United Kingdom
Extreme Energetic Materials at Ultrahigh Pressures
Jul 2020
Publication
Owing to their extremely high energy density single-bonded polymeric nitrogen and atomic metallic hydrogen are generally regarded as the ultimate energetic materials. Although their syntheses normally require ultrahigh pressures of several hundred gigapascals (GPa) which prohibit direct materials application research on their stability metastability and fundamental properties are valuable for seeking extreme energetic materials through alternative synthetic routes. Various crystalline and amorphous polymeric nitrogens have been discovered between 100 and 200 GPa. Metastability at ambient conditions has been demonstrated for some of these phases. Cubic-gauche and black-phosphorus polymorphs of single-bonded nitrogen are two particularly interesting phases. Their large hystereses warrant further application-inspired basic research of nitrogen. In contrast although metallic hydrogen contains the highest-estimated energy density its picosecond lifetime and picogram quantity make its practical material application impossible at present. “Metallic hydrogen” remains a curiosity-driven basic research pursuit focusing on the pressure-induced evolution of the molecular hydrogen crystal and its electronic band structure from a low-density insulator with a very wide electronic band gap to a semiconductor with a narrow gap to a dense molecular metal and atomic metal and eventually to a previously unknown exotic state of matter. This great experimental challenge is driving relentless advancement in ultrahigh-pressure science and technology.
Hy4Heat Safety Assessment: Precis - Work Package 7
May 2021
Publication
The Hy4Heat Safety Assessment has focused on assessing the safe use of hydrogen gas in certain types of domestic properties and buildings. The summary reports (the Precis and the Safety Assessment Conclusions Report) bring together all the findings of the work and should be looked to for context by all readers. The technical reports should be read in conjunction with the summary reports. While the summary reports are made as accessible as possible for general readers the technical reports may be most accessible for readers with a degree of technical subject matter understanding. All of the safety assessment reports have now been reviewed by the HSE.<br/><br/>This document is an overview of the Safety Assessment work undertaken as part of the Hy4Heat programme
Methane Emissions from Natural Gas and LNG Imports: An Increasingly Urgent Issue for the Future of Gas in Europe
Nov 2020
Publication
Pressure is mounting on the natural gas and LNG community to reduce methane emissions and this is most urgent in EU countries following the adoption of much tougher greenhouse gas reduction targets of 2030 and the publication of the European Commission’s Methane Strategy. With rapidly declining indigenous EU production and therefore rising import dependence there are increasing calls for emissions from imported pipeline gas and LNG to be quantified and based on actual measurements as opposed to standard emission factors. The Methane Strategy promises to be a significant milestone in that process. Companies which are supplying (or intending to supply) natural gas to the EU – the largest global import market for pipeline gas and a very significant market for LNG – would be well advised to pay close attention to how the regulation of methane emissions is unfolding and to make an immediate and positive response. Failure to do so could accelerate the demise of natural gas in European energy balances faster than would otherwise have been the case and shorten the time available for transition to decarbonised gases – specifically hydrogen – using existing natural gas infrastructure.<br/>This EU initiative will (and arguably already has) attracted attention from non-EU governments and companies involved in global gas and LNG trade. We have already seen deliveries of `carbon neutral’ LNG cargos to Asia as well as a long-term LNG contract in which the greenhouse gas content of cargos will be measured reported and verified (MRV) according to an agreed methodology. Natural gas and LNG exports if based on these standards or those set out in the EU Methane Strategy may be able to command premium prices from buyers eager to demonstrate their own GHG reduction credentials to governments customers and civil society.
Decarbonising UK Transport: Implications for Electricity Generation, Land Use and Policy
Dec 2022
Publication
To ensure the UK’s net zero targets are met the transition from conventionally fueled transport to low emission alternatives is necessary. The impact from increased decarbonised electricity generation on ecosystem services (ES) and natural capital (NC) are not currently quantified with decarbonisation required to minimise impacts from climate change. This study aims to project the future electric and hydrogen energy demand between 2020 and 2050 for car bus and train to better understand the land/sea area that would be required to support energy generation. In this work predictions of the geospatial impact of renewable energy (onshore/offshore wind and solar) nuclear and fossil fuels on ES and NC were made considering generation mix number of generation installations and energy density. Results show that electric transport will require ~136599 GWh for all vehicle types analysed in 2050 much less than hydrogen transport at ~425532 GWh. We estimate that to power electric transport at least 1515 km2 will be required for solar 1672 km2 for wind and 5 km2 for nuclear. Hydrogen approximately doubles this requirement. Results provide an approximation of the future demands from the transport sector on land and sea area use indicating that a combined electric and hydrogen network will be needed to accommodate a range of socio-economic requirements. While robust assessments of ES and NC impacts are critical in future policies and planning significant reductions in energy demands through a modal shift to (low emission) public transport will be most effective in ensuring a sustainable transport future.
