Publications
Modelling Flexibility Requirements in Deep Decarbonisation Scenarios: The Role of Conventional Flexibility and Sector Coupling Options in the European 2050 Energy System
Feb 2024
Publication
Russia’s invasion of Ukraine has reaffirmed the importance of scaling up renewable energy to decarbonise Europe’s economy while rapidly reducing its exposure to foreign fossil fuel suppliers. Therefore the question of sources of flexibility to support a fully decarbonised European energy system is becoming even more critical in light of a renewable-dominated energy system. We developed and used a Pan-European energy system model to systematically assess and quantify sources of flexibility to meet deep decarbonisation targets. The electricity supply sector and electricity-based end-use technologies are crucial in achieving deep decarbonisation. Other low-carbon energy sources like biomethane hydrogen synthetic e-fuels and bioenergy with carbon capture and storage will also play a role. To support a fully decarbonised European energy system by 2050 both temporal and spatial flexibility will be needed. Spatial flexibility achieved through investments in national electricity networks and cross-border interconnections is crucial to support the aggressive roll-out of variable renewable energy sources. Cross-border trade in electricity is expected to increase and in deep decarbonisation scenarios the electricity transmission capacity will be larger than that of natural gas. Hydrogen storage and green hydrogen production will play a key role in providing traditional inter-seasonal flexibility and intraday flexibility will be provided by a combination of electrical energy storage hydrogen-based storage solutions (e.g. liquid H2 and pressurised storage) and hybrid heat pumps. Hydrogen networks and storage will become more critical as we move towards the highest decarbonisation scenario. Still the need for natural gas networks and storage will decrease substantially.
An Artificial Neural Network-Based Fault Diagnostics Approach for Hydrogen-Fueled Micro Gas Turbines
Feb 2024
Publication
The utilization of hydrogen fuel in gas turbines brings significant changes to the thermophysical properties of flue gas including higher specific heat capacities and an enhanced steam content. Therefore hydrogen-fueled gas turbines are susceptible to health degradation in the form of steam-induced corrosion and erosion in the hot gas path. In this context the fault diagnosis of hydrogen-fueled gas turbines becomes indispensable. To the authors’ knowledge there is a scarcity of fault diagnosis studies for retrofitted gas turbines considering hydrogen as a potential fuel. The present study however develops an artificial neural network (ANN)-based fault diagnosis model using the MATLAB environment. Prior to the fault detection isolation and identification modules physics-based performance data of a 100 kW micro gas turbine (MGT) were synthesized using the GasTurb tool. An ANN-based classification algorithm showed a 96.2% classification accuracy for the fault detection and isolation. Moreover the feedforward neural network-based regression algorithm showed quite good training testing and validation accuracies in terms of the root mean square error (RMSE). The study revealed that the presence of hydrogen-induced corrosion faults (both as a single corrosion fault or as simultaneous fouling and corrosion) led to false alarms thereby prompting other incorrect faults during the fault detection and isolation modules. Additionally the performance of the fault identification module for the hydrogen fuel scenario was found to be marginally lower than that of the natural gas case due to assumption of small magnitudes of faults arising from hydrogen-induced corrosion.
Renewable Methanol Synthesis
Oct 2019
Publication
Renewable methanol production is an emerging technology that bridges the gap in the shift from fossil fuel to renewable energy. Two thirds of the global emission of CO2 stems from humanity’s increasing energy need from fossil fuels. Renewable energy mainly from solar and wind energy suffers from supply intermittency which current grid infrastructures cannot accommodate. Excess renewable energy can be harnessed to power the electrolysis of water to produce hydrogen which can be used in the catalytic hydrogenation of waste CO2 to produce renewable methanol. This review considers methanol production in the current context regionally for Europe which is dominated by Germany and globally by China. Appropriate carbon-based feedstock for renewable methanol production is considered as well as state-of-the-art renewable hydrogen production technologies. The economics of renewable methanol production necessitates the consideration of regionally relevant methanol derivatives. The thermodynamics kinetics catalytic reaction mechanism operating conditions and reactor design are reviewed in the context of renewable methanol production to reveal the most up to date understanding.
CFD Thermo‑Hydraulic Evaluation of a Liquid Hydrogen Storage Tank with Different Insulation Thickness in a Small‑Scale Hydrogen Liquefier
Aug 2023
Publication
Accurate evaluation of thermo‑fluid dynamic characteristics in tanks is critically important for designing liquid hydrogen tanks for small‑scale hydrogen liquefiers to minimize heat leakage into the liquid and ullage. Due to the high costs most future liquid hydrogen storage tank designs will have to rely on predictive computational models for minimizing pressurization and heat leakage. Therefore in this study to improve the storage efficiency of a small‑scale hydrogen liquefier a three‑ dimensional CFD model that can predict the boil‑off rate and the thermo‑fluid characteristics due to heat penetration has been developed. The prediction performance and accuracy of the CFD model was validated based on comparisons between its results and previous experimental data and a good agreement was obtained. To evaluate the insulation performance of polyurethane foam with three different insulation thicknesses the pressure changes and thermo‑fluid characteristics in a partially liquid hydrogen tank subject to fixed ambient temperature and wind velocity were investigated nu‑ merically. It was confirmed that the numerical simulation results well describe not only the temporal variations in the thermal gradient due to coupling between the buoyance and convection but also the buoyancy‑driven turbulent flow characteristics inside liquid hydrogen storage tanks with differ‑ ent insulation thicknesses. In the future the numerical model developed in this study will be used for optimizing the insulation systems of storage tanks for small‑scale hydrogen liquefiers which is a cost‑effective and highly efficient approach.
Recent Advances in Combustion Science Related to Hydrogen Safety
Dec 2024
Publication
Hydrogen is a key pillar in the global Net Zero strategy. Rapid scaling up of hydrogen production transport distribution and utilization is expected. This entails that hydrogen which is traditionally an industrial gas will come into proximity of populated urban areas and in some situations handled by the untrained public. To realize all their benefits hydrogen and its technologies must be safely developed and deployed. The specific properties of hydrogen involving wide flammability range low ignition energy and fast flame speed implies that any accidental release of hydrogen can be easily ignited. Comparing with conventional fuels combustion systems fueled by hydrogen are also more prone to flame instability and abnormal combustion. This paper aims to provide a comprehensive review about combustion research related to hydrogen safety. It starts with a brief introduction which includes some overview about risk analysis codes and standards. The core content covers ignition fire explosions and deflagration to detonation transition (DDT). Considering that DDT leads to detonation and that detonation may also be induced directly under special circumstances the subject of detonation is also included for completeness. The review covers laboratory medium and large-scale experiments as well as theoretical analysis and numerical simulation results. While highlights are provided at the end of each section the paper closes with some concluding remarks highlighting the achievements and key knowledge gaps.
Advancing the Affordable and Clean Energy in Large Energy-consuming Economies: The Role of Green Transition, Complexity-based, and Geostrategy Policy
Aug 2023
Publication
With decreasing costs of the clean technologies the balanced scales of the Sustainable Development Goal 7 targets e.g. energy equity (EE) energy security (ES) and environmental sustainability (EVS) are quickly changing. This fundamental balancing process is a key requirement for a net-zero future. Accordingly this research analyzes the regime-switching effect of Hydrogen economy as the green transition sharing economy and economic complexity as the complexity-based and geopolitical risks and energy prices as the geostrategy policies on the Goal 7 targets. To this end a Markov-switching panel vector autoregressive method with regime-heteroskedasticity is applied to study advancing the Goal 7 in the world's twenty-five large energy consumers during 2004–2020. Concerning the parameters and statistics of the model the results refer to the existence of two regimes associated with the Goal 7 corners called “upward and downward” regimes for EE and “slightly upward and sharply upward” regimes for ES and EVS. It is revealed that the vulnerability of EE and ES targets is considerably reduced when the regime switches to the dominant regime that is “downward” and “slightly upward” regimes respectively and that of the EVS target remains unaffected. Through the impulse-response analysis the findings denote that the first hypothesis of the efficiency of the Hydrogen economy in promoting the Goal 7 targets is insignificant. However the significant short-term and dynamic shock effects of the complexity-based and geostrategy policies on the Hydrogen economy are detected which will be a feasible alternative assessment in advancing the Goal 7. Further the complexity-based policies support the Goal 7 targets under different regimes especially in the short- and medium-term. Hence the second hypothesis regarding the effectiveness of the complexity-based policies in promoting Goal 7 targets is confirmed. The third hypothesis concerning the complexity of the impact of geostrategy policies on the Goal 7 targets is verified. Particularly the switching process towards the Goal 7 may not necessarily be restricted by the geopolitical risks. Moreover EE is supported through energy prices in the short-term under both regimes while they are non-conductive to promote ES and EVS through time. Accordingly the decision-makers should acknowledge adopting a regime-switching path forward for ensuring the time-varying balanced growth of the Goal 7 targets as the impact of the suggested policy instruments is asymmetric.
