Publications

The recognition of hydrogen as a technically viable combustion fuel and as an alternative to more carbon intensive technologies for all forms of industrial applications has resulted in significant global interest leading to both public and private investment. As with most shifts in technology public acceptance and its safe production and handling will be key to its growth as a widespread energy vector. Specific properties of hydrogen that may prompt concern from the public and that need to be considered in terms of its use and safe handling include the following:<br/>• Hydrogen in its natural state is a colourless odourless and tasteless gas that is combustible with very low ignition energy burns nearly invisibly and is explosive at a very wide range of concentrations with an oxidate.<br/>• Hydrogen as any other gas except oxygen is an asphyxiant in a confined space.<br/>• Hydrogen is an extremely small molecule and interacts with many materials which over time can alter the physical properties and can lead to embrittlement and failure. Additionally due to the small molecular size its permeation and diffusion characteristics make it more difficult to contain compared to other gases.<br/>As hydrogen production use and storage increases these properties will come under greater scrutiny and may raise questions surrounding the cost/benefit of the technology. Understanding how the public sees this technology in relation to their safety and daily lives is important in hydrogen’s adoption as a low carbon alternative. A review of deployable experience relevant to the handling of hydrogen in other industries will help us to understand the technology and experience necessary for ensuring the success of the scaling up of a hydrogen economy. The social considerations of the impacts should also be examined to consider acceptance of the technology as it moves into the mainstream.

The necessity for transitioning to renewable energy sources and the intermittent nature of the natural variables lead to the integration of storage units into these projects. In this research paper wind turbines and solar modules are combined with pumped hydro storage batteries and green hydrogen. Energy management strategies are described for five different scenarios of hybrid renewable energy systems based on single or hybrid storage technologies. The motivation is driven by grid stability issues and the limited access to fresh water in the Greek islands. A RES-based desalination unit is introduced into the hybrid system for access to low-cost fresh water. The comparison of single and hybrid storage methods the exploitation of seawater for the simultaneous fulfillment of water for domestic and agricultural purposes and the evaluation of different energy economic and environmental indices are the innovative aspects of this research work. The results show that pumped hydro storage systems can cover the energy and water demand at the minimum possible price 0.215 EUR/kWh and 1.257 EUR/m3 while hybrid storage technologies provide better results in the loss of load probability payback period and CO2 emissions. For the pumped hydro– hydrogen hybrid storage system these values are 21.40% 10.87 years and 2297 tn/year respectively.

Hydrogen energy technologies are forecasted to play a critical supporting role in global decarbonisation efforts as reflected by the growth of national hydrogen energy strategies in recent years. Notably the UK government published its Hydrogen Strategy in August 2021 to support decarbonisation targets and energy security ambitions. While establishing techno-economic feasibility for hydrogen energy systems is a prerequisite of the prospective transition social acceptability is also needed to support visions for the ‘hydrogen economy’. However to date societal factors are yet to be embedded into policy prescriptions. Securing social acceptance is especially critical in the context of ‘hydrogen homes’ which entails replacing natural gas boilers and hobs with low-carbon hydrogen appliances. Reflecting the nascency of hydrogen heating and cooking technologies the dynamics of social acceptance are yet to be explored in a comprehensive way. Similarly public perceptions of the hydrogen economy and emerging national strategies remain poorly understood. Given the paucity of conceptual and empirical insights this study develops an integrated acceptance framework and tests its predictive power using partial least squares structural equation modelling. Results highlight the importance of risk perceptions trust dynamics and emotions in shaping consumer perceptions. Foremost prospects for deploying hydrogen homes at scale may rest with coupling renewable-based hydrogen production to local environmental and socio-economic benefits. Policy prescriptions should embed societal factors into the technological pursuit of large-scale sustainable energy solutions to support socially acceptable transition pathways.

