Publications
Low-Carbon Economic Dispatch of Integrated Energy Systems for Electricity, Gas, and Heat Based on Deep Reinforcement Learning
Oct 2025
Publication
Under the background of “dual-carbon” the development of energy internet is an inevitable trend for China’s low-carbon energy transition. This paper proposes a hydrogen-coupled electrothermal integrated energy system (HCEH-IES) operation mode and optimizes the source-side structure of the system from the level of carbon trading policy combined with low-carbon technology taps the carbon reduction potential and improves the renewable energy consumption rate and system decarbonization level; in addition for the operation optimization problem of this electric–gas–heat integrated energy system a flexible energy system based on electric–gas–heat is proposed. Furthermore to address the operation optimization problem of the HCEH-IES a deep reinforcement learning method based on Soft Actor–Critic (SAC) is proposed. This method can adaptively learn control strategies through interactions between the intelligent agent and the energy system enabling continuous action control of the multi-energy flow system while solving the uncertainties associated with source-load fluctuations from wind power photovoltaics and multi-energy loads. Finally historical data are used to train the intelligent body and compare the scheduling strategies obtained by SAC and DDPG algorithms. The results show that the SAC-based algorithm has better economics is close to the CPLEX day-ahead optimal scheduling method and is more suitable for solving the dynamic optimal scheduling problem of integrated energy systems in real scenarios.
The Impact of Temporal Hydrogen Regulation on Hydrogen Exporters and their Domestic Energy Transition
Aug 2025
Publication
As global demand for green hydrogen rises potential hydrogen exporters move into the spotlight. While exports can bring countries revenue large-scale on-grid hydrogen electrolysis for export can profoundly impact domestic energy prices and energy-related emissions. Our investigation explores the interplay of hydrogen exports domestic energy transition and temporal hydrogen regulation employing a sector-coupled energy model in Morocco. We find substantial co-benefits of domestic carbon dioxide mitigation and hydrogen exports whereby exports can reduce market-based costs for domestic electricity consumers while mitigation reduces costs for hydrogen exporters. However increasing hydrogen exports in a fossil-dominated system can substantially raise market-based costs for domestic electricity consumers but surprisingly temporal matching of hydrogen production can lower these costs by up to 31% with minimal impact on exporters. Here we show that this policy instrument can steer the welfare (re-)distribution between hydrogen exporting firms hydrogen importers and domestic electricity consumers and hereby increases acceptance among actors.
Combustion Process Analysis of Secondary Jet-Guided Combustion in Hydrogen Direct-Injection Engines
Oct 2025
Publication
This study investigates the effects of secondary jet-guided combustion on the combustion and emissions of a hydrogen direct-injection engine through numerical simulations. The results show that secondary jet-guided combustion which involves injecting and igniting the hydrogen jet at the end of the compression stroke significantly shortens the delay period improves combustion stability and brings the combustion center closer to the top dead center (TDC) achieving a maximum indicative thermal efficiency (ITE) of 46.55% (λ = 2.4). However this strategy results in higher NOx emissions due to high-temperature combustion. In contrast single and double injections lead to worsened combustion and reduced thermal efficiency under lean-burn conditions but with relatively lower NOx emissions. This study demonstrates that secondary jet-guided combustion can effectively enhance hydrogen engine performance by optimizing mixture stratification and flame propagation providing theoretical support for clean and efficient combustion.
Assistance in the Development of an Auction Design and Necessary Pre-conditions for a European Import Auction for Renewable Hydrogen under the European Hydrogen Bank: Final Report
Aug 2025
Publication
This report supports the European Commission (DG ENER) in the design and implementation of a European import auction for renewable hydrogen and its derivatives under the European Hydrogen Bank (EHB). The EHB aims to contribute to the EU's climate neutrality goal by 2050. While domestic auctions have already been launched under the EHB its international leg focusing on renewable fuels of non-biological origin (RFNBO) imports from third countries remains to be designed. This report offers strategic recommendations based on hydrogen market analyses the assessment of existing and planned hydrogen auction schemes in Europe and beyond as well as preliminary considerations on auction design. The analysis highlights the potential for hydrogen imports from regions like North America Australia Latin America and the MENA region. It includes concrete case studies on both pipeline-based imports of pure hydrogen and ship-based imports of key derivatives (ammonia methanol and synthetic aviation fuels (eSAF) to reflect Member State preferences and provides a concrete starting point for further defining import auctions. Priority considerations for auction design include ensuring fair competition between domestic production and imports addressing geopolitical risks and achieving cost efficiency. The case studies serve as a flexible blueprint for implementing EHB import auctions considering Member State interests and aligning with the EU's broader objectives.
