Publications

Due to the high cost of hydrogen utilization and the uncertainties in renewable energy generation and load demand significant challenges are posed for the operation optimization of hydrogen-containing integrated energy systems (IESs). In this study a robust operational model for an electric–heat–gas IES (EHG-IES) is proposed considering the hydrogen energy system heat recovery (HESHR) and multiple uncertainties. Firstly a heat recovery model for the hydrogen system is established based on thermodynamic equations and reaction principles; secondly through the constructed adjustable robust optimization (ARO) model the optimal solution of the system under the worst-case scenario is obtained; lastly the original problem is decomposed based on the column and constraint generation method and strong duality theory resulting in the formulation of a master problem and subproblem with mixed-integer linear characteristics. These problems are solved through alternating iterations ultimately obtaining the corresponding optimal scheduling scheme. The simulation results demonstrate that our model and method can effectively reduce the operation and maintenance costs of HESHR-EHG-IES while being resilient to uncertainties on both the supply and demand sides. In summary this study provides a novel approach for the diversified utilization and flexible operation of energy in HESHR-EHG-IES contributing to the safe controllable and economically efficient development of the energy market. It holds significant value for engineering practice.

This review article provides a comprehensive overview of the pivotal role that nanomaterials particularly graphene and its derivatives play in advancing hydrogen energy technologies with a focus on storage production and transport. As the quest for sustainable energy solutions intensifies the use of nanoscale materials to store hydrogen in solid form emerges as a promising strategy toward mitigate challenges related to traditional storage methods. We begin by summarizing standard methods for producing modified graphene derivatives at the nanoscale and their impact on structural characteristics and properties. The article highlights recent advancements in hydrogen storage capacities achieved through innovative nanocomposite architectures for example multi-level porous graphene structures containing embedded nickel particles at nanoscale dimensions. The discussion covers the distinctive characteristics of these nanomaterials particularly their expansive surface area and the hydrogen spillover effect which enhance their effectiveness in energy storage applications including supercapacitors and batteries. In addition to storage capabilities this review explores the role of nanomaterials as efficient catalysts in the hydrogen evolution reaction (HER) emphasizing the potential of metal oxides and other composites to boost hydrogen production. The integration of nanomaterials in hydrogen transport systems is also examined showcasing innovations that enhance safety and efficiency. As we move toward a hydrogen economy the review underscores the urgent need for continued research aimed at optimizing existing materials and developing novel nanostructured systems. Addressing the primary challenges and potential future directions this article aims to serve as a roadmap to enable scientists and industry experts to maximize the capabilities of nanomaterials for transforming hydrogen-based energy systems thus contributing significantly to global sustainability efforts.

Renewable Energy Sources (RESs) are characterized by high unevenness cyclicality and seasonality of energy production. Due to the trends in the production of electricity itself and the utilization of hydrogen distributed generation systems are preferred. They can be connected to the energy distribution network or operate without its participation (off-grid). However in both cases such distributed energy sources should be balanced in terms of power generation. According to the authors it is worth combining different RESs to ensure the stability of energy production from such a mix. Within the mix the sources can complement and replace each other. According to the authors an effective system for generating energy from RESs should contain at least two different sources and energy storage. The purpose of the analyses and calculations performed is to determine the characteristics of energy generation from a photovoltaic system and a wind turbine with a specific power and geographical location in the Lublin region in Poland. Another important goal is to determine the substitutability of the sources studied. Probabilistic analysis will be used to determine the share of given energy sources in the energy mix and will allow us to estimate the size of the stationary energy storage. The objective of these procedures is to strive for the highest possible share of renewable energy in the total energy required to charge electric vehicle fleets and to produce low-emission hydrogen for transportation. The article proves that the appropriately selected components of the photovoltaic and wind energy mix located in the right place lead to the self-balancing of the local energy network using a small energy storage. The conclusions drawn from the conducted research can be used by RES developers who intend to invest in new sources of power generation to produce low-emission hydrogen. This is in line with the current policy of the European Union aimed at climate and energy transformation of many companies using green hydrogen.

Due to concerns regarding fossil greenhouse gas emissions biogenic material such as forest residues is viewed nowadays as a valuable source of carbon atoms to produce syngas that can be used to synthesise biofuels such as methanol. A great challenge in using gasified biomass for methanol production is the large excess of carbon in the syngas as compared to the H2 content. The water–gas shift (WGS) reaction is often used to add H2 and balance the syngas. CO2 is also produced by this reaction. Some of the CO2 has to be removed from the gaseous mixture thus decreasing the process carbon yield and maintaining CO2 emissions. The WGS reaction also decreases the overall process heat output. This paper demonstrates the usefulness of using an extra source of renewable H2 from steam electrolysis instead of relying on the WGS reaction for a much higher performance of syngas production from gasification of wood in a simple system with a fixed-bed gasifier. A commercial process simulation software is employed to predict that this approach will be more efficient (overall energy efficiency of about 67%) and productive (carbon conversion yield of about 75%) than relying on the WGS reaction. The outlook for this process that includes the use of the solid oxide electrolyser technology appears to be very promising because the electrolyser has the dual function of providing all of the supplemental H2 required for syngas balancing and all the O2 required for the production of a suitable hot raw syngas. This process is conducive to biomethanol production in dispersed small plants using local biomass for end-users from the same geographical area thus contributing to regional sustainability.

The adoption of low-carbon fuels in maritime propulsion requires operational autonomy material suitability and compliance with safety standards making liquid fuels like LNG and LH2 the most viable options. LNG is widely used for reducing GHG NOx and SOx emissions while LH2 though new to the maritime sector leverages aerospace experience. This paper explores the operational requirements and challenges of LH2 cryogenic handling systems using LNG practices as a reference. Key comparisons are made between LNG and LH2 supply systems focusing on cryogenic materials hydrogen embrittlement and structural integrity under maritime conditions. Most maritime-approved materials are suitable for cryogenic use and hydrogen embrittlement is less critical at cryogenic temperatures due to reduced atomic mobility. Risk assessments suggest LH2’s safety record stems from limited operational data rather than superior inherent safety. The paper also addresses crucial safety and regulatory considerations for both fuels underscoring the need for strict adherence to standards to ensure the safe and compliant integration of LH2 in the maritime industry.

Chemical hydrogen storage is a key step for establishing hydrogen as a main energy vector. For this purpose liquid organic hydrogen carriers (LOHCs) present the outstanding advantage of allowing a safe efficient and high-density hydrogen storage being also highly compatible with existing transport infrastructures. Typical LOHCs are organic compounds able to be hydrogenated and dehydrogenated at mild conditions enabling the hydrogen storage and release respectively. In addition the physical properties of these chemicals are also critical for practical implementation. In this work key properties of potential LOHCs of three different chemical families (homoaromatics and Nand O-heteroaromatics) are estimated using molecular simulations. Thus density viscosity vapour pressure octanol-water coefficient melting point flash point dehydrogenation enthalpy and hydrogen content are estimated using the programs COSMO-RS and HYSYS. In addition we have also evaluated the performance of several binary mixtures as LOHCs using these methodologies. Considering the hydrogen content characteristic temperatures and previous experimental results of the cyclic process; our simulation results suggest that 1-methylnaphthalene/1-methyldecahydronaftalene and methylbenzylpyridine/perhydromethylbenzylpyridine pairs are appropriate candidates for chemical hydrogen storage. Binary mixtures of LOHCs are also relevant alternatives since substances with a great potential can be used as LOHCS when dissolved. That is the case of naphthalene and 1-methyl-naphthalene mixtures or indoles dissolved in benzene or benzylbenzene. Concerning O-compounds although several pairs could be used as LOHCs thermodynamic and kinetic feasibility of the hydrogenation/dehydrogenation cycles must be better studied.