A Renewable Power System for an Off-grid Sustainable Telescope Fueled by Solar Power, Batteries and Green Hydrogen
Jul 2023
Publication
A large portion of astronomy’s carbon footprint stems from fossil fuels supplying the power demand of astronomical observatories. Here we explore various isolated low-carbon power system setups for the newly planned Atacama Large Aperture Submillimeter Telescope and compare them to a business-as-usual diesel power generated system. Technologies included in the designed systems are photovoltaics concentrated solar power diesel generators batteries and hydrogen storage. We adapt the electricity system optimization model highRES to this case study and feed it with the telescope’s projected energy demand cost assumptions for the year 2030 and site-specific capacity factors. Our results show that the lowest-cost system with LCOEs of $116/MWh majorly uses photovoltaics paired with batteries and fuel cells running on imported and on-site produced green hydrogen. Some diesel generators run for backup. This solution would reduce the telescope’s power-side carbon footprint by 95% compared to the businessas-usual case.
19 Import Options for Green Hydrogen and Derivatives - An Overview of Efficiencies and Technology Readiness Levels
Oct 2024
Publication
The import of hydrogen and derivatives forms part of many national strategies and is fundamental to achieving climate protection targets. This paper provides an overview and technical comparison of import pathways for hydrogen and derivatives in terms of efficiency technological maturity and development and construction times with a focus on the period up to 2030. The import of hydrogen via pipeline has the highest system efficiency at 57–67 % and the highest technological maturity with a technology readiness level (TRL) of 8–9. The import of ammonia and methanol via ship and of SNG via pipeline shows efficiencies in the range of 39–64 % and a technological maturity of TRL 7 to 9 when using point sources. Liquid hydrogen LOHC and Fischer-Tropsch products have the lowest efficiency and TRL in comparison. The use of direct air capture (DAC) reduces efficiency and TRL considerably. Reconversion of the derivatives to hydrogen is also associated with high losses and is not achievable for all technologies on an industrial scale up to 2030. In the short to medium term import routes for derivatives that can utilise existing infrastructures and mature technologies are the most promising for imports. In the long term the most promising option is hydrogen via pipelines.
Techno-Economic Potential of Wind-Based Green Hydrogen Production in Djibouti: Literature Review and Case Studies
Aug 2023
Publication
Disputed supply chains inappropriate weather and low investment followed by the Russian invasion of Ukraine has led to a phenomenal energy crisis especially in the Horn of Africa. Accordingly proposing eco-friendly and sustainable solutions to diversify the access of electricity in the Republic of Djibouti which has no conventional energy resources and is completely energy dependent on its neighboring countries has become a must. Therefore the implementation of sustainable renewable and energy storage systems is nationally prioritized. This paper deals for the first time with the exploitation of such an affordable and carbon-free resource to produce hydrogen from wind energy in the rural areas of Nagad and Bara Wein in Djibouti. The production of hydrogen and the relevant CO2 emission reduction using different De Wind D6 Vestas and Nordex wind turbines are displayed while using Alkaline and Proton Exchange Membrane (PEM) electrolyzers. The Bara Wein and Nagad sites had a monthly wind speed above 7 m/s. From the results the Nordex turbine accompanied with the alkaline electrolyzer provides the most affordable electricity production approximately 0.0032 $/kWh for both sites; this cost is about one per hundred the actual imported hydroelectric energy price. Through the ecological analysis the Nordex turbine is the most suitable wind turbine with a CO2 emission reduction of 363.58 tons for Bara Wein compared to 228.76 tons for Nagad. While integrating the initial cost of wind turbine implementation in the capital investment the mass and the levelized cost of the produced green hydrogen are estimated as (29.68 tons and 11.48 $/kg) for Bara Wein with corresponding values of (18.68 tons and 18.25 $/kg) for Nagad.
The Evolution of Green Hydrogen in Renewable Energy Research: Insights from a Bibliometric Perspective
Dec 2024
Publication
Green hydrogen generated from water through renewable energies like solar and wind is a key player in sus tainable energy. It only produces water when used making it a clean energy source. However the inconsistent nature of solar and wind energy highlights the need for storage solutions where green hydrogen is promising. This study uniquely combines green hydrogen (GH) and renewable energy (RE) domains using a comprehensive bibliometric approach covering 2018–2022. It identifies emerging trends collaboration networks and key contributors that shape the global landscape of GH research. Our findings show a significant yearly growth in this research field averaging 93.56 %. The study also identifies China Germany India and Italy as leaders among 76 countries involved in this area. Research trends have shifted from technical details to social and economic factors. Given the increasing global commitment to achieving carbon neutrality understanding the evolution and integration of GH within RE systems is essential for guiding future research policy-making and technology development. The analysis categorizes the research into seven main themes focusing on green hydrogen’s role in energy transition and storage. Other vital topics include improving hydrogen production methods assessing its climate impact examining its environmental benefits and exploring various production techniques like water electrolysis and photocatalysis. Our analysis reveals a 93.56 % annual growth rate in GH research highlighting key challenges in storage integration and policy development and offering a roadmap for future studies. The study highlights areas needing more exploration such as better storage methods integration with existing energy infrastructures risk management and policy development. The advancement of green hydrogen as a sustainable energy solution depends on innovative research international collaboration and supportive policy frameworks.
Sixteen Percent Solar-to-Hydrogen Efficiency Using a Power-Matched Alkaline Electrolyzer and a High Concentrated Solar Cell: Effect of Operating Parameters
Apr 2020
Publication
The effect of electrode area electrolyte concentration temperature andlight intensity (up to 218 sun) on PV electrolysis of water is studied using a highconcentrated triple-junction (3-J) photovoltaic cell (PV) connected directly to analkaline membrane electrolyzer (EC). For a given current the voltage requirement torun an electrolyzer increases with a decrease in electrode sizes (4.5 2.0 0.5 and 0.25cm2) due to high current densities. The high current density operation leads to highOhmic losses most probably due to the concentration gradient and bubble formation.The EC operating parameters including the electrolyte concentration and temperaturereduce the voltage requirement by improving the thermodynamics kinetics andtransport properties of the overall electrolysis process. For a direct PV−EC coupling themaximum power point of PV (Pmax) is matched using EC I−V (current−voltage) curvesmeasured for different electrode sizes. A shift in the EC I−V curves toward open-circuitvoltage (Voc) reduces the Pop (operating power) to hydrogen efficiencies due to theincreased voltage losses above the equilibrium water-splitting potential. The solar-to-hydrogen (STH) efficiencies remainedcomparable (∼16%) for all electrode sizes when the operating current (Iop) was similar to the short-circuit current (Isc ) irrespectiveof the operating voltage (Vop) electrolyzer temperature and electrolyte concentration.
Solar-driven (Photo)electrochemical Devices for Green Hydrogen Production and Storage: Working Principles and Design
Feb 2024
Publication
The large-scale deployment of technologies that enable energy from renewables is essential for a successful transition to a carbon-neutral future. While photovoltaic panels are one of the main technologies commonly used for harvesting energy from the Sun storage of renewable solar energy still presents some challenges and often requires integration with additional devices. It is believed that hydrogen – being a perfect energy carrier – can become one of the broadly utilised storage alternatives that would effectively mitigate the energy supply and demand issues associated with the intermittent nature of renewable energy sources. Current pathways in the development of green technologies indicate the need for more sustainable material utilisation and more efficient device operation. To address this requirement integration of various technologies for renewable energy harvesting conversion and storage in a single device appears as an advantageous option. From the hydrogen economy perspective systems driven by green solar electricity that allow for (photo)electrochemical water splitting would generate hydrogen with the minimal CO2 footprint. If at the same time one of the device electrodes could store the generated gas and release it on demand the utilisation of critical and often costly elements would be reduced with possible gain in more effective device operation. Although conceptually attractive this cross-disciplinary concept has not gained yet enough attention and only limited number of experimental setups have been designed tested and reported. This review presents the first exhaustive overview and critical examination of various laboratory-scale prototype setups that attempt to combine both the hydrogen production and storage processes in a single unit via integration of a metal hydride-based electrode into a photoelectrochemical cell. The architectures of presented configurations enables direct solar energy to hydrogen conversion and its subsequent storage in a single device which – in some cases – can also release the stored (hydrogen) energy on demand. In addition this work explores perspectives and challenges related with the potential upscaling of reviewed solar-to-hydrogen storage systems trying to map and indicate the main future directions of their technological development and optimization. Finally the review also combines information and expertise scattered among various research fields with the aim of stimulating much-needed exchange of knowledge to accelerate the progress in the development and deployment of optimum green hydrogen-based solutions.