Hydrogen UK - Driving Demand
Jul 2025
Publication
Low carbon hydrogen has a fundamental role to play in not one but two of the UK Government’s core missions. First it can help grow the economy - with thousands of new jobs and opportunities breathing new life into our industrial heartlands. Second it can help the UK become a clean energy superpower by using clean secure energy that we control. Third it can future-proof the UK’s foundational industries delivering decarbonisation and energy security to the hard-to-abate sectors which underpin the UK economy. Hydrogen developers across our membership report growing interest from customers in a wide range of sectors. Whilst current government policy has helped start the hydrogen economy industry wants this to accelerate and become more holistic so that interest is translated into demand allowing the sector to fully develop and the UK to meet its decarbonisation targets. With growing international competition the UK Government should prioritise the growth of hydrogen technology implementation leveraging the nation’s natural geological and geographical advantages. Although £20 billion in private capital investment is estimated to be ready to support the UK Government’s hydrogen ambitions persistent delays and market uncertainty risk this funding being lost to other markets. This report outlines the importance of Driving Demand for offtakers complementing the strong market foundation built from Government’s early hydrogen production focus. For effective policy implementation industry stakeholders have highlighted the importance of finding balance: retaining low-carbon technology optionality alongside certainty and support for investment with the adoption of a clear ‘vision’ and ‘market creation’ supported by a tailored mix of ‘carrots and sticks’ to support the market. From the research conducted by HUK it is clear that the choice of decarbonisation options is not done on a sector-by-sector basis that even within companies the decision-making process is site-by-site. This reflects the sensitivity of numerous factors that will ultimately determine the best solution for their site and re-enforces the view that customers must be allowed the choice of decarbonisation options. Hydrogen will play a significant role in decarbonising some of the hardest to abate sectors of the UK economy complimenting the role of electrification CCUS and other decarbonisation technologies. These sectors represent the hardest and therefore most expensive to decarbonise. However hydrogen also provides an opportunity to deliver significant economic growth through a thriving domestic supply chain and so a holistic approach should be applied.
The paper can be found on their website.
The paper can be found on their website.
Comparative Risk Assessment of Gaseous and Liquid Hydrogen Fuel Gas Supply Systems for Hydrogen-fueled Vessels
Aug 2025
Publication
This study compares qualitative risk analyses of compressed hydrogen gas (GH2) and liquid hydrogen (LH2) fuel gas supply systems (FGSSs) for eco-friendly marine vessels. Using hazard identification (HAZID) and hazard and operability (HAZOP) methodologies the study systematically identifies and compares the unique risks and safety strategies for GH2 and LH2 FGSS. For GH2-FGSS HAZID identifies 22 hazards with one unacceptable risk related to potential explosions from high-pressure hydrogen accumulation due to ventilation failure. HAZOP identifies 27 hazards all categorized as acceptable or ALARP. Recommended safety measures include pressure protection devices real-time alarms and enhanced piping durability. For LH2-FGSS HAZID identifies 38 hazards without any unacceptable risks though cryogenic icing and overpressure remain significant concerns. HAZOP reveals 43 hazards with one unacceptable risk involving thermal contraction and piping damage from repeated operations posing fire hazards. Suggested mitigations include improved cooling and purge gas procedures along with rigorous insulation management. Primary differences in safety management focus on high explosion risk of GH2-FGSS from high-pressure storage and the piping damage risk of LH2-FGSS from icing and thermal contraction. To enhance risk management for each system future research implements an operational simulation-based quantitative risk assessment. This study provides foundational safety strategies and guidelines for future vessels supporting the adoption of eco-friendly fuels in the maritime industry.
