Publications
Green Hydrogen Viability in the Transition to a Fully-Renewable Energy Grid
Sep 2025
Publication
With the transition to a fully renewable energy grid arises the need for a green source of stability and baseload support which classical renewable generation such as wind and solar cannot offer due to their uncertain and highly-variable generation. In this paper we study whether green hydrogen can close this gap as a source of supplemental generation and storage. We design a two-stage mixed-integer stochastic optimization model that accounts for uncertainties in renewable generation. Our model considers the investment in renewable plants and hydrogen storage as well as the operational decisions for running the hydrogen storage systems. For the data considered we observe that a fully renewable network driven by green hydrogen has a greater potential to succeed when wind generation is high. In fact the main investment priorities revealed by the model are in wind generation and in liquid hydrogen storage. This long-term storage is more valuable for taking full advantage of hydrogen than shorter-term intraday hydrogen gas storage. In addition we note that the main driver for the potential and profitability of green hydrogen lies in the electricity demand and prices as opposed to those for gas. Our model and the investment solutions proposed are robust with respect to changes in the investment costs. All in all our results show that there is potential for green hydrogen as a source of baseload support in the transition to a fully renewable-powered energy grid.
A Review of Caprock Integrity in Underground Hydrogen Storage Sites: Implication of Wettability, Interfacial Tension, and Diffusion
Oct 2025
Publication
As industry moves from fossil fuels to green energy substituting hydrocarbons with hydrogen as an energy carrier seems promising. Hydrogen can be stored in salt caverns depleted hydrocarbon fields and saline aquifers. Among other criteria these storage solutions must ensure storage safety and prevent leakage. The ability of a caprock to prevent fluid from flowing out of the reservoir is thus of utmost importance. In this review the main factors influencing fluid flow are examined. These are the wettability of the caprock formation the interfacial tension (IFT) between the rock and the gas or liquid phases and the ability of gases to diffuse through it. To achieve effective sealing the caprock formation should possess low porosity a disconnected or highly complicated pore system low permeability and remain strongly water-wet regardless of pressure and temperature conditions. In addition it must exhibit low rock–liquid IFT while presenting high rock–gas and liquid–gas IFT. Finally the effective diffusion coefficient should be the lowest possible. Among all of the currently reviewed formations and minerals the evaporites low-organic-content shales mudstones muscovite clays and anhydrite have been identified as highly effective caprocks offering excellent sealing capabilities and preventing hydrogen leakages.
Decarbonising Agriculture with Green Hydrogen: A Stakeholder Guided Feasibility Study
Oct 2025
Publication
Green hydrogen offers a promising yet underexplored pathway for agricultural decarbonisation requiring technological readiness and coordinated action from policymakers industry and farmers. This paper integrates techno-economic modelling with stakeholder engagement (semi-structured interviews and an expert workshop) to assess its potential. Analyses were conducted for farms of 123 hectares and clusters of 10 farms complemented by seven interviews and a workshop with nine sector experts. Findings show both opportunities and barriers. While on-farm hydrogen production is technically feasible it remains economically uncompetitive due to high levelised costs shaped by seasonal demand variability and low utilisation of electrolysers and storage. Pooling demand across multiple users is essential to improve cost-effectiveness. Stakeholders identified three potential business models: fertiliser production via ammonia synthesis cooperative-based models and local refuelling stations. Of these cooperative hydrogen hubs emerged as the most promising enabling clusters of farms to jointly invest in renewable-powered electrolysers storage and refuelling facilities thereby reducing costs extending participation to smaller farms and mitigating risks through collective investment. By linking techno-economic feasibility with stakeholder perspectives and business model considerations the results contribute to socio-technical transition theory by showing how technological institutional and social factors interact in shaping hydrogen adoption in agriculture. With appropriate policy support cooperative hubs could lower costs ease concerns over affordability and complexity and position hydrogen as a practical driver of agricultural decarbonisation and rural resilience. Keywords: green
Development of Sustainability Assessment Framework for Preliminary Design of Chemical Process: Hydrogen Production as Case Study
Aug 2025
Publication
Sustainable process design has become increasingly important in transitioning from conventional to sustainable chemical production yet comprehensive sustainability assessment at the preliminary design stage remains a challenge. This study addresses this gap by proposing a hierarchical framework that integrates the Principles Criteria and Indicators (PC&I) method with multi-criteria decision-making (MCDM) tools including entropy weighting TOPSIS and weighted addition. The framework guides the systematic selection of sustainability indicators across economic environmental and social dimensions. To validate its applicability a case study on hydrogen production via four process routes natural gas reforming biomass-derived syngas methanol purge gas recovery and alkaline electrolysis is conducted. Results show that the methanol purge gas process exhibits the best overall sustainability followed by biomass syngas and alkaline electrolysis. The case demonstrates the framework’s capability to differentiate between alternatives under conflicting sustainability dimensions. This work provides a structured and replicable approach to support sustainable decision-making in early-stage chemical process design.
Scaling of Automotive Fuel Cells in Terms of Operating Indicators
Oct 2025
Publication
The search for alternatives to fossil fuels has led to hydrogen becoming an important factor in the powering means of transportation. Its most effective application is in fuel cells. A single fuel cell is not a sufficient source of power which is why a stack of fuel cells is the more common solution. Fuel cells are tested using single units as this allows all cell parameters (the current density flow rates and efficiency) to be evaluated. Therefore the scalability of fuel cells is an essential factor. This paper analyses the scalability of fuel cells with a power of approximately 100 kW and 1.2 kW. Road tests of the fuel cells were compared with stationary tests which allowed the load to be reproduced and scaled. This provided a representation of the scaled current and the scalable power of the fuel cell. The research provided voltage–current characteristics of fuel cell stacks and their individual equivalents. It was concluded that regardless of the power scaling or current values the characteristics obtain similar patterns. A very important element of the research is the awareness of the properties of these cells (the number of cells and active charge exchange area) in order to compare the unit characteristics of fuel cells.
Numerical Investigation on the Diffusion and Ventilation Characteristics of Hydrogen-Blended Natural Gas Leakage in Indoor Spaces
Oct 2025
Publication
The blending of hydrogen significantly impacts the diffusion and safety characteristics of natural gas within indoor environments. This study employs ANSYS Fluent 2021 R1 to numerically investigate the diffusion and ventilation characteristics of hydrogen-blended natural gas (HBNG) leakage in indoor spaces. A physical and mathematical model of gas leakage from pipelines is established to study hazardous areas flammable regions ventilation characteristics alarm response times safe ventilation rates and the concentration distribution of leaked gas. The effects of hydrogen blending ratio (HBR) ventilation conditions and space dimensions on leakage diffusion and safety are analyzed. Results indicate that HBNG leakage forms vertical concentration stratification in indoor spaces with ventilation height being negatively correlated with gas concentration and flammable regions. In the indoor space conditions of this study by improving ventilation conditions the hazardous area can be reduced by up to 92.67%. Increasing HBR substantially expands risk zones—with pure hydrogen producing risk volumes over five times greater than natural gas. Mechanical ventilation significantly enhances indoor safety. Safe ventilation rates escalate with hydrogen content providing quantitative safety criteria for HBNG implementation. The results underscore the critical influence of HBR and ventilation strategy on risk assessment providing essential insights for the safe indoor deployment of HBNG.
Thermochemical Aspects of Substituting Natural Gas by Hydrogen in Blister Copper Deoxidation
Aug 2025
Publication
This study employs computational thermodynamics to evaluate the feasibility of replacing methane with hydrogen as both burner fuel and reductant during blister copper deoxidation aiming to enhance deoxidation efficiency and reduce CO2 emissions. A comprehensive thermodynamic model was developed using FactSage 8.3 for dilute Cu–O and Cu–S–O melts containing trace impurities (Fe Ni Pb Zn) incorporating methane thermal decomposition and temperature-dependent variations in liquid copper density with oxygen and sulfur content. Model parameters were optimized against over 105 deoxidation simulation data points yielding temperature- and composition-dependent expressions for rapid density estimates. Benchmarking against existing literature models demonstrated improved accuracy. Key findings include: (1) increasing impurities contents from electronics waste recycling (Fe Ni Pb Zn) reduces oxygen activity deteriorating the deoxidation efficiency; (2) under global equilibrium methane provides greater reducing power per mole than hydrogen due to full thermal cracking but real-world mass transfer limitations render hydrogen more consistently effective up to 1200 C with methane gas needing to achieve at least 472 C to match hydrogen’s performance; (3) adiabatic flame equilibrium studies show that O2/H2 ratios of 0.5 to 1 yield liquid copper oxygen activities comparable to industrial O2/CH4 ratios of 2 to 3 supporting the direct substitution of methane with hydrogen in oxy-fuel anode furnace burners without compromising metal quality.
