Publications
Sector Coupling and Migration towards Carbon-Neutral Power Systems
Feb 2023
Publication
There is increasing interest in migrating to a carbon-neutral power system that relies on renewable energy due to concerns about greenhouse gas emissions energy shortages and global warming. However the increasing share of renewable energy has added volatility and uncertainty to power system operations. Introducing new devices and using flexible resources may help solve the problem but expanding the domain of the problem can be another solution. Sector coupling which integrates production consumption conversion and storage by connecting various energy domains could potentially meet the needs of each energy sector. It can also reduce the generation of surplus energy and unnecessary carbon emissions. As a result sector coupling an integrated energy system increases the acceptance of renewable energy in the traditional power system and makes it carbon neutral. However difficulties in large-scale integration low conversion efficiency and economic feasibility remain obstacles. This perspective paper discusses the background definition and components of sector coupling as well as its functions and examples in rendering power systems carbon-neutral. The current limitations and outlook of sector coupling are also examined.
Energy and Environmental Assessment of Hydrogen from Biomass Sources: Challenges and Perspectives
Aug 2022
Publication
Hydrogen is considered as one of the pillars of the European decarbonisation strategy boosting a novel concept of the energy system in line with the EU’s commitment to achieve clean energy transition and reach the European Green Deal carbon neutrality goals by 2050. Hydrogen from biomass sources can significantly contribute to integrate the renewable hydrogen supply through electrolysis at large-scale production. Specifically it can cover the non-continuous production of green hydrogen coming from solar and wind energy to offer an alternative solution to such industrial sectors necessitating of stable supply. Biomass-derived hydrogen can be produced either from thermochemical pathways (i.e. pyrolysis liquefaction and gasification) or from biological routes (i.e. direct or indirect-biophotolysis biological water–gas shift reaction photo- and dark-fermentation). The paper reviews several production pathways to produce hydrogen from biomass or biomass-derived sources (biogas liquid bio-intermediates sugars) and provides an exhaustive review of the most promising technologies towards commercialisation. While some pathways are still at low technology readiness level others such as the steam bio-methane reforming and biomass gasification are ready for an immediate market uptake. The various production pathways are evaluated in terms of energy and environmental performances highlighting the limits and barriers of the available LCA studies. The paper shows that hydrogen production technologies from biomass appears today to be an interesting option almost ready to constitute a complementing option to electrolysis.
The Roles of Nuclear Energy in Hydrogen Production
Dec 2021
Publication
Fossil resources are unevenly distributed on the earth and are finite primary energy which is widely used in the fields of industry transportation and power generation etc.<br/>Primary energies that can replace fossil resources include renewable energy and nuclear energy. Hydrogen has the potential to be secondary energy that can be widely used in industry for various purposes. Nuclear energy can be used for producing hydrogen; it is becoming more important to convert this primary energies into hydrogen. This paper describes the roles of nuclear energy as a primary energy in hydrogen production from the viewpoint of the basics of energy form conversion.
An Overview on Safety Issues Related to Hydrogen and Methane Blend Applications in Domestic and Industrial Use
Sep 2017
Publication
The share of electrical energy hailing from renewable sources in the European electricity mix is increasing. The match between renewable power supply and demand has become the greatest challenge to cope with. Gas infrastructure can accommodate large volumes of electricity converted into gas whenever this supply of renewable power is larger than the grid capacity or than the electricity demand. The Power-to-Gas (P2G) process chain could play a significant role in the future energy system. Renewable electric energy can be transformed into storable hydrogen via electrolysis and subsequent methanation. The aim of this paper is to provide an overview of the required technical adaptations of the most common devices for end users such as heating plants CHP systems home gas furnaces and cooking surfaces wherever these are fuelled with methane and hydrogen blends in variable percentages by volume. Special attention will be given to issues related to essential safety standards firstly comparing existing Italian and European regulations in this regard and secondly highlighting the potential need for legislation to regulate the suitability of hydrogen methane blends. Finally a list of foreseeable technical solutions will be provided and discussed thoroughly
Operation of a Circular Economy, Energy, Environmental System at a Wastewater Treatment Plant
Oct 2022
Publication
Decarbonising economies and improving environment can be enhanced through circular economy energy and environmental systems integrating electricity water and gas utilities. Hydrogen production can facilitate intermittent renewable electricity through reduced curtailment of electricity in periods of over production. Positioning an electrolyser at a wastewater treatment plant with existing sludge digesters offers significant advantages over stand-alone facilities. This paper proposes co-locating electrolysis and biological methanation technologies at a wastewater treatment plant. Electrolysis can produce oxygen for use in pure or enhanced oxygen aeration offering a 40% reduction in emissions and power demand at the treatment facility. The hydrogen may be used in a novel biological methanation system upgrading carbon dioxide (CO2)in biogas from sludge digestion yielding a 54% increase in biomethane production. A 10MW electrolyser operating at 80% capacity would be capable of supplying the oxygen demand for a 426400 population equivalent wastewater treatment plant producing 8500 tDS/a of sludge. Digesting the sludge could generate 1409000 m 3 CH4/a and 776000 m 3 CO2/a. Upgrading the CO2 to methane would consume 22.2% of the electrolyser generated hydrogen and capture 1.534 ktCO2e/a. Hydrogen and methane are viable advanced transport fuels that can be utilised in decarbonising heavy transport. In the proposed circular economy energy and environment system sufficient fuel would be generated annually for 94 compressed biomethane gas (CBG) heavy goods vehicles (HGV) and 296 compressed hydrogen gas fuel cell (CHG) HGVs. Replacement of the equivalent number of diesel HGVs would offset approximately 16.1 ktCO2e/a.