Numerical Investigation of Marine Dual-Fuel Engine Operating with High Shares of Premixed Hydrogen Fuel Using LES
Oct 2025
Publication
Hydrogen fuel presents a promising pathway for achieving long-term decarbonization in the maritime sector. However its use in diesel engines introduces challenges due to high reactivity leading to increased NOx emissions and combustion instability. The aim of this study is to identify settings so that the investigated engine operates with 60% hydrogen energy fraction at high load through CFD modelling. The model is utilized to simulate a four-stroke 10.5 MW marine engine at 90% load incorporating 60% hydrogen injection by energy at the engine intake port. The CFD model is verified using experimental data from diesel operation of the marine engine and hydrogen operation of a light-duty engine. The engine performance was determined and detailed emissions analysis was conducted including NO NO2 HO2 and OH. The findings indicate a substantial rise in NOx emissions as opposed to diesel operation due to elevated combustion temperatures and increased residence time at elevated temperature of the mixture in-cylinder. The presence of HO2 and OH highlights critical zones of combustion which contribute to operational stability. The novelty of this study is supported by the examination of the high hydrogen energy fraction the advanced emissions analysis and the insights into the emissions–performance trade-offs in hydrogen-fueled dual-fuel marine engines. The results offer guidance for the development of sustainable hydrogen-based marine propulsion systems.
The Lack of Systems Thinking and Interdisciplinarity is Killing the Hydrogen Economy
Sep 2025
Publication
Hydrogen’s promise as a transformative energy solution has been consistently unfulfilled. This perspective article suggests that the primary barrier is not necessarily technological but a systemic failure to apply holistic systems thinking and genuine interdisciplinary collaboration. Through historical analysis and contemporary case studies we argue that only by integrating technical economic policy and social expertise within a holistic systems framework across the entire value chain can hydrogen overcome its boom-and-bust cycles and become a foundational component of the low-carbon energy future.
Decarbonising European Heavy-duty Transport: A Stakeholder Analysis of Technology Readiness and Future R&I Priorities for Zero-emission Vehicles and Infrastructure
Sep 2025
Publication
This report identifies the critical research and innovation (R&I) priorities for decarbonising Europe's heavy-duty vehicles based on direct feedback from industry stakeholders. The findings reveal a consensus: battery electric technology is the primary pathway forward with significant stakeholder support for R&I focused on its improvement. While battery electric technology is perceived as more mature hydrogen is considered a complementary solution for the most demanding long-haul routes. Large-scale demonstrations are suggested for de-risking operations and evaluating integration with the transport and energy system. The analysis confirms that achieving TCO parity or better compared to diesel is the most important factor for market uptake. This study provides direct evidence-based guidance for EU transport R&I policy helping to chart the road ahead and orient R&I call programming to meet the ambitious CO₂ emission standards for heavy-duty vehicles.
Plasma-Assisted Hydrogen Production: Technologies, Challenges, and Future Prospects
Apr 2025
Publication
As global demand for clean energy continues to rise hydrogen as an ideal energy carrier plays a crucial role in the energy transition. Traditional hydrogen production methods predominantly rely on fossil fuels leading to environmental pollution and energy inefficiency. In contrast plasma-assisted hydrogen production as an emerging technology has gained significant attention due to its high efficiency environmental friendliness and flexibility. Plasma technology generates high-energy electrons or ions by exciting gas molecules which under specific conditions effectively decompose water vapor or hydrocarbon gases to produce hydrogen. This review systematically summarizes the basic principles technological routes research progress and potential applications of plasmaassisted hydrogen production. It focuses on various plasma-based hydrogen production methods such as water vapor decomposition hydrocarbon cracking arc discharge and microwave discharge highlighting their advantages and challenges. Additionally it addresses key issues facing plasma-assisted hydrogen production including energy efficiency improvement reactor stability and cost optimization and discusses the future prospects of these technologies. With ongoing advancements plasma-assisted hydrogen production is expected to become a mainstream technology for hydrogen production contributing to global goals of zero carbon emissions and sustainable energy development.
GB Energy Networks: Experts' Views on Future Pathways and Multi-vector Energy Networks Approach
Jul 2025
Publication
The decarbonization of energy systems poses significant challenges to energy networks due to the introduction of new energy vectors and changes in the pattern of energy demand. However this is currently an under-researched area. This paper addresses a gap in the literature by drawing on the socio-technological transitions and multi-system interactions literature to explore the views of experts from industry academia and other sectors about the challenges facing UK energy networks and the possible solutions including taking a more wholistic approach to the planning and operation of dierent networks. Using these frameworks we have demonstrated that systems can be deliberately integrated to interact and solve particular system challenges and have identified the nature of these interactions. The empirical results identify areas of consensus and disagreement about the future development of network infrastructure and regulation. They also highlight how government policy responds to the challenges and opportunities presented by the UK climate targets. The findings show widespread agreement that the UK energy system will become more electrified and decentralized as it incorporates more renewable energy. However the role of gaseous fuels in the energy system is more uncertain with some experts seeing a move from natural gas to hydrogen as being key to maintaining the security of supply while others see little or no role for hydrogen. There is also widespread agreement that the regulatory structure should change to address the challenges facing energy networks with much less agreement on whether this could happen quickly enough. Recent developments indicate the UK Government recognizes the need for regulatory change but it is premature to foresee their success in helping networks be a driver of rather than a barrier to a net-zero energy system.
