United States
Policy Design for Diffusing Hydrogen Economy and Its Impact on the Japanese Economy for Carbon Neutrality by 2050: Analysis Using the E3ME-FTT Model
Nov 2023
Publication
To achieve carbon neutrality in Japan by 2050 renewable energy needs to be used as the main energy source. Based on the constraints of various renewable energies the importance of hydrogen cannot be ignored. This study aimed to investigate the diffusion of hydrogen demand technologies in various sectors and used projections and assumptions to investigate the hydrogen supply side. By performing simulations with the E3ME-FTT model and comparing various policy scenarios with the reference scenario the economic and environmental impacts of the policy scenarios for hydrogen diffusion were analyzed. Moreover the impact of realizing carbon neutrality by 2050 on the Japanese economy was evaluated. Our results revealed that large-scale decarbonization via hydrogen diffusion is possible (90% decrease of CO2 emissions in 2050 compared to the reference) without the loss of economic activity. Additionally investments in new hydrogen-based and other low-carbon technologies in the power sector freight road transport and iron and steel industry can improve the gross domestic product (1.6% increase in 2050 compared to the reference) as they invoke economic activity and require additional employment (0.6% increase in 2050 compared to the reference). Most of the employment gains are related to decarbonizing the power sector and scaling up the hydrogen supply sector while a lot of job losses can be expected in the mining and fossil fuel industries.
Designing Off-grid Green Hydrogen Plants Using Dynamic Polymer Electrolyte Membrane Electrolyzers to Minimize the Hydrogen Production Cost
Oct 2023
Publication
Hydrogen produced from electrolysis is an attractive carbon-free fuel and feedstock but potential benefits depend on the carbon intensity of electricity production. This study uses technoeconomic modeling to analyze the benefits of producing zero-carbon hydrogen through dynamically operated polymer electrolyte membrane electrolyzers connected to photovoltaic and wind variable renewable energy (VRE) sources. Dynamic operation is considered for current densities between 0 and 6 A cm2 and compared to a constant current density of 2 A cm2 for different combinations of VRE to electrolysis (VRE:E) capacity ratios and compositions of photovoltaic and wind energy in four locations across the United States. For optimal VRE:E and wind:photovoltaic capacity ratios dynamic operation is found to reduce the levelized cost of hydrogen by 5%–9% while increasing hydrogen production by 134%–173% and decreasing excess electrical power by 82%–95%. The framework herein may be used to determine the optimal VRE:E capacity and VRE mix for dynamically operated green hydrogen systems.
Hydrogen-Powered Aircraft at Airports: A Review of the Infrastructure Requirements and Planning Challenges
Nov 2023
Publication
Hydrogen-fueled aircraft are a promising innovation for a sustainable future in aviation. While hydrogen aircraft design has been widely studied research on airport requirements for new infrastructure associated with hydrogen-fueled aircraft and its integration with existing facilities is scarce. This study analyzes the current body of knowledge and identifies the planning challenges which need to be overcome to enable the operation of hydrogen flights at airports. An investigation of the preparation of seven major international airports for hydrogen-powered flights finds that although there is commitment airports are not currently prepared for hydrogen-based flights. Major adjustments are required across airport sites covering land use plans airside development utility infrastructure development and safety security and training. Developments are also required across the wider aviation industry including equipment updates such as for refueling and ground support and supportive policy and regulations for hydrogen-powered aircraft. The next 5–10 years is identified from the review as a critical time period for airports given that the first commercial hydrogen-powered flight is likely to depart in 2026 and that the next generation of short-range hydrogen-powered aircraft is predicted to enter service between 2030 and 2035.
Increasing Energy Efficiency of Hydrogen Refueling Stations via Optimal Thermodynamic Paths
Sep 2023
Publication
This work addresses the energy efficiency of hydrogen refueling stations (HRS) using a first principles model and optimal control methods to find minimal entropy production operating paths. The HRS model shows good agreement with experimental data achieving maximum state of charge and temperature discrepancies of 1 and 7% respectively. Model solution and optimization is achieved at a relatively low computational time (40 s) when compared to models of the same degree of accuracy. The entropy production mapping indicates the flow control valve as the main source of irreversibility accounting for 85% of the total entropy production in the process. The minimal entropy production refueling path achieves energy savings from 20 to 27% with respect to the SAE J2601 protocol depending on the ambient temperature. Finally the proposed method under nearreversible refueling conditions shows a theoretical reduction of 43% in the energy demand with respect to the SAE J2601 protocol.
Recent Progress on Rational Design of Catalysts for Fermentative Hydrogen Production
May 2022
Publication
The increasingly severe energy crisis has strengthened the determination todevelop environmentally friendly energy. And hydrogen has emerged as a candi-date for clean energy. Among many hydrogen generation methods biohydrogenstands out due to its environmental sustainability simple operating environ-ment and cost advantages. This review focuses on the rational design of catalystsfor fermentative hydrogen production. The principles of microbial dark fermen-tation and photo-fermentation are elucidated exhaustively. Various strategiesto increase the efficiency of fermentative hydrogen production are summa-rized and some recent representative works from microbial dark fermentationand photo-fermentation are described. Meanwhile perspectives and discussionson the rational design of catalysts for fermentative hydrogen production areprovided.
The Impact of Rock Morphology on Gas Dispersion in Underground Hydrogen Storage
Jul 2025
Publication
Fluid dispersion directly influences the transport mixing and efficiency of hydrogen storage in depleted gas reservoirs. Pore structure parameters such as pore size throat geometry and connectivity influence the complexity of flow pathways and the interplay between advective and diffusive transport mechanisms. Hence these factors are critical for predicting and controlling flow behavior in the reservoirs. Despite its importance the relationship between pore structure and dispersion remains poorly quantified particularly under elevated flow conditions. To address this gap this study employs pore network modeling (PNM) to investigate the influence of sandstone and carbonate structures on fluid flow properties at the micro-scale. Eleven rock samples comprising seven sandstone and four carbonate were analyzed. Pore network extraction from CT images was used to obtain detailed pore structure parameters and their statistical measures. Pore-scale simulations were conducted across 60 scenarios with varying average interstitial velocities and water as the injected fluid. Effluent hydrogen concentrations were measured to generate elution curves as a function of injected pore volumes (PV). This approach enables the assessment of the relationship between the dispersion coefficient and pore structure parameters across all rock samples at consistent average interstitial velocities. Additionally dispersivity and n-exponent values were calculated and correlated with pore structure parameters.
Feasibility of Hydrogen Fuel Cell Technology for Railway Intercity Services: A Case Study for the Piedmont in North Carolina
Jul 2021
Publication
Diesel fuel combustion results in exhaust containing air pollutants and greenhouse gas emissions. Many railway vehicles use diesel fuel as their energy source. Exhaust emissions as well as concerns about economical alternative power supply have driven efforts to move to hydrogen motive power. Hydrogen fuel cell technology applied to railways offers the opportunity to eliminate harmful exhaust emissions and the potential for a low- or zero-emission energy supply chain. Currently only multiple-unit trains with hydrail technology operate commercially. Development of an Integrated Hybrid Train Simulator for intercity railway is presented. The proposed tool incorporates the effect of powertrain components during the wheel-to-tank process. Compared to its predecessors the proposed reconfigurable tool provides high fidelity with medium requirements and minimum computation time. Single train simulation and the federal government’s Greenhouse gases Regulated Emissions and Energy use in Transportation (GREET) model are used in combination to evaluate the feasibility of various train and powertrain configurations. The Piedmont intercity service operating in North Carolina is used as a case study. The study includes six train configurations and powertrain options as well as nine hydrogen supply options in addition to the diesel supply. The results show that a hydrail option is not only feasible but a low- or zero-carbon hydrogen supply chain could be possible.
Grid Ancillary Services using Electrolyzer-based Power-to-Gas Systems with Increasing Renewable Penetration
Nov 2023
Publication
Increasing penetrations of renewable-based generation have led to a decrease in the bulk power system inertia and an increase in intermittency and uncertainty in generation. Energy storage is considered to be an important factor to help manage renewable energy generation at greater penetrations. Hydrogen is a viable long-term storage alternative. This paper analyzes and presents use cases for leveraging electrolyzer-based power-to-gas systems for electric grid support. The paper also discusses some grid services that may favor the use of hydrogenbased storage over other forms such as battery energy storage. Real-time controls are developed implemented and demonstrated using a power-hardware-in-the-loop(PHIL) setup with a 225-kW proton-exchange-membrane electrolyzer stack. These controls demonstrate frequency and voltage support for the grid for different levels of renewable penetration (0% 25% and 50%). A comparison of the results shows the changes in respective frequencies and voltages as seen as different buses as a result of support from the electrolyzers and notes the impact on hydrogen production as a result of grid support. Finally the paper discusses the practical nuances of implementing the tests with physical hardware such as inverter/electrolyzer efficiency as well as the related constraints and opportunities.
A Multi-period Sustainable Hydrogen Supply Chain Model Considering Pipeline Routing and Carbon Emissions: The Case Study of Oman
Nov 2022
Publication
This paper presents a mathematical model for a multi-period hydrogen supply chain design problem considering several design features not addressed in other studies. The model is formulated as a mixed-integer program allowing the production and storage facilities to be extended over time. Pipeline and tube trailer transport modes are considered for carrying hydrogen. The model also allows finding the optimal pipeline routes and the number of transport units. The objective is to obtain an efficient supply chain design within a given time frame in a way that the demand and carbon dioxide emissions constraints are satisfied and the total cost is minimized. A computer program is developed to ease the problem-solving process. The computer program extracts the geographical information from Google Maps and solves the problem using an optimization solver. Finally the applicability of the proposed model is demonstrated in a case study from Oman.
Experimental Comparison of Hydrogen Refueling with Directly Pressurized vs. Cascade Method
Aug 2023
Publication
This paper presents a comparative analysis of two hydrogen station configurations during the refueling process: the conventional “directly pressurized refueling process” and the innovative “cascade refueling process.” The objective of the cascade process is to refuel vehicles without the need for booster compressors. The experiments were conducted at the Hydrogen Research and Fueling Facility located at California State University Los Angeles. In the cascade refueling process the facility buffer tanks were utilized as high-pressure storage enabling the refueling operation. Three different scenarios were tested: one involving the cascade refueling process and two involving compressor-driven refueling processes. On average each refueling event delivered 1.6 kg of hydrogen. Although the cascade refueling process using the high-pressure buffer tanks did not achieve the pressure target it resulted in a notable improvement in the nozzle outlet temperature trend reducing it by approximately 8 ◦C. Moreover the overall hydrogen chiller load for the two directly pressurized refuelings was 66 Wh/kg and 62 Wh/kg respectively whereas the cascading process only required 55 Wh/kg. This represents a 20% and 12% reduction in energy consumption compared to the scenarios involving booster compressors during fueling. The observed refueling range of 150–350 bar showed that the cascade process consistently required 12–20% less energy for hydrogen chilling. Additionally the nozzle outlet temperature demonstrated an approximate 8 ◦C improvement within this pressure range. These findings indicate that further improvements can be expected in the high-pressure region specifically above 350 bar. This research suggests the potential for significant improvements in the high-pressure range emphasizing the viability of the cascade refueling process as a promising alternative to the direct compression approach.
Techno-economic Analysis and Optmization of Intensified, Large-scale Hydrogen Production with Membrane Reactors
Oct 2023
Publication
Steam methane reforming (SMR) currently supplies 76% of the world’s hydrogen (H2) demand totaling ∼70 million tonnes per year. Developments in H2 production technologies are required to meet the rising demand for cleaner less costly H2. Therefore palladium membrane reactors (Pd-MR) have received significant attention for their ability to increase the efficiency of traditional SMR. This study performs novel economic analyses and constrained nonlinear optimizations on an intensified SMR process with a Pd-MR. The optimization extends beyond the membrane’s operation to present process set points for both the conventional and intensified H2 processes. Despite increased compressor and membrane capital costs along with electric utility costs the SMR-MR design offers reductions in the natural gas usage and annual costs. Economic comparisons between each plant show Pd membrane costs greater than $25 000/m2 are required to break even with the conventional design for membrane lifetimes of 1–3 years. Based on the optimized SMR-MR process this study concludes with sensitivity analyses on the design operational and cost parameters for the intensified SMR-MR process. Overall with further developments of Pd membranes for increased stability and lifetime the proposed SMR-MR design is thus profitable and suitable for intensification of H2 production.
Technology Assessment for the Transition to a Renewable Electric Grid
Jun 2024
Publication
To reduce carbon emissions generation of electricity from combustion systems is being replaced by renewable resources. However the most abundant renewable sources – solar and wind – are not dispatchable vary diurnally and are subject to intermittency and produce electricity at times in excess of demand (excess production). To manage this variability and capture the excess renewable energy energy storage technologies are being developed and deployed such as battery energy storage (BES) hydrogen production with electrolyzers (ELY) paired with hydrogen energy storage (HES) and fuel cells (FCs) and renewable natural gas (RNG) production. While BES may be better suited for short duration storage hydrogen is suited for long duration storage and RNG can decarbonize the natural gas system. California Senate Bill 100 (SB100) sets a goal that all retail electricity sold in the State must be sourced from renewable and zero-carbon resources by 2045 raising the questions of which set of technologies and in what proportion are required to meet the 2045 target in the required timeframe as well as the role of the natural gas infrastructure if any. To address these questions this study combines electric grid dispatch modeling and optimization to identify the energy storage and dispatchable technologies in 5-year increments from 2030 to 2045 required to transition from a 60% renewable electric grid in 2035 to a 100% renewable electric grid in 2045. The results show that by utilizing the established natural gas system to store and transmit hydrogen and RNG the deployment of battery energy storage is dramatically reduced. The required capacity for BES in 2045 for example is 40 times lower by leveraging the natural gas infrastructure with a concomitant reduction in cost and associated challenges to transform the electric grid.
Adaptive Network Fuzzy Inference System and Particle Swarm Optimization of Biohydrogen Production Process
Sep 2022
Publication
Green hydrogen is considered to be one of the best candidates for fossil fuels in the near future. Bio-hydrogen production from the dark fermentation of organic materials including organic wastes is one of the most cost-effective and promising methods for hydrogen production. One of the main challenges posed by this method is the low production rate. Therefore optimizing the operating parameters such as the initial pH value operating temperature N/C ratio and organic concentration (xylose) plays a significant role in determining the hydrogen production rate. The experimental optimization of such parameters is complex expensive and lengthy. The present research used an experimental data asset adaptive network fuzzy inference system (ANFIS) modeling and particle swarm optimization to model and optimize hydrogen production. The coupling between ANFIS and PSO demonstrated a robust effect which was evident through the improvement in the hydrogen production based on the four input parameters. The results were compared with the experimental and RSM optimization models. The proposed method demonstrated an increase in the biohydrogen production of 100 mL/L compared to the experimental results and a 200 mL/L increase compared to the results obtained using ANOVA.
Meeting the Challenges of Large-scale Carbon Storage and Hydrogen Production
Mar 2023
Publication
There is a pressing need to rapidly and massively scale up negative carbon strategies such as carbon capture and storage (CCS). At the same time large-scale CCS can enable ramp-up of large-scale hydrogen production a key component of decarbonized energy systems. We argue here that the safest and most practical strategy for dramatically increasing CO2 storage in the subsurface is to focus on regions where there are multiple partially depleted oil and gas reservoirs. Many of these reservoirs have adequate storage capacity are geologically and hydrodynamically well understood and are less prone to injection-induced seismicity than saline aquifers. Once a CO2 storage facility is up and running it can be used to store CO2 from multiple sources. Integration of CCS with hydrogen production appears to be an economically viable strategy for dramatically reducing greenhouse gas emissions over the next decade particularly in oil- and gas-producing countries where there are numerous depleted reservoirs that are potentially suitable for large-scale carbon storage.
