Publications

As an important piece of equipment for hydrogen energy application the hydrogen internal combustion engine is helpful for the realization of zero carbon emissions where the aluminum connecting rod is one of the key core components. A semi-solid forging forming process for the 7075 aluminum alloy connecting rod is proposed in this work. The influence of process parameters such as the forging ratio sustaining temperature and duration time on the microstructures of the semi-solid blank is experimentally investigated. The macroscopic morphology metallographic structure and physical properties of the connecting-rod parts are analyzed. Reasonable process parameters for preparing the semi-solid blank are obtained from the experimental results. Under the reasonable parameters the average grain size is 41.48~42.57 µm and the average shape factor is 0.80~0.81. The yield strength and tensile strength improvement ratio of the connecting rod produced by the proposed process are 47.07% and 20.89% respectively.

Green hydrogen promises to be critical in achieving a sustainable and renewable energy transition. As green hydrogen is produced with renewables green hydrogen could become an energy storage medium of the future and even substitute the current unsustainable grey or blue hydrogen used in the industry. Bringing this transition into reality for instance in Germany there are visions to rapidly build hydrogen facilities in Africa and export the produced green hydrogen to Europe. One problem however is that these visions presumably conflict with the visions of actors within Africa. Therefore this study aims to provide an initial assessment of African stakeholders’ visions for future energy exports and renewable energy expectations. By comparing visions from Germany and Africa this assessment was conducted to identify differences in green energy and hydrogen visions that could lead to conflict and similarities that could be the basis for cooperation. The National Hydrogen Strategy outlines the German visions which clarifies that Germany will have to import green hydrogen to meet its green transition target. In this context of future energy export demand a partnership between German and African researchers on assessing green hydrogen potentials in Africa started. The African visions were explored by surveying the partners from different African countries working on the project. The results revealed that while both sides see the need for an immediate transition to renewable energy the African side is not envisioning the immediate export of green hydrogen. Based on the responses the partners are primarily concerned with improving the continent’s still deficient energy access for both the population and industry. Nevertheless this African perspective greatly emphasises cross-border cooperation where both sides can realise their visions. In the case of Germany that German investment could build infrastructure which would benefit the receiving African country or countries and open up the possibility for the envisioned green hydrogen export to Europe.

Chile abundant in solar and wind energy resources presents significant potential for the production of green hydrogen a promising renewable energy vector. However realizing this potential requires an understanding of the most suitable locations for the installation of green hydrogen industries. This study proposes a quantitative methodology that identifies and ranks potential public lands for industrial use based on a range of technical parameters (such as solar and wind availability) and socio-environmental considerations (including land use restrictions and population density). The results reveal optimal locations that can facilitate informed sustainable decision-making for large-scale green hydrogen implementation in Chile. While this methodology does not replace project-specific technical or environmental impact studies it provides a flexible general classification to guide initial site selection. Notably this approach can be applied to other regions worldwide with abundant solar and wind resources such as Australia and Northern Africa promoting more effective and sustainable global decision-making for green hydrogen production.

Canada’s commitment to be net-zero by 2050 combined with ATCO’s own Environmental Social and Governance goals has led ATCO to pursue hydrogen blending within the existing natural gas system to reduce CO2 emissions while continuing to provide safe reliable energy service to customers. Utilization of hydrogen in the distribution system is the least-cost alternative for decarbonizing the heating loads in jurisdictions like Alberta where harsh winter climates are encountered and low-carbon hydrogen production can be abundant. ATCO’s own Fort Saskatchewan Hydrogen Blending Project began blending 5% hydrogen by volume to over 2100 customers in the Fall of 2022 and plans to increase the blend rates to 20% hydrogen in 2023. Prior to blending ATCO worked together with DNV to examine the impact of hydrogen blended natural gas to twelve Canadian appliances: range/stove oven garage heater high and medium efficiency furnaces conventional and on demand hot water heaters barbeque clothes dryer radiant heater and two gas fireplaces. The tests were performed not only within the planned blend rates of 0-20% hydrogen but also to higher percentages to determine how much hydrogen can be blended into a system before appliance retrofits would be required. The testing was designed to get insights on safety-related combustion issues such as flash-back burner overheating flame detection and other performance parameters such as emissions and burner power. The experimental results indicate that the radiant heater is the most sensitive appliance for flashback observed at 30 vol% hydrogen in natural gas. At 50% hydrogen the range and the radiant burner of the barbeque tested were found to be sensitive to flashback. All other 9 appliances were found to be robust for flashback with no other short-term issues observed. This paper will detail the findings of ATCO and DNV’s appliance testing program including results on failure mechanisms and sensitivities for each appliance.

