United Kingdom
Enabling Large-scale Hydrogen Storage in Porous Media – The Scientific Challenges
Jan 2021
Publication
Niklas Heinemann,
Juan Alcalde,
Johannes M. Miocic,
Suzanne J. T. Hangx,
Jens Kallmeyer,
Christian Ostertag-Henning,
Aliakbar Hassanpouryouzband,
Eike M. Thaysen,
Gion J. Strobel,
Cornelia Schmidt-Hattenberger,
Katriona Edlmann,
Mark Wilkinson,
Michelle Bentham,
Stuart Haszeldine,
Ramon Carbonell and
Alexander Rudloff
Expectations for energy storage are high but large-scale underground hydrogen storage in porous media (UHSP) remains largely untested. This article identifies and discusses the scientific challenges of hydrogen storage in porous media for safe and efficient large-scale energy storage to enable a global hydrogen economy. To facilitate hydrogen supply on the scales required for a zero-carbon future it must be stored in porous geological formations such as saline aquifers and depleted hydrocarbon reservoirs. Large-scale UHSP offers the much-needed capacity to balance inter-seasonal discrepancies between demand and supply decouple energy generation from demand and decarbonise heating and transport supporting decarbonisation of the entire energy system. Despite the vast opportunity provided by UHSP the maturity is considered low and as such UHSP is associated with several uncertainties and challenges. Here the safety and economic impacts triggered by poorly understood key processes are identified such as the formation of corrosive hydrogen sulfide gas hydrogen loss due to the activity of microbes or permeability changes due to geochemical interactions impacting on the predictability of hydrogen flow through porous media. The wide range of scientific challenges facing UHSP are outlined to improve procedures and workflows for the hydrogen storage cycle from site selection to storage site operation. Multidisciplinary research including reservoir engineering chemistry geology and microbiology more complex than required for CH4 or CO2 storage is required in order to implement the safe efficient and much needed large-scale commercial deployment of UHSP.
Hydrogen Production from Natural Gas and Biomethane with Carbon Capture and Storage – A Techno-environmental Analysis
Mar 2020
Publication
This study presents an integrated techno-environmental assessment of hydrogen production from natural gas and biomethane combined with CO2 capture and storage (CCS). We have included steam methane reforming (SMR) and autothermal reforming (ATR) for syngas production. CO2 is captured from the syngas with a novel vacuum pressure swing adsorption (VPSA) process that combines hydrogen purification and CO2 separation in one cycle. As comparison we have included cases with conventional amine-based technology. We have extended standard attributional Life Cycle Assessment (LCA) following ISO standards with a detailed carbon balance of the biogas production process (via digestion) and its by-products. The results show that the life-cycle greenhouse gas (GHG) performance of the VPSA and amine-based CO2 capture technologies is very similar as a result of comparable energy consumption. The configuration with the highest plant-wide CO2 capture rate (almost 100% of produced CO2 captured) is autothermal reforming with a two-stage water-gas shift and VPSA CO2 capture – because the latter has an inherently high CO2 capture rate of 98% or more for the investigated syngas. Depending on the configuration the addition of CCS to natural gas reforming-based hydrogen production reduces its life-cycle Global Warming Potential by 45–85 percent while the other environmental life-cycle impacts slightly increase. This brings natural gas-based hydrogen on par with renewable electricity-based hydrogen regarding impacts on climate change. When biomethane is used instead of natural gas our study shows potential for net negative greenhouse gas emissions i.e. the net removal of CO2 over the life cycle of biowaste-based hydrogen production. In the special case where the biogas digestate is used as agricultural fertiliser and where a substantial amount of the carbon in the digestate remains in the soil the biowaste-based hydrogen reaches net-negative life cycle greenhouse gas emissions even without the application of CCS. Addition of CCS to biomethane-based hydrogen production leads to net-negative emissions in all investigated cases.
Hydrogen or Batteries for Grid Storage? A Net Energy Analysis
Apr 2015
Publication
Energy storage is a promising approach to address the challenge of intermittent generation from renewables on the electric grid. In this work we evaluate energy storage with a regenerative hydrogen fuel cell (RHFC) using net energy analysis. We examine the most widely installed RHFC configuration containing an alkaline water electrolyzer and a PEM fuel cell. To compare RHFC's to other storage technologies we use two energy return ratios: the electrical energy stored on invested (ESOIe) ratio (the ratio of electrical energy returned by the device over its lifetime to the electrical-equivalent energy required to build the device) and the overall energy efficiency (the ratio of electrical energy returned by the device over its lifetime to total lifetime electrical-equivalent energy input into the system). In our reference scenario the RHFC system has an ESOIeratio of 59 more favorable than the best battery technology available today (Li-ion ESOIe= 35). (In the reference scenario RHFC the alkaline electrolyzer is 70% efficient and has a stack lifetime of 100 000 h; the PEM fuel cell is 47% efficient and has a stack lifetime of 10 000 h; and the round-trip efficiency is 30%.) The ESOIe ratio of storage in hydrogen exceeds that of batteries because of the low energy cost of the materials required to store compressed hydrogen and the high energy cost of the materials required to store electric charge in a battery. However the low round-trip efficiency of a RHFC energy storage system results in very high energy costs during operation and a much lower overall energy efficiency than lithium ion batteries (0.30 for RHFC vs. 0.83 for lithium ion batteries). RHFC's represent an attractive investment of manufacturing energy to provide storage. On the other hand their round-trip efficiency must improve dramatically before they can offer the same overall energy efficiency as batteries which have round-trip efficiencies of 75–90%. One application of energy storage that illustrates the trade-off between these different aspects of energy performance is capturing overgeneration (spilled power) for later use during times of peak output from renewables. We quantify the relative energetic benefit of adding different types of energy storage to a renewable generating facility using [EROI]grid. Even with 30% round-trip efficiency RHFC storage achieves the same [EROI]grid as batteries when storing overgeneration from wind turbines because its high ESOIeratio and the high EROI of wind generation offset the low round-trip efficiency.
Hydrogen an Enabler of the Grand Transition Future Energy Leader Position Paper
Jan 2018
Publication
A major transformation and redesign of the global energy system is required towards decarbonisation and to achieve the Paris Agreement targets. This Grand Transition is a complex pressing issue where global joint efforts and system solutions are essential; with hydrogen being one of them.<br/>Hydrogen has the potential to be a powerful effective accelerator towards a low-carbon energy system capable of addressing multiple energy challenges: from facilitating the massive integration of renewables and decarbonisation of energy production to energy transportation in a zero-carbon energy economy to electrification of end uses.
Innovation Insights Brief - Five Steps to Energy Storage
Jan 2020
Publication
As the global electricity systems are shaped by decentralisation digitalisation and decarbonisation the World Energy Council’s Innovation Insights Briefs explore the new frontiers in energy transitions and the challenges of keeping pace with fast moving developments. We use leadership interviews to map the state of play and case studies across the whole energy landscape and build a broader and deeper picture of new developments within and beyond the new energy technology value chain and business ecosystem.<br/><br/>With major decarbonisation efforts and the scaling up of renewable power generation the widespread adoption of energy storage continues to be described as the key game changer for electricity systems. Affordable storage systems are a critical missing link between intermittent renewable power and a 24/7 reliability net-zero carbon scenario. Beyond solving this salient challenge energy storage is being increasingly considered to meet other needs such as relieving congestion or smoothing out the variations in power that occur independently of renewable-energy generation. However whilst there is plenty of visionary thinking recent progress has focused on short-duration and battery-based energy storage for efficiency gains and ancillary services; there is limited progress in developing daily weekly and even seasonal cost-effective solutions which are indispensable for a global reliance on intermittent renewable energy sources.
Hydrogen: A Critical Part of Heat Decarbonisation
Feb 2021
Publication
The use of clean hydrogen is likely to form a key part of a net-zero emissions future and has the potential to replace natural gas for end use heating. As part of BDR Thermea Group Baxi Heating UK are at the forefront of hydrogen boiler development. Working with the Hy4Heat programme hydrogen fuelled boilers have been produced for inclusion in trial sites across the UK. This presentation will explore progress to date together with the hydrogen-ready boiler concept.