Underground Storage of Hydrogen and Hydrogen/methane Mixtures in Porous Reservoirs: Influence of Reservoir Factors and Engineering Choices on Deliverability and Storage Operations
Jul 2023
Publication
Seasonal storage of natural gas (NG) which primarily consists of methane (CH4) has been practiced for more than a hundred years at underground gas storage (UGS) facilities that use depleted hydrocarbon reservoirs saline aquifers and salt caverns. To support a transition to a hydrogen (H2) economy similar facilities are envisioned for long-duration underground H2 storage (UHS) of either H2 or H2/CH4 mixtures. Experience with UGS can be used to guide the deployment of UHS so we identify and quantify factors (formation/fluid properties and engineering choices) that influence reservoir behavior (e.g. viscous fingering and gravity override) the required number of injection/withdrawal wells and required storage volume contrasting the differences between the storage of CH4 H2 and H2/CH4 mixtures. The most important engineering choices are found to be the H2 fraction in H2/CH4 mixtures storage depth and injection rate. Storage at greater depths (higher pressure) but with relatively lower temperature is more favorable because it maximizes volumetric energy-storage density while minimizing viscous fingering and gravity override due to buoyancy. To store an equivalent amount of energy storing H2/CH4 mixtures in UHS facilities will require more wells and greater reservoir volume than corresponding UGS facilities. We use our findings to make recommendations about further research needed to guide deployment of UHS in porous reservoirs.
Supply and Demand Drivers of Global Hydrogen Deployment in the Transition Toward a Decarbonized Energy System
Nov 2023
Publication
The role of hydrogen in energy system decarbonization is being actively examined by the research and policy communities. We evaluate the potential “hydrogen economy” in global climate change mitigation scenarios using the Global Change Analysis Model (GCAM). We consider major hydrogen production methods in conjunction with delivery options to understand how hydrogen infrastructure affects its deployment. We also consider a rich set of hydrogen end-use technologies and vary their costs to understand how demand technologies affect deployment. We find that the availability of hydrogen transmission and distribution infrastructure primarily affects the hydrogen production mix particularly the share produced centrally versus on-site whereas assumptions about end-use technology primarily affect the scale of hydrogen deployment. In effect hydrogen can be a source of distributed energy enabled by on-site renewable electrolysis and to a lesser extent by on-site production at industrial facilities using natural gas with carbon capture and storage (CCS). While the share of hydrogen in final energy is small relative to the share of other major energy carriers in our scenarios hydrogen enables decarbonization in difficult-to-electrify end uses such as industrial high-temperature heat. Hydrogen deployment and in turn its contribution to greenhouse gas mitigation increases as the climate objective is tightened.
Preliminary Study for the Commercialization of a Electrochemical Hydrogen Compressor
Mar 2023
Publication
A global energy shift to a carbon‐neutral society requires clean energy. Hydrogen can accelerate the process of expanding clean and renewable energy sources. However conventional hydrogen compression and storage technology still suffers from inefficiencies high costs and safety concerns. An electrochemical hydrogen compressor (EHC) is a device similar in structure to a water electrolyzer. Its most significant advantage is that it can accomplish hydrogen separation and compression at the same time. With no mechanical motion and low energy consumption the EHC is the key to future hydrogen compression and purification technology breakthroughs. In this study the compression performance efficiency and other related parameters of EHC are investigated through experiments and simulation calculations. The experimental results show that under the same experimental conditions increasing the supply voltage and the pressure in the anode chamber can improve the reaction rate of EHC and balance the pressure difference between the cathode and anode. The presence of residual air in the anode can impede the interaction between hydrogen and the catalyst as well as the proton exchange membrane (PEM) resulting in a decrease in performance. In addition it was found that a single EHC has a better compression ratio and reaction rate than a double EHC. The experimental results were compatible with the theoretical calculations within less than a 7% deviation. Finally the conditions required to reach commercialization were evaluated using the theoretical model.
Minimizing the Cost of Hydrogen Production through Dynamic Polymer Electrolyte Membrane Electrolyzer Operation
Jun 2022
Publication
Growing imbalances between electricity demand and supply from variable renewable energy sources (VREs) create increasingly large swings in electricity prices. Polymer electrolyte membrane (PEM) electrolyzers can help to buffer against these imbalances and minimize the levelized cost of hydrogen (LCOH) by ramping up production of hydrogen through high-current-density operation when low-cost electricity is abundant and ramping down current density to operate efficiently when electricity prices are high. We introduce a technoeconomic model that optimizes current density profiles for dynamically operated electrolyzers while accounting for the potential of increased degradation rates to minimize LCOH for any given time-of-use (TOU) electricity pricing. This model is used to predict LCOH from different methods of operating a PEM electrolyzer for historical and projected electricity prices in California and Texas which were chosen due to their high penetration of VREs. Results reveal that dynamic operation could enable reductions in LCOH ranging from 2% to 63% for historical 2020 pricing and 1% to 53% for projected 2030 pricing. Moreover high-current-density operation above 2.5 A cm2 is increasingly justified at electricity prices below $0.03 kWh1 . These findings suggest an actionable means of lowering LCOH and guide PEM electrolyzer development toward devices that can operate efficiently at a range of current densities.
Techno-economic Assessment of Renewable Methanol from Biomass Gasification and PEM Electrolysis for Decarbonization of the Maritime Sector in California
Mar 2022
Publication
At scale biomass-based fuels are seen as long-term alternatives to conventional shipping fuels to reduce greenhouse gas emissions in the maritime sector. While the operational benefits of renewable methanol as a marine fuel are well-known its cost and environmental performance depend largely on production method and geographic context. In this study a techno-economic and environmental assessment of renewable methanol produced by gasification of forestry residues is performed. Two biorefinery systems are modeled thermody namically for the first time integrating several design changes to extend past work: (1) methanol synthesized by gasification of torrefied biomass while removing and storing underground a fraction of the carbon initially contained in it and (2) integration of a polymer electrolyte membrane (PEM) electrolyzer for increased carbon efficiency via hydrogen injection into the methanol synthesis process. The chosen use case is set in California with forest residue biomass as the feedstock and the ports of Los Angeles and Long Beach as the shipping fuel demand point. Methanol produced by both systems achieves substantial lifecycle greenhouse gas emissions savings compared to traditional shipping fuels ranging from 38 to 165% from biomass roadside to methanol combustion. Renewable methanol can be carbon-negative if the CO2 captured during the biomass conversion process is sequestered underground with net greenhouse gas emissions along the lifecycle amounting to − 57 gCO2eq/MJ. While the produced methanol in both pathways is still more expensive than conventional fossil fuels the introduction of CO2eq abatement incentives available in the U.S. and California could bring down minimum fuel selling prices substantially. The produced methanol can be competitive with fossil shipping fuels at credit amounts ranging from $150 to $300/tCO2eq depending on the eligible credits.
Hydrogen-Powered Aviation: Insights from a Cross-Sectional Scientometric and Thematic Analysis of Patent Claims
May 2025
Publication
Hydrogen-powered aviation is gaining momentum as a sustainable alternative to fossil-fueled flight yet the field faces complex technological and operational challenges. To better understand commercial innovation pathways this study analyzes the claims sections of 166 hydrogen aviation patents issued between 2018 and 2024. Unlike prior studies that focused on patent titles or abstracts this approach reveals the protected technical content driving commercialization. The study classifies innovations into seven domains: fuel storage fuel delivery fuel management turbine enhancement fuel cell integration hybrid propulsion and safety enhancement. Thematic word clouds and term co-occurrence networks based on natural language processing techniques validate these classifications and highlight core technical themes. Scientometric analyses uncover rapid patent growth rising international participation and strong engagement from both established aerospace firms and young companies. The findings provide stakeholders with a structured view of the innovation landscape helping to identify technological gaps emerging trends and areas for strategic investment and policymaking. This claims-based method offers a scalable framework to track progress in hydrogen aviation and is adaptable to other emerging technologies.
Recent Breakthroughs and Future Horizons in Next-generation HT-PEMs for Hydrogen Fuel Cell
Aug 2025
Publication
Aminul Islam,
Mamun Shahriar,
Tarekul Islam,
Md. Tarekul Islam,
Afsana Papia,
Suman Chandra Mohanta,
M. Azizur R. Khan,
Md Aliur Rahman,
Khadiza Tul Kubra,
Md. Munjur Hasan,
Ariyan Islam Rehan,
Mohammed Sohrab Hossain,
Adiba Islam Rasee,
M.A. Shenashen,
Eti Awual,
Md. Chanmiya Sheikh,
Tetsuya Uchida,
R.M. Waliullah,
Md. Shad Salman,
Md. Nazmul Hasan and
Md. Rabiul Awual
High-temperature proton exchange membranes (HT-PEMs) for fuel cells are considered transformative technologies for efficient energy conversion particularly in hydrogen-based transportation owing to their ability to deliver high power density and operational efficiency in harsh environments. However several critical challenges limit their broader adoption notably the limited durability and high costs associated with core components such as membranes and electrocatalysts under elevated temperature conditions. This review systematically addresses these challenges by examining the role of engineered nanomaterials in overcoming performance and stability limitations. The potential of nanomaterials to improve catalytic activity proton conductivity and thermal stability is discussed in detail emphasizing their impact on the optimization of catalyst layer composition including catalysts binders phosphoric acid electrolytes and additives. Recent advancements in nanostructured assemblies and 3D morphologies are explored to enhance fuel cell efficiency through synergistic interactions of these components. Additionally ongoing issues such as catalyst degradation long-term stability and resistance to high-temperature operation are critically analyzed. This manuscript offers a comprehensive overview of current HT-PEMs research and proposes future material design strategies that could bridge the gap between laboratory prototypes and large-scale industrial applications.
Produced Water Use for Hydrogen Production: Feasibility Assessment in Wyoming, USA
May 2025
Publication
This study evaluates the feasibility of repurposing produced water—an abundant byproduct of hydrocarbon extraction—for green hydrogen production in Wyoming USA. Analysis of geospatial distribution and production volumes reveals that there are over 1 billion barrels of produced water annually from key basins with a general total of dissolved solids (TDS) ranging from 35000 to 150000 ppm though Wyoming’s sources are often at the lower end of this spectrum. Optimal locations for hydrogen production hubs have been identified particularly in high-yield areas like the Powder River Basin where the top 2% of fields contribute over 80% of the state’s produced water. Detailed water-quality analysis indicates that virtually all of the examined sources exceed direct electrolyzer feed requirements (e.g. 10% LCOH) are notable electricity pricing (50–70% LCOH) and electrolyzer CAPEX (20–40% LCOH) are dominant cost factors. While leveraging produced water could reduce freshwater consumption and enhance hydrogen production sustainability further research is required to optimize treatment processes and assess economic viability under real-world conditions. This study emphasizes the need for integrated approaches combining water treatment renewable energy and policy incentives to advance a circular economy model for hydrogen production.
Virtual Failure Assessment Diagrams for Hydrogen Transmission Pipelines
Jun 2025
Publication
We combine state-of-the-art thermo-metallurgical welding process modeling with coupled diffusion-elastic– plastic phase field fracture simulations to predict the failure states of hydrogen transport pipelines. This enables quantitatively resolving residual stress states and the role of brittle hard regions of the weld such as the heat affected zone (HAZ). Failure pressures can be efficiently quantified as a function of asset state (existing defects) materials and weld procedures adopted and hydrogen purity. Importantly simulations spanning numerous relevant conditions (defect size and orientations) are used to build Virtual Failure Assessment Diagrams (FADs) enabling a straightforward uptake of this mechanistic approach in fitness-for-service assessment. Model predictions are in very good agreement with FAD approaches from the standards but show that the latter are not conservative when resolving the heterogeneous nature of the weld microstructure. Appropriate mechanistic FAD safety factors are established that account for the role of residual stresses and hard brittle weld regions.
Toward More Efficient Large-Scale Green Hydrogen Systems via Waste Heat Recovery and ORC
May 2025
Publication
This research models a 20 MW PEM hydrogen plant. PEM units operate in the 60 to 80 ◦C range based on their location and size. This study aims to recover the waste heat from PEM modules to enhance the efficiency of the plant. In order to recover the heat two systems are implemented: (a) recovering the waste heat from each PEM module; (b) recovering the heat from hot water to produce electricity utilizing an organic refrigerant cycle (ORC). The model is made by ASPEN® V14. After modeling the plant and utilizing the ORC the module is optimized using Python to maximize the electricity produced by the turbine therefore enhancing the efficiency. The system is a closed-loop cycle operating at 25 ◦C and ambient pressure. The 20 MW PEM electrolyzer plant produces 363 kg/hr of hydrogen and 2877 kg/hr of oxygen. Based on the higher heating value of hydrogen the plant produces 14302.2 kWh of hydrogen energy equivalents. The ORC is maximized by increasing the electricity output from the turbine and reducing the pump work while maintaining energy conservation and mass balance. The results show that the electricity power output reaches 555.88 kW and the pump power reaches 23.47 kW.
Potential Financing Mechanisms for Green Hydrogen Development in Sub-Saharan Africa
Aug 2025
Publication
Green hydrogen is gaining global attention as a zero-carbon energy carrier with the potential to drive sustainable energy transitions particularly in regions facing rising fossil fuel costs and resource depletion. In sub-Saharan Africa financing mechanisms and structured off-take agreements are critical to attracting investment across the green hydrogen value chain from advisory and pilot stages to full-scale deployment. While substantial funding is required to support a green economic transition success will depend on the effective mobilization of capital through smart public policies and innovative financial instruments. This review evaluates financing mechanisms relevant to sub-Saharan Africa including green bonds public–private partnerships foreign direct investment venture capital grants and loans multilateral and bilateral funding and government subsidies. Despite their potential current capital flows remain insufficient and must be significantly scaled up to meet green energy transition targets. This study employs a mixed-methods approach drawing on primary data from utility firms under the H2Atlas-Africa project and secondary data from international organizations and the peer-reviewed literature. The analysis identifies that transitioning toward Net-Zero emissions economies through hydrogen development in sub-Saharan Africa presents both significant opportunities and measurable risks. Specifically the results indicate an estimated investment risk factor of 35% reflecting potential challenges such as financing infrastructure and policy readiness. Nevertheless the findings underscore that green hydrogen is a viable alternative to fossil fuels in subSaharan Africa particularly if supported by targeted financing strategies and robust policy frameworks. This study offers practical insights for policymakers financial institutions and development partners seeking to structure bankable projects and accelerate green hydrogen adoption across the region.
Energy Storage: From Fundamental Principles to Industrial Applications
Jun 2025
Publication
The increasing global energy demand and the transition toward sustainable energy systems have highlighted the importance of energy storage technologies by ensuring efficiency reliability and decarbonization. This study reviews chemical and thermal energy storage technologies focusing on how they integrate with renewable energy sources industrial applications and emerging challenges. Chemical Energy Storage systems including hydrogen storage and power-to-fuel strategies enable long-term energy retention and efficient use while thermal energy storage technologies facilitate waste heat recovery and grid stability. Key contributions to this work are the exploration of emerging technologies challenges in large-scale implementation and the role of artificial intelligence in optimizing Energy Storage Systems through predictive analytics real-time monitoring and advanced control strategies. This study also addresses regulatory and economic barriers that hinder widespread adoption emphasizing the need for policy incentives and interdisciplinary collaboration. The findings suggest that energy storage will be a fundamental pillar of the sustainable energy transition. Future research should focus on improving material stability enhancing operational efficiency and integrating intelligent management systems to maximize the benefits of these technologies for a resilient and low-carbon energy infrastructure.
