Publications
Ignition of Hydrogen-air Mixtures Under Volumetric Expansion Conditions
Sep 2017
Publication
A better understanding of chemical kinetics under volumetric expansion is important for a number of situations relevant to industrial safety including detonation diffraction and direct initiation reflected shock-ignition at obstacles ignition behind a decaying shock among others. The ignition of stoichiometric hydrogen-air mixtures was studied using 0D numerical simulations with time-dependent specific volume variations. The competition between chemical energy release and expansion-induced cooling was characterized for different cooling rates and mathematical forms describing the shock decay rate. The critical conditions for reaction quenching were systematically determined and the thermo-chemistry dynamics were analyzed near the critical conditions.
Systematic Overview of Newly Available Technologies in the Green Maritime Sector
Jan 2023
Publication
The application of newly available technologies in the green maritime sector is difficult due to conflicting requirements and the inter-relation of different ecological technological and economical parameters. The governments incentivize radical reductions in harmful emissions as an overall priority. If the politics do not change the continuous implementation of stricter government regulations for reducing emissions will eventually result in the mandatory use of what we currently consider alternative fuels. Immediate application of radically different strategies would significantly increase the economic costs of maritime transport thus jeopardizing its greatest benefit: the transport of massive quantities of freight at the lowest cost. Increased maritime transport costs would immediately disrupt the global economy as seen recently during the COVID-19 pandemic. For this reason the industry has shifted towards a gradual decrease in emissions through the implementation of “better” transitional solutions until alternative fuels eventually become low-cost fuels. Since this topic is very broad and interdisciplinary our systematic overview gives insight into the state-of-the-art available technologies in green maritime transport with a focus on the following subjects: (i) alternative fuels; (ii) hybrid propulsion systems and hydrogen technologies; (iii) the benefits of digitalization in the maritime sector aimed at increasing vessel efficiency; (iv) hull drag reduction technologies; and (v) carbon capture technologies. This paper outlines the challenges advantages and disadvantages of their implementation. The results of this analysis elucidate the current technologies’ readiness levels and their expected development over the coming years.
Towards Unified Protocol for Par's Performance Rating and Safety Margins Assessment: Par Life-cycle Systemic Model
Sep 2021
Publication
Passive Autocatalytic Recombiners (PAR) is one of the important technical mitigation means for hydrogen combustion in the NPP containments under accident conditions. For the PWR/VVER/CANDU units the PARs execute functions important for safety - reduce the local hydrogen concentration to an acceptable level and provide the homogenization of gas composition and of temperature fields in the containment. Certification and licensing of PAR technology have been accepted for the different NPP types and in the different countries on the case-by-case basement. But a comprehensive and generally accepted terminology and procedures for PAR characterization and its performance and safety rating are still absent. As a next step in PAR's technology improvement and maturity it would be logical a development of their unified technical standardization and certification. Report is aimed to - 2) justify need in standardization of the PARs in the nuclear industry and in the hydrogen energy applications 2) define a minimal set of the notions which can be used for quantitative characterization of the of PARs throughout its life-cycle 3) formulate a systemic (generic state-machine or automata) model of PAR's states under the normal and accident conditions. After verification and validation of proposed PAR systemic model it can be used as one of ints for the development of an international standard for PAR performance and safety.
Conceptual Design of a Hybrid Hydrogen Fuel Cell/Battery Blended-Wing-Body Unmanned Aerial Vehicle—An Overview
May 2022
Publication
The manuscript presents the conceptual design phase of an unmanned aerial vehicle with the objective of a systems approach towards the integration of a hydrogen fuel-cell system and Li-ion batteries into an aerodynamically efficient platform representative of future aircraft configurations. Using a classical approach to aircraft design and a combination of low- and high-resolution computational simulations a final blended wing body UAV was designed with a maximum take-off weight of 25 kg and 4 m wingspan. Preliminary aerodynamic and propulsion sizing demonstrated that the aircraft is capable of completing a 2 h long mission powered by a 650 W fuel cell hybridized with a 100 Wh battery pack and with a fuel quantity of 80 g of compressed hydrogen.
