Publications
Ammonia Decomposition and Hydrogen Production via Novel FeCoNiCuMnO High-entropy Ceramic Catalysts
Oct 2025
Publication
Ammonia (NH3) decomposition offers a pathway for water purification and green hydrogen production yet conventional catalysts often suffer from poor stability due to agglomeration. This study presents a novel (FeCoNiCuMn)O high-entropy ceramic (HEC) catalyst synthesized via fast-moving bed pyrolysis (FMBP) which prevents aggregation and enhances catalytic performance. The HEC catalyst applied as an anode in electrochemical oxidation (EO) demonstrated a uniform spinel (AB2O4) structure confirmed by XRD XRF and ICP-OES. Electronic structure characterization using UPS and LEIPS revealed a bandgap of 4.722 eV with EVBM and ECBM values facilitating redox reactions. Under 9 V and 50 mA/cm² current density the HEC electrode achieved 99% ammonia decomposition within 90 min and retained over 90% efficiency after four cycles. Surface analysis by XPS and HAXPES indicated oxidation state variations confirming catalyst activity and stability. Gas chromatography identified H2 N2 and O2 as the main products with ~64.7% Faradaic efficiency for H2 classifying it as green hydrogen. This dual-function approach highlights the (FeCoNiCuMn)O HEC anode as a promising and sustainable solution for wastewater treatment and hydrogen production.
Current Developments on MIL-based Metal-organic Frameworks for Photocatalytic Hydrogen Production
Sep 2025
Publication
The escalating global energy demand has intensified research into sustainable hydrogen production particularly through water splitting. A highly promising avenue involves photocatalytic water splitting which leverages readily available earth-abundant materials to generate clean hydrogen from water using only renewable energy sources. Among the various catalytic materials investigated metal-organic frameworks (MOFs) have recently attracted considerable interest. Their tunable porosity high crystallinity as well as the customisable molecular structures position them as a transformative class of catalysts for efficient and sustainable photocatalytic hydrogen generation. This review examines MOFs detailing their structural characteristics unique properties and diverse synthetic routes. The discussion extends to the various composite materials that can be derived from MOFs with particular emphasis on their application in photocatalytic hydrogen production via water splitting. Furthermore the review identifies current challenges hindering MOF implementation and proposes modification strategies to overcome these limitations. The concluding section summarises the presented information and future perspectives on the continued development of MOF composites for enhanced photocatalytic hydrogen production from water.
Techno-economic Optimization of Renewable Hydrogen Infrastructure via AI-based Dynamic Pricing
Aug 2025
Publication
This study presents a techno-economic optimization of hydrogen production using hybrid wind-solar systems across six Australian cities highlighting Australia’s green hydrogen potential. A hybrid PVwind-electrolyzer-hydrogen tank (PV-WT-EL-HT) system demonstrated superior performance with Perth achieving the lowest Levelized Cost of Hydrogen (LCOH) at $0.582/kg Net Present Cost (NPC) of $27.5k and Levelized Cost of Electricity (LCOE) of $0.0166/kWh. Perth also showed the highest return on investment present worth and annual worth making it the preferred project site. All locations maintained a 100% renewable fraction proving the viability of fully decarbonized hydrogen production. Metaheuristic validation using nine algorithms showed the Mayfly Algorithm improved techno-economic metrics by 3–8% over HOMER Pro models. The Gray Wolf and Whale Optimization Algorithms enhanced system stability under wind-dominant conditions. Sensitivity analysis revealed that blockchain-based dynamic pricing and reinforcement learning-driven demand response yielded 8–10% cost savings under ±15% demand variability. Nevertheless regional disparities persist; southern cities such as Hobart and Melbourne exhibited 20–30% higher LCOH due to reduced renewable resource availability while densely urbanized cities like Sydney presented optimization ceilings with minimal LCOH improvements despite algorithmic refinements. Investment in advanced materials (e.g. perovskite-VAWTs) and offshore platforms targeting hydrogen export markets is essential. Perth emerged as the optimal hub with hybrid PV/WT/B systems producing 200–250 MWh/ month of electricity and 200–250 kg/month of hydrogen supported by policy incentives. This work offers a blueprint for region-specific AI-augmented hydrogen systems to drive Australia’s hydrogen economy toward $2.10/kg by 2030.
TwinP2G: A Software Application for Optimal Power-to Gas Planning
Sep 2025
Publication
This paper presents TwinP2G a software application for optimal planning of investments in power-to-gas (PtG) systems. TwinP2G provides simulation and optimization services for the techno-economic analysis of user-customized energy networks. The core of TwinP2G is based on power flow simulation; however it supports energy sector coupling including electricity green hydrogen natural gas and synthetic methane. The framework provides a user-friendly user interface (UI) suitable for various user roles including data scientists and energy experts using visualizations and metrics on the assessed investments. An identity and access management mechanism also serves the security and authorization needs of the framework. Finally TwinP2G revolutionizes the concept of data availability and data sharing by granting its users access to distributed energy datasets available in the EnerShare Data Space. These data are available to TwinP2G users for conducting their experiments and extracting useful insights on optimal PtG investments for the energy grid.
Sequential System for Hydrogen and Methane Production from Sucrose Wastewater: Effects of Substrate Concentration and Addition of FE2+ Ions
Oct 2025
Publication
A two-stage system is used for hydrogen (H2) and methane (CH4) production from sucrose wastewater. The H2- producing reactor is operated at pH temperature (T) and hydraulic retention time (HRT) of 5.5 35 ◦C 24 h respectively. While operating conditions of 7–8 pH 35 ◦C T and 144 h HRT are used to conduct the CH4 production stage. The effects of two different parameters as sucrose concentration (5 10 and 20 g/L) and addition of ferrous ions (60 and 120 mg/L) are investigated. Both H2 and CH4 productions are increased at high sucrose concentrations. However the optimum H2 and CH4 yields of 163.2 mL-H2/g-sucrose and 211.8 mL-CH4/g-TVS are obtained at 5 g-sucrose/L. At 5 g-sucrose/L addition of Fe2+ increases the H2 yield to 192.5 and 176.2 mLH2/g-sucrose corresponding to 60 and 120 mg-Fe2+/L respectively. Higher removal efficiencies and total energy recovery are measured using the two-stage system than the single-stage reactor.
A Comprehensive Review of Green Hydrogen-based Hybrid Energy Systems: Technologies, Evaluation, and Process Safety
Aug 2025
Publication
The reliability and sustainability of multi-energy networks are increasingly critical in addressing modern energy demands and environmental concerns. Hydrogen-based hybrid energy systems can mitigate the challenges of renewable energy utilization such as intermittency grid stability and energy storage by integrating hydrogen generation and electricity storage from renewable sources such as solar and wind. Therefore this review offers a comprehensive evaluation of the environmental economic and technological aspects of green hydrogen-based hybrid energy systems particularly highlighting improvements in terms of the economics of fuel cell and electrolysis procedures. It also highlights new approaches such as hybrid energy management strategies and power-to-gas (PtG) conversion to enhance the system’s dependability and resilience. Analyzing the role of green hydrogen-based hybrid energy systems in supporting global climate goals and improving energy security underscores their high potential to make a significant contribution to carbon-neutral energy networks and provide policymakers with useful recommendations for developing guidelines. In addition the social aspect of hydrogen systems like energy equity and community engagement towards a hydrogen-based society provides reasons for the continued development of next-generation energy systems.
High-Performance Two-Stroke Opposed-Piston Hydrogen Engine: Numerical Study on Injection Strategies, Spark Positioning and Water Injection to Mitigate Pre-Ignition
Sep 2025
Publication
In the pursuit of zero-emission mobility hydrogen represents a promising fuel for internal combustion engines. However its low volumetric energy density poses challenges especially for high-performance applications where compactness and lightweight design are crucial. This study investigates the feasibility of an innovative hydrogen-fueled two-stroke opposed-piston (2S-OP) engine targeting a specific power of 130 kW/L and an indicated thermal efficiency above 40%. A detailed 3D-CFD analysis is conducted to evaluate mixture formation combustion behavior abnormal combustion and water injection as a mitigation strategy. Innovative ring-shaped multi-point injection systems with several designs are tested demonstrating the impact of injector channels’ orientation on the final mixture distribution. The combustion analysis shows that a dual-spark configuration ensures faster combustion compared to a single-spark system with a 27.5% reduction in 10% to 90% combustion duration. Pre-ignition is identified as the main limiting factor strongly linked to mixture stratification and high temperatures. To suppress it water injection is proposed. A 55% evaporation efficiency of the water mass injected lowers the in-cylinder temperature and delays pre-ignition onset. Overall the study provides key design guidelines for future high-performance hydrogen-fueled 2S-OP engines.
