Publications

As the world’s largest integrated energy and chemicals company Saudi Aramco continues to invest in technologies and innovative business models to enable the sustainable use of hydrocarbon resources across the value chain.  In this podcast David Ledesma discusses with Yasser Mufti Vice President Strategy & Market Analysis Saudi Aramco about Saudi Aramco’s perspectives on hydrogen its opportunities and challenges. This wide-ranging interview discusses Saudi Aramco’s investment in new technologies and the sustainable use of its hydrocarbon resources before addressing the role of hydrogen in achieving a low emissions economy possible business models and the barriers to achieving hydrogen’s growth. The podcast then moves on to discuss ammonia carbon capture utilisation and storage finishing up with a forward-looking perspective on the vision for Saudi Aramco asking how will the company look in 2050 and specifically whether it will still be a hydrocarbon company?

The podcast can be found on their website

Many railway vehicles use diesel as their energy source but exhaust emissions and concerns about economical fuel supply demand alternatives. Railway electrification is not cost effective for some routes particularly low-traffic density regional lines. The journey of a regional diesel–electric train is simulated over the British route Birmingham Moor Street to Stratford-upon-Avon and return to establish a benchmark for the conceptual design of a hydrogen-powered and hydrogen-hybrid vehicle. A fuel cell power plant compressed hydrogen at 350 and 700 bar and metal-hydride storage are evaluated. All equipment required for the propulsion can be accommodated within the space of the original diesel– electric train while not compromising passenger-carrying capacity if 700 bar hydrogen tanks are employed. The hydrogen trains are designed to meet the benchmark journey time of 94 min and the operating range of a day without refuelling. An energy consumption reduction of 34% with the hydrogen-powered vehicle and a decrease of 55% with the hydrogen-hybrid train are achieved compared with the original diesel–electric. The well-to-wheel carbon dioxide emissions are lower for the conceptual trains: 55% decrease for the hydrogen-powered and 72% reduction for the hydrogen-hybrid assuming that the hydrogen is produced from natural gas.

In this work we are interested in examining the strain rate effect on the mechanical behavior of Ni–Ti superelastic wires after hydrogen charging and ageing for 24 h. Specimens underwent 50 cycles of loading-unloading reaching an imposed deformation of 7.6%. During loading strain rates from 10⁻⁴ s⁻¹ to 10⁻² s⁻¹ were achieved. With a strain rate of 10⁻² s⁻¹ the specimens were charged by hydrogen for 6 h and aged for one day showed a superelastic behavior marked by an increase in the residual deformation as a function of the number of cycles. In contrast after a few number of cycles with a strain rate of 10⁻⁴ s⁻¹ the Ni-Ti alloy archwire specimens fractured in a brittle manner during the martensite transformation stage. The thermal desorption analysis showed that for immersed specimens the desorption peak of hydrogen appeared at 320 °C. However after annealing the charged specimens by hydrogen at 400 °C for 1 h an embrittlement took place at the last cycles for the lower strain rates of 10⁻⁴ s⁻¹. The present study suggests that the embrittlement can be due to the development of an internal stress in the subsurface of the parent phase during hydrogen charging and due to the creation of cracks and local zones of plasticity after desorption.

Integrated energy systems have become an area of interest as with growing energy demand globally means of producing sustainable energy from flexible sources is key to meet future energy demands while keeping carbon emissions low. Hydrogen is a potential solution for providing flexibility in the future energy mix as it does not emit harmful gases when used as an energy source. In this paper an integrated energy system including hydrogen as an energy vector and hydrogen storage is studied. The system is used to assess the behaviour of a hydrogen production and storage system under different renewable energy generation profiles. Two case studies are considered: a high renewable energy generation scenario and a low renewable energy generation scenario. These provide an understanding of how different levels of renewable penetration may affect the operation of an electrolyser and a fuel cell against an electricity import/export pricing regime. The mathematical model of the system under study is represented using the energy hub approach with system optimisation through linear programming conducted via MATLAB to minimise the total operational cost. The work undertaken showcases the unique interactions the fuel cell has with the hydrogen storage system in terms of minimising grid electricity import and exporting stored hydrogen as electricity back to the grid when export prices are competitive.

