Applications & Pathways
Simulation of the Refuelling Process for an LH2-powered Commercial Aircraft Part 1 - Modelling and Validation
Nov 2025
Publication
Liquid hydrogen (LH2) is a promising candidate for zero emission aviation but its cryogenic properties make the refuelling process fundamentally different from that of conventional jet fuels. Although previous studies have addressed LH2 storage and system integration detailed modelling of the refuelling process remains limited. This paper presents the first part of a two-part study focused on simulation of the refuelling process for an LH2-powered commercial aircraft. An existing tank model is substantially modified to more accurately capture relevant physical phenomena including heat transfer and droplet dynamics during top-fill spray injection. Newly available experimental data on LH2 no-vent filling enables direct validation of the model under conditions that match the experimental setup. A sensitivity analysis identifies the most influential parameters that affect model precision including loss coefficient droplet diameter radiative heat ingress and vent-closing pressure. The validated model forms the basis for Part 2 of this study in which it is applied to a representative LH2-powered commercial aircraft to simulate refuelling times quantify venting losses and assess the impact of key operational settings. These results support the design of efficient LH2 refuelling systems for future aircraft and airport infrastructure.
Techno-economic Assessment of Hythane-fueled Industrial SOFC Systems
Nov 2025
Publication
Solid oxide fuel cell (SOFC) systems offer high-efficiency conversion of the chemical energy of fuel gases into electrical energy. To meet market and policy targets such systems must be able of operating on an industrial scale and be compatible with environmentally friendly fuels. This study models the scale-up of a 750 W naturalgas-fueled SOFC to a 240 kW system with various gas-path configurations evaluating the impact of blending up to 30 vol% of hydrogen (H2) into the methane feed. Aspen Plus simulations coupled with pressure-loss and carbon-deposition models were used to optimize recirculation ratio and reactant utilization for maximum efficiency. The parallel configuration achieved the highest electrical efficiency of 64.0 % while series-connected and intermediate systems suffered from increased pressure losses. H2 admixture simulations confirm that operation is feasible without loss of efficiency in the small- and large-scale systems due to reduced carbondeposition potential. A techno-economic analysis indicates a 91.7 % cost reduction through scale-up and a 1.6 % cost increase for adjusting the system to H2 admixtures. The economic viability of the large-scale system was evaluated for all tested fuel compositions (0.201–0.204 €/kWh) with payback times under 20 years at market-relevant electricity prices. These results demonstrate the technical and economic feasibility of large-scale H2-adapted SOFC systems for industrial decarbonization.
Direct Injection Hydrogen Combustion under Leaner Conditions in an Optical Engine using Optical/Laser Diagnostics
Nov 2025
Publication
Hydrogen’s increasing potential as an alternative fuel for heavy-duty transport has led to the conversion of conventional diesel compression-ignition engines to spark-ignition hydrogen operation. Hydrogen’s broad flammability range enables leaner operation achieving both higher engine efficiency and near-zero emissions. In particular direct injection hydrogen combustion improves volumetric efficiency and reduces problems including pre-ignition and knock related to hydrogen port-fuel injection. In the present work we performed an optical investigation of direct injection (DI) hydrogen combustion under leaner mixture conditions. The study was conducted using a heavy-duty optical diesel engine modified for spark-ignition operation. Bottom-view natural flame luminosity and OH-PLIF imaging were conducted along with in-cylinder pressure measurements. Experiments were conducted at three air-excess ratios (3 3.4 and 3.8) with spark timings (ST) varied from − 15 ◦CA aTDC to − 30 ◦CA aTDC. Hydrogen injection ended at − 30 ◦CA aTDC with the start of injection adjusted accordingly to achieve the desired lambda conditions. The maximum IMEPg corresponded to the lowest COV of the IMEPg indicating optimal spark timing for lean DI hydrogen combustion. The optimized spark timing for λ = 3 λ = 3.4 and λ = 3.8 were occurred at − 25 ◦CA aTDC − 25 ◦CA aTDC and − 30 ◦CA aTDC respectively. The corresponding COV of IMEPg values were below 5 % indicating stable combustion. The flame kernel first initiates at the spark plug and then propagates toward the piston’s outer boundary however the flame propagation does not remain as a continuous front unlike port-fuel injected hydrogen combustion. The effect of fuel stratification is evident in combustion luminosity and OH-PLIF images showing pockets of varying intensity within the combustion chamber. Natural flame luminosity images reveal incomplete flame coverage and asymmetric combustion emphasizing the need for metal engine experiments to further quantify the unburned hydrogen and associated combustion losses.
Accelerated Numerical Simulations of Hydrogen Flames: Open-source Implementation of an Advanced Diffusion Model Library in OpenFOAM
Oct 2025
Publication
Here the OpenFOAM software with the dynamic load balancer library DLBFoam is investigated for computational fluid dynamics (CFD) simulations of different hydrogen (H2 ) flames. The benefits of DLBFoam for hydrogen have not been thoroughly investigated in the past. To explore this a new open-source diffusion model library FickianTransportFoam is implemented in this study. FickianTransportFoam includes species-specific constant Lewis number and mixture-averaged models with correction velocity to account for preferential diffusion. The model is first verified for one-dimensional (1D) premixed and non-premixed counterflow flames. Additionally four hydrogen/air flames are explored: (1) two-dimensional (2D) laminar freely propagating premixed flame (2) 2D axisymmetric laminar non-premixed jet flame (3) three-dimensional (3D) turbulent non-premixed swirling flame and (4) 3D turbulent premixed swirling flame. The main results and achievements regarding the implemented transport models are as follows. First the results from 2D freely propagating flame demonstrated thermodiffusively unstable flame formation using the mixture averaged model. The analytical and numerical dispersion relationships agree well for the linear instability growth phase. Second the model functionality is demonstrated for a laminar 2D jet case with conjugate heat transfer. Furthermore validation and grid sensitivity studies for the 3D turbulent flames are carried out. Third the computational benchmark for each configuration indicates a factor of ∼10-100 speed-up when utilizing DLBFoam. Finally the test cases and source codes for FickianTransportFoam are openly shared.
Optimal Sizing and Energy Management for Fuel Cell Electric Vehicles with 3D-ordered MEAs: A Pareto Frontier Study
Oct 2025
Publication
Fuel cell electric vehicles (FCEVs) are zero-emission but face cost and power density challenges. To mitigate these limitations a novel 3D-ordered nano-structured self-supporting membrane electrode assembly (MEA) has been developed. This paper investigates the optimal component sizing of the battery and fuel cell in FCEVs equipped with 3D-ordered MEAs integrating the energy management. To explore the trade-offs between component cost operational cost and fuel cell degradation the sizing and energy management problem is formulated into a multi-objective optimisation problem. A Pareto frontier (PF) study is conducted using the decomposed multi-objective evolutionary algorithm (MOEA/D) for a more diverse distribution of feasible solutions. The modular design of fuel cells is derived from a scaled and stressed experiment. After executing MOEA/D across the three aggressive driving cycles power source configurations are selected from the corresponding PFs based on objective trade-offs ensuring robustness of the overall system. The optimisation performance of the MOEA/D is compared with that of the multi-objective Particle Swarm Optimisation. In addition the selected powertrain configurations are evaluated and compared through standard and realworld driving cycles in a simulation environment. This paper also performs a sensitivity analysis to reveal the influence of diverse component unit costs and hydrogen price. The results indicate that the mediumsized configuration consisting of a 63.31 kW fuel cell stack and a 52.15 kWh battery pack delivers the best overall performance. It achieves a 26.71% reduction in component cost and up to 12.76% savings in hydrogen consumption across various driving conditions. These findings provide valuable insights into the design and optimisation of fuel cell systems for FCEVs.
Experimental Validation of DC-link Based Voltage Control Framework for Islanded Hydrogen DC Microgrids
Oct 2025
Publication
The integration of hydrogen technologies into islanded DC microgrids presents significant challenges in maintaining voltage stability and coordinating power flow under highly variable renewable energy conditions. This paper proposes a novel DC-link voltage control (DCVC) framework that incorporates adaptive droop control and autonomous operation algorithms to regulate fuel cells electrolysers and battery systems in a coordinated manner. Unlike conventional fixed-gain or priority-based methods the proposed adaptive control dynamically adjusts the droop coefficient in response to voltage deviations enhancing system stability and responsiveness. The control framework is validated on an industry-standard hydrogen DC microgrid platform developed at Griffith University featuring real-time implementation on a Raspberry Pi controller and comprehensive integration with solar wind wave and hydrogen energy sources. A small-signal stability analysis confirms that the proposed control ensures asymptotic voltage convergence under dynamic operating conditions. Experimental results across five case studies demonstrate that the proposed DCVC strategy ensures fast transient response minimises overshoot and maintains the DC-link voltage near the nominal 380 V under varying load and generation scenarios. The framework facilitates flexible energy sharing while ensuring safe hydrogen production and storage. It is also compatible with low-cost open-source hardware making it a scalable solution for remote and off-grid energy applications.