The Pathway to Net Zero Heating in the UK: A UKERC Policy Brief
Oct 2020
Publication
There is uncertainty over how heating might practically be decarbonised in the future. This briefing provides some clarity about the possible pathways forward focusing on the next 5-10 years.<br/>Meeting the UK government’s net zero emissions goal for 2050 will only be possible by complete decarbonisation of the building stock (both existing and new). There is uncertainty over the extent to which heating might practically be decarbonised in the future and what the optimal technologies may be. This paper provides some clarity about the pathways forward focusing on the next 5-10 years.
Synthesis of Activated Ferrosilicon-based Microcomposites by Ball Milling and their Hydrogen Generation Properties
Jan 2019
Publication
Ferrosilicon 75 a 50:50 mixture of silicon and iron disilicide has been activated toward hydrogen generation by processing using ball milling allowing a much lower concentration of sodium hydroxide (2 wt %) to be used to generate hydrogen from the silicon in ferrosilicon with a shorter induction time than has been reported previously. An activation energy of 62 kJ/mol was determined for the reaction of ball-milled ferrosilicon powder with sodium hydroxide solution which is around 30 kJ/mol lower than that previously reported for unmilled ferrosilicon. A series of composite powders were also prepared by ball milling ferrosilicon with various additives in order to improve the hydrogen generation properties from ferrosilicon 75 and attempt to activate the silicon in the passivating FeSi2 component. Three different classes of additives were employed: salts polymers and sugars. The effects of these additives on hydrogen generation from the reaction of ferrosilicon with 2 wt% aqueous sodium hydroxide were investigated. It was found that composites formed of ferrosilicon and sodium chloride potassium chloride sodium polyacrylate sodium polystyrene sulfonate-co-maleic acid or fructose showed reduced induction times for hydrogen generation compared to that observed for ferrosilicon alone and all but fructose also led to an increase in the maximum hydrogen generation rate. In light of its low cost and toxicity and beneficial effects sodium chloride is considered to be the most effective of these additives for activating the silicon in ferrosilicon toward hydrogen generation. Materials characterisation showed that neither ball milling on its own nor use of additives was successful in activating the FeSi2 component of ferrosilicon for hydrogen generation and the improvement in rate and shortening of the induction period was attributed to the silicon component of the mixture alone The gravimetric storage capacity for hydrogen in ferrosilicon 75 is therefore maintained at only 3.5% rather than the 10.5% ideally expected for a material containing 75% silicon. In light of these results ferrosilicon 75 does not appear a good candidate for hydrogen production in portable applications.
Exploring the Evidence on Potential Issues Associated with Trialling Hydrogen Heating in Communities
Dec 2020
Publication
Replacing natural gas with hydrogen in an everyday setting – piping hydrogen to homes and businesses through the existing gas network – is a new and untested proposition. At the same time piloting this proposition is an essential ingredient to a well-managed low carbon transition.<br/>The Department of Business Energy and Industrial Strategy (BEIS) has commissioned CAG Consultants to undertake a literature review and conduct a set of four focus groups to inform the development of work to assess issues associated with setting up a hypothetical community hydrogen trial. This report sets out the findings from the research and presents reflections on the implications of the findings for any future community hydrogen heating trials.<br/>The literature review was a short focused review aimed at identifying evidence relevant to members of the public being asked to take part in a hypothetical community trial. Based primarily on Quick Scoping Review principles the review involved the analysis of evidence from 26 items of literature. The four focus groups were held in-person in two city locations Manchester and Birmingham in November 2019. They involved consumers who either owned or rented houses (i.e. not flats) connected to the gas grid. Two of the focus groups involved owner-occupiers one was with private landlords and the other was with a mixture of tenants (private social and student).<br/>This report was produced in October 2019 and published in December 2020.
City Blood: A Visionary Infrastructure Solution for Household Energy Provision through Water Distribution Networks
May 2013
Publication
This paper aims to expand current thinking about the future of energy and water utility provision by presenting a radical idea: it proposes a combined delivery system for household energy and water utilities which is inspired by an analogy with the human body. It envisions a multi-functional infrastructure for cities of the future modelled on the human circulatory system. Red blood cells play a crucial role as energy carriers in biological energy distribution; they are suspended in the blood and distributed around the body to fuel the living cells. So why not use an analogous system e an urban circulatory system or “city blood” e to deliver energy and water simultaneously via one dedicated pipeline system? This paper focuses on analysing the scientific technological and economic feasibilities and hurdles which would need to be overcome in order to achieve this idea.<br/>We present a rationale for the requirement of an improved household utility delivery infrastructure and discuss the inspirational analogy; the technological components required to realise the vignette are also discussed. We identify the most significant advance requirement for the proposal to succeed: the utilisation of solid or liquid substrate materials delivered through water pipelines; their benefits and risks are discussed.
Exploring Possible Transition Pathways for Hydrogen Energy: A Hybrid Approach Using Socio-technical Scenarios and Energy System Modelling
Jul 2014
Publication
Hydrogen remains an important option for long-term decarbonisation of energy and transport systems. However studying the possible transition paths and development prospects for a hydrogen energy system is challenging. The long-term nature of technological transitions inevitably means profound uncertainties diverging perspectives and contested priorities. Both modelling approaches and narrative storyline scenarios are widely used to explore the possible future of hydrogen energy but each approach has shortcomings.<br/>This paper presents a hybrid approach to assessing hydrogen transitions in the UK by confronting qualitative socio-technical scenarios with quantitative energy systems modelling through a process of ‘dialogue’ between scenario and model. Three possible transition pathways are explored each exploring different uncertainties and possible decision points. Conclusions are drawn for both the future of hydrogen and on the value of an approach that brings quantitative formal models and narrative scenario techniques into dialogue.
Hy4Heat Progress Report
Jan 2021
Publication
Hy4Heat’s mission is to establish if it is technically possible safe and convenient to replace natural gas (methane) with hydrogen in residential and commercial buildings and gas appliances. This will enable the government to determine whether to proceed to a community trial.
There is growing international consensus that hydrogen will be essential to successfully tackling climate change. So BEIS is working to develop hydrogen as a strategic decarbonised energy carrier for the UK which will be an essential element of the UK’s efforts to transform and decarbonise our energy system in line with our legally binding 2050 net zero commitment. Hydrogen can be used across multiple end-use sectors including industry transport heat and power. BEIS is looking to support and develop low carbon hydrogen production methods which will position hydrogen as a highly effective decarbonisation option particularly in hard-to electrify sectors and processes.
At the end of 2017 BEIS appointed Arup to be the programme manager for the Hy4Heat programme. Arup partnered with technical and industry specialists: Kiwa Gastec Progressive Energy Embers and Yo Energy and together the team oversees the programme and technical management of all the work packages. For the past three years Hy4Heat has been exploring whether replacing natural gas (methane) with hydrogen for domestic heating and cooking is feasible and could be part of a plausible potential pathway to help meet heat decarbonisation targets. To do this the programme has been seeking to provide the technical performance usability and safety evidence to demonstrate whether hydrogen can be used for heat in buildings.
This report and any attachment is freely available on the Hy4Heat website here. The report can also be downloaded directly by clicking on the pdf icon above.
There is growing international consensus that hydrogen will be essential to successfully tackling climate change. So BEIS is working to develop hydrogen as a strategic decarbonised energy carrier for the UK which will be an essential element of the UK’s efforts to transform and decarbonise our energy system in line with our legally binding 2050 net zero commitment. Hydrogen can be used across multiple end-use sectors including industry transport heat and power. BEIS is looking to support and develop low carbon hydrogen production methods which will position hydrogen as a highly effective decarbonisation option particularly in hard-to electrify sectors and processes.
At the end of 2017 BEIS appointed Arup to be the programme manager for the Hy4Heat programme. Arup partnered with technical and industry specialists: Kiwa Gastec Progressive Energy Embers and Yo Energy and together the team oversees the programme and technical management of all the work packages. For the past three years Hy4Heat has been exploring whether replacing natural gas (methane) with hydrogen for domestic heating and cooking is feasible and could be part of a plausible potential pathway to help meet heat decarbonisation targets. To do this the programme has been seeking to provide the technical performance usability and safety evidence to demonstrate whether hydrogen can be used for heat in buildings.
This report and any attachment is freely available on the Hy4Heat website here. The report can also be downloaded directly by clicking on the pdf icon above.