Techno-economic Assessments of Electrolyzers for Hydrogen Production
Jul 2025
Publication
This review provides a comprehensive techno-economic assessment of four leading electrolyzer technologies such as the Alkaline Water Electrolyzers (AWE) Proton Exchange Membrane (PEM) electrolyzers Solid Oxide Electrolyzer Cells (SOEC) and Anion Exchange Membrane (AEM) systems for green hydrogen production. Drawing on more than 40 peer-reviewed studies and real-world deployment scenarios the analysis compares performance indicators such as levelised cost of hydrogen (LCOH) capital expenditure (CAPEX) operating expenditure (OPEX) efficiency stack durability and water treatment requirements. AWE is identified as the most cost-effective option for baseload power contexts while PEM offers superior dynamic response and gas purity at a higher cost. SOECs despite their high theoretical efficiency remain limited by thermal cycling and material degradation. AEMs though less mature hold promise for low-cost decentralized hydrogen production. Cost of electricity is more than 64 % of LCOH in all technologies so it is important to match electrolyzers with stable or hybrid renewable energy resources such as geothermal wind-solar or Concentrated Solar Power (CSP). Optimisation methods such as genetic algorithms and GIS-based siting also enhance system performance and economic value. The report also considers regional and policy dimensions of deployment underlining the need for site-specific solutions in the context of local energy portfolios water supply and infrastructure readiness. Recommendations are provided for advancing membrane longevity integrating smart control systems and optimizing techno-economic assessment models. This study is a policy decision-making tool for policymakers investors and researchers who are interested in accelerating the global scale-up of green hydrogen using contextrelevant and economically viable electrolyzer technologies.
Performance Assessment and Optimization of the Ultra-High Speed Air Compressor in Hydrogen Fuel Cell Vehicles
Feb 2024
Publication
Air compressors in hydrogen fuel cell vehicles play a crucial role in ensuring the stability of the cathode air system. However they currently face challenges related to low efficiency and poor stability. To address these issues the experimental setup for the pneumatic performance of air compressors is established. The effects of operational parameters on energy consumption efficiency and mass flow rate of the air compressor are revealed based on a Morris global sensitivity analysis. Considering a higher flow rate larger efficiency and lower energy consumption simultaneously the optimal operating combination of the air compressor is determined based on grey relational multi-objective optimization. The optimal combination of operational parameters consisted of a speed of 80000 rpm a pressure ratio of 1.8 and an inlet temperature of 18.3 °C. Compared to the average values the isentropic efficiency achieved a 48.23% increase and the mass flow rate rose by 78.88% under the optimal operational combination. These findings hold significant value in guiding the efficient and stable operation of air compressors. The comprehensive methodology employed in this study is applicable further to investigate air compressors for hydrogen fuel cell vehicles.
Optimisation of Size and Control Strategy in Utility-scale of Green Hydrogen Production Systems
Aug 2023
Publication
The optimisation of green hydrogen production systems is challenging. Moreover an accurate simulation of the system is required for effective optimisation. This study presents a novel method for optimising utility-scale hybrid photovoltaice-wind systems for hydrogen production using accurate simulation models. The optimisation objective is to minimise the levelised cost of hydrogen (LCOH) using genetic algorithms. Different types of systems (such as islanded systems grid-connected systems with or without the possibility of purchasing electricity from the grid and grid-connected systems considering power curtailment) are evaluated and optimised. Each combination of components and control strategy is simulated during the system lifetime (20 yrs) in time steps of 5 min considering the degradation of renewable generators during the system lifetime and different real-time pricing curves and renewable resource curves for each year of the system lifetime. Accurate models are used in the simulations including electrolyser efficiency dependent on the input power and cold-start extra ageing. An application example located in Zaragoza (Spain) is shown obtaining LCOH from 4.74 to 16.06 V/kg depending on the type of project and electrolyser.
The Necessity and Feasibility of Hydrogen Storage for Large-Scale, Long-Term Energy Storage in the New Power System in China
Jun 2023
Publication
In the process of building a new power system with new energy sources as the mainstay wind power and photovoltaic energy enter the multiplication stage with randomness and uncertainty and the foundation and support role of large-scale long-time energy storage is highlighted. Considering the advantages of hydrogen energy storage in large-scale cross-seasonal and cross-regional aspects the necessity feasibility and economy of hydrogen energy participation in long-time energy storage under the new power system are discussed. Firstly power supply and demand production simulations were carried out based on the characteristics of new energy generation in China. When the penetration of new energy sources in the new power system reaches 45% long-term energy storage becomes an essential regulation tool. Secondly by comparing the storage duration storage scale and application scenarios of various energy storage technologies it was determined that hydrogen storage is the most preferable choice to participate in large-scale and long-term energy storage. Three long-time hydrogen storage methods are screened out from numerous hydrogen storage technologies including salt-cavern hydrogen storage natural gas blending and solid-state hydrogen storage. Finally by analyzing the development status and economy of the above three types of hydrogen storage technologies and based on the geographical characteristics and resource endowment of China it is pointed out that China will form a hydrogen storage system of “solid state hydrogen storage above ground and salt cavern storage underground” in the future.
Energy Management in a Super-Tanker Powered by Solar, Wind, Hydrogen and Boil-Off Gas for Saving CO2 Emissions
Apr 2024
Publication
In terms of energy generation and consumption ships are autonomous isolated systems with power demands varying according to the type of ship: passenger or commercial. The power supply in modern ships is based on thermal engines-generators which use fossil fuels marine diesel oil (MDO) and liquefied natural gas (LNG). The continuous operation of thermal engines on ships during cruises results in increased emissions of polluting gases mainly CO/CO2 . The combination of renewable energy sources (REs) and triple-fuel diesel engines (TFDEs) can reduce CO/CO2 emissions resulting in a “greener” interaction between ships and the ecosystem. This work presents a new control method for balancing the power generation and the load demands of a ship equipped with TFDEs fuel cells (FCs) and REs based on a real and accurate model of a super-tanker and simulation of its operation in real cruise conditions. The new TFDE technology engines are capable of using different fuels (marine diesel oil heavy fuel oil and liquified natural gas) producing the power required for ship operation as well as using compositions of other fuels based on diesel aiming to reduce the polluting gases produced. The energy management system (EMS) of a ship is designed and implemented in the structure of a finite state machine (FSM) using the logical design of transitions from state to state. The results demonstrate that further reductions in fossil fuel consumption as well as CO2 emissions are possible if ship power generation is combined with FC units that consume hydrogen as fuel. The hydrogen is produced locally on the ship through electrolysis using the electric power generated by the on-board renewable energy sources (REs) using photovoltaic systems (PVs) and wind energy conversion turbines (WECs).
Advantages and Technological Progress of Hydrogen Fuel Cell Vehicles
Jun 2023
Publication
The automotive industry is undergoing a profound transformation driven by the need for sustainable and environmentally friendly transportation solutions [1]. In this context fuel cell technology has emerged as a promising alternative offering clean efficient and high-performance power sources for vehicles [2]. Fuel cell vehicles are electric vehicles that use fuel cell systems as a single power source or as a hybrid power source in combination with rechargeable energy storage systems. A typical fuel cell system for electric vehicle is exhibited in Figure 1 which provides a comprehensive demonstration of this kind of complex system. Hydrogen energy is a crucial field in the new energy revolution and will become a key pillar in building a green efficient and secure new energy system. As a critical field for hydrogen utilization fuel cell vehicles will play an important role in the transformation and development of the automotive industry. The development of fuel cell vehicles offers numerous advantages such as strong power outputs safety reliability and economic energy savings [3]. However improvements must urgently be made in existing technologies such as fuel cell stacks (including proton exchange membranes catalysts gas diffusion layers and bipolar plates) compressors and onboard hydrogen storage systems [4]. The advantages and current technological status are analyzed here.
