Publications
A Probabilistic Framework for the Techno-economic Assessment of Smart Energy Hubs for Electric Vehicle Charging
Apr 2022
Publication
Smart energy hubs (Smart Hubs) equipped with Vehicle-to-Grid (V2G) charging photovoltaic (PV) energy generation and hydrogen storage capabilities are an emerging technology with potential to alleviate the impact of electric vehicles (EV) on the electricity grid. Their operation however is characterised by intermittent PV energy generation as well as uncertainties in EV traffic and driver preference. These uncertainties when combined with the need to maximise their financial return while guaranteeing driver satisfaction yields a challenging decision-making problem. This paper presents a novel Monte-Carlo-based modelling and computational framework for simulating the operation of Smart Hubs — providing a means for a holistic assessment of their technical and financial viability. The framework utilises a compact and representative mathematical model accounting for power losses PV module degradation variability in EV uptake price inflation driver preference and diversity in charge points and EVs. It provides a comprehensive approach for dealing with uncertainties and dependencies in EV data while being built on an energy management algorithm that maximises revenue generation ensures driver satisfaction and preserves battery life. The energy management problem is formulated as a mixed-integer linear programming problem constituting a business case that includes an adequate V2G reward model for drivers. To demonstrate its applicability the framework was used to assess the financial viability of a fleet management site for various caps on vehicle stay at the site. From the assessment controlled charging was found to be more financially rewarding in all cases yielding between 1.7% and 3.1% more revenue than uncontrolled charging. The self-consumption of the site was found to be nearly 100% due mainly to local load shifting and dispatchable hydrogen generation. V2G injection was however negligible — suggesting its unattractiveness for sites that do not participate in the demand side response market. Overall the numerical results obtained validate the applicability of the proposed framework as a decision-support tool in the sustainable design and operation of Smart Hubs for EV charging.
Remarkable Visible-light Induced Hydrogen Generation with ZnIn2S4 Microspheres/CuInS2 Quantum Dots Photocatalytic System
Oct 2020
Publication
A new and active material in the form of ZnIn2S4 microspheres decorated by CuInS2 quantum dots have been obtained by hydrothermal method for the first time. The optimum amount of CuInS2 quantum dots (1.13 wt.%) introduced into rection medium during ZnIn2S4 microspheres synthesis increased the photocatalytic H2 generation rate by 2.5 times than that of bare ZnIn2S4 photocatalysis under visible light irradiation. This sample exhibited strong photoactivity in the extended visible range up to 540 nm with 30.6% apparent quantum efficiency (λ = 420 nm).
Electric and Hydrogen Rail: Potential Contribution to Net Zero in the UK
Sep 2020
Publication
Electric trains (ET) and hydrogen trains (HT) are considered zero emission at the point of use. True emissions are dependent upon non-tailpipe sources primarily in energy production. We present UK carbon dioxide (CO2) operating emission model outputs for conventionally fuelled trains (CFT) ETs and HTs between 2017 and 2050 under four National Grid electricity generation scenarios.
Comparing four service categories (urban regional intercity and high speed) to private conventionally fuelled vehicles (CFV) and electric vehicles considering average distance travelled per trip under different passenger capacity levels (125% 100% 75% 50% and 25%).
Results indicate by 2050 at 100% capacity CFTs produce a fifth of the emissions of CFVs per kilometre per person. Under two degree generation scenario by 2050 ETs produced 14 times and HTs produced five times less emissions than CFTs. Policymakers should encourage shifts away from private vehicles to public transport powered by low carbon electricity.
Comparing four service categories (urban regional intercity and high speed) to private conventionally fuelled vehicles (CFV) and electric vehicles considering average distance travelled per trip under different passenger capacity levels (125% 100% 75% 50% and 25%).
Results indicate by 2050 at 100% capacity CFTs produce a fifth of the emissions of CFVs per kilometre per person. Under two degree generation scenario by 2050 ETs produced 14 times and HTs produced five times less emissions than CFTs. Policymakers should encourage shifts away from private vehicles to public transport powered by low carbon electricity.