This paper proposes a novel dual-fuel dual-mode dual-thermodynamic cycle aviation propulsion system for the first time and conducts theoretical research on it based on a moderately simplified mathematical model. It is specifically designed to significantly reduce carbon emissions for wide-body aircraft. A comprehensive thermodynamic model is developed for this hybrid power system which integrates a high-temperature proton exchange membrane fuel cell with a dual-rotor turbofan engine. The matching characteristics between aircraft and engine performance are analyzed by systematically varying the fuselage length of the dual-fuel aircraft configuration. Results show that the specific fuel consumption of the proposed engine is decreased by 12.6% compared with that of the traditional turbofan engine as the Mach number increases. Conversely as the relative physical rotational speed decreases the thrust of the novel engine is increased by 10%. With a 20 % extension in fuselage length the dual-fuel aircraft operating on 100 % hydrogen fuel can achieve an endurance exceeding 17 h representing a 20 % endurance improvement over conventional aviation kerosene-powered aircraft. In this case the aircraft weight can be reduced by 96.79 tons and CO2 emissions can be decreased by 301.65 tons.

This paper presents the results of the H2SAREA project which focuses on integrating hydrogen (H2) into the existing natural gas (NG) distribution network with blends of up to 20%. A key component of the project was the H2Loop testing platform built using ex-service materials and components to realistically assess the impact of hydrogen on current systems and components. The investigation covered several critical areas including gas injection and blending network capacity leak detection gas pressure regulation station (GPRS) performance valve and meter functionality materials compatibility permeation testing and gas deblending. Results show the feasibility of safely injecting up to 20% hydrogen into the existing system offering valuable insights to guide the transition of gas distribution networks toward a hydrogen-based energy future.

In the coming years as a result of changing climate policies and finite fossil fuel resources energy producers will be compelled to introduce new fuels with lower carbon footprints. One of the solutions is hydrogen which can be burned or co-fired with methane in energy generation systems. Therefore this study presents a thermodynamic and emission analysis of a gas turbine fueled by a mixture of CH4 and H2 as well as pure hydrogen. Numerical studies were conducted for the actual operating parameters of the LM6000 gas turbine in both simple and combined cycles. Aspen Hysys and Chemkin-Pro 2023R1 commercial software were used for the calculations. It was demonstrated that with a constant turbine inlet temperature set at 1723 K the thermal efficiency increased from 39.4% to 40.2% for the gas turbine cycle and from 49% to 49.4% for the combined cycle gas turbine. Nitrogen oxides emissions were calculated using the reactor network revealing that an increase in H2 content above 20%vol. in the fuel leads to a significant rise in nitric oxides emissions. In the case of pure H2 emissions are more than three times higher than for CH4 . The main reason for this increase in emissions was identified as the greater presence of H O and OH radicals in the reaction zone causing an acceleration in the formation of nitric oxides.

Reducing greenhouse gas emissions in the transport sector is known to be an important contribution to climate change mitigation. Some parts of the transport sector are particularly difficult to decarbonize; this includes the heavy-duty vehicle sector which is considered one of the “hardto-abate” sectors of the economy. Transitioning from diesel trucks to hydrogen fuel cell trucks has been identified as a potential way to decarbonize the sector. However the current and future costs and efficiencies of the enabling technologies remain unclear. In light of these uncertainties this paper investigates the investments required to decarbonize New Zealand’s heavy-duty vehicle sector with green hydrogen. By combining system dynamics modelling literature and hydrogen transition modelling literature a customized methodology is developed for modelling hydrogen transitions with system dynamics modelling. Results are presented in terms of the investments required to purchase the hydrogen production capacity and the investments required to supply electricity to the hydrogen production systems. Production capacity investments are found to range between 1.59 and 2.58 billion New Zealand Dollars and marginal electricity investments are found to range between 4.14 and 7.65 billion New Zealand Dollars. These investments represent scenarios in which 71% to 90% of the heavy-duty vehicle fleet are replaced with fuel cell trucks by 2050. The wide range of these findings reflects the large uncertainties in estimates of how hydrogen technologies will develop over the course of the next thirty years. Policy recommendations are drawn from these results and a clear opportunity for future work is outlined. Most notably the results from this study should be compared with research investigating the investments required to decarbonize the heavy-duty vehicle sectors with alternative technologies such as battery-electric trucks biodiesel and catenary systems. Such a comparison would ensure that the most cost effective decarbonization strategy is employed.

Hydrogen energy is considered a crucial clean energy carrier for replacing fossil fuels in the future. Liquid hydrogen (LH2) with its economic advantages and high purity is central to the development of future hydrogen refueling stations (HRSs). However leakage poses significant fire and explosion risks challenging its safe industrial use. In this study a numerical model of LH2 leakage at an HRS in Chongqing was established using Computational Fluid Dynamics (CFD) software. The diffusion law of a flammable gas cloud (FGC) was examined under the synergistic effect of the leakage direction rate and wind speed of an LH2 storage tank in an HRS. The phase transition of LH2 presents dual risks of combustion and frostbite owing to the spatial overlap between low-temperature areas and FGCs. The findings revealed that the equivalent stoichiometric gas cloud volume (Q9) reached 685 m3 in the case of crosswind leakage with the superimposed effect of reflected waves from the LH2 transport vehicle resulting in a peak explosion overpressure of 0.61 bar. The low-temperature hazard area and the FGC (with a concentration of 30–75%) show significant spatial overlap. These research outcomes offer crucial theoretical underpinning for enhancing equipment layout optimization and safety protection strategies at HRSs.

One of the biggest global challenges we are facing today is the provision of affordable green and sustainable energy to a growing population. Enshrined in multiple United Nation Sustainable Development Goals – Goal 7: Affordable and Clean Energy; Goal 11: Sustainable Cities and Communities; Goal 12: Responsible Consumption and Production and Goal 13: Climate Action – as well as at the core of the Paris Agreement it is our task as scientists and engineers to develop innovative technologies that satisfy society’s needs while pivoting away from the use of fossil resources. This is a mammoth task with an ambitious timeline. The global development of the industrial sector as we know it is solely based on the exploitation of energy-rich fossil fuels that remain cost-competitive today. However a gradual change from a market driven to a policy-driven transition allows alternative technologies to make inroads and find applications. One of the most prominently discussed approaches is the Power-to-X (PtX) process envelope. It describes a series of catalytic conversions using only renewable energy water and captured CO2 to produce green hydrogen liquid hydrocarbon fuels and chemicals. Especially for sectors that are difficult or impossible to decarbonise such processes that effectively defossilising the production of energy and goods represent an important solution. The Catalysis Institute at the University of Cape Town (herein/after referred to as the Catalysis Institute) builds on decades of experience in the individual catalytic processes combined in the PtX concept. In collaboration with our global partners we are therefore able to develop technologies for the full value chain considering interdependencies and develop solutions for the African and indeed global society.