The transition from fossil fuels to carbon-neutral energy sources is necessary to reduce greenhouse gas (GHG) emissions and combat climate change. Hydrogen (H2) provides a promising path to harness fossil fuels to reduce emissions in sectors such as transportation. However regional economic analyses of various H2 production techniques are still lacking. We selected a well-known fossil fuel-exporting region the USA’s Intermountain-West (I-WEST) to analyze the carbon intensity of H2 production and demonstrate regional tradeoffs. Currently 78 % of global H2 production comes from natural gas and coal. Therefore we considered steam methane reforming (SMR) surface coal gasification (SCG) and underground coal gasification (UCG) as H2 production methods in this work. We developed the cost estimation frameworks of SMR SCG and UCG with and without carbon capture utilization and sequestration (CCUS). In addition we identified optimal sites for H2 hubs by considering the proximity to energy sources energy markets storage sites and CO2 sequestration sites. We included new production tax credits (PTCs) in the cost estimation to quantify the economic benefit of CCUS. Our results suggest that the UCG has the lowest levelized cost of H2 production due to the elimination of coal production cost. H2 production using the SMR process with 99 % carbon capture is profitable when the PTCs are considered. We also analyzed carbon utilization opportunities where CO2 conversion to formic acid is a promising profitable option. This work quantifies the potential of H2 production from fossil fuels in the I-WEST region a key parameter for designing energy transition pathways.

One of the key factors of the current energy transition is the use of hydrogen (H2 ) as fuel in energy transformation technologies. This fuel has the advantage of being produced from the most primary forms of energy and has the potential to reduce carbon dioxide (CO2 ) emissions. In recent years hydrogen or hydrogen-rich mixtures in internal combustion engines (ICEs) have gained popularity with numerous reports documenting their use in spark ignition (SI) and compression ignition (CI) engines. Homogeneous charge compression ignition (HCCI) engines have the potential for substantial reductions in nitrogen oxides (NOx) and particulate matter (PM) emissions and the use of hydrogen along with this kind of combustion could substantially reduce CO2 emissions. However there have been few reports using hydrogen in HCCI engines with most studies limited to evaluating technical feasibility combustion characteristics engine performance and emissions in laboratory settings at sea level. This paper presents a study of HCCI combustion using hydrogen in a stationary air-cooled Lombardini 25 LD 425-2 modified diesel engine located at 1495 m above sea level. An experimental phase was conducted to determine the intake temperature requirements and equivalence ratios for stable HCCI combustion. These results were compared with previous research carried out at sea level. To the best knowledge of the authors this is the first report on the combustion and operational limits for an HCCI engine fueled with hydrogen under the mentioned specific conditions. Equivalence ratios between 0.21 and 0.28 and intake temperatures between 188 ◦C and 235 ◦C effectively achieved the HCCI combustion. These temperature values were on average 100 ◦C higher than those reported in previous studies. The maximum value for the indicated mean effective pressure (IMEPn) was 1.75 bar and the maximum thermal efficiency (ITEn) was 34.5%. The achieved results are important for the design and implementation of HCCI engines running solely on hydrogen in developing countries located at high altitudes above sea level.

Hydrogen as one of the most promising renewable clean energy sources holds significant strategic importance and vast application potential. However as a high-energy combustible gas hydrogen poses risks of fire and explosion in the event of a leakage. Hydrogen production plants typically feature large spatial volumes and complex obstacles which can significantly influence the diffusion pathways and localized accumulation of hydrogen during a short-term high-volume release further increasing the risk of accidents. Implementing effective hydrogen leakage monitoring measures can mitigate these risks ensuring the safety of personnel and the environment to the greatest extent possible. Therefore this paper uses CFD methods to simulate the hydrogen leakage process in a hydrogen production plant. The study examines the molar fraction distribution characteristics of hydrogen in the presence of obstacles by varying the ventilation speed of the plant and the directions of leakage. The main conclusions are as follows: enhancing ventilation can effectively prevent the rapid increase in hydrogen concentration with higher ventilation speeds yielding better suppression. After a hydrogen leak in a confined space hydrogen tends to diffuse along the walls and accumulate in corner areas indicating that hydrogen monitoring equipment should be placed in corner locations.