Sizing of Fuel Distribution and Thermopropulsion Systems for Liquid-Hydrogen-Powered Aircraft Using an MBSE Approach
Jun 2025
Publication
Hydrogen-powered aircraft constitute a transformative innovation in aviation motivated by the imperative for sustainable and environmentally friendly transportation solutions. This paper aims to concentrate on the design of hydrogen powertrains employing a system approach to propose representative design models for distribution and propulsion systems. Initially the requirements for powertrain design are formalized and a usecase-driven analysis is conducted to determine the functional and physical architectures. Subsequently for each component pertinent to preliminary design an analytical model is proposed for multidisciplinary analysis and optimization for powertrain sizing. A doublewall pipe model incorporating foam and vacuum multi-layer insulation was developed. The internal and outer pipes sizing were performed in accordance with standards for hydrogen piping design. Valves sizing is also considered in the present study following current standards and using data available in the literature. Furthermore models for booster pumps to compensate pressure drop and high-pressure pumps to elevate pressure at the combustion chamber entrance are proposed. Heat exchanger and evaporator models are also included and connected to a burning hydrogen engine in the sizing process. An optimal liner pipe diameter was identified which minimizes distribution systems weight. We also expect a reduction in engine length and weight while maintaining equivalent thrust.
Adaptive Robust Energy Management of Smart Grid with Renewable Integrated Energy System, Fuel Cell and Electric Vehicles Stations and Renewable Distributed Generation
Aug 2025
Publication
This study expresses energy scheduling in intelligent distribution grid with renewable resources charging stations and hydrogen stations for electric vehicles and integrated energy systems. In deterministic model objective function minimizes total operating energy losses and environmental costs of grid. Constraints are power flow equations network operating and voltage security limits operating model of renewable resources electric vehicle stations and integrated energy systems. Scheme includes uncertainties in load renewable resources charging and hydrogen stations and energy prices. Robust optimization uses to obtain an operation that is robust against the forecast error of the aforementioned uncertainties. Modeling electric vehicles station and aforementioned integrated energy systems considering economic operational and environmental objectives of network operator as objective function extracting a robust model of aforementioned uncertainties in order to extract a solution that is robust against the uncertainty prediction error and examining ability of energy management to improve voltage security of grid are among innovations of this paper. Numerical results obtained from various cases prove the aforementioned advantages and innovations. Energy management of resources charging and hydrogen stations and aforementioned integrated systems lead to scheme being robust against 35% of the prediction error of various uncertainties. In these conditions scheme has improved economic operational environmental and voltage security conditions by about 33.6% 7%- 37.4% 44.4% and 24.7% respectively compared to load flow studies. By applying optimal penalty price for energy losses and pollution pollution and energy losses in the network are reduced by about 45.15% and 34.1% respectively.
Thermodynamics Analysis of Generation of Green Hydrogen and Methanol through Carbon Dioxide Capture
Oct 2025
Publication
This extensive study delves into analyzing carbon dioxide (CO2)-capturing green hydrogen plant exploring its operation using multiple electrolysis techniques and examining their efficiency and impact on environment. The solar energy is used for the electrolysis to make hydrogen. Emitted CO2 from thermal power plants integrate with green hydrogen and produces methanol. It is a process crucial for mitigating environmental damage and fostering sustainable energy practices. The findings demonstrated that solid oxide electrolysis is the most effective process by which hydrogen can be produced with significant rate of 90 % efficiency. Moreover proton exchange membrane (PEM) becomes a viable and common method with an 80 % efficiency whereas the alkaline electrolysis has a moderate level of 63 % efficiency. Additionally it was noted that the importance of seasonal fluctuations where the capturing of CO2 is maximum in summer months and less in the winter is an important factor to consider in order to maximize the working of the plant and the allocation of resources.
Comprehensive Experimental Assessment of NOx Emissions in Swirling Diffusion Flames of Natural Gas-hydrogen Blends
Oct 2025
Publication
In the transformation process from fossil-fuel based to carbon-neutral combustion full or partial replacement of natural gas with hydrogen is considered in numerous industrial applications. As hydrogen flames yield significantly higher NOX emissions than natural gas flames understanding what factors influence these emissions in flames of natural gas/hydrogen blends is crucial for the retrofitting process. Our work is concerned with the simplest form of industrial retrofitting where hydrogen is injected into the natural gas line without any modifications to the burner construction while keeping the burner power constant. We provide quantifications of NOX emissions with respect to changes in hydrogen content (pure natural gas to 100% hydrogen) swirl number (S=0.6 to S=1.4) excess air ratio ( = 1 to =4.5) and air preheat (ambient air to 300 ◦C). The changes were determined in small steps and over a large range. The emission data is to be used in industrial CFD for both validation and tuning therefore Laser Doppler Velocimetry was used for precise determination of the burner inlet conditions. Key findings of the investigation include that for hydrogen flames the NOX emission index [mg/kWh] is 1.2 to 3 times larger than for pure natural gas flames at similar firing conditions. The steepest increase in NOX emissions occurs above 75% volume fraction of hydrogen in the fuel. For natural gas flames NOX emissions peak at 1.3 to 1.4 excess air while the maximum for hydrogen and natural gas/hydrogen blends lays at =1.6. NOX emissions decrease slightly as the swirl number increases but this effect is minor in comparison to the effects of hydrogen content excess air ratio and air temperature.
Innovative Sulfer-based Photocatalysts for Seawater Splitting: Synthesis Strategies, Engineering Advances, and Prospective Pathways for Sustainable Hydrogen Production
Oct 2025
Publication
While hydrogen production through pure water splitting remains a key focus in solar hydrogen research photocatalytic seawater splitting presents a more sustainable alternative better aligned with global development goals amid increasing freshwater scarcity. Nevertheless the deactivation of the photocatalyst by the corrosion of various ions present in seawater as well as the chloride ions’ redox side reaction limits the practical use of the photocatalytic seawater splitting process. In this context sulfur has emerged as a crucial component in photocatalytic composites for seawater splitting owing to its unique chemical properties. It acts as a chlorine-repulsive agent effectively suppressing chloride ion oxidation which mitigates corrosion enhances structural stability and significantly improves overall photocatalytic performance in saline environments. This review offers a thorough explanation of the basic ideas of solar-driven seawater splitting delves into various synthesis strategies and explores recent advancements in sulfur-based composites for efficient hydrogen generation using seawater. Optimizing synthesis techniques and incorporating strategies like doping cocatalyst and heterojunctions significantly enhance the performance of sulfur-based photocatalysts for seawater splitting. Future advances include integrating AI-guided material discovery sustainable use of industrial sulfur waste and precise control of sacrificial agents to ensure long-term efficiency and stability.
Effect of Hydrogen Injection Strategy on Combustion and Emissions of Ammonia-Hydrogen Sustainable Engines
Oct 2025
Publication
Driven by the global energy transition and the dual carbon goals developing low-carbon and zero-carbon alternative fuels has become a core issue for sustainable development in the internal combustion engine sector. Ammonia is a promising zero-carbon fuel with broad application prospects. However its inherent combustion characteristics including slow flame propagation high ignition energy and narrow flammable range limit its use in internal combustion engines necessitating the addition of auxiliary fuels. To address this issue this paper proposes a composite injection technology combining “ammonia duct injection + hydrogen cylinder direct injection.” This technology utilizes highly reactive hydrogen to promote ammonia combustion compensating for ammonia’s shortcomings and enabling efficient and smooth engine operation. This study based on bench testing investigated the effects of hydrogen direct injection timing (180 170 160 150 140◦ 130 120 ◦CA BTDC) hydrogen direct injection pressure (4 5 6 7 8 MPa) on the combustion and emissions of the ammonia–hydrogen engine. Under hydrogen direct injection timing and hydrogen direct injection pressure conditions the hydrogen mixture ratios are 10% 20% 30% 40% and 50% respectively. Test results indicate that hydrogen injection timing that is too early or too late prevents the formation of an optimal hydrogen layered state within the cylinder leading to prolonged flame development period and CA10-90. The peak HRR also exhibits a trend of first increasing and then decreasing as the hydrogen direct injection timing is delayed. Increasing the hydrogen direct injection pressure to 8 MPa enhances the initial kinetic energy of the hydrogen jet intensifies the gas flow within the cylinder and shortens the CA0-10 and CA10-90 respectively. Under five different hydrogen direct injection ratios the CA10- 90 is shortened by 9.71% 11.44% 13.29% 9.09% and 13.42% respectively improving the combustion stability of the ammonia–hydrogen engine.
