Applications & Pathways
Enhancing Power-to-Hydrogen Flexibility Through Optimal Bidding in Nordic Energy Activation Market with Wind Integration
Oct 2025
Publication
The recent updates to the Single Day-Ahead Coupling (SDAC) framework in the European energy market along with new rules for providing manual frequency restoration reserve (mFRR) products in the Nordic Energy Activation Market (EAM) have introduced a finer Market Time Unit (MTU) resolution. These developments underscore the growing importance of flexible assets such as power-to-hydrogen (PtH) facilities in delivering system flexibility. However to successfully participate in such markets well-designed and accurate bidding strategies are essential. To fulfill this aim this paper proposes a Mixed Integer Linear Programming (MILP) model to determine the optimal bidding strategies for a typical PtH facility accounting for both the technical characteristics of the involved technologies and the specific participation requirements of the mFRR EAM. The study also explores the economic viability of sourcing electricity from nearby wind turbines (WTs) under a Power Purchase Agreement (PPA). The simulation is conducted using a case study of a planned PtH facility at the Port of Hirtshals Denmark. Results demonstrate that participation in the mFRR EAM particularly through the provision of downward regulation can yield significant economic benefits. Moreover involvement in the mFRR market reduces power intake from the nearby WTs as capacity must be reserved for downward services. Finally the findings highlight the necessity of clearly defined business models for such facilities considering both technical and economic aspects.
Toward Zero-emission Ferries: Integrating Systematic Review and Bibliometric Analysis Insights on Alternative Fuels and Policies
Nov 2025
Publication
The shipping industry aims to achieve full decarbonization at the European Union (EU) level by mid-century. Over the past decade various alternative fuels have been explored to address this goal. However challenges such as insufficient bunkering infrastructure technological immaturity and high costs have made shipowners hesitant to invest in“clean” propulsion systems. This study conducts a bibliometric analysis supported by a systematic literature review to map and critically synthesize current knowledge on alternative fuels for ferry decarbonization and their alignment with emissions reduction policies. Using the Greek ferry fleet as a representative case study the paper evaluates the regulatory framework and technical characteristics of various fuel options and examines their compatibility with different vessel categories. A qualitative comparative framework is introduced to link policy types with alternative fuel pathways offering original insights into policy—fuel alignment. The findings highlight methanol and green electricity (battery-electric systems) as highly promising solutions especially if battery technologies further advance in the coming years. Hydrogen also presents significant potential but is currently limited by high production costs and infrastructure requirements. Rather than presenting a quantitative decision-making model this review establishes the conceptual basis for such a framework in future research. This paper also offers innovative proposals to accelerate the adoption of zero-emission fuels addresses key gaps in existing research and provides insights for advancing ferry decarbonization.
A Two-Stage Optimal Dispatch Strategy for Electric-ThermalHydrogen Integrated Energy System Based on IGDT and Fuzzy Chance-Constrained Programming
Nov 2025
Publication
Na Sun,
Hongxu He and
Haiying Dong
To address the economic and reliability challenges of high-penetration renewable energy integration in electricity-heat-hydrogen integrated energy systems and support the dualcarbon strategy this paper proposes an optimal dispatch method integrating Information Gap Decision Theory (IGDT) and Fuzzy Chance-Constrained Programming (FCCP). An IES model coupling multiple energy components was constructed to exploit multi-energy complementarity. A stepped carbon trading mechanism was introduced to quantify emission costs. For interval uncertainties in renewable generation IGDT-based robust and opportunistic dispatch models were established; for fuzzy load uncertainties FCCP transformed them into deterministic equivalents forming a dual-layer “IGDT-FCCP” uncertainty handling framework. Simulation using CPLEX demonstrated that the proposed model dynamically adjusts uncertainty tolerance and confidence levels effectively balancing economy robustness and low-carbon performance under complex uncertainties: reducing total costs by 12.7% cutting carbon emissions by 28.1% and lowering renewable curtailment to 1.8%. This study provides an advanced decision-making paradigm for low-carbon resilient IES.
