Publications
Small-Scale High-Pressure Hydrogen Storage Vessels: A Review
Feb 2024
Publication
Nowadays high-pressure hydrogen storage is the most commercially used technology owing to its high hydrogen purity rapid charging/discharging of hydrogen and low-cost manufacturing. Despite numerous reviews on hydrogen storage technologies there is a relative scarcity of comprehensive examinations specifically focused on high-pressure gaseous hydrogen storage and its associated materials. This article systematically presents the manufacturing processes and materials used for a variety of high-pressure hydrogen storage containers including metal cylinders carbon fiber composite cylinders and emerging glass material-based hydrogen storage containers. Furthermore it introduces the relevant principles and theoretical studies showcasing their advantages and disadvantages compared to conventional high-pressure hydrogen storage containers. Finally this article provides an outlook on the future development of high-pressure hydrogen storage containers.
Green with Envy? Hydrogen Production in a Carbon-constrained World
Jan 2024
Publication
Hydrogen is widely recognized as a key component of a decarbonized global energy system serving as both a fuel source and an energy storage medium. While current hydrogen production relies almost entirely on emissionsintensive processes two low-emissions production pathways – natural-gas-derived production combined with carbon capture and storage and electrolysis using carbon-free electricity – are poised to change the global supply mix. Our study assesses the financial conditions under which natural-gas-based hydrogen production combined with carbon capture and storage would be available at a cost lower than hydrogen produced through electrolysis and the degree to which these conditions are likely to arise in a transition to a net-zero world. We also assess the degree to which emissions reduction policies namely carbon pricing and carbon capture and storage tax credits affect the relative costs of hydrogen production derived from different pathways. We show that while carbon pricing can improve the relative cost of both green and blue hydrogen production compared with unabated grey hydrogen targeted tax credits favouring either blue or green hydrogen explicitly may increase emissions and/or increase the costs of the energy transition.
Synergy of Carbon Capture, Waste Heat Recovery and Hydrogen Production for Industrial Decarbonisation
May 2024
Publication
Industry is the biggest sector of energy consumption and greenhouse gas emissions whose decarbonisation is essential to achieve the Sustainable Development Goals. Carbon capture energy efficiency improvement and hydrogen are among the main strategies for industrial decarbonization. However novel approaches are needed to address the key requirements and differences between sectors to ensure they can work together to well integrate industrial decarbonisation with heat CO2 and hydrogen. The emerging Calcium Looping (CaL) is attracting interest in designing CO2-involved chemical processes for heat capture and storage. The reversibility relatively high-temperature (600 to 900 ◦C) and high energy capacity output as well as carbon capture function make CaL well-fit for CO2 capture and utilisation and waste heat recovery from industrial flue gases. Meanwhile methane dry reforming (MDR) is a promising technology to produce blue hydrogen via the consumption of two major greenhouse gases i.e. CO2 and CH4. It has great potential to combine the two technologies to achieve insitu CO2 utilization with multiple benefits. In this paper progresses on the reaction conditions and performance of CaL for CO2 capture and industrial waste heat recovery as well as MDR were screened. Secondly recent approaches to CaL-MDR synergy have been reviewed to identify the advantages. The major challenges in such a synergistic process include MDR catalyst deactivation CaL sorbents sintering and system integration. Thirdly the paper outlooks future work to explore a rational design of a multi-function system for the proposed synergistic process.
PEM Water Electrolysis for Hydrogen Production: Fundamentals, Advances, and Prospects
Jun 2022
Publication
Hydrogen as a clean energy carrier is of great potential to be an alternative fuel in the future. Proton exchange membrane (PEM) water electrolysis is hailed as the most desired technology for high purity hydrogen production and self-consistent with volatility of renewable energies has ignited much attention in the past decades based on the high current density greater energy efficiency small mass-volume characteristic easy handling and maintenance. To date substantial efforts have been devoted to the development of advanced electrocatalysts to improve electrolytic efficiency and reduce the cost of PEM electrolyser. In this review we firstly compare the alkaline water electrolysis (AWE) solid oxide electrolysis (SOE) and PEM water electrolysis and highlight the advantages of PEM water electrolysis. Furthermore we summarize the recent progress in PEM water electrolysis including hydrogen evolution reaction (HER) and oxygen evolution reaction (OER) electrocatalysts in the acidic electrolyte. We also introduce other PEM cell components (including membrane electrode assembly current collector and bipolar plate). Finally the current challenges and an outlook for the future development of PEM water electrolysis technology for application in future hydrogen production are provided.
