Publications

In this paper a new isolated hybrid system is simulated and analyzed to obtain the optimal sizing and meet the electricity demand with cost improvement for servicing a small remote area with a peak load of 420 kW. The major configuration of this hybrid system is Photovoltaic (PV) modules Biomass gasifier (BG) Electrolyzer units Hydrogen Tank units (HT) and Fuel Cell (FC) system. A recent optimization algorithm namely Mayfly Optimization Algorithm (MOA) is utilized to ensure that all load demand is met at the lowest energy cost (EC) and minimize the greenhouse gas (GHG) emissions of the proposed system. The MOA is selected as it collects the main merits of swarm intelligence and evolutionary algorithms; hence it has good convergence characteristics. To ensure the superiority of the selected MOA the obtained results are compared with other well-known optimization algorithms namely Sooty Tern Optimization Algorithm (STOA) Whale Optimization Algorithm (WOA) and Sine Cosine Algorithm (SCA). The results reveal that the suggested MOA achieves the best system design achieving a stable convergence characteristic after 44 iterations. MOA yielded the best EC with 0.2106533 $/kWh the net present cost (NPC) with 6170134 $ the loss of power supply probability (LPSP) with 0.05993% and GHG with 792.534 t/y.

The National Renewable Energy Laboratory’s (NREL) Hydrogen Safety Research and Development (HSR&D) program in collaboration with the University of Maryland’s Systems Risk and Reliability Analysis Laboratory (SyRRA) are working to improve reliability and reduce risk in hydrogen systems. This approach strives to use quantitative data on component leaks and failures together with Prognosis and Health Management (PHM) and Quantitative Risk Assessment (QRA) to identify atrisk components reduce component failures and downtime and predict when components require maintenance. Hydrogen component failures increase facility maintenance cost facility downtime and reduce public acceptance of hydrogen technologies ultimately increasing facility size and cost because of conservative design requirements. Leaks are a predominant failure mode for hydrogen components. However uncertainties in the amount of hydrogen emitted from leaking components and the frequency of those failure events limit the understanding of the risks that they present under real-world operational conditions. NREL has deployed a test fixture the Leak Rate Quantification Apparatus (LRQA) to quantify the mass flow rate of leaking gases from medium and high-pressure components that have failed while in service. Quantitative hydrogen leak rate data from this system could ultimately be used to better inform risk assessment and Regulation Codes and Standards (RCS). Parallel activity explores the use of PHM and QRA techniques to assess and reduce risk thereby improving safety and reliability of hydrogen systems. The results of QRAs could further provide a systematic and science-based foundation for the design and implementation of RCS as in the latest versions of the NFPA 2 code for gaseous hydrogen stations. Alternatively data-driven techniques of PHM could provide new damage diagnosis and health-state prognosis tools. This research will help end users station owners and operators and regulatory bodies move towards risk-informed preventative maintenance versus emergency corrective maintenance reducing cost and improving reliability. Predictive modelling of failures could improve safety and affect RCS requirements such as setback distances at liquid hydrogen fueling sites. The combination of leak rate quantification research PHM and QRA can lead to better informed models enabling data-based decision to be made for hydrogen system safety improvements.

Hydrogen has emerged as a new energy vector beyond its usual role as an industrial feedstock primarily for the production of ammonia methanol and petroleum refining. In addition to environmental sustainability issues energy-scarce developed countries such as Japan and Korea are also facing an energy security issue and hydrogen or hydrogen carriers such as ammonia and methylcyclohexane seem to be options to address these long-term energy availability issues. China has been eagerly developing renewable energy and hydrogen infrastructure to meet their sustainability goals and the growing energy demand. In this review we focus on hydrogen electrification through proton-exchange membrane fuel cells (PEMFCs) which are widely believed to be commercially suitable for automotive applications particularly for vehicles requiring minimal hydrogen infrastructure support such as fleets of taxies buses and logistic vehicles. This review covers all the key components of PEMFCs thermal and water management and related characterization techniques. A special consideration of PEMFCs in automotive applications is the highlight of this work leading to the infrastructure development for hydrogen generation storage and transportation. Furthermore national strategies toward the use of hydrogen are reviewed thereby setting the rationale for the hydrogen economy.

