Publications

Underground hydrogen storage will be an essential part of the future hydrogen infrastructure to provide flexibility and security of supply. Storage in porous reservoirs should complement storage in salt caverns to be able to meet the projected high levels of required storage capacities. To assess its techno-economic feasibility a case study of hydrogen storage in a depleted gas field in the Netherlands is developed. Subsurface modelling is performed and various surface facility design concepts are investigated to calculate the levelized cost of hydrogen storage (LCOHS). Our base case with hydrogen as cushion gas results in an LCOHS of 0.79 EUR/kg (range of 0.58–1.04 EUR/kg). Increasing the number of full-cycle equivalents from 1 to 6 lowers the storage cost to 0.25 EUR/kg. The investment cost of the cushion gas represents 76% of the total cost. With nitrogen as cushion gas LCOHS is reduced to 0.49 EUR/kg (range of 0.42–0.56 EUR/kg).

In the new scenario where the transportation sector must be decarbonized to limit global warming fuel cellpowered aerial vehicles have been selected as a strategic target application to compose part of the urban fleet to minimize road transport congestion and make goods and personal transportation fast and efficient. To address the necessity of clean and efficient urban air transport this work consists of the conceptual development of a lightweight rotary-winged transport vehicle using a hydrogen-based fuel cell propulsion system and the optimization of its energy balance. For that purpose the methods for integrating the coupled aerodynamic and propulsion system sizing and optimization was developed with the aim of designing concepts capable of carrying 0 (unmanned aerial vehicle — Design 1) and 1 (Aerotaxi — Design 2) passengers for a distance of 300 km at a cruise altitude of 500 m with a minimum climbing rate capability of 6 m s−1 at 1000 m. The results show how these designs with the desired performance specifications can be obtained with a vehicle mass ranging from 416 to 648 kg depending on the application and with specific range and endurance respectively within 46.2–47.8 km/kg and 20.4–21.3 min/kg for design 1 and 33.3–33.8 km/kg and 12.5–13.9 min/kg for design 2.

Hydrogen is one of the main energy carriers playing a prominent role in the future decarbonization of the economy. However several aspects regarding the transport and storage of this gas are challenging. The intermediary conversion of hydrogen into high-density energy molecules may be a crucial step until technological conditions are ready to attain a significant reduction in fossil fuel use in transport and the industrial sector. The process of transforming hydrogen into methane by anaerobic digestion is reviewed showing that this technology is a feasible option for facilitating hydrogen storage and transport. The manuscript focuses on the role of anaerobic digestion as a technology driver capable of fast adaptation to current energy needs. The use of thermophilic systems and reactors capable of increasing the contact between the H2 -fuel and liquid phase demonstrated outstanding capabilities attaining higher conversion rates and increasing methane productivity. Pressure is a relevant factor of the process allowing for better hydrogen solubility and setting the basis for considering feasible underground hydrogen storage concomitant with biological methanation. This feature may allow the integration of sequestered carbon dioxide as a relevant substrate.

Defossilisation of the current fossil fuels dominated global energy system is one of the key goals in the upcoming decades to mitigate climate change. Sharp reduction in the costs of solar photovoltaics wind power and battery technologies enables a rapid transition of the power and some segments of the transport sectors to sustainable energy resources. However renewable electricity-based fuels and chemicals are required for the defossilisation of hard-to-abate segments of transport and industry. The global demand for carbon dioxide as raw material for the production of e-fuels and e-chemicals during a global energy transition to 100% renewable energy is analysed in this research. Carbon dioxide capture and utilisation potentials from key industrial point sources including cement mills pulp and paper mills and waste incinerators are evaluated. According to this study’s estimates the demand for carbon dioxide increases from 0.6 in 2030 to 6.1 gigatonnes in 2050. Key industrial point sources can potentially supply 2.1 gigatonnes of carbon dioxide and thus meet the majority of the demand in the 2030s. By 2050 however direct air capture is expected to supply the majority of the demand contributing 3.8 gigatonnes of carbon dioxide annually. Sustainable and unavoidable industrial point sources and direct air capture are vital technologies which may help the world to achieve ambitious climate goals.

As the main body of resource aggregation Virtual Power Plant (VPP) not only needs to participate in the external energy market but also needs to optimize the management of internal resources. Different from other energy storage hydrogen energy storage systems can participate in the hydrogen market in addition to assuming the backup supplementary function of electric energy. For the Virtual Power Plant Operator (VPPO) it needs to optimize the scheduling of internal resources and formulate bidding strategies for the electric-hydrogen market based on external market information. In this study a two-stage model is constructed considering the internal and external interaction mechanism. The first stage model optimizes the operation of renewable energy flexible load extraction storage and hydrogen energy storage system based on the complementary characteristics of internal resources; the second stage model optimizes the bidding strategy to maximize the total revenue of the electricity energy market auxiliary service market and hydrogen market. Finally a typical scenario is constructed and the rationality and effectiveness of the strategy are verified. The results show that the hybrid VPP with hydrogen storage has better economic benefits resource benefits and reliability.