A systematic method for obtaining a novel electrode structure based on PtCoMn ternary alloy catalyst supported on graphitic carbon nanofibers (CNF) for hydrogen evolution reaction (HER) in acidic media is proposed. Ternary alloy nanoparticles (Co0.6Mn0.4 Pt) with a mean crystallite diameter under 10 nm were electrodeposited onto a graphitic support material using a two-step pulsed deposition technique. Initially a surface functionalisation of the carbon nanofibers is performed with the aid of oxygen plasma. Subsequently a short galvanostatic pulse electrodeposition technique is applied. It has been demonstrated that if pulsing current is employed compositionally controlled PtCoMn catalysts can be achieved. Variations of metal concentration ratios in the electrolyte and main deposition parameters such as current density and pulse shape led to electrodes with relevant catalytic activity towards HER. The samples were further characterised using several physico-chemical methods to reveal their morphology structure chemical and electrochemical properties. X-ray diffraction confirms the PtCoMn alloy formation on the graphitic support and energy dispersive X-ray spectroscopy highlights the presence of the three metallic components from the alloy structure. The preliminary tests regarding the electrocatalytic activity of the developed electrodes display promising results compared to commercial Pt/C catalysts. The PtCoMn/CNF electrode exhibits a decrease in hydrogen evolution overpotential of about 250 mV at 40 mA cm⁻² in acidic solution (0.5 M H₂SO₄) when compared to similar platinum based electrodes (Pt/CNF) and a Tafel slope of around 120 mV dec−1 indicating that HER takes place under the Volmer-Heyrovsky mechanismm

Global demand for alternative renewable energy sources is increasing due to the consumption of fossil fuels and the increase in greenhouse gas emissions. Hydrogen (H2 ) from biomass gasification is a green energy segment among the alternative options as it is environmentally friendly renewable and sustainable. Accordingly researchers focus on conducting experiments and modeling the reforming reactions in conventional and membrane reactors. The construction of computational fluid dynamics (CFD) models is an essential tool used by researchers to study the performance of reforming and membrane reactors for hydrogen production and the effect of operating parameters on the methane stream improving processes for reforming untreated biogas in a catalyst-fixed bed and membrane reactors. This review article aims to provide a good CFD model overview of recent progress in catalyzing hydrogen production through various reactors sustainable steam reforming systems and carbon dioxide utilization. This article discusses some of the issues challenges and conceivable arrangements to aid the efficient generation of hydrogen from steam reforming catalytic reactions and membrane reactors of bioproducts and fossil fuels.

Understanding the mechanism of hydrogen embrittlement (HE) of austenitic steels and developing an effective strategy to improve resistance to HE are of great concern but challenging. In this work first-principles studies were performed to investigate the HE mechanism and the improved resistance of Al-containing austenite to HE. Our results demonstrate that interstitial hydrogen atoms have different site preferences in Al-free and Al-containing austenites. The calculated binding energies and diffusion barriers of interstitial hydrogen atoms in Al-containing austenite are remarkably higher than those in Al-free austenite indicating that the presence of Al is more favorable for reducing hydrogen mobility. In Al-free austenite interstitial hydrogen atoms caused a remarkable increase in lattice compressive stress and a distinct decrease in bulk shear and Young’s moduli. Whereas in Al-containing austenite the lattice compressive stress and the mechanical deterioration induced by interstitial hydrogen atoms were effectively suppressed.

In the first episode of Hydrogen Europe's podcast "Hydrogen the first element" our CEO Jorgo Chatzimarkakis discusses with NEL's CEO and President of Hydrogen Europe Jon Andre Løkke. Starting off on how Jon joined the hydrogen sector the two CEOs investigate the historical moment renewable hydrogen is currently living.