Sustainable Vehicles for Decarbonizing the Transport Sector: A Comparison of Biofuel, Electric, Fuel Cell and Solar-powered Vehicles
Mar 2024
Publication
Climate change necessitates urgent action to decarbonize the transport sector. Sustainable vehicles represent crucial alternatives to traditional combustion engines. This study comprehensively compares four prominent sustainable vehicle technologies: biofuel-powered vehicles (BPVs) fuel cell vehicles (FCVs) electric vehicles (EVs) and solar vehicles. We examine each technology’s history development classification key components and operational principles. Furthermore we assess their sustainability through technical factors environmental impacts cost considerations and policy dimensions. Moreover the discussion section addresses the challenges and opportunities associated with each technology and assesses their social impact including public perception and adoption. Each technology offers promise for sustainable transportation but faces unique challenges. Policymakers industry stakeholders and researchers must collaborate to address these challenges and accelerate the transition toward a decarbonized transport future. Potential future research areas are identified to guide advancements in sustainable vehicle technologies.
Modern Hydrogen Technologies in the Face of Climate Change—Analysis of Strategy and Development in Polish Conditions
Aug 2023
Publication
The energy production market based on hydrogen technologies is an innovative solution that will allow the industry to achieve climate neutrality in the future in Poland and in the world. The paper presents the idea of using hydrogen as a modern energy carrier and devices that in cooperation with renewable energy sources produce the so-called green hydrogen and the applicable legal acts that allow for the implementation of the new technology were analyzed. Energy transformation is inevitable and according to reports on good practices in European Union countries hydrogen and the hydrogen value chain (production transport and transmission storage use in transport and energy) have wide potential. Thanks to joint projects and subsidies from the EU initiatives supporting hydrogen technologies are created such as hydrogen clusters and hydrogen valleys and EU and national strategic programs set the main goals. Poland is one of the leaders in hydrogen production both in the world and in Europe. Domestic tycoons from the energy refining and chemical industries are involved in the projects. Eight hydrogen valleys that have recently been created in Poland successfully implement the assumptions of the “Polish Hydrogen Strategy until 2030 with a perspective until 2040” and “Energy Policy of Poland until 2040” which are in line with the assumptions of the most important legal acts of the EU including the European Union’s energy and climate policy the Green Deal and the Fit for 55 Package. The review of the analysis of the development of hydrogen technologies in Poland shows that Poland does not differ from other European countries. As part of the assumptions of the European Hydrogen Strategy and the trend related to the management of energy surpluses electrolyzers with a capacity of at least 6 GW will be installed in Poland in 2020–2024. It is also assumed that in the next phase planned for 2025–2030 hydrogen will be a carrier in the energy system in Poland. Poland as a member of the EU is the creator of documents that take into account the assumptions of the European Union Commission and systematically implement the assumed goals. The strategy of activities supporting the development of hydrogen technologies in Poland and the value chain includes very extensive activities related to among others obtaining hydrogen using hydrogen in transport energy and industry developing human resources for the new economy supporting the activities of hydrogen valley stakeholders building hydrogen refueling stations and cooperation among Poland Slovakia and the Czech Republic as part of the HydrogenEagle project.
Evaluation of the Technical Condition of Pipes during the Transportation of Hydrogen Mixtures According to the Energy Approach
Jun 2024
Publication
In this study a theoretical–experimental methodology for determining the stress–strain state in pipeline systems taking into account the hydrogen environment was developed. A complex of theoretical and experimental studies was conducted to determine the specific energy of destruction as an invariant characteristic of the material’s resistance to strain at different hydrogen concentrations. The technique is based on the construction of complete diagrams of the destruction of the material based on the determination of true strains and stresses in the local volume using the method involving the optical–digital correlation of speckle images. A complex of research was carried out and true diagrams of material destruction were constructed depending on the previous elastic–plastic strain and the action of the hydrogen environment. The change in the concentration of hydrogen absorbed by the material was estimated depending on the value of the specific energy of destruction. A study was conducted on tubular samples and the degree of damage to the material of the inner wall under the action of hydrogen and stress from the internal pressure was evaluated according to the change in specific energy depending on the value of the true strain established with the help of an optical–digital correlator on the outer surface and the degree of damage was determined. It has been established that the specific fracture energy of 17G1S steel decreases by 70–90% under the influence of hydrogen. The effect of the change in the amount of strain energy on the thickness of the pipe wall is illustrated.
Transitioning towards Net-Zero Emissions in Chemical and Process Industries: A Holistic Perspective
Sep 2023
Publication
Given the urgency to combat climate change and ensure environmental sustainability this review examines the transition to net-zero emissions in chemical and process industries. It addresses the core areas of carbon emissions reduction efficient energy use and sustainable practices. What is new however is that it focuses on cutting-edge technologies such as biomass utilization biotechnology applications and waste management strategies that are key drivers of this transition. In particular the study addresses the unique challenges faced by industries such as cement manufacturing and highlights the need for innovative solutions to effectively reduce their carbon footprint. In particular the role of hydrogen as a clean fuel is at the heart of revolutionizing the chemical and process sectors pointing the way to cleaner and greener operations. In addition the manuscript explores the immense importance of the European Green Deal and the Sustainable Development Goals (SDGs) for the chemical industry. These initiatives provide a clear roadmap and framework for advancing sustainability driving innovation and reducing the industry’s environmental impact and are a notable contribution to the existing body of knowledge. Ultimately alignment with the European Green Deal and the SDGs can bring numerous benefits to the chemical industry increasing its competitiveness promoting societal well-being and supporting cross-sector collaboration to achieve shared sustainability goals. By highlighting the novelty of integrating cutting-edge technologies addressing unique industrial challenges and positioning global initiatives this report offers valuable insights to guide the chemical and process industries on their transformative path to a sustainable future.
Correlations between Component Size Green Hydrogen Demand and Breakeven Price for Energy Islands
Jun 2023
Publication
The topic of energy islands is currently a focal point in the push for the energy transition. An ambitious project in the North Sea aims to build an offshore wind-powered electrolyser for green hydrogen production. Power-to-X (PtX) is a process of converting renewable electricity into hydrogen-based energy carriers such as natural gas liquid fuels and chemicals. PtH2 represents a subset of PtX wherein hydrogen is the resultant green energy from the conversion process. Many uncertainties surround PtH2 plants affecting the economic success of the investment and making the price of hydrogen and the levelized cost of hydrogen (LCOH) of this technology uncompetitive. Several studies have analysed PtH2 layouts to identify the hydrogen price without considering how component capacities and external inputs affect the breakeven price. Unlike previous works this paper investigates component capacity dependencies under variables such as wind and hydrogen demand shape for dedicated/non-dedicated system layouts. To this end the techno-economic analysis finds the breakeven price optimising the components to reach the lowest selling price. Results show that the hydrogen price can reach 2.2 €/kg for a non-dedicated system for certain combinations of maximum demand and electrolyser capacity. Furthermore the LCOH analysis revealed that the offshore wind electrolyser system is currently uncompetitive with hydrogen production from carbon-based technologies but is competitive with renewable technologies. The sensitivity analysis reveals the green electricity price in the non-dedicated case for which a dedicated system has a lower optimum hydrogen price. The price limit for the dedicated case is 116 €/MWh.
Study on Hydrogen Substitution in a Compressed Natural Gas Spark-ignition Passenger Car Engine
Jun 2023
Publication
Hydrogen substitution in applications fueled by compressed natural gas arises as a potential alternative to fossil fuels and it may be the key to an effective hydrogen economy transition. The reduction of greenhouse gas emissions especially carbon dioxide and unburned methane as hydrogen is used in transport and industry applications makes its use an attractive option for a sustainable future. The purpose of this research is to examine the gradual adoption of hydrogen as a fuel for light-duty transportation. Particularly the study focuses on evaluating the performance and emissions of a single-cylinder port fuel injection spark-ignition engine as hydrogen is progressively increased in the natural gas-based fuel blend. Results identify the optimal conditions for air dilution and engine operation parameters to achieve the best performance. They corroborate that the dilution rate has to be adjusted to control pollutant emissions as the percentage of hydrogen is increased. Moreover the study identifies the threshold for hydrogen substitution below which the reduction of carbon dioxide emissions due to efficiency gains is negligible compared to the reduction of the carbon content in the fuel blend. These findings will help reduce the environmental footprint of light-duty transportation not only in the long term but also in the short and medium terms.