Preliminary Feasibility Study of Using Hydrogen as a Fuel for an Aquaculture Vessel in Tasmania, Australia
Oct 2025
Publication
Decarbonising aquaculture support vessels is pivotal to reducing greenhouse gas (GHG) emissions across both the aquaculture and maritime sectors. This study evaluates the technical and economic feasibility of deploying hydrogen as a marine fuel for a 14.95 m net cleaning vessel (NCV) operating in Tasmania Australia. The analysis retains the vessel’s original layout and subdivision to enable a like-for-like comparison between conventional diesel and hydrogen-based systems. Two options are evaluated: (i) replacing both the main propulsion engines and auxiliary generator sets with hydrogen-based systems— either proton exchange membrane fuel cells (PEMFCs) or internal combustion engines (ICEs); and (ii) replacing only the diesel generator sets with hydrogen power systems. The assessment covers system sizing onboard hydrogen storage integration operational constraints lifecycle cost and GHG abatement. Option (i) is constrained by the sizes and weights of PEMFC systems and hydrogen-fuelled ICEs rendering full conversion unfeasible within current spatial and technological limits. Option (ii) is technically feasible: sixteen 700 bar cylinders (131.2 kg H2 total) meet one day of onboard power demand for net-cleaning operations with bunkering via swap-and-go skids at the berth. The annualised total cost of ownership for the PEMFC systems is 1.98 times that of diesel generator sets while enabling annual CO2 reductions of 433 t. The findings provide a practical decarbonisation pathway for small- to medium-sized service vessels in niche maritime sectors such as aquaculture while clarifying near-term trade-offs between cost and emissions.
Toward Sustainable Hydrogen Production from Renewable Energy Sources: A Review
Sep 2025
Publication
The escalating global pursuit of environmentally benign energy alternatives has spurred intensive investigations into sustainable hydrogen generation technologies. Although hydrogen energy can be produced via multiple approaches the integration of nanotechnology materials in its generation results in its production improvements and efficiency of the production methods. Nanotechnology with its astonishing ability to control materials at the atomic and molecular scale has emerged as a vital technology for improving the efficiency and affordability of hydrogen production from renewable energy sources. This technology provides a unique platform for creating materials with specific properties for energy conversion and storage. Nanotechnology is accelerating the transition to a hydrogen economy by boosting hydrogen production efficiency and storage. Its applications span from enhancing water-splitting catalysts to developing advanced membranes and photocatalysts. These nanomaterial-based innovations are crucial for producing clean hydrogen and its effective storage. Nevertheless nanotechnology highlights the significant role of nanomaterials in overcoming the kinetic challenges associated with hydrogen evolution reactions which can be attained through several features like increased surface area enhanced catalytic activity and improved charge transfer. Therefore this study explores the latest advancements in nanomaterials and their catalytic impact on hydrogen generation particularly in photocatalysis electrocatalysis and photoelectrochemical systems. The study has examined the nanomaterials’ production characterization and performance their integration into renewable energy systems and their potential for widespread commercial use.
Effect of Hydrogen-Containing Fuel on the Mechanical Properties of an Aluminum Alloy ICE Piston
Oct 2025
Publication
The transition to cleaner hydrogen-containing fuels is critical for reducing the environmental impact of marine infrastructure yet their potential effects on the durability and mechanical reliability of engine components remain a significant engineering challenge. Although aluminum alloys are generally regarded as less susceptible to hydrogeninduced degradation and are widely applied in internal combustion engine components experimental data obtained under real operating conditions with hydrogen-containing fuel mixtures remain insufficient to fully assess all potential risks. In the present study two identical low-power gasoline engine–generators were operated for 220 h on fuels with and without hydrogen. Post-test analysis included mechanical testing and microstructural characterization of aluminum alloy pistons for comparative assessment. The measured values of ultimate tensile strength elongation and deflection maximum bending force and effective stress concentration factor revealed pronounced property degradation in the piston operated on the gasoline–hydrogen mixture compared to both the new piston and the one run on pure gasoline. Microstructural analysis provided a plausible explanation for this degradation. The results of this preliminary study provide insights into the effects of hydrogen-containing fuel on the mechanical performance of engine component alloys contributing to the development of safer and more reliable marine energy systems.
Physics-Informed Co-Optimization of Fuel-Cell Flying Vehicle Propulsion and Control Systems with Onboard Catalysis
Oct 2025
Publication
Fuel-cell flying vehicles suffer from limited endurance while ammonia decomposed onboard to supply hydrogen offers a carbon-free high-density solution to extend flight missions. However the system’s performance is governed by a multi-scale coupling between propulsion and control systems. To this end this paper introduces a novel optimization paradigm termed physics-informed gradient-enhanced multi-objective optimization (PIGEMO) to simultaneously optimize the ammonia decomposition unit (ADU) catalyst composition powertrain sizing and flight control parameters. The PI-GEMO framework leverages a physics-informed neural network (PINN) as a differentiable surrogate model which is trained not only on sparse simulation data but also on the governing differential equations of the system. This enables the use of analytical gradient information extracted from the trained PINN via automatic differentiation to intelligently guide the evolutionary search process. A comprehensive case study on a flying vehicle demonstrates that the PIGEMO framework not only discovers a superior set of Pareto-optimal solutions compared to traditional methods but also critically ensures the physical plausibility of the results.
Experimental Thermal and Environmental Impact Performance Evaluations of Hydrogen-enriched Fuels for Power Generation
Oct 2025
Publication
The transition to a low-carbon energy future requires a multi-faceted approach including the enhancement of existing power generation technologies. This study provides a comprehensive experimental evaluation of hydrogen enrichment as a strategy to improve the performance and reduce the emissions of a power generator. A 3.65 kW power generator that is equipped with spark-ignition engine is systematically tested with five distinct base fuels: gasoline propane methane ethanol and methanol. Each fuel is volumetrically blended with pure hydrogen in ratios of 5 % 10 % 15 % and 20 % using a custom-developed dual-fuel carburetor. The key parameters including exhaust emissions (CO2 CO HC NOx) cylinder exit temperature electrical power output and thermodynamic efficiencies (energy and exergy) are meticulously measured and analyzed. The results reveal that hydrogen enrichment is a powerful tool for decarbonization consistently reducing carbon-based emissions across all fuels. At a 20 % hydrogen blend CO2 emissions are reduced by 22–31 % CO emissions by 39–60 % and HC emissions by 21–60 %. This environmental benefit however is accompanied by a critical trade-off: a severe increase in NOx emissions which rose by 200–420 % due to significantly elevated combustion temperatures. The power outputs are increased by 2–16 % with hydrogen addition enabling lower-energy–density fuels like methane and propane to achieve performance parity with gasoline. Thermodynamic analysis confirms these gains with energy efficiency showing marked improvement particularly for methane which has increased from 42.0 % to 49.9 %. While hydrogen enrichment presents a viable pathway for enhancing engine performance and reducing the carbon emissions of power generators the profound increase in NOx necessitates the integration of advanced control and after-treatment systems for its practical and environmentally responsible deployment.
Techno-Economic Assessment of Green Hydrogen Production in Australia Using Off-Grid Hybrid Resources of Solar and Wind
Jun 2025
Publication
This study presents a techno-economic framework for assessing the potential of utilizing hybrid renewable energy sources (wind and solar) to produce green hydrogen with a specific focus on Australia. The model’s objective is to equip decision-makers in the green hydrogen industry with a reliable methodology to assess the availability of renewable resources for cost-effective hydrogen production. To enhance the credibility of the analysis the model integrates 10 min on-ground solar and wind data uses a high-resolution power dispatch simulation and considers electrolyzer operational thresholds. This study concentrates on five locations in Australia and employs high-frequency resource data to quantify wind and solar availability. A precise simulation of power dispatch for a large off-grid plant has been developed to analyze the PV/wind ratio element capacities and cost variables. The results indicate that the locations where wind turbines can produce cost-effective hydrogen are limited due to the high capital investment which renders wind farms uneconomical for hydrogen production. Our findings show that only one location—Edithburgh South Australia—under a 50% solar–50% wind scenario achieves a hydrogen production cost of 10.3 ¢USD/Nm3 which is lower than the 100% solar scenario. In the other four locations the 100% solar scenario proves to be the most cost-effective for green hydrogen production. This study suggests that precise and comprehensive resource assessment is crucial for developing hydrogen production plants that generate low-cost green hydrogen.