The Hydrogen Taskforce welcomes the opportunity to submit evidence to the Environmental Audit Committee’s inquiry into Hydrogen. It is the Taskforce’s view that:

• Due to its various applications hydrogen is critical for the UK to reach net zero by 2050;
• The UK holds world-class advantages in hydrogen production distribution and application; and
• Other economies are moving ahead in the development of this sector and the UK must respond.

The Taskforce has defined a set of policy recommendations for Government which are designed to ensure that hydrogen can scale to meet the future demands of a net zero energy system:

• Development of a cross departmental UK Hydrogen Strategy within UK Government;
• Commit £1bn of capex funding over the next spending review period to hydrogen production storage and distribution projects;
• Develop a financial support scheme for the production of hydrogen in blending industry power and transport;
• Amend Gas Safety Management Regulations (GSMR) to enable hydrogen blending and take the next steps towards 100% hydrogen heating through supporting public trials and mandating 100% hydrogen-ready boilers by 2025; and
• Commit to the support of 100 Hydrogen Refuelling Stations (HRS) by 2025 to support the roll-out of hydrogen transport.

You can download the whole document from the Hydrogen Taskforce website here 

We have designed a new method for electrochemical hydrogen charging which allows us to charge very thin coarse-grained specimens from the bottom and perform nanomechanical testing on the top. As the average grain diameter is larger than the thickness of the sample this setup allows us to efficiently evaluate the mechanical properties of multiple single crystals with similar electrochemical conditions. Another important advantage is that the top surface is not affected by corrosion by the electrolyte. The nanoindentation results show that hydrogen reduces the activation energy for homogenous dislocation nucleation by approximately 15–20% in a (001) grain. The elastic modulus also was observed to be reduced by the same amount. The hardness increased by approximately 4% as determined by load-displacement curves and residual imprint analysis.

Taiwan stands out globally in the manufacture of scooters. If fuel cell technology could be applied to the scooter Taiwan could gain an advantage in the trend for commercial applications for fct. In 2011 The Bureau of Standards Metrology and Inspection proposed this project “the Demonstration of Hydrogen Fuel Cell Scooters.” Thirty rental fuel cell scooters are to run a long distance. Evaluation during everyday use of the cells performance will be made and reported by the riders. All the evaluations will be put into consideration of future adjustments. The project is to map out a practice route in Taipei and set up a control center to follow progress. The data gathered from the practice project will help examine the performance of fuel cell scooters contributing to the creation of legal drafts and future standards. The Taiwan fuel cell industry chain is complete and the industry possesses the ability to produce key components. Thus it is a potential market in Taiwan. A review of fuel cell development conditions in Taiwan shows that the fuel cell scooters is a niche industry owing to the strength of this technology.

As the world strives to cut carbon emissions electric power from renewables has emerged as a vital energy source. Yet transport and industry will still require combustible fuels for many purposes. Such needs could be met with hydrogen which itself can be produced using renewable power.



Hydrogen provides high-grade heat helping to meet a range of energy needs that would be difficult to address through direct electrification. This could make hydrogen the missing link in the transformation of the global energy system.  



Key sectors for renewable-based hydrogen uptake include:  

• Industry where it could replace fossil-based feedstocks including natural gas in high-emission applications.
• Buildings and power where it could be mixed with natural gas or combined with industrial carbon dioxide (CO2) emissions to produce syngas.
• Transport where it can provide low-carbon mobility through fuel-cell electric vehicles.  

Electrolysers – which split hydrogen and oxygen – can make power systems more flexible helping to integrate high shares of variable renewables. Power consumption for electrolysis can be adjusted to follow actual solar and wind output while producing the hydrogen needed for transport industry or injection into the gas grid.  



In the long run hydrogen could become a key element in 100% renewable energy systems. With technologies maturing actual scale-up should yield major cost reductions. The right policy and regulatory framework however remains crucial to stimulate private investment in in hydrogen production in the first place.