Economic Analysis of a Photovoltaic Hydrogen Refueling Station Based on Hydrogen Load
Sep 2023
Publication
With the goal of achieving “carbon peak in 2030 and carbon neutrality in 2060” as clearly proposed by China the transportation sector will face long–term pressure on carbon emissions and the application of hydrogen fuel cell vehicles will usher in a rapid growth period. However true “zero carbon” emissions cannot be separated from “green hydrogen”. Therefore it is of practical significance to explore the feasibility of renewable energy hydrogen production in the context of hydrogen refueling stations especially photovoltaic hydrogen production which is applied to hydrogen refueling stations (hereinafter referred to “photovoltaic hydrogen refueling stations”). This paper takes a hydrogen refueling station in Shanghai with a supply capacity of 500 kg/day as the research object. Based on a characteristic analysis of the hydrogen demand of the hydrogen refueling station throughout the day this paper studies and analyzes the system configuration operation strategy environmental effects and economics of the photovoltaic hydrogen refueling station. It is estimated that when the hydrogen price is no less than 6.23 USD the photovoltaic hydrogen refueling station has good economic benefits. Additionally compared with the conventional hydrogen refueling station it can reduce carbon emissions by approximately 1237.28 tons per year with good environmental benefits.
Underground Hydrogen Storage: A UK Perspective
Oct 2023
Publication
Hydrogen is anticipated to play a key role in global decarbonization and within the UK’s pathway to achieving net zero targets. However as the production of hydrogen expands in line with government strategies a key concern is where this hydrogen will be stored for later use. This study assesses the different large-scale storage options in geological structures available to the UK and addresses the surrounding uncertainties moving towards establishing a hydrogen economy. Currently salt caverns look to be the most favourable option considering their proven experience in the storage of hydrogen especially high purity hydrogen natural sealing properties low cushion gas requirement and high charge and discharge rates. However their geographical availability within the UK can act as a major constraint. Additionally a substantial increase in the number of new caverns will be necessary to meet the UK’s storage demand. Salt caverns have greater applicability as a good short-term storage solution however storage in porous media such as depleted hydrocarbon reservoirs and saline aquifers can be seen as a long-term and strategic solution to meet energy demand and achieve energy security. Porous media storage solutions are estimated to have capacities which far exceed projected storage demand. Depleted fields have generally been well explored prior to hydrocarbon extraction. Although many saline aquifers are available offshore UK geological characterizations are still required to identify the right candidates for hydrogen storage. Currently the advantages of depleted gas reservoirs over saline aquifers make them the favoured option after salt caverns.
Advances in Hydrogen-Powered Trains: A Brief Report
Sep 2023
Publication
The majority of rail vehicles worldwide use diesel as a primary fuel source. Diesel engine carbon emissions harm the environment and human health. Although railway electrification can reduce emissions it is not always the most economical option especially on routes with low vehicle demand. As a result interest in hydrogen-powered trains as a way to reduce greenhouse gas (GHG) emissions has steadily grown in recent years. In this paper we discuss advancements made in hydrogen-powered freight and commuter trains as well as the technology used in some aspects of hydrogen-powered vehicles. It was observed that hydrogen-powered trains are already in use in Europe and Asia unlike most developing countries in Africa. Commuter trains have received most of the research and development (R&D) attention but interest in hydrogen-powered freight trains has recently picked up momentum. Despite the availability and use of gray and blue hydrogen green hydrogen is still the preferred fuel for decarbonizing the rail transport sector.
Collective Hydrogen Stand-alone Renewable Energy Systems for Buildings in Spain. Towards the Self-sufficiency
May 2024
Publication
The article examines the feasibility of implementing standalone hydrogen-based renewable energy systems in Spanish residential buildings specifically analyzing the optimization of a solar-battery and solar-hydrogen system for a building with 20 dwellings in Spain. The study initially assesses two standalone setups: solarbattery and solar-hydrogen. Subsequently it explores scenarios where these systems are connected to the grid to only generate and sell surplus energy. A scenario involving grid connection for self-consumption without storage serves as a benchmark for comparison. All system optimizations are designed to meet energy demands without interruptions while minimizing costs as determined by a techno-economic analysis. The systems are sized using custom software that incorporates an energy management system and employs the Jaya algorithm for optimization. The findings indicate that selling surplus energy can be economically competitive and enhance the efficiency of grid-connected self-consumption systems representing the study’s main innovation. The conclusion highlights the economic and technical potential of an autonomous hybrid energy system that includes hydrogen with the significant remaining challenge being the development of a regulatory framework to support its technical feasibility in Spain.
Composition Tracking of Natural Gas-Hydrogen Mixtures in Pipeline Flow Using High-resolution Schemes
Jul 2024
Publication
A transient pipeline flow model with gas composition tracking is solved for studying the operation of a natural gas pipeline under nonisothermal flow conditions in a hydrogen injection scenario. Two approaches to high-resolution pipeline flow modeling based on the WENO scheme are presented and compared with the implicit finite difference method. The high-resolution models are capable of capturing fast fluid transients and tracking the step changes in the composition of the transported mixture. The implicit method assumes the decoupling of the flow model components in order to enhance calculation efficiency. The validation of the composition tracking results against actual gas transmission pipeline indicates that both models exhibit good prediction performance with normalized root mean square errors of 0.406% and 1.48% respectively. Under nonisothermal flow conditions the prediction response of the reduced model against a high-resolution flow model with respect to the mass and energy linepack is at most 3.20%.
3D CFD Simulation of a Gaseous Fuel Injection in a Hydrogen-fueled Internal Combustion Engine
Oct 2021
Publication
Nowadays one of the hottest topic in the automotive engineering community is the reduction of fossil fuels. Hydrogen is an alternative energy source that is already providing clean renewable and efficient power being used in fuel cells. Despite being developed since a few decades fuel cells are affected by several hurdles the most impacting one being their cost per unit power. While waiting for their cost reduction and mass-market penetration hydrogen-fueled internal combustion engines (H2ICEs) can be a rapidly applicable solution to reduce pollution caused by the combustion of fossil fuels. Such engines benefit from the advanced technology of modern internal combustion engines (ICEs) and the advantages related to hydrogen combustion although some modifications are needed for conventional liquid-fueled engines to run on hydrogen. The gaseous injection of hydrogen directly into the combustion chamber is a challenge both for the designers and for the injection system suppliers. To reduce uncertainties time and development cost computational fluid dynamics (CFD) tools appear extremely useful since they can accurately predict mixture formation and combustion before the expensive production/testing phase. The high-pressure gaseous injection which takes place in Direct-Injected H2ICEs promotes a super-sonic flow with very high gradients in the zone between the bulk of the injected hydrogen and the flow already inside the combustion chamber. To develop a methodology for an accurate simulation of these phenomena the SoPHy Engine of the Engine Combustion Network group (ECN) is used and presented. This engine is fed through a single nozzle H2-injector; planar laser-induced fluorescence (PLIF) data are available for comparison with the CFD outcomes.
Engineering Models for Refueling Protocol Development: Validation and Recommendations
Sep 2023
Publication
Fouad Ammouri,
Nicola Benvenuti,
Elena Vyazmina,
Vincent Ren,
Guillaume Lodier,
Quentin Nouvelot,
Thomas Guewouo,
Dorine Crouslé,
Rony Tawk,
Nicholas Hart,
Steve Mathison,
Taichi Kuroki,
Spencer Quong,
Antonio Ruiz,
Alexander Grab,
Alexander Kvasnicka,
Benoit Poulet,
Christopher Kutz and
Martin Zerta
The PRHYDE project (PRotocol for heavy duty HYDrogEn refueling) funded by the Clean Hydrogen partnership aims at developing recommendations for heavy-duty refueling protocols used for future standardization activities for trucks and other heavy duty transport systems applying hydrogen technologies. Development of a protocol requires a validated approach. Due to the limited time and budget the experimental data cannot cover the whole possible ranges of protocol parameters such as initial vehicle pressure and temperature ambient and precooling temperatures pressure ramp refueling time hardware specifications etc. Hence a validated numerical tool is essential for a safe and efficient protocol development. For this purpose engineering tools are used. They give good results in a very reasonable computation time of several seconds or minutes. These tools provide the heat parameters estimation in the gas (volume average temperature) and 1D temperature distribution in the tank wall. The following models were used SOFIL (Air Liquide tool) HyFill (by ENGIE) and H2Fills (open access code by NREL). The comparison of modelling results and experimental data demonstrated a good capability of codes to predict the evolution of average gas temperature in function of time. Some recommendations on model validation for the future protocol development are given.