Analysis of the Efficiency of Hydrogen Fuel Cell Vehicle (HFCV) Applications in Manufacturing Processes Using Computer Simulation
Oct 2025
Publication
Implementing innovative solutions in the internal transport of manufacturing enterprises is becoming an important element of improving operational efficiency and reducing greenhouse gas emissions. This article assesses the potential of hydrogen fuel cell (HFCV) forklifts in a steel products manufacturing plant. The verification was carried out using a computer simulation which enabled the comparison of electric combustion and HFCV fleets under identical logistical conditions. The results showed that the HFCV fleet allowed for shorter process execution times and higher utilization compared to electric and combustion variants mainly due to the elimination of charging and refueling interruptions. Additionally when powered by green hydrogen the HFCV fleet offered clear environmental benefits and lower operating costs. The study confirms that HFCV technology can improve the efficiency of internal transport and reduce energy-related operating expenses although the costs of hydrogen refueling infrastructure were not included and should be addressed in future research.
Techno-Economic Optimization of Hybrid Renewable Energy Systems (HRESs) and Feasibility Study on Replacing Diesel and Photovoltaic Systems with Hydrogen for Electrical and Small Deferrable Loads: Case Study of Cameroon
Oct 2025
Publication
To reduce the amount of harmful gases produced by fossil fuels more environmentally friendly and sustainable alternatives are being proposed around the world. As a result technologies for manufacturing hydrogen fuel cells and producing green hydrogen are becoming more widespread with an impact on energy production and environmental protection. In many countries around the world and in Africa in particular leaders scientists and populations are considering switching from fossil fuels to so-called green energies. Hydrogen is therefore an interesting alternative that deserves to be explored especially since both rural and urban populations have shown an interest in using it in the near future which would reduce pollution and the proliferation of greenhouse gases thereby mitigating global warming. The aim of this paper is to determine the hybrid energy system best suited to addressing the energy problem in the study area and then to make successive substitutions of different energy sources starting with the most polluting in order to assess the possibilities for transitioning the energy used in the area to green hydrogen. To this end this study began with a technical and economic analysis which based on climatic parameters led to the proposal of a PV/DG-BATTery system configuration with a Net Present Cost (NPC) of USD 19267 and an average Cost Of Energy (COE) of USD 0.4 and with a high proportion of CO2 emissions compared with the PV/H2GEN-BATT and H2GEN systems. The results of replacing fossil fuel generators with hydrogen generators are beneficial in terms of environmental protection and lead to a reduction in energy-related expenses of around 2.1 times the cost of diesel and a reduction in mass of around 2.7 times the mass of diesel. The integration of H2GEN at high duty percentages increases the Cost Of Energy whether in a hybrid PV/H2GEN system or an H2GEN system. This shows the interest in the study country in using favorable duty proportions to make the use of hydrogen profitable.
Transforming Ports for a Low-carbon Future: Nexus Modeling of Hydrogen Infrastructure, Employment, and Resource Management in Contrasting Climates
Aug 2025
Publication
This research study highlights a transformative approach to port development for a lowcarbon future by integrating Climate Land Energy and Water Systems (CLEWs) and Water-Energy-Food (WEF) frameworks. The proposed nexus model integrates the hydrogen infrastructure with green employment and resource management in contrasting climates. The scenarios analyzed include Business As Usual (BAU) Balanced Reduction Approach (BRA) and Maximal Sustainability Push (MSP) which focuses mainly on energy efficiency resource utilization and workforce sustainability. By BRA it is estimated that carbon emissions will decline by 30% in cold climates and 20% in warm climates without changing renewable power plants producing 45% and 30% of the electricity supply mix. In the MSP scenario emission reductions rise to 90% in cold and 40% in warm climates with renewables providing 62% and 40% of the electricity mix. Under the whole capacity of Municipal Solid Waste (MSW) and fish waste under anaerobic digestion and fish waste rendering by 2040 across all BRA and MSP scenarios. In transport 44% replacement of marine vehicles and 87% of land vehicles with hydrogen electric and carbon capture and storage (CCS)-equipped vehicles is made under the BRA scenario. These percentages increase to 100% under the MSP scenario in cold climates while remaining at 87% in warm climates. By this integrated framework the present study demonstrates the potential of ports to be powerful engines for sustainable economic growth optimized resource efficiency and the creation of resilient green employment systems in diverse environmental contexts.
Hydrogen Safety in Energy Infrastructure: A Review
Oct 2025
Publication
For the transition to emission-free or low-emission energy hydrogen is a promising energy carrier and fuel of the future with the possibility of long-term storage. Due to its specific properties it poses certain safety risks; therefore it is necessary to have a comprehensive understanding of hydrogen. This review article contains ten main chapters and provides by synthesizing current findings primarily from standards and scientific studies (predominantly from 2023 to 2024) the theoretical basis for further research directed toward safe hydrogen infrastructure.
Study on the Thermodynamic Behavior of Large Volume Liquid Hydrogen Bottle Under the Coupling of Different Motion States and Operational Parameters
Oct 2025
Publication
Jun Shen,
Yuhang Liu,
Yongmei Hao,
Fei Li and
Hui Zhou
To investigate the variations in the thermodynamic behavior of large-volume liquid hydrogen tanks under different influencing factors a numerical model for liquid hydrogen tanks was developed. The changes in thermodynamic behavior in vehicle-mounted liquid hydrogen bottles under different motion states different operational pressures and different insulation thicknesses and their mutual coupling scenarios were studied. The results show that the movement makes the phase state in the liquid hydrogen bottle more uniform the pressure drop rate faster and the temperature lower: the heating rate in the liquid hydrogen bottle at 0.85 MPa operational pressure is lower than that at 0.5 MPa and 1.2 MPa. When the operational pressure is coupled with the motion state the influence of the motion state on the thermodynamic behavior of the fluid is dominant: the temperature near the wall rises rapidly. The temperature near the tank wall rises rapidly; however as the thickness of the insulation layer increases both the heating rate inside the liquid hydrogen tank and the temperature difference within the tank gradually tend to stabilize and become uniform.
Exploring the Potential of Ammonia as a Fuel: Advances in Combustion Understanding and Large-scale Furnace Applications
Sep 2025
Publication
From an environmental standpoint carbon-free energy carriers such as ammonia and hydrogen are essential for future energy systems. However their hightemperature chemical behavior remains insufficiently understood posing challenges for the development and optimization of advanced combustion technologies. Ammonia in particular is globally available and cost-effective especially for energy-intensive industries. The addition of ammonia or hydrogen to methane significantly reduces the accuracy of existing predictive models. Therefore validated and detailed data are urgently needed to enable reliable design and performance predictions. This review highlights the compatibility of ammonia with existing combustion infrastructure facilitating a smoother transition to more sustainable heating methods without the need for entirely new systems. Applications in high-temperature heating processes such as metal processing ceramics and glass production and power generation are of particular interest. This review focuses on the systematic assessment of alternative fuel mixtures comprising ammonia and hydrogen as well as natural gas with particular consideration of existing safety-related parameters and combustion characteristics. Fundamental quantities such as the laminar burning velocity are discussed in the context of their relevance for fuel mixtures and their scalability toward turbulent flame propagation which is of critical importance for industrial burner and reactor design. The influence of fuel composition on ignition limits is examined as these are essential parameters for safety margin definitions and operational boundary conditions. Furthermore flame stability in mixed-fuel systems is addressed to evaluate the practical feasibility and robustness of combustion under varying process conditions. A detailed overview of current diagnostic and analysis methods follows encompassing both pollutant measurement techniques and the detection of key radical species. These diagnostics form the experimental basis for reaction kinetics modeling and mechanism validation. Given the importance of emission formation in combustion systems a dedicated subsection summarizes major emission trends even though a comprehensive treatment would exceed the scope of this review. Thermal radiation effects which are highly relevant for heat transfer and system efficiency in large-scale applications are then reviewed. In parallel current developments in numerical simulation approaches for industrial-scale combustion systems are presented including aspects of model accuracy boundary conditions and computational efficiency. The review also incorporates insights from materials engineering particularly regarding high-temperature material performance corrosion resistance and compatibility with combustion products. Based on these interdisciplinary findings operational strategies for high-temperature furnaces are outlined and selected industrial reference systems are briefly presented. This integrated approach aims to support the design optimization and safe operation of next-generation combustion technologies utilizing carbon-free or low-carbon fuels.