Techno-enviro-socio-economic Assessment and Sensitivity Analysis of an off-grid Tidal/Fuel Cell/Electrolyzer/Photovoltaic Hybrid System for Hydrogen and Electricity Production in Cameroon Coastal Areas
Oct 2025
Publication
Coastal regions in Cameroon including Douala Kribi Campo Dibamba and Limbe faced persistent electricity challenges driven by grid instability growing demand and dependence on fossil fuels. Solar resource availability was high but intermittent whereas tidal energy was predictable and energy-dense yet underused. This pilot delivers the first Cameroonian assessment of an off-grid tidal/PV/electrolyzer/hydrogen-storage/fuel-cell architecture explicitly co-optimizing electricity service and green hydrogen production and evaluating performance with a tri-metric economic lens (net present cost levelized cost of electricity and the levelized cost of hydrogen). The system was optimized to minimize net present cost (NPC) levelized cost of electricity (LCOE) levelized cost of hydrogen (LCOH) and three tidal-flow scenarios were analyzed to represent hydrokinetic variability. The design served households small businesses fishing activities schools and health facilities with a baseline demand of 389.50 kWh/day; surplus renewable power drove the electrolyzer to produce hydrogen for later reconversion in the fuel cell. Under the first scenario (1.25 m/s average speed) the optimal mix comprised 137 PV modules (600 W each) a 100 kW fuel cell six 40 kW tidal turbines six 10 kW electrolyzers a 19.5 kW converter and 41 hydrogen tanks (40 L each) yielding an NPC of US$ 2.16 million an LCOE of US$ 0.782/kWh and a LCOH of US$ 19.2/kg of hydrogen. The second scenario (1.47 m/s) required only 12 PV modules one electrolyzer and an 11.3 kW converter lowering costs to an NPC of US$ 1.52 million an LCOE of US$ 0.553/ kWh and a LCOH of US$ 15.4/kg of hydrogen. In the third scenario (1.61 m/s) the configuration shifted to 298 PV modules three tidal turbines eight electrolyzers and a 39.6 kW converter resulting in the highest NPC (US$ 2.47 million) and LCOE (US$ 0.901/kWh) with a LCOH of US$ 18.8/kg of hydrogen. The study also contributes a transparent component-wise employment indicator linking installed capacities/energies to jobs; deployment is expected to create about seven local jobs during installation and early operation tidal turbines (3) solar panels (1) electrolyzers (1) hydrogen tanks (1) and fuel cell (1) with additional minor operation and maintenance positions thereafter. Social analysis indicated improved energy access support for local livelihoods and job creation; environmental results confirmed clean operation with limited marine disturbance. A sensitivity study varying capital and replacement-cost multipliers showed robust performance across economic conditions. Taken together these contributions provide a decision-ready blueprint for coastal communities: a first-of-its-kind Cameroonian hybrid that quantifies both electricity and hydrogen costs (including feasible LCOH) and demonstrates socio-economic co-benefits offering a cost-effective pathway to strengthen energy security foster local development and reduce environmental impact.
Cutting-edge Advances in Hydrogen Applications for the Medical and Pharmaceutical Industries
Oct 2025
Publication
The adoption of clean hydrogen is expected to transform the global energy landscape reducing greenhouse gas emissions bridging gaps in renewable energy integration and driving innovation across multiple sectors. In the medical and pharmaceutical industries hydrogen offers unique opportunities for transformative progress. This review critically examines recent advances in three domains: hydrogen fuel cells as reliable scalable and sustainable energy solutions for hospitals; molecular hydrogen as a therapeutic and preventive medical gas particularly for brain disorders; and hydrogenation technologies for the efficient and sustainable pharmaceutical production. Despite encouraging advancements widespread adoption remains limited by economic constraints regulatory gaps and limited clinical evidence. Addressing these barriers through technological innovation largescale studies and life-cycle sustainability assessments is essential to translate hydrogen’s full potential into clinical and industrial practice. Responsible adoption of green hydrogen is poised to reshape the clinical approach to global health and enhance the quality of life for people worldwide.
Optical Investigation and combustion Analysis of Stratified Ammonia-hydrogen Pre-chamber Engine with Variable Injection Timing
Oct 2025
Publication
This study presents an experimental investigation of a direct injection ammonia-fuelled engine using hydrogen pre-chamber jet ignition. All tests have been conducted in an optically accessible combustion chamber that is installed in the head of a single-cylinder engine. The effect of ammonia injection timing on ignition and combustion characteristics was investigated with the timing varied from 165 CAD BTDC to 40 CAD BTDC. The experiments were conducted with a fixed spark timing of 14 CAD BTDC while ammonia injection duration was adjusted to maintain a main chamber global equivalence ratio of 0.6. Two pre-chamber nozzle configurations a single-hole and a multi-hole were tested. The results show that the later NH3 injection timing (40 CAD BTDC) significantly improved combustion with a peak in-cylinder pressure of 80 bar measured compared to a peak in-cylinder pressure of 50 bar with earlier injection (165 CAD BTDC). This study indicates the importance of optimising ammonia injection timing in order to enhance combustion stability and efficiency. The hydrogen pre-chamber jet ignition combined with a late ammonia injection is a promising approach for addressing the combustion challenges of ammonia as a zero-carbon fuel for maritime applications.
A Comparative Analysis of Conventional Thermal and Electrochemical Reforming Pathways for Hydrogen Production Towards Sustainable Aviation Fuels (SAF)
Oct 2025
Publication
H2 is increasingly recognized as a cornerstone of global decarbonization strategies including in hard-toabate sectors such as aviation. Its large-scale applicability remains limited owing to the limited diversity and maturity of low-carbon production pathways. Approximately 96% of global H2 production originates from non-renewable sources primarily through steam methane reforming (SMR) which remains the most commercially established route. Another critical barrier to the substitution of conventional aviation fuels lies in hydrogen storage as the current volumetric energy density and cryogenic storage requirements render onboard integration impractical for most aircraft configurations. To address these challenges this study developed a techno-economic and environmental benchmarking framework that compares conventional thermal reforming technologies (SMR autothermal and POX) with emerging electrochemical routes (water electrolysis and alcohol electro-oxidation) highlighting their potential roles in the transition toward sustainable aviation fuels (SAF). By normalizing efficiency energy intensity CO2 emissions and cost (USD kg 1 H2 and USD GJ 1 ) this study quantifies the trade-offs that define current and emerging pathways. SMR remains the industrial baseline (70%–85% thermal efficiency 1–2 USD kg−1 H2 9–12 kg CO2 kg−1 H2) whereas ethanol-based electrochemical reforming operates 0.3–0.9 V below conventional electrolysis achieving up to 40% lower electrical energy demand (∼2.4 kW h Nm−3 H2 with near-zero direct emissions. A sensitivity analysis demonstrates that a 60% reduction in catalyst cost or electricity prices below 0.03 USD (kW h)−1 could make electrochemical reforming cost-competitive with SMR. This study consolidates fragmented knowledge into a comprehensive roadmap that links catalyst performance and technology readiness for aviation decarbonization by integrating engineering metrics with policy and infrastructure perspectives to identify realistic transition pathways toward sustainable hydrogen and hybrid aviation fuels.
The Role of Hydrogen-based Local Energy Communities in the Development of Hydrogen Cities: A Systematic Review
Nov 2025
Publication
Hydrogen-based Local Energy Communities (LECs) play a pivotal role in modern energy systems and form the fundamental building blocks of hydrogen cities. This review provides a comprehensive assessment of how hydrogen-based LECs advance the hydrogen city concept by examining the technological economic environmental regulatory and social dimensions that shape the integration of green hydrogen into local energy networks. The paper explores the structure of hydrogen cities focusing on the role of multiple LECs in alignment with the European Union’s Clean Energy Package (CEP). Furthermore a case study and mathematical model are presented where the hydrogen city is modelled and the impact of Electric Parking Lot (EPL) and Hydrogen Parking Lot (HPL) management on the hydrogen city’s operation cost is evaluated. The results show that optimised EPL and HPL management can reduce overall operational costs by 5.53 % demonstrating the economic advantages of intelligent scheduling strategies in hydrogen cities.