Can the Current EU Regulatory Framework Deliver Decarbonisation of Gas?
Jun 2020
Publication
This Energy Insight examines the current regulatory framework and challenges facing the natural gas industry (producers transporters suppliers and consumers) during the transition to a zero-carbon economy. The EU has declared its intention to be climate neutral by 2050 which means that the current level of natural gas usage will no longer be possible. However natural gas is a crucial component of energy supply representing 24 per cent of primary energy supply for the EU27+UK and 36 per cent of residential energy consumption. In some countries the use of natural gas is much higher – around 40 per cent of primary energy supply in Netherlands UK and Italy. The current framework impacting gas addresses two different market failures – natural monopolies for gas transportation and the externalities of Greenhouse Gas Emissions. The framework will not deliver decarbonisation of gas as it does not stimulate either supply or demand for alternatives such as hydrogen nor create the conditions to enable gas networks to transition to a decarbonised future. Policy makers need to prioritise their objectives to take account of the trade-offs involved in designing a new framework. Exclusion of certain low carbon technologies risks driving away investors and reduces the chances of targets being met whilst “picking winners” involves risks because of the many uncertainties involved such as future costs and time required to build new value chains.
Link to Document on Oxford Institute for Energy Studies website
Link to Document on Oxford Institute for Energy Studies website
Carbon Capture, Usage and Storage: An Update on Business Models for Carbon Capture, Usage and Storage
Dec 2020
Publication
An update on the proposed commercial frameworks for transport and storage power and industrial carbon capture business models.
Materials for End to End Hydrogen Roadmap
Jun 2021
Publication
This report is commissioned by the Henry Royce Institute for advanced materials as part of its role around convening and supporting the UK advanced materials community to help promote and develop new research activity. The overriding objective is to bring together the advanced materials community to discuss analyse and assimilate opportunities for emerging materials research for economic and societal benefit. Such research is ultimately linked to both national and global drivers namely Transition to Zero Carbon Sustainable Manufacture Digital & Communications Circular Economy as well as Health & Wellbeing.
This paper can be download from their website
This paper can be download from their website
Fuel Cell Industry Review 2019 - The Year of the Gigawatt
Jan 2020
Publication
E4tech’s 6th annual review of the global fuel cell industry is now available here. Using primary data straight from the main players and free to download it quantifies shipments by fuel cell type by application and by region of deployment and summarises industry developments over the year.
2019 saw shipments globally grow significantly to 1.1 GW. Numbers grew slightly to around 70000 units. The growth in capacity came mainly from cars Hyundai with its NEXO and Toyota with its Mirai together accounting for around two-thirds of shipments by capacity. Unit numbers are still dominated by Japan’s ene-Farm cogeneration appliances at around 45000 shipments. Large numbers of trucks and buses are now manufactured and shipped in China though numbers deployed are limited by the availability of refuelling infrastructure. But growth in China is uncertain as policy changes are under discussion.
2020 looks like it will be an even bigger year again dominated by Hyundai and Toyota. The Japanese fuel cell market is expected also to grow partly on the back of the Tokyo ‘Hydrogen Olympics’. Korea is another growth story buoyed by its latest roadmap which aims to shift large swathes of its economy to hydrogen energy by 2040. Elsewhere much of the supply chain development is in heavy duty vehicles and big supply chain players like Cummins Weichai and Michelin are making significant investments.
2019 saw shipments globally grow significantly to 1.1 GW. Numbers grew slightly to around 70000 units. The growth in capacity came mainly from cars Hyundai with its NEXO and Toyota with its Mirai together accounting for around two-thirds of shipments by capacity. Unit numbers are still dominated by Japan’s ene-Farm cogeneration appliances at around 45000 shipments. Large numbers of trucks and buses are now manufactured and shipped in China though numbers deployed are limited by the availability of refuelling infrastructure. But growth in China is uncertain as policy changes are under discussion.