Treatment of Dark Fermentative H2 Production Effluents by Microbial Fuel Cells: A Tutorial Review on Promising Operational Strategies and Practices
Nov 2020
Publication
Deriving biohydrogen from dark fermentation is a practically suitable pathway for scaling-up and envisaged mass production. However a common issue with these systems is the incomplete conversion of feedstock as a result of which a process effluent with notable organic strength is left behind. The main components of dark fermentation effluents are volatile fatty acids that can be utilized by integrated applications involving bioelectrochemical systems particularly microbial fuel cells (MFCs) to generate electrical energy. In this work MFCs deployed to treat dark fermentative H2 production effluents are assessed to take a look into the current standing of this specific research area and address what MFC design and operating features (reactor configuration mode of operation anode surface and reactor size) seem favorable towards improved working efficiency (e.g. power density Coulombic efficiency COD removal). Furthermore promising technological implementations are outlined and suggestions conclusions for future studies for this field are given.
Quantitative Risk Analysis of a Hazardous Jet Fire Event for Hydrogen Transport in Natural Gas Transmission Pipelines
Jan 2021
Publication
With the advent of large-scale application of hydrogen transportation becomes crucial. Reusing the existing natural gas transmission system could serve as catalyst for the future hydrogen economy. However a risk analysis of hydrogen transmission in existing pipelines is essential for the deployment of the new energy carrier. This paper focuses on the individual risk (IR) associated with a hazardous hydrogen jet fire and compares it with the natural gas case. The risk analysis adopts a detailed flame model and state of the art computational software to provide an enhanced physical description of flame characteristics.<br/>This analysis concludes that hydrogen jet fires yield lower lethality levels that decrease faster with distance than natural gas jet fires. Consequently for large pipelines hydrogen transmission is accompanied by significant lower IR. Howbeit ignition effects increasingly dominate the IR for decreasing pipeline diameters and cause hydrogen transmission to yield increased IR in the vicinity of the pipeline when compared to natural gas.
Fuel Cells and Hydrogen: Joint Undertaking Programme Review 2016 Final Report
Jun 2017
Publication
The Fuel Cell and Hydrogen 2 Joint Undertaking (FCH 2 JU) organised the sixth edition of its Programme Review Days (PRD). 100 projects allocated in 6 panels covering cross-cutting energy and transport in research and demonstration activities have been the basis of the FCH JU's annual review of its research and innovation programme.
Monitoring H2 Bubbles by Real Time H2 Sensor
Sep 2017
Publication
Portable H2 sensor was made by using mass spectrometer for the outside monitoring experiment: the leak test the replacement test of gas pipe line the combustion test the explosion experiment the H2 diffusion experiment and the recent issue of the exhaust gas of Fuel Cell Vehicle. In order to check the real time concentration of H2 in various conditions even in the highly humid condition the system volume of the sampling route was minimized with attaching the humidifier. Also to calibrate H2 concentration automatically the specific concentration H2 small cylinder was mounted in the system. In the experiment when H2 gas was introduced in the N2 flow or air in the tube or the high-pressure bottle highly concentrated H2 phases were observed by this sensor without diffusion. This H2 sensor can provide the real time information of the hydrogen molecules and the clouds. The basic characterization of this sensor showed 0-100% H2 concentrations within 2ms. Our observation showed the size of the high concentration phase of H2 and the low concentration phase after mixing process. The mixed and unmixed H2 unintended concentration of cloud gas the high speed small cluster of hydrogen molecules in purged gas were explored by this real time monitoring system.
Accelerating Innovation Towards Net Zero Emissions
Apr 2019
Publication
This report Accelerating innovation towards net zero commissioned by the Aldersgate Group and co-authored with Vivid Economics identifies out how the government can achieve a net zero target cost-effectively in a way that enables the UK to capture competitive advantages.
The unique contribution of this report is to identify the lessons from successful and more rapid historical innovations and apply them to the challenge of meeting net zero emissions in the UK.
Achieving net zero emissions is likely to require accelerated innovation across research demonstration and early deployment of low carbon technologies. Researchers analysed five international case studies of relatively rapid innovations to draw key lessons for government on the conditions needed to move from a typical multi-decadal cycle to one that will deliver net zero emissions by mid-Century.