Protonic ceramic fuel cells (PCFCs) are promising electrochemical devices for the efficient and clean conversion of hydrogen and low hydrocarbons into electrical energy. Their intermediate operation temperature (500–800 °C) proffers advantages in terms of greater component compatibility unnecessity of expensive noble metals for the electrocatalyst and no dilution of the fuel electrode due to water formation. Nevertheless the lower operating temperature in comparison to classic solid oxide fuel cells places significant demands on the cathode as the reaction kinetics are slower than those related to fuel oxidation in the anode or ion migration in the electrolyte. Cathode design and composition are therefore of crucial importance for the cell performance at low temperature. The different approaches that have been adopted for cathode materials research can be broadly classified into the categories of protonic–electronic conductors oxide-ionic–electronic conductors triple-conducting oxides and composite electrodes composed of oxides from two of the other categories. Here we review the relatively short history of PCFC cathode research discussing trends highlights and recent progress. Current understanding of reaction mechanisms is also discussed.

As one of the most promising alternative fuels hydrogen is expected with high hopes. The electrolysis of water is regarded as the cleanest and most efficient method of hydrogen production. Molybdenum disulfide (MoS2) is deemed as one of the most promising alternatives HER catalysts owing to its high catalytic activity and low cost. Its continuous production and efficient preparation become the key problems in future industrial production. In this work we first developed a continuous micro-reaction approach with high heat and mass transfer rates to synthesize few-layer MoS2 nanoplates with abundant active sites. The defective MoS2 ultrathin nanoplates exhibit excellent HER performance with an overpotential of 260 mV at a current density of 10 mA cm-2 small Tafel slope (53.6 mV dec-1) and prominent durability which are comparable to most reported MoS2 based catalysts. Considering the existence of continuous devices it’s suitable for the synthesis of MoS2 as high-performance electrocatalysts for the industrial water electrolysis. The novel preparation method may open up a new way to synthesize all two-dimension materials toward HER.

Although hydrogen is considered to be one of the most promising green fuels its efficient and safe storage and use still raise several technological challenges. Physisorption in porous materials may offer an attractive means of  storage but the state-of-the-art capacity of these kinds of systems is still limited. To overcome the present drawbacks a deeper understanding of the adsorption and surface diffusion mechanism is required along with new types of adsorbents developed and/or optimised for this purpose. In the present study we compare the hydrogen adsorption behaviour of three carbon gels exhibiting different porosity and/or surface chemistry. In addition to standard adsorption characterisation techniques neutron spin-echo spectroscopy (NSE) has been also applied to explore the surface mobility of the adsorbed hydrogen. Our results reveal that both the porosity and surface chemistry of the adsorbent play a significant role in the adsorption of  in these systems.