Integrated Optimization of Hydrogen Production: Evaluating Scope 3 Emissions and Sustainable Pathways
Jul 2025
Publication
The U.S. produces 10 million metric tons (MMT) of hydrogen annually emitting about 41 MMT of carbon dioxide equivalents (CO2-eqs). With rising hydrogen demand and new emission regulations integrating conventional and novel hydrogen production systems is crucial. This study presents an integrated optimization framework to model diversified hydrogen economies as mixed integer linear programs (MILPs). Moreover the accounting of emissions extends to the system exterior (scope 3) thus providing a comprehensive sustainability assessment. The primary focus of the presented computational example is to analyze the impact of scope 3 emissions particularly material emissions during the construction phase on process system optimization while complying with stringent environmental constraints such as carbon limits. By evaluating emission reduction scenarios the model highlights the role of power purchase agreements (PPAs) from renewable sources and the trade-offs between conventional and novel hydrogen production technologies. The key findings indicate that while electrolyzer-based systems (PEM and AWE) offer potential for emission reduction their high energy demand and significant scope 3 material emissions pose challenges for a complete transition in the near term. The study identified two optimal design configurations: one utilizing PPAs as the primary energy source coupled with the conventional SMR-CCS process and another that combines both conventional (SMR-CCS) and novel hydrogen production technologies under a hybrid purview. Ultimately the findings contribute toward the ongoing efforts to achieve true net-carbon neutrality.
Development of a MILP Optimization Framework to Design Grid-connected Microgrids: Enhancing Operational Synergy Among Wind, Solar, Batteries, and Hydrogen Storage
Sep 2025
Publication
By integrating Renewable Energy Sources (RES) and storage devices Hybrid Energy Systems (HESs) represent a promising solution for decarbonizing isolated and remote communities. Proper sizing and management of systems comprising a variety of components requires however more advanced methods than conventional energy systems. This study proposes a novel Mixed Integer Linear Programming (MILP) framework for the simultaneous design of a grid-connected HES supported by renewable generators. Unlike the standard design approach based on parametric dispatch strategies this framework simultaneously optimizes the energy management of each system configuration under analysis. The novel approach is applied to size a combination of Li-Ion batteries an alkaline electrolyzer H2 tanks and a PEM fuel cell to maximize the NPV of a system including a wind turbine and a photovoltaic field. Managing thousands of variables at the same time the framework simultaneously optimizes how all components are used to fulfill the load and balance the input/export of power within a limited electrical network. Results show that the combination of BESS and H2 can provide for both the need for short- and long-term energy storage and that the MILP optimization can effectively allocate the energy flows and produce 558 k€ of revenues per year 15.5% of the initial investment cost of 3.6 M€. The investment cost of the system is recovered in six years and presents an NPV of 5.51 M€ after 20 years. Results from the proposed method are also compared to common approaches based on rule-based parametric dispatch strategies demonstrating the superiority of MILP for the design and management of complex HESs.
Hydrogen Barrier Coatings: Application and Assessment
Sep 2025
Publication
Hydrogen embrittlement (HE) threatens the structural integrity of industrial components exposed to hydrogenrich environments. This review critically explores hydrogen barrier coatings (HBCs) polymeric metallic ceramic and composite their application and assessment focusing on measured effectiveness in limiting hydrogen permeation and hydrogen embrittlement. Also coating application methods and permeation assessment techniques are evaluated. Recent advances in nanostructured and hybrid coatings are emphasized highlighting the pressing need for durable scalable and environmentally sustainable hydrogen barrier coatings to ensure the reliability of emerging hydrogen-based energy solutions. This comprehensive critical review further distinguishes itself by linking coating deposition methods to defect-driven transport behaviour critically assessing permeation test approaches. It also highlights the emerging role of polymeric and hybrid multilayer coatings with direct implications for advanced and reliable hydrogen production storage and transport infrastructure.
Synthesis of Activated Carbon from Zhundong Coal and its Hydrogen Storage Application
May 2025
Publication
Activated carbon as a hydrogen storage material possesses advantages such as low cost high safety lightweight and good cycling performance. Zhundong coal characterized by low calorific value high volatility and elevated reaction activity stands out as an exceptional raw material for the production of activated carbon. This study employed Zhundong coal for the synthesis of hydrogen storage activated carbon exploring the impact of acid treatment and varied activation conditions on Zhundong coal. The specific surface area of sample ZD-HK3-AC is 1980 m2 /g and the gravimetric hydrogen storage density reaches 0.91 wt% under the condition of 80bar at room temperature. The adsorption–desorption isotherms nearly overlapped demonstrating excellent cycling performance and high mechanical strength. At the same time the relationship between the pore structure parameters of activated carbon and hydrogen storage density was explored revealing the mechanism of activated carbon adsorption and hydrogen storage. These findings hold significant guiding implications for the preparation and research of hydrogen storage materials utilizing activated carbon.
Advancing Electrochemical Modelling of PEM Electrolyzers through Robust Parameter Estimation with the Weighted Mean of Vectors Algorithm
Jul 2025
Publication
The electrochemical modelling of proton exchange membrane electrolyzers (PEMEZs) relies on the precise determination of several unknown parameters. Achieving this accuracy requires addressing a challenging optimization problem characterized by nonlinearity multimodality and multiple interdependent variables. Thus a novel approach for determining the unknown parameters of a detailed PEMEZ electrochemical model is proposed using the weighted mean of vectors algorithm (WMVA). An objective function based on mean square deviation (MSD) is proposed to quantify the difference between experimental and estimated voltages. Practical validation was carried out on three commercial PEMEZ stacks from different manufacturers (Giner Electrochemical Systems and HGenerators™). The first two stacks were tested under two distinct pressure-temperature settings yielding five V–J data sets in total for assessing the WMVA-based model. The results demonstrate that WMVA outperforms all optimizers achieving MSDs of 1.73366e−06 1.91934e−06 1.09306e−05 6.18248e−05 and 4.41586e−06 corresponding to improvements of approximately 88% 82.9% 82.4% 54.5% and 59.5% over the poorest-performing algorithm in each case respectively. Moreover comparative analyses statistical studies and convergence curves confirm the robustness and reliability of the proposed optimizer. Additionally the effects of temperature and hydrogen pressure variations on the electrical and physical steady-state performance of the PEMEZ are carefully investigated. The findings are further reinforced by a dynamic simulation that illustrates the impact of temperature and supplied current on hydrogen production. Accordingly the article facilitates better PEMEZ modelling and optimizing hydrogen production performance across various operating conditions.
Numerical Modelling of Gas Mixing in Salt Caverns During Cyclic Hydrogen Storage
Oct 2025
Publication
This study presents the development of a robust numerical model for simulating underground hydrogen storage (UHS) in salt caverns with a particular focus on the interactions between original gas-methane (CH4) and injected gas represented by hydrogen (H2). Using the Schlumberger Eclipse 300 compositional reservoir simulator the cavern was modelled as a highly permeable porous medium to accurately represent gas flow dynamics. Two principal mixing mechanisms were investigated: physical dispersion modelled by numerical dispersion and molecular diffusion. Multiple cavern configurations and a range of dispersion–diffusion coefficients were assessed. The results indicate that physical dispersion is the primary factor affecting hydrogen purity during storage cycles while molecular diffusion becomes more significant during long-term gas storage. Gas mixing was shown to directly impact the calorific value and quality of withdrawn hydrogen. This work demonstrates the effectiveness of commercial reservoir simulators for UHS analysis and proposes a methodological framework for evaluating hydrogen purity in salt cavern storage operations.