2020 looks like it will be an even bigger year again dominated by Hyundai and Toyota. The Japanese fuel cell market is expected also to grow partly on the back of the Tokyo ‘Hydrogen Olympics’. Korea is another growth story buoyed by its latest roadmap which aims to shift large swathes of its economy to hydrogen energy by 2040. Elsewhere much of the supply chain development is in heavy duty vehicles and big supply chain players like Cummins Weichai and Michelin are making significant investments.
Reference Standard for Low Pressure Hydrogen Utilisation
May 2021
Publication
This standard has been created for the specific purposes of the Hy4Heat programme. The standard was commissioned in 2018 and this version was considered and approved by the relevant IGEM committees in May of 2020. This version of the standard was developed using the latest publicly available information at that time and may include some conservative requirements which further research may deem not necessary. The supplement will be updated regularly following the publication of new research into the application of hydrogen.
This Reference Standard aims to identify and discuss the principles required for the safety and integrity of Hydrogen installation and utilisation in premises.
This document intends to:
The standard is available to download through the IGEM website here.
This Reference Standard aims to identify and discuss the principles required for the safety and integrity of Hydrogen installation and utilisation in premises.
This document intends to:
- provide a point of reference for those requiring an understanding of the implications of using hydrogen as a distributed gas in properties
- detail the characteristics of Hydrogen
- detail the comparisons between hydrogen and Natural Gas (NG)
- discuss the safety implications of using hydrogen
- discuss the implications for materials when using hydrogen
- discuss the implications for the installation and use of using hydrogen in domestic & smaller commercial buildings.
The standard is available to download through the IGEM website here.
The Future Role of Gas in Transport
Mar 2021
Publication
This is a Network Innovation Allowance funded project overseen by a steering group comprising the UK and Ireland gas network operators (Cadent Gas Networks Ireland National Grid Northern Gas Networks SGN Wales and West). The project follows on from previous studies that modelled the role of green gases in decarbonising the GB economy. The role of this study is to understand the transition from the GB economy today to a decarbonised economy in 2050 focusing on how the transition is achieved and the competing and complementary nature of different low and zero emission fuels and technologies over time.
While the project covers the whole economy it focuses on transport especially trucks as an early adopter of green gases and as a key enabler of the transition. The study and resulting report are aimed at the gas industry and government and tries to build a green gas decarbonisation narrative supported by a wide range of stakeholders in order clarify the path ahead and thereby focus future efforts on delivering decarbonisation through green gases as quickly as possible.
The objectives of the study are:
Green gases
This report discusses the future role of ‘green gases’ which are biomethane and hydrogen produced from low- and zero-carbon sources each produced via two main methods:
Biomethane from Anaerobic Digestion (AD): A mature technology for turning biological material into a non-fossil form of natural gas (methane). AD plants produce biogas which must then be upgraded to biomethane.
Biomethane from Bio-Substitute Natural Gas (Bio-SNG): This technology is at an earlier stage of development than AD but has the potential to unlock other feedstocks for biomethane production such as waste wood and residual household waste.
Blue Hydrogen: Hydrogen from reformation of natural gas which produces hydrogen and carbon monoxide. 90-95% of the carbon is captured and stored making this a low-carbon form of hydrogen.
Green Hydrogen: Water is split into hydrogen and oxygen via electrolysis using electricity generated by renewables. No carbon emissions are produced so this is zero-carbon hydrogen."
While the project covers the whole economy it focuses on transport especially trucks as an early adopter of green gases and as a key enabler of the transition. The study and resulting report are aimed at the gas industry and government and tries to build a green gas decarbonisation narrative supported by a wide range of stakeholders in order clarify the path ahead and thereby focus future efforts on delivering decarbonisation through green gases as quickly as possible.
The objectives of the study are:
- Analyse the complete supply chain production distribution and use of electricity biomethane bio-SNG and hydrogen to understand the role of each fuel and the timeline for scaling up of their use.
- Develop a narrative based on these findings to show how the use of these fuels scales up over time and how they compete and complement one another.