Catalytic Hydrogen Combustion as Heat Source for the Dehydrogenation of Liquid Organic Hydrogen Carriers using a Novel Compact Autothermal Reactor
Sep 2025
Publication
The experimental performance of an autothermal hydrogen release unit comprising a perhydro benzyltoluene (H12-BT) dehydrogenation chamber and a catalytic hydrogen combustion (CHC) chamber in thermal contact is discussed. In detail the applied set-up comprised a multi-tubular CHC heating based on seven parallel tubes with the reactor shell containing a commercial dehydrogenation catalyst. In this way the CHC heated the endothermal LOHC dehydrogenation using a part of the hydrogen generated in the dehydrogenation. The proposed heating concept for autothermal LOHC dehydrogenation offers several advantages over state-of-the-art heating concepts including minimized space consumption high efficiency and zero NOx emissions. During performance tests the process reached a minimum hydrogen combustion fraction of 37 % while the minimum heat requirement for the dehydrogenation reaction for industrial scale plants is 33 %. The reactor orientation (vertical vs horizontal) and the flow configuration (counter-current vs. co-current) showed very little influence on the performance demonstrating the robustness of the proposed reactor design.
A Comprehensive Review of Green Hydrogen Technology: Electrolysis Methods, Topologies and Control Strategies, Applications
Oct 2025
Publication
As a pivotal clean energy carrier for achieving carbon neutrality green hydrogen technology has attracted growing global attention. This review systematically examines four mainstream water electrolysis technologies—alkaline electrolysis proton exchange membrane electrolysis solid oxide electrolysis and anion exchange membrane electrolysis—analyzing their fundamental principles material challenges and development trends. It further classifies and compares power electronic converter topologies including non-isolated and isolated DC–DC converters as well as AC–DC converter architectures and summarizes advanced control strategies such as dynamic power regulation and fault-tolerant operation aimed at enhancing system efficiency and stability. A holistic “electrolyzer–power converter–control strategy” integration framework is proposed to provide tailored technological solutions for diverse application scenarios. Finally the challenges and future prospects of green hydrogen across the energy transportation and industrial sectors are discussed underscoring its potential to accelerate the global transition toward a sustainable low-carbon energy system.
Experimental Investigation of Hydrogen Production Performance of PEM Electrolyze
Jul 2025
Publication
As global awareness of environmental protection increases hydrogen is seen as a promising solution due to its high energy density and zero-emission combustion. The PEM electrolyze combined with renewable energy power generation is an effective method to solve the problem of hydrogen production. The market competitiveness of PEM electrolyte will be enhanced in the future and the equipment cost can be reduced by 35.8%. The fast dynamic response performance of PEM electrolyzes especially during start-up and shutdown affects system flexibility and stability. The 190 Nm3/h test platform is established to study the fast dynamic response performance considering the cold startup thermal start-up and shutdown behaviors. The results shown that the 190 Nm³/h PEM electrolyze required 6340 s to achieve cold start-up 1100 s to achieve thermal start-up and 855 s to complete shutdown. When operating stably the temperature fluctuation of the PEM remains below 5 °C demonstrating the excellent temperature control performance. However during cold start-up and shutdown the concentrations of hydrogen and oxygen fluctuate significantly which can easily lead to a decrease in system performance. These findings provide guidance for optimizing the design and operating parameters of PEM Electrolyze systems.
Learning in Green Hydrogen Production: Insights from a Novel European Dataset
Jun 2025
Publication
The cost reduction of electrolysers is critical for scaling up green hydrogen production and achieving decarbonization targets. This study presents a novel and comprehensive dataset of electrolyser projects in Europe. It includes full cost and capacity details for each project and capturing project-specific characteristics such as technology type location and project type for the period 2005–2030. We apply the learning curve methodology to assess cost reductions across different electrolyser technologies and project sizes. Our findings indicate a significant learning effect for PEM and AEL electrolysers in the last 20 years with learning rates of 32.1% and 22.9% respectively. While AEL cost reductions are primarily driven by scaling effects PEM electrolysers benefit from both technological advancements and economies of scale. Small-scale electrolysers exhibit a stronger learning effect (25%) whereas large-scale projects show no clear cost reductions due to their early stage of deployment. Projections based on our learning rates suggest that reaching Europe’s 2030 target of 40 GW electrolyser capacity would require an estimated total investment of 14 billion EUR. These results align closely with previous studies and such predictions are closed to estimates from other organization. The dataset is publicly available allowing for further analysis and periodic updates to track cost trends.
Artificial Intelligence-based Multi-objective Optimization of a Solar-driven System for Hydrogen Production with Integrated Oxygen and Power Co-generation Across Different Climates
Oct 2025
Publication
This study develops and optimizes a solar-powered system for hydrogen generation with oxygen and power coproducts addressing the need for efficient scalable carbon-free energy solutions. The system combines a linear parabolic collector a Steam Rankine cycle and a Proton Exchange Membrane Electrolyzer (PEME) to produce electricity for electrolysis. Thermodynamic modeling was accomplished in Engineering Equation Solver while a hybrid Artificial Intelligence (AI) framework combining Artificial Neural Networks and Genetic Algorithms in Statistica coupled with Technique for Order Preference by Similarity to Ideal Solution (TOPSIS) decision support optimized technical and economic performance. Optimization considered seven key decision variables covering collector design thermodynamic inputs and component efficiencies. The optimization achieved energy and exergy efficiencies of 30.83 % and 26.32 % costing 47.02 USD/h and avoiding CO2 emissions equivalent to 190 USD/ton. Economic and exergy analyses showed the solar and hydrogen units had the highest costs (38.17 USD/h and 9.61 USD/h) with 4503 kWh of exergy destruction to generate 575 kWh of electricity. A case study across six cities suggested that Perth Bunbury and Adelaide with higher solar irradiance delivered the highest annual power and hydrogen outputs consistent with irradiance–electrolyzer correlation. Unlike conventional single-site studies this work delivers a climate-responsive multi-city analysis integrating solar thermal and PEME within an AI-driven framework. By linking techno-economic performance with quantified environmental value and co-production synergies of hydrogen oxygen and electricity the study highlights a novel pathway for scalable clean hydrogen measurable CO2 reductions and global decarbonization with future work focused on digital twins and dynamic uncertainty-aware optimization.
The Concept of an Infrastructure Location to Supply Buses with Hydrogen: A Case Study of the West Pomeranian Voivodeship in Poland
Jun 2025
Publication
The growing energy crisis and increasing threat of climate change are driving the need to take action regarding the use of alternative fuels in transport including public transport. Hydrogen is undoubtedly a fuel which is environmentally friendly and constitutes an alternative to fossil fuels. The wider deployment of hydrogen-powered vehicles involves the need to adapt infrastructure to support the operation of these vehicles. Such infrastructure includes refuelling stations for hydrogen-powered vehicles. The widespread use of hydrogen-powered vehicles is dependent on the development of a network of hydrogen refuelling stations. The aim of this article is to propose the conceptual location of infrastructure for fuelling public transport vehicles with hydrogen in selected cities of the West Pomeranian Voivodeship in particular the cities of Szczecin and Koszalin. The methodology used to determine the number of refuelling stations is described and the concept of the location for the refuelling stations has been proposed. Based on a set assumptions it was stated that two stations may be located in the Voivodeship in 2025 and seven stations in 2040. The research results will be of interest to infrastructure developers public transport companies and municipalities involved in making decisions related to the purchase and operation of hydrogen-powered buses.