The potentials of phenolic productions from lignin and black liquor (BL) via hydrothermal technology with the aids of alkalis and hydrogen donors were investigated by conducting batch experiments in micro-tube reactors with 300 °C sub-critical water as the solvent. The results showed that all the employed alkalis improved lignin degradation and thus phenolics production and the strong alkalis additionally manifested deoxygenation to produce more phenolics free of methoxyl group(s). Relatively hydrogen donors more visibly facilitated phenolics formation. Combination of strong alkali and hydrogen donors exhibited synergistically positive effects on producing phenolics (their total yield reaching 22 wt%) with high selectivities to phenolics among which the yields of catechol and cresols respectively peaked 16 and 3.5 wt%. BL could be hydrothermally converted into phenolics at high yields (approaching 10 wt% with the yields of catechol and cresols of about 4 and 2 wt% respectively) with the aids of its inherent alkali and hydrogen donors justifying its cascade utilization.

Carbon capture and storage (CCS) and hydrogen will be a catalyst to deeply decarbonize the world’s energy system but not for another 15 years according to DNV’s Energy Transition Outlook. Many aspects from policy to technology developments can help to scale these technologies and accelerate the timeline.<br/>In the report A System-Approach to Data can Help Install Trust and Enable a Net Zero Future DNV considers what role data could play to support the initiation execution and operation of CCS and hydrogen projects.<br/>The research is based on interviews with representatives from across the UK energy supply chain. It focuses in particular on the emerging carbon and hydrogen industries and the cross sectoral challenges they face. It explores how data can facilitate the flow of the product both with respect to fiscal and technical risk matters.<br/>The report is intended for anyone involved in or has an interest in CCUS or hydrogen projects and in how data eco-systems will support the efficient operation and the transition to net-zero.<br/>DNV produced the report for and in partnership with the ODI an organization that advocates for the innovative use of open data to affect positive change across the globe.

The H2@Scale program of the U.S. Department of Energy (DOE) Hydrogen and Fuel Cell Technologies Office (HFTO) is supporting work on the hydrogen compatibility of polymers to improve the durability and reliability of materials for hydrogen infrastructure. The hydrogen compatibility program (H-Mat) seeks “to address the challenges of hydrogen degradation by elucidating the mechanisms of hydrogen-materials interactions with the goal of providing science-based strategies to design materials (micro)structures and morphology with improved resistance to hydrogen degradation.” Previous work on ethylene propylene diene indicated hydrogen interaction with plasticizer increased its migration to the surface and coalescing within the elastomer compound. New research on nitrile butadiene (NBR) has found hydrogen and pressure interactions with a series model rubber-material compounds to behave similarly in some compounds and improved in other compounds that is demonstrated through volume change and compression-set differences in the materials. Further studies were conducted using a helium-ion microscope (HeIM) which revealed significant morphological changes in the plasticizer-incorporating compounds after static exposure and pressure cycling as evidenced by time-of-flight secondary ion mass spectrometry. Additional studies using x-ray chromatography revealed that more micro-voids/-cracks developed after gas decompression in unfilled materials than in filled materials; transmission electron microscopy (TEM) probed at the nano-meter level showing change in filler distribution and morphology around Zinc-based particles.