The case studies include:
Six key actions for government policy to accelerate low carbon innovation in the UK:
The unique contribution of this report is to identify the lessons from successful and more rapid historical innovations and apply them to the challenge of meeting net zero emissions in the UK.
Achieving net zero emissions is likely to require accelerated innovation across research demonstration and early deployment of low carbon technologies. Researchers analysed five international case studies of relatively rapid innovations to draw key lessons for government on the conditions needed to move from a typical multi-decadal cycle to one that will deliver net zero emissions by mid-Century.
The case studies include:
- The deployment of the ATM network and cash cards across the UK
- Roll out of a gas network and central heating in the UK
- The development of wind turbines in Denmark and then the UK
- Moving from late-stage adoption of steel technology in South Korea to being the world leading exporter; and
- The slower than expected development of commercial-scale CCUS to date across the world.
Six key actions for government policy to accelerate low carbon innovation in the UK:
- Increase ambition in demonstrating complex and high capital cost technologies and systems.
- Create new markets to catalyse early deployment and move towards widespread commercialisation.
- Use concurrent innovations such as digital technologies to improve system efficiency and make new products more accessible and attractive to customers.
- Use existing or new organisations (cross-industry associations or public-private collaborations) to accelerate innovation in critical areas and coordinate early stage deployment.
- Harness trusted voices to build consumer acceptance through information sharing and rapid responses to concerns.
- Align innovation policy in such a way that it strengthens the UK’s industrial advantages and increases knowledge spillovers between businesses and sectors.
Hydrogen Powered Aviation: A Fact-based Study of Hydrogen Technology, Economics, and Climate Impact by 2050
Jul 2020
Publication
This report assesses the potential of hydrogen (H2) propulsion to reduce aviation’s climate impact. To reduce climate impact the industry will have to introduce further levers such as radically new technology significantly scale sustainable aviation fuels (SAF) such as synthetic fuel (synfuel) temporarily rely on offsets in large quantities or rely on a combination thereof. H2 propulsion is one such technology and this report assesses its potential in aviation. Developed with input from leading companies and research institutes it projects the technological development of H2 combustion and fuel cell-powered propulsion evaluates their technical and economic feasibility compares them to synfuel and considers implications on aircraft design airport infrastructure and fuel supply chains.
HyDeploy Overview
May 2020
Publication
An overview of the HyDeploy project at Keele University where hydrogen is being blended with natural gas to demonstrate the feasibility of using hydrogen to heat our homes.
Comparison of Liquid Hydrogen, Methylcyclohexane and Ammonia on Energy Efficiency and Economy
Mar 2019
Publication
Among several candidates of hydrogen storage liquid hydrogen methylcyclohexane (MCH) and ammonia are considered as potential hydrogen carriers in terms of their characteristics application feasibility and economic performance. In addition as a main motor in the hydrogen introduction Japan has focused and summarized the storage methods for hydrogen into these three methods. Each of them has advantages and disadvantages compared to each other. This study focuses on the effort to analyze and clarify the potential of these three hydrogen storages especially in terms of physical characteristics energy efficiency and economic cost. Liquid hydrogen faces challenges in huge energy consumption during liquefaction and boil-off during storage. MCH has main obstacles in largely required energy in dehydrogenation. Lastly ammonia encounters high energy demand in both synthesis and decomposition (if required). In terms of energy efficiency ammonia is predicted to have the highest total energy efficiency (34–37%) followed by liquid hydrogen (30–33%) and MCH (about 25%). In addition from cost calculation ammonia with direct utilization (without decomposition) is considered to have the highest feasibility for being massively adopted as it shows the lowest cost (20–22 JPY/Nm3-H2 in 2050). However in case that highly pure hydrogen (such as for fuel cell) is demanded liquid hydrogen looks to be promising (24–25 JPY/Nm3-H2 in 2050) compared to MCH and ammonia with decomposition and purification.