Semi-Systematic Literature Review on the Contribution of Hydrogen to Universal Access to Energy in the Rationale of Sustainable Development Goal Target 7.1
Feb 2023
Publication
As part of the United Nations’ (UN) Sustainable Development Goal 7 (SDG7) SDG target 7.1 recognizes universal electrification and the provision of clean cooking fuel as two fundamental challenges for global society. Faltering progress toward SDG target 7.1 calls for innovative technologies to stimulate advancements. Hydrogen has been proposed as a versatile energy carrier to be applied in both pillars of SDG target 7.1: electrification and clean cooking. This paper conducts a semi-systematic literature review to provide the status quo of research on the application of hydrogen in the rationale of SDG 7.1 covering the technical integration pathways as well as the key economic environmental and social aspects of its use. We identify decisive factors for the future development of hydrogen use in the rationale of SDG target 7.1 and by complementing our analysis with insights from the related literature propose future avenues of research. The literature on electrification proposes that hydrogen can serve as a backup power supply in rural off-grid communities. While common electrification efforts aim to supply appliances that use lower amounts of electricity a hydrogen-based power supply can satisfy appliances with higher power demands including electric cook stoves while simultaneously supporting clean cooking efforts. Alternatively with the exclusive aim of stimulating clean cooking hydrogen is proposed to be used as a clean cooking fuel via direct combustion in distribution and utilization infrastructures analogous to Liquid Petroleum Gas (LPG). While expected economic and technical developments are seen as likely to render hydrogen technologies economically competitive with conventional fossil fuels in the future the potential of renewably produced hydrogen usage to reduce climate-change impacts and point-of-use emissions is already evident today. Social benefits are likely when meeting essential safety standards as a hydrogen-based power supply offers service on a high tier that might overachieve SDG 7.1 ambitions while hydrogen cooking via combustion fits into the existing social habits of LPG users. However the literature lacks clear evidence on the social impact of hydrogen usage. Impact assessments of demonstration projects are required to fill this research gap.
Forecasting the Development of Clean Energy Vehicles in Large Cities: A System Dynamics Perspective
Jan 2024
Publication
Clean energy vehicles (CEVs) e.g. battery electric vehicles (BEVs) and fuel cell electric vehicles (FCEVs) are being adopted gradually to substitute for internal combustion engine vehicles (ICEVs) around the world. The fueling infrastructure is one of the key drivers for the development of the CEV market. When the government develops funding policies to support the fueling infrastructure development for FCEVs and BEVs it has to assess the effectiveness of different policy options and identify the optimal policy combination which is very challenging in transportation research. In this paper we develop a system dynamics model to study the feedback mechanism between the fueling infrastructure funding policies and the medium- to long-term diffusion of FCEVs and BEVs and the competition between FCEVs and BEVs based on relevant policy and market data in Guangzhou China. The results of the modeling analysis are as follows. (1) Funding hydrogen refueling stations and public charging piles has positive implications for achieving the substitution of CEVs for ICEVs. (2) Adjusting the funding ratio of hydrogen refueling stations and public charging piles or increasing the funding budget and extending the funding cycle does not have a significant impact on the overall substitution of CEVs for ICEVs but only impacts the relative competitive advantage between FCEVs and BEVs. (3) An equal share of funding for hydrogen refueling stations and public charging piles would have better strategic value for future net-zero-emissions urban transportation. (4) Making a moderate-level full investment in hydrogen refueling stations coupled with hydrogen refueling subsidies can provide the ideal conditions for FCEV diffusion.
Techno-economic Viability of Decentralised Solar Photovoltaic-based Green Hydrogen Production for Sustainable Energy Transition in Ghana
Feb 2024
Publication
Transition to a sustainable energy supply is essential for addressing the challenges of climate change and achieving a low-carbon future. Green hydrogen produced from solar photovoltaic (PV) systems presents a promising solution in Ghana where energy demands are increasing rapidly. The levelized cost of hydrogen (LCOH) is considered a critical metric to evaluate hydrogen production techniques cost competitiveness and economic viability. This study presents a comprehensive analysis of LCOH from solar PV systems. The study considered a 5 MW green hydrogen production plant in Ghana’s capital Accra as a proposed system. The results indicate that the LCOH is about $9.49/kg which is comparable to other findings obtained within the SubSaharan Africa region. The study also forecasted that the LCOH for solar PV-based hydrogen produced will decrease to $5–6.5/kg by 2030 and $2–2.5/kg by 2050 or lower making it competitive with fossil fuel-based hydrogen. The findings of this study highlight the potential of green hydrogen as a sustainable energy solution and its role in driving the country’s net-zero emissions agenda in relation to its energy transition targets. The study’s outcomes are relevant to policymakers researchers investors and energy stakeholders in making informed decisions regarding deploying decentralised green hydrogen technologies in Ghana and similar contexts worldwide.