Freeze-dried Ammonia Borane-polyethylene Oxide Composites: Phase Behaviour and Hydrogen Release
Feb 2018
Publication
A solid-state hydrogen storage material comprising ammonia borane (AB) and polyethylene oxide (PEO) has been produced by freeze-drying from aqueous solutions from 0% to 100% AB by mass. The phase mixing behaviour of AB and PEO has been investigated using X-ray diffraction which shows that a new ‘intermediate’ crystalline phase exists different from both AB and PEO as observed in our previous work (Nathanson et al. 2015). It is suggested that hydrogen bonding interactions between the ethereal oxygen atom (–O–) in the PEO backbone and the protic hydrogen atoms attached to the nitrogen atom (N–H) of AB molecules promote the formation of a reaction intermediate leading to lowered hydrogen release temperatures in the composites compared to neat AB. PEO also acts to significantly reduce the foaming of AB during hydrogen release. A temperature-composition phase diagram has been produced for the AB-PEO system to show the relationship between phase mixing and hydrogen release.
The Impact of Disruptive Powertrain Technologies on Energy Consumption and Carbon Dioxide Emissions from Heavy-duty Vehicles
Jan 2020
Publication
Minimising tailpipe emissions and the decarbonisation of transport in a cost effective way remains a major objective for policymakers and vehicle manufacturers. Current trends are rapidly evolving but appear to be moving towards solutions in which vehicles which are increasingly electrified. As a result we will see a greater linkage between the wider energy system and the transportation sector resulting in a more complex and mutual dependency. At the same time major investments into technological innovation across both sectors are yielding rapid advancements into on-board energy storage and more compact/lightweight on-board electricity generators. In the absence of sufficient technical data on such technology holistic evaluations of the future transportation sector and its energy sources have not considered the impact of a new generation of innovation in propulsion technologies. In this paper the potential impact of a number of novel powertrain technologies are evaluated and presented. The analysis considers heavy duty vehicles with conventional reciprocating engines powered by diesel and hydrogen hybrid and battery electric vehicles and vehicles powered by hydrogen fuel cells and freepiston engine generators (FPEGs). The benefits are compared for each technology to meet the expectations of representative medium and heavy-duty vehicle drivers. Analysis is presented in terms of vehicle type vehicle duty cycle fuel economy greenhouse gas (GHG) emissions impact on the vehicle etc.. The work shows that the underpinning energy vector and its primary energy source are the most significant factor for reducing primary energy consumption and net CO2 emissions. Indeed while an HGV with a BEV powertrain offers no direct tailpipe emissions it produces significantly worse lifecycle CO2 emissions than a conventional diesel powertrain. Even with a de-carbonised electricity system (100 g CO2/kWh) CO2 emissions are similar to a conventional Diesel fuelled HGV. For the HGV sector range is key to operator acceptability of new powertrain technologies. This analysis has shown that cumulative benefits of improved electrical powertrains on-board storage efficiency improvements and vehicle design in 2025 and 2035 mean that hydrogen and electric fuelled vehicles can be competitive on gravimetric and volumetric density. Overall the work demonstrates that presently there is no common powertrain solution appropriate for all vehicle types but how subtle improvements at a vehicle component level can have significant impact on the design choices for the wider energy system.
HyNet North West- from Vision to Reality
Jan 2018
Publication
HyNet North West (NW) is an innovative integrated low carbon hydrogen production distribution and carbon capture utilisation and storage (CCUS) project. It provides hydrogen distribution and CCUS infrastructure across Liverpool Manchester and parts of Cheshire in support of the Government’s Clean Growth Strategy (CGS) and achievement of the UK’s emissions reduction targets.<br/>Hydrogen will be produced from natural gas and sent via a new pipeline to a range of industrial sites for injection as a blend into the existing natural gas network and for use as a transport fuel. Resulting carbon dioxide (CO2) will be captured and together with CO2 from local industry which is already available sent by pipeline for storage offshore in the nearby Liverpool Bay gas fields. Key data for the Project are presented in Table ES1.
Properties of the Hydrogen Oxidation Reaction on Pt/C catalysts at Optimised High Mass Transport Conditions and its Relevance to the Anode Reaction in PEFCs and Cathode Reactions in Electrolysers
Jul 2015
Publication
Using a high mass transport floating electrode technique with an ultra-low catalyst loading (0.84–3.5 μgPt cm−2) of commonly used Pt/C catalyst (HiSPEC 9100 Johnson Matthey) features in the hydrogen oxidation reaction (HOR) and hydrogen evolution reaction (HER) were resolved and defined which have rarely been previously observed. These features include fine structure in the hydrogen adsorption region between 0.18 < V vs. RHE < 0.36 V vs. RHE consisting of two peaks an asymptotic decrease at potentials greater than 0.36 V vs. RHE and a hysteresis above 0.1 V vs. RHE which corresponded to a decrease in the cathodic scan current by up to 50% of the anodic scan. These features are examined as a function of hydrogen and proton concentration anion type and concentration potential scan limit and temperature. We provide an analytical solution to the Heyrovsky–Volmer equation and use it to analyse our results. Using this model we are able to extract catalytic properties (without mass transport corrections; a possible source of error) by simultaneously fitting the model to HOR curves in a variety of conditions including temperature hydrogen partial pressure and anion/H+ concentration. Using our model we are able to rationalise the pH and hydrogen concentration dependence of the hydrogen reaction. This model may be useful in application to fuel cell and electrolyser simulation studies.
Plasmonic Nickel Nanoparticles Decorated on to LaFeO3 Photocathode for Enhanced Solar Hydrogen Generation
Nov 2018
Publication
Plasmonic Ni nanoparticles were incorporated into LaFeO3 photocathode (LFO-Ni) to excite the surface plasmon resonances (SPR) for enhanced light harvesting for enhancing the photoelectrochemical (PEC) hydrogen evolution reaction. The nanostructured LFO photocathode was prepared by spray pyrolysis method and Ni nanoparticles were incorporated on to the photocathode by spin coating technique. The LFO-Ni photocathode demonstrated strong optical absorption and higher current density where the untreated LFO film exhibited a maximum photocurrent of 0.036 mA/cm2 at 0.6 V vs RHE and when incorporating 2.84 mmol Ni nanoparticles the photocurrent density reached a maximum of 0.066 mA/cm2 at 0.6 V vs RHE due to the SPR effect. This subsequently led to enhanced hydrogen production where more than double (2.64 times) the amount of hydrogen was generated compared to the untreated LFO photocathode. Ni nanoparticles were modelled using Finite Difference Time Domain (FDTD) analysis and the results showed optimal particle size in the range of 70–100 nm for Surface Plasmon Resonance (SPR) enhancement.
Enabling Efficient Networks For Low Carbon Futures: Options for Governance and Regulation
Sep 2015
Publication
This report summarises key themes emerging from the Energy Technologies Institute’s (ETI) project ‘Enabling efficient networks for low carbon futures’. The project aimed to explore the options for reforming the governance and regulatory arrangements to enable major changes to and investment in the UK’s energy network infrastructures. ETI commissioned four expert perspectives on the challenges and options facing the UK.
Advanced Hydrogen and CO2 Capture Technology for Sour Syngas
Apr 2011
Publication
A key challenge for future clean power or hydrogen projects via gasification is the need to reduce the overall cost while achieving significant levels of CO2 capture. The current state of the art technology for capturing CO2 from sour syngas uses a physical solvent absorption process (acid gas removal–AGR) such as Selexol™ or Rectisol® to selectively separate H2S and CO2 from the H2. These two processes are expensive and require significant utility consumption during operation which only escalates with increasing levels of CO2 capture. Importantly Air Products has developed an alternative option that can achieve a higher level of CO2 capture than the conventional technologies at significantly lower capital and operating costs. Overall the system is expected to reduce the cost of CO2 capture by over 25%.<br/>Air Products developed this novel technology by leveraging years of experience in the design and operation of H2 pressure swing adsorption (PSA) systems in its numerous steam methane reformers. Commercial PSAs typically operate on clean syngas and thus need an upstream AGR unit to operate in a gasification process. Air Products recognized that a H2 PSA technology adapted to handle sour feedgas (Sour PSA) would enable a new and enhanced improvement to a gasification system. The complete Air Products CO2 Capture technology (CCT) for sour syngas consists of a Sour PSA unit followed by a low-BTU sour oxycombustion unit and finally a CO2 purification / compression system.