During the development of hydrogen fuel cell systems with the augmentation of power conventional air-cooling systems which are frequently employed in portable scenarios encounter difficulties in maintaining the balance between radiator heat dissipation and power consumption. In contrast liquid-cooling systems are widely adopted in high-power applications. In this regard aiming to address the heat dissipation problem and make use of the wastewater from the stack tailpipe a novel spray cooling system integrated with the traditional air-cooling for the radiator of hydrogen fuel cell systems is put forward. Through experimental investigations based on heat transfer theory and the design principles of fuel cell systems it is discovered that under specific nozzle apertures and spray water pressures the heat dissipation rate can be enhanced by 40 % and 30 % respectively. With particular radiator internal water flow rates and fan speeds the heat dissipation rate can be increased by 30 % and 108 % respectively. And the spray angle of 60 ◦ is the best angle. In contrast to the conventional air-cooling system the spray-air cooling system exhibits a heat dissipation rate that is approximately 50 % higher. Exper imental analyses demonstrate that the new system effectively harnesses water resources and enhances the heat dissipation performance of the radiator thereby providing a technical reference for the application of spray cooling in the radiators of hydrogen fuel cell systems.

The iron and steel industry contributes approximately 25% of global industrial CO2 emissions necessitating substantial decarbonisation efforts. Hydrogen-based iron and steel plants (HISPs) which utilise hydrogen-based direct reduction of iron ore followed by electric arc furnace steelmaking have attracted substantial research interest. However commercialisation of HISPs faces economic feasibility issues due to the high electricity costs of hydrogen production. To improve economic feasibility HISPs are jointly powered by local renewable generators and bulk power grid i.e. by a grid-assisted renewable energy system. Given the variability of renewable energy generation and time-dependent electricity prices flexible scheduling of HISP production tasks is essential to reduce electricity costs. However cost-effectively scheduling of HISP production tasks is non-trivial as it is subject to critical operational constraints arising from the tight coupling and distinct operational characteristics of HISPs sub-processes. To address the above issues this paper proposes an integrated resource-task network (RTN) to elaborately model the critical operational constraints such as resource balance task execution and transfer time. More specifically each sub-process is first modelled as an individual RTN which is then seamlessly integrated through boundary dependency constraints. By embedding the formulated operational constraints into optimisation a cost-effective scheduling model is developed for HISPs powered by the grid-assisted renewable energy system. Numerical results demonstrate that compared to conventional scheduling approaches the proposed method significantly reduces total operational costs across various production scales.

This study introduces an innovative nuclear-biomass integrated energy and cleaner production multigeneration system incorporating sonohydrogen technology and a desalination unit for the sustainable and efficient production of hydrogen electricity hot water and heat. A small modular nuclear reactor acts as the primary energy source ensuring stable and low-carbon power generation while enhancing hydrogen yield through sonochemical processes. Biomass-derived biogas is strategically utilized for both electricity generation and hydrogen production via steam methane reforming. The heat wasted in the system is efficiently utilized. A high-performance multistage flash desalination unit converts some of the waste heat into desalinated seawater. In addition a portion of the waste heat is utilized for heat production. The results of this study show that the overall energy and exergy efficiencies of the integrated system are 82.7 % and 68.3 % respectively. Through detailed energy and exergy assessments the study demonstrates the feasibility of the proposed system in enhancing energy conversion efficiency improving waste heat utilization and increasing sustainability. In addition the results of the cost assessment show that the integrated energy system is economically viable in the long term with hydrogen production driving substantial annual revenue and profitability projected within the first decade of operation. The findings highlight the system’s potential to contribute to cleaner energy production by reducing greenhouse gas emissions maximizing resource efficiency and advancing hydrogen and freshwater production technologies.

This study examines the steps to lower air emissions in South Korea’s domestic shipping sector. It highlights the significant contributions of the sector to air pollution and greenhouse gas emissions emphasizing its impact on environmental sustainability and climate change mitigation. By looking at the current shipping energy use and emissions the research identifies ways to reduce the environmental impact of domestic shipping. Data was collected from domestic ferry routes and the fuel use was reviewed with respect to existing global technologies for reducing emissions. The results show that operational changes and current energy-efficient technologies can quickly cut emissions. Furthermore a long-term plan is suggested involving the development of new ship designs and the use of net-zero fuels like biofuels methanol hydrogen and ammonia. These efforts aim to meet climate goals targeting a 40% reduction in greenhouse emissions by 2030 and a 70% reduction by 2050 making South Korea’s shipping industry more sustainable and resilient.

Green hydrogen produced via renewable-powered electrolysis offers a promising path toward deep decarbonisation in energy systems. This study investigates the major technological infrastructural and economic challenges facing green hydrogen production in Jordan—a resource-constrained yet renewable-rich country. Key barriers were identified through a structured survey of 52 national stakeholders including water scarcity low electrolysis efficiency limited grid compatibility and underdeveloped transport infrastructure. Respondents emphasised that overcoming these challenges requires investment in smart grid technologies seawater desalination advanced electrolysers and policy instruments such as subsidies and public–private partnerships. These findings are consistent with global assessments which recognise similar structural and financial obstacles in scaling up green hydrogen across emerging economies. Despite the constraints over 50% of surveyed stakeholders expressed optimism about Jordan’s potential to develop a competitive green hydrogen sector especially for industrial and power generation uses. This paper provides empirical context-specific insights into the conditions required to scale green hydrogen in developing economies. It proposes an integrated roadmap focusing on infrastructure modernisation targeted financial mechanisms and enabling policy frameworks.

We analyze barriers to setting up a hydrogen market by using a PESTEL framework that examines political economic social technological environmental and legal barriers. This framework is advantageous for analyzing macro-environmental factors to understand potential challenges and opportunities in creating such a market. Internationally the framework was applied to analyzing barriers in 56 national hydrogen roadmaps and domestically in the U.S. to semi-structured interviews with 43 stakeholders involved with hydrogen projects across the U.S. today. In the country-level international analysis infrastructure development was the most identified barrier with 43 countries including this factor. Infrastructure development included infrastructure for hydrogen storage transportation and distribution and frequently alluded not only to the need for the infra structure but also the costs associated. The second most identified barrier was related to the need for market development - including but not limited to capital costs economic competition supply and demand matching and first-mover reticence. For the domestic analysis results from qualitative content analysis confirmed considerable variability across regions and stakeholder backgrounds. Particularly notable were divergent views about the importance of public understanding of and support for hydrogen projects with industry respondents arguing this was not important and government and academic respondents considering it very important. The barriers seen as having the largest impact on deployment of hydrogen projects was a lack of regulatory clarity and lack of decision makers’ knowledge and awareness. Domestically the most often introduced barriers were the need for the support of market demand and the need to develop a hydrogen workforce.