Hydrogen Energy Storage via Carbon-Based Materials: From Traditional Sorbents to Emerging Architecture Engineering and AI-Driven Optimization
Jul 2025
Publication
Hydrogen is widely recognized as a key enabler of the clean energy transition but the lack of safe efficient and scalable storage technologies continues to hinder its broad deployment. Conventional hydrogen storage approaches such as compressed hydrogen storage cryo-compressed hydrogen storage and liquid hydrogen storage face limitations including high energy consumption elevated cost weight and safety concerns. In contrast solid-state hydrogen storage using carbon-based adsorbents has gained growing attention due to their chemical tunability low cost and potential for modular integration into energy systems. This review provides a comprehensive evaluation of hydrogen storage using carbon-based materials covering fundamental adsorption mechanisms classical materials emerging architectures and recent advances in computationally AI-guided material design. We first discuss the physicochemical principles driving hydrogen physisorption chemisorption Kubas interaction and spillover effects on carbon surfaces. Classical adsorbents such as activated carbon carbon nanotubes graphene carbon dots and biochar are evaluated in terms of pore structure dopant effects and uptake capacity. The review then highlights recent progress in advanced carbon architectures such as MXenes three-dimensional architectures and 3D-printed carbon platforms with emphasis on their gravimetric and volumetric performance under practical conditions. Importantly this review introduces a forward-looking perspective on the application of artificial intelligence and machine learning tools for data-driven sorbent design. These methods enable high-throughput screening of materials prediction of performance metrics and identification of structure– property relationships. By combining experimental insights with computational advances carbon-based hydrogen storage platforms are expected to play a pivotal role in the next generation of energy storage systems. The paper concludes with a discussion on remaining challenges utilization scenarios and the need for interdisciplinary efforts to realize practical applications.
What Will it Take to Get to Net-zero Emissions in California?
Sep 2025
Publication
In this work a new modeling tool called DECAL (DEcarbonize CALifornia) is developed and used to evaluate what it will take to reach California’s climate mandate of net-zero emissions by 2045. DECAL is a scenario-based model that projects emissions society-wide costs and resource consumption in response to user-defined inputs. DECAL has sufficient detail to model true net-zero pathways and reveal fine-grain technology insights. Using DECAL we find the State can achieve 52 % of the emissions abatement needed to meet net-zero by 2045 using technologies that are already commercially available such as electric vehicles heat pumps and renewable electricity & storage. While these technologies are mature the speed and scale of deployment required will still pose significant practical challenges if not technical ones. In addition we find that 25 % of emissions abatement will come from technologies currently at early-stage deployment and 23 % from technologies at research scale motivating the continued research & development of these technologies including zero-emission heavy-duty vehicles carbon capture & sequestration clean industrial heating low global warming potential refrigerants and direct air capture. Significant carbon dioxide removal will also be needed for California to meet its net-zero target on time at least 45 Mt/yr and more likely up to 75 Mt/yr by 2045. Accelerating deployment of mature technologies can further reduce the need for carbon removal nevertheless establishing enforceable carbon removal targets and conducting policy planning to make said goals a reality will be needed if California is to meet its net-zero by 2045 goal.
Relationship Between Clay Minerals and Microorganims in Underground Hydrogen Storage Reservoirs: A Mini Review
Feb 2025
Publication
Hydrogen (H2) will play a vital role in the global shift towards sustainable energy systems. Due to the high cost and challenges associated with storing hydrogen in large quantities for industrial applications Underground Hydrogen Storage (UHS) in geological formations has emerged as a promising solution. Clay minerals abundant in subsurface environments play a critical role in UHS by providing low permeability cation exchange capacity and stability essential for preventing hydrogen leakage. However microorganisms in the subsurface particularly hydrogenotrophic species interact with clay minerals in ways that can affect the integrity of these storage systems. Microbes form biofilms on clay surfaces which can cause pore clogging and reduce the permeability of the reservoir potentially stabilizing H2 storage and limiting injectivity. Microbial-induced chemical weathering through the production of organic acids and redox reactions can degrade clay minerals releasing metal ions and destabilizing the storage site. These interactions raise concerns about the long-term storage capacity of UHS as microbial processes could lead to H2 loss and caprock degradation compromising the storage system’s effectiveness. This mini review aims to cover the current understanding of the interactions between clay minerals and microorganisms and how these dynamics can affect the safe and sustainable deployment of UHS.
Everything About Hydrogen Podcast: LIFTE OFF! Expanding the Hydrogen Market to it's Next Step
Jul 2023
Publication
This week the EAH team discusses LIFTE H2’s plans for the future and discusses the challenges in hydrogen markets expansion and rollout the need for resiliency for offtakers and how to build consumer confidence.
The podcast can be found on their website.
The podcast can be found on their website.
Review - Engineering Challenges in Green Hydrogen Production Systems
May 2022
Publication
Today hydrogen (H2) is overwhelmingly produced through steam methane reforming (SMR) of natural gas which emits about 12 kg of carbon dioxide (CO2) for 1 kg of H2 (∼12 kg-CO2/kg-H2). Water electrolysis offers an alternative for H2 production but today’s electrolyzers consume over 55 kWh of electricity for 1 kg of H2 (>55 kWh/kg-H2). Electric grid-powered water electrolysis would emit less CO2 than the SMR process when the carbon intensity for grid power falls below 0.22 kg-CO2/kWh. Solar- and wind-powered electrolytic H2 production promises over 80% CO2 reduction over the SMR process but large-scale (megawatt to gigawatt) direct solar- or wind-powered water electrolysis has yet to be demonstrated. In this paper several approaches for solar-powered electrolysis are analyzed: (1) coupling a photovoltaic (PV) array with an electrolyzer through alternating current; (2) direct-current (DC) to DC coupling; and (3) direct DC-DC coupling without a power converter. Co-locating a solar or wind farm with an electrolyzer provides a lower power loss and a lower upfront system cost than long-distance power transmission. A load-matching PV system for water electrolysis enables a 10%–50% lower levelized cost of electricity than the other systems and excellent scalability from a few kilowatts to a gigawatt. The concept of maximum current point tracking is introduced in place of maximum power point tracking to maximize the H2 output by solarpowered electrolysis.
A Methodology for Quantitative Risk Assessment of a High-capacity Hydrogen Fueling Station with Liquid Hydrogen Storage
Mar 2025
Publication
Hydrogen fueling stations are critical infrastructure for deploying zero emission hydrogen fuel cell electric vehicles (FCEV). Stations with greater dispensing capacities and higher energy efficiency are needed and cryogenic liquid hydrogen (LH2) has the potential to meet these needs. It is necessary to ensure that hazards and risks are appropriately identified and managed. This paper presents a Quantitative Risk Assessment (QRA) methodology for high-capacity (dispensing >1000 kg/day) hydrogen fueling stations with liquid hydrogen storage and presents the application of that methodology by presenting a Failure Mode and Effect Analysis (FMEA) and data curation for the design developed for this study. This methodology offers a basis for risk and reliability evaluation of these systems as their designs evolve and as operational data becomes available. We developed a generic station design and process flow diagram for a high-capacity hydrogen fueling station with LH2 storage. Following the system description is hazard identification done from FMEA to identify the causes of hydrogen releases and the critical components causing the releases. Finally data collection and curation is discussed including challenges stemming from the limited public availability of reliability data on components used in liquid hydrogen systems. This paper acts as an introduction to the full QRA presented in its companion paper Schaad et al. [1].
Holding the Invisible: Advanced Materials for Hydrogen Storage
Aug 2025
Publication
Hydrogen storage remains the main barrier to the broader use of hydrogen as an energy carrier despite hydrogen’s high energy density and clean combustion. This study presents a comparative evaluation of conventional and emerging storage methods integrating thermodynamic kinetic economic and environmental metrics to assess capacity efficiency cost and reversibility. Physisorption analysis reveals that metal organic frameworks can achieve storage capacities up to 14.0 mmol/g. Chemical storage systems are evaluated including nanostructured MgH2 (7.6 wt%) catalyzed reversible complex hydrides liquid organic hydrogen carriers and clathrate hydrates. Techno-economic analysis shows storage costs from $500–700/kg H2 to $30–50/kg H2 with energy efficiencies of 50%–90%. Life cycle assessment identifies manufacturing as the primary source of emissions with carbon footprints varying from 150 to 2057 kg CO2 -eq/kg H2 . Cryo-compressed is the most practical transportation option while metal hydrides suit stationary use. This study provides a quantitative foundation to guide material selection and system design for next-generation hydrogen storage technologies.
Review of Electrochemical Systems for Grid Scale Power Generation and Conversion: Low- and High-Temperature Fuel Cells and Electrolysis Processes
May 2025
Publication
This review paper presents an overview of fuel cell electrochemical systems that can be used for clean large-scale power generation and energy storage as global energy concerns regarding emissions and greenhouse gases escalate. The fundamental thermochemical and operational principles of fuel cell power generation and electrolyzer technologies are discussed with a focus on high-temperature solid oxide fuel cells (SOFCs) and solid oxide electrolysis cells (SOECs) that are best suited for grid scale energy generation. SOFCs and SOECs share similar promising characteristics and have the potential to revolutionize energy conversion and storage due to improved energy efficiency and reduced carbon emissions. Electrochemical and thermodynamic foundations are presented while exploring energy conversion mechanisms electric parameters and efficiency in comparison with conventional power generation systems. Methods of converting hydrocarbon fuels to chemicals that can serve as fuel cell fuels are also presented. Key fuel cell challenges are also discussed including degradation thermal cycling and long-term stability. The latest advancements including in materials selection research design and manufacturing methods are also presented as they are essential for unlocking the full potential of these technologies and achieving a sustainable near zero-emission energy future.
Long Duration Energy Storage Usin gHydrogen in Metal−Organic Frameworks: Opportunities and Challenges
May 2024
Publication
Materials-based H2 storage plays a critical role infacilitating H2 as a low-carbon energy carrier but there remainslimited guidance on the technical performance necessary for specificapplications. Metal−organic framework (MOF) adsorbents haveshown potential in power applications but need to demonstrateeconomic promises against incumbent compressed H2 storage.Herein we evaluate the potential impact of material propertiescharge/discharge patterns and propose targets for MOFs’ deploy-ment in long-duration energy storage applications including backupload optimization and hybrid power. We find that state-of-the-artMOF could outperform cryogenic storage and 350 bar compressedstorage in applications requiring ≤8 cycles per year but need ≥5 g/Lincrease in uptake to be cost-competitive for applications thatrequire ≥30 cycles per year. Existing challenges include manufacturing at scale and quantifying the economic value of lower-pressure storage. Lastly future research needs are identified including integrating thermodynamic effects and degradation mechanisms.
Differentiating Hydrogen-driven Hazards from Conventional Failure Modes in Hydrogen Infrastructure
Oct 2025
Publication
Hydrogen is a promising carbon-free energy carrier for large-scale applications yet its adoption faces unique safety challenges. Microscopic physicochemical properties such as high diffusivity low ignition energy and distinct chemical pathways alter the safety of hydrogen systems. Analyzing the HIAD 2.0 incident database an occurrence-based review of past hydrogen incidents shows that 59% arise from general industrial failures common to other hydrocarbon carrier systems. Of the remaining 41% only 15% are unequivocally linked to the fuel’s unique properties. This study systematically isolates hazards driven by hydrogen’s intrinsic properties by filtering out confounding factors and provides an original clear characterization of the different failure mechanisms of hydrogen systems. These hydrogen-specific cases are often poorly described limiting their contribution to safety strategies and regulations improvement. A case study on pipeline failures illustrates how distinguishing hydrogen-specific hazards supports targeted risk mitigation. The findings highlight the need for evidence-based regulation over broadly precautionary approaches.
Everything About Hydrogen Podcast: Sustainable Shipping
Nov 2023
Publication
The teams sits down with Johannah Christensen to discuss regulatory policies and risk mitigation for vessel owners switching to green fuels and what we can do to encourage that jump as well as ensure a Just Transition.
The podcast can be found on their website.
The podcast can be found on their website.
Hydrogen Production Efficiency: A Critical Factor in Integrated Planning of Distributed and Transmission System for Large-scale Centralized Offshore Wind-hydrogen System
Dec 2024
Publication
Green hydrogen plays a pivotal role in decarbonizing our energy system and achieving the Net-Zero Emissions goal by 2050. Offshore wind farms (OWFs) dedicated to green hydrogen production are currently recognized as the most feasible solution for scaling up the production of cost-effective electrolytic hydrogen. However the cost associated with distribution and transmission systems constitute a significant portion of the total cost in the large-scale wind-hydrogen system. This study pioneers the simultaneous optimization of the inter-array cable routing of OWFs and the location and capacity of offshore hydrogen production platforms (OHPPs) aiming to minimize the total cost of distribution and transmission systems. Considering the characteristics of hydrogen production efficiency this paper constructs a novel mathematical model for OHPPs across diverse wind scenarios. Subsequently we formulate the joint planning problem as a relaxed mixed-integer second-order cone programming (MISOCP) model and employ the Benders decomposition algorithm for the solution introducing three valid inequalities to expedite convergence. Through validation on real-world large-scale OWFs we demonstrate the validity and rapid convergence of our approach. Moreover we identify hydrogen production efficiency as a major bottleneck cost factor for the joint planning problem it decreases by 1.01% of total cost for every 1% increase in hydrogen production efficiency.
Photoelectrochemical Water Splitting under Concentrated Sunlight: Best Practices and Protocols
Mar 2025
Publication
Photoelectrochemical (PEC) water splitting is a promising technology for green hydrogen production by harnessing solar energy. Traditionally this sustainable approach is studied under light intensity of 100 mW/cm2 mimicking the natural solar irradiation at the Earth’s surface. Sunlight can be easily concentrated using simple optical systems like Fresnel lens to enhance charge carrier generation and hydrogen production in PEC water splitting. Despite the great potentials this strategy has not been extensively studied and faces challenges related to the stability of photoelectrodes. To prompt the investigations and applications this work outlines the best practices and protocols for conducting PEC solar water splitting under concentrated sunlight illumination incorporating our recent advancements and providing some experimental guidelines. The key factors such as light source calibration photoelectrode preparation PEC cell configuration and long-term stability test are discussed to ensure reproducible and high performance. Additionally the challenges of the expected photothermal effect and the heat energy utilization strategy are discussed.