Modeling Thermal Response of Polymer Composite Hydrogen Cylinders
Oct 2015
Publication
With the anticipated introduction of hydrogen fuel cell vehicles to the market there is an increasing need to address the fire resistance of hydrogen cylinders for onboard storage. Sufficient fire resistance is essential to ensure safe evacuation in the event of car fire accidents. The authors have developed a Finite Element (FE) model for predicting the thermal response of composite hydrogen cylinders within the frame of the open source FE code Elmer. The model accounts for the decomposition of the polymer matrix and effects of volatile gas transport in the composite. Model comparison with experimental data has been conducted using a classical one-dimensional test case of polymer composite subjected to fire. The validated model was then used to analyze a type-4 hydrogen cylinder subjected to an engulfing external propane fire mimicking a published cylinder fire experiment. The external flame is modelled and simulated using the open source code FireFOAM. A simplified failure criteria based on internal pressure increase is subsequently used to determine the cylinder fire resistance.
Kinetics Study and Modelling of Steam Methane Reforming Process Over a NiO/Al2O3 Catalyst in an Adiabatic Packed Bed Reactor
Dec 2016
Publication
Kinetic rate data for steam methane reforming (SMR) coupled with water gas shift (WGS) over an 18 wt. % NiO/α-Al2O3 catalyst are presented in the temperature range of 300–700 °C at 1 bar. The experiments were performed in a plug flow reactor under the conditions of diffusion limitations and away from the equilibrium conditions. The kinetic model was implemented in a one-dimensional heterogeneous mathematical model of catalytic packed bed reactor developed on gPROMS model builder 4.1.0®. The mathematical model of SMR process was simulated and the model was validated by comparing the results with the experimental values. The simulation results were in excellent agreement with the experimental results. The effect of various operating parameters such as temperature pressure and steam to carbon ratio on fuel and water conversion (%) H2 yield (wt. % of CH4) and H2 purity was modelled and compared with the equilibrium values.
Gas Goes Green: Britain's Hydrogen Network Plan Report
Jan 2021
Publication
Britain stands on the cusp of a world-leading hydrogen revolution and one which we are almost uniquely positioned to take advantage of. With an extensive world-leading gas grid huge amounts of offshore wind resource and liquid energy markets there are few other places as well positioned as the UK to lead the international race to build a hydrogen economy. Published as part of Energy Networks Association’s Gas Goes Green programme Britain’s Hydrogen Network Plan will play a vital role in delivering the UK’s ambitions for hydrogen as set out in the Prime Minister’s Ten Point Plan For A Green Industrial Revolution.<br/>This Plan sets out how Britain’s gas network companies will enable 100% hydrogen to be transported for use in different sectors of the UK economy. It also identifies the wider actions needed to provide hydrogen production and storage showing how transitioning the gas networks to hydrogen will allow hydrogen to play a full role in achieving net zero in the hard to decarbonise sectors such as industry heavy transport and domestic heating saving an estimated 40 million tonnes of CO2 emissions every year. All five of Britain’s gas network companies responsible for owning and operating £24bn of critical national energy infrastructure are committing through this Plan to delivering this work. It forms a key part of their ambition to building the world’s first zero carbon gas grid here in the UK.<br/>Britain’s Hydrogen Network Plan is founded on four tenets that will underpin the role of Britain’s gas network infrastructure in a hydrogen economy. These tenets reflect the breadth and scale of the impact that the transformation of our gas networks will have. They will guide how gas network companies ensure people’s safety in a fast moving and changing energy system. They reflect how the companies will maintain security of supply to our homes and businesses as we move away from the natural gas that has been the bedrock of our energy system for half a century. They will support the public’s ability to choose the right technology so households and businesses can choose the low carbon technologies that are best suited to their needs. And they will deliver jobs and investment so the transition of our gas networks has a lasting and enduring economic impact in communities across the country.<br/>As we look to the future the exciting role that hydrogen has to play in delivering a net zero economy is becoming increasingly clear. We look forward to working closely with the customers we serve the Government and the wider energy industry to turn that ambition into reality.
Photocatalytic Hydrogen Production by Biomimetic Indium Sulfide Using Mimosa Pudica Leaves as Template
Jan 2019
Publication
Biomimetic sulfur-deficient indium sulfide (In2.77S4) was synthesized by a template-assisted hydrothermal method using leaves of Mimosa pudica as a template for the first time. The effect of this template in modifying the morphology of the semiconductor particles was determined by physicochemical characterization revealing an increase in surface area decrease in microsphere size and pore size and an increase in pore volume density in samples synthesized with the template. X-ray photoelectron spectroscopy (XPS) analysis showed the presence of organic sulfur (Ssingle bondO/Ssingle bondC/Ssingle bondH) and sulfur oxide species (single bondSO2 SO32− SO42−) at the surface of the indium sulfide in samples synthesized with the template. Biomimetic indium sulfide also showed significant amounts of Fe introduced as a contaminant present on the Mimosa pudica leaves. The presence of these sulfur and iron species favors the photocatalytic activity for hydrogen production by their acting as a sacrificial reagent and promoting water oxidation on the surface of the templated particles respectively. The photocatalytic hydrogen production rates over optimally-prepared biomimetic indium sulfide and indium sulfide synthesized without the organic template were 73 and 22 μmol g−1 respectively indicating an improvement by a factor of three in the templated sample.
Scotland’s Energy Strategy Position Statement
Mar 2021
Publication
This policy statement provides:
An overview of our key priorities for the short to medium-term and then moves on to look at how we have continued to abide by the three key principles set out in Scotland's Energy Strategy published in 2017 in our policy design and delivery. Those principles are:
Separate sections have been included on Maximising Scotland's International Potential in the lead up to the UN Framework Convention on Climate Change Conference of the Parties (COP26) and on Consumers to reflect the challenging economic climate we currently face and to highlight the action being taken by the Scottish Government to ensure the cost of our energy transition does not fall unequally.
This statement provides an overview of our approach to supporting the energy sector in the lead up to COP26 and as we embark on a green economic recovery from the COVID-19 pandemic. It summarises how our recent policy publications such as our Hydrogen Policy Statement Local Energy Policy Statement and Offshore Wind Policy Statement collectively support the delivery of the Climate Change Plan update along with the future findings from our currently live consultations including our draft Heat in Buildings Strategy our Call for Evidence on the future development of the Low Carbon Infrastructure Transition Programme (LCITP) and our consultation on Scottish skills requirements for energy efficiency.
While this statement sets out our comprehensive programme of work across the energy sector the current Energy Strategy (2017) remains in place until any further Energy Strategy refresh is adopted by Ministers. It is at the stage of refreshing Scotland's Energy Strategy where we will embark on a series of stakeholder engagements and carry out the relevant impact assessments to inform our thinking on future policy development.
An overview of our key priorities for the short to medium-term and then moves on to look at how we have continued to abide by the three key principles set out in Scotland's Energy Strategy published in 2017 in our policy design and delivery. Those principles are:
- a whole-system view;
- an inclusive energy transition; and
- a smarter local energy model.
- Skills and Jobs;
- Supporting Local Communities:
- Investment; and
- Innovation
Separate sections have been included on Maximising Scotland's International Potential in the lead up to the UN Framework Convention on Climate Change Conference of the Parties (COP26) and on Consumers to reflect the challenging economic climate we currently face and to highlight the action being taken by the Scottish Government to ensure the cost of our energy transition does not fall unequally.
This statement provides an overview of our approach to supporting the energy sector in the lead up to COP26 and as we embark on a green economic recovery from the COVID-19 pandemic. It summarises how our recent policy publications such as our Hydrogen Policy Statement Local Energy Policy Statement and Offshore Wind Policy Statement collectively support the delivery of the Climate Change Plan update along with the future findings from our currently live consultations including our draft Heat in Buildings Strategy our Call for Evidence on the future development of the Low Carbon Infrastructure Transition Programme (LCITP) and our consultation on Scottish skills requirements for energy efficiency.
While this statement sets out our comprehensive programme of work across the energy sector the current Energy Strategy (2017) remains in place until any further Energy Strategy refresh is adopted by Ministers. It is at the stage of refreshing Scotland's Energy Strategy where we will embark on a series of stakeholder engagements and carry out the relevant impact assessments to inform our thinking on future policy development.