Among the new energy carriers aimed at reducing greenhouse gas emissions the use of hydrogen is expected to grow significantly in various applications and sectors (i.e. industrial commercial transportation etc.) due to its high energy content by weight and zero carbon emissions. The increasingly widespread use of hydrogen will require massive distribution from production sites to final consumers and the delivery by means of liquid hydrogen road tankers may be a suitable cost-effective option for market penetration in the short-medium term. Liquid hydrogen (LH2) presents different hazards compared to gaseous hydrogen and an accidental release in confined spaces such as road tunnels might lead to the formation of a flammable hydrogen cloud that might deflagrate or even detonate. Nevertheless the potential negative effects on users in the event of accidental leakage of liquid hydrogen from a tanker in road tunnels so far have not been sufficiently investigated. Therefore a 3D Computational Fluid Dynamics model for the release of LH2 and its dispersion within a road tunnel was developed in this study. The proposed model was validated by a comparison with certain experimental and numerical studies found in the literature. Such modeling is demanding for long tunnels. Therefore the results of the simulations (e.g. the amount of hydrogen contained within the cloud) were combined with established simplified consequence methods to estimate the overpressures generated from a potential hydrogen deflagration. This was then used to evaluate the effects on users while evacuating from the tunnel. The findings showed that the worst scenario is when the release is in the middle of the tunnel length and the ignition occurs 90 s after the leakage.

The flammable hydrogen-blended methane–air and natural gas–air mixtures raise specific safety and environmental issues in the industry and transportation; therefore their explosion characteristics such as the explosion limits explosion pressures and rates of pressure rise have significant importance from a safety point of view. At the same time the laminar burning velocities are the most useful parameters for practical applications and in basic studies for the validation of reaction mechanisms and modeling turbulent combustion. In the present study an experimental and numerical study of the effect of hydrogen addition on the laminar burning velocity (LBV) of methane–air and natural gas–air mixtures was conducted using mixtures with equivalence ratios within 0.90 and 1.30 and various hydrogen fractions rH within 0.0 and 0.5. The experiments were performed in a 14 L spherical vessel with central ignition at ambient initial conditions. The LBVs were calculated from p(t) data determined in accordance with EN 15967 by using only the early stage of flame propagation. The results show that hydrogen addition determines an increase in LBV for all examined binary flammable mixtures. The LBV variation versus the fraction of added hydrogen rH follows a linear trend only at moderate hydrogen fractions. The further increase in rH results in a stronger variation in LBV as shown by both experimental and computed LBVs. Hydrogen addition significantly changes the thermal diffusivity of flammable CH4–air or NG–air mixtures the rate of heat release and the concentration of active radical species in the flame front and contribute thus to LBV variation.

The road-transport is one of the major contributors to greenhouse global gas (GHG) emissions where hydrogen (H2) combustion engines can play a crucial role in the path towards the sector’s decarbonization goal. This study focuses on comparing the performance and emissions of port-fuel injection (PFI) and direct injection (DI) in a spark ignited combustion engine when is fuelled by hydrogen and other noteworthy fuels like methane and coke oven gas (COG). Computational fluid dynamic simulations are performed at optimal spark advance and air-fuel ratio (λ) for engine speeds between 2000 and 5000 rpm. Analysis reveals that brake power increases by 40% for DI attributed to 30.6% enhanced volumetric efficiency while the sNOx are reduced by 36% compared to PFI at optimal λ = 1.5 for hydrogen. Additionally H2 results in 71.8% and 67.2% reduction in fuel consumption compared to methane and COG respectively since the H2 lower heating value per unit of mass is higher.

The commercialization of hydrogen as a fuel faces severe technological economic and environmental challenges. As a method to overcome these challenges microalgal biohydrogen production has become the subject of growing research interest. Microalgal biohydrogen can be produced through different metabolic routes the economic considerations of which are largely missing from recent reviews. Thus this review briefly explains the techniques and economics associated with enhancing microalgae-based biohydrogen production. The cost of producing biohydrogen has been estimated to be between $10 GJ-1 and $20 GJ−1 which is not competitive with gasoline ($0.33 GJ−1 ). Even though direct biophotolysis has a sunlight conversion efficiency of over 80% its productivity is sensitive to oxygen and sunlight availability. While the electrochemical processes produce the highest biohydrogen (>90%) fermentation and photobiological processes are more environmentally sustainable. Studies have revealed that the cost of producing biohydrogen is quite high ranging between $2.13 kg−1 and 7.24 kg−1 via direct biophotolysis $1.42kg−1 through indirect biophotolysis and between $7.54 kg−1 and 7.61 kg−1 via fermentation. Therefore low-cost hydrogen production technologies need to be developed to ensure long-term sustainability which requires the optimization of critical experimental parameters microalgal metabolic engineering and genetic modification.

The ability for existing burners to operate safely and efficiently on hydrogen-blended fuels is a primary concern for the many industries looking to adopt hydrogen as an alternative fuel. This study investigates the efficacy of increasing fuel injector diameter as a simple modification strategy to extend the hydrogen-blending limits before flashback. The collateral effects of this modification are quantified with respect to a set of key performance criteria. The results show that the unmodified burner can sustain up to 50 vol% hydrogen addition before flashback. Increasing the fuel injector diameter reduces primary aeration allowing for stable operation on up to 100% hydrogen. The flame length visibility and radiant heat transfer properties are all increased as a result of the reduced air entrainment with a trade-off reported for NOx emissions where in addition to the effects of hydrogen reducing air entrainment further increases NOx emissions.

The agro-livestock sector produces about one third of global greenhouse gas (GHG) emissions. Since more energy is needed to meet the growing demand for food and the industrial revolution in agriculture renewable energy sources could improve access to energy resources and energy security reduce dependence on fossil fuels and reduce GHG emissions. Hydrogen production is a promising energy technology but its deployment in the global energy system is lagging. Here we analyzed the theoretical and practical application of green hydrogen generated by electrolysis of water powered by renewable energy sources in the agro-livestock sector. Green hydrogen is at an early stage of development in most applications and barriers to its large-scale deployment remain. Appropriate policies and financial incentives could make it a profitable technology for the future.

The growing need for hydrogen indicates that there is likely to be a demand for transporting hydrogen. Hydrogen pipelines are an economical option but the issue of hydrogen damage to pipeline steels needs to be studied and investigated. So far limited research has been dedicated to determining how the choice of inspection method for pipeline integrity management changes depending on the presence of a coating. Thus this review aims to evaluate the effectiveness of inspection methods specifically for detecting the defects formed uniquely in coated hydrogen pipelines. The discussion will begin with a background of hydrogen pipelines and the common defects seen in these pipelines. This will also include topics such as blended hydrogen-natural gas pipelines. After which the focus will shift to pipeline integrity management methods and the effectiveness of current inspection methods in the context of standards such as ASME B31.12 and BS 7910. The discussion will conclude with a summary of newly available inspection methods and future research directions.

The growing use of proton-exchange membrane fuel cells (PEMFCs) in hybrid propulsion systems is aimed at replacing traditional internal combustion engines and reducing greenhouse gas emissions. Effective power distribution between the fuel cell and the energy storage system (ESS) is crucial and has led to a growing emphasis on developing energy management systems (EMSs) to efficiently implement this integration. To address this goal this study examines the performance of a fuzzy logic rule-based strategy for a hybrid fuel cell propulsion system in a small hydrogenpowered passenger vessel. The primary objective is to optimize fuel efficiency with particular attention on reducing hydrogen consumption. The analysis is carried out under typical operating conditions encountered during a river trip. Comparisons between the proposed strategy with other approaches—control based optimization based and deterministic rule based—are conducted to verify the effectiveness of the proposed strategy. Simulation results indicated that the EMS based on fuzzy logic mechanisms was the most successful in reducing fuel consumption. The superior performance of this method stems from its ability to adaptively manage power distribution between the fuel cell and energy storage systems.