This comprehensive review explores the transformative role of nanomaterials in advancing the frontier of hydrogen energy specifcally in the realms of storage production and transport. Focusing on key nanomaterials like metallic nanoparticles metal–organic frameworks carbon nanotubes and graphene the article delves into their unique properties. It scrutinizes the application of nanomaterials in hydrogen storage elucidating both challenges and advantages. The review meticulously evaluates diverse strategies employed to overcome limitations in traditional storage methods and highlights recent breakthroughs in nanomaterial-centric hydrogen storage. Additionally the article investigates the utilization of nanomaterials to enhance hydrogen production emphasizing their role as efcient nanocatalysts in boosting hydrogen fuel cell efciency. It provides a comprehensive overview of various nanocatalysts and their potential applications in fuel cells. The exploration extends to the realm of hydrogen transport and delivery specifcally in storage tanks and pipelines ofering insights into the nanomaterials investigated for this purpose and recent advancements in the feld. In conclusion the review underscores the immense potential of nanomaterials in propelling the hydrogen energy frontier. It emphasizes the imperative for continued research aimed at optimizing the properties and performance of existing nanomaterials while advocating for the development of novel nanomaterials with superior attributes for hydrogen storage production and transport. This article serves as a roadmap shedding light on the pivotal role nanomaterials can play in advancing the development of clean and sustainable hydrogen energy technologies.

The role of hydrogen as a clean energy source is a promising but also a contentious issue. The global energy production is currently characterized by an unprecedented shift to renewable energy sources (RES) and their technologies. However the local and environmental benefits of such RES-based technologies show a wide variety of technological maturity with a common mismatch to local RES stocks and actual utilization levels of RES exploitation. In this literature review the collected documents taken from the Scopus database using relevant keywords have been organized in homogeneous clusters and are accompanied by the registration of the relevant studies in the form of one figure and one table. In the second part of this review selected representations of typical hydrogen energy system (HES) installations in realistic in-field applications have been developed. Finally the main concerns challenges and future prospects of HES against a multi-parametric level of contributing determinants have been critically approached and creatively discussed. In addition key aspects and considerations of the HES-RES convergence are concluded.

This report aims to summarise the status of the European hydrogen policies and standards landscape. It is based on the information available at the European Hydrogen Observatory (EHO) platform the leading source of data and information on hydrogen in Europe (EU27 EFTA and the UK) providing an overview of the European and national policies legislations strategies and codes and standards which impact the deployment of hydrogen technologies and infrastructures. The EHO database covers a total of 29 EU policies and legislations that directly or indirectly affect the development and deployment of hydrogen technologies. To achieve its net zero ambitions the EU started with cross-cutting strategies such as the EU Green Deal and the EU Hydrogen Strategy setting forward roadmaps and targets that are to be achieved in the near future. As a next step the EU has developed legislations such as those bundled in the Fit for 55 package to meet the targets they have put forward. The implemented legislations including funding vehicles and initiatives have an impact on the whole value chain of hydrogen including production transport storage and distribution and end-uses. At national level as of July 2023 63% of the European countries have successfully published their national strategies in the hydrogen sector while 6% of the countries are currently in the draft stage. Several European countries have strategically incorporated quantitative indicators within their national strategies outlining their targets and estimates across the hydrogen value chain. This deliberate approach reflects a commitment to providing clear and measurable goals within their hydrogen strategies. A target often used in the national strategies is on electrolyser capacity as an effort to enhance the domestic renewable hydrogen production. Germany took the lead with an ambitious goal of achieving 10 GW by 2030 followed by France (6.5 GW) and Denmark (4 - 6 GW). Other targets that some of the countries use in their strategies are on the number of hydrogen refuelling stations fuel cell electric vehicles and total (renewable) hydrogen demand. A few countries also have targets on renewable hydrogen uptake in industry and hydrogen injection limit in the transmission grid. To monitor the policies and legislation that are adopted on a national level across the hydrogen value chain a survey was launched with national experts which was validated by Hydrogen Europe. In total 28 European countries have participated to the survey. On production the survey revealed that 61% of country specialists report that their country provides support for capital expenditure (CAPEX) in the development of renewable or low-carbon hydrogen production plants. Moreover 7 countries also provide support for operational expenditure (OPEX). Furthermore 8 countries have instituted official 6 permitting guidelines for hydrogen production projects while 5 countries have enacted a legal act or established an agency serving as a single point of contact for hydrogen project developers. For transmission only two countries reported to provide support schemes for hydrogen injection. Several countries have policies in place that clearly define the hydrogen limit in their transmission grid for now and in the future ranging from 0.02% up to 15% while a few countries define within their policies the operation of hydrogen storage facilities. On end-use the majority of countries totalling 71% reported to have implemented support schemes aimed at promoting the adoption of hydrogen in the mobility sector. Purchase subsidies stand out as the predominant form of support for fuel cell electric vehicles (FCEVs) with implementation observed in 17 countries. In the context of support schemes for stationary fuel applications for heating or power generation only two countries have adopted such measures. A slightly larger group of four countries do provide support for the deployment of residential and commercial heating systems utilizing hydrogen. For hydrogen end-use in industry a total of 9 countries reported to provide support schemes with a major focus on ammonia production (8) and the chemicals industry (7). On the topic of technology manufacturing 7 countries have reported to have support schemes of which grants emerge as the mainly used method (4). Exploring the latest advancements into European codes and standards relevant to the deployment of hydrogen technologies and infrastructures a total of 11 standards have been revised and developed between January 2022 and September 2023. This includes standards covering the following areas: 6 for fuel cell technologies 2 for gas cylinders 2 for road vehicles and 1 for hydrogen refuelling. Moreover 5 standards were published since September 2023 which will be added to the EHO database in its next update. This includes ISO/TS 19870:2023 which sets a methodology for determining the greenhouse gas emissions associated with the production conditioning and transport of hydrogen to consumption gate. This landmark standard which was unveiled at COP28 aims to act as a foundation for harmonization safety interoperability and sustainability across the hydrogen value chain.