Design of Hydrogen-Powered Mobile Emergency Power Vehicle with Soft Open Point and Appropriate Energy Management Strategy
Oct 2025
Publication
Zhigang Liu,
Wen Chen,
Shi Liu,
Yu Cao and
Yitao Li
Mobile emergency power supply vehicles (MEPSVs) powered by diesel engines or lithiumion batteries (LIBs) have become a viable tool for emergency power supply. However diesel-powered MEPSVs generate noise and environmental pollution while LIB-powered vehicles suffer from limited power supply duration. To overcome these limitations a hydrogen-powered MEPSV incorporating a soft open point (SOP) was developed in this study. We analyzed widely used operating scenarios for the SOP-equipped MEPSV and determined important parameters including vehicle body structure load capacity driving speed and power generation capability for the driving motor hydrogen fuel cell (FC) module auxiliary LIB module and SOP equipment. Subsequently we constructed an energy management strategy for the model for MEPSV which uses multiple energy sources of hydrogen fuel cells and lithium-ion batteries. Through simulations an optimal hydrogen consumption rate in various control strategies was validated using a predefined load curve to optimize the energy consumption minimization strategy and achieve the highest efficiency.
Enhancing Power-to-Hydrogen Flexibility Through Optimal Bidding in Nordic Energy Activation Market with Wind Integration
Oct 2025
Publication
The recent updates to the Single Day-Ahead Coupling (SDAC) framework in the European energy market along with new rules for providing manual frequency restoration reserve (mFRR) products in the Nordic Energy Activation Market (EAM) have introduced a finer Market Time Unit (MTU) resolution. These developments underscore the growing importance of flexible assets such as power-to-hydrogen (PtH) facilities in delivering system flexibility. However to successfully participate in such markets well-designed and accurate bidding strategies are essential. To fulfill this aim this paper proposes a Mixed Integer Linear Programming (MILP) model to determine the optimal bidding strategies for a typical PtH facility accounting for both the technical characteristics of the involved technologies and the specific participation requirements of the mFRR EAM. The study also explores the economic viability of sourcing electricity from nearby wind turbines (WTs) under a Power Purchase Agreement (PPA). The simulation is conducted using a case study of a planned PtH facility at the Port of Hirtshals Denmark. Results demonstrate that participation in the mFRR EAM particularly through the provision of downward regulation can yield significant economic benefits. Moreover involvement in the mFRR market reduces power intake from the nearby WTs as capacity must be reserved for downward services. Finally the findings highlight the necessity of clearly defined business models for such facilities considering both technical and economic aspects.
Toward Zero-emission Ferries: Integrating Systematic Review and Bibliometric Analysis Insights on Alternative Fuels and Policies
Nov 2025
Publication
The shipping industry aims to achieve full decarbonization at the European Union (EU) level by mid-century. Over the past decade various alternative fuels have been explored to address this goal. However challenges such as insufficient bunkering infrastructure technological immaturity and high costs have made shipowners hesitant to invest in“clean” propulsion systems. This study conducts a bibliometric analysis supported by a systematic literature review to map and critically synthesize current knowledge on alternative fuels for ferry decarbonization and their alignment with emissions reduction policies. Using the Greek ferry fleet as a representative case study the paper evaluates the regulatory framework and technical characteristics of various fuel options and examines their compatibility with different vessel categories. A qualitative comparative framework is introduced to link policy types with alternative fuel pathways offering original insights into policy—fuel alignment. The findings highlight methanol and green electricity (battery-electric systems) as highly promising solutions especially if battery technologies further advance in the coming years. Hydrogen also presents significant potential but is currently limited by high production costs and infrastructure requirements. Rather than presenting a quantitative decision-making model this review establishes the conceptual basis for such a framework in future research. This paper also offers innovative proposals to accelerate the adoption of zero-emission fuels addresses key gaps in existing research and provides insights for advancing ferry decarbonization.
A Two-Stage Optimal Dispatch Strategy for Electric-ThermalHydrogen Integrated Energy System Based on IGDT and Fuzzy Chance-Constrained Programming
Nov 2025
Publication
Na Sun,
Hongxu He and
Haiying Dong
To address the economic and reliability challenges of high-penetration renewable energy integration in electricity-heat-hydrogen integrated energy systems and support the dualcarbon strategy this paper proposes an optimal dispatch method integrating Information Gap Decision Theory (IGDT) and Fuzzy Chance-Constrained Programming (FCCP). An IES model coupling multiple energy components was constructed to exploit multi-energy complementarity. A stepped carbon trading mechanism was introduced to quantify emission costs. For interval uncertainties in renewable generation IGDT-based robust and opportunistic dispatch models were established; for fuzzy load uncertainties FCCP transformed them into deterministic equivalents forming a dual-layer “IGDT-FCCP” uncertainty handling framework. Simulation using CPLEX demonstrated that the proposed model dynamically adjusts uncertainty tolerance and confidence levels effectively balancing economy robustness and low-carbon performance under complex uncertainties: reducing total costs by 12.7% cutting carbon emissions by 28.1% and lowering renewable curtailment to 1.8%. This study provides an advanced decision-making paradigm for low-carbon resilient IES.
Effects of Hydrogen-rich Gas Injection on Combustion Characteristics in Blast Furnace Raceway and Thermal Load of Tuyere: A Numerical Simulation Study
Nov 2025
Publication
Hydrogen-rich gas (HRG) injection is a promising low-carbon solution for blast furnace ironmaking. This study conducted numerical simulations in the lower part of a blast furnace to analyze the combustion behavior of coinjected coke oven gas (COG) and pulverized coal (PC) within the raceway and the associated thermal load on the tuyere. A three-dimensional computational fluid dynamics model incorporating fluid–thermal–solid coupling and the GRI-Mech 3.0 chemical kinetic mechanism (validated for 300–2500 K) was established to simulate the lance–blowpipe–tuyere–raceway region. The simulation results revealed that moderate COG injection accelerated volatile release from PC and enlarged the high-temperature zone (>2000 K). However excessive COG injection intensified oxygen competition and shortened the residence time of PC ultimately decreasing the burnout rate. Notably although COG has high reactivity its injection did not cause an increase in tuyere temperature. By contrast the presence of an unburned gas layer near the upper wall of the tuyere and the existence of a strong convective cooling effect contributed to a reduction in tuyere temperature. An optimized cooling water channel was designed to enhance flow distribution and effectively suppress localized overheating. The findings of this study offer valuable technical insights for ensuring safe COG injection and advancing low-carbon steelmaking practices.
Joint Optimization Scheduling of Electric Vehicles and Electro–Olefin–Hydrogen Electromagnetic Energy Supply Device for Wind–Solar Integration
Nov 2025
Publication
In northern China the long winter heating period is accompanied by severe wind curtailment. To address this issue a joint optimization scheduling strategy of electric vehicles (EVs) and electro–olefin–hydrogen electromagnetic energy supply device (EHED) is proposed to promote deep wind–solar integration. Firstly the feasibility analysis of EVs participating in scheduling is conducted and the operation models of dispatchable EVs and thermal energy storage EHEDs within the scheduling period are established. Secondly a control strategy for the joint optimization scheduling of wind–solar farms EVs EHEDs and power grid is constructed. Then an economic dispatch model for joint optimization of EVs and EHEDs is established to minimize the system operation cost within the scheduling period and the deep wind–solar integration of the joint optimization model is studied by considering EVs under different demand responses. Finally the proposed model is solved by CPLEX solver. The simulation results show that the established joint optimization economic dispatch model of EV-EHEDs can improve the enthusiasm of dispatchable EVs to participate in deep wind–solar integration reduce wind curtailment power and decrease the overall system operation cost.
An Explainable Fault Diagnosis Algorithm for Proton Exchange Membrane Fuel Cells Integrating Gramian Angular Fields and Gradient-Weighted Class Activation Mapping
Nov 2025
Publication
Reliable operation of proton exchange membrane fuel cells (PEMFCs) is crucial for their widespread commercialization and accurate fault diagnosis is the key to ensuring their long-term stable operation. However traditional fault diagnosis methods not only lack sufficient interpretability making it difficult for users to trust their diagnostic decisions but also one-dimensional (1D) feature extraction methods highly rely on manual experience to design and extract features which are easily affected by noise. This paper proposes a new interpretable fault diagnosis algorithm that integrates Gramian angular field (GAF) transform convolutional neural network (CNN) and gradient-weighted class activation mapping (Grad-CAM) for enhanced fault diagnosis and analysis of proton exchange membrane fuel cells. The algorithm is systematically validated using experimental data to classify three critical health states: normal operation membrane drying and hydrogen leakage. The method first converts the 1D sensor signal into a two-dimensional GAF image to capture the temporal dependency and converts the diagnostic problem into an image recognition task. Then the customized CNN architecture extracts hierarchical spatiotemporal features for fault classification while Grad-CAM provides visual explanations by highlighting the most influential regions in the input signal. The results show that the diagnostic accuracy of the proposed model reaches 99.8% which is 4.18% 9.43% and 2.46% higher than other baseline models (SVM LSTM and CNN) respectively. Furthermore the explainability analysis using Grad-CAM effectively mitigates the “black box” problem by generating visual heatmaps that pinpoint the key feature regions the model relies on to distinguish different health states. This validates the model’s decision-making rationality and significantly enhances the transparency and trustworthiness of the diagnostic process.