An Overview on the Technologies Used to Storage Hydrogen
Aug 2023
Publication
Hydrogen energy has a significant potential in mitigating the intermittency of renewable energy generation by converting the excess of renewable energy into hydrogen through many technologies. Also hydrogen is expected to be used as an energy carrier that contribute to the global decarbonization in transportation industrial and building sectors. Many technologies have been developed to store hydrogen energy. Hydrogen can be stored to be used when needed and thus synchronize generation and consumption. The current paper presents a review on the different technologies used to store hydrogen. The storage capacity advantages drawbacks and development stages of various hydrogen storage technologies were presented and compared.
Off-grid Wind/Hydrogen Systems with Multi-electrolyzers: Optimized Operational Strategies
Sep 2023
Publication
Optimized operation of wind/hydrogen systems can increase the system efficiency and further reduce the hydrogen production cost. In this regard extensive research has been done but there is a lack of detailed electrolyzer models and effective management of multiple electrolyzers considering their physical restrictions. This work proposes electrolyzer models that integrate the efficiency variation caused by load level change start–stop cycle (including hot and cold start) thermal management and degradation caused by frequent starts. Based on the proposed models three operational strategies are considered in this paper: two traditionally utilized methods simple start–stop and cycle rotation strategies and a newly proposed rolling optimizationbased strategy. The results from daily operation show that the new strategy results in a more balanced load level among the electrolyzers and a more stable temperature. Besides from a yearly operation perspective it is found that the proposed rolling optimization method results in more hydrogen production higher system efficiency and lower LCOH. The new method leads to hydrogen production of 311297 kg compared to 289278 kg and 303758 kg for simple start–stop and cycle rotation methods. Correspondingly the system efficiencies for the new simple start–stop and cycle rotation methods are 0.613 0.572 and 0.587. The resulting LCOH from the new method is 3.89 e/kg decreasing by 0.35 e/kg and 0.21 e/kg compared to the simple start–stop and cycle rotation methods. Finally the proposed model is compared with two conventional models to show its effectiveness in revealing more operational details and reliable results.
Re-enacting the Hydrogen Tank Explosion of a Fuel-cell Electric Vehicle: An Experimental Study
May 2023
Publication
With the world-wide decision to reduce carbon emissions through the Paris Agreement (2015) the demand for hydrogen-fuelled vehicles has been increasing. Although hydrogen is not a toxic gas it has a wide flammable range (4e75%) and can explode due to static electricity. Therefore studies on hydrogen safety are urgently required. In this study an explosion was induced by applying fire to the lower part of a fuel cell electric vehicle (FCEV). Out of three compressed hydrogen storage tanks installed in the vehicle two did not have hydrogen fuel and one was filled with compressed gaseous hydrogen of 700 bar and forcedly deactivated its temperature-activated pressure relief device. The side-on overpressure transducers were installed by distance in main directions to measure the side-on overpressure generated by the vehicle explosion. A 10 m-long protective barrier was installed on which reflected overpressure displacement and acceleration were measured to examine the effect of attenuation of explosion damage in the event of an accident. The vehicle exploded approximately 11 min after ignition generating a blast wave fireballs and fragments. The results of the experiment showed that the protective barrier could almost completely block explosive pressure smoke and scattering generated during an explosion. Through Probit function analysis the probabilities of an accident occurring were derived based on peak overpressure peak impulse and scattering. The results of this study can be used to develop standard operating procedures (SOPs) for firefighters as the base data for setting the initial operation location and deriving the safe separation distance.
Thermal Design and Heat Transfer Optimisation of a Liquid Organic Hydrogen Carrier Batch Reactor for Hydrogen Storage
Aug 2023
Publication
Liquid organic hydrogen carriers (LOHCs) are considered a promising hydrogen storage technology. Heat must be exchanged with an external medium such as a heat transfer fluid for the required chemical reactions to occur. Batch reactors are simple but useful solutions for small-scale storage applications which can be modelled with a lumped parameter approach adequately reproducing their dynamic performance. For such reactors power is consumed to circulate the external heat transfer fluid and stir the organic liquid inside the reactor and heat transfer performance and power consumption are two key parameters in reactor optimisation. Therefore with reference to the hydrogen release phase this paper describes a procedure to optimise the reactor thermal design based on a lumped-parameter model in terms of heat transfer performance and minimum power consumption. Two batch reactors are analysed: a conventional jacketed reactor with agitation nozzles and a half-pipe coil reactor. Heat transfer performance is evaluated by introducing a newly defined dimensionless parameter the Heat Transfer Ratio (HTR) whose value directly correlates to the heat rate required by the carrier's dehydrogenation reaction. The resulting model is a valid tool for adequately reproducing the hydrogen storage behaviour within dynamic models of complex and detailed energy systems.
Study on the Inherent Safety of On-board Methanol Reforming Hydrogen Production Fuel Cell System
Sep 2023
Publication
Methanol as a liquid phase hydrogen storage carrier has broad prospects. Although the on-board methanol reforming hydrogen fuel cell system (MRFC) has long been proposed to replace the traditional hydrogen fuel cell vehicle the inherent safety of the system itself has rarely been studied. This paper adopted the improved method of Inherently Safer Process Piping (ISPP) to evaluate the pipeline inherent safety of MRFC. The process data such as temperature pressure viscosity and density were obtained by simulating the MRFC in ASPEN HYSYS. The Process Stream Characteristic Index (PSCI) and risk assessment of jet fire and vapor cloud explosion was carried out for the key streams with those simulated data. The results showed the risk ranks of different pipelines in the MRFC and the countermeasures were given according to different risk ranks. Through the in-depth study of the evaluation results this paper demonstrates the risk degree of the system in more detail and reduces the fuzziness of risk rating. By applying ISPP to the small integrated system of MRFC this paper realizes the leap of inherent safety assessment method in the object and provides a reference for the inherent safety assessment of relevant objects in the future.
LES of Turbulent Under-expanded Hydrogen Jet Flames
Sep 2023
Publication
In the frame of hydrogen-powered aircraft Airbus wants to understand all the H2 physics and explore every scenario in order to develop and manufacture safe products operated in a safe environment. Within the framework of a Large Eddy Simulation (LES) methodology for modeling turbulence a comparative numerical study of free under-expanded jet H2/AIR flame is conducted. The investigated geometry consists of straight nozzles with a millimetric diameter fed with pure H2 at upstream pressures ranging from 2 to 10 bar. Numerical results are compared with available experimental measurements such as; temperature signals using thermocouples. LES confirms its prediction capability in terms of shock jet structure and flame length. A particular attention is paid for capturing experimental unstable flame when upstream pressure decreases. Furthermore flame stabilization and flame anchoring are analyzed. Mechanisms of flame stabilization are highlighted for case 1 and stabilization criteria are tested. Finally an ignition map to reach flame stabilization is proposed for each case regarding the literature.