From Natural Gas to Hydrogen: Climate Impacts of Current and Future Gas Transmission Networks in Germany
May 2025
Publication
Hydrogen emissions arise from leakage during its production transport storage and use leading to an increase in atmospheric hydrogen concentrations. These emissions also cause an indirect climate effect which has been quantified in the literature with a global warming potential over 100 years (GWP100) of about 11.6 placing hydrogen between carbon dioxide (1) and methane (29.8). There is increasing debate about the climate impact of an energy transition based on hydrogen. As a case study we have therefore evaluated the expected climate impact of switching from the long-distance natural gas transmission network to the outlined future “hydrogen core network” in Germany. Our analysis focuses on the relevant sources and network components of emissions. Our results show that the emissions from the network itself represent only about 1.8% of total emissions from the transmission of hydrogen with 98% attributed to energy-related compressor emissions and only 2% to fugitive and operational hydrogen leakage. Compared to the current natural gas transmission network we calculate a 99% reduction in total network emissions and a 97% reduction in specific emissions per transported unit of energy. In the discussion we show that when considering the entire life cycle which also includes emissions from the upstream and end-use phases the switch to hydrogen reduces the overall climate impact by almost 90%. However while our results show a significantly lower climate impact of hydrogen compared to natural gas minimising any remaining emissions remains crucial to achieve carbon neutrality by 2045 as set in Germany’s Federal Climate Action Act. Hence we recommend further reducing the emissions intensity of hydrogen supply and minimising the indirect emissions associated with the energy supply of compressors.
Thermo-economic Analysis of Blending Hydrogen into Natural Gas Pipeline with Gaseous Inhibitors for Sustainable Hydrogen Transportation
Apr 2025
Publication
Hydrogen transportation through a new pipeline poses significant economic barriers and blending hydrogen into existing natural gas pipelines offers promising alternative. However hydrogen’s low energy density and potential material compatibility challenges necessitate modifications to existing infrastructure. This study conducts a comprehensive thermo-economic analysis of natural gas and hydrogen mixtures with and without gaseous inhibitors evaluating the impact on thermophysical properties (Wobbe index density viscosity energy density higher and lower heating values) compression power economic feasibility and storage volume requirement. A pipeline transmission model was developed in Aspen HYSYS to assess these properties considering major and minor infrastructure modifications. The findings suggest that the addition of 5% carbon monoxide and 2% ethylene as gaseous inhibitors in maintaining desired properties ensuring compatibility with existing infrastructure and operational processes. The findings also indicate that blending 30% hydrogen increases storage volume by 30–55% while reducing higher and lower heating values by 20–25%. However the addition of 5% carbon monoxide and 2% ethylene improves the pipeline performance and reduces the carbon emissions by 23–26% supporting the transition to low-carbon energy systems. The results suggest that hydrogen blending is viable under specific infrastructure modifications providing critical insights for optimizing pipeline repurposing for sustainable hydrogen transportation.
