressure Reducing Valves: A Review on Multi-Physics Coupling, Flow Dynamics, and Structural Optimization for Ship-Borne Storage Systems
Oct 2025
Publication
As a zero-carbon energy carrier hydrogen is playing an increasingly vital role in the decarbonization of maritime transportation. The hydrogen pressure reducing valve (PRV) is a core component of ship-borne hydrogen storage systems directly influencing the safety efficiency and reliability of hydrogen-powered vessels. However the marine environment— characterized by persistent vibrations salt spray corrosion and temperature fluctuations— poses significant challenges to PRV performance including material degradation flow instability and reduced operational lifespan. This review comprehensively summarizes and analyzes recent advances in the study of high-pressure hydrogen PRVs for marine applications with a focus on transient flow dynamics turbulence and compressible flow characteristics multi-stage throttling strategies and valve core geometric optimization. Through a systematic review of theoretical modeling numerical simulations and experimental studies we identify key bottlenecks such as multi-physics coupling effects under extreme conditions and the lack of marine-adapted validation frameworks. Finally we conducted a preliminary discussion on future research directions covering aspects such as the construction of coupled multi-physics field models the development of marine environment simulation experimental platforms the research on new materials resistant to vibration and corrosion and the establishment of a standardized testing system. This review aims to provide fundamental references and technical development ideas for the research and development of high-performance marine hydrogen pressure reducing valves with the expectation of facilitating the safe and efficient application and promotion of hydrogen-powered shipping technology worldwide.
Co-Optimization of Capacity and Operation for Battery-Hydrogen Hybrid Energy Storage Systems Based on Deep Reinforcement Learning and Mixed Integer Programming
Oct 2025
Publication
The hybrid energy storage system (HESS) that combines battery with hydrogen storage exploits complementary power/energy characteristics but most studies optimize capacity and operation separately leading to suboptimal overall performance. To address this issue this paper proposes a bi-level co-optimization framework that integrates deep reinforcement learning (DRL) and mixed integer programming (MIP). The outer layer employs the TD3 algorithm for capacity configuration while the inner layer uses the Gurobi solver for optimal operation under constraints. On a standalone PV–wind–load-HESS system the method attains near-optimal quality at dramatically lower runtime. Relative to GA + Gurobi and PSO + Gurobi the cost is lower by 4.67% and 1.31% while requiring only 0.52% and 0.58% of their runtime; compared with a direct Gurobi solve the cost remains comparable while runtime decreases to 0.07%. Sensitivity analysis further validates the model’s robustness under various cost parameters and renewable energy penetration levels. These results indicate that the proposed DRL–MIP cooperation achieves near-optimal solutions with orders of magnitude speedups. This study provides a new DRL–MIP paradigm for efficiently solving strongly coupled bi-level optimization problems in energy systems.
Assessment of Regional Hydrogen Refueling Station Layout Planning and Carbon Reduction Benefits Based on Multi-Dimensional Factors of Population, Land, and Demand
Oct 2025
Publication
The urgent global transition toward low-carbon energy systems has highlighted the need for systematic planning of hydrogen refueling stations (HRS) to facilitate clean energy adoption. This study develops an integrated framework for regional HRS layout optimization and carbon emission assessment considering population distribution land area and hydrogen demand. Using Hainan Province as a case study the model estimates regional hydrogen demand determines optimal HRS deployment evaluates spatial coverage and refueling distances and quantifies potential carbon emission reductions under various renewable energy scenarios. Model validation with Haikou demonstrates its reliability and applicability at the regional scale. Results indicate pronounced spatial disparities in hydrogen demand and infrastructure requirements emphasizing that prioritizing station deployment in densely populated urban areas can enhance accessibility and maximize emission reduction. The framework offers a practical data-efficient tool for policymakers and planners to guide early-stage hydrogen infrastructure development and supports strategies for regional decarbonization and sustainable energy transitions.