Effect of Hydrogen Addition on Combustion and Thermal Characteristics of Impinging Non-premixed Jet Flames for Various Heating Value Gases
Jun 2023
Publication
This study experimentally investigates the effect of hydrogen addition on combustion and thermal characteristics of impinging non-premixed jet flames for low-heating values gases (LHVGs). We evaluate the flame morphology and stability using a concentric non-premixed combustor with an impingement plate. OH radicals are visualized using the OH* chemiluminescence and OH-planar laser-induced fluorescence (OH-PLIF) system. Emission characteristics are investigated by calculating CO and NOx emission indices. The results show that the flame stability region narrows as the heating value decreases but expands as hydrogen has been added. The low-OH radical intensity of LHVGs increases with the hydrogen addition. EICO and EINOx decrease with the reduction of heating values. EICO rapidly declines near the lifted flame limit due to the premixing of fuel and air downstream of the flame region. The effect of the hydrogen addition on EINOx is insignificant and shows very low emissions. The heat transfer rate into cooling water indicates a linear tendency with thermal power regardless of the fuel type. These findings show that LHVGs can be employed in existing-impinging flame systems so long as they remain within flame sta bility regions. Furthermore hydrogen addition positively affects the expansion of flame stability enhancing the utility of LHVGs.
Underground Hydrogen Storage: Transforming Subsurface Science into Sustainable Energy Solutions
Feb 2025
Publication
As the global economy moves toward net-zero carbon emissions large-scale energy storage becomes essential to tackle the seasonal nature of renewable sources. Underground hydrogen storage (UHS) offers a feasible solution by allowing surplus renewable energy to be transformed into hydrogen and stored in deep geological formations such as aquifers salt caverns or depleted reservoirs making it available for use on demand. This study thoroughly evaluates UHS concepts procedures and challenges. This paper analyzes the most recent breakthroughs in UHS technology and identifies special conditions needed for its successful application including site selection guidelines technical and geological factors and the significance of storage characteristics. The integrity of wells and caprock which is important for safe and efficient storage can be affected by the operating dynamics of the hydrogen cycle notably the fluctuations in pressure and stress within storage formations. To evaluate its potential for broader adoption we also examined economic elements such as cost-effectiveness and the technical practicality of large-scale storage. We also reviewed current UHS efforts and identified key knowledge gaps primarily in the areas of hydrogen–rock interactions geochemistry gas migration control microbial activities and geomechanical stability. Resolving these technological challenges regulatory frameworks and environmental sustainability are essential to UHS’s long-term and extensive integration into the energy industry. This article provides a roadmap for UHS research and development emphasizing the need for further research to fully realize the technology’s promise as a pillar of the hydrogen economy
Recent Advances in Hydrogen Production, Storage and Fuel Cell Technologies with an Emphasis on Inventions, Innovations and Commercialization
Nov 2023
Publication
The future is bright for hydrogen as a clean mobile energy source to replace petroleum products. This paper examines new and emerging technologies for hydrogen production storage and conversion and highlights recent commercialization efforts to realize its potential. Also the paper presents selected notable patents issued within the last few years. There is no shortage of inventions and innovations in hydrogen technologies in both academia and industry. While metal hydrides and functionalized carbon-based materials have improved tremendously as hydrogen storage materials over the years storing gaseous hydrogen in underground salt caverns has also become feasible in many commercial projects. Production of “blue hydrogen” is rising as a method of producing hydrogen in large quantities economically. Although electric/battery powered vehicles are dominating the green transport today innovative hydrogen fuel cell technologies are knocking at the door because of their lower refueling time compared to EV charging time. However the highest impact of hydrogen technologies in trans portation might be seen in the aviation industry. Hydrogen is expected to play a key role and provides hope in transforming aviation into a zero-carbon emission transportation over the next few decades.
Pipeline Regulation for Hydrogen: Choosing Between Paths and Networks
Oct 2025
Publication
The reliance on hydrogen as part of the transition towards a low-carbon economy will require developing dedicated pipeline infrastructure. This deployment will be shaped by regulatory frameworks governing investment and access conditions ultimately structuring how the commodity is traded. The paper assesses the market design for hydrogen infrastructure assuming the application of unbundling requirements. For this purpose it develops a general economic framework for regulating pipeline infrastructure focusing on asset specificity market power and access rules. The paper assesses the scope of application of infrastructure regulation which can be set to individual pipelines or to entire networks. When treated as entire networks the infrastructure can provide flexibility to enhance market liquidity. However this requires establishing network monopolies which rely on central planning and reduce the overall dynamic efficiency of the sector. The paper further compares the regulation applied to US and EU natural gas pipeline infrastructure. Based on the different challenges faced by the EU hydrogen sector including absence of wholesale concentration and large infrastructure needs the paper draws lessons for a regulatory framework establishing the main building blocks of a hydrogen target model. The paper recommends a review of the current EU regulatory framework in the Hydrogen and Decarbonised Gas Package to enable i) the application of regulation to individual pipelines rather than entire networks; ii) the use of negotiated third-party access light-touch regulation and possibly marketbased coordination mechanisms for the access to the infrastructure and iii) a more significant role for long-term capacity contracts to underpin infrastructure investments.
Factors Affecting Energy Consumption in Hydrogen Liquefaction Plants
Aug 2025
Publication
Hydrogen energy is valued for its diverse sources and clean low-carbon nature and is a promising secondary energy source with wide-ranging applications and a significant role in the global energy transition. Nonetheless hydrogen’s low energy density makes its largescale storage and transport challenging. Liquid hydrogen with its high energy density and easier transport offers a practical solution. This study examines the global hydrogen liquefaction methods with a particular emphasis on the liquid nitrogen pre-cooling Claude cycle process. It also examines the factors in the helium refrigeration cycle—such as the helium compressor inlet temperature outlet pressure and mass—that affect energy consumption in this process. Using HYSYS software the hydrogen liquefaction process is simulated and a complete process system is developed. Based on theoretical principles this study explores the pre-cooling refrigeration and normal-to-secondary hydrogen conversion processes. By calculating and analyzing the process’s energy consumption an optimized flow scheme for hydrogen liquefaction is proposed to reduce the total power used by energy equipment. The study shows that the hydrogen mass flow rate and key helium cycle parameters—like the compressor inlet temperature outlet pressure and flow rate—mainly affect energy consumption. By optimizing these parameters notable decreases in both the total and specific energy consumption were attained. The total energy consumption dropped by 7.266% from the initial 714.3 kW and the specific energy consumption was reduced by 11.94% from 11.338 kWh/kg.
Fuel Cell Technology Review: Types, Economy, Applications, and Vehicle-to-grid Scheme
Feb 2025
Publication
This study conducts a thorough review of fuel cell technology including types economy applications and V2G scheme. Fuel cells have been considered for diverse applications namely electric vehicles specialty vehicles such as warehouse forklifts public transportation including buses trains and ferries. Other applications include grid-related stationary and portable applications. Among available five types of fuel cells PEMFC is presently the optimal choice for electric vehicle usage due to its low operating temperature and durability. Meanwhile high temperature fuel cells such as MCFC and SOFC currently remain the best choice for utility and grid related applications. The economy of fuel cells has been continuously improving and has been illustrated to only grow into a potential main source of sustainable energy soon. With the transportation sector as fuel cell electric ve hicles evolve V2G technology is beneficial towards energy efficiency and fuel cell economy. There is evidence for V2G using FCEV being more advantageous in comparison to conventional BEVs. The costs of the five types of fuel cell vary from US$1784 to US$4500 per kW capacity. The findings are beneficial for researchers and industry professionals who wish to gain comprehensive understanding of fuel cells for adoption and development of the emerging low-emission energy solutions.
Towards Carbon-Neutral Hydrogen: Integrating Methane Pyrolysis with Geothermal Energy
Oct 2025
Publication
Methane pyrolysis produces hydrogen (H2) with solid carbon black as a co-product eliminating direct CO2 emissions and enabling a low-carbon supply when combined with renewable or low-carbon heat sources. In this study we propose a hybrid geothermal pyrolysis configuration in which an enhanced geothermal system (EGS) provides baseload preheating and isothermal holding while either electrical or solar–thermal input supplies the final temperature rise to the catalytic set-point. The work addresses four main objectives: (i) integrating field-scale geothermal operating envelopes to define heatintegration targets and duty splits; (ii) assessing scalability through high-pressure reactor design thermal management and carbon separation strategies that preserve co-product value; (iii) developing a techno-economic analysis (TEA) framework that lists CAPEX and OPEX incorporates carbon pricing and credits and evaluates dual-product economics for hydrogen and carbon black; and (iv) reorganizing state-of-the-art advances chronologically linking molten media demonstrations catalyst development and integration studies. The process synthesis shows that allocating geothermal heat to the largest heat-capacity streams (feed recycle and melt/salt hold) reduces electric top-up demand and stabilizes reactor operation thereby mitigating coking sintering and broad particle size distributions. Highpressure operation improves the hydrogen yield and equipment compactness but it also requires corrosion-resistant materials and careful thermal-stress management. The TEA indicates that the levelized cost of hydrogen is primarily influenced by two factors: (a) electric duty and the carbon intensity of power and (b) the achievable price and specifications of the carbon co-product. Secondary drivers include the methane price geothermal capacity factor and overall conversion and selectivity. Overall geothermal-assisted methane pyrolysis emerges as a practical pathway to turquoise hydrogen if the carbon quality is maintained and heat integration is optimized. The study offers design principles and reporting guidelines intended to accelerate pilot-scale deployment.
Risk Assessment Framework for Green Hydrogen Megaprojects: Balancing Climate Goals with Project Viability
Dec 2024
Publication
Green hydrogen presents a promising solution for decarbonisation but its widespread adoption faces significant challenges. To meet Europe’s 2030 targets a 250-fold increase in electrolyser capacity is required necessitating an investment of €170-240 billion. This involves constructing 20-40 pioneering megaprojects each with a 1-5 GW capacity. Historically pioneering energy projects have seen capital costs double or triple from initial estimates with over 50% failing to meet production goals at startup due to new technology introductions site-specific characteristics and project complexity. Additionally megaprojects costing more than €1 billion frequently succumb to the "iron law" which states they are often over budget take longer than anticipated and yield fewer benefits than expected mainly because key players consistently underestimate costs and risks. Pursuing multiple pioneering megaprojects simultaneously restricts opportunities for iterative learning which raises risks related to untested technologies and infrastructure demands. This vision paper introduces a novel risk assessment framework that combines insights from pioneering and megaprojects with technology readiness evaluations and comparative CO2 reduction analyses to tackle these challenges. The framework aims to guide investment decisions and risk mitigation strategies such as staged scaling and limiting the introduction of new technology. The analysis highlights that using green ammonia for fertiliser production can reduce CO2 emissions by 51 tons of CO2 per ton of hydrogen significantly outperforming hydrogen use in transportation and heating. This structured approach considers risks and environmental benefits while promoting equitable risk distribution between developed and developing nations.
Hydrogen Production Plant via an Intensified Plasma-based Technology
Oct 2025
Publication
Developing cleaner processes via newer technologies will accelerate advancement toward more sustainable energy systems. Hydrogen is an energy carrier and an intermediate molecule in chemical processes. This research investigates an innovative hydrogen production process utilizing a non-thermal Cold Atmospheric Pressure Plasma-based Reformer (CAPR). Exploring environmentally friendly and economically viable pathways for hydrogen production is crucial for addressing climate change and reducing the carbon footprint of industrial processes. The study investigates the conversion of natural gas to hydrogen at ambient temperature and pressure highlighting the ability of plasma-based technology to operate without direct CO2 emissions.<br/>Initially through experimental studies natural gas was passed through the CAPR where the plasma's energetic discharges initiate the reforming process. Subsequently the produced hydrogen along with other light hydrocarbons enters the separation system for producing purified hydrogen. The research focuses on techno-economic analyses and sensitivity assessments to determine the levelized cost of producing hydrogen via a nanosecond plasma-based refining plant and benchmark technologies. Sensitivity analyses identify two primary factors that significantly affect the levelized cost of hydrogen production in a plasma-based reforming system.<br/>The research suggests that instead of producing carbon dioxide and capturing the emitted CO2 utilize processes that do not emit direct CO2. CAPR shows potential for cost competitiveness with conventional hydrogen production methods including steam methane reforming (SMR) and electrolysis. The findings underscore the need for further research to optimize the system's performance and cost-effectiveness positioning CAPR as a potentially transformative technology for the chemical process industry.
Everything About Hydrogen Podcast: COP28 Special
Dec 2023
Publication
To round off Season 5 the team are taking the podcast to COP28 in Dubai and providing listeners with a bit of texture including what the event was like to attend as well as sharing a snapshot of some of the varied voices and discussions that took place. Having had a little time for reflection Alicia Chris and Patrick also offer their thoughts and takeaways on what this COP might mean for the future.
COP28 was the first in nearly 30 years to feature hydrogen as part of the Presidential Action Agenda.
The podcast can be found on their website.
COP28 was the first in nearly 30 years to feature hydrogen as part of the Presidential Action Agenda.
The podcast can be found on their website.
Future of Hydrogen in the U.S. Energy Sector: MARKAL Modeling Results
Mar 2024
Publication
Hydrogen is an attractive energy carrier which could play a role in decarbonizing process heat power or transport applications. Though the U.S. already produces about 10 million metric tons of H2 (over 1 quadrillion BTUs or 1% of the U.S. primary energy consumption) production technologies primarily use fossil fuels that release CO2 and the deployment of other cleaner H2 production technologies is still in the very early stages in the U.S. This study explores (1) the level of current U.S. hydrogen production and demand (2) the importance of hydrogen to accelerate a net-zero CO2 future and (3) the challenges that must be overcome to make hydrogen an important part of the U.S. energy system. The study discusses four scenarios and hydrogen production has been shown to increase in the future but this growth is not enough to establish a hydrogen economy. In this study the characteristics of hydrogen technologies and their deployments in the long-term future are investigated using energy system model MARKAL. The effects of strong carbon constraints do not cause higher hydrogen demand but show a decrease in comparison to the business-as-usual scenario. Further according to our modeling results hydrogen grows only as a fuel for hard-to-decarbonize heavy-duty vehicles and is less competitive than other decarbonization solutions in the U.S. Without improvements in reducing the cost of electrolysis and increasing the performance of near-zero carbon technologies for hydrogen production hydrogen will remain a niche player in the U.S. energy system in the long-term future. This article provides the reader with a comprehensive understanding of the role of hydrogen in the U.S. energy system thereby explaining the long-term future projections.
Nanomaterials for Hydrogen Storage Applications: A Review
Sep 2008
Publication
Nanomaterials have attracted great interest in recent years because of the unusual mechanical electrical electronic opticalmagnetic and surface properties. The high surface/volume ratio of these materials has significant implications with respectto energy storage. Both the high surface area and the opportunity for nanomaterial consolidation are key attributes of thisnew class of materials for hydrogen storage devices. Nanostructured systems including carbon nanotubes nano-magnesiumbased hydrides complex hydride/carbon nanocomposites boron nitride nanotubes TiS2/MoS2 nanotubes alanates polymernanocomposites and metal organic frameworks are considered to be potential candidates for storing large quantities of hydrogen.Recent investigations have shown that nanoscale materials may offer advantages if certain physical and chemical effects related tothe nanoscale can be used efficiently. The present review focuses the application of nanostructured materials for storing atomicor molecular hydrogen. The synergistic effects of nanocrystalinity and nanocatalyst doping on the metal or complex hydrides forimproving the thermodynamics and hydrogen reaction kinetics are discussed. In addition various carbonaceous nanomaterialsand novel sorbent systems (e.g. carbon nanotubes fullerenes nanofibers polyaniline nanospheres and metal organic frameworksetc.) and their hydrogen storage characteristics are outlined.