Techno-Economic Analysis of Cement Decarbonization Techniques: Oxygen Enrichment vs. Hydrogen Fuel
Feb 2024
Publication
The Paris Agreement aims to limit global warming and one of the most polluting sectors is heavy industry where cement production is a significant contributor. This work briefly explores some alternatives recycling reducing clinker content waste heat recovery and carbon capture discussing their advantages and drawbacks. Then it examines the economic viability and benefits of increasing oxygen concentration in the primary burning air from 21 to 27 vol.% which could improve clinker production by 7% and the production of hydrogen through PEM electrolysis to make up 5% of the fuel thermal fraction considering both in a cement plant producing 3000 tons of clinker per day. This analysis used reference values from Secil an international company for cement and building materials to determine the required scale of the oxygen and hydrogen production respectively and calculate the CAPEX of each approach. It is concluded that oxygen enrichment can provide substantial fuel savings for a relatively low cost despite a possible significant increase in NOx emissions. However hydrogen production at this scale is not currently economically viable.
Modeling the Long-term Evolution of the Italian Power Sector: The Role of Renewable Resources and Energy Storage Facilities
Feb 2024
Publication
The aim of this study is to investigate the long-term planning of the Italian power sector from 2021 to 2050. The key role of photovoltaic and wind technologies in combination with power-to-power systems based on hydrogen and batteries is investigated. An updated version of the OSeMOSYS tool is used which employs a clustering method for the representation of time-varying input data. First the potential of variable renewable energy sources (VRES) is assessed. A sensitivity analysis is also performed on the temporal resolution of the model to determine an adequate trade-off between the computation time and the accuracy of the results. Then a technoeconomic optimization scenario is carried out resulting in a total net present cost of about 233.7 B€. A high penetration of VRES technologies is foreseen by 2050 with a total VRES installed capacity of 272.9 GW (mainly photovoltaic and onshore wind). Batteries are found to be the preferable energy storage solution in the first part of the energy transition while the hydrogen storage starts to be convenient from about the year 2040. Indeed the role of hydrogen storage becomes fundamental as the VRES penetration increases thanks to its cost-effective long-term storage capability. By 2050 74.6 % of electricity generation will be based on VRES which will also enable a significant reduction in CO2 emissions of about 87 %.
A Review on Biohydrogen Sources, Production Routes, and Its Application as a Fuel Cell
Aug 2023
Publication
More than 80% of the energy from fossil fuels is utilized in homes and industries. Increased use of fossil fuels not only depletes them but also contributes to global warming. By 2050 the usage of fossil fuels will be approximately lower than 80% than it is today. There is no yearly variation in the amount of CO2 in the atmosphere due to soil and land plants. Therefore an alternative source of energy is required to overcome these problems. Biohydrogen is considered to be a renewable source of energy which is useful for electricity generation rather than relying on harmful fossil fuels. Hydrogen can be produced from a variety of sources and technologies and has numerous applications including electricity generation being a clean energy carrier and as an alternative fuel. In this review a detailed elaboration about different kinds of sources involved in biohydrogen production various biohydrogen production routes and their applications in electricity generation is provided.
A Novel Layout for Combined Heat and Power Production for a Hospital Based on a Solid Oxide Fuel Cell
Feb 2024
Publication
This paper addresses the problem of the reduction in the huge energy demand of hospitals and health care facilities. The sharp increase in the natural gas price due to the Ukrainian–Russian war has significantly reduced economic savings achieved by combined heat and power (CHP) units especially for hospitals. In this framework this research proposes a novel system based on the integration of a reversible CHP solid oxide fuel cell (SOFC) and a photovoltaic field (PV). The PV power is mainly used for balancing the hospital load. The excess power production is exploited to produce renewable hydrogen. The SOFC operates in electrical tracking mode. The cogenerative heat produced by the SOFC is exploited to partially meet the thermal load of the hospital. The SOFC is driven by the renewable hydrogen produced by the plant. When this hydrogen is not available the SOFC is driven by natural gas. In fact the SOFC is coupled with an external reformer. The simulation model of the whole plant including the reversible SOFC PV and hospital is developed in the TRNSYS18 environment and MATLAB. The model of the hospital is calibrated by means of measured data. The proposed system achieves very interesting results with a primary energy-saving index of 33% and a payback period of 6.7 years. Therefore this energy measure results in a promising solution for reducing the environmental impact of hospital and health care facilities.