Emissions from natural gas combustion and use are the largest source of greenhouse gas (GHG) emissions in the UK. The use of hydrogen in place of natural gas in principle offers a potential route to long term widespread decarbonisation of gas distribution networks as shown by the Leeds City Gate (‘H21’) study.1 The purpose of considering conversion to hydrogen is to deliver widespread carbon abatement across the UK at lower cost than alternative decarbonisation strategies.<br/>The Government is to finalise and publish the long-awaited ‘Clean Growth Plan’ along with an Industrial Strategy White Paper in Autumn 2017. Conversion from natural gas to hydrogen potentially on an incremental basis would likely represent a major opportunity for new industrial growth. This might be through the longer term stability or potential expansion of existing (newly decarbonised) energy intensive industry or through business opportunities and growth created from new technologies developed to facilitate the transition to hydrogen as the UK becomes a global leader and major exporter of equipment and skills. Job creation and the resulting gross value added (GVA) to the economy could therefore be significant in delivery of the goals of the Industrial Strategy Challenge Fund (ISCF).<br/>The core requirement is to supply low carbon hydrogen in bulk matching production to distribution network demand at an affordable cost. The H21 study concluded that to do so reliably hydrogen is best produced by reducing natural gas in steam methane reformers (SMRs) fitted with Carbon Capture and Storage (CCS). The study proposed that the considerable inter-seasonal and daily fluctuations in network demand can be managed by storing hydrogen in underground salt formations. It concluded that the SMRs with associated carbon dioxide (CO2) capture should be located near to where CO2 transport and storage infrastructure was likely to be created and noted that candidate locations for this are Teesside Humberside Grangemouth and the Liverpool-Manchester (L-M) area. Two of these Humberside and the L-M area are within the Cadent Gas Ltd (‘Cadent’) network and are also industrial ‘clusters’ with significant populations.<br/>The work reported here builds upon the approach proposed in the H21 project by focussing on defining ‘low carbon’ hydrogen supply and distribution systems in Humberside and the L-M area at a system scale sufficient to supply a large city.2 Both the Humber and L-M clusters are close to salt deposits which are suitable for both daily and inter-seasonal storage of hydrogen (for initial or expanded projects). Furthermore new large-scale gas Combined Cycle Gas Turbine (CCGT) plants widely assumed as likely anchor projects for CCS infrastructure have been consented in both cluster areas confirming that they are both strong candidates as locations for the first CCS clusters and hence as locations for a hydrogen supply system.

Biomass gasification is a promising technology to produce secondary fuels or heat and power offering considerable advantages over fossil fuels. An important aspect in the usage of producer gas is the removal of harmful contaminants from the raw syngas. Thus the object of this study is the development of a simulation model for a gasifier including gas clean-up for which a fluidized-bed gasifier for biomass-derived syngas production was considered based on a quasi-equilibrium approach through Gibbs free energy minimisation and including an innovative hot gas cleaning constituted by a combination of catalyst sorbents inside the gasification reactor catalysts in the freeboard and subsequent sorbent reactors by using Aspen Plus software. The gas cleaning chain simulates the raw syngas clean-up for several organic and inorganic contaminants i.e. toluene benzene naphthalene hydrogen sulphide hydrogen chloride and ammonia. The tar and inorganic contaminants final values achieved are under 1 g/Nm3 and 1 ppm respectively.

Energy Technology Perspectives 2020 is a major new IEA publication focused on the technology needs and opportunities for reaching international climate and sustainable energy goals. This flagship report offers vital analysis and advice on the clean energy technologies the world needs to meet net-zero emissions objectives.

The report’s comprehensive analysis maps out the technologies needed to tackle emissions in all parts of the energy sector including areas where technology progress is still lacking such as long-distance transport and heavy industries. It shows the amount of emissions reductions that are required from electrification hydrogen bioenergy and carbon capture utilisation and storage. It also provides an assessment of emissions from existing infrastructure and what can be done to address them.

Link to Document on IEA website

China has promised to reach the peak carbon dioxide emission (ca. 10 billion tons) by 2030 and carbon neutrality by 2060. To realize these goals it is necessary to develop hydrogen energy and fuel cell techniques. However the high cost and low intrinsic safety of high-pressure hydrogen storage limit their commercialization. NH3 is high in hydrogen content easily liquefied at low pressure and free of carbon and the technology of NH3 synthesis has been commercialized nationwide. It is worth noting that the production of NH3 in China is about 56 million tons per year accounting for 35% of worldwide production. Hence with the well established infrastructure for NH3 synthesis and transportation and the demand for clean energy in China it is feasible to develop a green and economical energy roadmap viz. “Clean low-pressure NH3 synthesis → Safe and economical NH3 storage and transportation → Carbon-free efficient NH3-H2 utilization” for low-carbon or even carbon-free energy production.<br/>Currently the academic and industrial communities in China are striving to make technological breakthroughs in areas such as photocatalytic water splitting electrocatalytic water splitting mild-condition NH3 synthesis low-temperature NH3 catalytic decomposition and indirect or direct NH3 fuel cells with significant progress.<br/>Taking full advantage of the NH3 synthesis industry and readjusting the industrial structure it is viable to achieve energy saving and emission reduction in NH3 synthesis industry (440 million tons CO2 per year) as well as promote a new energy industry and ensure national energy security. Therefore relevant academic and industrial communities should put effort on mastering the key technologies of “Ammonia-Hydrogen” energy conversion and utilization with complete self-dependent intellectual property. It is envisioned that through the establishment of “Renewable Energy-Ammonia-Hydrogen” circular economy a green technology chain for hydrogen energy industry would pose as a promising pathway to achieve the 2030 and 2060 goals.