Investigation on Implementing Hydrogen Technology in Residential Sector
Jul 2024
Publication
Rapid urbanization and globalization are causing a rise in the energy demand within the residential sector. Currently majority of the energy demand for the residential sector being supplied from fossil fuels these sources account for greenhouse gas emissions responsible for anthropogenic-driven climate change. About 85 % of the world’s energy demands are being met by non-renewable sources of energy. An immediate need to shift towards renewable energy sources to generate electricity is the need of the hour. These long-standing renewable energy sources including solar hydropower and wind energy have been crucial pillars of sustainable energy for years. However as their implementation has matured we are increasingly recognizing their limitations. Issues such as the scarcity of suitable locations and the significant carbon footprint associated with constructing renewable energy infrastructure are becoming more apparent. Hydrogen has been found to play a vital role as an energy carrier in framing the energy picture in the 21st century. Currently about 1 % of the global energy demands are being met by hydrogen energy harnessed through renewable methods. Its low carbon emissions when compared to other methods lower comparative production costs and high energy efficiency of 40–60 % make it a suitable choice. Integrating hydrogen production systems with other renewable source of energy such as solar and wind energy have been discussed in this review in detail. With the concepts of green buildings or net zero energy buildings gaining attraction integration of hydrogen-based systems within residential and office sectors through the use of devices such as micro–Combined Heat and Power devices (mCHP) have proven to be effective and efficient. These devices have been found to save the consumed energy by 22 % along with an effective reduction in carbon emissions of 18 % when used in residential sectors. Using the rejected energy from other processes these mCHP devices can prove to be vital in meeting the energy demands of the residential sector. Through the support of government schemes mCHP devices have been widely used in countries such as Japan and Finland and have benefitted from the same. Hydrogen storage is critical for efficient operation of the integrated renewable systems as improper storage of the hydrogen produced could lead to human and environmental disasters. Using boron hydrides or ammonia (121 kg H2/m3 ) or through organic carriers hydrogen can be stored safely and easily regenerated without loss of material. A thorough comparison of all the renewable sources of energy that are used extensively is required to evaluate the merits of using hydrogen as an energy carrier which has been addressed in this review paper. The need to address the research gap in application of mCHP devices in the residential sector and the benefits they provide has been addressed in this review. With about 2500 GW of energy ready to be harnessed through the mCHP devices globally the potential of mCHP systems globally are discussed in detail in this paper. This review discusses challenges and solutions to hydrogen production storage and ways to implement hydrogen technology in the residential sector. This review allows researchers to build a renewable alternative with hydrogen as a clean energy vector for generating electricity in residential systems.
Flexibility Value of Multimodal Hydrogen Energy Utilization in Electric–Hydrogen–Thermal Systems
Jun 2024
Publication
Hydrogen energy is now a crucial technological option for decarbonizing energy systems. Comprehensive utilization is a typical mode of hydrogen energy deployment leveraging its excellent conversion capabilities. Hydrogen is often used in combination with electrical and thermal energy. However current hydrogen utilization modes are relatively singular resulting in low energy utilization efficiency and high wind curtailment rates. To improve energy utilization efficiency and promote the development of hydrogen energy we discuss three utilization modes of hydrogen energy including hydrogen storage integration into a fuel cell and gas turbine hybrid power generation system and hydrogen methanation. We propose a hydrogen energy system with multimodal utilization and integrate it into an electrolytic hydrogen–thermal integrated energy system (EHTIES). A mixed-integer linear programming (MILP) optimization scheduling model for the EHT-IES is developed and solved using the Cplex solver to improve the operational feasibility of the EHTIES focusing on minimizing economic costs and reducing wind curtailment rates. Case studies in northwest China verify the effectiveness of the proposed model. By comparing various utilization modes energy storage methods and scenarios this study demonstrated that integrating a hydrogen energy system with multimodal utilization into the EHT-IES offers significant technical benefits. It enhances energy utilization efficiency and promotes the absorption of wind energy thereby increasing the flexibility of the EHT-IES.
Analysis of China’s Low-Carbon Power Transition Path Considering Low-Carbon Energy Technology Innovation
Jan 2025
Publication
Innovation in key low-carbon technologies plays a supporting role in achieving a high-quality low-carbon transition in the power sector. This paper aims to integrate research on the power transition pathway under the “dual carbon” goals with key technological innovation layouts. First it deeply analyzes the development trends of three key low-carbon technologies in the power sector—new energy storage CCUS and hydrogen energy—and establishes a quantitative model for their technological support in the low-carbon transition of the power sector. On this basis the objective function and constraints of traditional power planning models are improved to create an integrated optimization model for the power transition pathway and key low-carbon technologies. Finally a simulation analysis is conducted using China’s power industry “dual carbon” pathway as a case study. The optimization results include the power generation capacity structure power generation mix carbon reduction pathway and key low-carbon technology development path for China from 2020 to 2060. Additionally the impact of uncertainties in breakthroughs in new energy storage CCUS and hydrogen technologies on the power “dual carbon” pathway is analyzed providing technological and decision-making support for the low-carbon transition of the power sector.
Integration of Underground Green Hydrogen Storage in Hybrid Energy Generation
May 2024
Publication
One of the major challenges in harnessing energy from renewable sources like wind and solar is their intermittent nature. Energy production from these sources can vary based on weather conditions and time of day making it essential to store surplus energy for later use when there is a shortfall. Energy storage systems play a crucial role in addressing this intermittency issue and ensuring a stable and reliable energy supply. Green hydrogen sourced from renewables emerges as a promising solution to meet the rising demand for sustainable energy addressing the depletion of fossil fuels and environmental crises. In the present study underground hydrogen storage in various geological formations (aquifers depleted hydrocarbon reservoirs salt caverns) is examined emphasizing the need for a detailed geological analysis and addressing potential hazards. The paper discusses challenges associated with underground hydrogen storage including the requirement for extensive studies to understand hydrogen interactions with microorganisms. It underscores the importance of the issue with a focus on reviewing the the various past and present hydrogen storage projects and sites as well as reviewing the modeling studies in this field. The paper also emphasizes the importance of incorporating hybrid energy systems into hydrogen storage to overcome limitations associated with standalone hydrogen storage systems. It further explores the past and future integrations of underground storage of green hydrogen within this dynamic energy landscape.
Expansion of Next-Generation Sustainable Clean Hydrogen Energy in South Korea: Domino Explosion Risk Analysis and Preventive Measures Due to Hydrogen Leakage from Hydrogen Re-Fueling Stations Using Monte Carlo Simulation
Apr 2024
Publication
Hydrogen an advanced energy source is growing quickly in its infrastructure and technological development. Urban areas are constructing convergence-type hydrogen refilling stations utilizing existing gas stations to ensure economic viability. However it is essential to conduct a risk analysis as hydrogen has a broad range for combustion and possesses significant explosive capabilities potentially leading to a domino explosion in the most severe circumstances. This study employed quantitative risk assessment to evaluate the range of damage effects of single and domino explosions. The PHAST program was utilized to generate quantitative data on the impacts of fires and explosions in the event of a single explosion with notable effects from explosions. Monte Carlo simulations were utilized to forecast a domino explosion aiming to predict uncertain events by reflecting the outcome of a single explosion. Monte Carlo simulations indicate a 69% chance of a domino explosion happening at a hydrogen refueling station if multi-layer safety devices fail resulting in damage estimated to be three times greater than a single explosion
A Systems-Level Study of Ammonia and Hydrogen for Maritime Transport
Aug 2023
Publication
An energy systems comparison of grid-electricity derived liquid hydrogen (LH2) and liquid ammonia (LNH3) is conducted to assess their relative potential in a low-carbon future. Under various voyage weather conditions their performance is analysed for use in cargo transport energy vectors for low-carbon electricity transport and fuel supply. The analysis relies on literature projections for technological development and grid decarbonisation towards 2050. Various voyages are investigated from regions such as North America (NA) Europe (E) and Latin America (LA) to regions projected to have a higher electricity and fuel grid carbon intensity (CI) (i.e. Asia Pacific Africa the Middle-East and the CIS). In terms of reducing the CI of electricity and fuel at the destination port use of LH2 is predicted to be favourable relative to LNH3 whereas LNH3 is favourable for low-carbon transport of cargo. As targeted by the International Maritime Organisation journeys of LNH3 cargo ships originating in NA E and LA achieve a reduction in volumetric energy efficiency design index (kg-CO2/m3 -km) of at least 70% relative to 2008 levels. The same targets can be met globally if LH2 is supplied to high CI regions for production of LNH3 for cargo transport. A future shipping system thus benefits from the use of both LH2 and LNH3 for different functions. However there are additional challenges associated with the use of LH2. Relative to LNH3 1.6 to 1.7 times the number of LH2 ships are required to deliver the same energy. Even when reliquefaction is employed their success is reliant on the avoidance of rough sea states (i.e. Beaufort Numbers >= 6) where fuel depletion rates during a voyage are impractical.