Prospective Life Cycle Assessment of Future Swedish Hydrogen-powered Aviation Pathways
Jun 2025
Publication
Hydrogen-powered aviation is promoted as a low-carbon alternative for future long-distance air travel but its broader environmental impacts remain unclear. This study evaluates the potential environmental impacts of six future air travel pathways in Sweden including e-kerosene liquid hydrogen and fossil kerosene using prospective life cycle assessment. Results show that hydrogen-powered aviation has lower global warming potential than fossil kerosene but higher impacts on other environmental issues such as toxicity and land use. Key hotspots include resources in energy infrastructure and energy use in fuel production and airport operations however resource substitutions and energy efficiency improvements have limits. This study highlights the potential environmental benefits and tradeoffs of hydrogen-powered aviation and also the dependency of aviation on other sectors. Further research should integrate technological innovations in long-distance air travel pathways with scenarios that account for demand-side measures as well as regulatory political and economic barriers.
Technoeconomic analysis of Hydrogen Versus Natural Gas Considering Safety Hazards and Energy Efficiency Indicators
Aug 2025
Publication
Hydrogen (H2) is emerging as a key alternative to fossil fuels in the global energy transition. This study presents a comparative techno-economic analysis of H2 and natural gas (NG) focusing on safety hazards energy output CO2 emissions and cost-effectiveness aspects. Our analysis showed that compared to NG and other highly flammable gases like acetylene (C2 H2) and propane (C3 H8) H2 has a higher hazard potential due to factors such as its wide flammability range low ignition energy and high flame speed. In terms of energy output 1 kg of NG produces 48.60 MJ while conversion to liquefied natural gas (LNG) grey H2 and blue H2 reduces energy output to 45.96 MJ 35.45 MJ and 31.21 MJ respectively. Similarly while unconverted NG emits 2.72 kg of CO2 per kg emissions increase to 3.12 kg for LNG and 3.32 kg for grey H2. However blue H2 significantly reduces CO2 emissions to 1.05 kg per kg due to carbon capture and storage. From an economic perspective producing 1 kg of NG yields a profit of $0.011. Converting NG to grey H2 is most profitable yielding a net profit of $0.609 per kg of NG while blue H2 despite higher production costs remains viable with a profit of $0.390 per kg of NG. LNG conversion also shows profitability with $0.061 per kg of NG. This analysis highlights the trade-offs between energy efficiency environmental impact and economic viability providing valuable insights for stakeholders formulating hydrogen and LNG implementation strategies.
The Need for Change: A Roadmap for the Sustainable Transformation of the Chemical Industry
Jun 2025
Publication
The chemical industry faces major challenges worldwide. Since 1950 production has increased 50-fold and is projected to continue growing particularly in Asia. It is one of the most energy- and resource-intensive industries contributing significantly to greenhouse gas emissions and the depletion of finite resources. This development exceeds planetary boundaries and calls for a sustainable transformation of the industry. The key transformation areas are as follows: (1) Non-Fossil Energy Supply: The industry must transition away from fossil fuels. Renewable electricity can replace natural gas while green hydrogen can be used for high-temperature processes. (2) Circularity: Chemical production remains largely linear with most products ending up as waste. Sustainable product design and improved recycling processes are crucial. (3) Non-Fossil Feedstock: To achieve greenhouse gas neutrality oil gas and coal must be replaced by recycling plastics renewable biomaterials or CO2-based processes. (4) Sustainable Chemical Production: Energy and resource savings can be achieved through advancements like catalysis biotechnology microreactors and new separation techniques. (5) Sustainable Chemical Products: Chemicals should be designed to be “Safe and Sustainable by Design” (SSbD) meaning they should not have hazardous properties unless essential to their function. (6) Sufficiency: Beyond efficiency and circularity reducing overall material flows is essential to stay within planetary boundaries. This shift requires political economic and societal efforts. Achieving greenhouse gas neutrality in Europe by 2050 demands swift and decisive action from industry governments and society. The speed of transformation is currently too slow to reach this goal. Science can drive innovation but international agreements are necessary to establish a binding framework for action.
Energy Storage in the Energy Transition and Blue Economy: Challenges, Innovations, Future Perspectives, and Educational Pathways
Sep 2025
Publication
Transitioning to renewable energy is vital to achieving decarbonization at the global level but energy storage is still a major challenge. This review discusses the role of energy storage in the energy transition and the blue economy focusing on technological development challenges and directions. Effective storage is vital for balancing intermittent renewable energy sources like wind solar and marine energy with the power grid. The development of battery technologies hydrogen storage pumped hydro storage and emerging technologies like sodium-ion and metal-air batteries is discussed for their potential for large-scale deployment. Shortages in critical raw materials environmental impact energy loss and costs are some of the challenges to large-scale deployment. The blue economy promises opportunities for offshore energy storage notably through ocean thermal energy conversion (OTEC) and compressed air energy storage (CAES). Moreover the capacity of datadriven optimization and artificial intelligence to enhance storage efficiency is discussed. Policy interventions and economic incentives are necessary to spur the development and deployment of sustainable energy storage technology. Education and workforce training are also important in cultivating future researchers engineers and policymakers with the ability to drive energy innovation. Merging sustainability training with an interdisciplinary approach can potentially establish an efficient workforce that is capable of addressing energy issues. Future work needs to focus on higher energy density efficiency recyclability and cost-effectiveness of the storage technologies without sacrificing their environmental sustainability. The study underlines the need for converging technological economic and educational approaches to enable a sustainable and resilient energy future.
Day-Ahead Dispatch Optimization of an Integrated Hydrogen–Electric System Considering PEMEL/PEMFC Lifespan Degradation and Fuzzy-Weighted Dynamic Pricing
Sep 2025
Publication
Integrated Hydrogen–Energy Systems (IHES) have attracted widespread attention; however distributed energy sources such as photovoltaics (PV) and wind turbines (WT) within these systems exhibit significant uncertainty and intermittency posing key challenges to scheduling complexity and system instability. As a core mechanism for the integrated operation of IHES electricity price regulation can promote the absorption of renewable energy optimize resource allocation and enhance operational economy. Nevertheless uncertainties in IHES hinder the formulation of accurate electricity prices which easily lead to delays in scheduling responses and an increase in cumulative operating costs. To address these issues this study develops lifespan models for Proton Exchange Membrane Electrolyzers (PEMELs) and Proton Exchange Membrane Fuel Cells (PEMFCs) constructs dynamic equations for the demand side and response side and proposes a fuzzy-weighted dynamic pricing strategy. Simulation results show that compared with fixed pricing the proposed dynamic pricing strategy reduces economic indicators by an average of 15.3% effectively alleviates energy imbalance and optimizes the energy supply of components. Additionally it reduces the lifespan degradation of PEMELs by 21.59% and increases the utilization rate of PEMFCs by 54.8%.
Overcoming Hurdles and Harnessing the Potential of the Hydrogen Transition in Germany
Jun 2025
Publication
Green hydrogen has become a core element of Europe’s energy transition to assist in lowering carbon emissions. However the transition to green hydrogen faces challenges including the cost of production availability of renewable energy sources public opposition and the need for supportive government policies and financial initiatives. While there are other alternatives for producing low-carbon hydrogen for example blue hydrogen German funding favours projects that involve hydrogen production via electrolysis. Beyond climate goals it is anticipated that a green hydrogen industry will create economic benefits and a wide-range of collaborative opportunities with key international partnerships increasing energy security if done appropriately. Germany a leader in green hydrogen technology will need to rely on imports to meet long-term demand due to limited renewable energy capacity. Despite the current obstacles to transitioning to green hydrogen it is felt that ultimately the benefits of this industry and reducing emissions will outweigh the associated costs of production. This study analyses the hydrogen transition in Germany by interviewing 37 European experts guided by the research question: What are the key perceived barriers and opportunities influencing the successful adoption and integration of hydrogen technologies in Germany’s hydrogen transition?
Renewables, Electrification and Flexibility for a Competitive EU Energy System Transformation by 2030
Jun 2025
Publication
The European Union is on a pathway to achieve climate neutrality by 2050. This report explores the historic and necessary efforts to align Europe′s electricity heating and transport systems with transformative EU benchmarks for 2030 to meet that longer-term goal. CO2 emissions have declined significantly in the EU electricity subsystem over the past few decades. This presents an important opportunity to decarbonise rapidly in the near future and to roll out electrification to other sectors while strengthening energy independence security and competitiveness for all EU countries. Through accelerated gains in energy and resource efficiency and the alignment of Member States′ efforts within a more coherent EU energy system the rapid electrification of buildings transport and industry can greatly reduce Europe′s reliance on foreign fossil fuels and unlock critical progress in heating and transport. Over the past five years EU policy frameworks for climate mitigation and energy system transformation have become far more coherent and complete. Infrastructure security and resilience have been bolstered through integrated climate and energy planning in tandem with national and cross-border efforts to ensure sound policy implementation. It is now critical that decision-makers translate objectives and priorities for the energy system transition into actionable measures. This includes crafting fiscal strategies to finance key upfront infrastructure investments; distributing the cost of capital proportionally to not overburden taxpayers; aligning taxation pricing and information signals across the whole energy system; and regularly monitoring and evaluating performance to recalibrate policies when needed.