<br/>The decarbonisation of heating represents a transformative challenge for many countries. The UK’s net-zero greenhouse gas emissions target requires the removal of fossil fuel combustion from heating in just three decades. A greater understanding of policy processes linked to system transformations is expected to be of value for understanding systemic change; how policy makers perceive policy issues can impact on policy change with knock-on effects for energy system change. This article builds on the literature considering policy maker perceptions and focuses on the issue of UK heat policy. Using qualitative analysis we show that policy makers perceive heat decarbonisation as disruptive technological pathways are seen as deeply uncertain and heat decarbonisation appears to offer policy makers little ‘up-side’. Perceptions are bounded by uncertainty affected by concerns over negative impacts influenced by external influences and relate to ideas of continuity. Further research and evidence on optimal heat decarbonisation and an adaptive approach to governance could support policy makers to deliver policy commensurate with heat decarbonisation. However even with reduced uncertainty and more flexible governance the perceptions of disruption to consumers mean that transformative heat policy may remain unpopular for policy makers potentially putting greenhouse mitigation targets at risk of being missed.

Hydrogen is an essential element in the energy transition and can account for 24% of final energy demand and 5.4m jobs by 2050 says the new study by the FCH JU “Hydrogen Roadmap Europe: A sustainable pathway for the European Energy Transition“. Developed with input from 17 leading European industrial actors the study lays out a pathway for the large-scale deployment of hydrogen and fuel cells until 2050 and quantifies the associated socio-economic impacts.<br/>The report makes the case that hydrogen is required to address the challenges ahead. At scale decarbonisation of key segments such as the gas grid transport (particularly as relates to heavy duty vehicles) industrial processes that use high-grade heat and hydrogen as chemical feedstock require the use of hydrogen in large quantities.<br/>In addition the electrification of the economy and the large scale integration of intermittent renewable energy sources require large scale energy storage enabling seasonal storage and the efficient transport of clean energy across regions at low cost. Hydrogen is the only at scale technology capable of addressing all of these challenges.<br/>Importantly there will be important socio-economic and environmental benefits associated with this deployment such as an EUR 820B per year market and a total of 560Mt CO2 abated. The report lays out a roadmap for the ramp-up of market deployment across applications setting specific milestones between now and 2050. It also calls for a coordinated approach from policy makers industry and investors in order to achieve the 2-degree scenario.

This article presents a summary of the main findings from a collaborative research project between Aalto University in Finland and partner universities. A comparative process synthesis modelling and thermal assessment was conducted for the production of Bio-synthetic natural gas (SNG) and hydrogen from supercritical water refining of a lipid extracted algae feedstock integrated with onsite heat and power generation. The developed reactor models for product gas composition yield and thermal demand were validated and showed conformity with reported experimental results and the balance of plant units were designed based on established technologies or state-of-the-art pilot operations. The poly-generative cases illustrated the thermo-chemical constraints and design trade-offs presented by key process parameters such as plant organic throughput supercritical water refining temperature nature of desirable coproducts downstream indirect production and heat recovery scenarios. The evaluated cases favoring hydrogen production at 5 wt. % solid content and 600 ◦C conversion temperature allowed higher gross syngas and CHP production. However mainly due to the higher utility demands the net syngas production remained lower compared to the cases favoring BioSNG production. The latter case at 450 ◦C reactor temperature 18 wt. % solid content and presence of downstream indirect production recorded 66.5% 66.2% and 57.2% energetic fuel-equivalent and exergetic efficiencies respectively