Update on Regulation Review for HRS Construction and Operations in Japan
Oct 2015
Publication
In 2005 the Japanese High-pressure Gas Safety Act the Fire Service Act and the Building Standards Act were revised to establish the requirements for 35 MPa hydrogen stations. And in 2012-2014 revisions were made to the High-pressure Gas Safety Act and the Fire Service Act to provide the regulatory requirements for 70 MPa hydrogen stations. We conducted a study on materials that may contribute to prepare technical standards concerning the major 4 items 12 additional items and 13 new items which may affect the costs from the point of view of promoting the hydrogen infrastructure.
Hazid for CO2-free Hydrogen Supply Chain Feed (Front End Engineering Design)
Oct 2015
Publication
We at Kawasaki have proposed a “CO2 free H2 chain” using the abundant brown coal of Australia as a hydrogen source. We developed the basic design package and finished the Front End Engineering Design (FEED) in 2014. There are not only the hazards of the processing plant system but also the characteristic hazards of a hydrogen plant system. We considered and carried out Hazard Identification (HAZID) as the most appropriate approach for safety design in this stage. This paper describes the safety design and HAZID which we practiced for the CO2-Free Hydrogen Supply Chain FEED.
Beyond Haber-Bosch: The Renaissance of the Claude Process
Apr 2021
Publication
Ammonia may be one of the energy carriers in the hydrogen economy. Although research has mostly focused on electrochemical ammonia synthesis this however remains a scientific challenge. In the current article we discuss the feasibility of single-pass thermochemical ammonia synthesis as an alternative to the high-temperature high-pressure Haber-Bosch synthesis loop. We provide an overview of recently developed low temperature ammonia synthesis catalysts as well as an overview of solid ammonia sorbents. We show that the low temperature low pressure single-pass ammonia synthesis process can produce ammonia at a lower cost than the Haber-Bosch synthesis loop for small-scale ammonia synthesis (<40 t-NH3 d−1).
Expected Impacts on Greenhouse Gas and Air Pollutant Emissions Due to a Possible Transition Towards a Hydrogen Economy in German Road Transport
Nov 2020
Publication
Transitioning German road transport partially to hydrogen energy is among the possibilities being discussed to help meet national climate targets. This study investigates impacts of a hypothetical complete transition from conventionally-fuelled to hydrogen-powered German transport through representative scenarios. Our results show that German emissions change between −179 and +95 MtCO2eq annually depending on the scenario with renewable-powered electrolysis leading to the greatest emissions reduction while electrolysis using the fossil-intense current electricity mix leads to the greatest increase. German energy emissions of regulated pollutants decrease significantly indicating the potential for simultaneous air quality improvements. Vehicular hydrogen demand is 1000 PJ annually requiring 446–525 TWh for electrolysis hydrogen transport and storage which could be supplied by future German renewable generation supporting the potential for CO2-free hydrogen traffic and increased energy security. Thus hydrogen-powered transport could contribute significantly to climate and air quality goals warranting further research and political discussion about this possibility.
Ammonia-hydrogen Combustion in a Swirl Burner with Reduction of NOx Emissions
Sep 2019
Publication
Recently ammonia is being considered for fuelling gas turbines as a new sustainable source. It can undergo thermal cracking producing nitrogen hydrogen and unburned ammonia thus enabling the use of these chemicals most efficiently for combustion purposes. Ammonia being carbon-free may allow the transition towards a hydrogen economy. However one of the main constraints of this fuelling technique is that although the combustion of ammonia produces no CO2 there is a large NOx proportion of emissions using this fuel. In this work cracked ammonia obtained from a modified combustion rig designed at Cardiff University was used to simulate a swirl burner under preheating conditions via heat exchangers. The primary objective of this system is to find new ways for the reduction of NOx emissions by injecting various amounts of ammonia/hydrogen at different mixtures downstream of the primary flame zone. The amount of injected ammonia/hydrogen mixture (X) taken from the thermal cracking system was ranged from 0%-4% (vol %) of the total available fuel in the system while the remaining gas (1.00-X) was then employed as primary fuel into the burner. CHEMKIN- PRO calculations were conducted by employing a novel chemical reaction code developed at Cardiff University to achieve the goal of this paper. The predictions were performed under low pressure and rich conditions with an equivalence ratio ϕ =1.2 in a swirl burner previously characterised at output powers of ~10 kW. Ammonia and hydrogen blends were evaluated from 50% NH3 (vol %) with the remaining gas as hydrogen continuing in steps of 10% (vol %) NH3 increments. Results showed that the minimum unburned ammonia and higher flame temperature were achieved at 60%-40% NH3-H2 when compared to other blends but with high NO emissions. These NO levels were reduced by injecting a small amount of NH3/H2 mixture (X=4 %) downstream the primary zone in a generated circulations promoted by the new design of the burner which affecting the residence time hence reducing the NO emission in the exhaust gas.
