Publications

Gi Editor Sharon Baker-Hallam sits down with Chris Stark CEO of the Committee on Climate Change to talk about this year’s Sir Denis Rooke Memorial Lecture the economic opportunities to be found in going green and why 2020 is a critical year in the ongoing battle against rising global temperatures

Current developments of non-relativistic quantum mechanics appear to predict and reveal counter-intuitive dynamical effects of hydrogen in nanostructured materials that are of considerable importance for basic research as well as for technological applications. In this review the experimental focus is on H₂O and H molecules in carbon nanotubes and other nanocavities that have been experimentally investigated using the well-established technique of incoherent inelastic neutron scattering (INS). For instance the momentum and energy transfers as obtained from the commonly used standard data analysis techniques from a

(I) H₂ molecule in a C-nanotube resulting in a roto-translational motion along the nanotube axis seems to (1) either violate the standard conservation laws or (2) to attribute to the H molecule undergoing translation the effective mass a.m.u. (atomic mass units) instead of the expected 2 a.m.u. A similar striking anomalous effect has been found in the neutron-H scattering from the

(II) H₂O molecules in nano-channels of some solid materials in which O-H stretching vibrations along the channel axis are created.

The results of this scattering process seem to once again either violate the standard conservation laws or to attribute to the effective mass of the struck H₂ molecule as a.m.u. instead of the expected value of 1 a.m.u. We show that these counterintuitive observations from the INS studies have no conventional interpretation within the standard non-relativistic scattering theory. However they can be qualitatively interpreted “from first principles” within the framework of modern theories of

(III) time-symmetric quantum dynamics as provided by the weak values (WV) and two-state- vector formalism (TSVF)

and/or

(IV) quantum correlations especially quantum discord (QD) and quantum thermodynamics (QTD).

The theoretical analysis provides an intuitive understanding of the experimental results gives strong evidence that the nano-structured cavities do represent quantum systems which participate significantly in the dynamics of the neutron-H scattering and surprisingly shows that new physical information can be derived from the experimental data. This latter point may also have far-reaching consequences for technology and material sciences (e.g. fuel cells H storage materials etc.). Moreover novel insights into the short-lived quantum dynamics and/or quantum information theory can be gained.

The reliable supplies of electricity and hydrogen required for 100% renewable energy systems have been found to be achievable by utilisation of a mix of different resources and storage technologies. In this paper more demanding parameter conditions than hitherto considered are used in measurement of the reliability of variable renewable energy resources. The defined conditions require that supply of baseload electricity (BLEL) and baseload hydrogen (BLH2) occurs solely using cost-optimised configurations of variable photovoltaic solar power onshore wind energy and balancing technologies. The global scenario modelling is based on hourly weather data in a 0.45° × 0.45° spatial resolution. Simulations are conducted for Onsite and Coastal Scenarios from 2020 to 2050 in 10-year time-steps. The results show that for 7% weighted average cost of capital Onsite BLEL can be generated at less than 119 54 41 and 33 €/MWhel in 2020 2030 2040 and 2050 respectively across the best sites with a maximum 20000 TWh annual cumulative generation potential. Up to 20000 TWhH2HHV Onsite BLH2 can be produced at less than 66 48 40 and 35 €/MWhH2HHV in 2020 2030 2040 and 2050 respectively. A partially flexible electricity demand at 8000 FLh could significantly reduce the costs of electricity supply in the studied scenario. Along with battery storage power-to-hydrogen-to-power is found to have a major role in supply of BLEL beyond 2030 as both a daily and seasonal balancing solution. Batteries are not expected to have a significant role in the provision of electricity to water electrolysers.

The key direction of political actions in the field of sustainable development of the energy sector and economy is the process of energy transformation (decarbonization) and increasing the share of renewable energy sources (RES) in the supply of primary energy. Regardless of the indisputable advantages RES are referred to as unstable energy sources. A possible solution might be the development of the concept of hydrogen supply chains especially the so-called green hydrogen obtained in the process of electrolysis from electricity produced from RES. The aim of the research undertaken in the article is to identify the scope of research carried out in the area of hydrogen supply chains and to link this research with the issues of the operation of electricity distribution networks powered by RES. As a result of the scoping review and the application of the text-mining method using the IRaMuTeQ tool which includes the analysis of the content of 12 review articles presenting the current research achievements in this field over the last three years (2016–2020) it was established that the issues related to hydrogen supply chains including green hydrogen are still not significantly associated with the problem of the operation of power grids. The results of the conducted research allow formulating recommendations for further research areas.

The Paris Agreement has set the goal of carbon neutrality to cope with global climate change. China has pledged to achieve carbon neutrality by 2060 which will strategically change everything in our society. As the main source of carbon emissions the consumption of fossil energy is the most profoundly affected by carbon neutrality. This work presents an analysis of how China can achieve its goal of carbon neutrality based on its status of fossil energy utilization. The significance of transforming fossils from energy to resource utilization in the future is addressed while the development direction and key technologies are discussed.

Power-to-gas is a key area of interest for decarbonisation and increasing flexibility in energy systems as it has the potential both to absorb renewable electricity at times of excess supply and to provide backup energy at times of excess demand. By integrating power-to-gas with the natural gas grid it is possible to exploit the inherent linepack flexibility of the grid and shift some electricity variability onto the gas grid. Furthermore provided the gas injected into the gas grid is low-carbon such as hydrogen from renewable power-to-gas then overall greenhouse gas emissions from the gas grid can be reduced.<br/>This work presents the first review of power-to-gas to consider real-life projects economic assessments and systems modelling studies and to compare them based on scope assumptions and outcomes. The review focuses on power-to-gas for injection into the gas grid as this application has specific economic technical and modelling opportunities and challenges.<br/>The review identified significant interest in and potential for power-to-gas in combination with the gas grid however there are still challenges to overcome to find profitable business cases and manage local and system-wide technical issues. Whilst significant modelling of power-to-gas has been undertaken more is needed to fully understand the impacts of power-to-gas and gas grid injection on the operational behaviour of the gas grid taking into account dynamic and spatial effects.