Effect of Injection Timing on Gas Jet Developments in a Hydrogen Low-pressure Direct-injection Spark-ignition Engine
Sep 2025
Publication
Injection timing in low-pressure hydrogen direct injection (H2LPDI) engines plays a critical role in optimising gas jet structure and mixture formation due to the complex and transient nature of ambient air flow and density inside the cylinder. This study systematically investigates the macroscopic characteristics of gas jet development at five distinct injection timings from 210 to 120 ◦CA bTDC with the intake valve closure (IVC) as a reference point in a motored inline four-cylinder spark-ignition engine at 2000 rpm and 160 Nm load using low-pressure injection of 3.5 MPa. Optical access was made with two endoscopes: one for high-speed imaging and the other for laser insertion to realise laser shadowgraph imaging of the gas jet delivered using a side-mounted outwardopening pintle nozzle injector. The experimental results reveal spatial and temporal variations in jet morphology penetration spreading angle and mixture dispersion as a function of injection timing. Pre-IVC injection (210 ◦CA bTDC) produced a narrow mean cone angle of ~40◦ and the highest penetration-rate proxy (0.49) whereas postIVC injection (120 ◦CA bTDC) retained a wider ~53◦ cone yet reduced the penetration rate to 0.28 while increasing the sheet-based mixing index from − 0.084 to − 0.106. Pre-IVC injection occurring under low ambient pressure and with active intake airflow was found to produce elongated jets with enhanced penetration and mixing rates though accompanied by substantial cyclic variations. Conversely post-IVC injection was strongly influenced by a fully developed tumble flow which redirected the jet trajectory towards the pent-roof and facilitated mixing through increased turbulence. However the elevated air density constrained the jet penetration. At-IVC injection resulted in a more uniform and stable jet structure. However the lack of convective flow constrained the overall mixing effectiveness. Quantitative analysis of jet spreading angle pixel intensity gradient and centroid movement using 100 consecutive cycles confirms the critical role of injection timing in shaping the gas jet development as suggested by the images.
Harnessing Wind for Hydrogen: Comparative MCDM-GIS Assessment of Optimal Plant Locations
Jul 2025
Publication
This research aimed to perform an in-depth comparative analysis of MCDM methods utilizing ArcGIS Pro 3.0.2 to identify the most suitable sites for wind-powered hydrogen production plants in Erbil Governorate Iraq. VIKOR TOPSIS SAW and Weighted Overlay techniques were implemented and applied to evaluate various criteria. A comparative analysis determined that VIKOR had the highest consistency and robustness making it the most suitable approach for selecting a site for windpowered hydrogen facilities. Spatial analysis showed that the southern and southwestern regions of Erbil Governorate were the most favourable areas for hydrogen generation. Wind turbine technical feasibility assessments identified the E112/4500 and V126e3.45 turbine models as the most efficient for these regions with high annual hydrogen production. The spatial configuration including the optimal turbine spacing had a significant effect on the capacity and production potential. ArcPro integration with MCDM significantly enhanced spatial analysis providing high-resolution data processing and advanced visualization capabilities.
Flexible Economic Energy Management Including Environmental Indices in Heat and Electrical Microgrids Considering Heat Pump with Renewable and Storage Systems
Oct 2025
Publication
This study discusses energy management in thermal and electrical microgrids while taking heat pumps renewable sources thermal and hydrogen storages into account. The weighted total of the operating cost grid emissions level voltage and temperature deviation function and other factors makes up the objective function of the suggested method. The restrictions include the operationflexibility model of resources and storages micro-grid flexibility limits and optimum power flow equations. Point Estimation Method is used in this work to simulate load energy price and renewable phenomenon uncertainty. A fuzzy decision-making methodology is used to arrive at a compromise solution that satisfies network operators’ operational environmental and financial goals. The innovations of this paper include energy management of various smart microgrids simultaneous modeling of several indicators especially flexibility investigation of optimal performance of resources and storage devices and modeling of uncertainty considering low computational time and an accurate flexibility model. Numerical findings indicate that the fuzzy decision-making approach has the capability to reach a compromise point in which the objective functions approach their minimum values. The integration of the proposed uncertainty modeling with precise flexibility modeling results in a reduction in computational time when compared to stochastic optimization based on scenarios. For the compromise point and uncertainty modeling with PEM by efficiently managing resources and thermal and hydrogen storages scheme is capable of attaining high flexibility conditions. Compared to load flow studies the approach can enhance the operational environmental and economic conditions of smart microgrids by approximately 33–57% 68% and 33–68% respectively under these circumstances.
Research on Hydrogen Leakage Risk Control Methods in Deck Compartments of Hydrogen Fuel Cell-Powered Ships Based on CFD Simulation and Ventilation Optimization
Oct 2025
Publication
Hydrogen fuel cell vessels represent a vital direction for green shipping but the risk of large-scale hydrogen leakage and diffusion in their enclosed compartments is particularly prominent. To enhance safety a simplified three-dimensional model of the deck-level cabins of the “Water-Go-Round” passenger ship was established using SolidWorks (2023) software. Based on a hydrogen leakage and diffusion model the effects of leakage location leakage aperture and initial ambient temperature on the diffusion patterns and distribution of hydrogen within the cabins were investigated using FLUENT software. The results show that leak location significantly affects diffusion direction with hydrogen leaking from the compartment ceiling diffusing horizontally much faster than from the floor. When leakage occurs at the compartment ceiling hydrogen can reach a maximum horizontal diffusion distance of up to 5.04 m within 540 s; the larger the leak aperture the faster the diffusion with a 10 mm aperture exhibiting a 40% larger diffusion range than a 6 mm aperture at 720 s. The study provides a theoretical basis for the safety design and risk prevention of hydrogen fuel cell vessels.
Preliminary Design of Regional Aircraft—Integration of a Fuel Cell-Electric Energy Network in SUAVE
Mar 2025
Publication
To enable climate-neutral aviation improving the energy efficiency of aircraft is essential. The research project Synergies of Highly Integrated Transport Aircraft investigates cross-disciplinary synergies in aircraft and propulsion technologies to achieve energy savings. This study examines a fuel cell electric powered configuration with distributed electric propulsion. For this a reverse-engineered ATR 72-500 serves as a reference model for calibrating the methods and ensuring accurate performance modeling. A baseline configuration featuring a state-of-the-art turboprop engine with the same entry-into-service is also introduced for a meaningful performance comparison. The analysis uses an enhanced version of the Stanford University Aerospace Vehicle Environment (SUAVE) a Python-based aircraft design environment that allows for novel energy network architectures. This paper details the preliminary aircraft design process including calibration presents the resulting aircraft configurations and examines the integration of a fuel cell-electric energy network. The results provide a foundation for higher fidelity studies and performance comparisons offering insights into the trade-offs associated with hydrogen-based propulsion systems. All fundamental equations and methodologies are explicitly presented ensuring transparency clarity and reproducibility. This comprehensive disclosure allows the broader scientific community to utilize and refine these findings facilitating further progress in hydrogen-powered aviation technologies.
Case Study of a Greenfield Blue Hydrogen Plant: A Comparative Analysis of Production Methods
Jun 2025
Publication
Blue hydrogen is a key pathway for reducing greenhouse gas emissions while utilizing natural gas with carbon capture and storage (CCS). This study conducts a techno-economic and environmental analysis of a greenfield blue hydrogen plant in Saskatchewan Canada integrating both SMR and ATR technologies. Unlike previous studies that focus mainly on production units this research includes all process and utility systems such as H2 and CO2 compression air separation refrigeration co-generation and gas dehydration. Aspen HYSYS simulations revealed ATR’s energy demand is 10% lower than that of SMR. The hydrogen production cost was USD 3.28/kg for ATR and USD 3.33/kg for SMR while a separate study estimated a USD 2.2/kg cost for design without utilities highlighting the impact of indirect costs. Environmental analysis showed ATR’s lower Global Warming Potential (GWP) compared to SMR reducing its carbon footprint. The results signified the role of utility integration site conditions and process selection in optimizing energy efficiency costs and sustainability.