Hydrogen Production from Municipal Waste and Low Grade Lignite Blend
Nov 2024
Publication
The updraft rotating bed gasifier (URBG) offers a sustainable solution for waste-to-energy conversion utilizing low-grade lignite and municipal solid waste (MSW) from metropolitan dumping sites. This study investigates the co-gasification of lignite with various MSW components demonstrating a significant enhancement in gasification efficiency due to the synergistic effects arising from their higher hydrogen-to-carbon (H/C) ratios. We find feedstock blending is key to maximizing gasification efficiency from 11% to 52% while reducing SO emissions from 739 mg/kg to 155 mg/kg. Increasing the combustion zone temperature to 1100 K resulted in a peak hydrogen yield which was 19% higher than at 800 K. However steam management is complicated as increasing it improves hydrogen fraction in produced gas but gasification efficiency is compromised. These findingsshowcase the URBG’s potential to address both energy production and waste management challenges guiding fossil-reliant regions toward a more sustainable energy future.
A Comparative Science-Based Viability Assessment Among Current and Emerging Hydrogen Production Technologies
Jan 2025
Publication
This research undertakes a comparative analysis of current and emerging hydrogen (H2) production technologies evaluating them based on quantitative and qualitative decision criteria. The quantitative criteria include cost of H2 production (USD/kg H2) energy consumption (MJ/kg H2) global warming potential (kg CO2-eq/kg H2) and technology energy efficiency (%). The qualitative criteria encompass technology readiness level (TRL) and availability of supply chain materials (classified as low medium or high). To achieve these objectives an extensive literature review has been conducted systematically assessing the selected H2 production technologies against the aforementioned criteria. The insights synthesized from the literature provide a foundation for an informed science-based evaluation of the potentials and techno-economic challenges that these technologies face in achieving the 1-1-1 goal set by the U.S. Department of Energy (DOE) in 2021. This target aims for a H2 production cost of USD 1/kg H2 within one decade (by 2031) including costs associated with production delivery and dispensing at H2 fueling stations (HRSs). Also the DOE established an interim goal of USD 2/kg H2 by 2026. This research concludes that among the examined H2 production technologies water electrolysis and biomass waste valorization emerge as the most promising near-term solutions to meet the DOE’s goal.
A Multi-model Assessment of the Global Warming Potential of Hydrogen
Jun 2023
Publication
With increasing global interest in molecular hydrogen to replace fossil fuels more attention is being paid to potential leakages of hydrogen into the atmosphere and its environmental consequences. Hydrogen is not directly a greenhouse gas but its chemical reactions change the abundances of the greenhouse gases methane ozone and stratospheric water vapor as well as aerosols. Here we use a model ensemble of five global atmospheric chemistry models to estimate the 100-year time-horizon Global Warming Potential (GWP100) of hydrogen. We estimate a hydrogen GWP100 of 11.6 ± 2.8 (one standard deviation). The uncertainty range covers soil uptake photochemical production of hydrogen the lifetimes of hydrogen and methane and the hydroxyl radical feedback on methane and hydrogen. The hydrogeninduced changes are robust across the different models. It will be important to keep hydrogen leakages at a minimum to accomplish the benefits of switching to a hydrogen economy.
A Model-Based Systems Engineering Approach for Effective Decision Support of Modern Energy Systems Depicted with Clean Hydrogen Production
Aug 2024
Publication
A holistic approach to decision-making in modern energy systems is vital due to their increase in complexity and interconnectedness. However decision makers often rely on narrowlyfocused strategies such as economic assessments for energy system strategy selection. The approach in this paper helps considers various factors such as economic viability technological feasibility environmental impact and social acceptance. By integrating these diverse elements decision makers can identify more economically feasible sustainable and resilient energy strategies. While existing focused approaches are valuable since they provide clear metrics of a potential solution (e.g. an economic measure of profitability) they do not offer the much needed system-as-a-whole understanding. This lack of understanding often leads to selecting suboptimal or unfeasible solutions which is often discovered much later in the process when a change may not be possible. This paper presents a novel evaluation framework to support holistic decision-making in energy systems. The framework is based on a systems thinking approach applied through systems engineering principles and model-based systems engineering tools coupled with a multicriteria decision analysis approach. The systems engineering approach guides the development of feasible solutions for novel energy systems and the multicriteria decision analysis is used for a systematic evaluation of available strategies and objective selection of the best solution. The proposed framework enables holistic multidisciplinary and objective evaluations of solutions and strategies for energy systems clearly demonstrates the pros and cons of available options and supports knowledge collection and retention to be used for a different scenario or context. The framework is demonstrated in case study evaluation solutions for a novel energy system of clean hydrogen generation.
Deploying Green Hydrogen to Decarbonize China's Coal Chemical Sector
Dec 2023
Publication
China’s coal chemical sector uses coal as both a fuel and feedstock and its increasing greenhouse gas (GHG) emissions are hard to abate by electrification alone. Here we explore the GHG mitigation potential and costs for onsite deployment of green H2 and O2 in China’s coal chemical sector using a lifecycle assessment and techno-economic analyses. We estimate that China’s coal chemical production resulted in GHG emissions of 1.1 gigaton CO2 equivalent (GtCO2eq) in 2020 equal to 9% of national emissions. We project GHG emissions from China’s coal chemical production in 2030 to be 1.3 GtCO2eq ~50% of which can be reduced by using solar or wind power-based electrolytic H2 and O2 to replace coal-based H2 and air separation-based O2 at a cost of 10 or 153 Chinese Yuan (CNY)/tCO2eq respectively. We suggest that provincial regions determine whether to use solar or wind power for water electrolysis based on lowest cost options which collectively reduce 53% of the 2030 baseline GHG emissions at a cost of 9 CNY/tCO2eq. Inner Mongolia Shaanxi Ningxia and Xinjiang collectively account for 52% of total GHG mitigation with net cost reductions. These regions are well suited for pilot policies to advance demonstration projects.
Global Land and Water Limits to Electrolytic Hydrogen Production Using Wind and Solar Resources
Sep 2023
Publication
Proposals for achieving net-zero emissions by 2050 include scaling-up electrolytic hydrogen production however this poses technical economic and environmental challenges. One such challenge is for policymakers to ensure a sustainable future for the environment including freshwater and land resources while facilitating low-carbon hydrogen production using renewable wind and solar energy. We establish a country-by-country reference scenario for hydrogen demand in 2050 and compare it with land and water availability. Our analysis highlights countries that will be constrained by domestic natural resources to achieve electrolytic hydrogen self-sufficiency in a net-zero target. Depending on land allocation for the installation of solar panels or wind turbines less than 50% of hydrogen demand in 2050 could be met through a local production without land or water scarcity. Our findings identify potential importers and exporters of hydrogen or conversely exporters or importers of industries that would rely on electrolytic hydrogen. The abundance of land and water resources in Southern and Central-East Africa West Africa South America Canada and Australia make these countries potential leaders in hydrogen export.
Risk Sensitivity Study as the Basis for Risk-informed Consequence-based Setback Distances for Liquid Hydrogen Storage Systems
Sep 2023
Publication
A quantitative risk assessment on a representative liquid hydrogen storage system was performed to identify the main drivers of individual risk and provide a technical basis for revised separation distances for bulk liquid hydrogen storage systems in regulations codes and standards requirements. The framework in the Hydrogen Plus Other Alternative Fuels Risk Assessment Models (HyRAM+) toolkit was used and multiple relevant inputs to the risk assessment (e.g. system pipe size ignition probabilities) were individually varied. For each set of risk assessment inputs the individual risk as a function of the distance away from the release point was determined and the risk-based separation distance was determined from an acceptable risk criterion. These risk-based distances were then converted to equivalent leak size using consequence models that would result in the same distance to selected hazard criteria (i.e. extent of flammable cloud heat flux and peak overpressure). The leak sizes were normalized to a fraction of the flow area of the source piping. The resulting equivalent fractional hole sizes for each sensitivity case were then used to inform selection of a conservative fractional flow area leak size of 5% that serves as the basis for consequence-based separation distance calculations. This work demonstrates a method for using a quantitative risk assessment sensitivity study to inform the selection of a basis for determining consequence-based separation distances.
Fuelling the Future: An In-depth Review of Recent Trends, Challenges and Opportunities of Hydrogen Fuel Cell for a Sustainable Hydrogen Economy
Sep 2023
Publication
Hydrogen has gained tremendous momentum worldwide as an energy carrier to transit to a net zero emission energy sector. It has been widely adopted as a promising large-scale renewable energy (RE) storage solution to overcome RE resources’ variability and intermittency nature. The fuel cell (FC) technology became in focus within the hydrogen energy landscape as a cost-effective pathway to utilize hydrogen for power generation. Therefore FC technologies’ research and development (R&D) expanded into many pathways such as cost reduction efficiency improvement fixed and mobile applications lifetime safety and regulations etc. Many publications and industrial reports about FC technologies and applications are available. This raised the necessity for a holistic review study to summarize the state-of-the-art range of FC stacks such as manufacturing the balance of plant types technologies applications and R&D opportunities. At the beginning the principal technologies to compare the well known types followed by the FC operating parameters are presented. Then the FC balance of the plant i.e. building components and materials with its functionality and purpose types and applications are critically reviewed with their limitations and improvement opportunities. Subsequently the electrical properties of FCs with their key features including advantages and disadvantages were investigated. Applications of FCs in different sectors are elaborated with their key characteristics current status and future R&D opportunities. Economic attributes of fuel cells with a pathway towards low cost are also presented. Finally this study identifies the research gaps and future avenues to guide researchers and the hydrogen industry.
Route-to-Market Strategy for Low-carbon Hydrogen from Natural Gas in the Permian Basin
Aug 2023
Publication
This paper investigates the untapped potential of the Permian Basin a multifaceted energy axis in Texas and adjoining states in the emerging era of decarbonization. Aligned with current policy directives on regional hydrogen hubs this study explores the viability of developing a hydrogen energy hub in the Permian Basin thereby producing low-carbon intensity hydrogen from natural gas in the Basin and transporting it to the Greater Houston area. Diverging from existing literature this study provides an integrated techno-economic evaluation of the entire hydrogen value chain in the Permian Basin encompassing production storage and transportation. Furthermore it comparatively analyzes the scenario of interest against an optimized base scenario thereby underlining comparative advantages and disadvantages. The paper concludes that the delivered cost of Permian based low-carbon intensity hydrogen to the Greater Houston area is $1.85/kg benchmarked to the scenario with hydrogen produced close to the Greater Houston area and delivered at $1.42/kg. Our findings reveal that Permian-based low-carbon intensity hydrogen production can achieve cost savings in feedstock ($0.25/kg) and potentially accrue a higher production tax credit due to a shorter gas supply chain to production ($0.33/kg). Nevertheless a significant cost barrier is the expense of long-haul pipeline transport ($0.90/kg) from the Permian Basin to Houston as opposed to local production. Despite the obstacles the study identifies a potential breakeven solution where increasing the production scale to at least 412000 metric ton per year (about 3 steam reforming plants) in the Permian Basin can effectively lower costs in the transport sector. Hence a scaled-up production can mitigate the cost difference and establish the Permian Basin as a competitive player in the hydrogen market. In conclusion a SWOT analysis presents Strengths Weaknesses Opportunities and Threats associated with Permian-based hydrogen production.
A Comparative Analysis of Different Hydrogen Production Methods and Their Environmental Impact
Nov 2023
Publication
This study emphasises the growing relevance of hydrogen as a green energy source in meeting the growing need for sustainable energy solutions. It foregrounds the importance of assessing the environmental consequences of hydrogen-generating processes for their long-term viability. The article compares several hydrogen production processes in terms of scalability costeffectiveness and technical improvements. It also investigates the environmental effects of each approach considering crucial elements such as greenhouse gas emissions water use land needs and waste creation. Different industrial techniques have distinct environmental consequences. While steam methane reforming is cost-effective and has a high production capacity it is coupled with large carbon emissions. Electrolysis a technology that uses renewable resources is appealing but requires a lot of energy. Thermochemical and biomass gasification processes show promise for long-term hydrogen generation but further technological advancement is required. The research investigates techniques for improving the environmental friendliness of hydrogen generation through the use of renewable energy sources. Its ultimate purpose is to offer readers a thorough awareness of the environmental effects of various hydrogen generation strategies allowing them to make educated judgements about ecologically friendly ways. It can ease the transition to a cleaner hydrogen-powered economy by considering both technological feasibility and environmental issues enabling a more ecologically conscious and climate-friendly energy landscape.
Effects of Surface Modification on a Proton Exchange Membrane for Improvements in Green Hydrogen Production
Oct 2023
Publication
Proton Exchange Membrane (PEM) electrolysis an advanced technique for producing hydrogen with efficiency and environmental friendliness signifies the forefront of progress in this domain. Compared to alkaline cells these electrolytic cells offer numerous advantages such as lower operating temperatures enhanced hydrogen production efficiency and eliminating the need for an aqueous solution. However PEM electrolysis still faces limitations due to the high cost of materials used for the membrane and catalysts resulting in elevated expenses for implementing large-scale systems. The pivotal factor in improving PEM electrolysis lies in the Platinum catalyst present on the membrane surface. Enhancing catalytic efficiency through various methods and advancements holds immense significance for the progress of this technology. This study investigates the use of patterned membranes to improve the performance of PEM electrolytic cells toward green hydrogen production. By increasing the Platinum loading across the membrane surface and enhancing catalytic performance these patterned membranes overcome challenges faced by conventionally fabricated counterparts. The findings of this research indicate that membranes with modified surfaces not only exhibit higher current draw but also achieve elevated rates of hydrogen production.
Enabling Safe and Sustainable Hydrogen Mobility: Circular Economy-Driven Management of Hydrogen Vehicle Safety
Sep 2023
Publication
Hydrogen vehicles encompassing fuel cell electric vehicles (FCEVs) are pivotal within the UK’s energy landscape as it pursues the goal of net-zero emissions by 2050. By markedly diminishing dependence on fossil fuels FCEVs including hydrogen vehicles wield substantial influence in shaping the circular economy (CE). Their impact extends to optimizing resource utilization enabling zero-emission mobility facilitating the integration of renewable energy sources supplying adaptable energy storage solutions and interconnecting diverse sectors. The widespread adoption of hydrogen vehicles accelerates the UK’s transformative journey towards a sustainable CE. However to fully harness the benefits of this transition a robust investigation and implementation of safety measures concerning hydrogen vehicle (HV) use are indispensable. Therefore this study takes a holistic approach integrating quantitative risk assessment (QRA) and an adaptive decision-making trial and evaluation laboratory (DEMATEL) framework as pragmatic instruments. These methodologies ensure both the secure deployment and operational excellence of HVs. The findings underscore that the root causes of HV failures encompass extreme environments material defects fuel cell damage delivery system impairment and storage system deterioration. Furthermore critical driving factors for effective safety intervention revolve around cultivating a safety culture robust education/training and sound maintenance scheduling. Addressing these factors is pivotal for creating an environment conducive to mitigating safety and risk concerns. Given the intricacies of conducting comprehensive hydrogen QRAs due to the absence of specific reliability data this study dedicates attention to rectifying this gap. A sensitivity analysis encompassing a range of values is meticulously conducted to affirm the strength and reliability of our approach. This robust analysis yields precise dependable outcomes. Consequently decision-makers are equipped to discern pivotal underlying factors precipitating potential HV failures. With this discernment they can tailor safety interventions that lay the groundwork for sustainable resilient and secure HV operations. Our study navigates the intersection of HVs safety and sustainability amplifying their importance within the CE paradigm. Using the careful amalgamation of QRA and DEMATEL methodologies we chart a course towards empowering decision-makers with the insights to steer the hydrogen vehicle domain to safer horizons while ushering in an era of transformative eco-conscious mobility.