Forward Osmosis Membrane Bioreactor for Sustainable Hydrogen Production from Waste Molasses
Oct 2025
Publication
The current study evaluates the feasibility of a forward osmosis membrane bioreactor (FO-MBR) for dark fermentation aiming at simultaneous biohydrogen production and wastewater treatment. Optimal microbial inoculation was achieved via heat-treated activated sludge enriching Clostridium sensu stricto 1 and yielding up to 2.21 mol H2.(mol hexose)− 1 in batch mode. In continuous operation a substrate concentration of 4.4 g L− 1 and a hydraulic retention time (HRT) of 12 h delivered the best results producing 1.51 mol H2.(mol hexosesupplied) − 1 . The FO-MBR configured with a 1.1 m2 hollow fiber side-stream membrane module and operated under dynamic HRT (2.5–12 h) dependent on membrane flux was integrated with intermittent CSTR (Continuous stirred tank reactor) operation to counter metabolite accumulation. This system outperformed a conventional CSTR achieving a hydrogen yield of 1.78 mol H2.(mol hexosesupplied) − 1 . Remarkable treatment efficiencies were observed with BOD5 COD and TOC removal rates of 95.32 % 99.02 % and 99.10 % respectively and an 83.8 % reduction in total waste volume. Additionally the FO-MBR demonstrated strong antifouling performance with 96.14 % water flux recovery achieved after a brief 5 min hydraulic rinse following 47.5 h of continuous highstrength broth exposure. These results highlight the FO-MBR system’s ability as a sustainable and highperformance alternative for integrated hydrogen production and effluent treatment. Further studies are recommended to address long-term fouling control and metabolite management for industrial scalability.
Hydrogen UK - Splitting the Difference: Reducing the Cost of Electrolytic Hydrogen to Accelerate Deployment
Jan 2025
Publication
The UK is set to build on its world leading position of renewables deployment targeting as much as 50GW of offshore wind 27GW of onshore wind and 47GW of solar by 2030 as part of the Clean Power 2030 mission. As we move towards a net zero power system driven by renewables and away from unabated gas the UK will need greater capability to manage periods of low and excess renewable generation. Electrolytic hydrogen is a critical solution to this challenge as the Clean Power Plan and the advice from NESO make clear. Firstly because hydrogen can be stored for long periods of time and in large volumes and because curtailed power can be very low cost. Therefore electrolytic hydrogen can provide cost-effective long duration energy storage which can then be used as a low carbon alternative to natural gas for dispatchable power generation and for a wide variety of uses essential to the full decarbonisation of other sectors including industry and heavy transport. Secondly electrolytic hydrogen can be produced using the renewable power in places such as Scotland that would otherwise go to waste due to the lack of network capacity or demand. Building electrolytic hydrogen production capacity in areas with high renewables and behind grid constraints has a wide range of benefits. Providing electricity demand for the increasing levels of onshore and offshore wind that is in the pipeline in Scotland is going to be critical for renewable deployment while reducing constraint costs paid by consumers. Thus by providing a source of firm power and demand for excess renewable generation electrolytic hydrogen is fundamental to ensuring security of supply in a low carbon power system.
This paper can be found on their website.
This paper can be found on their website.
Photoelectrochemical Water Splitting under Concentrated Sunlight: Best Practices and Protocols
Mar 2025
Publication
Photoelectrochemical (PEC) water splitting is a promising technology for green hydrogen production by harnessing solar energy. Traditionally this sustainable approach is studied under light intensity of 100 mW/cm2 mimicking the natural solar irradiation at the Earth’s surface. Sunlight can be easily concentrated using simple optical systems like Fresnel lens to enhance charge carrier generation and hydrogen production in PEC water splitting. Despite the great potentials this strategy has not been extensively studied and faces challenges related to the stability of photoelectrodes. To prompt the investigations and applications this work outlines the best practices and protocols for conducting PEC solar water splitting under concentrated sunlight illumination incorporating our recent advancements and providing some experimental guidelines. The key factors such as light source calibration photoelectrode preparation PEC cell configuration and long-term stability test are discussed to ensure reproducible and high performance. Additionally the challenges of the expected photothermal effect and the heat energy utilization strategy are discussed.