A Review of Green Hydrogen Technologies and Their Role in Enabling Sustainable Energy Access in Remote and Off-Grid Areas Within Sub-Saharan Africa
Sep 2025
Publication
Electricity access deficits remain acute in Sub-Saharan Africa (SSA) where more than 600 million people lack reliable supply. Green hydrogen produced through renewablepowered electrolysis is increasingly recognized as a transformative energy carrier for decentralized systems due to its capacity for long-duration storage sector coupling and near-zero carbon emissions. This review adheres strictly to the PRISMA 2020 methodology examining 190 records and synthesizing 80 peer-reviewed articles and industry reports released from 2010 to 2025. The review covers hydrogen production processes hybrid renewable integration techno-economic analysis environmental compromises global feasibility and enabling policy incentives. The findings show that Alkaline (AEL) and PEM electrolyzers are immediately suitable for off-grid scenarios whereas Solid Oxide (SOEC) and Anion Exchange Membrane (AEM) electrolyzers present high potential for future deployment. For Sub-Saharan Africa (SSA) the levelized costs of hydrogen (LCOH) are in the range of EUR5.0–7.7/kg. Nonetheless estimates from the learning curve indicate that these costs could fall to between EUR1.0 and EUR1.5 per kg by 2050 assuming there is (i) continued public support for the technology innovation (ii) appropriate flexible and predictable regulation (iii) increased demand for hydrogen and (iv) a stable and long-term policy framework. Environmental life-cycle assessments indicate that emissions are nearly zero but they also highlight serious concerns regarding freshwater usage land occupation and dependence on platinum group metals. Namibia South Africa and Kenya exhibit considerable promise in the early stages of development while Niger demonstrates the feasibility of deploying modular community-scale systems in challenging conditions. The study concludes that green hydrogen cannot be treated as an integrated solution but needs to be regarded as part of blended off-grid systems. To improve its role targeted material innovation blended finance and policies bridging export-oriented applications to community-scale access must be established. It will then be feasible to ensure that hydrogen
Operational Optimization of Electricity–Hydrogen Coupling Systems Based on Reversible Solid Oxide Cells
Sep 2025
Publication
To effectively address the issues of curtailed wind and photovoltaic (PV) power caused by the high proportion of renewable energy integration and to promote the clean and lowcarbon transformation of the energy system this paper proposes a “chemical–mechanical” dual-pathway synergistic mechanism for the reversible solid oxide cell (RSOC) and flywheel energy storage system (FESS) electricity–hydrogen hybrid system. This mechanism aims to address both short-term and long-term energy storage fluctuations thereby minimizing economic costs and curtailed wind and PV power. This synergistic mechanism is applied to regulate system operations under varying wind and PV power output and electricity–hydrogen load fluctuations across different seasons thereby enhancing the power generation system’s ability to integrate wind and PV energy. An economic operation model is then established with the objective of minimizing the economic costs of the electricity–hydrogen hybrid system incorporating RSOC and FESS. Finally taking a large-scale new energy industrial park in the northwest region as an example case studies of different schemes were conducted on the MATLAB platform. Simulation results demonstrate that the reversible solid oxide cell (RSOC) system—integrated with a FESS and operating under the dual-path coordination mechanism—achieves a 14.32% reduction in wind and solar curtailment costs and a 1.16% decrease in total system costs. Furthermore this hybrid system exhibits excellent adaptability to the dynamic fluctuations in electricity– hydrogen energy demand which is accompanied by a 5.41% reduction in the output of gas turbine units. Notably it also maintains strong adaptability under extreme weather conditions with particular effectiveness in scenarios characterized by PV power shortage.
Sustainable Transition Pathways for Steel Manufacturing: Low-Carbon Steelmaking Technologies in Enterprises
Jun 2025
Publication
Amid escalating global climate crises and the urgent imperative to meet the Paris Agreement’s carbon neutrality targets the steel industry—a leading contributor to global greenhouse gas emissions—confronts unprecedented challenges in driving sustainable industrial transformation through innovative low-carbon steelmaking technologies. This paper examines decarbonization technologies across three stages (source process and end-of-pipe) for two dominant steel production routes: the long process (BF-BOF) and the short process (EAF). For the BF-BOF route carbon reduction at the source stage is achieved through high-proportion pellet charging in the blast furnace and high scrap ratio utilization; at the process stage carbon control is optimized via bottom-blowing O2-CO2-CaO composite injection in the converter; and at the end-of-pipe stage CO2 recycling and carbon capture are employed to achieve deep decarbonization. In contrast the EAF route establishes a low-carbon production system by relying on green and efficient electric arc furnaces and hydrogen-based shaft furnaces. At the source stage energy consumption is reduced through the use of green electricity and advanced equipment; during the process stage precision smelting is realized through intelligent control systems; and at the end-of-pipe stage a closed-loop is achieved by combining cascade waste heat recovery and steel slag resource utilization. Across both process routes hydrogen-based direct reduction and green power-driven EAF technology demonstrate significant emission reduction potential providing key technical support for the low-carbon transformation of the steel industry. Comparative analysis of industrial applications reveals varying emission reduction efficiencies economic viability and implementation challenges across different technical pathways. The study concludes that deep decarbonization of the steel industry requires coordinated policy incentives technological innovation and industrial chain collaboration. Accelerating large-scale adoption of low-carbon metallurgical technologies through these synergistic efforts will drive the global steel sector toward sustainable development goals. This study provides a systematic evaluation of current low-carbon steelmaking technologies and outlines practical implementation strategies contributing to the industry’s decarbonization efforts.
Optimization Framework for Efficient and Robust Renewable Energy Hub Operation
Oct 2025
Publication
This research proposes an advanced optimization framework for renewable energy hubs within integrated electrical and thermal networks aimed at improving energy management. The motivation stems from the need for a more flexible and efficient solution that addresses the variability of renewable energy sources such as wind and bio-waste units while integrating storage solutions like hydrogen and thermal systems. The hypothesis is that combining a market-clearing price model with robust decision-making frameworks can optimize both economic viability and operational efficiency. The methodology adopts a two-tier optimization approach: the upper tier maximizes hub profits and the lower tier minimizes operational costs through a market-clearing price model. The study also incorporates a robust optimization model that accounts for decision-dependent uncertainties with a novel class of polyhedral uncertainty sets used for improved decision-making. Numerical results from case studies demonstrate that the proposed method increases the objective function by approximately 3% and achieves a 25% faster solution time compared to the Benders decomposition approach. These findings support the conclusion that the proposed framework enhances both flexibility and economic performance of energy hubs offering a viable solution for modern energy systems.
Techno-Economic Environmental Risk Analysis (TERA) in Hydrogen Farms
Sep 2025
Publication
This study presents a techno-economic environmental risk analysis (TERA) of large-scale green hydrogen production using Alkaline Water Electrolysis (AWE) and Proton Exchange Membrane (PEM) systems. The analysis integrates commercial data market insights and academic forecasts to capture variability in capital expenditure (CAPEX) efficiency electricity cost and capacity factor. Using Libya as a case study 81 scenarios were modelled for each technology to assess financial and operational trade-offs. For AWE CAPEX is projected between $311 billion and $905.6 billion for 519 GW (gigawatts) of installed capacity equivalent to 600–1745 $/kW. PEM systems show a wider range of $612 billion to $1020 billion for 510 GW translating to 1200–2000 $/kW. Results indicate that AWE while requiring greater land use provides significant cost advantages due to lower capital intensity and scalability. In contrast PEM systems offer compact design and operational flexibility but at substantially higher costs. The five most economical scenarios for both technologies consistently feature low CAPEX and high efficiency while sensitivity analyses confirm these two parameters as the dominant cost drivers. The findings emphasise that technology choice should reflect context-specific priorities such as land availability budget and performance needs. This study provides actionable guidance for policymakers and investors developing cost-effective hydrogen infrastructure in emerging green energy markets.