Modifications in the Composition of CuO/ZnO/Al2O3 Catalyst for the Synthesis of Methanol by CO2 Hydrogenation
Jun 2021
Publication
Renewable methanol obtained from CO2 and hydrogen provided from renewable energy was proposed to close the CO2 loop. In industry methanol synthesis using the catalyst CuO/ZnO/Al2O3 occurs at a high pressure. We intend to make certain modification on the traditional catalyst to work at lower pressure maintaining high selectivity. Therefore three heterogeneous catalysts were synthesized by coprecipitation to improve the activity and the selectivity to methanol under mild conditions of temperature and pressure. Certain modifications on the traditional catalyst Cu/Zn/Al2O3 were employed such as the modification of the synthesis time and the addition of Pd as a dopant agent. The most efficient catalyst among those tested was a palladium-doped catalyst 5% Pd/Cu/Zn/Al2O3. This had a selectivity of 64% at 210 °C and 5 bar.
Acorn: Developing Full-chain Industrial Carbon Capture and Storage in a Resource- and Infrastructure-rich Hydrocarbon Province
Jun 2019
Publication
Juan Alcalde,
Niklas Heinemann,
Leslie Mabon,
Richard H. Worden,
Heleen de Coninck,
Hazel Robertson,
Marko Maver,
Saeed Ghanbari,
Floris Swennenhuis,
Indira Mann,
Tiana Walker,
Sam Gomersal,
Clare E. Bond,
Michael J. Allen,
Stuart Haszeldine,
Alan James,
Eric J. Mackay,
Peter A. Brownsort,
Daniel R. Faulkner and
Steve Murphy
Research to date has identified cost and lack of support from stakeholders as two key barriers to the development of a carbon dioxide capture and storage (CCS) industry that is capable of effectively mitigating climate change. This paper responds to these challenges through systematic evaluation of the research and development process for the Acorn CCS project a project designed to develop a scalable full-chain CCS project on the north-east coast of the UK. Through assessment of Acorn's publicly-available outputs we identify strategies which may help to enhance the viability of early-stage CCS projects. Initial capital costs can be minimised by infrastructure re-use particularly pipelines and by re-use of data describing the subsurface acquired during oil and gas exploration activity. Also development of the project in separate stages of activity (e.g. different phases of infrastructure re-use and investment into new infrastructure) enables cost reduction for future build-out phases. Additionally engagement of regional-level policy makers may help to build stakeholder support by situating CCS within regional decarbonisation narratives. We argue that these insights may be translated to general objectives for any CCS project sharing similar characteristics such as legacy infrastructure industrial clusters and an involved stakeholder-base that is engaged with the fossil fuel industry.
Energy Innovation Needs Assessment: Overview
Nov 2019
Publication
This project provides evidence to identify the key innovation needs across the UK’s energy system to inform the prioritisation of public sector investment in low-carbon innovation including any future phases of the Department for Business Energy & Industrial Strategy (BEIS) Energy Innovation1 Programme. The BEIS Energy Innovation Programme aims to accelerate the commercialisation of innovative clean energy technologies and processes into the 2020s and 2030s. The current Programme with a budget of £505 million from 2015-2021 consists of six themes and invests in smart systems industry & CCS (Carbon Capture and Storage) the built environment nuclear renewables and support for energy entrepreneurs and green financing.
Vivid Economics was contracted to lead a consortium with technical expertise in each of the Energy Innovation Needs Assessment (EINA) priority areas. The programme relied on evidence from a programme of workshops with over 180 participants energy system modelling and detailed technical advice. Partners include the Carbon Trust E4tech Imperial College London and Fraser-Nash. The Energy Systems Catapult (ESC) provided analytical evidence using their Energy System Modelling Environment (ESME) to support an early pre-screening of technologies.
Innovations have been prioritised where there is a strong case for UK Government investment. The prioritisation in this report is based on evidence of the potential benefits to the UK via a lower cost energy system and larger export markets. We also consider whether there is a need for UK Government intervention in addition to private and international efforts.
A distinctive feature of this project is its focus on innovation that benefits the whole energy system. Internationally there are other efforts attempting to answer the question of where to target resources to maximise benefits from innovation2. In selecting priorities we identify innovations that can unlock value across electricity heat transport sectors and the rest of the economy.
Vivid Economics was contracted to lead a consortium with technical expertise in each of the Energy Innovation Needs Assessment (EINA) priority areas. The programme relied on evidence from a programme of workshops with over 180 participants energy system modelling and detailed technical advice. Partners include the Carbon Trust E4tech Imperial College London and Fraser-Nash. The Energy Systems Catapult (ESC) provided analytical evidence using their Energy System Modelling Environment (ESME) to support an early pre-screening of technologies.
Innovations have been prioritised where there is a strong case for UK Government investment. The prioritisation in this report is based on evidence of the potential benefits to the UK via a lower cost energy system and larger export markets. We also consider whether there is a need for UK Government intervention in addition to private and international efforts.
A distinctive feature of this project is its focus on innovation that benefits the whole energy system. Internationally there are other efforts attempting to answer the question of where to target resources to maximise benefits from innovation2. In selecting priorities we identify innovations that can unlock value across electricity heat transport sectors and the rest of the economy.
Energy Saving Technologies and Mass-thermal Network Optimization for Decarbonized Iron and Steel Industry: A Review
Jul 2020
Publication
The iron and steel industry relies significantly on primary energy and is one of the largest energy consumers in the manufacturing sector. Simultaneously numerous waste heat is lost and discharged directly into the environment in the process of steel production. Thus considering conservation of energy energy-efficient improvement should be a holistic target for iron and steel industry. The research gap is that almost all the review studies focus on the primary energy saving measures in iron and steel industry whereas few work summarize the secondary energy saving technologies together with former methods. The objective of this paper is to develop the concept of mass-thermal network optimization in iron and steel industry which unrolls a comprehensive map to consider current energy conservation technologies and low grade heat recovery technologies from an overall situation. By presenting an overarching energy consumption in the iron and steel industry energy saving potentials are presented to identify suitable technologies by using mass-thermal network optimization. Case studies and demonstration projects around the world are also summarized. The general guideline is figured out for the energy optimization in iron and steel industry while the improved mathematical models are regarded as the future challenge.
SGN Project Report - Flame Visibility Risk Assessment
Feb 2021
Publication
This report contains information on the relative risks of natural gas and hydrogen fires particularly regarding their visibility. The fires considered are those that could occur on the H100 Fife trial network. The H100 Fife project will connect a number of residential houses to 100% hydrogen gas supply. The project includes hydrogen production storage and a new distribution network. From a review of large and small-scale tests and incidents it is concluded that hydrogen flames are likely to be clearly visible for releases above 2 bar particularly for larger release rates. At lower pressures hydrogen flame visibility will be affected by ambient lighting background colour and release orientation although this is also the case for natural gas. Potential safety implications from lack of flame visibility are that SGN workers other utility workers or members of the public could inadvertently come into contact with an ignited release. However some releases would be detected through noise thrown soil or interaction with objects. From a workshop and review of risk reduction measures and analysis of historical interference damage incidents it is concluded that flames with the potential for reduced visibility are adequately controlled. This is due to the likelihood of such scenarios occurring being low and that the consequences of coming into contact with such a flame are unlikely to be severe. These conclusions are supported by cost-benefit analysis that shows that no additional risk mitigation measures are justified for the H100 project. It is recommended that the cost-benefit analysis is revisited before applying the approach to a network wider than the H100 project. It was observed that the addition of odorant at relevant concentrations did not have an effect on the visibility of hydrogen flames.
This report and any attachment is freely available on the ENA Smarter Networks Portal here. IGEM Members can download the report and any attachment directly by clicking on the pdf icon above.
This report and any attachment is freely available on the ENA Smarter Networks Portal here. IGEM Members can download the report and any attachment directly by clicking on the pdf icon above.