To cope with the growing penetration rate of renewable energy and to enhance the absorption capacity of wind power this paper investigates the applications of an Integrated Energy System (IES) Hydrogen Compressed Natural Gas (HCNG) and power-to-hydrogen (P2H) devices within the IES. It employs power-to-gas and gas blending with hydrogen to construct an efficient electricity–gas–electricity energy flow loop establishing a Natural Gas–Electricity Coupling System (NGECS) model. On this basis a coordinated scheduling method for gas–electric coupling systems using gas blended with hydrogen is proposed. A carbon trading mechanism is introduced to constrain carbon emissions further reducing the system’s carbon footprint. Multiple scenarios are set up for a comparative analysis in order to validate the effectiveness of the proposed model. This study also analyzes the impact of different hydrogen blending ratios and methods on the low-carbon and economic performance of IES.

Quantitative Risk Assessment (QRA) is a risk-informed approach that considers past performances and the likelihood of events and distinguishes must-haves from nice-to-haves. Following the approach applied for the HyRAM code developed by the Sandia National Laboratories a QRA toolkit for hydrogen systems was developed using MATLAB by Canadian Nuclear Laboratories (CNL). Based on user inputs for system components and their operating parameters the toolkit calculates the consequence of a hydrogen leak from the system. The fatality likelihood can be estimated from the severity of a person’s exposure to radiant heat flux (from a jet fire) and overpressure (from an explosion). This paper presents a verification and validation exercise by comparing the CNL model predictions with the HyRAM code and available experimental data including a QRA case study for a locomotive. The analysis produces risk contours recommending personnel (employees/public) numbers time spent and safe separation distances near the incident (during maintenance or an accident). The case study demonstrated the importance of hydrogen leak sensors’ reliability for leak detection and isolation. The QRA toolkit calculates a more practical value of the safe separation distance for hydrogen installations and provides evidence to support communication with authorities and other stakeholders for decision-making.

This manuscript explores the role of green hydrogen produced through ethanol reforming in accelerating Brazil’s transition to a low-carbon economic framework. Despite ongoing efforts to lessen carbon dependence Brazil’s reliance on biofuels and other renewable energy sources remains inadequate for fully achieving its decarbonization objectives. Green hydrogen presents a vital opportunity to boost energy sustainability especially in sectors that are challenging to decarbonize such as industry and transportation. By analyzing Brazil’s input–output (I-O) table using data from the Brazilian Institute of Geography and Statistics (IBGE) this study evaluates the macroeconomic potential of green hydrogen focusing on GDP growth and employment generation. Furthermore the research explores green hydrogen systems’ economic feasibility and potential impact on future energy policies offering valuable insights for stakeholders and decision-makers. In addition this investigation highlights Brazil’s abundant renewable resources and identifies the infrastructural investments necessary to support a green hydrogen economy. The findings aim to strengthen Brazil’s national decarbonization strategy and serve as a model for other developing nations transitioning to clean energy.

The production of hydrogen from photovoltaics (PV) has gained attention due to its potential as an energy vector. In this context there are two basic configurations for electrically coupling PV to hydrogen electrolyzers: direct and indirect. The direct configuration operates variably based on meteorological conditions but has simplicity as an advantage. The indirect configuration involves a power stage (PS) with a maximum power point tracker and a DC-DC converter maintaining an optimal power transfer from PV to electrolyzers but incurs losses at the PS. The direct configuration avoids these losses but requires a specific design of the PV generator to achieve high electrical transfer. The comparative analysis of hydrogen production between these two approaches indicates that the indirect paradigm yields a 37.5% higher hydrogen output throughout a typical meteorological year compared to the optimized direct configuration. This increase enhances the overall sunlight-to-hydrogen efficiency elevating it from 5.0% in the direct case to 6.9% in the indirect one. Furthermore the direct setup sensitive to PV power fluctuations suffers an 18% reduction in hydrogen production with just a 5% reduction in photogenerated power. Under optimal performance the direct coupling produces less hydrogen unless the DCDC converter efficiency drops 17% below commercial standards.