In-service and Repair Welding of Pressurized Hydrogen Pipelines - A Review on Current Challenges and Strategies
Aug 2025
Publication
Hydrogen is the energy carrier for a sustainable future without fossil fuels. As this requires a reliable transportation infrastructure the conversion of existing natural gas (NG) grids is an essential part of the worldwide individual national hydrogen strategies in addition to newly erected pipelines. In view of the known effect of hydrogen embrittlement the compatibility of the materials already in use (typically low-alloy steels in a wide range of strengths and thicknesses) must be investigated. Initial comprehensive studies on the hydrogen compatibility of pipeline materials indicate that these materials can be used to a certain extent. Nevertheless the material compatibility for hydrogen service is currently of great importance. However pipelines require frequent maintenance and repair work. In some cases it is necessary to carry out welding work on pipelines while they are under pressure e.g. the well-known tapping of NG grids. This in-service welding brings additional challenges for hydrogen operations in terms of additional hydrogen absorption during welding and material compatibility. The challenge can be roughly divided into two parts: (1) the possible austenitization of the inner piping material exposed to hydrogen which can lead to additional hydrogen absorption and (2) the welding itself causes an increased temperature range. Both lead to a significantly increased hydrogen solubility in the respective materials compared to room temperature. In that connection the knowledge on hot tapping on hydrogen pipelines is rare so far due to the missing service experiences. Fundamental experimental investigations are required to investigate the possible transferability of the state-of-the-art concepts from NG to hydrogen pipeline grids. This is necessary to ensure that no critical material degradation occurs due to the potentially increased hydrogen uptake. For this reason the paper introduces the state of the art in pipeline hot tapping encompassing current research projects and their individual solution strategies for the problems that may arise for future hydrogen service. Methods of material testing their limitations and possible solutions will be presented and discussed.
Hydrogen-Enabled Microgrids for Railway Applications: A Seasonal Energy Storage Solution for Switch-Point Heating
Sep 2025
Publication
Switch-point heating systems are essential for railway reliability and safety in winter but present logistical and economic challenges in remote regions. This study presents a novel application of a hydrogen-enabled microgrid as an off-grid energy solution for powering a switch-point heating system at a rural Austrian railway station offering an alternative to conventional grid-based electricity with a specific focus on enhancing the share of renewable energy sources. The proposed system integrates photovoltaics (PV) optional wind energy and hydrogen storage to address the seasonal mismatch between a high energy supply in the summer and peak winter demand. Three energy supply scenarios are analysed and compared based on local conditions technical simplicity and economic viability. Energy flow modelling based on site-specific climate and operational data is used to determine hydrogen production rates storage capacity requirements and system sizing. A comprehensive cost analysis of all major subsystems is conducted to assess economic viability. The study demonstrates that hydrogen is a highly effective solution for seasonal energy storage with a PV-only configuration emerging as the most suitable option under current site conditions. Thus it offers a replicable framework for decarbonising critical stationary railway infrastructure.
An Integrated AI-driven Framework for Maximizing the Efficiency of Heterostructured Nanomaterials in Photocatalytic Hydrogen Production
Jul 2025
Publication
The urgency for sustainable and efficient hydrogen production has increased interest in heterostructured nanomaterials known for their excellent photocatalytic properties. Traditional synthesis methods often rely on trial-and-error resulting in inefficiencies in material discovery and optimization. This work presents a new AI-driven framework that overcomes these challenges by integrating advanced machine-learning techniques specific to heterostructured nanomaterials. Graph Neural Networks (GNNs) enable accurate representations of atomic structures predicting material properties like bandgap energy and photocatalytic efficiency within ±0.05 eV. Reinforcement Learning optimises synthesis parameters reducing experimental iterations by 40% and boosting hydrogen yield by 15–20%. Physics-Informed Neural Networks (PINNs) successfully predict reaction pathways and intermediate states minimizing synthesis errors by 25%. Variational Autoencoders (VAEs) generate novel material configurations improving photocatalytic efficiency by up to 15%. Additionally Bayesian Optimisation enhances predictive accuracy by 30% through efficient hyperparameter tuning. This holistic framework integrates material design synthesis optimization and experimental validation fostering a synergistic data flow. Ultimately it accelerates the discovery of novel heterostructured nanomaterials enhancing efficiency scalability and yield thus moving closer to sustainable hydrogen production with improvements in photolytic efficiency setting a benchmark for AI-assisted research.
Hydrogen Production Intensification by Energy Demand Management in High-Temperature Electrolysis
Aug 2025
Publication
Solid oxide electrolysers (SOEs) can decarbonise H2 supply when powered by renewable electricity but remain constrained by high electrical demand and integration penalties. Our objective is to minimise the electrical (Pel) and thermal (Qth) energy demand per mole of H2 by jointly tuning cell temperature steam fraction steam utilisation pressure and current density. Compared with prior single-variable or thermo-neutral-constrained studies we develop and validate a steady-state process-level optimisation framework that couples an Aspen Plus SOE model with electrochemical post-processing and heat caused by ohmic resistance recovery. A Box–Behnken design explores five key operating parameters to capture synergies and trade-offs between Qth and Pel energy inputs. Single-objective optimisation yields Pel = 170.1 kJ mol⁻¹ H2 a 41.4% reduction versus literature baselines. Multi-objective optimisation using an equal-weighted composite desirability function aggregating thermal and electrical demands further reduces Pel by 21.2% while balancing thermal input 4–8% lower than single-objective baselines at moderate temperature (~781 °C) and pressure (~17.5 bar). Findings demonstrate a clear process intensification advantage over previous studies by simultaneously leveraging operating parameter synergies and heat-integration. However results are bounded by steady-state perfectly mixed isothermal assumptions. The identified operating windows are mechanistically grounded targets that warrant stack-scale and plantlevel validation.
Cyclic Liquid Organic Hydrogen Carriers for Efficient Hydrogen Storage using Mesoporous Catalytic Systems
Jul 2025
Publication
Liquid organic hydrogen carriers (LOHCs) are a promising class of hydrogen storage media in which hydrogen is reversibly bound to organic molecules. In this work we focus explicitly on cyclic LOHCs (both homocyclic and heterocyclic organic compounds) and their catalytic dehydrogenation. We clarify that other carriers (e.g. alcohols like methanol or carboxylic acids like formic acid) exist but are not the focus here; these alternatives are discussed only in comparative context. Cyclic LOHCs typically enable safe ambient-temperature hydrogen storage with hydrogen contents around 6–8 wt%. Key challenges include the high dehydrogenation temperatures (often 200–350 °C) catalyst costs and catalyst deactivation via coke formation. We introduce a comparative analysis table contrasting cyclic LOHCs with alternative carriers in terms of hydrogen density operating conditions catalyst types toxicity and cost. We also expand the catalyst discussion to highlight coke formation mechanisms and the use of mesoporous metal-oxide supports to mitigate deactivation. Finally a techno-economic analysis is provided to address system costs of LOHC storage and regeneration. Finally we underscore the viability and limitations of cyclic LOHCs including practical storage capacities catalyst life and projected costs.
Can Hydrogen-powered Air Travel Grow within the Planetary Limits?
Aug 2025
Publication
Air travel demand is rising rapidly and the aviation sector is relying on technology to decouple environmental impacts from its growth. Using Sweden as a case study we assessed the absolute environmental sustainability of medium-distance air travel in 2050 positioning the aviation sector's environmental impacts in relation to the planetary limits. We employed a novel framework that integrates prospective life cycle assessment and absolute environmental sustainability assessment methodologies. Our findings suggest that projected medium-distance air travel powered by e-kerosene or liquid hydrogen could have life cycle environmental impacts that overshoot global climate change and biodiversity loss thresholds by several orders of magnitude. Based on our case results for Sweden for aviation to develop within the planetary limits we recommend cross-sector collaboration to address environmental impacts from fossil-free energy supplies and the establishment of integrated targets that incorporate broader environmental issues. Given the unlikelihood of decoupling growth from environmental impacts policymakers and the aviation sector should consider concurrently supporting technological development and implementing measures to manage air travel demand.
Techno-Economic Optimization of a Hybrid Renewable Energy System with Seawater-Based Pumped Hydro, Hydrogen, and Battery Storage for a Coastal Hotel
Oct 2025
Publication
This study presents the design and techno-economic optimization of a hybrid renewable energy system (HRES) for a coastal hotel in Manavgat Türkiye. The system integrates photovoltaic (PV) panels wind turbines (WT) pumped hydro storage (PHS) hydrogen storage (electrolyzer tank and fuel cell) batteries a fuel cell-based combined heat and power (CHP) unit and a boiler to meet both electrical and thermal demands. Within this broader optimization framework six optimal configurations emerged representing gridconnected and standalone operation modes. Optimization was performed in HOMER Pro to minimize net present cost (NPC) under strict reliability (0% unmet load) and renewable energy fraction (REF > 75%) constraints. The grid-connected PHS–PV–WT configuration achieved the lowest NPC ($1.33 million) and COE ($0.153/kWh) with a renewable fraction of ~96% and limited excess generation (~21%). Off-grid PHS-based and PHS–hydrogen configurations showed competitive performance with slightly higher costs. Hydrogen integration additionally provides complementary storage pathways coordinated operation waste heat utilization and redundancy under component unavailability. Battery-only systems without PHS or hydrogen storage resulted in 37–39% higher capital costs and ~53% higher COE confirming the economic advantage of long-duration PHS. Sensitivity analyses indicate that real discount rate variations notably affect NPC and COE particularly for battery-only systems. Component cost sensitivity highlights PV and WT as dominant cost drivers while PHS stabilizes system economics and the hydrogen subsystem contributes minimally due to its small scale. Overall these results confirm the techno-economic and environmental benefits of combining seawater-based PHS with optional hydrogen and battery storage for sustainable hotel-scale applications.