Renewable Energy Sources for Green Hydrogen Generation in Colombia and Applicable Case of Studies
Nov 2023
Publication
Electrification using renewable energy sources represents a clear path toward solving the current global energy crisis. In Colombia this challenge also involves the diversification of the electrical energy sources to overcome the historical dependence on hydropower. In this context green hydrogen represents a key energy carrier enabling the storage of renewable energy as well as directly powering industrial and transportation sectors. This work explores the realistic potential of the main renewable energy sources including solar photovoltaics (8172 GW) hydropower (56 GW) wind (68 GW) and biomass (14 GW). In addition a case study from abroad is presented demonstrating the feasibility of using each type of renewable energy to generate green hydrogen in the country. At the end an analysis of the most likely regions in the country and paths to deploy green hydrogen projects are presented favoring hydropower in the short term and solar in the long run. By 2050 this energy potential will enable reaching a levelized cost of hydrogen (LCOH) of 1.7 1.5 3.1 and 1.4 USD/kg-H2 for solar photovoltaic wind hydropower and biomass respectively.
Alternative Fuels in Sustainable Logistics—Applications, Challenges, and Solutions
Sep 2024
Publication
Logistics is becoming more cost competitive while customers and regulatory bodies pressure businesses to disclose their carbon footprints creating interest in alternative fuels as a decarbonization strategy. This paper provides a thematic review of the role of alternative fuels in sustainable air land and sea logistics their challenges and potential mitigations. Through an extensive literature survey we determined that biofuels synthetic kerosene natural gas ammonia alcohols hydrogen and electricity are the primary alternative fuels of interest in terms of environmental sustainability and techno-economic feasibility. In air logistics synthetic kerosene from hydrogenated esters and fatty acids is the most promising route due to its high technical maturity although it is limited by biomass sourcing. Electrical vehicles are favorable in road logistics due to cheaper green power and efficient vehicle designs although they are constrained by recharging infrastructure deployment. In sea logistics liquified natural gas is advantageous owing to its supply chain maturity but it is limited by methane slip control and storage requirements. Overall our examination indicates that alternative fuels will play a pivotal role in the logistics networks of the future.
Batteries or Hydrogen or Both for Grid Electricity Storage Upon Full Electrification of 145 Countries with Wind-Water-Solar?
Jan 2024
Publication
Grids require electricity storage. Two emerging storage technologies are battery storage (BS) and green hydrogen storage (GHS) (hydrogen produced and compressed with clean-renewable electricity stored then returned to electricity with a fuel cell). An important question is whether GHS alone decreases system cost versus BS alone or BS+GHS. Here energy costs are modeled in 145 countries grouped into 24 regions. Existing conventional hydropower (CH) storage is used along with new BS and/or GHS. A method is developed to treat CH for both baseload and peaking power. In four regions only CH is needed. In five CH+BS is lowest cost. Otherwise CH+BS+GHS is lowest cost. CH+GHS is never lowest cost. A metric helps estimate whether combining GHS with BS reduces cost. In most regions merging (versus separating) grid and non-grid hydrogen infrastructure reduces cost. In sum worldwide grid stability may be possible with CH+BS or CH+BS+GHS. Results are subject to uncertainties.
Comparative Life cycle Greenhouse Gas Emission and Cost Assessment of Hydrogen Fuel and Power for Singapore
Feb 2025
Publication
To identify lower-carbon and cost-effective hydrogen supplies for fuel and power generation in Singapore we assessed the cradle-to-gate greenhouse gas (GHG) emissions and the landed costs of over fifty supply chains from Malaysia and Australia with current and emerging blue turquoise and green hydrogen production and carrier technologies. We found that with current technologies the total life cycle global warming potential of local H2 production using steam methane reforming with carbon capture (4.47 kg CO2e/kg H2) is lower than importing solar-generated green H2 from Australia transported as NH3 (6.48 kg CO2e/kg H2) due to large emissions from conversion and transportation processes in the latter supply chain. When also considering emerging technologies turquoise H2 produced with the thermal decomposition of methane locally or in Malaysia is the most economical solution while wind-generated H2 from Australia transported as liquefied H2 or NH3 produce the least GHG emissions. In addition we projected the impacts of the Singapore carbon tax methane abatement in NG production and reduction of renewable energy embodied emissions and costs on the supply chains in the year 2030. We estimated that with the expected renewable energy improvements the emissions and costs of power generated from imported solar-powered H2 could drop by as much as 74% and 70% respectively.
Linking Cost Decline and Demand Surge in the Hydrogen Market: A Case Study in China
Jun 2023
Publication
Hydrogen is crucial in achieving global energy transition and carbon neutrality goals. Existing market estimates typically presume linear or exponential growth but fail to consider how market demand responds to the declining cost of underlying technologies. To address this this study utilizes a learning curve model to project the cost of electrolyzers and its subsequent impact on hydrogen market aligning with a premise that the market demand is proportional to the cost of hydrogen. In a case study of China’s hydrogen market projecting from 2020 to 2060 we observed substantial differences in market evolution compared to exponential growth scenarios. Contrary to exponential growth scenarios China’s hydrogen market experiences faster growth during the 2020–2040 period rather than later. Such differences underscore the necessity for proactive strategic planning in emerging technology markets particularly for those experiencing rapid cost decline such as hydrogen. The framework can also be extended to other markets by using local data providing valuable insights to investors policymakers and developers engaged in the hydrogen market.
Visualisation and Quantification of Wind-induced Variability in Hydrogen Clouds Following Releases of Liquid Hydrogen
Sep 2023
Publication
Well characterized experimental data for consequence model validation is important in progressing the use of liquid hydrogen as an energy carrier. In 2019 the Health and Safety Executive (HSE) undertook a series of liquid hydrogen dispersion and combustion experiments as a part of the Pre-normative Research for Safe Use of Liquid Hydrogen (PRESLHY) project. In partnership between the National Renewable Energy Laboratory (NREL) and HSE time and spatially varying hydrogen concentration measurements were made in 25 dispersion experiments and 23 congested ignition experiments associated with PRESLHY WP3 and WP5 respectively. These measurements were undertaken using the hydrogen wide area monitoring system developed by NREL. During the 23 congested ignition experiments high variability was observed in the measured explosion severity during experiments with similar initial conditions. This led to the conclusion that wind including localized gusts had a large influence on the dispersion of the hydrogen and therefore the quantity of hydrogen that was present in the congested region of the explosions. Using the hydrogen concentration measurements taken immediately prior to ignition the hydrogen clouds were visualized in an attempt to rationalize the variability in overpressure between the tests. Gaussian process regression was applied to quantify the variability of the measured hydrogen concentrations. This analysis could also be used to guide modifications in experimental designs for future research on hydrogen combustion behavior.
Developing a Generalized Framework for Assessing Safety of Hydrogen Vehicles in Tunnels
Sep 2023
Publication
For widespread adoption of hydrogen fuel cell powered vehicles such vehicles need to be able to provide similar transportation capabilities as their gasoline/diesel powered counterparts. Meeting this requirement in many regions will necessitate access to tunnels. Previous work completed at Sandia National Laboratories provided high-fidelity consequence modeling of hydrogen vehicle tunnel crashes for a specific fire scenario in selected Massachusetts tunnels. To consider additional tunnels a generalized tunnel safety analysis framework is being developed. This framework aims to be broader than specific fire scenarios in specific tunnels allowing it to be applied to a range of tunnel geometries vehicle types and crash scenarios. Initial steps in the development of the generalized framework are reported within this work. Representative tunnel characteristics are derived based on data for tunnels in the U.S. Tunnel dimensions shapes and traffic levels are among the many characteristics reported within the data that can be used to inform crash scenario specification. Various crash scenario parameters are varied using lower-fidelity consequence modeling to quantify the impact on resulting safety hazards for time-dependent releases. These lower-fidelity models consider the unignited dispersion of hydrogen gas the thermal effects of jet fires and potential impacts of overpressures. Different sizes/classes of vehicles are considered as the total amount of hydrogen onboard may greatly affect scenario-specific consequences. The generalized framework will allow safety assessments to be both more agile and consistent when applied to different types of tunnels.
Review of the US 2050 Long Term Strategy to Reach Net Zero Carbon Emissions
Jul 2024
Publication
In 2015 during the lead up to the Paris Climate Agreement the United States set forth a Nationally Determined Contribution that outlines national goals for greenhouse gas emission reductions. It was not until 2021 that the US put forth a long-term strategy that lays out the pathway to reach these goals. The US long-term strategy lays the framework for research needs to meet the greenhouse gas emission reduction goals and incentivizes industry to meet the goals using a variety of policies. The five US long term strategy core elements are to decarbonize electricity electrify end uses and switch to clean fuels cut energy waste reduce methane and other non-carbon dioxide greenhouse gas emissions and to scale up carbon dioxide removal. Implementation of the long term strategy has generally been funded by tax incentives and government grants that were approved as part of the Inflation Reduction Act. Political headwinds societal Not in My Backyard resistance long-term economic funding cumbersome permitting requirements and incentives vs. taxation debate are significant policy/nontechnical hurdles. Technical challenges remain regarding effective energy efficiency implementation the use of hydrogen as a fuel cost effective carbon emission treatment nuclear energy expansion renewables expansion and grid integration biofuel integration efficient and safe energy storage and electrical grid adequacy/expansion. This review article condenses the multitude of technical and policy issues facing the US long-term strategy providing readers with an overview of the extent and magnitude of the challenges while outlining possible solutions.
Assessment of a Coupled Electricity and Hydrogen Sector in the Texas Energy System in 2050
Oct 2024
Publication
Due to its ability to reduce emissions in the hard-to-abate sectors hydrogen is expected to play a significant role in future energy systems. This study modifies a sector-coupled dynamic modeling framework for electricity and hydrogen by including policy constraints carbon prices and possible hydrogen pathways and applies it to Texas in 2050. The impact of financial policies including the US clean hydrogen production tax credit on required infrastructure and costs are explored. Due to low natural gas prices financial levers are necessary to promote low-carbon hydrogen production as the optimized solution. The Levelized Costs of Hydrogen are found to be $1.50/kg in the base case (primarily via steam methane reformation production) and lie between $2.10 - 3.10/kg when production is via renewable electrolysis. The supporting infrastructure required to supply those volumes of renewable hydrogen is immense. The hydrogen tax credit was found to be enough to drive production via electrolysis.
Critical Mineral Demands May Limit Scaling of Green Hydrogen Production
Jan 2024
Publication
Hydrogen (H2) is widely viewed as critical to the decarbonization of industry and transportation. Water electrolysis powered by renewable electricity commonly referred to as green H2 can be used to generate H2 with low carbon dioxide emissions. Herein we analyze the critical mineral and energy demands associated with green H2 production under three different hypothetical future demand scenarios ranging from 100–1000 Mtpa H2. For each scenario we calculate the critical mineral demands required to build water electrolyzers (i.e. electrodes and electrolyte) and to build dedicated or additional renewable electricity sources (i.e. wind and solar) to power the electrolyzers. Our analysis shows that scaling electrolyzer and renewable energy technologies that use platinum group metals and rare earth elements will likely face supply constraints. Specifically larger quantities of lanthanum yttrium or iridium will be needed to increase electrolyzer capacity and even more neodymium silicon zinc molybdenum aluminum and copper will be needed to build dedicated renewable electricity sources. We find that scaling green H2 production to meet projected netzero targets will require ~24000 TWh of dedicated renewable energy generation which is roughly the total amount of solar and wind projected to be on the grid in 2050 according to some energy transition models. In summary critical mineral constraints may hinder the scaling of green H2 to meet global net-zero emissions targets motivating the need for the research and development of alternative lowemission methods of generating H2
Recent Progress on Ammonia Cracking Technologies for Scalable Hydrogen Production
Jun 2024
Publication
The global energy transition necessitates the development of technologies enabling cost-effective and scalable conversion of renewable energies into storable and transportable forms. Green ammonia with its high hydrogen storage capacity emerges as a promising carbon-free hydrogen carrier. This article reviews recent progress in industrially relevant catalysts and technologies for ammonia cracking which is a pivotal step in utilizing ammonia as a hydrogen storage material. Catalysts based on Ru Ni Fe Co and Fe–Co are evaluated with Cobased catalysts showing exceptional potential for ammonia cracking. Different reactor technologies and their applications are briefly discussed. This review concludes with perspectives on overcoming existing challenges emphasizing the need for catalyst development effective reactor design and sustainable implementation in the context of the energy transition.
Techno-economic Analysis of a Renewable-based Hybrid Energy system for Utility and Transportation Facilities in a Remote Community of Northern Alberta
Jun 2023
Publication
Many off-grid communities in Canada are dependent on diesel generators to fulfill their utility and transportation needs causing destructive environmental impact. This study aims to optimize and investigate the technoeconomic feasibility of a hybrid renewable energy system to satisfy the 1.6 MWh/day electricity 184.2 kWh/day thermal and 428.38 kg/year hydrogen demand simultaneously Trout Lake a remote community of Northern Alberta. A novel hybrid energy system consisting of solar PV wind turbine electrolyzer hydrogen tank battery fuel cell hydrogen boiler and thermal load controller has been proposed to generate electricity heat and hydrogen by renewables which reduce carbon emission utilizing the excess energy (EE). Five different scenarios were developed in HOMER Pro software and the results were compared to identify the best combination of hybrid renewable energy systems. The results indicate that the fifth scenario is the optimal renewable energy system that provides a lower cost of energy (COE) at $0.675/kWh and can reduce 99.99% carbon emission compared to the diesel-based system. Additionally the utilization of thermal load controller battery and fuel cell improved the system’s reliability increasing renewable fraction (RF) (93.5%) and reducing EE (58.3%) significantly. In comparison to the diesel-based systems it is also discovered that battery energy storage is the most affordable option while fuel cells are the more expensive choice for remote community. Sensitivity analyses are performed to measure the impact of different dominating factors on COE EE and RF.
Future Hydrogen Economies Imply Environmental Trade-offs and a Supply-demand Mismatch
Aug 2024
Publication
Hydrogen will play a key role in decarbonizing economies. Here we quantify the costs and environmental impacts of possible large-scale hydrogen economies using four prospective hydrogen demand scenarios for 2050 ranging from 111–614 megatonne H2 year−1 . Our findings confirm that renewable (solar photovoltaic and wind) electrolytic hydrogen production generates at least 50–90% fewer greenhouse gas emissions than fossil-fuel-based counterparts without carbon capture and storage. However electrolytic hydrogen production could still result in considerable environmental burdens which requires reassessing the concept of green hydrogen. Our global analysis highlights a few salient points: (i) a mismatch between economical hydrogen production and hydrogen demand across continents seems likely; (ii) regionspecific limitations are inevitable since possibly more than 60% of large hydrogen production potentials are concentrated in water-scarce regions; and (iii) upscaling electrolytic hydrogen production could be limited by renewable power generation and natural resource potentials.