Fuel cell- and electric-powered trucks are promising technologies for zero-emission heavyduty transportation. Recently Fuel Cell Trucks (FCT) have gained wider acceptance as the technology of choice for long-distance trips due to their lighter weight and shorter fueling time than electric-powered trucks. Broader adoption of Fuel Cell Trucks (FCT) requires planning strategies for locating future hydrogen refueling stations (HRS) especially for fleets that transport freight along intercity and inter-country highways. Existing mathematical models of HRS placement often focus on inner-city layouts which make them inadequate when studying the intercity and intercountry FCT operation scale of FCT. Furthermore the same models rarely consider decentralized hydrogen production from renewable energy sources essential for decarbonizing the transportation sector. This paper proposes a mathematical model to guide the planning of the hydrogen infrastructure to support future long-haul FCTs. First the model uses Geographic Information System (GIS) data to determine the HRS’s optimal number and location placement. Then the model categorizes and compares potential hydrogen production sources including off-site delivery and on-site solar-to-hydrogen production. The proposed model is illustrated through a case study of the west coastal area of the United States (from Baja California Mexico to British Columbia Canada). Different geospatial scenarios were tested ranging from the current operational distance of FCEV (250km) and future releases of hydrogen FCT (up to 1500km). Results highlight the capabilities of the model in identifying the number and location of the HRS based on operation distances in addition to determining the optimal hydrogen production technology for each HRS. The findings also confirm the viability of green hydrogen production through solar energy which could play a critical role in a low-carbon transportation future.

Currently the issue of creating decarbonized energy systems in various spheres of life is acute. Therefore for gas turbine power systems including hybrid power plants with fuel cells it is relevant to transfer the existing engines to pure hydrogen or mixtures of hydrogen with natural gas. However significant problems arise associated with the possibility of the appearance of flashback zones and acoustic instability of combustion an increase in the temperature of the walls of the flame tubes and an increase in the emission of nitrogen oxides in some cases. This work is devoted to improving the efficiency of gas turbine power systems by combusting pure hydrogen and mixtures of natural gas with hydrogen. The organization of working processes in the premixed combustion chamber and the combustion chamber with a sequential injection of ecological and energy steam for the “Aquarius” type power plant is considered. The conducted studies of the basic aerodynamic and energy parameters of a gas turbine combustor working on hydrogen-containing gases are based on solving the equations of conservation and transfer in a multicomponent reacting system. A four-stage chemical scheme for the burning of a mixture of natural gas and hydrogen was used which allows for the rational parameters of environmentally friendly fuel burning devices to be calculated. The premixed combustion chamber can only be recommended for operations on mixtures of natural gas with hydrogen with a hydrogen content not exceeding 20% (by volume). An increase in the content of hydrogen leads to the appearance of flashback zones and fuel combustion inside the channels of the swirlers. For the combustion chamber of the combined-cycle power plant “Vodoley” when operating on pure hydrogen the formation of flame flashback zones does not occur.

The widespread production and use of hydrogen (H2) requires safe handling due to its wide range of flammability and low ignition energy. In confined and semi-confined areas such as garages and tunnels a hydrogen leak will create a potential accumulation of flammable gases. Hence forced ventilation is required in such confined spaces to prevent hydrogen hazards. However this practice may incur higher operating costs and could become ineffective during a power outage. Passive Autocatalytic Recombiners (PARs) are defined as safety devices for preventing hydrogen accumulation in confined spaces. PARs have been widely adopted for hydrogen mitigation in nuclear containment buildings in worst case accident scenarios where forced ventilation is not feasible. PARs are equipped with catalyst plates that self-start due to hydrogen reacting with oxygen at relatively low concentrations (<2 vol. % H2 in air). The heat generated from the reaction creates a self-sustained flow continuously supplying the catalyst surface with fresh hydrogen and oxygen. In this study a 2D transient numerical model has been developed in COMSOL Multiphysics to simulate the operation of PARs. The model was used to analyze the effect of surface reactions on the catalyst temperature flow dynamics self-start behaviour forced versus natural convective flow and steady-state hydrogen recombination rates. The model was also used to simulate carbon monoxide poisoning and its influence on the catalyst performance. Experimental data were used for model calibration and validation showing good agreement for different conditions. Overall the model provides novel insights into PARs operation such as radiation and poisoning effects on the catalyst plate. As a next step assessment of the effectiveness of PARs is underway to mitigate hydrogen hazards in selected confined and semi-confined areas including nuclear and non-nuclear applications.

Hydrogen (H2) as an energy carrier may play a role in various hard-to-abate subsectors but to maximize emission reductions supplied hydrogen must be reliable low-emission and low-cost. Here we build a model that enables direct comparison of the cost of producing net-zero hourly-reliable hydrogen from various pathways. To reach net-zero targets we assume upstream and residual facility emissions are mitigated using negative emission technologies. For the United States (California Texas and New York) model results indicate nextdecade hybrid electricity-based solutions are lower cost ($2.02-$2.88/kg) than fossil-based pathways with natural gas leakage greater than 4% ($2.73-$5.94/ kg). These results also apply to regions outside of the U.S. with a similar climate and electric grid. However when omitting the net-zero emission constraint and considering the U.S. regulatory environment electricity-based production only achieves cost-competitiveness with fossil-based pathways if embodied emissions of electricity inputs are not counted under U.S. Tax Code Section 45V guidance.

This work presents simulation results from a system where offshore wind power is used to produce hydrogen via electrolysis. Real-world data from a 2.3 MW floating offshore wind turbine and electricity price data from Nord Pool were used as input to a novel electrolyzer model. Data from five 31-day periods were combined with six system designs and hydrogen production system efficiency and production cost were estimated. A comparison of the overall system performance shows that the hydrogen production and cost can vary by up to a factor of three between the cases. This illustrates the uncertainty related to the hydrogen production and profitability of these systems. The highest hydrogen production achieved in a 31-day period was 17 242 kg using a 1.852 MW electrolyzer (i.e. utilization factor of approximately 68%) the lowest hydrogen production cost was 4.53 $/kg H2 and the system efficiency was in the range 56.1e56.9% in all cases.