Mitigating Microbial Artifacts in Laboratory Research on Underground Hydrogen Storage
Jul 2025
Publication
The global energy sector is aiming to substantially reduce CO2 emissions to meet the UN climate goals. Among the proposed strategies underground storage solutions such as radioactive disposal CO2 NH3 and underground H2 storage (UHS) have emerged as promising options for mitigating anthropogenic emissions. These approaches require rigorous research and development (R&D) often involving laboratory-scale experiments to establish their feasibility before being scaled up to pilot plant operations. Microorganisms which are ubiquitous in laboratory environments can significantly influence geochemical reactions under variable experimental conditions of porous media and a salt cavern. We have selected a consortium composed of Bacillus sp. Enterobacter sp. and Cronobacter sp. bacteria which are typically present in the laboratory environment. These microorganisms can contaminate the rock sample and develop experimental artifacts in UHS experiments. Hence it is pivotal to sterilize the rock prior to conduct experimental research related to effects of microorganisms in the porous media and the salt cavern for the investigation of UHS. This study investigated the efficacy of various disinfection and sterilization methods including ultraviolet irradiation autoclaving oven heating ethanol treatments and gamma irradiation in removing the microorganisms from silica sand. Additionally the consideration of their effects on mineral properties are reviewed. A total of 567 vials each filled with 9 mL of acid-producing bacteria (APB) media were used to test killing efficacy of the cleaning methods. We conducted serial dilutions up to 10−8 and repeated them three times to determine whether any deviation occurred. Our findings revealed that gamma irradiation and autoclaving were the most effective techniques for eradicating microbial contaminants achieving sterilization without significantly altering the mineral characteristics. These findings underscore the necessity of robust cleaning protocols in hydrogeochemical research to ensure reliable reproducible data particularly in future studies where microbial contamination could induce artifacts in laboratory research.
Underground Hydrogen Storage Suitability Index: A Geological Tool for Evaluating and Ranking Storage Sites
Jun 2025
Publication
Underground Hydrogen Storage (UHS) is a promising solution to maximize the use of hydrogen as an energy carrier. This study presents a standardized methodology for assessing UHS quality by introducing the Underground Hydrogen Storage Suitability Index (UHSSI) which integrates three sub-indices: the Caprock Potential Index (CPI) the Reservoir Quality Index (RQI) and the Site Potential Index (SPI). Parameters such as porosity permeability lithology caprock thickness depth temperature and salinity are evaluated and ranked from 0 (unsuitable) to 5 (excellent). The methodology was validated using data from six worldwide sites including salt caverns and aquifers. Sites like Moss Bluff Clemens Dome and Spindletop (USA) scored highly while Teesside (UK) Lobodice (Czech Republic) and Beynes (France) were classified as unsuitable due to shallow depths and microbial activity. A software tool the UHSSI Calculator was developed to automate site evaluations. This approach offers a cost-effective tool for preliminary screening and supports the safer development of UHS.
Exploring the Gas Permeability of Type IV Hydrogen Storage Cylinder Liners: Research and Applications
Jul 2025
Publication
As hydrogen fuel cell vehicles gain momentum as crucial zero-emission transportation solutions the urgency to address hydrogen permeability through the polymer liner becomes paramount for ensuring the safety efficiency and longevity of Type IV hydrogen storage tanks. This paper synthesizes existing research findings analyzes the influence of different materials and structures on gas permeability elucidates the dissolution and diffusion mechanisms of hydrogen in plastic liners and discusses their engineering applications. We focus on measurement methods influencing factors and improvement strategies for liner gas permeability. Additionally we explore the prospects of Type IV hydrogen storage tanks in fields such as automotive aerospace and energy storage industries. Through this comprehensive review of liner gas permeability critical insights are provided to guide the development of efficient and safe hydrogen storage and transportation systems. These insights are vital for advancing the widespread application of hydrogen energy technology and fostering sustainable energy development significantly contributing to efforts aimed at enhancing the performance and safety of Type IV hydrogen storage tanks.
Global Warming Impacts of the Transition from Fossil Fuel Conversion and Infrastructure to Hydrogen
Jul 2025
Publication
Emissions from fossil fuel extraction conveyance and combustion are among the most significant causes of air pollution and climate change leading to arguably the most acute crises mankind has ever faced. The transition from fossil fuel-based energy systems to hydrogen is essential for meeting a portion of global decarbonization goals. Hydrogen offers certain features such as high gravimetric energy density that is required for heavy-duty shipping and freight applications and chemical properties such as high temperature combustion and reducing capabilities that are required for steel chemicals and fertilizer industries. However hydrogen that leaks has indirect climate implications stemming from atmospheric interactions that are emerging as a critical area of research. This study reviews recent literature on hydrogen’s global warming potential (GWP) highlighting its indirect contributions to radiative forcing via methane’s extended atmospheric lifetime tropospheric ozone formation and stratospheric water vapor formation. The 100-year GWP (GWP100) of hydrogen estimated to range between 8 and 12.8 underscores the need to minimize leakage throughout the hydrogen supply chain to maximize the climate benefits of using hydrogen instead of fossil fuels. Comparisons with methane reveal hydrogen’s shorter atmospheric lifetime and reduced long-term warming effects establishing it as a viable substitute for fossil fuels in sectors such as steel cement and heavy-duty transport. The analysis emphasizes the importance of accurate leakage assessments robust policy frameworks and advanced infrastructure to ensure hydrogen realizes its potential as a sustainable energy carrier that displaces the use of fossil fuels. Future research is recommended to refine climate models better understand atmospheric sinks and hydrogen leakage phenomena and develop effective strategies to minimize hydrogen emissions paving the way for environmentally sound use of hydrogen.
Injection Strategies in a Hydrogen SI Engine: Parameter Selection and Comparative Analysis
Oct 2025
Publication
Injection strategies play a crucial role in determining hydrogen engine performance. The diversity of these strategies and the limited number of comparative studies highlight the need for further investigation. This study focuses on the analysis parameter selection and comparison of single early and late direct injection single injection with ignition occurring during injection (the so-called jet-guided operation) and dual injection in a hydrogen spark-ignition engine. The applicability and effectiveness of these injection strategies are assessed using contour maps with ignition timing and start of injection as coordinates representing equal levels of key engine parameters. Based on this approach injection and ignition settings are selected for a range of engine operating modes. Simulations of engine performance under different load conditions are carried out using the selected parameters for each strategy. The results indicate that the highest indicated thermal efficiencies are achieved with single late injection while the lowest occur with dual injection. At the same time both dual injection and jet-guided operation provide advantages in terms of knock suppression peak pressure reduction and reduced nitrogen oxide emissions.
Multi-Objective Optimal Energy Management Strategy for Grid-Interactive Hydrogen Refueling Stations in Rural Areas
Mar 2025
Publication
The transportation sector is a significant contributor to global carbon emissions thus necessitating a transition toward renewable energy sources (RESs) and electric vehicles (EVs). Among EV technologies fuel-cell EVs (FCEVs) offer distinct advantages in terms of refueling time and operational efficiency thus rendering them a promising solution for sustainable transportation. Nevertheless the integration of FCEVs in rural areas poses challenges due to the limited availability of refueling infrastructure and constraints in energy access. In order to address these challenges this study proposes a multi-objective energy management model for a hydrogen refueling station (HRS) integrated with RESs a battery storage system an electrolyzer (EL) a fuel cell (FC) and a hydrogen tank serving diverse FCEVs in rural areas. The model formulated using mixed-integer linear programming (MILP) optimizes station operations to maximize both cost and load factor performance. Additionally bi-directional trading with the power grid and hydrogen network enhances energy flexibility and grid stability enabling a more resilient and self-sufficient energy system. To the best of the authors’ knowledge this study is the first in the literature to present a multi-objective optimal management approach for grid-interactive renewablesupported HRSs serving hydrogen-powered vehicles in rural areas. The simulation results demonstrate that RES integration improves economic feasibility by reducing costs and increasing financial gains while maximizing the load factor enhances efficiency cost-driven strategies that may impact stability. The impact of the EL on cost is more significant while RES capacity has a relatively smaller effect on cost. However its influence on the load factor is substantial. The optimization of RES-supported hydrogen production has been demonstrated to reduce external dependency thereby enabling surplus trading and increasing financial gains to the tune of USD 587.83. Furthermore the system enhances sustainability by eliminating gasoline consumption and significantly reducing carbon emissions thus supporting the transition to a cleaner and more efficient transportation ecosystem.