Green gases
This report discusses the future role of ‘green gases’ which are biomethane and hydrogen produced from low- and zero-carbon sources each produced via two main methods:
Biomethane from Anaerobic Digestion (AD): A mature technology for turning biological material into a non-fossil form of natural gas (methane). AD plants produce biogas which must then be upgraded to biomethane.
Biomethane from Bio-Substitute Natural Gas (Bio-SNG): This technology is at an earlier stage of development than AD but has the potential to unlock other feedstocks for biomethane production such as waste wood and residual household waste.
Blue Hydrogen: Hydrogen from reformation of natural gas which produces hydrogen and carbon monoxide. 90-95% of the carbon is captured and stored making this a low-carbon form of hydrogen.
Green Hydrogen: Water is split into hydrogen and oxygen via electrolysis using electricity generated by renewables. No carbon emissions are produced so this is zero-carbon hydrogen."
Contrasting European Hydrogen Pathways: An Analysis of Differing Approaches in Key Markets
Mar 2021
Publication
European countries approach the market ramp-up of hydrogen very differently. In some cases the economic and political starting points differ significantly. While the probability is high that some countries such as Germany or Italy will import hydrogen in the long term other countries such as United Kingdom France or Spain could become hydrogen exporters. The reasons for this are the higher potential for renewable energies but also a technology-neutral approach on the supply side.
Unpacking Leadership-driven Global Scenarios Towards the Paris Agreement: Report Prepared for the UK Committee on Climate Change
Dec 2020
Publication
Outline
This independent report by Vivid Economics and University College London was commissioned to support the Climate Change Committee’s (CCC) 2020 report The Sixth Carbon Budget -The path to Net Zero. This research provided supporting information for Chapter 7 of the CCC’s report which considered the UK’s contribution to the global goals of the Paris Agreement.
Key recommendations
The report models ‘leadership-driven’ global scenarios that could reduce global emissions rapidly to Net Zero and analyses the levers available to developed countries such as the UK to help accelerate various key aspects of the required global transition.
It highlights a set of opportunities for the UK alongside other developed countries to help assist global decarbonisation efforts alongside achieving it’s domestic emissions reduction targets
This independent report by Vivid Economics and University College London was commissioned to support the Climate Change Committee’s (CCC) 2020 report The Sixth Carbon Budget -The path to Net Zero. This research provided supporting information for Chapter 7 of the CCC’s report which considered the UK’s contribution to the global goals of the Paris Agreement.
Key recommendations
The report models ‘leadership-driven’ global scenarios that could reduce global emissions rapidly to Net Zero and analyses the levers available to developed countries such as the UK to help accelerate various key aspects of the required global transition.
It highlights a set of opportunities for the UK alongside other developed countries to help assist global decarbonisation efforts alongside achieving it’s domestic emissions reduction targets
Hydrogen Generation by Photocatalytic Reforming of Potential Biofuels: Polyols, Cyclic Alcohols, and Saccharides
Jan 2018
Publication
We have studied hydrogen gas production using photocatalysis from C2-C5 carbon chain polyols cyclic alcohols and mono and di-saccharides using palladium nanoparticles supported on a TiO2 catalyst. For many of the polyols the hydrogen evolution rate is found to be dictated by the number of hydroxyl groups and available a-hydrogens in the structure. However the rule only applies to polyols and cyclic alcohols while the sugar activity is limited by the bulky structure of those molecules. There was also evidence of ring opening in photocatalytic reforming of cyclic alcohols that involved dehydrogenation and decarbonylation of a CC bond.
Transport Pathway to Hydrogen webinar
Mar 2021
Publication
Webinar to accompany the launch of the Cadent Future Role of Gas in Transport report which can be found here
H21- Phase 1 Technical Summary Report
May 2021
Publication
The UK Government signed legislation on 27th June 2019 committing the UK to a legally binding target of Net Zero emissions by 2050. Climate change is one of the most significant technical economic social and business challenges facing the world today.
The H21 NIC Phase 1 project delivered an optimally designed experimentation and testing programme supported by the HSE Science Division and DNV GL with the aim to collect quantifiable evidence to support that the UK distribution network of 2032 will be comparably as safe operating on 100% hydrogen as it currently is on
natural gas. This innovative project begins to fill critical safety evidence gaps surrounding the conversion of the UK gas network to 100% hydrogen. This will facilitate progression towards H21 Phase 2 Operational Safety Demonstrations and the H21 Phase 3 Live Trials to promote customer acceptability and ultimately aid progress towards a government policy decision on heat.