Hydrogen production from surplus solar electricity as energy storage for export purposes can push towards large-scale application of solar energy in the United Arab Emirates and the Middle East region; this region’s properties of high solar irradiance and vast empty lands provide a good fit for solar technologies such as concentrated solar power and photovoltaics. However a thorough comparison between the two solar technologies as well as investigating the infrastructure of the United Arab Emirates for a well-to-ship hydrogen pathway is yet to be fully carried out. Therefore in this study we aim to provide a full model for solar hydrogen production and delivery by evaluating the potential of concentrated solar power and photovoltaics in the UAE then comparing two different pathways for hydrogen delivery based on the location of hydrogen production sites. A Solid Oxide Cell Electrolyzer (SOEC) is used for technical comparison while the shortest routes for hydrogen transport were analyzed using Geographical Information System (GIS). The results show that CSP technology coupled with SOEC is the most favorable pathway for large-scale hydrogen from solar energy production in the UAE for export purposes. Although PV has a slightly higher electricity potential compared to CSP around 42 GWh/km2 to 41.1 GWh/km2 respectively CSP show the highest productions rates of over 6 megatons of hydrogen when the electrolyzer is placed at the same site as the CSP plant while PV generates 5.15 megatons when hydrogen is produced at the same site with PV plants; meanwhile hydrogen from PV and CSP shows similar levels of 4.8 and 4.6 megatons of hydrogen respectively when electrolyzers are placed at port sites. Even considering the constraints in the UAE’s infrastructure and suggesting new shorter electrical transmission lines that could save up to 0.1 megatons of hydrogen in the second pathway production at the same site with CSP is still the most advantageous scenario.

Hydrogen (H2) as a cleaner fuel has been suggested as a viable method of achieving the decarbonization objectives and meeting increasing global energy demand. However successful implementation of a full-scale hydrogen economy requires large-scale hydrogen storage (as hydrogen is highly compressible). A potential solution to this challenge is injecting hydrogen into geologic formations from where it can be withdrawn again at later stages for utilization purposes. The geostorage capacity of a porous formation is a function of its wetting characteristics which strongly influence residual saturations fluid flow rate of injection rate of withdrawal and containment security. However literature severely lacks information on hydrogen wettability in realistic geological and caprock formations which contain organic matter (due to the prevailing reducing atmosphere). We therefore measured advancing (θa) and receding (θr) contact angles of mica substrates at various representative thermo-physical conditions (pressures 0.1-25 MPa temperatures 308–343 K and stearic acid concentrations of 10−9 - 10−2 mol/L). The mica exhibited an increasing tendency to become weakly water-wet at higher temperatures lower pressures and very low stearic acid concentration. However it turned intermediate-wet at higher pressures lower temperatures and increasing stearic acid concentrations. The study suggests that the structural H2 trapping capacities in geological formations and sealing potentials of caprock highly depend on the specific thermo-physical condition. Thus this novel data provides a significant advancement in literature and will aid in the implementation of hydrogen geo-storage at an industrial scale.

Membrane reactors for hydrogen production can increase both the hydrogen production efficiency at small scale and the electric efficiency in micro-cogeneration systems when coupled with Polymeric Electrolyte Membrane fuel cells. This paper discusses the achievements of three European projects (FERRET FluidCELL BIONICO) which investigate the application of the membrane reactor concept to hydrogen production and micro-cogeneration systems using both natural gas and biofuels (biogas and bio-ethanol) as feedstock. The membranes used to selectively separate hydrogen from the other reaction products (CH4 CO2 H2O etc.) are of asymmetric type with a thin layer of Pd alloy (<5 μm) and supported on a ceramic porous material to increase their mechanical stability. In FERRET the flexibility of the membrane reactor under diverse natural gas quality is validated. The reactor is integrated in a micro-CHP system and achieves a net electric efficiency of about 42% (8% points higher than the reference case). In FluidCELL the use of bio-ethanol as feedstock for micro-cogeneration Polymeric Electrolyte Membrane based system is investigated in off-grid applications and a net electric efficiency around 40% is obtained (6% higher than the reference case). Finally BIONICO investigates the hydrogen production from biogas. While BIONICO has just started FERRET and FluidCELL are in their third year and the two prototypes are close to be tested confirming the potentiality of membrane reactor technology at small scale.

The establishment of a strong hydrogen economy nationally and locally is a very real opportunity and one that is rapidly becoming within reach.<br/>This report presents a vision for the role that hydrogen could play specifically in South Yorkshire (UK) to help meet carbon reduction targets and contribute to the health and economic prosperity of the region.<br/>It also highlights five themes as levers of growth and explores potential actions and collaborations as well as a list of ambitions for future hydrogen projects. Hydrogen can be used in transport industry and heating. Synergies need exploring for example the by-product of oxygen from hydrogen production can be used by industry. Aggregating opportunities is important in developing a hydrogen economy.<br/>The report concludes with a call to action to build momentum for the South Yorkshire hydrogen economy and accelerate the drive to net zero emissions particularly in the most challenging sectors.<br/>This South Yorkshire specific report supports our global thought piece Establishing a Hydrogen Economy: The future of energy 2035