2020 It's Time To Get Real
Mar 2020
Publication
Gi Editor Sharon Baker-Hallam sits down with Chris Stark CEO of the Committee on Climate Change to talk about this year’s Sir Denis Rooke Memorial Lecture the economic opportunities to be found in going green and why 2020 is a critical year in the ongoing battle against rising global temperatures
Power-to-gas for Injection into the Gas Grid: What Can We Learn from Real-life Projects, Economic Assessments and Systems Modelling
Sep 2018
Publication
Power-to-gas is a key area of interest for decarbonisation and increasing flexibility in energy systems as it has the potential both to absorb renewable electricity at times of excess supply and to provide backup energy at times of excess demand. By integrating power-to-gas with the natural gas grid it is possible to exploit the inherent linepack flexibility of the grid and shift some electricity variability onto the gas grid. Furthermore provided the gas injected into the gas grid is low-carbon such as hydrogen from renewable power-to-gas then overall greenhouse gas emissions from the gas grid can be reduced.<br/>This work presents the first review of power-to-gas to consider real-life projects economic assessments and systems modelling studies and to compare them based on scope assumptions and outcomes. The review focuses on power-to-gas for injection into the gas grid as this application has specific economic technical and modelling opportunities and challenges.<br/>The review identified significant interest in and potential for power-to-gas in combination with the gas grid however there are still challenges to overcome to find profitable business cases and manage local and system-wide technical issues. Whilst significant modelling of power-to-gas has been undertaken more is needed to fully understand the impacts of power-to-gas and gas grid injection on the operational behaviour of the gas grid taking into account dynamic and spatial effects.
Business Energy and Industrial Strategy Committee Inquiry into Decarbonising Heat in Homes
Dec 2020
Publication
The Hydrogen Taskforce welcomes the opportunity to submit evidence to the Business Energy and Industrial Strategy Committee’s inquiry into decarbonising heat in homes. It is the Taskforce’s view that:
In March 2020 the Taskforce has defined a set of policy recommendations for Government which are designed to ensure that hydrogen can scale to meet the future demands of a net zero energy system: • Development of a cross departmental UK Hydrogen Strategy within UK Government;• Commit £1bn of capex funding over the next spending review period to hydrogen production storage and distribution projects;• Develop a financial support scheme for the production of hydrogen in blending industry power and transport.• Amend Gas Safety Management Regulations (GSMR) to enable hydrogen blending and take the next steps towards 100% hydrogen heating through supporting public trials and mandating 100% hydrogen-ready boilers by 2025; and• Commit to the support of 100 Hydrogen Refuelling Stations (HRS) by 2025 to support the rollout of hydrogen transport.
You can download the whole document from the Hydrogen Taskforce website here
- Decarbonising heat is one of the biggest challenges that the UK faces in meeting Net Zero and several solutions will be required;
- Hydrogen can play a valuable role in reducing the cost of decarbonising heat. Its high energy density enables it to be stored cost effectively at scale providing system resilience;
- Hydrogen heating can be implemented at minimal disruption to the consumer;
- The UK holds world-class advantages in hydrogen production distribution and application; and
- Other economies are moving ahead in the development of this sector and the UK must respond.
In March 2020 the Taskforce has defined a set of policy recommendations for Government which are designed to ensure that hydrogen can scale to meet the future demands of a net zero energy system: • Development of a cross departmental UK Hydrogen Strategy within UK Government;• Commit £1bn of capex funding over the next spending review period to hydrogen production storage and distribution projects;• Develop a financial support scheme for the production of hydrogen in blending industry power and transport.• Amend Gas Safety Management Regulations (GSMR) to enable hydrogen blending and take the next steps towards 100% hydrogen heating through supporting public trials and mandating 100% hydrogen-ready boilers by 2025; and• Commit to the support of 100 Hydrogen Refuelling Stations (HRS) by 2025 to support the rollout of hydrogen transport.
You can download the whole document from the Hydrogen Taskforce website here
Establishing a Regional Hydrogen Economy: Accelerating the Carbon Transition in South Yorkshire, UK
May 2019
Publication
The establishment of a strong hydrogen economy nationally and locally is a very real opportunity and one that is rapidly becoming within reach.<br/>This report presents a vision for the role that hydrogen could play specifically in South Yorkshire (UK) to help meet carbon reduction targets and contribute to the health and economic prosperity of the region.<br/>It also highlights five themes as levers of growth and explores potential actions and collaborations as well as a list of ambitions for future hydrogen projects. Hydrogen can be used in transport industry and heating. Synergies need exploring for example the by-product of oxygen from hydrogen production can be used by industry. Aggregating opportunities is important in developing a hydrogen economy.<br/>The report concludes with a call to action to build momentum for the South Yorkshire hydrogen economy and accelerate the drive to net zero emissions particularly in the most challenging sectors.<br/>This South Yorkshire specific report supports our global thought piece Establishing a Hydrogen Economy: The future of energy 2035
What is Needed to Deliver Carbon-neutral Heat Using Hydrogen and CCS?
Sep 2020
Publication
In comparison with the power sector large scale decarbonisation of heat has received relatively little attention at the infrastructural scale despite its importance in the global CO2 emissions landscape. In this study we focus on the regional transition of a heating sector from natural gas-based infrastructure to H2 using mathematical optimisation. A discrete spatio-temporal description of the geographical region of Great Britain was used in addition to a detailed description of all network elements for illustrating the key factors in the design of nation-wide H2 and CO2 infrastructure. We have found that the synergistic deployment of H2 production technologies such as autothermal reforming of methane and biomass gasification with CO2 abatement technologies such as carbon capture and storage (CCS) are critical in achieving cost-effective decarbonisation. We show that both large scale underground H2 storage and water electrolysis provide resilience and flexibility to the heating system competing on cost and deployment rates. The optimal regions for siting H2 production infrastructure are characterised by proximity to: (1) underground H2 storage (2) high demands for H2 (3) geological storage for CO2. Furthermore cost-effective transitions based on a methane reforming pathway may necessitate regional expansions in the supply of natural gas with profound implications for security of supply in nations that are already highly reliant potentially creating an infrastructure lock-in during the near term. We found that the total system cost comprising both investment and operational elements is mostly influenced by the natural gas price followed by biomass price and CapEx of underground caverns. Under a hybrid Regulated Asset Base (RAB) commercial framework with private enterprises delivering production infrastructure the total cost of heat supply over the infrastructure lifetime is estimated as 5.2–8.6 pence per kW h. Due to the higher cost relative to natural gas a Contract for Difference payment between d20 per MW h and d53 per MW h will be necessary for H2-derived heat to be competitive in the market.
Cohesive Zone Modelling of Hydrogen Assisted Fatigue Crack Growth: The Role of Trapping
Apr 2022
Publication
We investigate the influence of microstructural traps in hydrogen-assisted fatigue crack growth. To this end a new formulation combining multi-trap stress-assisted diffusion mechanism-based strain gradient plasticity and a hydrogen- and fatigue-dependent cohesive zone model is presented and numerically implemented. The results show that the ratio of loading frequency to effective diffusivity governs fatigue crack growth behaviour. Increasing the density of beneficial traps not involved in the fracture process results in lower fatigue crack growth rates. The combinations of loading frequency and carbide trap densities that minimise embrittlement susceptibility are identified providing the foundation for a rational design of hydrogen-resistant alloys.
The Decarbonisation of Heat
Mar 2020
Publication
This paper proposes that whilst the exact pathway to decarbonising heat in the UK is not yet clear there are a range of actions that could be taken in the next ten years to shift heat onto the right route to meet our 2050 net zero obligation. We already possess many of the skills and technologies required but there are a number of significant barriers preventing a spontaneous movement towards low carbon heat on the scale required – a starting impulse is needed.<br/><br/>Energy efficiency and low carbon heating have the potential to radically improve the quality of life of not just the poorest in our society but all residents of the United Kingdom. With the right approach the decarbonisation of heat can improve health outcomes for millions create new jobs in manufacturing and construction reduce air pollution in our cities and reduce the burden on our health service. This in addition to leading the world in mitigating the climate emergency.
H21- Leeds City Gate Project Report
Jul 2016
Publication
The H21 Leeds City Gate project is a study with the aim of determining the feasibility from both a technical and economic viewpoint of converting the existing natural gas network in Leeds one of the largest UK cities to 100% hydrogen. The project has been designed to minimise disruption for existing customers and to deliver heat at the same cost as current natural gas to customers. The project has shown that:
The project has provided costs for the scheme and has modelled these costs in a regulatory finance model. In addition the availability of low-cost bulk hydrogen in a gas network could revolutionise the potential for hydrogen vehicles and via fuel cells support a decentralised model of combined heat and power and localised power generation.
This report and any attachment is freely available on the ENA Smarter Networks Portal here. IGEM Members can download the report and any attachment directly by clicking on the pdf icon above.
- The gas network has the correct capacity for such a conversion
- It can be converted incrementally with minimal disruption to customers
- Minimal new energy infrastructure will be required compared to alternatives
- The existing heat demand for Leeds can be met via steam methane reforming and salt cavern storage using technology in use around the world today
The project has provided costs for the scheme and has modelled these costs in a regulatory finance model. In addition the availability of low-cost bulk hydrogen in a gas network could revolutionise the potential for hydrogen vehicles and via fuel cells support a decentralised model of combined heat and power and localised power generation.