Purpose- To present an overview of the research and development carried out in a European funded framework 7 (FP7) project called SafeHPower for the implementation of neutron radiography to inspect fatigue cracks in vehicle and storage hydrogen fuel tanks. Project background– Hydrogen (H2) is the most promising replacement fuel for road transport due to its abundance efficiency low carbon footprint and the absence of harmful emissions. For the mass market of hydrogen to take off the safety issue surrounding the vehicle and storage hydrogen tanks needs to be addressed. The problem is the residual and additional stresses experienced by the tanks during the continuous cyclic loading between ambient and storage pressure which can result in the development of fatigue cracks. Steel tanks used as storage containers at service stations and depots and/or the composite tanks lined with steel are known to suffer from hydrogen embrittlement (HE). Another issue is the explosive nature of hydrogen (when it is present in the 18-59% range) where it is mixed with oxygen which can lead to catastrophic consequences including loss of life. Monitoring systems that currently exist in the market impose visual examination tests pressure tests and hydrostatic tests after the tank installation [1] [2]. Three inspection systems have been developed under this project to provide continuous monitoring solutions. Approach and scope- One of the inspection systems based on the neutron radiography (NR) technology that was developed in different phases with the application of varied strategies has been presented here. Monte Carlo (MCNP) simulation results to design and develop a bespoke collimator have been presented. A limitation of using an inertial electrostatic Deuterium-Tritium (D-T) pulsed neutron generator for fast neutron radiography has been discussed. Radiographs from the hydrogen tank samples obtained using thermal neutrons from a spallation neutron source at ISIS Rutherford laboratory UK have been presented. Furthermore radiograph obtained using thermal neutrons from a portable D-T neutron generator has been presented. In conclusion a proof in principle has been made to show that the defects in the hydrogen fuel tank can be detected using thermal neutron radiography.

The potential of electron-donating capability in methoxy groups of antioxidant containing protein (ACAP) as organic catalyst is restricted by its low isoelectric point. The goal of this study is to construct endure ACAP based metal-free organic catalyst for hydrogen production from electrolysis of noodle wastewater. The ACAP was coated thermomechanically on PVC sheet and its performance was tested during electrolysis of noodle wastewater. The morphological analysis phase analysis and elemental analysis of coated materials have shown a simultaneous pattern with electrolysis performances. The use of graphite flake to cover turmeric ACAP obstructs the electron to attack directly the positive charge of ACAP so that the electrocatalytic endurance increases while maintaining the hydrogen production rate. The combination of phenolic and enzymatic ACAPs is found to have the slowest reaction rate and lowest hydrogen production. The phenolic compound inhibits the enzymatic reaction.

Bioenergy with carbon capture and storage (BECCS) is one of the prevailing negative carbon emission technologies. Ensuring a hydrogen economy is essential to achieving the carbon-neutral goal. In this regard the present study contributed by proposing a carbon negative process for producing high purity hydrogen from the organic fraction of municipal solid waste (OFMSW). This integrated process comprises anaerobic digestion pyrolysis catalytic reforming water-gas shift and pressure swing adsorption technologies. By focusing on Sweden the proposed process was developed and evaluated through sensitivity analysis mass and energy balance calculations techno-economic assessment and practical feasibility analysis. By employing the optimum operating conditions from the sensitivity analysis 72.2 kg H2 and 701.47 kg negative CO2 equivalent emissions were obtained by treating 1 ton of dry OFMSW. To achieve these results 6621.4 MJ electricity and 325 kg of steam were utilized during this process. Based on this techno-economic assessment of implementing the proposed process in Stockholm when the negative CO2 equivalent emissions are recognized as income the internal rate of return and the discounted payback period can be obtained as 26% and 4.3 years respectively. Otherwise these values will be 13% and 7.2 years.