The Role of Financial Mechanisms in Advancing Renewable Energy and Green Hydrogen
Jun 2025
Publication
Europe’s transition toward a low-carbon energy system relies on the deployment of hydrogen produced with minimized carbon emissions; however regulatory requirements increase system costs and create financial barriers. This study investigates the financial implications of enforcing European Commission rules for renewable hydrogen production from 2024 to 2048. Using a scenario-based modeling approach that draws on European power system investments in renewable energy the results show that immediate compliance leads to an additional cost of approximately eighty billion euros over twenty-four years corresponding to a 3.6 percent increase in total system costs. To address this investment gap the study employs a segmentation analysis of support mechanisms based on existing policies and market practices identifying seven categories that range from investment incentives and production subsidies to infrastructure and financial instruments. Among these hydrogen offtake support and infrastructure funding are identified as the most effective measures for reducing risk and enabling private investment. These findings provide strategic insights for policymakers seeking to align their regulatory ambitions with financially viable pathways for integrating renewable energy.
Degradation Mechanisms of a Proton Exchange Membrane Water Electrolyzer Stack Operating at High Current Densities
Sep 2025
Publication
On the path to an emission free energy economy proton exchange membrane water electrolysis (PEMWE) is a promising technology for a sustainable production of green hydrogen at high current densities and thus high production rates. Long lifetime increasing the current density and the reduction of platinum group metal loadings are major challenges for a widespread implementation of PEMWE. In this context this work investigates the aging of a PEMWE stack operating at 4 A cm-2 which is twice the nominal current density of commercial electrolyzers. Specifically an 8-cells PEMWE stack using catalyst coated membranes (CCMs) with different platinum group metal (PGM) loading was operated for 2200 h. To understand degradation phenomena physical ex-situ analyses such as scanning electron microscopy (SEM) atomic force microscopy (AFM) and X-ray photoelectron spectroscopy (XPS) were carried out. The same aging mechanism were observed in all cells independent on their position in stack or the specific PGM loading of the membrane electrode assembly (CCM): (i) a decrease of ohmic resistance over time related to membrane thinning (ii) a significant loss of ionomer at anodes (iii) loss of noble metal from the electrodes leading to deposition of small Ir and Pt concentrations in the membrane (iv) heterogeneous enrichment of Ti on the cathode side likely originating from the cathode-side of the Ti bipolar plates (BPPs). These results are in good agreement with the electrochemical performance loss. Thus we were able to identify the degradation phenomena that dominate under high-current operation and their impact on performance.
A Framework for the Configuration and Operation of EV/FCEV Fast-Charging Stations Integrated with DERs Under Uncertainty
Oct 2025
Publication
The integration of electric vehicles (EVs) and fuel-cell electric vehicles (FCEVs) requires accessible and profitable facilities for fast charging. To promote fast-charging stations (FCSs) a systematic analysis that encompasses both planning and operation is required including the incorporation of multi-energy resources and uncertainty. This paper presents an optimization framework that addresses a joint strategy for the configuration and operation of an EV/FCEV fast-charging station (FCS) integrated with distributed energy resources (DERs) and hydrogen systems. The framework incorporates uncertainties related to solar photovoltaic (PV) generation and demand for EVs/FCEVs. The proposed joint strategy comprises a four-phase decision-making framework. Phase 1 involves modeling EV/FECE demand while Phase 2 focuses on determining an optimal long-term infrastructure configuration. Subsequently in Phase 3 the operator optimizes daily power scheduling to maximize profit. A real-time uncertainty update is then executed in Phase 4 upon the realization of uncertainty. The proposed optimization framework formulated as mixed-integer quadratic programming (MIQP) considers configuration investment operational maintenance and penalty costs for excessive grid power usage. A heuristic algorithm is proposed to solve this problem. It yields good results with significantly less computational complexity. A case study shows that under the most adverse conditions the proposed joint strategy increases the FCS owner’s profit by 3.32% compared with the deterministic benchmark.
Effect of Real Gas Equations on Calculation Accuracy of Thermodynamic State in Hydrogen Storage Tank
Oct 2025
Publication
The gas equation of state (EOS) serves as a critical tool for analyzing the thermal effects within the hydrogen storage tank during refueling processes. It quantifies the dynamic relationships among pressure temperature and volume playing a vital role in numerical simulations of hydrogen refueling the development of refueling protocols and ensuring refueling safety. This study first establishes a lumped-parameter thermodynamic model for the hydrogen refueling process which combines a zero-dimensional gas model with a one-dimensional tank wall model (0D1D). The model’s accuracy was validated against experimental data and will be used in combination with different EOSs to simulate hydrogen temperature and pressure. Subsequently parameter values are derived for the van der Waals EOS and its modified forms—Redlich–Kwong Soave and Peng–Robinson. The accuracy of the modified forms is evaluated using the Joule–Thomson inversion curve. A polynomial EOS is formulated and its parameters are numerically determined. Finally the hydrogen temperatures and pressures calculated using the van der Waals EOS Redlich– Kwong EOS polynomial EOS and the National Institute of Standards and Technology (NIST) database are compared. Within the initial and boundary conditions set in this study the results indicate that among the modified forms for van der Waals EOS the Redlich– Kwong EOS exhibits higher accuracy than the Soave and Peng–Robinson EOSs. Using the NIST-calculated hydrogen pressure as a benchmark the relative error is 0.30% for the polynomial EOS 1.83% for the Redlich–Kwong EOS and 17.90% for the van der Waals EOS. Thus the polynomial EOS exhibits higher accuracy followed by the Redlich–Kwong EOS while the van der Waals EOS demonstrates lower accuracy. This research provides a theoretical basis for selecting an appropriate EOS in numerical simulations of hydrogen refueling processes.
Optimizing Renewable Microgrid Performance Through Hydrogen Storage Integration
Oct 2025
Publication
The global transition to a low-carbon energy system requires innovative solutions that integrate renewable energy production with storage and utilization technologies. The growth in energy demand combined with the intermittency of these sources highlights the need for advanced management models capable of ensuring system stability and efficiency. This paper presents the development of an optimized energy management system integrating renewable sources with a focus on green hydrogen production via electrolysis storage and use through a fuel cell. The system aims to promote energy autonomy and support the transition to a low-carbon economy by reducing dependence on the conventional electricity grid. The proposed model enables flexible hourly energy flow optimization considering solar availability local consumption hydrogen storage capacity and grid interactions. Formulated as a Mixed-Integer Linear Programming (MILP) model it supports strategic decision-making regarding hydrogen production storage and utilization as well as energy trading with the grid. Simulations using production and consumption profiles assessed the effects of hydrogen storage capacity and electricity price variations. Results confirm the effectiveness of the model in optimizing system performance under different operational scenarios.
Response Surface Analysis of the Energy Performance and Emissions of a Dual-Fuel Engine Generator Using Biodiesel and Hydrogen-Enriched Biogas
Oct 2025
Publication
In this study we investigate the dual-fuel operation of compression ignition engines using biodiesel at varying concentrations in combination with biogas with and without hydrogen enrichment. A response surface methodology based on a central composite experimental design was employed to optimize energy efficiency and minimize pollutant emissions. The partial substitution of diesel with gaseous fuel substantially reduces the specific fuel consumption achieving a maximum decrease of 21% compared with conventional diesel operation. Enriching biogas with hydrogen accounting for 13.3% of the total flow rate increases the thermal efficiency by 0.8% compensating for the low calorific value and reduced volumetric efficiency of biogas. Variations in biodiesel concentration exhibits a nonlinear effect yielding an additional average efficiency gain of 0.4%. Regarding emissions the addition of hydrogen to biogas contributes to an average reduction of 5% in carbon monoxide emissions compared to the standard dual-fuel operation. However dual-fuel operation leads to higher unburned hydrocarbon emissions relative to neat diesel; hydrogen enrichment mitigates this drawback by reducing hydrocarbon emissions by 4.1%. Although NOx emissions increase by an average of 26.6% with hydrogen addition dual-fuel strategies achieve NOx reductions of 11.5% (hydrogen-enriched mode) and 33.3% (pure biogas mode) relative to diesel-only operation. Furthermore the application of response surface methodology is robust and reliable with experimental validation showing errors of 0.55–8.66% and an overall uncertainty of 4.84%.