Role of Low Carbon Emission H2 in the Energy Transition of Colombia: Environmental Assessment of H2 Production Pathways for a Certification Scheme
Oct 2022
Publication
Hydrogen (H2) is a low-carbon carrier. Hence measuring the impact of its supply chain is key to guaranteeing environmental benefits. This research proposes a classification of H2 in Colombia based on its carbon footprint and source. Such environmental characterization enables the design of regulatory instruments to incentivize the demand for low carbon-H2. Life cycle assessment (LCA) was used to determine the carbon footprint of H2 production technologies. Based on our LCA four classes of H2 were defined based on the emission threshold: (i) gray-H2 (21.8 - 17.0 kg CO2-eq/kg H2) (ii) low carbon-H2 (4.13 – 17.0 kg CO2-eq/kg H2) (iii) blue-H2 (<4.13 kg CO2-eq/kg H2) and (iv) green-H2 (<4.13 kg CO2-eq/kg H2). While low carbon-H2 could be employed to reduce 22% of the national greenhouse gas (GHG) emissions as defined in the National Determined Contribution (NDC) both blue and green-H2 could be employed for national and international trade since the standard emissions are aligned with international schemes such as CertifHy and the Chinese model. Besides gasification of biomass results in environmental savings indicating that biomass is a promising feedstock for international and local trade. Furthermore combinations of H2 production technologies such as renewable-based electrolysis natural gas steam reforming with CCS and ethanol conversion were evaluated to explore the production of a combination of green- and blue-H2 to meet the current and future demand of low carbon emission H2 in Colombia. However to comply with the proposed carbon emission threshold the installed capacities of solar and wind energies must be increase.
Multi-layer Coordinated Optimization of Integrated Energy System with Electric Vehicles Based on Feedback Correction
Sep 2022
Publication
The integrated energy system with electric vehicles can realize multi-energy coordination and complementarity and effectively promote the realization of low-carbon environmental protection goals. However the temporary change of vehicle travel plan will have an adverse impact on the system. Therefore a multi-layer coordinated optimization strategy of electric-thermal-hydrogen integrated energy system including vehicle to grid (V2G) load feedback correction is proposed. The strategy is based on the coordination of threelevel optimization. The electric vehicle charging and discharging management layer comprehensively considers the variance of load curve and the dissatisfaction of vehicle owners and the charging and discharging plan is obtained through multi-objective improved sparrow search algorithm which is transferred to the model predictive control rolling optimization layer. In the rolling optimization process according to the actual situation selectively enter the V2G load feedback correction layer to update V2G load so as to eliminate the impact of temporary changes in electric vehicle travel plans. Simulation results show that the total operating cost with feedback correction is 4.19% lower than that without feedback correction and tracking situation of tie-line planned value is improved which verifies the proposed strategy.