A CFD Analysis of Liquid Hydrogen Vessel Explosions using the ADREA-HF Code
Sep 2021
Publication
Despite hydrogen is one of the most suitable candidates in replacing fossil fuels its very low densityrepresents a drawback when it is stored. The liquefaction process can increase the hydrogen densityand therefore enhance its storage capacity. The boiling liquid expanding vapour explosion (BLEVE) isa typical accident scenario that must be always considered when liquefied gases are stored. Inparticular BLEVE is a physical explosion with low probabilities and high consequences which mayoccur after the catastrophic rupture of a vessel containing a liquid with a temperature above its boilingpoint at atmospheric pressure. In this paper a parametric CFD analysis of the BLEVE phenomenonwas conducted by means of the CFD code ADREA-HF for liquid hydrogen (LH2) vessels. Firstly theCFD model is validated against a well-documented CO2 BLEVE experiment. Next hydrogen BLEVEcases are examined. The physical parameters were chosen based on the BMW tests carried out in the1990s on LH2 tanks designed for automotive purposes. Different filling degrees initial pressures andtemperatures of the tank content are simulated to comprehend how the blast wave is influenced by theinitial conditions. The aim of this study is twofold: provide new insights and observations on theBLEVE dynamics and demonstrate the CFD tool effectiveness for conducting the consequenceanalysis and thus aiding the risk assessment of liquefied gas vessel explosion. Good agreement wasshown between the simulation outcomes and the experimental results.
Electrolyzers Enhancing Flexibility in Electric Grids
Nov 2017
Publication
This paper presents a real-time simulation with a hardware-in-the-loop (HIL)-based approach for verifying the performance of electrolyzer systems in providing grid support. Hydrogen refueling stations may use electrolyzer systems to generate hydrogen and are proposed to have the potential of becoming smarter loads that can proactively provide grid services. On the basis of experimental findings electrolyzer systems with balance of plant are observed to have a high level of controllability and hence can add flexibility to the grid from the demand side. A generic front end controller (FEC) is proposed which enables an optimal operation of the load on the basis of market and grid conditions. This controller has been simulated and tested in a real-time environment with electrolyzer hardware for a performance assessment. It can optimize the operation of electrolyzer systems on the basis of the information collected by a communication module. Real-time simulation tests are performed to verify the performance of the FEC-driven electrolyzers to provide grid support that enables flexibility greater economic revenue and grid support for hydrogen producers under dynamic conditions. The FEC proposed in this paper is tested with electrolyzers however it is proposed as a generic control topology that is applicable to any load.
Cotton Stalk Activated Carbon-supported Co–Ce–B Nanoparticles as Efficient Catalysts for Hydrogen Generation Through Hydrolysis of Sodium Borohydride
Nov 2019
Publication
Porous cotton stalk activated carbons (CSAC) were prepared by phosphoric acid activation of cotton stalks in a fluidized bed. The CSAC-supported Co–B and Co–Ce–B catalysts were prepared by the impregnation-chemical reduction method. The samples were characterized by the nitrogen adsorption XRD FTIR and TEM measurements. The effects of the sodium borohydride (NaBH4) and sodium hydroxide (NaOH) concentrations reaction temperature and recyclability on the rate of NaBH4 hydrolysis over the CSAC-supported Co–Ce–B catalysts were systematically investigated. The results showed that the agglomeration of the Co–Ce–B nanoclusters on the CSAC support surface was significantly reduced with the introduction of cerium. The CSAC-supported Co–Ce–B catalyst exhibited superior catalytic activity and the average hydrogen generation rate was 16.42 L min−1 g−1 Co at 25°C which is higher than the most reported cobalt-based catalysts. The catalytic hydrolysis of NaBH4 was zero order with respect to the NaBH4 concentration and the hydrogen generation rate decreased with the increase in the NaOH concentration. The activation energy of the hydrogen generation reaction on the prepared catalyst was estimated to be 48.22 kJ mol−1. A kinetic rate equation was also proposed.
Briefing on the EU Innovation Fund and the Implications for CCUS Projects- First Report on the Thematic Working Group on Policy, Regulation and Public Perception
Jan 2020
Publication
This report outlines the key modalities and procedures for the Innovation Fund and focuses on the potential funding implications for CCUS projects. The assessment of the suitability of the Innovation Fund for CCS projects has been completed based on discussion during a workshop hosted by the EU CCUS Projects Network in October 2019. This session was part of the Network’s Thematic Group on Policy Regulation and Public Perception. The session was held according to Chatham House rules to allow the projects present to exchange viewpoints and ideas freely.<br/>Broadly speaking it is hoped that the Innovation Fund Call for Proposal documents expected in mid-2020 will provide more information on how applicants should approach some of the key evaluation criteria namely calculating emissions avoidance for part-chain CCS and CCU projects demonstrating project maturity as well as project innovativeness. Furthermore there remains a concern that the costs for developing sufficient contingent storage sites could be overlooked by the Innovation Fund and EU policies directed towards CCS in general. Finally whereas there does not seem to be any regulatory barriers to blending Innovation Fund financing with Member State subsidies the asynchronous timing between the planned final investment decisions (FIDs) of some of the more advanced projects and the outcomes of the Innovation Fund (expected in 2022) means that certain projects may not be able to benefit from this.