Of all the alternatives to hydrocarbon fuels hydrogen offers the greatest long-term potential to radically reduce the many problems inherent in fuel used for transportation. Hydrogen vehicles have zero tailpipe emissions and are very efficient. If the hydrogen is made from renewable sources such as nuclear power or fossil sources with carbon emissions captured and sequestered hydrogen use on a global scale would produce almost zero greenhouse gas emissions and greatly reduce air pollutant emissions. The aim of this work is to realise a traceability chain for hydrogen flow metering in the range typical for fuelling applications in a wide pressure range with pressures up to 875 bar (for Hydrogen Refuelling Station - HRS with Nominal Working Pressure of 700 bar) and temperature changes from −40 °C (pre-cooling) to 85 °C (maximum allowed vehicle tank temperature) in accordance with the worldwide accepted standard SAE J2601. Several HRS have been tested in Europe (France Netherlands and Germany) and the results show a good repeatability for all tests. This demonstrates that the testing equipment works well in real conditions. Depending on the installation configuration some systematic errors have been detected and explained. Errors observed for Configuration 1 stations can be explained by pressure differences at the beginning and end of fueling in the piping between the Coriolis Flow Meter (CFM) and the dispenser: the longer the distance the bigger the errors. For Configuration 2 where this distance is very short the error is negligible.

To address the issues of diverse energy supply demands and power fluctuations in integrated energy systems (IESs) this study takes an IES composed of power-generation units such as wind and photovoltaic units along with various energy-storage systems including electrical thermal and hydrogen storage as the research subject. A collaborative control strategy is proposed for the IES which comprehensively considers the status of diverse energy-storage systems like battery packs thermal tanks and hydrogen tanks. First a mathematical model of the IES is constructed. Then a dual-layer collaborative control strategy is designed considering different operating modes of the IES which includes a multi-energy-storage power allocation control layer based on second-order power-frequency processing and distribution and an adaptive adjustment layer for adjusting powerfrequency coefficients based on adaptive fuzzy control. Finally MATLAB is used to simulate and validate the proposed strategy. The results indicate that the collaborative control strategy based on variable-frequency coefficients optimizes the allocation of fluctuating power among multiple energy-storage systems enhances the stability of bus voltage reduces the deep charge and discharge time of battery packs and extends the service life of battery packs.

The influence of mobility modes within Positive Energy Districts (PEDs) has gained limited attention despite their crucial role in reducing energy consumption and greenhouse gas emissions. Buildings in the European Union (EU) account for 40% of energy consumption and 36% of greenhouse gas emissions. In comparison transport contributes 28% of energy use and 25% of emissions with road transport responsible for 72% of these emissions. This study aims to design and optimize a synthetic PED in Istanbul that integrates renewable energy sources and public mobility systems to address these challenges. The renewable energy sources integrated into the synthetic PED model include solar energy hydrogen energy and regenerative braking energy from a tram system. Solar panels provided a substantial portion of the energy while hydrogen energy contributed to additional electricity generation. Regenerative braking energy from the tram system was also utilized to further optimize energy production within the district. This system powers a middle school 10 houses a supermarket and the tram itself. Optimization techniques including Linear Programming (LP) for economic purposes and the Weighted Sum Method (WSM) for environmental goals were applied to balance cost and CO2 emissions. The LP method identified that the PED model can achieve cost competitiveness with conventional energy grids when hydrogen costs are below $93.16/MWh. Meanwhile the WSM approach demonstrated that achieving a minimal CO2 emission level of 5.74 tons requires hydrogen costs to be $32.55/MWh or lower. Compared to a conventional grid producing 97 tons of CO2 annually the PED model achieved reductions of up to 91.26 tons. This study contributes to the ongoing discourse on sustainable urban energy systems by addressing key research gaps related to the integration of mobility modes within PEDs and offering insights into the optimization of renewable energy sources for reducing emissions and energy consumption.

This study investigated the pressure-dependent CO2 effect on the hydrogen embrittlement of X80 and GB20# pipeline steels by combining experiments and first-principles calculations. Results revealed that the CO2 effect enhanced the fatigue crack growth for GB20# steel in 10 MPa CO₂-enriched hydrogen mixtures. However the improved degree by the CO₂ effect at 10 MPa was less pronounced than at 0.4 MPa which was found for the first time. This was attributed to the decreased adsorption rate of CO₂ on iron as hydrogen pressure increased. Therefore in high-pressure CO₂-enriched hydrogen mixtures CO2 could not significantly accelerate the inherent rapid hydrogen uptake at high pressure.

The adoption of liquid hydrogen (LH2) holds promise for decarbonising long-range aviation. LH2 aircraft could weigh less than Jet-A aircraft thereby reducing the thrust requirement. However the lower volumetric energy density of LH2 can adversely impact the aerodynamic performance and energy consumption of tube-wing aircraft. In a first this work conducts an energy performance modelling of a futuristic (2030+) LH2 blendedwing-body (BWB) aircraft (301 passengers and 13890 km) using conceptual aircraft design-optimisation approach employing weight-sizing methods while considering the realistic gravimetric and volumetric energy density effects of LH2 on aircraft design and the resulting reduction in aircraft thrust requirement. This study shows that at the design point the futuristic LH2 BWB aircraft reduces the specific energy consumption (SEC MJ/ tonne-km) by 51.7–53.5% and 7.3–10.8% compared to (Jet-A) Boeing 777-200LR and Jet-A BWB respectively. At the off-design points this study shows that by increasing the load factor for a given range and/or increasing range for all load factor cases the SEC (or energy efficiency) of this LH2 BWB concept improves. The results of this work will inform future studies on use-phase emissions and contrails modelling LH2 aircraft operations for contrail reduction estimation of operating costs and lifecycle climate impacts.

In the vehicle-to-everything scenario the fuel cell bus can accurately obtain the surrounding traffic information and quickly optimize the energy management problem while controlling its own safe and efficient driving. This paper proposes an energy management strategy (EMS) that considers speed control based on deep reinforcement learning (DRL) in complex traffic scenarios. Using SUMO simulation software (Version 1.15.0) a two-lane urban expressway is designed as a traffic scenario and a hydrogen fuel cell bus speed control and energy management system is designed through the soft actor–critic (SAC) algorithm to effectively reduce the equivalent hydrogen consumption and fuel cell output power fluctuation while ensuring the safe efficient and smooth driving of the vehicle. Compared with the SUMO–IDM car-following model the average speed of vehicles is kept the same and the average acceleration and acceleration change value decrease by 10.22% and 11.57% respectively. Compared with deep deterministic policy gradient (DDPG) the average speed is increased by 1.18% and the average acceleration and acceleration change value are decreased by 4.82% and 5.31% respectively. In terms of energy management the hydrogen consumption of SAC–OPT-based energy management strategy reaches 95.52% of that of the DP algorithm and the fluctuation range is reduced by 32.65%. Compared with SAC strategy the fluctuation amplitude is reduced by 15.29% which effectively improves the durability of fuel cells.