This report and any attachment is freely available on the ENA Smarter Networks Portal here. IGEM Members can download the report and any attachment directly by clicking on the pdf icon above.
The Hydrogen Economy - Evaluation of the Materials Science and Engineering Issues
Jan 2005
Publication
The main objectives were to identify materials issues relating to the widespread use of hydrogen as a fuel.
MAIN FINDINGS
MAIN FINDINGS
- Hydrogen is seen by many as the answer to the environmental problems of reliance on fossil fuels for energy needs. A great deal of effort is currently being invested in research into all areas of the hydrogen economy such as fuel cells hydrogen generation transportation and storage.
- Fuel cells have the potential to provide power for a very wide range of applications ranging from small portable electronics devices to large stationary electricity production and vehicles covering the whole range of road vehicles and possibly extending to rail marine and even aviation.
- The main obstacles to achieving a viable hydrogen economy are costs of producing hydrogen from renewable sources issues relating to transportation and storage due to the low energy density of hydrogen gas and the cost and reliability of fuel cells.
- The main material considerations relating to the use of hydrogen are hydrogen embrittlement material properties at cryogenic temperatures (due to use of liquid hydrogen) and permeability.
- A number of new materials are likely to come to prominence in a hydrogen economy; high performance composites are likely to be used extensively for high pressure hydrogen cylinders new materials or combinations of materials may be used for hydrogen pipelines and a range of new materials are currently being considered for hydrogen storage such as metal hydrides and carbon nanotubes.
- Due to the effect of hydrogen on materials it is important to test any materials in the environment in which they would be used. Depending on the type of test this could require the use of very specialist expensive equipment.
Mapping of Hydrogen Fuel Quality in Europe
Nov 2020
Publication
As part of FCH-JU funded HyCoRA project running from 2014 to 2017 28 gaseous and 13 particulate samples were collected from hydrogen refuelling stations in Europe. Samples were collected with commercial sampling instruments and analysis performed in compliance with prevailing fuel quality standards. Sampling was conducted with focus on diversity in feedstock as well as commissioning date of the HRS. Results indicate that the strategy for sampling was good. No evidence of impurity cross-over was observed. Parallel samples collected indicate some variation in analytical results. It was however found that fuel quality was generally good. Fourteen analytical results were in violation with the fuel tolerance limits. Therefore eight or 29% of the samples were in violation with the fuel quality requirements. Nitrogen oxygen and organics were the predominant impurities quantified. Particulate impurities were found to be within fuel quality specifications. No correlation between fuel quality and hydrogen feedstock or HRS commissioning date was found. Nitrogen to oxygen ratios gave no indication of samples being contaminated by air. A comparison of analytical results between two different laboratories were conducted. Some difference in analytical results were observed.
Hydrogen for Cooking: A Review of Cooking Technologies, Renewable Hydrogen Systems and Techno-Economics
Dec 2022
Publication
About 3 billion people use conventional carbon-based fuels such as wood charcoal and animal dung for their daily cooking needs. Cooking with biomass causes deforestation and habitat loss emissions of greenhouse gases and smoke pollution that affects people’s health and well-being. Hydrogen can play a role in enabling clean and safe cooking by reducing household air pollution and reducing greenhouse gas emissions. This first-of-a-kind review study on cooking with hydrogen assessed existing cooking technologies and hydrogen systems in developing country contexts. Our critical assessment also included the modelling and experimental studies on hydrogen. Renewable hydrogen systems and their adoptability in developing countries were analysed. Finally we presented a scenario for hydrogen production pathways in developing countries. Our findings indicated that hydrogen is attractive and can be safely used as a cooking fuel. However radical and disruptive models are necessary to transform the traditional cooking landscape. There is a need to develop global south-based hydrogen models that emphasize adoptability and capture the challenges in developing countries. In addition the techno-economic assumptions of the models vary significantly leading to a wide-ranging levelized cost of electricity. This finding underscored the necessity to use comprehensive techno-economic assumptions that can accurately predict hydrogen costs.
Non-adiabatic Under-expanded Jet Theory for Blowdown and Fire Resistance Rating of Hydrogen Tank
Sep 2019
Publication
The European Regulations on type-approval of hydrogen vehicles require thermally-activated pressure relief device (TPRD) to be installed on hydrogen onboard storage tanks to release its content in a fire event to prevent its catastrophic rupture. The aim of this study is to develop a model for design of an inherently safer system TPRD-storage tank. Parameters of tank materials and hydrogen external heat flux from the fire to the tank wall TPRD diameter time to initiate TPRD are input parameters of the model. The energy conservation equation and real gas equation of state are employed to describe the dynamic behaviour of the system. The under-expanded jet theory developed previously for adiabatic release from a storage tank is applied here to non-adiabatic blowdown of a tank in a fire. Unsteady heat transfer equation is used to calculate heat conduction through the tank wall. It includes the decomposition of the wall material due to high heat flux. The convective heat transfer between tank wall and hydrogen is modelled through the dimensionless Nusselt number correlations. The model is validated against two types of experiments i.e. realistic (non-adiabatic) blowdown of high-pressure storage tank and failure of a tank without TPRD in a fire. The model is confirmed to be time efficient for computations and accurately predicts the dynamic pressure and temperature of the gas inside the tank temperature profile within the tank wall time to tank rupture in a fire and the blowdown time.
Probability of Occurrence of ISO 14687-2 Contaminants in Hydrogen: Principles and Examples from Steam Methane Reforming and Electrolysis (Water and Chlor-alkali) Production Processes Model
Apr 2018
Publication
According to European Directive 2014/94/EU hydrogen providers have the responsibility to prove that their hydrogen is of suitable quality for fuel cell vehicles. Contaminants may originate from hydrogen production transportation refuelling station or maintenance operation. This study investigated the probability of presence of the 13 gaseous contaminants (ISO 14687-2) in hydrogen on 3 production processes: steam methane reforming (SMR) process with pressure swing adsorption (PSA) chlor-alkali membrane electrolysis process and water proton exchange membrane electrolysis process with temperature swing adsorption. The rationale behind the probability of contaminant presence according to process knowledge and existing barriers is highlighted. No contaminant was identified as possible or frequent for the three production processes except oxygen (frequent for chlor-alkali membrane process) carbon monoxide (frequent) and nitrogen (possible) for SMR with PSA. Based on it a hydrogen quality assurance plan following ISO 19880-8 can be devised to support hydrogen providers in monitoring the relevant contaminants.
HyDeploy2: Materials Summary and Interpretation
May 2021
Publication
During the exemption application process the original report was evaluated as part of a regulatory review and responses to questions submitted for further consideration. These have been addressed in this revised version (revision 1) in the form of an addendum. The addendum includes the question raised its number and the response to it. The area of the main body of the report to which each question and response refers is indicated by square brackets and the addendum number e.g. [A1].<br/>Through analysis of the literature and results of the practical testing the susceptibility of materials present in the Winlaton trial site to hydrogen degradation has been assessed with consideration of the Winlaton operating conditions (up to 20% H2 at total blend pressures of 20 mbar – 2 bar). The aim of this report has been to determine whether there are any components which have been identified at the Winlaton trial site which could have a significantly increased risk of failure due to their exposure to hydrogen during the one year trial. Where possible direct supporting data has been used to make assessments on the likelihood of failure; in other cases the assessment was aided by collaborative expert opinion in the fields of mechanical engineering materials science and the domestic gas industry.<br/>Click on the supplements tab to view the other documents from this report
Green Hydrogen Powering Sustainable Festivals: Public Perceptions of Generators, Production and Ownership
Nov 2022
Publication
This paper is the first to explore public perceptions about a particular market niche for hydrogen; mobile generators. By utilising a combined research approach including in-situ surveys and online focus groups this paper explores what festival audience members and residents who live near festival sites think about the displacement of incumbent diesel generator technology with hydrogen alternatives. We investigate if hydrogen production methods are important in informing perceptions and subsequent support including the extent to which participants are influenced by the organisation or entity that produces the fuel and stands to profit from its sale. In addition to a primary focus on hydrogen energy we reflect upon how sustainability might be better conceptualised in a festival context. Our findings reveal broad support for hydrogen generators the use of green hydrogen as a fuel to generate electricity and community-led hydrogen production.