Multistage Risk Analysis and Safety Study of a Hydrogen Energy Station
Sep 2017
Publication
China has plenty of renewable energy like wind power and solar energy especially in the northwest part of the country. Due to the volatile and intermittent characters of the green powers high penetration level of renewable resources could arise grid stabilization problem. Therefore electricity storage is considered as a solution and hydrogen energy storage is proposed. Instead of storing the electricity directly it converts electricity into hydrogen and the energy in hydrogen will be released as needed from gas to electricity and heat. The transformed green power can be fed to the power grid and heat supply network. State Grid Corporation of China carried out its first hydrogen demonstration project. In the demonstration project an alkaline electrolyzer and a PEM hydrogen fuel cell stack are decided as the hydrogen producer and consumer respectively. Hydrogen safety issue is always of significant importance to secure the property. In order to develop a dedicated safety analysis method for hydrogen energy storage system in power industry the risk analysis for the power-to-gas-topower&heat facility was made. The hazard and operability (HAZOP) study and the failure mode and effects analysis (FMEA) are performed sequentially to the installation to identify the most problematic parts of the system in view of hydrogen safety and possible failure modes and consequences. At the third step the typical hydrogen leak accident scenarios are simulated by using computational fluid dynamics (CFD) computer code. The resulted pressure loads of the possibly ignited hydrogen-air mixture in the facility container are estimated conservatively. Important safeguards and mitigation measures are proposed based on the three-stage risk and safety studies.
Freeze of Nozzle & Receptacle During Hydrogen Fueling
Oct 2015
Publication
We conducted a fuelling test with hydrogen gas for a safety evaluation of the nozzle/receptacle at a controlled temperature and humidity. Test results confirmed that the nozzle/receptacle froze under specific conditions. However freezing did not cause apparatus damage nor hydrogen leakage. The nozzle/receptacle is thus able to fuel safely even if the nozzle/receptacle is stuck due to ice. In addition we quantified the water volume that causes freezing.
South Korea’s Big Move to Hydrogen Society
Nov 2020
Publication
Extensive energy consumption has become a major concern due to increase of greenhouse gas emissions and global warming. Hence hydrogen has attracted attention as a green fuel with zero carbon emission for green transportation through production of electric vehicles with hydrogen fuel cells. South Korea has launched a hydrogen society policy with the objective of expanding production of hydrogen from renewable energy sources. The hydrogen economy will play a critical role in reducing atmospheric pollution and global arming. However new development of infrastructure for hydrogen refuelling and increasing awareness of the hydrogen economy is required together with reduced prices of hydrogen-driven vehicles that are promising options for a sustainable green hydrogen economy.
CFD Simulations of Filling and Emptying of Hydrogen Tanks
Jun 2016
Publication
During the filling of hydrogen tanks high temperatures can be generated inside the vessel because of the gas compression while during the emptying low temperatures can be reached because of the gas expansion. The design temperature range goes from −40 °C to 85 °C. Temperatures outside that range could affect the mechanical properties of the tank materials. CFD analyses of the filling and emptying processes have been performed in the HyTransfer project. To assess the accuracy of the CFD model the simulation results have been compared with new experimental data for different filling and emptying strategies. The comparison between experiments and simulations is shown for the temperatures of the gas inside the tank for the temperatures at the interface between the liner and the composite material and for the temperatures on the external surface of the vessel.
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