While hydrogen is regularly discussed as a possible option for storing regenerative energies its low minimum ignition energy and broad range of explosive concentrations pose safety challenges regarding hydrogen storage and there are also challenges related to hydrogen production and transport and at the point of use. A risk assessment of the whole hydrogen energy system is necessary to develop hydrogen utilization further. Here we concentrate on the most important hydrogen storage technologies especially high-pressure storage liquid hydrogen in cryogenic tanks methanol storage and salt cavern storage. This review aims to study the most recent research results related to these storage techniques by describing typical sensors and explosion protection measures thus allowing for a risk assessment of hydrogen storage through these technologies.

In recent years there has been a significant increase in research on hydrogen due to the urgent need to move away from carbon-intensive energy sources. This transition highlights the critical role of hydrogen storage technology where hydrogen tanks are crucial for achieving cleaner energy solutions. This paper aims to provide a general overview of hydrogen treatment from a mechanical viewpoint and to create a comprehensive review that integrates the concepts of hydrogen safety and storage. This study explores the potential of hydrogen applications as a clean energy alternative and their role in various sectors including industry automotive aerospace and marine fields. The review also discusses design technologies safety measures material improvements social impacts and the regulatory landscape of hydrogen storage tanks and safety technology. This work provides a historical literature review up to 2014 and a systematic literature review from 2014 to the present to fill the gap between hydrogen storage and safety. In particular a fundamental feature of this work is leveraging systematic procedural techniques for performing an unbiased review study to offer a detailed analysis of contemporary advancements. This innovative approach differs significantly from conventional review methods since it involves a replicable scientific and transparent process which culminates in minimizing bias and allows for highlighting the fundamental issues about the topics of interest and the main conclusions of the experts in the field of reference. The systematic approach employed in the paper was used to analyze 55 scientific articles resulting in the identification of six primary categories. The key findings of this review work underline the need for improved materials enhanced safety protocols and robust infrastructure to support hydrogen adoption. More importantly one of the fundamental results of the present review analysis is pinpointing the central role that composite materials will play during the transition toward hydrogen applications based on thin-walled industrial vessels. Future research directions are also proposed in the paper thereby emphasizing the importance of interdisciplinary collaboration to overcome existing challenges and facilitate the safe and efficient use of hydrogen.

Low carbon hydrogen is essential to achieve the Government’s Clean Energy Superpower and Growth Missions. It will be a crucial enabler of a low carbon and renewables-based energy system and will help to deliver new clean energy industries which can support good jobs in our industrial heartlands and coastal communities. Hydrogen presents significant growth and economic opportunities across the UK by enhancing our energy security providing flexible cleaner energy for our power system and helping to decarbonise vital UK industries. Hydrogen has a critical role in helping to achieve our Clean Energy Superpower Mission. It can provide flexible low carbon power generation meaning we can use hydrogen to produce electricity during extended periods of low renewable output. Hydrogen can also provide interseasonal energy storage through conversion of electricity into hydrogen and then back into electricity at times of need using a combination of hydrogen production storage and hydrogen to power. To advance our Clean Energy and Growth Missions hydrogen also has a unique role in transitioning crucial UK industries away from oil and gas and towards a clean homegrown source of fuel. Hydrogen can decarbonise hard-to-abate sectors like chemicals and heavy transport complementing our wider electrification efforts and accelerating our progress to net zero. Using our strong domestic expertise and favourable geology geography and infrastructure backing UK hydrogen can unlock significant economic opportunities and new low carbon jobs of the future. Government has an ambitious range of policies in place to incentivise and support industry to invest in low carbon hydrogen. The recent Hydrogen Skills Workforce Assessment an industry-led study undertaken by the Hydrogen Skills Alliance estimated that the UK hydrogen economy could support 29000 direct jobs and 64500 indirect jobs by 2030. Since establishing in Summer 2024 this Government has already made significant progress in delivering the UK hydrogen economy. This includes confirming support for the 11 successful Hydrogen Allocation Round 1 projects announcing up to £21.7 billion of available funding to launch the UK’s new carbon capture utilisation and storage industry and publishing our hydrogen to power consultation response with an aim to establish a new hydrogen to power business model. We have also launched three new bodies – the National Energy System Operator Great British Energy and the National Wealth Fund – which will help to deliver a world-class energy system including for low carbon hydrogen. This December 2024 Hydrogen Strategy Update to the Market sets out the key milestones achieved by the Department for Energy Security and Net Zero in 2024 to deliver the hydrogen economy and an ambitious forward look at our next steps and upcoming opportunities. To achieve net zero and create a thriving and resilient energy landscape we are already working at considerable pace to deliver a world-leading UK hydrogen sector.

The combustion of hydrogen increases the water content of the combustion products affecting the aerodynamic performance of turbines using hydrogen as a fuel. This study aims to design a radial turbine using the differential evolution (DE) algorithm to improve its characteristics and optimize its aerodynamic performance through an orthogonal experiment and analysis of means (ANOM). The effects of varying water content in combustion products ranging from 12% to 22% on the performance of the radial turbine are also investigated. After optimization the total–static efficiency of the radial turbine increased to 89.12% which was 1.59% higher than the preliminary design. The study found that flow loss in the impeller primarily occurred at the leading edge trailing edge and the inlet of the suction surface tip and outlet. With a 10% increase in water content the enthalpy dropped Mach number increased and turbine power increased by 4.64% 1.71% and 2.41% respectively. However the total static efficiency and mass flow rate decreased by 0.71% and 2.13% respectively. These findings indicate that higher water content in hydrogen combustion products enhances the turbine’s output power while reducing the combustion products’ mass flow rate.

CO2 emissions have been identified as the main driver for climate change with devastating consequences for the global natural environment. The steel industry is responsible for ~7–11% of global CO2 emissions due to high fossil-fuel and energy consumption. The onus is therefore on industry to remedy the environmental damage caused and to decarbonise production. This desk research report explores the Bio Steel Cycle (BiSC) and proposes a seven-step-strategy to overcome the emission challenges within the iron and steel industry. The true levels of combined CO2 emissions from the blast-furnace and basic-oxygen-furnace operation at 4.61 t of CO2 emissions/t of steel produced are calculated in detail. The BiSC includes CO2 capture implementing renewable energy sources (solar wind green H2 ) and plantation for CO2 absorption and provision of biomass. The 7-step-implementation-strategy starts with replacing energy sources develops over process improvement and installation of flue gas carbon capture and concludes with utilising biogas-derived hydrogen as a product from anaerobic digestion of the grown agrifood in the cycle. In the past CO2 emissions have been seemingly underreported and underestimated in the heavy industries and implementing the BiSC using the provided seven-steps-strategy will potentially result in achieving net-zero CO2 emissions in steel manufacturing by 2030.