Ultra-fast Green Hydrogen Production from Municipal Wastewater by an Integrated Forward Osmosis-alkaline Water Electrolysis System
Mar 2024
Publication
Recent advancements in membrane-assisted seawater electrolysis powered by renewable energy offer a sustainable path to green hydrogen production. However its large-scale implementation faces challenges due to slow powerto-hydrogen (P2H) conversion rates. Here we report a modular forward osmosis-water splitting (FOWS) system that integrates a thin-film composite FO membrane for water extraction with alkaline water electrolysis (AWE) denoted as FOWSAWE. This system generates high-purity hydrogen directly from wastewater at a rate of 448 Nm3 day−1 m−2 of membrane area over 14 times faster than the state-of-the-art practice with specific energy consumption as low as 3.96 kWh Nm−3 . The rapid hydrogen production rate results from the utilisation of 1 M potassium hydroxide as a draw solution to extract water from wastewater and as the electrolyte of AWE to split water and produce hydrogen. The current system enables this through the use of a potassium hydroxide-tolerant and hydrophilic FO membrane. The established waterhydrogen balance model can be applied to design modular FO and AWE units to meet demands at various scales from households to cities and from different water sources. The FOWSAWE system is a sustainable and an economical approach for producing hydrogen at a record-high rate directly from wastewater marking a significant leap in P2H practice.
Hydrogen Supply Design for the Decarbonization of Energy-intensive Industries Addressing Cost, Inherent Safety and Environmental Performance
Sep 2025
Publication
Through mathematical modeling this paper integrates economic safety and environmental assessments to evaluate alternative hydrogen supply options (on-site production and external supply) and various hydrogenbased system configurations for decarbonizing energy-intensive industries. The model is applied to a case study in the glass sector. While reliance on natural gas remains the most cost-effective and safest solution it does not align with decarbonization objectives. Assuming a complete hydrogen transition on-site production reduces emissions by 85 % compared to current levels and improves safety performance over external supply. External supply of grey hydrogen becomes counterproductive increasing emissions by 68 % compared to natural gas operations. Nevertheless hydrogen cost rises from 3.6 €/kg with external supply to 4.2 €/kg with on-site production doubling the fuel cost relative to natural gas. To address the trade-offs the paper explores how specific constraints influence system design. A sensitivity analysis on key factors affecting hydrogen-related decisions provides additional support for strategic decision-making.
Investigating the Investments Required to Transition New Zealand’s Heavy-Duty Vehicles to Hydrogen
Mar 2021
Publication
Reducing greenhouse gas emissions in the transport sector is known to be an important contribution to climate change mitigation. Some parts of the transport sector are particularly difficult to decarbonize; this includes the heavy-duty vehicle sector which is considered one of the “hardto-abate” sectors of the economy. Transitioning from diesel trucks to hydrogen fuel cell trucks has been identified as a potential way to decarbonize the sector. However the current and future costs and efficiencies of the enabling technologies remain unclear. In light of these uncertainties this paper investigates the investments required to decarbonize New Zealand’s heavy-duty vehicle sector with green hydrogen. By combining system dynamics modelling literature and hydrogen transition modelling literature a customized methodology is developed for modelling hydrogen transitions with system dynamics modelling. Results are presented in terms of the investments required to purchase the hydrogen production capacity and the investments required to supply electricity to the hydrogen production systems. Production capacity investments are found to range between 1.59 and 2.58 billion New Zealand Dollars and marginal electricity investments are found to range between 4.14 and 7.65 billion New Zealand Dollars. These investments represent scenarios in which 71% to 90% of the heavy-duty vehicle fleet are replaced with fuel cell trucks by 2050. The wide range of these findings reflects the large uncertainties in estimates of how hydrogen technologies will develop over the course of the next thirty years. Policy recommendations are drawn from these results and a clear opportunity for future work is outlined. Most notably the results from this study should be compared with research investigating the investments required to decarbonize the heavy-duty vehicle sectors with alternative technologies such as battery-electric trucks biodiesel and catenary systems. Such a comparison would ensure that the most cost effective decarbonization strategy is employed.
Cost-effect Scheduling of a Hydrogen-based Iron and Steel Plant Powered by a Grid-assisted Renewable Energy System
Feb 2025
Publication
The iron and steel industry contributes approximately 25% of global industrial CO2 emissions necessitating substantial decarbonisation efforts. Hydrogen-based iron and steel plants (HISPs) which utilise hydrogen-based direct reduction of iron ore followed by electric arc furnace steelmaking have attracted substantial research interest. However commercialisation of HISPs faces economic feasibility issues due to the high electricity costs of hydrogen production. To improve economic feasibility HISPs are jointly powered by local renewable generators and bulk power grid i.e. by a grid-assisted renewable energy system. Given the variability of renewable energy generation and time-dependent electricity prices flexible scheduling of HISP production tasks is essential to reduce electricity costs. However cost-effectively scheduling of HISP production tasks is non-trivial as it is subject to critical operational constraints arising from the tight coupling and distinct operational characteristics of HISPs sub-processes. To address the above issues this paper proposes an integrated resource-task network (RTN) to elaborately model the critical operational constraints such as resource balance task execution and transfer time. More specifically each sub-process is first modelled as an individual RTN which is then seamlessly integrated through boundary dependency constraints. By embedding the formulated operational constraints into optimisation a cost-effective scheduling model is developed for HISPs powered by the grid-assisted renewable energy system. Numerical results demonstrate that compared to conventional scheduling approaches the proposed method significantly reduces total operational costs across various production scales.
Simulation of PEM Electrolyzer Power Management with Renewable Generation in Owerri, Nigeria
Jan 2025
Publication
Proton exchange membrane electrolyzers are an attractive technology for hydrogen production due to their high efficiency low maintenance cost and scalability. To receive these benefits however electrolyzers require high power reliability and have relatively high demand. Due to their intermittent nature integrating renewable energy sources like solar and wind has traditionally resulted in a supply too sporadic to consistently power a proton exchange membrane electrolyzer. This study develops an electrolyzer model operating with renewable energy sources at a highly instrumented university site. The simulation uses dynamic models of photovoltaic solar and wind systems to develop models capable of responding to changing climatic and seasonal conditions. The aim therefore is to observe the feasibility of operating a proton exchange membrane system fuel cell yearround at optimal efficiency. To address the problem of feasibility with dynamic renewable generation a case study demonstrates the proposed energy management system. A site with a river onsite is chosen to ensure sufficient wind resources. Aside from assessing the feasibility of pairing renewable generation with proton exchange membrane systems this project shows a reduction in the intermittency plaguing previous designs. Finally the study quantifies the performance and effectiveness of the PEM energy management system design. Overall this study highlights the potential of proton exchange membrane electrolysis as a critical technology for sustainable hydrogen production and the importance of modeling and simulation techniques in achieving its full potential.
Barriers to Creating a Market for Hydrogen: Insights from Global Roadmaps and Stakeholders in the United States
Feb 2025
Publication
We analyze barriers to setting up a hydrogen market by using a PESTEL framework that examines political economic social technological environmental and legal barriers. This framework is advantageous for analyzing macro-environmental factors to understand potential challenges and opportunities in creating such a market. Internationally the framework was applied to analyzing barriers in 56 national hydrogen roadmaps and domestically in the U.S. to semi-structured interviews with 43 stakeholders involved with hydrogen projects across the U.S. today. In the country-level international analysis infrastructure development was the most identified barrier with 43 countries including this factor. Infrastructure development included infrastructure for hydrogen storage transportation and distribution and frequently alluded not only to the need for the infra structure but also the costs associated. The second most identified barrier was related to the need for market development - including but not limited to capital costs economic competition supply and demand matching and first-mover reticence. For the domestic analysis results from qualitative content analysis confirmed considerable variability across regions and stakeholder backgrounds. Particularly notable were divergent views about the importance of public understanding of and support for hydrogen projects with industry respondents arguing this was not important and government and academic respondents considering it very important. The barriers seen as having the largest impact on deployment of hydrogen projects was a lack of regulatory clarity and lack of decision makers’ knowledge and awareness. Domestically the most often introduced barriers were the need for the support of market demand and the need to develop a hydrogen workforce.
Review on Ammonia as a Potential Fuel: From Synthesis to Economics
Feb 2021
Publication
Ammonia a molecule that is gaining more interest as a fueling vector has been considered as a candidate to power transport produce energy and support heating applications for decades. However the particular characteristics of the molecule always made it a chemical with low if any benefit once compared to conventional fossil fuels. Still the current need to decarbonize our economy makes the search of new methods crucial to use chemicals such as ammonia that can be produced and employed without incurring in the emission of carbon oxides. Therefore current efforts in this field are leading scientists industries and governments to seriously invest efforts in the development of holistic solutions capable of making ammonia a viable fuel for the transition toward a clean future. On that basis this review has approached the subject gathering inputs from scientists actively working on the topic. The review starts from the importance of ammonia as an energy vector moving through all of the steps in the production distribution utilization safety legal considerations and economic aspects of the use of such a molecule to support the future energy mix. Fundamentals of combustion and practical cases for the recovery of energy of ammonia are also addressed thus providing a complete view of what potentially could become a vector of crucial importance to the mitigation of carbon emissions. Different from other works this review seeks to provide a holistic perspective of ammonia as a chemical that presents benefits and constraints for storing energy from sustainable sources. State-of-the-art knowledge provided by academics actively engaged with the topic at various fronts also enables a clear vision of the progress in each of the branches of ammonia as an energy carrier. Further the fundamental boundaries of the use of the molecule are expanded to real technical issues for all potential technologies capable of using it for energy purposes legal barriers that will be faced to achieve its deployment safety and environmental considerations that impose a critical aspect for acceptance and wellbeing and economic implications for the use of ammonia across all aspects approached for the production and implementation of this chemical as a fueling source. Herein this work sets the principles research practicalities and future views of a transition toward a future where ammonia will be a major energy player.
Prediction of Transient Hydrogen Flow of Proton Exchange Membrane Electrolyzer Using Artificial Neural Network
Aug 2023
Publication
A proton exchange membrane (PEM) electrolyzer is fed with water and powered by electric power to electrochemically produce hydrogen at low operating temperatures and emits oxygen as a by-product. Due to the complex nature of the performance of PEM electrolyzers the application of an artificial neural network (ANN) is capable of predicting its dynamic characteristics. A handful of studies have examined and explored ANN in the prediction of the transient characteristics of PEM electrolyzers. This research explores the estimation of the transient behavior of a PEM electrolyzer stack under various operational conditions. Input variables in this study include stack current oxygen pressure hydrogen pressure and stack temperature. ANN models using three differing learning algorithms and time delay structures estimated the hydrogen mass flow rate which had transient behavior from 0 to 1 kg/h and forecasted better with a higher count (>5) of hidden layer neurons. A coefficient of determination of 0.84 and a mean squared error of less than 0.005 were recorded. The best-fitting model to predict the dynamic behavior of the hydrogen mass flow rate was an ANN model using the Levenberg–Marquardt algorithm with 40 neurons that had a coefficient of determination of 0.90 and a mean squared error of 0.00337. In conclusion optimally fit models of hydrogen flow from PEM electrolyzers utilizing artificial neural networks were developed. Such models are useful in establishing an agile flow control system for the electrolyzer system to help decrease power consumption and increase efficiency in hydrogen generation.
Production of Hydrogen and H2/NH3 Mixtures from Ammonia at Elevated Pressures in a Cataytic Membrane Reformer
Jul 2025
Publication
Hydrogen delivery at elevated pressures is often required for fuel cell and combustion applications to improve volumetric energy density. Catalytic membrane reformers (CMRs) integrate hydrogen production and purification from reforming liquid hydrogen carriers such as ammonia enabling direct recovery of pressurized purified hydrogen. In this study high-pressure ammonia is supplied to a catalytic membrane reformer (CMR) to enhance both performance and hydrogen recovery pressures. Increasing operating pressure in the CMR resulted in nearly doubling the hydrogen flux from 17.2 to 34 sccm cm− 2 compared to our previous work. However as the recovery pressure of the permeate increased the performance notably decreased with hydrogen recovery dropping from 98 % at atmospheric pressure to 44 % at 10 bar. Nevertheless the system demonstrated rates of ammonia conversion hydrogen flux and hydrogen recovery comparable to leading literature reports when supplying ammonia at 20 bar and recovering the permeate up to 10 bar. Additionally by using ammonia as both a feed and sweep gas we demonstrate the direct production of high-pressure NH3/H2 fuel blends including a 70:30 mixture representative of natural gas without loss in CMR performance. These results highlight the potential of CMR technology to reduce hydrogen compression costs and enable on-demand generation of ammonia-derived fuel blends.
Investigation of the Suitability of Viper: Blast CFD Software for Hydrogen and Vapor Cloud Explosions
Sep 2023
Publication
Many simplified methods for estimating blast loads from a hydrogen or vapor cloud explosion are unable to take into account the accurate geometry of confining spaces obstacles or landscape that may significantly interact with the blast wave and influence the strength of blast loads. Computation fluid dynamics (CFD) software Viper::Blast which was originally developed for the simulation of the detonation of high explosives is able to quickly and easily model geometry for blast analyses however its use for vapor cloud explosions and deflagrations is not well established. This paper describes the results of an investigation into the suitability of Viper::Blast for use in modeling hydrogen deflagration and detonation events from various experiments in literature. Detonation events have been captured with a high degree of detail and relatively little uncertainty in inputs while deflagration events are significantly more complex. An approach is proposed that may allow for a reasonable bounding of uncertainty potentially leading to an approach to CFD-based Monte Carlo analyses that are able to address a problem’s true geometry while remaining reasonably pragmatic in terms of run-time and computational investment. This will allow further exploration of practical CFD application to inform hydrogen safety in the engineering design assessment and management of energy mobility and transport systems infrastructure and operations.
Examining the Nature of Two-dimensional Transverse Waves in Marginal Hydrogen Detonations using Boundary Layer Loss Modeling with Detailed Chemistry
Sep 2023
Publication
Historically it has been a challenge to simulate the experimentally observed cellular structures and marginal behavior of multidimensional hydrogen-oxygen detonations in the presence of losses even with detailed chemistry models. Very recently a quasi-two-dimensional inviscid approach was pursued where losses due to viscous boundary layers were modeled by the inclusion of an equivalent mass divergence in the lateral direction using Fay’s source term formulation with Mirels’ compressible boundary layer solutions. The same approach was used for this study along with the inclusion of thermally perfect detailed chemistry in order to capture the correct ignition sensitivity of the gas to dynamic changes in the thermodynamic state behind the detonation front. In addition the strength of transverse waves and their impact on the detonation front was investigated. Here the detailed San Diego mechanism was applied and it has been found that the detonation cell sizes can be accurately predicted without the need to prescribe specific parameters for the combustion model. For marginal cases where the detonation waves approach their failure limit quasi-stable mode behavior was observed where the number of transverse waves monotonically decreased to a single strong wave over a long enough distance. The strong transverse waves were also found to be slightly weaker than the detonation front indicating that they are not overdriven in agreement with recent studies.
Advances in Photothermal Catalysts for Solar-driven Hydrogen Production
Nov 2024
Publication
Hydrogen is increasingly recognized as a pivotal energy storage solution and a transformative alternative to conventional energy sources. This review summarizes the evolving landscape of global H2 production and consumption markets focusing on the crucial role of photothermal catalysts (PTCs) in driving Hydrogen evolution reactions (HER) particularly with regards to oxide selenide and telluride-based PTCs. Within this exploration the mechanisms of PTCs take center stage elucidating the intricacies of light absorption localized heating and catalytic activation. Essential optimization parameters ranging from temperature and irradiance to catalyst composition and pH are detailed for their paramount role in enhancing catalytic efficiency. This work comprehensively explores photothermal catalysts (PTCs) for hydrogen production by assessing their synthesis techniques and highlighting the current research gaps particularly in optimizing catalytic stability light absorption and scalability. The energy-efficient nature of oxide selenide and telluride-based PTCs makes them prime candidates for sustainable H2 production when compared to traditional materials. By analyzing a range of materials we summarize key performance metrics including hydrogen evolution rates ranging from 0.47 mmolh− 1 g− 1 for Ti@TiO2 to 22.50 mmolh− 1 g− 1 for Mn0.2Cd0.8S/NiSe2. The review concludes with a strategic roadmap aimed at enhancing PTC performance to meet the growing demand for renewable hydrogen as well as a critical literature review addressing challenges and prospects in deploying PTCs.