Strategic Policy Targets and the Contribution of Hydrogen in a 100% Renewable European Power System
Jul 2021
Publication
The goal of the European energy policy is to achieve climate neutrality. The long-term energy strategies of various European countries include additional targets such as the diversification of energy sources maintenance of security of supply and reduction of import dependency. When optimizing energy systems these strategic policy targets are often only considered in a rudimentary manner and thus the understanding of the corresponding interdependencies is lacking. Moreover hydrogen is considered as a key component of a fully decarbonized energy system but its role in the power sector remains unclear due to the low round-trip efficiencies. This study reveals how fully decarbonized European power systems can benefit from hydrogen in terms of overall system costs and the achievement of strategic policy targets. We analyzed a broad spectrum of scenarios using an energy system optimization model and varied model constraints that reflect strategic policy targets. Our results are threefold. First compared to power systems without hydrogen systems using hydrogen realize savings of 14–16% in terms of the total system costs. Second the implementation of a hydrogen infrastructure reduces the number of infeasible scenarios when structural policy targets are considered within the power system. Third the role of hydrogen is highly diverse at a national level. Particularly in countries with low renewable energy potential hydrogen plays a crucial role. Here high levels of self-sufficiency and security of supply are achieved by deploying hydrogen-based power generation of up to 46% of their annual electricity demand realized via imports of green hydrogen.
The Key Techno-Economic and Manufacturing Drivers for Reducing the Cost of Power-to-Gas and a Hydrogen-Enabled Energy System
Jul 2021
Publication
Water electrolysis is a process which converts electricity into hydrogen and is seen as a key technology in enabling a net-zero compatible energy system. It will enable the scale-up of renewable electricity as a primary energy source for heating transport and industry. However displacing the role currently met by fossil fuels might require a price of hydrogen as low as 1 $/kg whereas renewable hydrogen produced using electrolysis is currently 10 $/kg. This article explores how mass manufacturing of proton exchange membrane (PEM) electrolysers can reduce the capital cost and thus make the production of renewable power to hydrogen gas (PtG) more economically viable. A bottom up direct manufacturing model was developed to determine how economies of scale can reduce the capital cost of electrolysis. The results demonstrated that (assuming an annual production rate of 5000 units of 200 kW PEM electrolysis systems) the capital cost of a PEM electrolysis system can reduce from 1990 $/kW to 590 $/kW based on current technology and then on to 431 $/kW and 300 $/kW based on the an installed capacity scale-up of ten- and one-hundred-fold respectively. A life-cycle costing analysis was then completed to determine the importance of the capital cost of an electrolysis system to the price of hydrogen. It was observed that based on current technology mass manufacturing has a large impact on the price of hydrogen reducing it from 6.40 $/kg (at 10 units units per year) to 4.16 $/kg (at 5000 units per year). Further analysis was undertaken to determine the cost at different installed capacities and found that the cost could reduce further to 2.63 $/kg and 1.37 $/kg based on technology scale-up by ten- and one hundred-fold respectively. Based on the 2030 (and beyond) baseline assumptions it is expected that hydrogen production from PEM electrolysis could be used as an industrial process feed stock provide power and heat to buildings and as a fuel for heavy good vehicles (HGVs). In the cases of retrofitted gas networks for residential or industrial heating solutions or for long distance transport it represents a more economically attractive and mass-scale compatible solution when compared to electrified heating or transport solutions.
Blast Wave Generated by Delayed Ignition of Under-Expanded Hydrogen Free Jet at Ambient and Cryogenic Temperatures
Nov 2022
Publication
An under-expanded hydrogen jet from high-pressure equipment or storage tank is a potential incident scenario. Experiments demonstrated that the delayed ignition of a highly turbulent under-expanded hydrogen jet generates a blast wave able to harm people and damage property. There is a need for engineering tools to predict the pressure effects during such incidents to define hazard distances. The similitude analysis is applied to build a correlation using available experimental data. The dimensionless blast wave overpressure generated by delayed ignition and the follow-up deflagration or detonation of hydrogen jets at an any location from the jet ∆Pexp/P0 is correlated to the original dimensionless parameter composed of the product of the dimensionless ratio of storage pressure to atmospheric pressure Ps/P0 and the ratio of the jet release nozzle diameter to the distance from the centre of location of the fast-burning near-stoichiometric mixture on the jet axis (30% of hydrogen in the air by volume) to the location of a target (personnel or property) d/Rw. The correlation is built using the analysis of 78 experiments regarding this phenomenon in the wide range of hydrogen storage pressure of 0.5–65.0 MPa and release diameter of 0.5–52.5 mm. The correlation is applicable to hydrogen free jets at ambient and cryogenic temperatures. It is found that the generated blast wave decays inversely proportional to the square of the distance from the fast-burning portion of the jet. The correlation is used to calculate the hazard distances by harm thresholds for five typical hydrogen applications. It is observed that in the case of a vehicle with onboard storage tank at pressure 70 MPa the “no-harm” distance for humans reduces from 10.5 m to 2.6 m when a thermally activated pressure relief device (TPRD) diameter decreases from 2 mm to a diameter of 0.5 mm.