Hydrogen Generation through Solar Photocatalytic Processes: A Review of the Configuration and the Properties of Effective Metal-Based Semiconductor Nanomaterials
Oct 2017
Publication
Photocatalytic water splitting and organic reforming based on nano-sized composites are gaining increasing interest due to the possibility of generating hydrogen by employing solar energy with low environmental impact. Although great efforts in developing materials ensuring high specific photoactivity have been recently recorded in the literature survey the solar-to-hydrogen energy conversion efficiencies are currently still far from meeting the minimum requirements for real solar applications. This review aims at reporting the most significant results recently collected in the field of hydrogen generation through photocatalytic water splitting and organic reforming with specific focus on metal-based semiconductor nanomaterials (e.g. metal oxides metal (oxy)nitrides and metal (oxy)sulfides) used as photocatalysts under UVA or visible light irradiation. Recent developments for improving the photoefficiency for hydrogen generation of most used metal-based composites are pointed out. The main synthesis and operating variables affecting photocatalytic water splitting and organic reforming over metal-based nanocomposites are critically evaluated.
A Proposal of Hydrogen Safety Technology for Decommissioning of the Fukushima Daiichi Nuclear Power Station
Mar 2025
Publication
The safe removal transportation and long-term storage of fuel debris in the decommissioning of Fukushima Daiichi is the biggest challenge facing Japan. In the nuclear power field passive autocatalytic recombiners (PARs) have become established as a technology to prevent hydrogen explosions inside the containment vessel. To utilize PAR as a measure to reduce the concentration of hydrogen generated in the fuel debris storage canister which is currently an issue it is required to perform in a sealed environment with high doses of radiation low temperature and high humidity and there are many challenges different from conventional PAR. A honeycombshaped catalyst based on automotive catalyst technology has been newly designed as a PAR and research has been conducted to solve unique problems such as high dose radiation low temperature high humidity coexistence of hydrogen and low oxygen and catalyst poisons. This paper summarizes the challenges of hydrogen generation in a sealed container the results of research and a guide to how to use the PAR for fuel debris storage canisters.
Net-Zero Backup Solutions for Green Ammonia Hubs Based on Hydrogen Power Generation
Jun 2025
Publication
This paper explores cleaner and techno-economically viable solutions to provide electricity heat and cooling using green hydrogen (H2) and green ammonia (NH3) across the entire decarbonized value chain. We propose integrating a 100% hydrogen-fueled internal combustion engine (e.g. Jenbacher JMS 420) as a stationary backup solution and comparing its performance with other backup technologies. While electrochemical storage systems or battery energy storage systems (BESSs) offer fast and reliable short-term energy buffering they lack flexibility in relocation and typically involve higher costs for extended backup durations. Through five case studies we highlight that renewable-based energy supply requires additional capacity to bridge longer periods of undersupply. Our results indicate that for cost reasons battery–electric solutions alone are not economically feasible for longterm backup. Instead a more effective system combines both battery and hydrogen storage where batteries address daily fluctuations and hydrogen engines handle seasonal surpluses. Despite lower overall efficiency gas engines offer favorable investment and operating costs in backup applications with low annual operating hours. Furthermore the inherent fuel flexibility of combustion engines eventually will allow green ammonia-based backup systems particularly as advancements in small-scale thermal cracking become commercially available. Future studies will address CO2 credit recognition carbon taxes and regulatory constraints in developing more effective dispatch and master-planning solutions.
Modeling Porosity Distribution Strategies in PEM Water Electrolyzers: A Comparative Analytical and Numerical Study
Jun 2025
Publication
Proton exchange membrane water electrolyzers (PEMWEs) are a promising technology for green hydrogen production. However the adoption of PEMWE-based hydrogen production systems remains limited due to several challenges including high material costs limited performance and durability and difficulties in scaling the technology. Computational modeling serves as a powerful tool to address these challenges by optimizing system design improving material performance and reducing overall costs thereby accelerating the commercial rollout of PEMWE technology. Despite this conventional models often oversimplify key components such as porous transport and catalyst layers by assuming constant porosity and neglecting the spatial heterogeneity found in real electrodes. This simplification can significantly impact the accuracy of performance predictions and the overall efficiency of electrolyzers. This study develops a mathematical framework for modeling variable porosity distributions—including constant linearly graded and stepwise profiles—and derives analytical expressions for permeability effective diffusivity and electrical conductivity. These functions are integrated into a three-dimensional multi-domain COMSOL simulation to assess their impact on electrochemical performance and transport behavior. The results reveal that although porosity variations have minimal effect on polarization at low voltages they significantly influence internal pressure species distribution and gas evacuation at higher loads. A notable finding is that reversing stepwise porosity—placing high porosity near the membrane rather than the channel—can alleviate oxygen accumulation and improve current density. A multi-factor comparison highlights this reversed configuration as the most favorable among the tested strategies. The proposed modeling approach effectively connects porous media theory and systemlevel electrochemical analysis offering a flexible platform for the future design of porous electrodes in PEMWE and other energy conversion systems.
Who Is in and How? A Comprehensive Study on Stakeholder Perspectives in the Green Hydrogen Sector in Luxembourg
Oct 2025
Publication
Green hydrogen has the potential to contribute to the decarbonization of the fossil fuel industry and its development is expected to increase in the coming years. The social dynamics among the various actors in the green hydrogen sector are studied to understand their public perception. Using the technological innovation system research approach for the stakeholder analysis and the qualitative thematic analysis method for the interviews with experts this study presents an overview of the actors in the green hydrogen sector and their relations in Luxembourg. As a central European country with strategic political and geographic relevance Luxembourg offers a timely case for analyzing public perception before the large-scale implementation of green hydrogen. Observing this early stage allows for future comparative insights as the national hydrogen strategy progresses. Results show high expectations for green hydrogen in mobility and industry but concerns persist over infrastructure costs safety and public awareness. Regional stakeholders demonstrate a strong willingness to collaborate recognizing that local public acceptance still requires effort particularly in areas such as clear and inclusive communication sharing knowledge and fostering trust. These findings provide practical insights for stakeholder engagement strategies and theoretical contributions to the study of social dynamics in sustainability transitions.
Socio-political Determinants of Public Acceptance of Green Hydrogen
Mar 2025
Publication
Green hydrogen produced through renewable energy sources is emerging as a pivotal element in global energy transitions. Despite its potential public acceptance remains a critical barrier to its large-scale implementation. This study aims to identify the socio-political and demographic determinants of public acceptance of green hydrogen. Using advanced variable selection methods including ridge lasso and elastic net regression we analyzed perceptions of climate change trust in government policies and demographic characteristics. The findings reveal that individuals prioritizing climate change over economic growth perceiving its impacts as severe and recognizing it as South Korea’s most pressing issue are more likely to accept green hydrogen. Trust in the government’s climate change response also emerged as a key factor. Demographic characteristics such as younger age higher income advanced education smaller family size and conservative political ideology were significantly associated with greater acceptance. These results highlight the importance of raising public awareness about the urgency of climate change and enhancing trust in government policies to promote societal acceptance of green hydrogen. Policymakers should consider these factors when developing strategies to advance the adoption of green hydrogen technologies and foster sustainable energy transitions.
Machine Learning-driven Stochastic Bidding for Hydrogen Refueling Station-integrated Virtual Power Plants in Energy Market
Aug 2025
Publication
Virtual power plants (VPPs) are gaining significance in the energy sector due to their capacity to aggregate distributed energy resources (DERs) and optimize energy trading. However their effectiveness largely depends on accurately modeling the uncertain parameters influencing optimal bidding strategies. This paper proposes a deep learning-based forecasting method to predict these uncertain parameters including solar irradiation temperature wind speed market prices and load demand. A stochastic programming approach is introduced to mitigate forecasting errors and enhance accuracy. Additionally this research assesses the flexibility of VPPs by mapping the flexible regions to determine their operational capabilities in response to market dynamics. The study also incorporates power-to‑hydrogen (P2H) and hydrogen-to-power (H2P) conversion processes to facilitate the integration of hydrogen fuel cell vehicles (HFCVs) into VPPs enhancing both technical and economic aspects. A network-aware VPP connected to generation resources storage facilities demand response programming (DRP) vehicle-to-grid technology (V2G) P2H and H2P is used to evaluate the proposed method. The problem is formulated as a convex model and solved using the GUROBI optimizer. Results indicate that a hydrogen refueling station can increase profits by approximately 49 % compared to the base case of directly selling surplus generation from renewable energy sources (RESs) to the market and profits can further increase to roughly 86 % when other DERs are incorporated alongside the hydrogen refueling station.
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