Techno-economic Modelling of AEM Electrolysis Systems to Identify Ideal Current Density and Aspects Requiring Further Research
Aug 2023
Publication
Hydrogen produced by water electrolysis using renewable energy is a sustainable alternative to steam reformation. As a nascent commercial technology performance and economic comparisons of anion exchange membrane water electrolyzers (AEMWE) to other electrolyzer technology benchmarks are not available. We present a techno-economic model estimating AEMWE's baseline levelized cost of hydrogen (LCOH) at $5.79/kg considering trade-offs between current density efficiency stability capital and operating costs. The optimal current density is 1.38 A cm2 balancing stability and performance for the lowest LCOH. Using low-cost electricity and larger stack sizes AEMWE could achieve $2/kg low-carbon hydrogen. Technical improvements targeting system efficiency particularly reducing overpotentials in hydrogen and oxygen evolution reactions could further reduce LCOH to $1.29/kg approaching U.S. Department of Energy cost targets. There are hopes this model could raise the profile of AEMWE's economic potential to produce green hydrogen and highlight its suitability for decarbonizing the energy sector.
Factors Driving the Decarbonisation of Industrial Clusters: A Rapid Evidence Assessment of International Experience
Sep 2023
Publication
Reducing industrial emissions to achieve net-zero targets by the middle of the century will require profound and sustained changes to how energy intensive industries operate. Preliminary activity is now underway with governments of several developed economies starting to implement policy and providing funding to support the deployment of low carbon infrastructure into high emitting industrial clusters. While clusters appear to offer the economies of scale and institutional capacity needed to kick-start the industrial transition to date there has been little systematic assessment of the factors that may influence the success of these initiatives. Drawing from academic and grey literature this paper presents a rapid evidence assessment of the approaches being used to drive the development of low carbon industrial clusters internationally. Many projects are still at the scoping stage but it is apparent that current initiatives focus on the deployment of carbon capture technologies alongside hydrogen as a future secondary revenue stream. This model of decarbonisation funnels investment into large coastal clusters with access to low carbon electricity and tends to obscure questions about the integration of these technologies with other decarbonisation interventions such as material efficiency and electrification. The technology focus also omits the importance that a favourable location and shared history and culture appears to have played in helping progress the most advanced initiatives; factors that cannot be easily replicated elsewhere. If clusters are to kick-start the low-carbon industrial transition then greater attention is needed to the social and political dimensions of this process and to a broader range of decarbonisation interventions and cluster types than represented by current projects.
A Control Strategy Study of a Renewable CCHP Energy System Integrated Hydrogen Production Unit - A Case Study of an Industrial Park in Jiangsu Province
Aug 2023
Publication
This paper describes a renewable energy system incorporating a hydrogen production unit to address the imbalance between energy supply and demand. The system utilizes renewable energy and hydrogen production energy to release energy to fill the power gap during peak demand power supply for demand peaking and valley filling. The system is optimized by analyzing marine predator behavioral logic and optimizing the system for maximum operational efficiency and best economic value. The results of the study show that after the optimized scheduling of the hydrogen production coupled renewable energy integrated energy system using the improved marine predator optimization algorithm the energy distribution of the whole energy system is good with the primary energy saving rate maintained at 24.75% the CO2 emission reduction rate maintained at 42.32% and the cost saving rate maintained at 0.78%. In addition this paper uses the Adaboost-BP prediction model to predictively analyze the system. The results show that as the price of natural gas increases the advantages of the combined hydrogen production renewable integrated energy system proposed in this paper become more obvious and the cumulative cost over three years is better than other related systems. These research results provide an important reference for the application and development of the system.
Techno-Economic Analysis of Hydrogen Production from Swine Manure Biogas via Steam Reforming in Pilot-Scale Installation
Sep 2023
Publication
The main purpose of this paper is the techno-economic analysis of hydrogen production from biogas via steam reforming in a pilot plant. Process flow modeling based on mass and energy balance is used to estimate the total equipment purchase and operating costs of hydrogen production. The pilot plant installation produced 250.67 kg/h hydrogen from 1260 kg/h biomethane obtained after purification of 4208 m3/h biogas using a heat and mass integration process. Despite the high investment cost the plant shows a great potential for biomethane reduction and conversion to hydrogen an attractive economic path with ecological possibilities. The conversion of waste into hydrogen is a possibility of increasing importance in the global energy economy. In the future such a plant will be expanded with a CO2 reduction module to increase economic efficiency and further reduce greenhouse gases in an economically viable manner.
Applying a 2 kW Polymer Membrane Fuel-Cell Stack to Building Hybrid Power Sources for Unmanned Ground Vehicles
Nov 2023
Publication
The novel constructions of hybrid energy sources using polymer electrolyte fuel cells (PEMFCs) and supercapacitors are developed. Studies on the energy demand and peak electrical power of unmanned ground vehicles (UGVs) weighing up to 100 kg were conducted under various conditions. It was found that the average electrical power required does not exceed ~2 kW under all conditions studied. However under the dynamic electrical load of the electric drive of mobile robots the short peak power exceeded 2 kW and the highest current load was in the range of 80–90 A. The electrical performance of a family of PEMFC stacks built in open-cathode mode was determined. A hydrogen-usage control strategy for power generation cleaning processes and humidification was analysed. The integration of a PEMFC stack with a bank of supercapacitors makes it possible to mitigate the voltage dips. These occur periodically at short time intervals as a result of short-circuit operation. In the second construction the recovery of electrical energy dissipated by a short-circuit unit (SCU) was also demonstrated in the integrated PEMFC stack and supercapacitor bank system. The concept of an energy-efficient mobile and environmentally friendly hydrogen charging unit has been proposed. It comprises (i) a hydrogen anion exchange membrane electrolyser (ii) a photovoltaic installation (iii) a battery storage (iv) a hydrogen buffer storage in a buffer tank (v) a hydrogen compression unit and (vi) composite tanks.
Hydrogen Station Prognostics and Health Monitoring Model
Aug 2023
Publication
Hydrogen fuel has shown promise as a clean alternative fuel aiding in the reduction of fossil fuel dependence within the transportation sector. However hydrogen refueling stations and infrastructure remains a barrier and are a prerequisite for consumer adoption of low-cost and low-emission fuel cell electric vehicles (FCEVs). The costs for FCEV fueling include both station capital costs and operation and maintenance (O&M) costs. Contributing to these O&M costs unscheduled maintenance is presently more costly and more frequent than for similar gasoline fueling infrastructure and is asserted to be a limiting factor in achieving FCEV customer acceptance and cost parity. Unscheduled maintenance leads to longer station downtime therefore causing an increase in missed fueling opportunities which forces customers to seek refueling at other operable stations that may be significantly farther away. This research proposes a framework for a hydrogen station prognostics health monitoring (H2S PHM) model that can minimize unexpected downtime by predicting the remaining useful life for primary hydrogen station components within the major station subsystems. The H2S PHM model is a data-driven statistical model based on O&M data collected from 34 retail hydrogen stations located in the U.S. The primary subcomponents studied are the dispenser compressor and chiller. The remaining useful life calculations are used to decide whether or not maintenance should be completed based on the prediction and expected future station use. This paper presents the background method and results for the H2S PHM model as for a means for improving station availability and customer confidence in FCEVs and hydrogen infrastructure
Alternatives for Transport, Storage in Port and Bunkering Systems for Offshore Energy to Green Hydrogen
Nov 2023
Publication
Offshore electricity production mainly by wind turbines and eventually floating PV is expected to increase renewable energy generation and their dispatchability. In this sense a significant part of this offshore electricity would be directly used for hydrogen generation. The integration of offshore energy production into the hydrogen economy is of paramount importance for both the techno-economic viability of offshore energy generation and the hydrogen economy. An analysis of this integration is presented. The analysis includes a discussion about the current state of the art of hydrogen pipelines and subsea cables as well as the storage and bunkering system that is needed on shore to deliver hydrogen and derivatives. This analysis extends the scope of most of the previous works that consider port-to-port transport while we report offshore to port. Such storage and bunkering will allow access to local and continental energy networks as well as to integrate offshore facilities for the delivery of decarbonized fuel for the maritime sector. The results of such state of the art suggest that the main options for the transport of offshore energy for the production of hydrogen and hydrogenated vectors are through direct electricity transport by subsea cables to produce hydrogen onshore or hydrogen transport by subsea pipeline. A parametric analysis of both alternatives focused on cost estimates of each infrastructure (cable/pipeline) and shipping has been carried out versus the total amount of energy to transport and distance to shore. For low capacity (100 GWh/y) an electric subsea cable is the best option. For high-capacity renewable offshore plants (TWh/y) pipelines start to be competitive for distances above approx. 750 km. Cost is highly dependent on the distance to land ranging from 35 to 200 USD/MWh.
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