State and Disturbance Estimation with Supertwisting Sliding Mode Control for Frequency Regulation in Hydrogen Based Microgrids
Nov 2025
Publication
This study considers the use of an enhanced super-twisting sliding mode control (STSMC) scheme via the incorporation of a hybrid extended state observer (ESO) and a higher order sliding mode observer (HOSMO) state estimation and disturbance observer (DO) based on exponential decay embedded via a tracking element in order to hasten the estimation of disturbance thus improving performance significantly. This scheme is employed to generate single and multiple control signals per agent based on the microgrid’s presented components such as energy storage devices and renewable energy sources (RESs) alongside the harness of a puma optimizer (PO) metaheuristics scheme to optimize each area regulator’s performance. The sliding surface incorporated is chosen based on desired control objectives. Adjusting the constricted area frequency and reducing tie-line power transfer fluctuations are considered the primary goals for frequency regulation in a multi-area power system. Also based on the presented simulations adequate performance in terms of minimum chattering low complexity fast convergence and adequate robustness has been achieved. Using various microgrid peripheral components such as a multi-terminal soft open point (SOP) with a dedicated terminal for hydrogen energy storage alongside the proposed enhanced STSMC the frequency change and power transfer rate of change are maintained within the range of ×10−6 values substantially preserving proper performance compared to other simulated scenarios. In regard to the final simulated case involving SOP the following has been achieved: steady state errors of 2.538×10−6 Hz for ΔF1 3.125×10−6 Hz for ΔF2 and 1.920×10−6 p.u for ΔPtie alongside peak disturbance overshoot reduction in comparison to stochastic case of 99.580% 99.605% and 99.771% for same mentioned elements respectively. Also a reduction in peak disturbance undershoot of 95.589% 99.547% and 99.573% respectively has been achieved. Thus the enhanced STSMC can effectively mitigate frequency fluctuations and tie-line power transfer abnormalities.
Advancing the Energy Transition in the Steel Industry: A Game-theoretic Bilevel Approach for Green Hydrogen Supply Chains
Sep 2025
Publication
Green hydrogen is essential for advancing the energy transition as it is regarded as a CO2-neutral flexible and storable energy carrier. Particularly in steel production which is known for its high energy intensity hydrogen has great potential to replace conventional energy sources. In a game-theoretic bi-level optimization model involving a power plant operator and a steel company we investigate in which situations the production and use of green hydrogen is advantageous from an economic and ecological point of view. Through an extensive case study based on a realworld scenario we can observe that hydrogen production can serve as a profitable and flexible secondary income opportunity for the power plant operator and help avoid curtailment and spot market losses. On the other hand the steel manufacturer can reduce CO2 emissions and associated costs while also meeting the growing customer demand for low-carbon products. However our findings also highlight important trade-offs and uncertainties. While lower electricity generation costs or improved electrolyzer efficiency enhance hydrogen’s competitiveness increases in coal and CO2 emission prices do not always result in greater hydrogen adoption. This is due to the persistent reliance on a non-replaceable share of coal in steel production which raises the overall cost of both low-carbon and carbon-intensive steel. The model further shows that consumer demand elasticity plays a critical role in determining hydrogen uptake. These insights underscore the importance of not only reducing hydrogen costs but also designing supportive policies that address market acceptance and the full cost structure of green industrial products.
Process Analysis and Techno-economic Comparison of Aviation Biofuel Production via Microbial Oil and Ethanol Upgrading
Oct 2025
Publication
The transport sector is the largest source of greenhouse gases in the EU after the energy supply one contributing approximately 27% of total emissions. Although decarbonization pathways for light-duty transport are relatively well established heavy-duty transport shipping and aviation emissions are difficult to eliminate through electrification. In particular the aviation sector is strongly dependent on liquid hydrocarbons making the development of sustainable aviation fuels (SAFs) a critical priority for achieving long-term climate targets. This study evaluates four biomass-to-liquid pathways for producing jet-like SAF from lignocellulosic biomass: (1) triacylglycerides (TAGs) production from syngas fermentation (2) TAGs production from sugar fermentation (3) ethanol production from syngas fermentation and (4) ethanol production from sugar fermentation. These pathways are simulated using Aspen Plus™ and the mass and heat balances obtained are used to assess their technical performance (e.g. carbon utilization energetic fuel efficiency) and techno-economic viability (e.g. production cost capital investment). Pathway (4) demonstrated the highest jet fuel selectivity (63%) and total carbon utilization (32.5%) but at higher power demands. Pathway (1) was self-sufficient in energy due to internal syngas utilization but exhibited lower carbon efficiencies. Cost analysis revealed that microbial oil-based pathways were restrained by higher hydrogen demands and lower product selectivity compared to ethanol-based routes. However with advancements in microbial oil production efficiency and reduced water usage these pathways could become competitive.
Towards Green and Smart Ports: A Review of Digital Twin and Hydrogen Applications in Maritime Management
Oct 2025
Publication
Modern ports are pivotal to global trade facing increasing pressures from operational demands resource optimization complexities and urgent decarbonization needs. This study highlights the critical importance of digital model adoption within the maritime industry particularly in the port sector while integrating sustainability principles. Despite a growing body of research on digital models industrial simulation and green transition a specific gap persists regarding the intersection of port management hydrogen energy integration and Digital Twin (DT) applications. Specifically a bibliometric analysis provides an overview of the current research landscape through a study of the most used keywords while the document analysis highlights three primary areas of advancement: optimization of hydrogen storage and integrated energy systems hydrogen use in propulsion and auxiliary engines and DT for management and validation in maritime operations. The main outcome of this research work is that while significant individual advancements have been made across critical domains such as optimizing hydrogen systems enhancing engine performance and developing robust DT applications for smart ports a major challenge persists due to the limited simultaneous and integrated exploration of them. This gap notably limits the realization of their full combined benefits for green ports. By mapping current research and proposing interdisciplinary directions this work contributes to the scientific debate on future port development underscoring the need for integrated approaches that simultaneously address technological environmental and operational dimensions.
Simulation of the Hydrogen Railway Engine Performance Under Different Load Conditions and Control Parameters
Oct 2025
Publication
The article examines the use of hydrogen fuel as an alternative to traditional diesel fuel for internal combustion engines (ICE) in railway applications. The main objective of the study is to analyze the operational consumption of hydrogen fuel based on the mathematical modeling of the working cycle of the EMD 12-645E3C engine installed on CIE 071 locomotives used in freight and passenger service. The article provides information on the design features of the EMD 12-645E3C engine its technical parameters and the results of bench tests. The indicator parameters of the engine at various controller positions are determined and analyzed and the results of mathematical modeling of its operation on hydrogen fuel are presented. Particular attention is paid to changes in indicator parameters including the maximum combustion pressure and the peak gas temperature in the cylinder as well as comparing the mass consumption of diesel and hydrogen fuel. The study results demonstrate that the use of hydrogen allows the engine to maintain effective power across all operational modes while simultaneously reducing energy costs up to 8%. In this case the pressure and temperature of the gases in the cylinder increased by 3–6% and 5–8%. Recommendations are also provided regarding technical challenges associated with transitioning to hydrogen fuel including the modernization of the combustion chamber fuel system and safety system.
Assessment of the Use of a Passive Pre-Chamber in a Marine Engine Fueled with Ammonia–Hydrogen Mixtures
Oct 2025
Publication
This study investigates the combustion process in a marine spark-ignition engine fueled with an ammonia–hydrogen blend (15% hydrogen by volume) using a passive pre-chamber. A 3D-CFD model supported by a 1D engine model was employed to analyze equivalence ratios between 0.7 and 0.9 and pre-chamber nozzle diameters from 7 to 3 mm. Results indicate that combustion is consistently initiated by turbulent jets but at an equivalence ratio of 0.7 the charge combustion is incomplete. For lean mixtures reducing nozzle size improves flame propagation although not sufficiently to ensure stable operation. At an equivalence ratio of 0.8 reducing the nozzle diameter from 7 to 5 mm advances CA50 by about 6 CAD while further reduction causes minor variations. At richer conditions nozzle diameter plays a negligible role. Optimal performance was achieved with a 7 mm nozzle at equivalence ratio 0.8 delivering about 43% efficiency and 1.17 MW per cylinder.