H2 URESONIC: Design of a Solar-Hydrogen University Renewable Energy System for a New and Innovative Campus
Feb 2024
Publication
The necessity to move to sustainable energy solutions has inspired an investigation of innovative technologies for satisfying educational institutions’ sustainable energy needs. The possibility of a solar-hydrogen storage system and its integration into university energy management is investigated in this article. The study opens by providing context noting the growing relevance of renewable energy in universities as well as the necessity for effective energy storage systems. The goal is to delve into solar-hydrogen technology outlining its components operating mechanism and benefits over typical storage systems. The chapter on Integration Design examines current university energy infrastructure identifies problems and provides ways for integrating solar-hydrogen systems seamlessly. This integration relies heavily on technological and economic considerations such as a cost-benefit analysis and scalability studies. Case studies include real-world examples performance measurements and significant insights learned from successful implementations. The chapter Future Prospects investigates new trends in solar-hydrogen technology as well as the impact of government legislation providing a forward-looking viewpoint for colleges considering adoption. The report concludes with a summary of significant findings emphasizing the benefits of solar-hydrogen integration and making recommendations for future implementations. The limitation of this research is that it only focuses on design and simulation as a phase of preliminary study.
Utilization of Hydro Sources in Canada for Green Hydrogen Fuel Production
Oct 2024
Publication
The present study comprehensively examines the application of hydro wave tidal undersea current and geothermal energy sources of Canada for green hydrogen fuel production. The estimated potential capacity of each province is derived from official data and acceptable assumptions and is subject to discussion and evaluation in the context of a viable hydrogen economy. According to the findings the potential for green hydrogen generation in Canada is projected to be 48.86 megatons. The economic value of the produced green hydrogen results in an equivalent of 21.30 billion US$. The top three provinces with the highest green hydrogen production potential using hydro resources including hydro wave tidal undersea current and geothermal are Alberta Quebec and British Columbia with 26.13 Mt 7.34 Mt and 4.39 Mt respectively. Quebec is ranked first by only considering the marine sources including 4.14 Mt with hydro 1.46 Mt with wave 0.27 Mt underwater current and 1.45 Mt with tidal respectively. Alberta is listed as the province with the highest capacity for hydrogen production from geothermal energy amounting up to 26.09 Mt. The primary objective is to provide comprehensive hydrogen maps for each province in Canada which will be based on the identified renewable energy potential and the utilization of electrolysers. This may further be examined within the framework of the prevailing policies implemented by local communities and officials in order to develop a sustainable energy plan for the nation.
Power Sector Effects of Green Hydrogen Production in Germany
Aug 2023
Publication
The use of green hydrogen can support the decarbonization of sectors which are difficult to electrify such as industry or heavy transport. Yet the wider power sector effects of providing green hydrogen are not well understood so far. We use an open-source electricity sector model to investigate potential power sector interactions of three alternative supply chains for green hydrogen in Germany in the year 2030. We distinguish between model settings in which Germany is modeled as an electric island versus embedded in an interconnected system with its neighboring countries as well as settings with and without technology-specific capacity bounds on wind energy. The findings suggest that large-scale hydrogen storage can provide valuable flexibility to the power system in settings with high renewable energy shares. These benefits are more pronounced in the absence of flexibility from geographical balancing. We further find that the effects of green hydrogen production on the optimal generation portfolio strongly depend on the model assumptions regarding capacity expansion potentials. We also identify a potential distributional effect of green hydrogen production at the expense of other electricity consumers of which policy makers should be aware.