Comparative Electrochemical Performance of Solid Oxide Fuel Cells: Hydrogen vs. Ammonia Fuels—A Mini Review
Apr 2025
Publication
Solid oxide fuel cells (SOFCs) have garnered significant attention as a promising technology for clean and efficient power generation due to their ability to utilise renewable fuels such as hydrogen and ammonia. As carbon-free energy carriers hydrogen and ammonia are expected to play a pivotal role in achieving net-zero emissions. However a critical research question remains: how does the electrochemical performance of SOFCs compare when fuelled by hydrogen vs. ammonia and what are the implications for their practical application in power generation? This mini-review paper is premised on the hypothesis that while hydrogen-fuelled SOFCs currently demonstrate superior stability and performance at low and high temperatures ammonia-fuelled SOFCs offer unique advantages such as higher electrical efficiencies and improved fuel utilisation. These benefits make ammonia a viable alternative fuel source for SOFCs particularly at elevated temperatures. To address this the mini-review paper provides a comprehensive comparative analysis of the electrochemical performance of SOFCs under direct hydrogen and ammonia fuels focusing on key parameters such as open-circuit voltage (OCV) power density electrochemical impedance spectroscopy fuel utilisation stability and electrical efficiency. Recent advances in electrode materials electrolytes fabrication techniques and cell structures are also highlighted. Through an extensive literature survey it is found that hydrogen-fuelled SOFCs exhibit higher stability and are less affected by temperature cycling. In contrast ammonia-fuelled SOFCs achieve higher OCVs (by 7%) and power densities (1880 mW/cm2 vs. 1330 mW/cm2 for hydrogen) at 650 °C along with 6% higher electrical efficiency. Despite these advantages ammonia-fuelled SOFCs face challenges such as NOx emissions nitride formation environmental impact and OCV stabilisation which are discussed alongside potential solutions. This mini review aims to provide insights into the future direction of SOFC research emphasising the need for further exploration of ammonia as a sustainable fuel alternative.
Hydrogen Production Plant Retrofit for Green H2: Experimental Validation of a High-Efficiency Retrofit of an Alkaline Hydrogen Plant Using an Isolated DC Microgrid
Oct 2025
Publication
Given the climate change observed in the past few decades sustainable development and the use of renewable energy sources are urgent. In this scenario hydrogen production through electrolyzers is a promising renewable source and energy vector because of its ultralow greenhouse emissions and high energy content. Hydrogen can be used in a variety of applications from transportation to electricity generation contributing to the diversification of the energy matrix. In this context this paper presents an autonomous isolated DC microgrid system for generating and storing electrical energy to be exclusively used for feeding an electrolyzer hydrogen production plant which has been retrofitted for green hydrogen production. Experimental verification was performed at Itaipu Parquetec which consists of an alkaline electrolysis unit directly integrated with a battery energy storage system and renewable sources (e.g. photovoltaic and wind) by using an isolated DC microgrid concept based on DC/DC and AC/DC converters. Experimental results revealed that the new electrolyzer DC microgrid increases the system’s overall efficiency in comparison to the legacy thyristor-based power supply system by 26% and it autonomously controls the energy supply to the electrolyzer under optimized conditions with an extremely low output current ripple. Another advantage of the proposed DC microgrid is its ability to properly manage the startup and shutdown process of the electrolyzer plant under power generation outages. This paper is the result of activities carried out under the R&D project of ANEEL program No. PD-10381-0221/2021 entitled “Multiport DC-DC Converter and IoT System for Intelligent Energy Management” which was conducted in partnership with CTG-Brazil.
Boosting Green Hydrogen Production—Energy Savings in Alkaline Water Electrolysis Using Synergy of Magnetic Field and In Situ Activation of Electrodes
Oct 2025
Publication
This study focuses on enhancing the efficiency of alkaline water electrolysis technology a key process in green hydrogen production by leveraging the synergy of magnetic fields and in situ electrode activation. Optimizing AWE efficiency is essential to meet increasing demands for sustainable energy solutions. In this research nickel mesh electrodes were modified through the application of magnetic fields and the addition of hypo-hyper d-metal (cobalt complexes and molybdenum salt) to the electrolyte. These enhancements improve mass transfer facilitate bubble detachment and create a high-surface-area catalytic layer on the electrodes all of which lead to improved hydrogen evolution rates. The integration of magnetic fields and in situ activation achieved over 35% energy savings offering a cost-effective and scalable pathway for industrial green hydrogen production.
Biohydrogen Production from Industrial Wastewater: An Overview
Jun 2019
Publication
Biohydrogen production from industrial wastewater has been a focus of interest in recent years. The in depth knowledge in lab scale parameters and emerging strategies are needed to be investigated in order to implement the biohydrogen production process at large scale. The operating parameters have great influence on biohydrogen productivity. With the aim to gain major insight into biohydrogen production process this review summarizes recent updates on dark fermentation inoculum pretreatment methods operating parameters (hydraulic retention time organic loading rate pH temperature volatile fatty acids bioreactor configuration nutrient availability partial pressure etc.). The challenges and limitations associated with the biohydrogen production are lack of biohydrogen producers biomass washout and accumulation of metabolites are discussed in detail. The advancement strategies to overcome these limitations are also briefly discussed.
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