Hydrogen is considered as a promising fuel in the 21st century due to zero tailpipe CO2 emissions from hydrogen-powered vehicles. The use of hydrogen as fuel in vehicles can play an important role in decarbonising the transport sector and achieving net-zero emissions targets. However there exist several issues related to hydrogen production efficient hydrogen storage system and transport and refuelling infrastructure where the current research is focussing on. This study critically reviews and analyses the recent technological advancements of hydrogen production storage and distribution technologies along with their cost and associated greenhouse gas emissions. This paper also comprehensively discusses the hydrogen refuelling methods identifies issues associated with fast refuelling and explores the control strategies. Additionally it explains various standard protocols in relation to safe and efficient refuelling analyses economic aspects and presents the recent technological advancements related to refuelling infrastructure. This study suggests that the production cost of hydrogen significantly varies from one technology to others. The current hydrogen production cost from fossil sources using the most established technologies were estimated at about $0.8–$3.5/kg H2 depending on the country of production. The underground storage technology exhibited the lowest storage cost followed by compressed hydrogen and liquid hydrogen storage. The levelised cost of the refuelling station was reported to be about $1.5–$8/kg H2 depending on the station's capacity and country. Using portable refuelling stations were identified as a promising option in many countries for small fleet size low-to-medium duty vehicles. Following the current research progresses this paper in the end identifies knowledge gaps and thereby presents future research directions.

While fossil fuels continue to be used and to increase air pollution across the world hydrogen gas has been proposed as an alternative energy source and a carrier for the future by scientists. Water electrolysis is a renewable and sustainable chemical energy production method among other hydrogen production methods. Hydrogen production via water electrolysis is a popular and expensive method that meets the high energy requirements of most industrial electrolyzers. Scientists are investigating how to reduce the price of water electrolytes with different methods and materials. The electrolysis structure equations and thermodynamics are first explored in this paper. Water electrolysis systems are mainly classified as high- and low-temperature electrolysis systems. Alkaline PEM-type and solid oxide electrolyzers are well known today. These electrolyzer materials for electrode types electrolyte solutions and membrane systems are investigated in this research. This research aims to shed light on the water electrolysis process and materials developments.

Electro-fuels (E-fuels) represent a potential solution for decarbonizing the maritime sector including pleasure vessels. Due to their large energy requirements direct electrification is not currently feasible. E-fuels such as synthetic diesel methanol ammonia methane and hydrogen can be used in existing internal combustion engines or fuel cells in hybrid configurations with lithium batteries to provide propulsion and onboard electricity. This study confirms that there is no clear winner in terms of efficiency (the power-to-power efficiency of all simulated cases ranges from 10% to 30%) and the choice will likely be driven by other factors such as fuel cost onboard volume/mass requirements and distribution infrastructure. Pure hydrogen is not a practical option due to its large storage necessity while methanol requires double the storage volume compared to current fossil fuel solutions. Synthetic diesel is the most straightforward option as it can directly replace fossil diesel and should be compared with biofuels. CO2 emissions from E-fuels strongly depend on the electricity source used for their synthesis. With Italy’s current electricity mix E-fuels would have higher impacts than fossil diesel with potential increases between +30% and +100% in net total CO2 emissions. However as the penetration of renewable energy increases in electricity generation associated E-fuel emissions will decrease: a turning point is around 150 gCO2/kWhel.

Hydrogen combustion engine vehicles have the potential to rapidly enter the market and reduce greenhouse gas emissions (GHG) compared to conventional engines. The ability to provide a rapid market deployment is linked to the fact that the industry would take advantage of the existing internal combustion engine production chain. The aim of this paper is twofold. First it aims to develop a methodology for applying life-cycle assessment (LCA) to internal combustion engines to estimate their life-cycle GHG emissions. Also it aims to investigate the decarbonization potential of hydrogen engines produced by exploiting existing diesel engine technology and assuming diverse hydrogen production routes. The boundary of the LCA is cradle-to-grave and the assessment is entirely based on primary data. The products under study are two monofuel engines: a hydrogen engine and a diesel engine. The hydrogen engine has been redesigned using the diesel engine as a base. The engines being studied are versatile and can be used for a wide range of uses such as automotive cogeneration maritime off-road and railway; however this study focuses on their application in pickup trucks. As part of the redesign process certain subsystems (e.g. combustion injection ignition exhaust gas recirculation and exhaust gas aftertreatment) have been modified to make the engine run on hydrogen. Results revealed that employing a hydrogen engine using green hydrogen (i.e. generated from water electrolysis using wind-based electricity) might reduce GHG emission by over 90% compared to the diesel engine This study showed that the benefits of the new hydrogen engine solution outweigh the increase of emissions related to the redesign process making it a potentially beneficial solution also for reconditioning current and used internal combustion engines.

Hydrogen is a versatile energy vector for a plethora of applications; nevertheless its production from waste/residues is often overlooked. Gasification and subsequent conversion of the raw synthesis gas to hydrogen are an attractive alternative to produce renewable hydrogen. In this paper recent developments in R&D on waste gasification (municipal solid waste tires plastic waste) are summarised and an overview about suitable gasification processes is given. A literature survey indicated that a broad span of hydrogen relates to productivity depending on the feedstock ranging from 15 to 300 g H2/kg of feedstock. Suitable gas treatment (upgrading and separation) is also covered presenting both direct and indirect (chemical looping) concepts. Hydrogen production via gasification offers a high productivity potential. However regulations like frame conditions or subsidies are necessary to bring the technology into the market.

Future power systems in which generation will come almost entirely from variable Renewable Energy Sources (vRES) will be characterized by weather-driven supply and flexible demand. In a simulation of the future Dutch power system we analyze whether there are sufficient incentives for market-driven investors to provide a sufficient level of security of supply considering the profit-seeking and myopic behavior of investors. We cosimulate two agent-based models (ABM) one for generation expansion and one for the operational time scale. The results suggest that in a system with a high share of vRES and flexibility prices will be set predominantly by the demand’s willingness to pay particularly by the opportunity cost of flexible hydrogen electrolyzers. The demand for electric heating could double the price of electricity in winter compared to summer and in years with low vRES could cause shortages. Simulations with stochastic weather profiles increase the year-to-year variability of cost recovery by more than threefold and the year-to-year price variability by more than tenfold compared to a scenario with no weather uncertainty. Dispatchable technologies have the most volatile annual returns due to high scarcity rents during years of low vRES production and diminished returns during years with high vRES production. We conclude that in a highly renewable EOM investors would not have sufficient incentives to ensure the reliability of the system. If they invested in such a way to ensure that demand could be met in a year with the lowest vRES yield they would not recover their fixed costs in the majority of years.

This paper offers a set of comprehensive guidelines aimed at facilitating the widespread adoption of hydrogen in the industrial hard-to-abate sectors. The authors begin by conducting a detailed analysis of these sectors providing an overview of their unique characteristics and challenges. This paper delves into specific elements related to hydrogen technologies shedding light on their potential applications and discussing feasible implementation strategies. By exploring the strengths and limitations of each technology this paper offers valuable insights into its suitability for specific applications. Finally through a specific analysis focused on the steel sector the authors provide in-depth information on the potential benefits and challenges associated with hydrogen adoption in this context. By emphasizing the steel sector as a focal point the authors contribute to a more nuanced understanding of hydrogen’s role in decarbonizing industrial processes and inspire further exploration of its applications in other challenging sectors.