DNV GL and HSE Science Division were engaged to undertake the experimentation testing and QRA update programme of work. DNV GL and HSE Science Division also peer reviewed each other’s programme of work at various stages throughout the project undertaking a challenge and review of the experimental data and results to provide confidence in the conclusions.
A strategic set of tests was designed to cover the range of assets represented across the Great Britain gas distribution networks. The assets used in the testing were mostly recovered from the distribution network as part of the ongoing Iron Mains Risk Reduction Replacement Programme. Controlled testing against a well-defined master testing plan with both natural gas and 100% hydrogen was then undertaken to provide the quantitative evidence to forecast any change to background leakage levels in a 100% hydrogen network.
Key Findings from Phase 1a:
The H21 NIC Phase 1 project delivered an optimally designed experimentation and testing programme supported by the HSE Science Division and DNV GL with the aim to collect quantifiable evidence to support that the UK distribution network of 2032 will be comparably as safe operating on 100% hydrogen as it currently is on
natural gas. This innovative project begins to fill critical safety evidence gaps surrounding the conversion of the UK gas network to 100% hydrogen. This will facilitate progression towards H21 Phase 2 Operational Safety Demonstrations and the H21 Phase 3 Live Trials to promote customer acceptability and ultimately aid progress towards a government policy decision on heat.
DNV GL and HSE Science Division were engaged to undertake the experimentation testing and QRA update programme of work. DNV GL and HSE Science Division also peer reviewed each other’s programme of work at various stages throughout the project undertaking a challenge and review of the experimental data and results to provide confidence in the conclusions.
A strategic set of tests was designed to cover the range of assets represented across the Great Britain gas distribution networks. The assets used in the testing were mostly recovered from the distribution network as part of the ongoing Iron Mains Risk Reduction Replacement Programme. Controlled testing against a well-defined master testing plan with both natural gas and 100% hydrogen was then undertaken to provide the quantitative evidence to forecast any change to background leakage levels in a 100% hydrogen network.
Key Findings from Phase 1a:
- Of the 215 assets tested 41 of them were found to leak 19 of them provided sufficient data to be able to compare hydrogen and methane leak rates.
- The tests showed that assets that were gas tight on methane were also gas tight on hydrogen. Assets that leaked on hydrogen also leaked
- on methane including repaired assets.
- The ratio of the hydrogen to methane volumetric leak rates varied between 1.1 and 2.2 which is largely consistent with the bounding values expected for laminar and turbulent (or inertial) flow which gave ratios of 1.2 and 2.8 respectively.
- None of the PE assets leaked; cast ductile and spun iron leaked to a similar degree (around 26-29% of all iron assets leaked) and the proportion of leaking steel assets was slightly less (14%).
- Four types of joint were responsible for most of the leaks on joints: screwed lead yarn bolted gland and hook bolts.
- All of the repairs that sealed methane leaks also were effective when tested with hydrogen.
Energy System Requirements of Fossil-free Steelmaking using Hydrogen Direct Reduction
May 2021
Publication
The iron and steel industry is one of the world’s largest industrial emitters of greenhouse gases. One promising option for decarbonising the industry is hydrogen direct reduction of iron (H-DR) with electric arc furnace (EAF) steelmaking powered by zero carbon electricity. However to date little attention has been given to the energy system requirements of adopting such a highly energy-intensive process. This study integrates a newly developed long-term energy system planning tool with a thermodynamic process model of H-DR/EAF steelmaking developed by Vogl et al. (2018) to assess the optimal combination of generation and storage technologies needed to provide a reliable supply of electricity and hydrogen. The modelling tools can be applied to any country or region and their use is demonstrated here by application to the UK iron and steel industry as a case study. It is found that the optimal energy system comprises 1.3 GW of electrolysers 3 GW of wind power 2.5 GW of solar 60 MW of combined cycle gas with carbon capture 600 GWh/600 MW of hydrogen storage and 30 GWh/130 MW of compressed air energy storage. The hydrogen storage requirements of the industry can be significantly reduced by maintaining some dispatchable generation for example from 600 GWh with no restriction on dispatchable generation to 140 GWh if 20% of electricity demand is met using dispatchable generation. The marginal abatement costs of a switch to hydrogen-based steelmaking are projected to be less than carbon price forecasts within 5–10 years.