Development of DC-DC Converters for Fuel-Cell Hybrid Power Systems in a Lift-Cruise Unmanned Aerial Vehicle
Oct 2025
Publication
Lift–cruise-type unmanned aerial vehicles (UAVs) powered by hydrogen fuel cells often integrate secondary energy storage devices to improve responsiveness to load fluctuations during different flight phases which necessitates an efficient energy management strategy that optimizes power allocation among multiple power sources. This paper presents an innovative fuel cell DC–DC converter (FDC) design for the hybrid power system of a lift–cruise-type UAV comprising a multi-stack fuel cell system and a battery. The novelty of this work lies in the development of an FDC suitable for a multi-stack fuel cell system through a dual-input single-output converter structure and a control algorithm. To integrate inputs supplied from two hydrogen fuel cell stacks into a single output a controller with a single voltage controller–dual current controller structure was applied and its performance was verified through simulations and experiments. Load balancing was maintained even under input asymmetry and fault-tolerant performance was evaluated by analyzing the FDC output waveform under a simulated single-stack input failure. Furthermore under the assumed flight scenarios the results demonstrate that stable and efficient power supply is achieved through power-supply mode switching and application of a power distribution algorithm.
Application and Research Progress of Mechanical Hydrogen Compressors in Hydrogen Refueling Stations: Structure, Performance, and Challenges
Nov 2025
Publication
The hydrogen energy industry is rapidly developing positioning hydrogen refueling stations (HRSs) as critical infrastructure for hydrogen fuel cell vehicles. Within these stations hydrogen compressors serve as the core equipment whose performance and reliability directly determine the overall system’s economy and safety. This article systematically reviews the working principles structural features and application status of mechanical hydrogen compressors with a focus on three prominent types based on reciprocating motion principles: the diaphragm compressor the hydraulically driven piston compressor and the ionic liquid compressor. The study provides a detailed analysis of performance bottlenecks material challenges thermal management issues and volumetric efficiency loss mechanisms for each compressor type. Furthermore it summarizes recent technical optimizations and innovations. Finally the paper identifies current research gaps particularly in reliability hydrogen embrittlement and intelligent control under high-temperature and high-pressure conditions. It also proposes future technology development pathways and standardization recommendations aiming to serve as a reference for further R&D and the industrialization of hydrogen compression technology.
An Overview of Development and Challenges in the Use of Hydrogen as a Fuel for a Dual-Fuel Diesel Engine
Nov 2025
Publication
The gradual exhaustion of fossil fuel reserves along with the adverse effects of their consumption on global climate drives the need for research into alternative energy sources that can meet the growing demand in a sustainable and eco-friendly way. Among these hydrogen stands out as one of the most promising options for the automotive sector being the cleanest available fuel and capable of being produced from renewable resources. This paper reviews the existing literature on compression ignition engines operating in a dualfuel configuration where diesel serves as the ignition source and hydrogen is used to enhance the combustion process. The reviewed studies focus on engine systems with hydrogen injection into the intake manifold. The investigations analyzed the influence of hydrogen energy fraction on combustion characteristics engine performance combustion stability and exhaust emissions in diesel/hydrogen dual-fuel engines operating under full or near-full-load conditions. The paper identifies the main challenges hindering the widespread and commercial application of hydrogen in diesel/hydrogen dual-fuel engines and discusses potential methods to overcome the existing barriers in this area.
Life Cycle of Fuel Cells: From Raw Materials to End-of-Life Management
Nov 2025
Publication
Fuel cells are highly efficient electrochemical devices that convert the chemical energy of fuel directly into electrical energy while generating minimal pollutant emissions. In recent decades they have established themselves as a key technology for sustainable energy supply in the transport sector stationary systems and portable applications. In order to assess their real contribution to environmental protection and energy efficiency a comprehensive analysis of their life cycle Life Cycle Assessment (LCA) is necessary covering all stages from the extraction of raw materials and the production of components through operation and maintenance to decommissioning and recycling. Particular attention is paid to the environmental challenges associated with the extraction of platinum catalysts the production of membranes and waste management. Economic aspects such as capital costs the price of hydrogen and maintenance costs also have a significant impact on their widespread implementation. This manuscript presents detailed mathematical models that describe the electrochemical characteristics energy and mass balances degradation dynamics and cost structures over the life cycle of fuel cells. The models focus on proton exchange membrane fuel cells (PEMFCs) with possible extensions to other types. LCA is applied to quantify environmental impacts such as global warming potential (GWP) while the levelized cost of electricity (LCOE) is used to assess economic viability. Particular attention is paid to the sustainability challenges of platinum catalyst extraction membrane production and end-of-life material recovery. By integrating technical environmental and economic modeling the paper provides a systematic perspective for optimizing fuel cell deployment within a circular economy.
Optimal Dispatch Model for Hybrid Energy Storage in Low-Carbon Integrated Energy Systems
Nov 2025
Publication
Integrated Energy Systems (IESs) which leverage the synergistic coordination of electricity heat and gas networks serve as crucial enablers for a low-carbon transition. Current research predominantly treats energy storage as a subordinate resource in dispatch schemes failing to simultaneously optimise IES economic efficiency and storage operators’ profit maximisation thereby overlooking their potential value as independent market entities. To address these limitations this study establishes an operator-autonomous management framework incorporating electrical thermal and hydrogen storage in IESs. We propose a joint optimal dispatch model for hybrid energy storage systems in low-carbon IES operation. The upper-level model minimises total system operation costs for IES operators while the lower-level model maximises net profits for independent storage operators managing various storage assets. These two levels are interconnected through power price and carbon signals. The effectiveness of the proposed model is verified by setting up multiple scenarios for example analysis.
Hydrogen-Rich Gaseous Mixture for Enhanced Combustion in a Flex-Fuel Engine: An Experimental Analysis
Nov 2025
Publication
This experimental study examines the effect of adding a hydrogen-enriched synthetic gaseous mixture (HGM’) on the combustion and fuel conversion efficiency of a singlecylinder research engine (SCRE). The work assesses the viability of using this mixture as a supplemental fuel for flex-fuel engines operating under urban driving cycling conditions. An SCRE the AVL 5405 model was employed operating with ethanol and gasoline as primary fuels through direct injection (DI) and a volumetric compression ratio of 11.5:1. The HGM’ was added in the engine’s intake via fumigation (FS) with volumetric proportions ranging from 5% to 20%. The tests were executed at 1900 rpm and 2500 rpm engine speeds with indicated mean effective pressures (IMEPs) of 3 and 5 bar. When HGM’s 5% v/v was applied at 2500 rpm the mean indicated effective pressure of 3 bar was observed. A decrease of 21% and 16.5% in the ISFC was observed when using gasoline and ethanol as primary fuels respectively. The usage of an HGM’ combined with gasoline or ethanol proved to be a relevant and economically accessible strategy in the improvement of the conversion efficiency of combustion fuels once this gaseous mixture could be obtained through the vapor-catalytic reforming of ethanol giving up the use of turbochargers or lean and ultra-lean burn strategies. These results demonstrated the potential of using HGM’ as an effective alternative to increase the efficiency of flex-fuel engines.
Hydrogen Utilization for Decarbonizing the Dairy Industry: A Techno-economic Scenario Analysis
Nov 2025
Publication
This study investigates the integration of on-site green hydrogen as a substitute for methane in steam generation in the dairy industry specifically in the production of Parmigiano Reggiano cheese. This represents a novel application of green hydrogen in industrial dairy processing with the potential to reduce greenhouse gas emissions. Hydrogen is assumed to be generated via electrolysis powered by photovoltaic energy. A comprehensive techno-economic assessment was conducted with simulations covering key design variables such as hydrogen fraction in steam production photovoltaic panel orientation and storage pressure. A wide range of scenarios was defined in order to account for variability in system structures and performance and a comprehensive economic assessment was then carried out using a Monte Carlo simulation approach and a sensitivity analysis. Results indicate that in all scenarios the net present value over a 15-year period remains negative when benefits are limited to methane savings. Indeed the high capital expenditure associated with hydrogen systems presents a major barrier. The most favorable cases occur at low hydrogen shares with seasonal storage while full conversion to hydrogen maximizes CO2 abatement but is least economical. With public funding the emissions saved per euro of public support range from 1.58 to 2.14 kg CO2eq/€.