Degradation Heterogeneity in Active X70 Pipeline Welds Microstructure-Property Coupling Under Multiphysics Environments of Hydrogen-Blended Natural Gas
Oct 2025
Publication
This study investigates the performance degradation of X70 steel weld material in highpressure natural gas pipelines in the Sichuan-Chongqing region and its impact on pipeline safety by investigating their behavior under multiphysics environments including varying gas media (nitrogen methane hydrogen-blended) pressure conditions (0.1–10 MPa) and material regions (base metal vs. weld). A key novelty of this work is the introduction of a “degradation rate” metric to quantitatively assess the deterioration of weld mechanical properties. A key novelty of this work is the explicit introduction of a “degradation rate” metric to quantitatively assess the deterioration of weld mechanical properties. Slow strain rate tensile tests combined with fracture morphology and microstructure analysis reveal that welds exhibit inferior mechanical properties due to microstructural inhomogeneity and residual stresses including a yield stress reduction of 15.2–18.7%. The risk of brittle fracture was highest in the hydrogen-blended environment while nitrogen exhibited the most benign effect. Material region changes were identified as the most significant factor affecting degradation. This research provides crucial data and theoretical support for pipeline safety design and material performance optimization.
Enhanced Performance of TiO2 Composites for Solar Cells and Photocatalytic Hydrogen Production
Oct 2025
Publication
Xue Bai,
Jian Chen,
Shengxi Du and
Yan Xiong
Titanium dioxide (TiO2) is widely used in solar cells and photocatalysts given its excellent photoactivity low cost and high structural electronic and optical stability. Here a novel TiO2 composite was prepared by coating TiO2 inverse opal (IO) with TiO2 nanorods (NRs). With a porous three-dimensional network structure the composite exhibited higher light absorption; enhanced the separation of the electron–hole pairs; deepened the infiltration of the electrolyte; better transported and collected charge carriers; and greatly improved the power conversion efficiency (PCE) of the quantum-dot sensitized solar cells (QDSSCs) based on it while also boosting its own photocatalytic hydrogen generation efficiency. A very high PCE of 12.24% was achieved by QDSSCs utilizing CdS/CdSe sensitizer. Furthermore the TiO2 composite exhibited high photocatalytic activity with a H2 release rate of 1080.2 µ mol h−1 g −1 several times that of bare TiO2 IO or TiO2 NRs.
A Review on Combustion Instability of Hydrogen-Enriched Marine Gas Turbines
Nov 2025
Publication
Hydrogen is widely regarded as a promising carbon-free alternative fuel. However the development of low-emission marine gas turbine combustion systems has been hindered by the associated risks of combustion instability also termed as thermoacoustic oscillations. Although there is sufficient literature on hydrogen fuel and combustion instability systematic reviews addressing the manifestations and mechanisms of these instabilities remain limited. The present study aims to provide a comprehensive review of combustion instabilities in hydrogen-enriched marine gas turbines with a particular focus on elucidating the characteristics and underlying mechanisms. The review begins with a concise overview of recent progress in understanding the fundamental combustion properties of hydrogen and then details various instability phenomena in hydrogen-enriched methane flames. The mechanisms by which hydrogen enrichment affects combustion instabilities are extensively discussed particularly in relation to the feedback loop in thermoacoustic combustion systems. The paper concludes with a summary of the key combustion instability challenges associated with hydrogen addition to methane flames and offers prospects for future research. In summary the review highlights the interaction between hydrogenenriched methane flames and thermoacoustic phenomena providing a foundation for the development of stable low-emission combustion systems in industrial marine applications incorporating hydrogen enrichment.