GIS-Based Method for Future Prospect of Energy Supply in Algerian Road Transport Sector Using Solar Roads Technology
May 2019
Publication
This paper aims to investigate the possibility of integration of Electric Vehicles EVs supply’s with electricity and/or hydrogen in the road transport sector and estimate the energy supply derived from solar irradiation by using solar roads technology. The case study is road Est-Oust (road E-O) of Algeria. A Geographic Information System and spatial analysis tools are combined with spatial data and technical models to carry out these calculations. The results of this study demonstrate that solar road panels which are integrated into the road E-O produce over to 804 GWh/year which equivalents to 13778 tons of hydrogen per year.by using FCEVs will saving over then 41.103 liter of fossil fuels (regular gasoline); and reduce GHG emission (CO2) in the transportation sector by 216 tons per year.
Fracture Properties of Welded 304L in Hydrogen Environments
Sep 2021
Publication
Austenitic stainless steels are used for hydrogen containment of high-pressure hydrogen gas due to their ability to retain high fracture properties despite the degradation due to hydrogen. Forging and other strain-hardening processes are desirable for austenitic stainless steels to increase the material strength and thus accommodate higher stresses and reduce material costs. Welding is often necessary for assembling components but it represents an area of concern in pressure containment structures due to the potential for defects more environmentally susceptible microstructure and reduced strength. Electron beam (EB) welding represent an advanced joining process which has advantages over traditional arc welding techniques through reduced input heat and reduced heat-affected zone (HAZ) microstructure and thus present a means to maintain high strength and improve weld performance in hydrogen gas containment. In this study fracture coupons were extracted from EB welds in forged 304L and subjected to thermal gaseous hydrogen precharging at select pressures to introduce different levels of internal hydrogen content. Fracture tests were then performed on hydrogen precharged coupons at temperatures of both 293 K and 223 K. It was observed that fracture resistance (JH) was dependent on internal hydrogen concentration; higher hydrogen concentrations resulted in lower fracture resistance in both the forged 304L base material and the 304L EB welds. This trend was also apparent at both temperatures: 293 K and 223 K. EB weld samples however maintain high fracture resistance comparable to the forged 304L base material. The role of weld microstructure solidification on fracture is discussed.
Investment Frameworks for Development of CCUS in the UK
Jul 2019
Publication
The CCUS Advisory Group (CAG) established in March 2019 is an industry-led group considering the critical challenges facing the development of CCUS market frameworks and providing insight into potential solutions. The CAG brings together experts from across the CCUS industry finance and legal sectors.<br/>The CAG has examined a range of business models focusing on industrial CCUS power production CO? transport and storage and hydrogen production. It has considered how the proposed business models interact in order to minimise issues such as cross-chain risk and has considered issues such as delivery capability. The conclusions of the CAG can be found in this report.
A Simple and Low-cost Integrative Sensor System for Methane and Hydrogen Measurement
Sep 2020
Publication
Energy production by methanization or gasification of biomass is dependant on the chemical composition of the gas generated. The resistive sensors based on semiconductor metal oxides like the MQ series sensors are inexpensive and frequently used in gas detection. These sensors initially dedicated to detecting gas leaks in safety systems have relatively small measurement ranges (i.e. limited to concentrations below 10000 ppm). It is therefore necessary to find solutions to adapt these categories of sensors for gas measurements in the energy sector where the gas concentration is much more significant. In this article we propose a protocol using an adaptable capsule for MQ-4 and MQ-8 sensors to measure high concentrations of CH4 and H2 respectively. The technique consists of diluting the gas to be studied in a known volume of air. Three methods are proposed and compared regarding the linearity and the repeatability of the measurements. The first method was done in an airtight enclosed chamber the second method consists of directly injecting the gas on the sensor placed in an open environment and the final method was accomplished by direct injection of the gas on the sensor placed in a partially closed capsule. Comparisons show that the first technique provides the best repeatability with a maximum standard deviation of 13.88% for CH4 measurement and 5.1% for H2. However its linearity is weak (i.e. R2 ¼ 0.8637 for CH4 and R2 ¼ 0.5756 for H2). The second technique has better linearity but bad repeatability. The third technique presents the best results with R2 values of 0.9973 for the CH4 measurement and 0.9472 for H2. The use of the partially closed capsule resulted in an acceptable linear response of the sensors by up to 20% concentration of CH4 and until 13.33% concentration of H2 in the studied gas. The use of this simple and low-cost technique facilitates the characterization of combustible gases in isolated areas. It allows local operators of biomass valorization systems to control and improve their installations while avoiding the high costs of conventional measurement devices. This study hence contributes to the development of rural electrification projects in remote areas.