Hydrogen is a prospective energy carrier because there are practically no gaseous emissions of greenhouse gases in the atmosphere during its use as a fuel. The great benefit of hydrogen being a practically inexhaustible carbon-free fuel makes it an attractive alternative to fossil fuels. I.e. there is a circular process of energy recovery and use. Another big advantage of hydrogen as a fuel is its high energy content per unit mass compared to fossil fuels. Nowadays hydrogen is broadly used as fuel in transport including fuel cell applications as a raw material in industry and as an energy carrier for energy storage. The mass exploitation of hydrogen in energy production and industry poses some important challenges. First there is a high price for its production compared to the price of most fossil fuels. Next the adopted traditional methods for hydrogen production like water splitting by electrolysis and methane reforming lead to the additional charging of the atmosphere with carbon dioxide which is a greenhouse gas. This fact prompts the use of renewable energy sources for electrolytic hydrogen production like solar and wind energy hydropower etc. An important step in reducing the price of hydrogen as a fuel is the optimal design of supply chains for its production distribution and use. Another group of challenges hindering broad hydrogen utilization are storage and safety. We discuss some of the obstacles to broad hydrogen application and argue that they should be overcome by new production and storage technologies. The present review summarizes the new achievements in hydrogen application production and storage. The approach of optimization of supply chains for hydrogen production and distribution is considered too.

Europe’s heavy reliance on diesel power for nearly half of its railway lines for both goods and passengers has significant implications for carbon emissions. To address this challenge the European Union advocates for a shift towards hydrogen-based mobility necessitating the development of robust and cost-effective hydrogen supply chains at regional and national levels. Leveraging renewable energy sources such as wind farms and solid biomass could foster the transition to sustainable hydrogen-based transportation. In this study a mixed-integer linear programming approach integrated with an external heavy-duty refueling station analysis model is employed to address the optimal design of a new hydrogen supply chain. Through multi-objective optimization this study aimed to minimize the overall daily costs and emissions of the supply chain. By applying the model to a case study in Sicily different scenarios with varying supply chain configurations and wind curtailment factors were explored. The findings revealed that increasing the wind curtailment factor from 1% to 2% led to reductions of 12% and 15% in the total daily emission costs and network costs respectively. Additionally centralized biomass-based plants dominated hydrogen production accounting for 96% and 94% of the total production under 1% and 2% wind curtailment factors respectively. Furthermore transporting gaseous hydrogen via tube trailers proved more cost effective than using tanker trucks for liquid hydrogen when compressed gaseous hydrogen is required at the dispenser of forecourt refueling stations. Finally the breakdown of the levelized cost for the hydrogen refuelling station strongly depends on the form of hydrogen received at the gate namely liquid or gaseous. Specifically for the former the dispenser accounts for 60% of the total cost whereas for the latter the compressor is responsible for 58% of the total cost. This study highlights the importance of preliminary and quantitative analyses of new hydrogen supply chains through model-based optimization.

The MultHyFuel Project funded by the Clean Hydrogen Partnership aims to achieve the effective and safe deployment of hydrogen as a carbon-neutral fuel by developing a common strategy for implementing Hydrogen Refueling Stations (HRS) in a multifuel context. The project hopes to contribute to the harmonisation of existing regulations codes and standards (RCS) by generating practical theoretical and experimental data related to HRS.<br/>This paper presents how a set of safety critical scenarios have been identified from the initial preliminary as well as detailed risk analysis of three different hydrogen refueling station configurations. To achieve this a detailed examination of each potential hazardous phenomenon (DPh) or major accident event at or near the hydrogen dispenser was carried out. Particular attention is paid to the scenarios which could affect third parties external to the refueling station.<br/>The paper presents a methodology subdivided into the following steps:<br/>♦ determination of the consequence level and likelihood of each hazardous phenomenon<br/>♦ the classification of major hazard scenarios for the 3 HRS configurations specifically those arising on the dispensing forecourt;<br/>♦ proposal of example preventative control and/or mitigation barriers that could potentially reduce the probability of occurrence and/ or consequences of safety critical scenarios and hence reducing risks to a tolerable level or to as low as reasonably practicable.

Many simplified methods for estimating blast loads from a hydrogen or vapor cloud explosion are unable to take into account the accurate geometry of confining spaces obstacles or landscape that may significantly interact with the blast wave and influence the strength of blast loads. Computation fluid dynamics (CFD) software Viper::Blast which was originally developed for the simulation of the detonation of high explosives is able to quickly and easily model geometry for blast analyses however its use for vapor cloud explosions and deflagrations is not well established. This paper describes the results of an investigation into the suitability of Viper::Blast for use in modeling hydrogen deflagration and detonation events from various experiments in literature. Detonation events have been captured with a high degree of detail and relatively little uncertainty in inputs while deflagration events are significantly more complex. An approach is proposed that may allow for a reasonable bounding of uncertainty potentially leading to an approach to CFD-based Monte Carlo analyses that are able to address a problem’s true geometry while remaining reasonably pragmatic in terms of run-time and computational investment. This will allow further exploration of practical CFD application to inform hydrogen safety in the engineering design assessment and management of energy mobility and transport systems infrastructure and operations.

Hydrogen is increasingly recognized as a pivotal energy storage solution and a transformative alternative to conventional energy sources. This review summarizes the evolving landscape of global H2 production and consumption markets focusing on the crucial role of photothermal catalysts (PTCs) in driving Hydrogen evolution reactions (HER) particularly with regards to oxide selenide and telluride-based PTCs. Within this exploration the mechanisms of PTCs take center stage elucidating the intricacies of light absorption localized heating and catalytic activation. Essential optimization parameters ranging from temperature and irradiance to catalyst composition and pH are detailed for their paramount role in enhancing catalytic efficiency. This work comprehensively explores photothermal catalysts (PTCs) for hydrogen production by assessing their synthesis techniques and highlighting the current research gaps particularly in optimizing catalytic stability light absorption and scalability. The energy-efficient nature of oxide selenide and telluride-based PTCs makes them prime candidates for sustainable H2 production when compared to traditional materials. By analyzing a range of materials we summarize key performance metrics including hydrogen evolution rates ranging from 0.47 mmolh− 1 g− 1 for Ti@TiO2 to 22.50 mmolh− 1 g− 1 for Mn0.2Cd0.8S/NiSe2. The review concludes with a strategic roadmap aimed at enhancing PTC performance to meet the growing demand for renewable hydrogen as well as a critical literature review addressing challenges and prospects in deploying PTCs.

The low-carbon construction of integrated energy systems is a crucial path to achieving dual carbon goals with the power-generation side having the greatest potential for emissions reduction and the most direct means of reduction which is a current research focus. However existing studies lack the precise modeling of carbon capture devices and the cascaded utilization of hydrogen energy. Therefore this paper establishes a carbon capture power plant model based on a comprehensive flexible operational mode and a coupled model of a two-stage P2G (Power-to-Gas) device exploring the “energy time-shift” characteristics of the coupled system. IGDT (Information Gap Decision Theory) is used to discuss the impact of uncertainties on the power generation side system. The results show that by promoting the consumption of clean energy and utilizing the high energy efficiency of hydrogen while reducing reliance on fossil fuels the proposed system not only meets current energy demands but also achieves a more efficient emission reduction laying a solid foundation for a sustainable future. By considering the impact of uncertainties the system ensures resilience and adaptability under fluctuating renewable energy supply conditions making a significant contribution to the field of sustainable energy transition.