A Two-Layer HiMPC Planning Framework for High-Renewable Grids: Zero-Exchange Test on Germany 2045
Oct 2025
Publication
High-renewables grids are planned in min but judged in milliseconds; credible studies must therefore resolve both horizons within a single model. Current adequacy tools bypass fast frequency dynamics while detailed simulators lack multi-hour optimization leaving investors without a unified basis for sizing storage shifting demand or upgrading transfers. We present a two-layer Hierarchical Model Predictive Control framework that links 15-min scheduling with 1-s corrective action and apply it to Germany’s four TSO zones under a stringent zero-exchange stress test derived from the NEP 2045 baseline. Batteries vehicleto-grid pumped hydro and power-to-gas technologies are captured through aggregators; a decentralized optimizer pre-positions them while a fast layer refines setpoints as forecasts drift; all are subject to inter-zonal transfer limits. Year-long simulations hold frequency within ±2 mHz for 99.9% of hours and below ±10 mHz during the worst multi-day renewable lull. Batteries absorb sub-second transients electrolyzers smooth surpluses and hydrogen turbines bridge week-long deficits—none of which violate transfer constraints. Because the algebraic core is modular analysts can insert new asset classes or policy rules with minimal code change enabling policy-relevant scenario studies from storage mandates to capacity-upgrade plans. The work elevates predictive control from plantscale demonstrations to system-level planning practice. It unifies adequacy sizing and dynamic-performance evaluation in a single optimization loop delivering an open scalable blueprint for high-renewables assessments. The framework is readily portable to other interconnected grids supporting analyses of storage obligations hydrogen roll-outs and islanding strategies.
Solar-powered Electric Vehicles - Batter EV & Fuel Cell EV: A Review
Sep 2025
Publication
The transport sector is a major contributor to greenhouse gas emissions largely due to its dependence on fossil fuels. Electrifying transport through Battery Electric Vehicles (BEVs) and Hydrogen Fuel Cell Electric Vehicles (FCEVs) is widely recognized as a key pathway to reducing emissions. While both BEVs and FCEVs are zero-emission during operation they still require electricity to function. Sourcing this electricity from solar energy presents a promising opportunity for sustainable operation. The novelty of this work lies in exploring how solar energy can be effectively integrated into both BEV and FCEV systems. The paper examines the potential scope and infrastructure requirements of these vehicle types as well as innovative charging and refuelling strategies. For BEVs charging options include fixed charging stations battery swapping stations and wireless charging. In the context of solar integration photovoltaic (PV) systems can be mounted directly on the vehicle body or used to power charging stations. While current PV efficiency and reliability are insufficient to meet the full energy demand of BEVs they can provide valuable auxiliary power. For FCEVs solar energy can be utilized for hydrogen production enabling the concept of solar-powered FCEVs. Refuelling options include onsite and offsite hydrogen production facilities as well as mobile refuelling units. In both cases land requirements for PV installations are significant. Alternatives to ground-mounted PV such as floating PV or agrivoltaics (agriPV) should be considered to optimize land use. While solar-powered charging or refuelling stations are technically feasible complete reliance on solar power alone is not yet practical. A hybrid approach with grid connections energy storage or backup generation remains necessary to ensure consistent energy availability. For BEVs the cost of charging particularly for long-distance travel where rapid charging is required remains a barrier. For FCEVs challenges include the high cost of hydrogen production and the limited availability of refuelling infrastructure despite their advantage of fast refuelling times. Government policies and incentives are playing a critical role in overcoming these barriers fostering investment in infrastructure and accelerating the transition toward a cleaner transport sector. In summary integrating solar energy into BEV and FCEV infrastructure can advance sustainable mobility by reducing lifecycle emissions. While current PV efficiency storage and hydrogen production limitations require hybrid energy solutions ongoing technological improvements and supportive policies can enable broader adoption. A balanced renewable energy mix with solar as a key component will be essential for realizing truly sustainable zero-emission transport.
Experimental and Numerical Analysis of Hydrogen-Induced Effects in ASTM A131 and A36 Steels for Naval Fuel Systems
Oct 2025
Publication
Hydrogen embrittlement (HE) can degrade the mechanical integrity of steel pipes increasing failure risks in naval fuel systems. This study assesses HE effects on ASTM A131 and A36 steels through tensile testing and numerical modeling. Tests conducted with varying exposure times to hydrogen revealed that A131 outperformed A36 in terms of mechanical strength. However both materials experienced property degradation after six hours. After nine hours a transient increase in strength occurred due to temporary microstructural hardening though the overall trend remained a decline. The maximum reductions in ultimate tensile strength and toughness were 19% and 47% for A131 and 39% and 61% for A36 respectively. Additionally microstructural analysis revealed the presence of inclusions intergranular decohesion and micro-crack in specimens exposed for longer periods. Finally a combined GTN-PLNIH numerical model was implemented demonstrating its effectiveness in predicting the mechanical behavior of structures exposed to hydrogen.
Hydrogen Propulsion Technologies for Aviation: A Review of Fuel Cell and Direct Combustion Systems Towards Decarbonising Medium-Haul Aircraft
Oct 2025
Publication
Hydrogen propulsion technologies are emerging as a key enabler for decarbonizing the aviation sector especially for regional commercial aircraft. The evolution of aircraft propulsion technologies in recent years raises the question of the feasibility of a hydrogen propulsion system for beyond regional aircraft. This paper presents a comprehensive review of hydrogen propulsion technologies highlighting key advancements in component-level performance metrics. It further explores the technological transitions necessary to enable hydrogen-powered aircraft beyond the regional category. The feasibility assessment is based on key performance parameters including power density efficiency emissions and integration challenges aligned with the targets set for 2035 and 2050. The adoption of hydrogen-electric powertrains for the efficient transition from KW to MW powertrains depends on transitions in fuel cell type thermal management systems (TMS) lightweight electric machines and power electronics and integrated cryogenic cooling architectures. While hydrogen combustion can leverage existing gas turbine architectures with relatively fewer integration challenges it presents its technical hurdles especially related to combustion dynamics NOx emissions and contrail formation. Advanced combustor designs such as micromix staged and lean premixed systems are being explored to mitigate these challenges. Finally the integration of waste heat recovery technologies in the hydrogen propulsion system is discussed demonstrating the potential to improve specific fuel consumption by up to 13%.
Energy Management in an Insular Region with Renewable Energy Sources and Hydrogen: The Case of Graciosa, Azores
Sep 2025
Publication
Insular regions face unique energy management challenges due to physical isolation. Graciosa (Azores) has high renewable energy sources (RES) potential theoretically enabling a 100% green system. However RES intermittency combined with the lack of energy storage solutions reduces renewable penetration and raises curtailment. This article studies the technical and economic feasibility of producing green hydrogen from curtailment energy in Graciosa through two distinct case studies. Case Study 1 targets maximum renewable penetration with green hydrogen serving as chemical storage converted back to electricity via fuel cells during RES shortages. Case Study 2 focuses on maximum profitability where produced gases are sold to monetize curtailment without additional electricity production. Levelized Cost of Hydrogen (LCOH) values of €3.06/kgH2 and €2.68/kgH2 respectively and Internal Rate of Return (IRR) values of 3.7% and 17.1% were obtained for Case Studies 1 and 2 with payback periods of 15.2 and 6.1 years. Hence only Case Study 2 is economically viable but it does not allow increasing the renewable share in the energy mix. Sensitivity analysis for Case Study 1 shows that overall efficiency and CAPEX are the main factors affecting viability highlighting the need for technological advances and economies of scale as well as the importance of public funding to promote projects like this.