Investigation into the Cross-sensitivity of Domestic Carbon Monoxide Alarms to Hydrogen
Sep 2021
Publication
Preliminary research suggests domestic carbon monoxide detectors with an electrochemical sensor are approximately 10 -20% sensitive to hydrogen atmospheres in their factory configuration. That is the display on a carbon monoxide detector would give a carbon monoxide reading of approximately 10-20% of the concentration of hydrogen it is exposed to. Current British standards require detectors to sound an alarm within three minutes when subjected to a continuous concentration of ≥ 300 ppm CO. This would equate to a concentration of 1500-3000 ppm hydrogen in air or approximately 3.75 – 7% %LEL. The current evacuation criteria for a natural gas leak in a domestic property is 20 %LEL indicating that standard carbon monoxide detectors could be used as cheap and reliable early warning systems for hydrogen leaks. Given the wide use of carbon monoxide detectors and the affordability of the devices the use of carbon monoxide detectors for hydrogen detection is of particular interest as the UK drives towards energy decarbonisation. Experiments to determine the exact sensitivity of a range of the most common domestic carbon monoxide detectors have been completed by DNV Spadeadam Research & Testing. Determining the effects of repeated exposure to varying concentrations of hydrogen in air on the sensitivity of electrochemical sensors allows recommendations to be made on their adoption as hydrogen detectors. Changing the catalysts used within the electrochemical cell would improve the sensitivity to hydrogen however simply calibrating the sensor to report a concentration of hydrogen rather than carbon monoxide would represent no additional costs to manufacturers. Having determined the suitability of such sensors at an early stage; the technology can then be linked with other technological developments required for the change to hydrogen for domestic heating (e.g. change in metering equipment and appliances). This report finds that from five simple and widely available carbon monoxide detectors the lowest sensitivity to hydrogen measured at the concentration required to sound an alarm within three minutes was approximately 10%. It was also discovered that as the hydrogen concentration was increased over the range tested the sensitivity to hydrogen also increased. It is proposed that coupling these devices with other elements of the domestic gas system would allow actions such as remote meter isolation or automatic warning signals sent to response services would provide a reliable and inherently safe system for protecting occupants as gas networks transition to net-zero greenhouse gas emissions. In this respect it is noted that wireless linking of smoke and heat detectors for domestic application is already widely available in low-cost devices. This could be extended to CO detectors adapted for hydrogen use.
A Critical Review on the Principles, Applications, and Challenges of Waste-to-hydrogen Technologies
Sep 2020
Publication
Hydrogen sourced from energy recovery processes and conversion of waste materials is a method of providing both a clean fuel and a sustainable waste management alternative to landfill and incineration. The question is whether waste-to–hydrogen can become part of the zero-carbon future energy mix and serve as one of the cleaner hydrogen sources which is economically viable and environmentally friendly. This work critically assessed the potential of waste as a source of hydrogen production via various thermochemical (gasification and pyrolysis) and biochemical (fermentation and photolysis) processes. Research has shown hydrogen production yields of 33.6 mol/kg and hydrogen concentrations of 82% from mixed waste feedstock gasification. Biochemical methods such as fermentation can produce hydrogen up to 418.6 mL/g. Factors including feedstock quality process requirements and technology availability were reviewed to guide technology selection and system design. Current technology status and bottlenecks were discussed to shape future development priorities. These bottlenecks include expensive production and operation processes heterogeneous feedstock low process efficiencies inadequate management and logistics and lack of policy support. Improvements to hydrogen yields and production rates are related to feedstock processing and advanced energy efficiency processes such as torrefaction of feedstock which has shown thermal efficiency of gasification up to 4 MJ/kg. This will affect the economic feasibility and concerns around required improvements to bring the costs down to allow waste to viewed as a serious competitor for hydrogen production. Recommendations were also made for financially competitive waste-to-hydrogen development to be part of a combined solution for future energy needs.
Hydrogen Mobility Europe (H2ME): Vehicle and Hydrogen Refuelling Station Deployment Results
May 2018
Publication
Hydrogen Mobility Europe (H2ME 2015–2022) is the largest European Fuel Cells and Hydrogen Joint Undertaking (EU FCH JU)-funded hydrogen light vehicle and infrastructure demonstration. Up until April 2017 the 40 Daimler passenger car fuel cell electric vehicles (FCEVs) and 62 Symbio Fuel Cell-Range Extended Electric Vans (FC-REEV)-vans deployed by the project drove 625300 km and consumed a total of 7900 kg of hydrogen with no safety incidents. During its first year of operation (to April 2017) the NEL Hydrogen Fueling HRS (hydrogen refuelling station) in Kolding Denmark dispensed 900 kg of hydrogen and demonstrated excellent reliability (98.2% availability) with no safety incidents. The average hydrogen refuelling time for passenger cars is comparable to that for conventional vehicles (2–3 min).
Achieving Carbon-neutral Iron and Steelmaking in Europe Through the Deployment of Bioenergy with Carbon Capture and Storage
Jan 2019
Publication
The 30 integrated steel plants operating in the European Union (EU) are among the largest single-point CO2 emitters in the region. The deployment of bioenergy with carbon capture and storage (bio-CCS) could significantly reduce their emission intensities. In detail the results demonstrate that CO2 emission reduction targets of up to 20% can be met entirely by biomass deployment. A slow CCS technology introduction on top of biomass deployment is expected as the requirement for emission reduction increases further. Bio-CCS could then be a key technology particularly in terms of meeting targets above 50% with CO2 avoidance costs ranging between €60 and €100 tCO2−1 at full-scale deployment. The future of bio-CCS and its utilisation on a larger scale would therefore only be viable if such CO2 avoidance cost were to become economically appealing. Small and medium plants in particular would economically benefit from sharing CO2 pipeline networks. CO2 transport however makes a relatively small contribution to the total CO2 avoidance cost. In the future the role of bio-CCS in the European iron and steelmaking industry will also be influenced by non-economic conditions such as regulations public acceptance realistic CO2 storage capacity and the progress of other mitigation technologies.
Hydrogen Power Focus Shifts from Cars to Heavy Vehicles
Oct 2020
Publication
Hydrogen has been hailed as a promising energy carrier for decades. But compared to the thriving success of hybrid and plug-in electric cars the prospects for cars powered by hydrogen fuel cells have recently diminished mostly due to challenges in bringing down the costs of fuel cells and developing a broad network of fuelling stations.<br/>Beginning in March 2020 three major auto manufacturers—Daimler AG] Volkswagen and General Motors (GM)]—followed the April 2019 move by Honda to back out of the hydrogen-powered passenger car market. Instead these companies and others are looking to develop the technology as an emission-free solution to power heavy commercial and military vehicles with refuelling taking place at centralized locations.
Blended Hydrogen: The UK Public’s Perspective
Nov 2019
Publication
Hydrogen is increasingly being positioned as an important component of the UK’s Net Zero ambitions and commitments. In particular hydrogen could be an appropriate way to decarbonise the heat produced for domestic and industrial buildings. It is possible that hydrogen could replace natural gas in the UK gas network achieving key carbon emissions reduction targets while enabling homes to be heated to a similar level and standard as they currently are.<br/>In the interim small amounts of hydrogen will soon be blended into current natural gas supplies. The premise of this idea is to blend hydrogen into the existing gas network in small enough quantities to not require any adjustments to domestic cookers boilers and other gas-fired appliances but in large enough quantities to generate significant immediate reductions in carbon emissions. Three trials will take place between 2019 and 2022 as part of the HyDeploy project with the aim of demonstrating that hydrogen blending can occur at scale with no safety implications and no disruption to users.<br/>Public perceptions and acceptance of hydrogen will be pivotal in this scenario. At present there is very little indication of how acceptable hydrogen will be for heating homes and questions around safety cost and performance are only beginning to be understood and addressed.<br/>This report investigates public perceptions of blended hydrogen as a fuel for UK homes. In March 2019 we administered a survey to a sample (n=742) representative of the UK adult population in terms of age sex ethnicity and personal income. Our survey covered initial perceptions values and knowledge of hydrogen; the possibilities and pitfalls of hydrogen blending; public trust; and participants’ overall support for hydrogen. Key Findings and Conclusions and Recommendations for Policy and Practice follow immediately with the full report beginning on p.6.
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