Decarbonization of Hard-to-abate Industries under Water Constraints via Renewable Hydrogen Infrastructure Planning
Nov 2025
Publication
Achieving global decarbonization is essential to mitigate climate change yet heat-intensive industries remain challenging to decarbonize through electrification alone. Green hydrogen offers a clean alternative to replace fossil fuels and fossil fuel–based hydrogen but its deployment requires careful planning and robust economic assessment. This study addresses the optimal design of a green hydrogen supply chain in a Mediterranean region where ceramics and cement dominate as energy-intensive industries while oil refining is the main consumer of fossil fuel–based hydrogen. The region also faces freshwater scarcity due to its climate and the high demand for water from tourism and agriculture. A Mixed-Integer Linear Programming (MILP) model is developed to minimize the total cost of supplying green hydrogen by determining the optimal size and location of renewable energy sources integrating desalinated seawater from existing desalination plants as feedstock and designing the infrastructure connecting production storage and demand centers. The cost-optimal configuration includes 3.4 GW of PEM electrolyzers requiring 41.1 m3 /h of desalinated seawater supplied by existing desalination plants along with 5.1 GW of wind and 12 GW of solar power as renewable energy sources for large-scale hydrogen production. Results show that supplying green hydrogen to these industries can avoid approximately 4.4 million tons of CO2 emissions annually achieving a levelized cost of hydrogen (LCOH) of $2.18/kg for the period 2030–2050. Beyond this case study the proposed framework provides a replicable methodology for planning hydrogen-based energy systems in regions facing similar water and decarbonization challenges.
Technical and Environmental Assessment of New Green Iron Production Strategies using Hydrogen
Nov 2025
Publication
In order to assess the decarbonization potential and overall environmental benefits of new reduction pathways in the ironmaking industry using hydrogen to produce Direct Reduced Iron (DRI) a coupled approach combining process simulation for rigorous technical and energy evaluation of iron ore conversion and Life Cycle Assessment (LCA) for environmental assessment was developed and extended to two alternative renewable heating strategies: (i) electric gas heating and (ii) solar reactor heating. The entire hydrogen-based ironmaking process including conversion in a shaft reactor gas and solid heating gas recycling and electrolysis was therefore simulated. The hydrogen-based reduction of iron ores in the shaft reactor was modeled using a rigorous reactor model describing the reduction of multi-layer iron ore pellets in countercurrent gas–solid moving beds with the particularity of representing the dual influence of particle size and temperature on conversion. The remainder of the process including gas recycling and hydrogen production was simulated using ProSim software. The hydrogen-based green ironmaking scenarios were then compared to MIDREX NG a leading natural gas-based reduction technology. Hydrogen-based scenarios powered by the French electricity mix reduce carbon footprints by 53 % for electric gas heating and 57 % for solar reactor heating potentially reaching 82 % (− 0.79 kgCO2-eq/kgDRI) with low-carbon electricity (hydro nuclear). Compared to MIDREX NG the energy requirements of both hydrogen-based scenarios are primarily determined by the use of electricity for hydrogen production illustrating the importance of hydrogen production for the assessment of future hydrogen-based green ironmaking.
Heat Transfer Enhancement in Regenerative Cooling Channels: Numerical Analysis of Single- and Double-row Cylindrical Ribs with Supercritical Hydrogen
Nov 2025
Publication
The thermal protection of rocket engine combustion chambers presents a critical challenge in supersonic flight applications. This study numerically investigates the enhancement of heat transfer and coolant flow characteristics in regenerative cooling channels through cylindrical rib integration employing ANSYS Fluent with SST k-ω turbulence modeling to evaluate single- and double-row configurations (0.75–1.25 mm diameter) under supercritical hydrogen conditions (3 MPa 300 K inlet). Results demonstrate that rib-induced turbulence disrupts thermal boundary layers with a 1.25 mm single-row design achieving a 13.67 % reduction in peak wall temperature compared to smooth channels while double-row arrangements show diminishing returns due to increased flow resistance. The thermal performance factor (η = (Nu/Nu₀)/(f/f₀) 1/3) reveals Case 3′s superiority (21.88 % improvement over the smooth channel configuration) in balancing heat transfer enhancement against pressure drop penalties (9.23–20.93 % for single-row 8.26–18.7 % for double-row). Notably density-driven flow acceleration near heated walls mitigates pressure losses through localized viscosity reduction. Furthermore cylindrical ribs reduce thermal stratification by up to 30 % in single-row configurations with double-row designs providing additional temperature homogenization at the cost of increased flow resistance. These findings offer critical insights for optimizing rib-enhanced cooling systems in high-performance rocket engines achieving simultaneous thermal efficiency and hydraulic performance improvements.
Flame Curvature in Heat-loss-affected Lean Hydrogen Flames: A One-dimensional Manifold Approach
Oct 2025
Publication
Curvature effects are incorporated into a one-dimensional composition-space formulation of a non-unity Lewis number lean premixed flame with strong heat loss. The results of this new canonical problem successfully compare with direct numerical simulations (DNS) of a lean hydrogen-air flame propagating in a narrow channel with heat conduction through the confining plates. The complex dynamics of the flame front consisting of isolated flame kernels are analyzed through the various terms arising from the projection of the fuel and energy equations onto a moving scalar reference frame attached to the reaction zone. Novelty and significance statement A novel one-dimensional flame model incorporating curvature and differential diffusion effects is introduced to address non-unity Lewis number lean premixed flames with strong heat loss. This canonical flame model arises from the projection of temperature and fuel gradient magnitude onto composition space. The framework is employed to analyze flame front dynamics and identify the reaction zones governing flame kernel propagation and heat release. The composition-space flame structure shows strong agreement between the canonical problem and direct numerical simulations (DNS) of a lean hydrogen-air flame propagating in a narrow channel with heat conduction.
Thermal Energy Integration and Optimization in a Biomass-fueled Multi-generation System for Power, Hydrogen, and Freshwater Production
Nov 2025
Publication
This work investigates a biomass-driven multi-generation system designed for simultaneous power freshwater and hydrogen production addressing the interlinked energy-waterenvironment nexus. The configuration integrates Brayton supercritical carbon dioxide (SCO2) organic Rankine cycle (ORC) and thermoelectric generator (TEG) subsystems to maximize utilization of biomass-derived syngas. The recovered energy drives a reverse osmosis (RO) desalination unit for freshwater production and an alkaline electrolyzer for hydrogen generation followed by two-stage compression for storage. Under baseline conditions the system generates 1.99 MW of electricity 9.38 kg/h of hydrogen and 88.6 m3 /h of freshwater with an overall exergetic efficiency of 20.25 % emissions intensity of 0.85 kg/kWh and a payback period of 5.87 years. The Brayton cycle accounts for 49.3 % of the total cost rate while the gasifier exhibits the highest exergy destruction at 46 %. Sensitivity analyses show that varying biomass moisture content (10–30 %) and operating temperatures (700–900 ◦C) significantly influence system performance. Using a data-driven optimization framework that combines artificial neural networks (ANN) and a genetic algorithm (GA) the system’s exergetic efficiency improves to 21.76 % freshwater output rises to 90.96 m3 /h and emissions intensity decreases to 0.877 kg/kWh. Additionally optimization reduces the total cost rate by 2.71 % leading to a payback period of 5.4 years and enhances the system’s overall performance by 12.64 %.
Optimal Possibilistic-robust Operation of Multi-energy Microgrids Considering Infrastructure Hydrogen Storage Capability
Nov 2025
Publication
In sustainable energy transitions the utilization of hydrogen is crucial providing flexibility in the operation of net-zero emission renewable-based energy systems. This paper presents a study on the optimal operation of netzero emission multi-energy future microgrids that utilize hydrogen as an alternative fuel instead of natural gas. The electrolyzers’ output is injected into the hydrogen grid to meet demand or converted back to electricity later using generating units owing to the storage capability of pipes called linepack. For this purpose a detailed mathematical model is developed to simulate the main characteristics of grids (e.g. voltage current hydrogen flow and pressure) as well as various components (e.g. renewable systems electrolyzers and hydrogen-fired units). To become more realistic a possibilistic-robust approach is developed to account for the uncertainty arising from the lack of real-world implementation. By representing a case study a test is performed to evaluate the possibility of employing a low-pressure gas grid to meet the demand for hydrogen. After that the effects of electrolyzers are analyzed in the presence and absence of the uncertainty consideration approach. The result indicates that despite hydrogen’s lower energy density compared to natural gas it is still feasible to satisfy the same energy demand level considering the technical characteristics of the grid. The integration of electrolyzers can reduce wind curtailment by 2 % and supplement hydrogen demand by 50 %. A higher level of conservatism in the possibilistic-robust approach leads to an increase in the mean value of the objective function and a reduction in the standard deviation under the realization of uncertain parameters which provides the decisionmakers with a more realistic insight.