On the Road to Sustainable Transport: Acceptance and Preferences for Renewable Fuel Production Infrastructure
Sep 2022
Publication
To abate climate change and ameliorate the air quality in urban areas innovative solutions are required to reduce CO2 and pollutant emissions from traffic. Alternative fuels made from biomass or CO2 and hydrogen can contribute to these goals by substituting fossil gasoline or diesel in combustion engines. Using a conjoint analysis approach the current study investigates preferences of laypeople (n = 303) for fuel production facilities in terms of siting location plant size raw material used in the production and raw material transport. The location was most decision-relevant followed by raw material transport whereas plant size and type of raw material played a less prominent role for the preference choice. The best-case scenario from the point of view of acceptance would be the installation of a rather small bio-hybrid fuel production plant in an industrial area (instead of an agricultural or pristine environment). No transport or transport via underground pipeline were preferred over truck/tank car or overground pipeline. The findings can be used as a basis for planning and decision-making for designing production networks for new fuel types.
Planetary Boundaries Assessment of Deep Decarbonisation Options for Building Heating in the European Union
Jan 2023
Publication
Building heating is one of the sectors for which multiple decarbonisation options exist and current geopolitical tensions provide urgency to design adequate regional policies. Heat pumps and hydrogen boilers alongside alternative district heating systems are the most promising alternatives. Although a host of city or country-level studies exist it remains controversial what role hydrogen should play for building heating in the European Union compared with electrification and how blue and green hydrogen differ in terms of costs and environmental impacts. This works assesses the optimal technology mix for staying within planetary boundaries and the influence of international cooperation and political restrictions. To perform the analysis a bottom-up optimisation model was developed incorporating life cycle assessment constraints and covering production storage transport of energy and carbon dioxide as well as grid and non-grid connected end-users of heat. It was found that a building heating system within planetary boundaries is feasible through large-scale electrification via heat pumps although at a higher cost than the current system with abatement costs of around 200 €/ton CO2. Increasing interconnector capacity or onshore wind energy is found to be vital to staying within boundaries. A strong trade-off for hydrogen was identified with blue hydrogen being cost-competitive but vastly unsustainable (when applied to heating) and green hydrogen being 2–3 times more expensive than electrification while still transgressing several planetary boundaries. The insights from this work indicate that heat pumps and renewable electricity should be prioritised over hydrogen-based heating in most cases and grid-stability and storage aspects explored further while revealing a need for policy instruments to mitigate increased costs for consumers.
A Comparison of Two Hydrogen Storages in a Fossil Free Direct Reduced Iron Process
Jul 2021
Publication
Hydrogen direct reduction has been proposed as a means to decarbonize primary steelmaking. Preferably the hydrogen necessary for this process is produced via water electrolysis. A downside to electrolysis is the large electricity demand. The electricity cost of water electrolysis may be reduced by using a hydrogen storage to exploit variations in electricity price i.e. producing more hydrogen when the electricity price is low and vice versa. In this paper we compare two kinds of hydrogen storages in the context of a hydrogen direct reduction process via simulations based on historic Swedish electricity prices: the storage of gaseous hydrogen in an underground lined rock cavern and the storage of hydrogen chemically bound in methanol. We find the methanol-based storages to be economically advantageous to lined rock caverns in several scenarios. The main advantages of methanol-based storage are the low investment cost of storage capacity and the possibility to decouple storage capacity from rate capacity. Nevertheless no storage option is found to be profitable for historic Swedish electricity prices. For the storages to be profitable electricity prices must be volatile with relatively frequent high peaks which has happened rarely in Sweden in recent years. However such scenarios may become more common with the expected increase of intermittent renewable power in the Swedish electricity system.