Benefit Allocation Strategies for Electric–Hydrogen Coupled Virtual Power Plants with Risk–Reward Tradeoffs
Nov 2025
Publication
Driven by carbon neutrality goals electric–hydrogen coupled virtual power plants (EHCVPPs) integrate renewable hydrogen production with power system flexibility resources emerging as a critical technology for large-scale renewable integration. As distributed energy resources (DERs) within EHCVPPs diversify heterogeneous resources generate diversified market values. However inadequate benefit allocation mechanisms risk reducing participation incentives destabilizing cooperation and impairing operational efficiency. To address this benefit allocation must balance fairness and efficiency by incorporating DERs’ regulatory capabilities risk tolerance and revenue contributions. This study proposes a multi-stage benefit allocation framework incorporating risk–reward tradeoffs and an enhanced optimization model to ensure sustainable EHCVPP operations and scalability. The framework elucidates bidirectional risk–reward relationships between DERs and EHCVPPs. An individualized risk-adjusted allocation method and correction mechanism are introduced to address economic-centric inequities while a hierarchical scheme reduces computational complexity from diverse DERs. The results demonstrate that the optimized scheme moderately reduces high-risk participants’ shares increasing operator revenue by 0.69% demand-side gains by 3.56% and reducing generation-side losses by 1.32%. Environmental factors show measurable yet statistically insignificant impacts. The framework meets stakeholders’ satisfaction and minimizes deviation from reference allocations.
Durable Pt-Decorated NiFe-LDH for High-Current-Density Electrocatalytic Water Splitting Under Alkaline Conditions
Nov 2025
Publication
The development of durable and efficient catalysts capable of driving both hydrogen and oxygen evolution reactions is essential for advancing sustainable hydrogen production through overall water electrolysis. In this study we developed a corrosion-mediated approach where Ni ions originate from the self-corrosion of the nickel foam (NF) substrate to construct Pt-modified NiFe layered double hydroxide (Pt-NiFeOxHy@NiFe-LDH) under ambient conditions. The obtained catalyst exhibits a hierarchical architecture with abundant defect sites which favor the uniform distribution of Pt clusters and optimized electronic configuration. The Pt-NiFeOxHy@NiFe-LDH catalyst constructed through the interaction between Pt sites and defective NiFe layered double hydroxide (NiFe-LDH) demonstrates remarkable hydrogen evolution reaction (HER) activity delivering an overpotential as low as 29 mV at a current density of 10 mA·cm−2 and exhibiting a small tafel slope of 34.23 mV·dec−1 in 1 M KOH together with excellent oxygen evolution reaction (OER) performance requiring only 252 mV to reach 100 mA·cm−2 . Moreover the catalyst demonstrates outstanding activity and durability in alkaline seawater maintaining stable operation over long-term tests. The Pt-NiFeOxHy@NiFe-LDH electrode when integrated into a two-electrode system demonstrates operating voltages as low as 1.42 and 1.51 V for current densities of 10 and 100 mA·cm−2 respectively and retains outstanding stability under concentrated alkaline conditions (6 M KOH 70 ◦C). Overall this work establishes a scalable and economically viable pathway toward high-efficiency bifunctional electrocatalysts and deepens the understanding of Pt-LDH interfacial synergy in promoting water-splitting catalysis.
Correlation Development for Para-to-Ortho Hydrogen Catalytic Conversion in Vapor-Cooled Shields of Hydrogen Tanks
Nov 2025
Publication
The cooling effect from the para-ortho hydrogen conversion (POC) combined with a vaporcooled shield (VCS) and multi-layer insulation (MLI) can effectively extend the storage duration of liquid hydrogen in cryogenic tanks. However there is currently no effective and straightforward empirical correlation available for predicting the catalytic POC efficiency in VCS pipelines. This study focuses on the development of correlations for the catalytic conversion of para-hydrogen to ortho-hydrogen in pipelines particularly in the context of cryogenic hydrogen storage systems. A model that incorporates the Langmuir adsorption characteristics of catalysts and introduces the concept of conversion efficiency to quantify the catalytic process’s performance is introduced. Experimental data were obtained in the temperature range of 141.9~229.9 K from a cryogenic hydrogen catalytic conversion facility where the effects of temperature pressure and flow rate on the catalytic conversion efficiency were analyzed. Based on a validation against the experimental data the proposed model offers a reliable method for predicting the cooling effects and optimizing the catalytic conversion process in VCS pipelines which may contribute to the improvement of liquid hydrogen storage systems enhancing both the efficiency and duration of storage.
No more items...