Wax: A Benign Hydrogen-storage Material that Rapidly Releases H2-rich Gases Through Microwave-assisted Catalytic Decomposition
Oct 2016
Publication
Hydrogen is often described as the fuel of the future especially for application in hydrogen powered fuel-cell vehicles (HFCV’s). However its widespread implementation in this role has been thwarted by the lack of a lightweight safe on-board hydrogen storage material. Here we show that benign readily available hydrocarbon wax is capable of rapidly releasing large amounts of hydrogen through microwave-assisted catalytic decomposition. This discovery offers a new material and system for safe and efficient hydrogen storage and could facilitate its application in a HFCV. Importantly hydrogen storage materials made of wax can be manufactured through completely sustainable processes utilizing biomass or other renewable feedstocks.
Approaches and Methods to Demonstrate Repurposing of the UK's Local Transmission System (LTS) Pipelines for Transportation of Hydrogen
Sep 2021
Publication
Hydrogen has the potential as an energy solution to contribute to decarbonisation targets as it has the capability to deliver low-carbon energy at the scale required. For this to be realised the suitability of the existing natural gas pipeline networks for transporting hydrogen must be established. The current paper describes a feasibility study that was undertaken to assess the potential for repurposing the UK’s Local Transmission System (LTS) natural gas pipelines for hydrogen service. The analysis focused on SGN’s network which includes 3000 km of LTS pipelines in Scotland and the south of England. The characteristics of the LTS pipelines in terms of materials of construction and operation were first evaluated. This analysis showed that a significant percentage of SGN’s LTS network consists of lower strength grades of steel pipeline that operate at low stresses which are factors conducive to a pipeline’s suitability for hydrogen service. An assessment was also made of where existing approaches in pipeline operation may require modifications for hydrogen. The effects of changes in mechanical properties of steel pipelines on integrity and lifetime as a result of potential hydrogen degradation were demonstrated using fitness-for-purpose analysis. A review of pipeline risk assessment and Land-Use Planning (LUP) zone calculations for hydrogen was undertaken to identify any required changes. Case studies on selected sections of the LTS pipeline were then carried out to illustrate the potential changes to LUP zones. The work concluded with a summary of identified gaps that require addressing to ensure safe pipeline repurposing for hydrogen which cover materials performance inspection risk assessment land use planning and procedures.
Preliminary Analysis of Compression System Integrated Heat Management Concepts Using LH2-Based Parametric Gas Turbine Model
Apr 2021
Publication
The investigation of the various heat management concepts using LH2 requires the development of a modeling environment coupling the cryogenic hydrogen fuel system with turbofan performance. This paper presents a numerical framework to model hydrogen-fueled gas turbine engines with a dedicated heat-management system complemented by an introductory analysis of the impact of using LH2 to precool and intercool in the compression system. The propulsion installations comprise Brayton cycle-based turbofans and first assessments are made on how to use the hydrogen as a heat sink integrated into the compression system. Conceptual tubular compact heat exchanger designs are explored to either precool or intercool the compression system and preheat the fuel to improve the installed performance of the propulsion cycles. The precooler and the intercooler show up to 0.3% improved specific fuel consumption for heat exchanger effectiveness in the range 0.5–0.6 but higher effectiveness designs incur disproportionately higher pressure losses that cancel-out the benefits.
HydroGenerally - Episode 2: Where Should Hydrogen Be Used?
Apr 2022
Publication
The Innovate UK KTN Hydrogen Innovation Network is bringing you this second episode with Steffan Eldred and Simon Buckley from Innovate UK KTN who continue their ‘back to basics' approach and delve deeper to understand where hydrogen should be used with their special guest Joanna Richart Head of Hydrogen Business at Ricardo. As with any technology or fuel discussions can get carried away implying they are the solution to all things but at Innovate UK KTN we strongly believe that we should ensure hydrogen is used where it can be most effective for decarbonising energy industrial and chemical industries.
The podcast can be found on their website
The podcast can be found on their website
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