Modeling Gas Producibility and Hydrogen Potential—An Eastern Mediterranean Case Study
Oct 2025
Publication
The transition to low-carbon energy systems demands robust strategies that leverage existing fossil resources while integrating renewable technologies. In this work a single-cycle Gaussian-based producibility model is developed to forecast natural gas production profiles domestic consumption export potential hydrogen production and revenues adaptive for untapped natural gas discoveries. Annual natural gas production is represented by a bell curve defined by peak year and maximum capacity allowing flexible adaptation to different reserve sizes. The model integrates renewable energy adoption and steam–methane reforming to produce hydrogen while tracking revenue streams from domestic sales exports and hydrogen markets alongside carbon taxation. Applicability is demonstrated through a case study of Eastern Mediterranean gas discoveries where combined reserves of 2399 bcm generate a production peak of 100 bcm/year in 2035 and deliver 40.71 billion kg of hydrogen by 2050 leaving 411.87 bcm of reserves. A focused Cyprus scenario with 411 bcm of reserves peaks at 10 bcm/year produces 4.07 billion kg of hydrogen and retains 212.29 bcm of reserves. Cumulative revenues span from USD 84.37 billion under low hydrogen pricing to USD 247.29 billion regionally while the Cyprus-focused case yields USD 1.79 billion to USD 18.08 billion. These results validate the model’s versatility for energy transition planning enabling strategic insights into infrastructure deployment market dynamics and resource management in gas-rich regions.
Carbon Emission Reduction Capability Analysis of Electricity–Hydrogen Integrated Energy Storage Systems
Oct 2025
Publication
Against the dual backdrop of intensifying carbon emission constraints and the large-scale integration of renewable energy integrated electricity–hydrogen energy systems (EH-ESs) have emerged as a crucial technological pathway for decarbonising energy systems owing to their multi-energy complementarity and cross-scale regulation capabilities. This paper proposes an operational optimisation and carbon reduction capability assessment framework for EH-ESs focusing on revealing their operational response mechanisms and emission reduction potential under multi-disturbance conditions. A comprehensive model encompassing an electrolyser (EL) a fuel cell (FC) hydrogen storage tanks and battery energy storage was constructed. Three optimisation objectives—cost minimisation carbon emission minimisation and energy loss minimisation—were introduced to systematically characterise the trade-offs between economic viability environmental performance and energy efficiency. Case study validation demonstrates the proposed model’s strong adaptability and robustness across varying output and load conditions. EL and FC efficiencies and costs emerge as critical bottlenecks influencing system carbon emissions and overall expenditure. Further analysis reveals that direct hydrogen utilisation outperforms the ‘electricity–hydrogen–electricity’ cycle in carbon reduction providing data support and methodological foundations for low-carbon optimisation and widespread adoption of electricity–hydrogen systems.
Hydrogen Direct Reduced Iron Melting in an Electric Arc Furnace: Benefits of In Situ Monitoring
Oct 2025
Publication
The transition toward environmentally friendly steelmaking using hydrogen direct reduced iron as feed material in electric arc furnaces will eventually require process adjustments due to changes in the pellet properties when compared to e.g. blast furnace pellets. To this end the melting of hydrogen direct reduced iron pellets with 68 and 100% reduction degrees and Fe content of 67.24% was investigated in a laboratory-scale electric arc furnace. The presence of iron oxide-rich slag had a significant effect on the arc movement on the melt and an inhibiting effect on iron evaporation. The melting was monitored with video recording and optical emission spectroscopy. The videos were used to monitor the melting behavior whereas optical emissions revealed iron gangue elements and hydrogen from the pellets radiating in the plasma. Furthermore the flow of the melt is well seen in the videos as well as the movement of slag droplets on the melt surface. After the experiments the metal had silica-rich inclusions whereas slag had mostly penetrated into the crucible. The most notable differences in melting behavior can be attributed to the iron oxide-rich slag its interaction with the arc and penetration into the crucible and how it affects the arc movement and heat transfer.
Sensitivity Analysis of Geological Parameters to Evaluate Uncertainty in Underground Hydrogen Storage Performance for a Saline Aquifer at Ketzin (Germany)
May 2025
Publication
A numerical sensitivity analysis of a hydrogen pore storage system is carried out on a reservoir-scale geological model of the Ketzin site (Germany) to analyze the influence of uncertainty in geological parameters and fluid properties on storage performance. Therefore the following physical geological parameters and fluid properties were investigated: Porosity and permeability of the reservoir rock the brine salinity relative permeability and capillary pressure and mechanical dispersion. The range of the applied parameters is based on experimental and field data of the chosen location obtained during the former CO2 storage projects at the Ketzin site from 2008 to 2013. Using the open-source reservoir software MUFITS for the numerical simulations strong differences between the results can be observed. The results were evaluated based on measures to quantify performance such as the ratio of produced hydrogen mass to produced cushion gas (nitrogen) productivity index and sustainability index. The strongest impact on the performance parameters was observed with variations in the capillary pressure and the relative permeability curves followed by the absolute permeabilities while the least impact was seen with changes in the porosity and salinity of the brine. This work is not only crucial as a pre-feasibility study for the Ketzin storage site for hydrogen storage but also as a basis for decision-making for other potential storage sites in sedimentary basins.
Mapping Hydrogen Demand for Heavy-duty Vehicles: A Spatial Disaggregation Approach
Jul 2025
Publication
Hydrogen is the key to decarbonising heavy-duty transport. Understanding the distribution of hydrogen demand is crucial for effective planning and development of infrastructure. However current data on future hydrogen demand is often coarse and aggregated limiting its utility for detailed analysis and decision-making. This study developed a spatial disaggregation approach to estimating hydrogen demand for heavy-duty trucks and mapping the spatial distribution of hydrogen demand across multiple scales in Australia. By integrating spatial datasets with economic factors market penetration rates and technical specifications of hydrogen fuel cell vehicles the approach disaggregates the projected demand into specific demand centres allowing for the mapping of regional hydrogen demand patterns and the identification of key centres of hydrogen demand based on heavy-duty truck traffic flow projections under different scenarios. This approach was applied to Australia and the findings offered valuable insights that can help policymakers and stakeholders plan and develop hydrogen infrastructure such as optimising hydrogen refuelling station locations and support the transition to a low-carbon heavy-duty transport sector.
Techno-Economic Assessment of Carbon-Neutral Ammonia Fuel for Ships from Renewable Wind Energy
Oct 2025
Publication
Climate change is fuelled by the continued growth of global carbon emissions with the widespread use of fossil fuels being the main driver. To achieve a decarbonisation transition of the energy mix the development of clean and renewable fuels has become crucial. Ammonia is seen as an important option for decarbonisation in the transport and energy sectors due to its zero-carbon emission potential and renewable energy compatibility. However the high energy consumption and carbon emissions of the conventional Haber– Bosch method limit its sustainability. A green ammonia synthesis system was designed using ECLIPSE and Excel simulations in the study. Results show that at a recirculation ratio of 70% the system’s annual total energy consumption is 426.22 GWh with annual ammonia production reaching 8342.78 t. The optimal system configuration comprises seven 12 MW offshore wind turbines integrated with a 460 MWh lithium battery and 240 t of hydrogen storage capacity. At this configuration the LCOE is approximately £5956.58/t. It shows that incorporating renewable energy can significantly reduce greenhouse gas emissions but further optimisation of energy storage configurations and reaction conditions is needed to lower costs. This research provides a reference for the industrial application of green ammonia in the transportation sector.
Comparative Techno-Economic and Life Cycle Assessment of Stationary Energy Storage Systems: Lithium-Ion, Lead-Acid, and Hydrogen
Oct 2025
Publication
This study presents a comparative techno-economic and environmental assessment of three leading stationary energy storage technologies: lithium-ion batteries lead-acid batteries and hydrogen systems (electrolyzer–tank–fuel cell). The analysis integrates Life Cycle Assessment (LCA) and Levelized Cost of Storage (LCOS) to provide a holistic evaluation. The LCA covers the full cradle-to-grave stages while LCOS accounts for capital and operational expenditures efficiency and cycling frequency. The results indicate that lithium-ion batteries achieve the lowest LCOS (120–180 EUR/MWh) and high round-trip efficiency (90–95%) making them optimal for short- and medium-duration storage. Lead-acid batteries though characterized by low capital expenditures (CAPEX) and high recyclability (>95%) show limited cycle life and lower efficiency (75–80%). Hydrogen systems remain costly (>250 EUR/MWh) and less efficient (30–40%) yet they demonstrate clear advantages for long-term and seasonal storage particularly under scenarios with “green” hydrogen production and reduced CAPEX. These findings provide practical guidance for policymakers investors and industry stakeholders in selecting appropriate storage solutions aligned with decarbonization and sustainability goals.
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