A New Method to Quantify the Leakage Scenarios (Frequencies and Flowrates) on Hydrogen High Pressure Components
Sep 2023
Publication
This work is part of the MULTHYFUEL E.U. research program [1] aiming at enabling the implementation of hydrogen dispersers in refuelling stations. One important challenge is the severity of accidents due to a leakage of hydrogen from a dispenser in the forecourt. The work presented in this paper deals with the quantification of the leakage scenarios in terms of frequencies and severities. The risk analysis exercise although performed by experts showed very large discrepancies between the frequencies of leakages of the same categories and even between the consequences. A large part of the disagreement comes from the failure databases chosen as shown in the paper. The mismatch between the components on which the databases have been settled and the actual hydrogen components may be responsible for this situation. However as it stands limited confidence can be laid on the outcome of the risk analysis.<br/>A new method is being developed to calculate the frequencies of the leakage and the flowrate based on an accurate description of each component and of each hazardous situation. For instance the possibility for a fitting to become untight due to pressure cycling is modelled based on the contact mechanics. Human errors can also be introduced by describing the tasks. In addition of the description of the method the application to a disperser is proposed with some comparison to experiments. One of the outcomes is that leakage cross sections can be much larger than expected.
Advancements in Hydrogen Energy Systems: A Review of Levelized Costs, Financial Incentives and Technological Innovations
Apr 2024
Publication
Hydrogen energy systems (HES) are increasingly recognized as pivotal in cutting global carbon dioxide (CO2) emissions especially in transportation power generation and industrial sectors. This paper offers a comprehensive review of HES emphasizing their diverse applications and economic viability. By 2030 hydrogen energy is expected to revolutionize various sectors significantly impacting CO2 abatement and energy demand. In electricity and power generation hydrogen could reduce CO2 emissions by 50–100 million tons annually requiring 10–20 million tons of hydrogen and an investment of $50–100 billion underscoring its role in grid stabilization. Additionally in the heating sector hydrogen could facilitate a CO2 abatement of 30–50 million tons. We examine the levelized cost of hydrogen (LCOH) production influenced by factors like production methods efficiency and infrastructure. While steam methane reforming is cost-effective it poses a larger environmental impact compared to electrolysis. The global life-cycle cost of hydrogen production decreases as production scales up with current costs ranging from $1–3 per kg for fossil-based sources to $3.4–7.5 per kg for electrolysis using low-emission electricity. These costs are projected to decrease especially for electrolytic hydrogen in regions with abundant solar energy. However despite the technical feasibility of decarbonization high production costs still pose challenges. A systematic and effective transition to a hydrogen economy requires comprehensive policy and financial support mechanisms including incentives subsidies tax measures and funding for research and development of pilot projects. Additionally the paper discusses hydrogen's role in advanced storage technologies such as hydrides and Japan's ENE-FARM solution for residential energy emphasizing the need for strategic investments across the hydrogen value chain to enhance HES competitiveness reduce LCOH and advance the learning rates of hydrogen production technologies.
Techno-economic Assessment of Low-carbon Ammonia as Fuel for the Maritime Sector
Mar 2025
Publication
Low-carbon ammonia has recently received interest as alternative fuel for the maritime sector. This paper presents a techno-economic analysis of the total cost of ownership (TCO) of a Post-Panamax vessel powered by low-carbon ammonia. We also calculate the annual increase in carbon tax needed to compensate for the increment in TCO compared to a vessel powered by very low sulfur fuel oil. The increment in TCO is calculated as function of propulsion efficiency to account for uncertainties in the thermodynamics of ammonia combustion for three different cost scenarios of low-carbon ammonia. We evaluate the benefits and drawbacks of hydrogen and diesel as dual fuel for three types of propulsion systems: a compression ignition engine a spark-ignition engine and a combination of a solid oxide fuel cell (SOFC) system and a spark-ignition engine. We incorporate three different cost levels for ammonia and a variable engine efficiency ranging from 35% to 55%. If the ammonia engine has the efficiency of a conventional marine engine the increment in TCO is 25% in the most optimistic cost scenario. SOFCs can reach a better efficiency and yield no pollutant emissions but the reduction in fuel expenses in comparison to conventional combustion engines only offsets their high investment costs at either low engine efficiency or high fuel prices. The increment in TCO and reduction in GHG emissions depend on whether high combustion efficiencies small dual fuel fractions and low NOx N2O and NH3 emissions can be simultaneously achieved.