Hydrogen Economy Model for Nearly Net-Zero Cities with Exergy Rationale and Energy-Water Nexus
May 2018
Publication
The energy base of urban settlements requires greater integration of renewable energy sources. This study presents a “hydrogen city” model with two cycles at the district and building levels. The main cycle comprises of hydrogen gas production hydrogen storage and a hydrogen distribution network. The electrolysis of water is based on surplus power from wind turbines and third-generation solar photovoltaic thermal panels. Hydrogen is then used in central fuel cells to meet the power demand of urban infrastructure. Hydrogen-enriched biogas that is generated from city wastes supplements this approach. The second cycle is the hydrogen flow in each low-exergy building that is connected to the hydrogen distribution network to supply domestic fuel cells. Make-up water for fuel cells includes treated wastewater to complete an energy-water nexus. The analyses are supported by exergy-based evaluation metrics. The Rational Exergy Management Efficiency of the hydrogen city model can reach 0.80 which is above the value of conventional district energy systems and represents related advantages for CO2 emission reductions. The option of incorporating low-enthalpy geothermal energy resources at about 80 ◦C to support the model is evaluated. The hydrogen city model is applied to a new settlement area with an expected 200000 inhabitants to find that the proposed model can enable a nearly net-zero exergy district status. The results have implications for settlements using hydrogen energy towards meeting net-zero targets.
Assessment of Hydrogen Fuel for Rotorcraft Applications
Jun 2022
Publication
This paper presents the application of a multidisciplinary approach for the preliminary design and evaluation of the potential improvements in performance and environmental impact through the utilization of compressed (CGH2) and liquefied (LH2) hydrogen fuel for a civil tilt-rotor modelled after the NASA XV-15. The methodology deployed comprises models for rotorcraft flight dynamics engine performance flight path analysis hydrogen tank and thermal management system sizing. Trade-offs between gravimetric efficiency energy consumption fuel burn CO2 emissions and cost are quantified and compared to the kerosene-fuelled rotorcraft. The analysis carried out suggests that for these vehicle scales gravimetric efficiencies of the order of 13% and 30% can be attained for compressed and liquid hydrogen storage respectively leading to reduced range capability relative to the baseline tilt-rotor by at least 40%. At mission level it is shown that the hydrogen-fuelled configurations result in increased energy consumption by at least 12% (LH2) and 5% (CGH2) but at the same time significantly reduced life-cycle carbon emissions compared to the kerosene counterpart. Although LH2 storage at cryogenic conditions has a higher gravimetric efficiency than CGH2 (at 700 bar) it is shown that for this class of rotorcraft the latter is more energy efficient when the thermal management system for fuel pressurization and heating prior to combustion is accounted for.
Research on the Sealing Mechanism of Split-Liner High-Pressure Hydrogen Storage Cylinders
Mar 2024
Publication
Hydrogen storage is a crucial factor that limits the development of hydrogen energy. This paper proposes using a split liner for the inner structure of a hydrogen storage cylinder. A self-tightening seal is employed to address the sealing problem between the head and the barrel. The feasibility of this structure is demonstrated through hydraulic pressure experiments. The influence laws of the O-ring compression rate the distance from the straight edge section of the head to the sealing groove and the thickness of the head on the sealing performance of gas cylinders in this sealing structure are revealed using finite elements analysis. The results show that when the gas cylinder is subjected to medium internal pressure the maximum contact stress on the O-ring extrusion deformation sealing surface is greater than the medium pressure. There is sufficient contact width that is the arc length of the part where the stress on the O-ring contact surface is greater than the medium pressure so that it can form a good sealing condition. At the same time increasing the compression ratio of the O-ring and the head’s thickness will help improve the sealing performance and reducing the distance from the straight edge section of the head to the sealing groove will also improve the sealing performance.
Clean Energy Futures: An Australian Based Foresight Study
Aug 2022
Publication
Political decarbonisation commitments and outcompeting renewable electricity costs are disrupting energy systems. This foresight study prepares stakeholders for this dynamic reactive change by examining visions that constitute a probable plausible and possible component of future energy systems. Visions were extrapolated through an expert review of energy technologies and Australian case studies. ‘Probable–Abundant’ envisages a high penetration of solar and wind with increased value of balancing services: batteries pumped hydro and transmission. This vision is exemplified by the South Australian grid where variable and distributed sources lead generation. ‘Plausible–Traded’ envisages power and power fuel exports given hydrogen and high-voltage direct-current transmission advances reflected by public and private sector plans to leverage rich natural resources for national and intercontinental exchanges. ‘Possible–Zero’ envisages the application of carbon removal and nuclear technologies in response to the escalating challenge of deep decarbonisation. The Australian critical minerals strategy signals adaptations of high-emission industries to shifting energy resource values. These visions contribute a flexible accessible framework for diverse stakeholders to discuss uncertain energy systems changes and consider issues from new perspectives. Appraisal of preferred futures allows stakeholders to recognise observed changes as positive or negative and may lead to new planning aspirations.