OH* Chemiluminescence in Non-premixed Industrial Natural Gas/hydrogen Flames under Air-fuel and Oxy-fuel Conditions: Kinetic Modeling and Experimental Validation
Oct 2025
Publication
The application of OH* chemiluminescence diagnostics is becoming increasingly prevalent in the combustion characterization of hydrogen. As the current literature is lacking a systematic study of OH* chemiluminescence in non-premixed turbulent natural gas (NG) and hydrogen (H2 ) flames the present work was designed to address this research gap. Therefore extensive experiments were performed on a semi-industrial burner operating at 50–100 kW in NG/H2–Air/O2 combustion modes which were complemented by comprehensive numerical simulations including 1D laminar counterflow diffusion flamelet calculations and full 3D CFD simulations of the semi-industrial furnace setup. In this way an OH* chemistry model is presented that accurately predicts the global reaction zone characteristics and their difference between CH4 and H2 in air-fired and oxygen-fired flames. The comprehensive numerical approach in conjunction with the subsequent study of different operating conditions yielded novel insights into both combustion modeling and the underlying thermochemical phenomena providing an essential contribution to the transition of the thermal energy sector towards hydrogen as an alternative carbon-free fuel.
Towards the Decarbonization of the Maritime Industry: Design of a Novel Methodology for the Sustainable Strategy Assessment
Oct 2025
Publication
The growing concern about the increase in European Union (EU)’s total CO2 emissions due to maritime activities and the ambitious goal of net zero emissions they are asked to fulfil by 2050 are leading the way to the adoption of new sustainable strategies. In this article a novel methodology for the classification of the sustainable actions is proposed. Moreover new indicators have been designed to compare the level of sustainable development of each port. Among them a new coefficient for the assessment of the Ports’ Potential Sustainability (PPS) have been designed. Main results showed that 56% of the actions were in the improvement and environmentally sustainable group while 19% were shift-economic actions related to the installation of technologies. As a matter of the fact all European ports under analysis have adopted cold ironing system which can reduce up to 4% of the global shipping emissions. Similarly 50% of them have already integrated renewables energies and prioritize equipment electrification in their processes. Finally the most relevant projects to optimize the energy consumption of daily operations and the main challenges that still need to be addressed have been analyzed showing the current trends maritime sector is undertaking to advance towards the sustainable development.
Life Cycle and Economic Viability Assessment of Clean Hydrogen as a Fuel in Corn Drying
Oct 2025
Publication
This study presents a comparative life cycle and economic assessment of using clean hydrogen as a sustainable alternative to natural gas and propane for corn grain drying. The study compares the environmental performance limited to GWP100 and cost-effectiveness of hydrogen from various renewable sources (hydro wind solar) and plasma pyrolysis of natural gas against conventional fossil fuels under two delivery scenarios: pipeline and trucking. A life cycle assessment is conducted using Open LCA to quantify the carbon intensity of each fuel from cradle to combustion at multiple energy requirements based on four burner efficiencies across each scenario. In parallel economic analysis is conducted by calculating the fuel cost required per ton of dried corn grains at each efficiency across both scenarios. The results indicate that green hydrogen consistently outperforms current fuels in terms of emissions but it is generally more expensive at lower burner efficiencies and in trucking scenarios. However the cost competitiveness of green hydrogen improves significantly at higher efficiency and with pipeline infrastructure development it can become more economical when compared to propane. Hydrogen produced via plasma pyrolysis offers high environmental and economic costs due to its electricity and natural gas requirements. Sensitivity analysis further explores the impact of a 50% reduction in hydrogen production and transportation costs revealing that hydrogen could become a viable option for grain drying in both pipeline and trucking scenarios. This study highlights the long-term potential of hydrogen in reducing carbon emissions and offers insights into the economic feasibility of hydrogen adoption in agricultural drying processes. The findings suggest that strategic investments in hydrogen infrastructure could significantly enhance the sustainability of agricultural practices paving the way for a greener future in food production.
Hydrogen Strategies Under Uncertainty: Risk-Averse Choices for Green Hydrogen Pathways
Oct 2025
Publication
The last decade has been characterized by a growing environmental awareness and the rise of climate change concerns. Continuous advancement of renewable energy technologies in this context has taken a central stage on the global agenda leading to a diverse array of innovations ranging from cutting-edge green energy production technologies to advanced energy storage solutions. In this evolving context ensuring the sustainability of energy systems—through the reduction of carbon emissions enhancement of energy resilience and responsible resource integration—has become a primary objective of modern energy planning. The integration of hydrogen technologies for power-to-gas (P2G) and power-topower (P2P) and energy storage systems is one of the areas where the most remarkable progress is being made. However real case implementations are lagging behind expectations due to large-scale investments needed which under high energy price uncertainty act as a barrier to widespread adoption. This study proposes a risk-averse approach for sizing an Integrated Hybrid Energy System considering the uncertainty of electricity and gas prices. The problem is formulated as a mixed-integer program and tested on a real-world case study. The analysis sheds light on the value of synergies and innovative solutions that hold the promise of a cleaner more sustainable future for generations to come.
Modeling Hydrogen-Assisted Combustion of Liquid Fuels in Compression-Ignition Engines Using a Double-Wiebe Function
Oct 2025
Publication
This article discusses the potential of using the double-Wiebe function to model combustion in a compression-ignition engine fueled by diesel fuel or its substitutes such as hydrotreated vegetable oil (HVO) and rapeseed methyl ester (RME) and hydrogen injected into the engine intake manifold. The hydrogen amount ranged from 0 to 35% of the total energy content of the fuels burned. It was found that co-combustion of liquid fuel with hydrogen is characterized by two distinct combustion phases: premixed and diffusion combustion. The premixed phase occurring just after ignition is characterized by a rapid combustion rate which increases with an increase in hydrogen injected. The novelty in this work is the modified formula for a double-Wiebe function and the proposed parameters of this function depending on the amount of hydrogen added for co-combustion with liquid fuel. To model this combustion process the modified double-Wiebe function was proposed which can model two phases with different combustion rates. For this purpose a normalized HRR was calculated and based on this curve coefficients for the double-Wiebe function were proposed. Satisfactory consistency with the experiment was achieved at a level determined by the coefficient of determination (R-squared) of above 0.98. It was concluded that the presented double-Wiebe function can be used to model combustion in 0-D and 1-D models for fuels: RME and HVO with hydrogen addition.
Insights from Swirl Number and Ambient Pressure Variations with a Hydrogen/Ammonia Swirl Stabilized Diffusion Flame
Oct 2025
Publication
Contemporary research into decarbonized fuels such as H2/NH3 has highlighted complex challenges with applied combustion with marked changes in thermochemical properties leading to significant issues such as limited operational range flashback and instability particularly when attempts are made to optimize emissions production in conventional lean-premixed systems. Non-premixed configurations may address some of these issues but often lead to elevated NOx production particularly when ammonia is retained in the fuel mixture. Optimized fuel injection and blending strategies are essential to mitigate these challenges. This study investigates the application of a 75 %/25 %mol H2/NH3 blend in a swirl-stabilized combustor operated at elevated conditions of inlet temperature (500 K) and ambient pressure (0.11–0.6 MPa). A complex nonmonotonic relationship between swirl number and increasing ambient combustor pressure is demonstrated highlighting the intricate interplay between swirling flow structures and reaction kinetics which remains poorly understood. At medium swirl (SN = 0.8) an increase in pressure initially reduces NO emissions diminishing past ~0.3 MPa with an opposing trend evident for high swirl (SN = 2.0) as NO emissions fall rapidly when combustor pressure approaches 0.6 MPa. High-fidelity numerical modeling is presented to elucidate these interactions in detail. Numerical data generated using Detached Eddy Simulations (DES) were validated against experimental results to demonstrate a change in flame anchoring on the axial shear layer and marked change in recirculated flow structure successfully capturing the features of higher swirl number flows. Favorable comparisons are made with optical data and a reduction in NO emissions with increasing pressure is demonstrated to replicate changes to the swirling flame chemical kinetics. Findings provide valuable insights into the combustion behavior of hydrogen-rich ammonia flames contributing to the development of cleaner combustion technologies.