Mapping Hydrogen Initiatives in Italy: An Overview of Funding and Projects
May 2024
Publication
The global momentum towards hydrogen has led to various initiatives aimed at harnessing hydrogen’s potential. In particular low-carbon hydrogen is recognized for its crucial role in reducing greenhouse gas emissions across hard-to-abate sectors such as steel cement and heavy-duty transport. This study focuses on the presentation of all hydrogen-related financing initiatives in Italy providing a comprehensive overview of the various activities and their geographical locations. The examined funding comes from the National Recovery and Resilience Plan (PNRR) from projects directly funded through the Important Projects of Common European Interest (IPCEI) and from several initiatives supported by private companies or other funding sources (hydrogen valleys). Specific calls for proposals within the PNRR initiative outline the allocation of funds focusing on hydrogen production in brownfield areas (52 expected hydrogen production plants by 2026) hydrogen use in hard-to-abate sectors and the establishment of hydrogen refuelling stations for both road (48 refuelling stations by 2026) and railway transport (10 hydrogen-based railway lines). A detailed description of the funded initiatives (150 in total) is presented encompassing their geographical location typology and size (when available) as well as the funding they have received. This overview sheds light on regions prioritising decarbonisation efforts in heavy-duty transport especially along cross-border commercial routes as evident in northern Italy. Conversely some regions concentrate more on local transport typically buses or on the industrial sector primarily steel and chemical industries. Additionally the study presents initiatives aimed at strengthening the national manufacturing capacity for hydrogenrelated technologies alongside new regulatory and incentive schemes for hydrogen. The ultimate goal of this analysis is to foster connections among existing and planned projects stimulate new initiatives along the entire hydrogen value chain raise an awareness of hydrogen among stakeholders and promote cooperation and international competitiveness.
Critical Review of Life Cycle Assessment of Hydrogen Production Pathways
May 2024
Publication
In light of growing concerns regarding greenhouse gas emissions and the increasingly severe impacts of climate change the global situation demands immediate action to transition towards sustainable energy solutions. In this sense hydrogen could play a fundamental role in the energy transition offering a potential clean and versatile energy carrier. This paper reviews the recent results of Life Cycle Assessment studies of different hydrogen production pathways which are trying to define the routes that can guarantee the least environmental burdens. Steam methane reforming was considered as the benchmark for Global Warming Potential with an average emission of 11 kgCO2eq/kgH2. Hydrogen produced from water electrolysis powered by renewable energy (green H2 ) or nuclear energy (pink H2 ) showed the average lowest impacts with mean values of 2.02 kgCO2eq/kgH2 and 0.41 kgCO2eq/kgH2 respectively. The use of grid electricity to power the electrolyzer (yellow H2 ) raised the mean carbon footprint up to 17.2 kgCO2eq/kgH2 with a peak of 41.4 kgCO2eq/kgH2 in the case of countries with low renewable energy production. Waste pyrolysis and/or gasification presented average emissions three times higher than steam methane reforming while the recourse to residual biomass and biowaste significantly lowered greenhouse gas emissions. The acidification potential presents comparable results for all the technologies studied except for biomass gasification which showed significantly higher and more scattered values. Regarding the abiotic depletion potential (mineral) the main issue is the lack of an established recycling strategy especially for electrolysis technologies that hamper the inclusion of the End of Life stage in LCA computation. Whenever data were available hotspots for each hydrogen production process were identified.
A General Criterion for the Design and Operation of Flexible Hydrogen Storage in Power-to-X Processed
Dec 2024
Publication
This paper introduces a general criterion for the optimal design and operation of hydrogen storage tanks. Specifically the proposed procedure identifies the optimal delivery schedule that minimizes the capacity of material storage systems. Indeed many manufacturing processes need some buffer storage to administer mass flows appropriately according to the operating needs (one class above all: Power-to-X processes) and have one of their highest expenditures right in those tanks when proving not sufficiently flexible. Hence the novelty of the proposed method lies in a rigorous mathematical formulation that converts arbitrarily fluctuating inlet streams into optimally fluctuating outlet streams that minimize the storage volume and comply with different operating requirements. The criterion is validated by considering the techno-economic assessment of a chemical plant featuring a dedicated green hydrogen production facility that feeds the process. Specifically the required capacity of the “Flexible” hydrogen buffer storage which connects the green hydrogen generation system to the conversion process significantly decreases by 91.31%–99.31% (depending on the flexibility ranges enabled by the downstream conversion process) compared to the “Rigid” storage alternative based on a constant outlet mass flow withdrawal coinciding with the hydrogen consumption rate at nominal operating conditions. Correspondingly the resulting levelized cost of hydrogen benefits accordingly ranging from 4.19 to 6.03 USD/kg (California 2023).
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