Stand-off Detection of Hydrogen Concentration
Sep 2021
Publication
The ability to remotely monitor hydrogen and map its concentration is a pressing challenge in large scale production and distribution as well as other sectors such as nuclear storage. We present a photonicsbased approach for the stand-off sensing and mapping of hydrogen concentration capable of detecting and locating <0.1% concentrations at 100m distance. The technique identifies the wavelength of light resulting from interaction with laser pulses via Raman scattering and can identify a range of other gas species e.g. hydrocarbons ammonia by the spectroscopic analysis of the wavelengths present in the return signal. LIDAR Light Detection and Ranging – analogous to Radar is used for ranging. Laserbased techniques for the stand-off detection of hydrocarbons frequently employ absorption of light at specific wavelengths which are characteristic of the gas species. Unfortunately Hydrogen does not exhibit strong absorption however it does exhibit strong Raman scattering when excited in the UV wavelength range. Raman scattering is a comparatively weak effect. However the use of solid-state detectors capable of detecting single photons known as SPADS (Single Photon Avalanche Photodiode) enables the detection of low concentrations at range while making use of precise time-of-flight range location correlation. The initial safety case which necessitated our development of stand-off hydrogen sensing was the condition monitoring of stored nuclear waste supported and funded by Sellafield and the National Nuclear Laboratory in the UK. A deployable version of the device has been developed and hydrogen characterisation has been carried out in an active nuclear store. Prior to deployment a full ignition risk assessment was carried out. To the best of our knowledge this technique is the strongest candidate for the remote stand-off sensing of hydrogen.
Multi-vector Energy Management System including Scheduling Electrolyser, Electric Vehicle Charging Station and Other Assets in a Real Scenario
Oct 2022
Publication
Today in the field of energy the main goal is to reduce emissions with 7 the aim of maintaining a clean environment. To reduce energy consumption 8 from fossil fuels new tools for micro-grids have been proposed. In the context 9 of multi-vector energy management systems the present work proposes an 10 optimal scheduler based on genetic algorithms to manage flexible assets in the 11 energy system such as energy storage and manageable demand. This tool is 12 applied to a case study for a Spanish technology park (360 kW consumption 13 peak) with photovoltaic and wind generation (735 kW generation peak) 14 hydrogen production (15 kW) and electric and fuel cell charging stations. 15 It provides an hourly day-ahead scheduling for the existing flexible assets: 16 the electrolyser the electric vehicle charging station the hydrogen refuelling 17 station and the heating ventilation and air conditioning system in one 18 building of the park. 19 A set of experiments is carried out over a period of 14 days using real 20 data and performing computations in real time in order to test and validate 21 the tool. The analysis of results show that the solution maximises the use of 22 local renewable energy production (demand is shifted to those hours when 23 there is a surplus of generation) which means a reduction in energy costs 24 whereas the computational cost allows the implementation of the tool in real 25 time.
Techno-Economic Analysis of Hydrogen Storage Technologies for Railway Engineering: A Review
Sep 2022
Publication
According to the specific requirements of railway engineering a techno-economic comparison for onboard hydrogen storage technologies is conducted to discuss their feasibility and potentials for hydrogen-powered hybrid trains. Physical storage methods including compressed hydrogen (CH2 ) liquid hydrogen (LH2 ) and cryo-compressed hydrogen (CcH2 ) and material-based (chemical) storage methods such as ammonia liquid organic hydrogen carriages (LOHCs) and metal hydrides are carefully discussed in terms of their operational conditions energy capacity and economic costs. CH2 technology is the most mature now but its storage density cannot reach the final target which is the same problem for intermetallic compounds. In contrast LH2 CcH2 and complex hydrides are attractive for their high storage density. Nevertheless the harsh working conditions of complex hydrides hinder their vehicular application. Ammonia has advantages in energy capacity utilisation efficiency and cost especially being directly utilised by fuel cells. LOHCs are now considered as a potential candidate for hydrogen transport. Simplifying the dehydrogenation process is the important prerequisite for its vehicular employment. Recently increasing novel hydrogen-powered trains based on different hydrogen storage routes are being tested and optimised across the world. It can be forecasted that hydrogen energy will be a significant booster to railway decarbonisation.
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