Climate Change Committee: Progress in Reducing Emissions, 2022 Report to Parliament
Jun 2022
Publication
This statutory report provides a comprehensive overview of the UK Government’s progress to date in reducing emissions. It is accompanied by a new Monitoring Framework which details the CCC’s updated approach to tracking real-world progress through a host of new indicators.<br/>This is a pivotal point in the UK’s journey to Net Zero. The UK is one of the few countries with emissions targets in line with the long-term temperature goal of the Paris Agreement. Policy ambition has moved substantially with the publication of the UK’s Net Zero Strategy. Now is the time to deliver the promised action.
Renewable Hydrogen Economy Outlook in Africa
Jun 2022
Publication
Hydrogen presents an opportunity for Africa to not only decarbonise its own energy use and enable clean energy access for all but also to export renewable energy. This paper developed a framework for assessing renewable resources for hydrogen production and provides a new critical analysis as to how and what role hydrogen can play in the complex African energy landscape. The regional solar wind CSP and bio hydrogen potential ranges from 366 to 1311 Gt/year 162 to 1782 Gt/year 463 to 2738 Gt/year and 0.03 to 0.06 Gt/year respectively. The water availability and sensitivity results showed that the water shortages in some countries can be abated by importing water from regions with high renewable water resources. A techno-economic comparative analysis indicated that a high voltage direct current (HVDC) system presents the most cost-effective transportation system with overall costs per kg hydrogen of 0.038 $/kg followed by water pipeline with 0.084 $/kg seawater desalination 0.1 $/kg liquified hydrogen tank truck 0.12 $/kg compressed hydrogen pipeline 0.16 $/kg liquefied ammonia pipeline 0.38 $/kg liquefied ammonia tank truck 0.60 $/kg and compressed hydrogen tank truck with 0.77 $/kg. The results quantified the significance of economies of scale due to cost effectiveness of systems such as compressed hydrogen pipeline and liquefied hydrogen tank truck systems when hydrogen production is scaled up. Decentralization is favorable under some constraints e.g. compressed hydrogen and liquefied ammonia tank truck systems will be more cost effective below 800 km and 1400 km due to lower investment and operation costs.
Energy Management Control Strategy for Saving Trip Costs of Fuel Cell/Battery Electric Vehicles
Mar 2022
Publication
Fuel cell vehicles (FCVs) should control the energy management between two energy sources for fuel economy using the stored energy in a battery or generation of energy through a fuel cell system. The fuel economy for an FCV includes trip costs for hydrogen consumption and the lifetime of two energy sources. This paper proposes an implementable energy management control strategy for an FCV to reduce trip costs. The concept of the proposed control strategy is first to analyze the allowable current of a fuel cell system from the optimal strategies for various initial battery state of charge (SOC) conditions using dynamic programming (DP) and second to find a modulation ratio determining the current of a fuel cell system for driving a vehicle using the particle swarm optimization method. The control strategy presents the on/off moment of a fuel cell system and the proper modulation ratio of the turned-on fuel cell system with respect to the battery SOC and the power demand. The proposed strategy reduces trip costs in real-time similar to the DP-based optimal strategy and more than the simple energy control strategy of switching a fuel cell system on/off at the battery SOC boundary conditions even for long-term driving cycles.