A global energy shift to a carbon‐neutral society requires clean energy. Hydrogen can accelerate the process of expanding clean and renewable energy sources. However conventional hydrogen compression and storage technology still suffers from inefficiencies high costs and safety concerns. An electrochemical hydrogen compressor (EHC) is a device similar in structure to a water electrolyzer. Its most significant advantage is that it can accomplish hydrogen separation and compression at the same time. With no mechanical motion and low energy consumption the EHC is the key to future hydrogen compression and purification technology breakthroughs. In this study the compression performance efficiency and other related parameters of EHC are investigated through experiments and simulation calculations. The experimental results show that under the same experimental conditions increasing the supply voltage and the pressure in the anode chamber can improve the reaction rate of EHC and balance the pressure difference between the cathode and anode. The presence of residual air in the anode can impede the interaction between hydrogen and the catalyst as well as the proton exchange membrane (PEM) resulting in a decrease in performance. In addition it was found that a single EHC has a better compression ratio and reaction rate than a double EHC. The experimental results were compatible with the theoretical calculations within less than a 7% deviation. Finally the conditions required to reach commercialization were evaluated using the theoretical model.

The depletion of fossil fuel reserves has resulted from their application in the industrial and energy sectors. As a result substantial efforts have been dedicated to fostering the shift from fossil fuels to renewable energy sources via technological advancements in industrial processes. Microalgae can be used to produce biofuels such as biodiesel hydrogen and bioethanol. Microalgae are particularly suitable for hydrogen production due to their rapid growth rate ability to thrive in diverse habitats ability to resolve conflicts between fuel and food pro duction and capacity to capture and utilize atmospheric carbon dioxide. Therefore microalgae-based bio hydrogen production has attracted significant attention as a clean and sustainable fuel to achieve carbon neutrality and sustainability in nature. To this end the review paper emphasizes recent information related to microalgae-based biohydrogen production mechanisms of sustainable hydrogen production factors affecting biohydrogen production by microalgae bioreactor design and hydrogen production advanced strategies to improve efficiency of biohydrogen production by microalgae along with bottlenecks and perspectives to over come the challenges. This review aims to collate advances and new knowledge emerged in recent years for microalgae-based biohydrogen production and promote the adoption of biohydrogen as an alternative to con ventional hydrocarbon biofuels thereby expediting the carbon neutrality target that is most advantageous to the environment.

Proton-Exchange Membrane-Fuel Cells (PEM-FC) are regarded as one of the prime candidates to provide emissions-free electricity for propulsion systems of aircraft. Here a turbocharged Fuel Cell Power System (FCPS) powered with liquid H2 (LH2) is designed and modelled to provide a primary power source in retrofitted Cessna 208 Caravan aircraft. The proposed FCPS comprises multiple PEM-FCs assembled in stacks two single-stage turbochargers to mitigate the variation of the ambient pressure with altitude two preheaters two humidifiers and two combustors. Interlinked component sub-models are constructed in MATLAB and referenced to commercially available equipment. The FCPS model is used to simulate steady-state responses in a proposed 1.5 h (∼350 km) mission flight determining the overall efficiency of the FCPS at 43% and hydrogen consumption of ∼28 kg/h. The multi-stack FCPS is modelled applying parallel fluidic and electrical architectures analysing two power-sharing methods: equally distributed and daisy-chaining. The designed LH2-FCPS is then proposed as a power system to a retrofitted Cessna 208 Caravan and with this example analysed for the probability of failure occurrence. The results demonstrate that the proposed “dual redundant” FCPS can reach failure rates comparable to commercial jet engines with a rate below 1.6 failures per million hours.