Modelling Flexibility Requirements in Deep Decarbonisation Scenarios: The Role of Conventional Flexibility and Sector Coupling Options in the European 2050 Energy System
Feb 2024
Publication
Russia’s invasion of Ukraine has reaffirmed the importance of scaling up renewable energy to decarbonise Europe’s economy while rapidly reducing its exposure to foreign fossil fuel suppliers. Therefore the question of sources of flexibility to support a fully decarbonised European energy system is becoming even more critical in light of a renewable-dominated energy system. We developed and used a Pan-European energy system model to systematically assess and quantify sources of flexibility to meet deep decarbonisation targets. The electricity supply sector and electricity-based end-use technologies are crucial in achieving deep decarbonisation. Other low-carbon energy sources like biomethane hydrogen synthetic e-fuels and bioenergy with carbon capture and storage will also play a role. To support a fully decarbonised European energy system by 2050 both temporal and spatial flexibility will be needed. Spatial flexibility achieved through investments in national electricity networks and cross-border interconnections is crucial to support the aggressive roll-out of variable renewable energy sources. Cross-border trade in electricity is expected to increase and in deep decarbonisation scenarios the electricity transmission capacity will be larger than that of natural gas. Hydrogen storage and green hydrogen production will play a key role in providing traditional inter-seasonal flexibility and intraday flexibility will be provided by a combination of electrical energy storage hydrogen-based storage solutions (e.g. liquid H2 and pressurised storage) and hybrid heat pumps. Hydrogen networks and storage will become more critical as we move towards the highest decarbonisation scenario. Still the need for natural gas networks and storage will decrease substantially.
Recent Advances in Combustion Science Related to Hydrogen Safety
Dec 2024
Publication
Hydrogen is a key pillar in the global Net Zero strategy. Rapid scaling up of hydrogen production transport distribution and utilization is expected. This entails that hydrogen which is traditionally an industrial gas will come into proximity of populated urban areas and in some situations handled by the untrained public. To realize all their benefits hydrogen and its technologies must be safely developed and deployed. The specific properties of hydrogen involving wide flammability range low ignition energy and fast flame speed implies that any accidental release of hydrogen can be easily ignited. Comparing with conventional fuels combustion systems fueled by hydrogen are also more prone to flame instability and abnormal combustion. This paper aims to provide a comprehensive review about combustion research related to hydrogen safety. It starts with a brief introduction which includes some overview about risk analysis codes and standards. The core content covers ignition fire explosions and deflagration to detonation transition (DDT). Considering that DDT leads to detonation and that detonation may also be induced directly under special circumstances the subject of detonation is also included for completeness. The review covers laboratory medium and large-scale experiments as well as theoretical analysis and numerical simulation results. While highlights are provided at the end of each section the paper closes with some concluding remarks highlighting the achievements and key knowledge gaps.
Engineering Models for Refueling Protocol Development: Validation and Recommendations
Sep 2023
Publication
Fouad Ammouri,
Nicola Benvenuti,
Elena Vyazmina,
Vincent Ren,
Guillaume Lodier,
Quentin Nouvelot,
Thomas Guewouo,
Dorine Crouslé,
Rony Tawk,
Nicholas Hart,
Steve Mathison,
Taichi Kuroki,
Spencer Quong,
Antonio Ruiz,
Alexander Grab,
Alexander Kvasnicka,
Benoit Poulet,
Christopher Kutz and
Martin Zerta
The PRHYDE project (PRotocol for heavy duty HYDrogEn refueling) funded by the Clean Hydrogen partnership aims at developing recommendations for heavy-duty refueling protocols used for future standardization activities for trucks and other heavy duty transport systems applying hydrogen technologies. Development of a protocol requires a validated approach. Due to the limited time and budget the experimental data cannot cover the whole possible ranges of protocol parameters such as initial vehicle pressure and temperature ambient and precooling temperatures pressure ramp refueling time hardware specifications etc. Hence a validated numerical tool is essential for a safe and efficient protocol development. For this purpose engineering tools are used. They give good results in a very reasonable computation time of several seconds or minutes. These tools provide the heat parameters estimation in the gas (volume average temperature) and 1D temperature distribution in the tank wall. The following models were used SOFIL (Air Liquide tool) HyFill (by ENGIE) and H2Fills (open access code by NREL). The comparison of modelling results and experimental data demonstrated a good capability of codes to predict the evolution of average gas temperature in function of time. Some recommendations on model validation for the future protocol development are given.
Integration of Underground Green Hydrogen Storage in Hybrid Energy Generation
May 2024
Publication
One of the major challenges in harnessing energy from renewable sources like wind and solar is their intermittent nature. Energy production from these sources can vary based on weather conditions and time of day making it essential to store surplus energy for later use when there is a shortfall. Energy storage systems play a crucial role in addressing this intermittency issue and ensuring a stable and reliable energy supply. Green hydrogen sourced from renewables emerges as a promising solution to meet the rising demand for sustainable energy addressing the depletion of fossil fuels and environmental crises. In the present study underground hydrogen storage in various geological formations (aquifers depleted hydrocarbon reservoirs salt caverns) is examined emphasizing the need for a detailed geological analysis and addressing potential hazards. The paper discusses challenges associated with underground hydrogen storage including the requirement for extensive studies to understand hydrogen interactions with microorganisms. It underscores the importance of the issue with a focus on reviewing the the various past and present hydrogen storage projects and sites as well as reviewing the modeling studies in this field. The paper also emphasizes the importance of incorporating hybrid energy systems into hydrogen storage to overcome limitations associated with standalone hydrogen storage systems. It further explores the past and future integrations of underground storage of green hydrogen within this dynamic energy landscape.
Hydrogen Station Prognostics and Health Monitoring Model
Aug 2023
Publication
Hydrogen fuel has shown promise as a clean alternative fuel aiding in the reduction of fossil fuel dependence within the transportation sector. However hydrogen refueling stations and infrastructure remains a barrier and are a prerequisite for consumer adoption of low-cost and low-emission fuel cell electric vehicles (FCEVs). The costs for FCEV fueling include both station capital costs and operation and maintenance (O&M) costs. Contributing to these O&M costs unscheduled maintenance is presently more costly and more frequent than for similar gasoline fueling infrastructure and is asserted to be a limiting factor in achieving FCEV customer acceptance and cost parity. Unscheduled maintenance leads to longer station downtime therefore causing an increase in missed fueling opportunities which forces customers to seek refueling at other operable stations that may be significantly farther away. This research proposes a framework for a hydrogen station prognostics health monitoring (H2S PHM) model that can minimize unexpected downtime by predicting the remaining useful life for primary hydrogen station components within the major station subsystems. The H2S PHM model is a data-driven statistical model based on O&M data collected from 34 retail hydrogen stations located in the U.S. The primary subcomponents studied are the dispenser compressor and chiller. The remaining useful life calculations are used to decide whether or not maintenance should be completed based on the prediction and expected future station use. This paper presents the background method and results for the H2S PHM model as for a means for improving station availability and customer confidence in FCEVs and hydrogen infrastructure
A Perspective on Broad Deployment of Hydrogen-fueled Vehicles for Ground Freight Transportation with a Comparison to Electric Vehicles
Oct 2024
Publication
The pressing global challenge of climate change necessitates a concerted effort to limit greenhouse gas emissions particularly carbon dioxide. A critical pathway is to replace fossil fuel sources by electrification including transportation. While electrification of light-duty vehicles is rapidly expanding the heavy-duty vehicle sector is subject to challenges notably the logistical drawbacks of the size and weight of high-capacity batteries required for range as well as the time for battery charging. This Perspective highlights the potential of hydrogen fuel-cell vehicles as a viable alternative for heavy-duty road transportation. We evaluate the implications of hydrogen integration into the freight economy energy dynamics and CO2 mitigation and envision a roadmap for a holistic energy transition. Our critical opinion presented in this Perspective is that federal incentives to produce hydrogen could foster growth in the nascent hydrogen economy. The pathway that we propose is that initial focus on operators of large fleets that could control their own fueling infrastructure. This opinion was formed from private discussions with numerous stakeholders during the formation of one of the awarded hydrogen hubs if they focus on early adopters that could leverage the hydrogen supply chain.
Overview of International Activities in Hydrogen System Safety in IEA Hydrogen TCP Task 43
Sep 2023
Publication
Safety and reliability have long been recognized as key issues for the development commercialization and implementation of new technologies and infrastructure and hydrogen systems are no exception to this rule. Reliability engineering quantitative risk assessment (QRA) and knowledge exchange each play a key role in proactive addressing safety – before problems happen – and help us learn from problems if they happen. Many international research activities are focusing on both reliability and risk assessment for hydrogen systems. However the element of knowledge exchange is sometimes less visible. To support international collaboration and knowledge exchange the International Energy Agency (IEA) convened a new Technology Collaboration Program “Task 43: Safety and Regulatory Aspects of Emerging Large Scale Hydrogen Energy Applications” started in June 2022. Within Task 43 Subtask E focuses on Hydrogen Systems Safety. This paper discusses the structure of the Hydrogen Systems Safety subtask and the aligned activities and introduces opportunities for future work.
Methodology for Consequence-based Setback Distance Calculations for Bulk Liquid Hydrogen Storage Systems
Sep 2023
Publication
Updates to the separation distances between different exposures and bulk liquid hydrogen systems are included in the 2023 version of NFPA 2: Hydrogen Technologies Code. This work details the models and calculations leading to those distances. The specific models used including the flow of liquid hydrogen through an orifice within the Hydrogen Plus Other Alternative Fuels Risk Assessment Models (HyRAM+) toolkit are described and discussed to emphasize challenges specific to liquid hydrogen systems. Potential hazards and harm affecting individual exposures (e.g. ignition sources air intakes) for different unignited concentrations overpressures and heat flux levels were considered and exposures were grouped into three bins. For each group the distances to a specific hazard criteria (e.g. heat flux level) for a characteristic leak size informed by a risk-analysis led to a hazard distance. The maximum hazard distance within each group was selected to determine a table of separation distances based on internal pressure and pipe size rather than storage volume similar to the bulk gaseous separation distance tables in NFPA 2. The new separation distances are compared to the previous distances and some implications of the updated distances are given.
Social Risk Approach for Assessing Public Safety of Large-scale Hydrogen Systems
Sep 2023
Publication
Social risk is a comprehensive concept that considers not only internal/external physical risks but also risks (which are multiple varied and diverse) associated with social activity. It should be considered from diverse perspectives and requires a comprehensive evaluation framework that takes into account the synergistic impact of each element on others rather than evaluating each risk individually. Social risk assessment is an approach that is not limited to internal system risk from an engineering perspective but also considers the stakeholders development stage and societal readiness and resilience to change. This study aimed to introduce a social risk approach to assess the public safety of large-scale hydrogen systems. Guidelines for comprehensive social risk assessment were developed to conduct appropriate risk assessments for advanced science and technology activities with high uncertainties to predict major impacts on society before an accident occurs and to take measures to mitigate the damage and to ensure good governance are in place to facilitate emergency response and recovery in addition to preventive measures. In a case study this approach was applied to a hydrogen refueling station in Japan and risk-based multidisciplinary approaches were introduced. These approaches can be an effective supporting tool for social implementation with respect to large-scale hydrogen systems such as liquefied hydrogen storage tanks. The guidelines for social risk assessment of large-scale hydrogen systems are under the International Energy Agency Technology Collaboration Program Hydrogen Safety Task 43. This study presents potential case studies of social risk assessment for large-scale hydrogen systems for future.
Evaluating Reservoir Suitability for Large-scale Hydrogen Storage: A Preliminary Assesment Considering Reservoir Properties
May 2024
Publication
With rising demand for clean energy global focus turns to finding ideal sites for large-scale underground hydrogen storage (UHS) in depleted petroleum reservoirs. A thorough preliminary reservoir evaluation before hydrogen (H2) injection is crucial for UHS success and safety. Recent criteria for UHS often emphasize economics and chemistry neglecting key reservoir attributes. This study introduces a comprehensive framework for the reservoir-scale preliminary assessment specifically tailored for long-term H2 storage within depleted gas reservoirs. The evaluation criteria encompass critical components including reservoir geometry petrophysical properties tectonics and formation fluids. To illustrate the practical application of this approach we assess the Barnett shale play reservoir parameters. The assessment unfolds through three key stages: (1) A systematic evaluation of the reservoir's properties against our comprehensive screening criteria determines its suitability for H2 storage. (2) Using both homogeneous and multilayered gas reservoir models we explore the feasibility and efficiency of H2 storage. This phase involves an in-depth examination of reservoir behavior during the injection stage. (3) To enhance understanding of UHS performance sensitivity analyses investigate the impact of varying reservoir dimensions and injection/production pressures. The findings reveal the following: (a) Despite potential challenges associated with reservoir compaction and aquifer support the reservoir exhibits substantial promise as an H2 storage site. (b) Notably a pronounced increase in reservoir pressure manifests during the injection stage particularly in homogeneous reservoirs. (c) Furthermore optimizing injection-extraction cycle efficiency can be achieved by augmenting reservoir dimensions while maintaining a consistent thickness. To ensure a smooth transition to implementation further comprehensive investigations are advised including experimental and numerical studies to address injectivity concerns and explore storage site development. This evaluation framework is a valuable tool for assessing the potential of depleted gas reservoirs for large-scale hydrogen storage advancing global eco-friendly energy systems.
Market Dynamics and Power Risks in Green Technology Materials: Platinum under the EU 2030 Hydrogen Target
Jan 2025
Publication
The central role of hydrogen in the EU’s decarbonization strategy has increased the importance of critical raw materials. To address this the EU has taken legislative steps including the 2023 Critical Raw Materials Act (CRMA) to ensure a stable supply. Using a leader–follower Stackelberg game framework this study analyzes CRM market dynamics integrating CRMA compliance through rules on sourcing and stockpiling value chain resilience via the inclusion of supply diversification strategies and geopolitical influences by modeling exporter behaviors and trade dependencies. Results highlight the potential for strategic behavior by major exporters stressing the benefits of diversifying export sources and maintaining strategic stockpiles to stabilize supply. The findings provide insights into the EU’s efforts to secure CRM supplies key to achieving decarbonization goals and fostering a sustainable energy transition. Future research should explore alternative cost-reduction strategies mitigate exporter market power and evaluate the implications for pricing mechanisms market outcomes and consumer welfare
Everything About Hydrogen Podcast: Decarbonizing Shipping
Mar 2024
Publication
On this episode of EAH Patrick Molloy Alicia Eastman and Chris Jackson are delighted to speak with Arsenio Dominguez the newly appointed Secretary General of the International Maritime Organization (IMO). Recorded before the highly successful MEPC81 Arsenio describes his vision for the IMO and his confidence in solutions that will reduce emissions from shipping without penalizing member states.
The podcast can be found on their website.
The podcast can be found on their website.
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