Global energy sources are being transformed from hydrocarbon-based energy sources to renewable and carbon-free energy sources such as wind solar and hydrogen. The biggest challenge with hydrogen as a renewable energy carrier is the storage and delivery system’s complexity. Therefore other media such as ammonia for indirect storage are now being considered. Research has shown that at reasonable pressures ammonia is easily contained as a liquid. In this form energy density is approximately half of that of gasoline and ten times more than batteries. Ammonia can provide effective storage of renewable energy through its existing storage and distribution network. In this article we aimed to analyse the previous studies and the current research on the preparation of ammonia as a next-generation renewable energy carrier. The study focuses on technical advances emerging in ammonia synthesis technologies such as photocatalysis electrocatalysis and plasmacatalysis. Ammonia is now also strongly regarded as fuel in the transport industrial and power sectors and is relatively more versatile in reducing CO₂ emissions. Therefore the utilisation of ammonia as a renewable energy carrier plays a significant role in reducing GHG emissions. Finally the simplicity of ammonia processing transport and use makes it an appealing choice for the link between the development of renewable energy and demand.

The article proposes the use of the analytic hierarchy process (AHP) method to select a risk assessment technique associated with underground hydrogen storage. The initial choosing and ranking of risk assessment techniques can be considered as a multi-criteria decision problem. The usage of a decision model based on six criteria is proposed. A ranking of methods for estimating the risks associated with underground hydrogen storage is presented. The obtained results show that the application of the AHP-based approach may be a useful tool for selecting the UHS risk assessment technique. The proposed method makes it possible to make an objective decision of the most satisfactory approach from the point of view of all the adopted decision criteria regarding the selection of the best risk assessment technique.

The objective of this paper is to derive for the first time decarbonization roadmaps for the ten nations of ASEAN. This study first presents a regional view of ASEAN’s fossil and renewable energy usage and energy-related CO2 emission. Results show that renewable energies have been losing ground to fossil energies in the last two decades and fossil fuels will likely continue to be an important part of ASEAN’s energy mix for the next few decades. Therefore decarbonizing efforts should focus not only on increasing the share of renewable energies in electricity generation but also on technologies to reduce CO2 emission from fossil power and industrial plants. This study next performs a technology mapping exercise for all ten ASEAN countries to determine decarbonization technologies that have high impact and high readiness for individual countries. Besides installing more sustainable renewable energies common themes coming from these roadmaps include switching from coal to gas for power generation using carbon capture and storage (CCS) technologies to decarbonize fossil and industrial plants replacing internal combustion vehicles by electric vehicles and for countries that have coal and natural gas resources upgrading them to blue hydrogen by chemical processes and using CCS to mitigate the emitted CO2. Blue hydrogen can be used to decarbonize hard-to-decarbonize industries. Policy implications of these roadmaps include imposing a credible carbon tax establishing a national hydrogen strategy intergovernmental coordination to establish regional CCS corridors funding research and development to improve carbon capture efficiency on a plant level and resolving sustainability issues of hydropower and bioenergy in ASEAN.

Renewable green fuels (RGF) such as hydrogen are the global energy future. Air pollution is compounded with climate change as the emissions driving both development problems come largely from the same source of fossil fuel burning. As an energy exporter Australian energy export dominates the total energy production and the RGF has become central to the current proposal of Australian government to reach net zero emission. The hydrogen production from solar panels only on 3% of Australia's land area could compensate 10 times of Germany's non-electricity energy consumption. In the unique geographic position Australia's RGF export attracts significant costs for long distance onboard storage and shipping. While the cost reduction of RGF production relies on technological advancement which needs a long time the storage and shipping costs must be minimised for Australia to remain competitive in the global energy market. The present review concentrates on Australian export pathways of lifecycles of liquid renewable green fuels including renewable liquified hydrogen (LH2) liquified methane (LCH4) ammonia (NH3) and methanol (CH3OH) as liquid RGF have the advantages of adopting the existing infrastructure. This review compares the advantages and disadvantages of discussed renewable energy carriers. It is found that the cost of LH2 pathway can be acceptable for shipping distance of up to 7000 km (Asian countries such as Japan) but ammonia (NH3) or methanol (CH3OH) pathways may be more cost effective for shipping distance above 7000 km for European counties such as Germany. These observations suggest the proper fuel forms to fulfill the requirements to different customers and hence will highlight Australia's position as one of major exporters of renewable energy in the future. Detailed techno-economic analysis is worth to be done for supplying more quantitative results.