Prospects for the Use of Hydrogen in the Armed Forces
Oct 2021
Publication
The energy security landscape that we envisage in 2050 will be different from that of today. Meeting the future energy needs of the armed forces will be a key challenge not least for military security. The World Energy Council’s World Energy Scenarios forecast that the world’s population will rise to 10 billion by 2050 which will also necessitate an increase in the size of the armed forces. In this context energy extraction distribution and storage become essential to stabilizing the imbalance between production and demand. Among the available solutions Power to Hydrogen (P2H) is one of the most appealing options. However despite the potential many obstacles currently hinder the development of the P2H market. This article aims to identify and analyse existing barriers to the introduction of P2H technologies that use hydrogen. The holistic approach used which was based on a literature survey identified obstacles and possible strategies for overcoming them. The research conducted presents an original research contribution at the level of hydrogen strategies considered in leading countries around the world. The research findings identified unresolved regulatory issues and sources of uncertainty in the armed forces. There is a lack of knowledge in the armed forces of some countries about the process of producing hydrogen energy and its benefits which raises concerns about the consistency of its exploitation. Negative attitudes towards hydrogen fuel energy can be a significant barrier to its deployment in the armed forces. Possible approaches and solutions have also been proposed to eliminate obstacles and to support decision makers in defining and implementing a strategy for hydrogen as a clean energy carrier. There are decisive and unresolved obstacles to its deployment not only in the armed forces
Analysis of Hydrogen in Inorganic Materials and Coatings: A Critical Review
Jun 2021
Publication
The currently used bulk analysis and depth profiling methods for hydrogen in inorganic materials and inorganic coatings are reviewed. Bulk analysis of hydrogen is based on fusion of macroscopic samples in an inert gas and the detection of the thereby released gaseous H2 using inert gas fusion (IGF) and thermal desorption spectroscopy (TDS). They offer excellent accuracy and sensitivity. Depth profiling methods involve glow discharge optical emission spectroscopy and mass spectrometry (GDOES and GDMS) laser-induced breakdown spectroscopy (LIBS) secondary ion mass spectrometry (SIMS) nuclear reaction analysis (NRA) and elastic recoil detection analysis (ERDA). The principles of all these methods are explained in terms of the methodology calibration procedures analytical performance and major application areas. The synergies and the complementarity of various methods of hydrogen analysis are described. The existing literature about these methods is critically evaluated and major papers concerning each method are listed.
Mobility from Renewable Electricity: Infrastructure Comparison for Battery and Hydrogen Fuel Cell Vehicles
May 2018
Publication
This work presents a detailed breakdown of the energy conversion chains from intermittent electricity to a vehicle considering battery electric vehicles (BEVs) and fuel cell electric vehicles (FCEVs). The traditional well-to-wheel analysis is adapted to a grid to mobility approach by introducing the intermediate steps of useful electricity energy carrier and on-board storage. Specific attention is given to an effective coupling with renewable electricity sources and associated storage needs. Actual market data show that compared to FCEVs BEVs and their infrastructure are twice as efficient in the conversion of renewable electricity to a mobility service. A much larger difference between BEVs and FCEVs is usually reported in the literature. Focusing on recharging events this work additionally shows that the infrastructure efficiencies of both electric vehicle (EV) types are very close with 57% from grid to on-board storage for hydrogen refilling stations and 66% for fast chargers coupled with battery storage. The transfer from the energy carrier at the station to on-board storage in the vehicle accounts for 9% and 12% of the total energy losses of these two modes respectively. Slow charging modes can achieve a charging infrastructure efficiency of 78% with residential energy storage systems coupled with AC chargers.
Factors Affecting Hydrogen Adsorption in Metal–Organic Frameworks: A Short Review
Jun 2021
Publication
Metal–organic frameworks (MOFs) have significant potential for hydrogen storage. The main benefit of MOFs is their reversible and high-rate hydrogen adsorption process whereas their biggest disadvantage is related to their operation at very low temperatures. In this study we describe selected examples of MOF structures studied for hydrogen adsorption and different factors affecting hydrogen adsorption in MOFs. Approaches to improving hydrogen uptake are reviewed including surface area and pore volume in addition to the value of isosteric enthalpy of hydrogen adsorption. Nanoconfinement of metal hydrides inside MOFs is proposed as a new approach to hydrogen storage. Conclusions regarding MOFs with incorporated metal nanoparticles which may be used as nanoscaffolds and/or H2 sorbents are summarized as prospects for the near future.
Effect of a Ripple Current on the Efficiency of a PEM Electrolyser
Mar 2021
Publication
The aim of this study was to determine how the efficiency of a proton exchange membrane (PEM) electrolyser is affected by an electric ripple current and the different characteristics of the ripple current (frequency amplitude and waveform). This paper presents the experimental method and measured results used to analyse the effect of ripple currents at various frequencies ripple factors and waveforms on the hydrogen production power consumption and efficiency of a PEM electrolyser. An active laboratory-size PEM electrolysis system was used to investigate the impact of various ripple currents on the efficiency of the system. The results revealed that the average power consumption increases as the ripple factor increases and decreases as the frequency of the ripple increases while the waveform of the applied current has no effect. Furthermore the average hydrogen flow rate is unaffected by the ripple factor frequency or waveform of the applied ripple current.
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