Hybrid Renewable Energy Systems for Off-Grid Electrification: A Comprehensive Review of Storage Technologies, Metaheuristic Optimization Approaches and Key Challenges
Nov 2025
Publication
Hybrid Renewable Energy Systems (HRESs) are a practical solution for providing reliable low-carbon electricity to off-grid and remote communities. This review examines the role of energy storage within HRESs by systematically comparing electrochemical mechanical thermal and hydrogen-based technologies in terms of technical performance lifecycle cost operational constraints and environmental impact. We synthesize findings from implemented off-grid projects across multiple countries to evaluate real-world performance metrics including renewable fraction expected energy not supplied (EENS) lifecycle cost and operation & maintenance burdens. Special attention is given to the emerging role of hydrogen as a long-term and cross-sector energy carrier addressing its technical regulatory and financial barriers to widespread deployment. In addition the paper reviews real-world implementations of off-grid HRES in various countries summarizing practical outcomes and lessons for system design and policy. The discussion also includes recent advances in metaheuristic optimization algorithms which have improved planning efficiency system reliability and cost-effectiveness. By combining technological operational and policy perspectives this review identifies current challenges and future directions for developing sustainable resilient and economically viable HRES that can accelerate equitable electrification in remote areas. Finally the review outlines key limitations and future directions calling for more systematic quantitative studies long-term field validation of emerging technologies and the development of intelligent Artificial Intelligence (AI)-driven energy management systems within broader socio-techno-economic frameworks. Overall this work offers concise insights to guide researchers and policymakers in advancing the practical deployment of sustainable and resilient HRES.
Hydrogen Blending as a Transitional Solution for Decarbonizing the Jordanian Electricity Generation Sector
Nov 2025
Publication
While renewable energy deployment has accelerated in recent years fossil fuels continue to play a dominant role in electricity generation worldwide. This necessitates the development of transitional strategies to mitigate greenhouse gas emissions from this sector while gradually reducing reliance on fossil fuels. This study investigates the potential of blending green hydrogen with natural gas as a transitional solution to decarbonize Jordan’s electricity sector. The research presents a comprehensive techno-economic and environmental assessment evaluating the compatibility of the Arab Gas Pipeline and major power plants with hydrogen–natural gas mixtures considering blending limits energy needs environmental impacts and economic feasibility under Jordan’s 2030 energy scenario. The findings reveal that hydrogen blending between 5 and 20 percent can be technically achieved without major infrastructure modifications. The total hydrogen demand is estimated at 24.75 million kilograms per year with a reduction of 152.7 thousand tons of carbon dioxide per annum. This requires 296980 cubic meters of water per year equivalent to only 0.1 percent of the National Water Carrier’s capacity indicating a negligible impact on national water resources. Although technically and environmentally feasible the project remains economically constrained requiring a carbon price of $1835.8 per ton of carbon dioxide for economic neutrality.
Green Hydrogen as a Decarbonization Pathway for Steel Industry in Pakistan
Nov 2025
Publication
The global steel industry emits 1.92 tons of CO2 per ton of output and faces urgent pressure to decarbonize. In Pakistan the sector accounts for 0.29 tons of CO2 per ton of output with limited mitigation frameworks in place. Green hydrogen (GH2)-based steelmaking offers a strategic pathway toward decarbonization. However realizing its potential depends on access to renewable energy. Despite Pakistan’s substantial technical wind potential of 340 GW grid limitations currently restrict wind power to only 4% of national electricity generation. This study explores GH2 production through sector coupling and power wheeling repurposing curtailed wind energy from Sindh to supply Karachi’s steel industry and proposing a phased roadmap for GH enabling fossil fuel substitution industrial resilience and alignment with global carbon-border regulations.
An Effective Integrated Optimal Day-ahead and Real-time Power Scheduling Approach for Hydrogen-based Microgrid
Oct 2025
Publication
The increasing penetration of renewable energy sources in power systems poses significant challenges for maintaining grid reliability mainly due to the variability and uncertainty of solar and demand profiles. Microgrids equipped with diverse storage technologies have emerged as a promising solution to address these issues.This paper proposes an integrated day-ahead and real-time power scheduling approach for grid-connected microgrids equipped with both conventional and hydrogen-based ESSs. While existing strategies often address day-ahead and real-time scheduling separately or rely on a single storage technology this work introduces a unified framework that exploits the complementary characteristics of batteries and hydrogen systems. The proposed approach is based on a novel two-stage stochastic optimization model embedded within a hierarchical optimization framework to address these two intertwined problems efficiently. For the day-ahead scheduling a two-stage stochastic programming energy management model is solved to optimize the microgrid schedule based on forecasted load demand and PV production profiles. Building upon the day-ahead schedule another optimization model is solved which addresses real-time power imbalances caused by deviations in actual PV production and load demand power profiles with respect to the forecasted ones with the aim of minimizing operational disruptions. Simulation results demonstrate the validity of the proposed approach achieving both cost reductions and minimal power imbalances. By dynamically adjusting energy flows and using both conventional batteries and hydrogen systems the proposed approach ensures improved reliability reduced operational costs and enhanced integration of RES in microgrids. These findings highlight the potential of the proposed hierarchical framework to support the large-scale deployment of RES while ensuring resilient and cost-effective microgrid operations.
Blockchain-based Traceability and Certifications of Hydrogen Refueling Station Components
Oct 2025
Publication
As hydrogen gains prominence in energy systems its adoption as an energy source for fuel cell electric vehicles (FCEVs) necessitates the establishment of hydrogen refueling stations (HRS). These stations contain critical compo-nents including nozzles storage tanks heat exchangers and compressors which must be certified by regulatory agen-cies to ensure safety and public trust. Current certification processes are fragmented and manually intensive creating inefficiencies and limiting transparency across the infrastructure lifecycle. In this paper we propose a blockchain-based solution that creates a secure and auditable network for certifying key HRS components. The system integrates an EVM-compatible blockchain decentralized storage and a modular suite of smart contracts (SCs) that formalize registration bidding accreditation certification and governance. Each contract encodes a distinct actor-driven work-flow enabling traceable and role-specific operations. A Decentralized Application (DApp) interface supports real-time and role-based interaction across the ecosystem. We present and evaluate the SCs and their underlying algorithms us-ing gas usage analysis load testing and security auditing. Load testing across the certification lifecycle shows stable transaction throughput and predictable cost profiles under increasing actor activity. A static security analysis con-firms resilience against common vulnerabilities. Our cost analysis indicates that while the framework is technically deployable on public blockchains the execution costs of certain functions make it more cost-effective for private blockchains or Layer 2 networks. We also compare our framework with existing systems to highlight its novelty and technical advantages. Our SCs DApp interface and load testing scripts are publicly available on GitHub.
Uncertainty Ahead: Should Stand-alone Energy Systems Bet on Hydrogen Backup?
Oct 2025
Publication
Achieving net zero by 2050 will require decarbonising stand-alone energy applications. Hydrogen is increasingly viewed as a promising energy carrier but its economic viability remains uncertain due to the lack of consensus on future demand and limited deployment of key components such as fuel cells in stationary stand-alone applications. This study investigates whether hybridising batteries with hydrogen can deliver meaningful cost benefits under future cost trajectories. Using a Monte Carlo framework we simulate 8000 scenarios across constant and seasonal load profiles varying the capital costs of batteries fuel cells electrolysers and hydrogen tanks based on 2025 estimates and 2050 projections. Our results show that hydrogen integration only becomes economically attractive when multiple component costs decline simultaneously. The fuel cell-to-battery power capital cost ratio emerges as the dominant driver of levelised cost of energy (LCOE) improvements. For constant loads median LCOE savings remain below 12 % with more than 5 % savings only achieved when the fuel cell cost is less than 7 times that of the battery. Seasonal nighttime loads offer a wider theoretical LCOE savings range (0–156 %) but substantial gains occur only under unrealistic cost mixes where battery costs remain high and fuel cell costs fall sharply. These findings highlight the sensitivity of hydrogen viability to load profile characteristics and cost interdependencies. They underscore the need for targeted cost reduction strategies particularly for fuel cells to justify added system complexity. These findings are important considerations for future investment and policy decisions.
Life Cycle Assessment of Hydrogen-based Fuels Use in Internal Combustion Engines of Container Ships until 2050
Oct 2025
Publication
Hydrogen-based fuels are potential candidates to help international shipping achieve net-zero greenhouse gas (GHG) emissions by around 2050. This paper quantifies the environmental impacts of liquid hydrogen liquid ammonia and methanol used in a Post-Panamax container ship from 2020 to 2050. It considers cargo capacity changes electricity decarbonization and hydrogen production transitions under two International Energy Agency scenarios: the Stated Policies Scenario (STEPS) and the Net Zero Emissions by 2050 Scenario (NZE). Results show that compared to the existing HFO ship hydrogen-based propulsion systems can decrease cargo weight capacity by 0.3 % to 25 %. In the NZE scenario hydrogen-based fuels can reduce GHG emissions per tonne-nautical mile by 48 %–65 % compared to heavy fuel oil by 2050. Even with fully renewable hydrogenbased fuels 18 %–31 % of GHG emissions would still remain. Using hydrogen-based fuels in internal combustion engines requires attention to minimize environmental trade-offs.
No more items...