Effects of Hydrogen-rich Gas Injection on Combustion Characteristics in Blast Furnace Raceway and Thermal Load of Tuyere: A Numerical Simulation Study
Nov 2025
Publication
Hydrogen-rich gas (HRG) injection is a promising low-carbon solution for blast furnace ironmaking. This study conducted numerical simulations in the lower part of a blast furnace to analyze the combustion behavior of coinjected coke oven gas (COG) and pulverized coal (PC) within the raceway and the associated thermal load on the tuyere. A three-dimensional computational fluid dynamics model incorporating fluid–thermal–solid coupling and the GRI-Mech 3.0 chemical kinetic mechanism (validated for 300–2500 K) was established to simulate the lance–blowpipe–tuyere–raceway region. The simulation results revealed that moderate COG injection accelerated volatile release from PC and enlarged the high-temperature zone (>2000 K). However excessive COG injection intensified oxygen competition and shortened the residence time of PC ultimately decreasing the burnout rate. Notably although COG has high reactivity its injection did not cause an increase in tuyere temperature. By contrast the presence of an unburned gas layer near the upper wall of the tuyere and the existence of a strong convective cooling effect contributed to a reduction in tuyere temperature. An optimized cooling water channel was designed to enhance flow distribution and effectively suppress localized overheating. The findings of this study offer valuable technical insights for ensuring safe COG injection and advancing low-carbon steelmaking practices.
Joint Optimization Scheduling of Electric Vehicles and Electro–Olefin–Hydrogen Electromagnetic Energy Supply Device for Wind–Solar Integration
Nov 2025
Publication
In northern China the long winter heating period is accompanied by severe wind curtailment. To address this issue a joint optimization scheduling strategy of electric vehicles (EVs) and electro–olefin–hydrogen electromagnetic energy supply device (EHED) is proposed to promote deep wind–solar integration. Firstly the feasibility analysis of EVs participating in scheduling is conducted and the operation models of dispatchable EVs and thermal energy storage EHEDs within the scheduling period are established. Secondly a control strategy for the joint optimization scheduling of wind–solar farms EVs EHEDs and power grid is constructed. Then an economic dispatch model for joint optimization of EVs and EHEDs is established to minimize the system operation cost within the scheduling period and the deep wind–solar integration of the joint optimization model is studied by considering EVs under different demand responses. Finally the proposed model is solved by CPLEX solver. The simulation results show that the established joint optimization economic dispatch model of EV-EHEDs can improve the enthusiasm of dispatchable EVs to participate in deep wind–solar integration reduce wind curtailment power and decrease the overall system operation cost.
An Explainable Fault Diagnosis Algorithm for Proton Exchange Membrane Fuel Cells Integrating Gramian Angular Fields and Gradient-Weighted Class Activation Mapping
Nov 2025
Publication
Reliable operation of proton exchange membrane fuel cells (PEMFCs) is crucial for their widespread commercialization and accurate fault diagnosis is the key to ensuring their long-term stable operation. However traditional fault diagnosis methods not only lack sufficient interpretability making it difficult for users to trust their diagnostic decisions but also one-dimensional (1D) feature extraction methods highly rely on manual experience to design and extract features which are easily affected by noise. This paper proposes a new interpretable fault diagnosis algorithm that integrates Gramian angular field (GAF) transform convolutional neural network (CNN) and gradient-weighted class activation mapping (Grad-CAM) for enhanced fault diagnosis and analysis of proton exchange membrane fuel cells. The algorithm is systematically validated using experimental data to classify three critical health states: normal operation membrane drying and hydrogen leakage. The method first converts the 1D sensor signal into a two-dimensional GAF image to capture the temporal dependency and converts the diagnostic problem into an image recognition task. Then the customized CNN architecture extracts hierarchical spatiotemporal features for fault classification while Grad-CAM provides visual explanations by highlighting the most influential regions in the input signal. The results show that the diagnostic accuracy of the proposed model reaches 99.8% which is 4.18% 9.43% and 2.46% higher than other baseline models (SVM LSTM and CNN) respectively. Furthermore the explainability analysis using Grad-CAM effectively mitigates the “black box” problem by generating visual heatmaps that pinpoint the key feature regions the model relies on to distinguish different health states. This validates the model’s decision-making rationality and significantly enhances the transparency and trustworthiness of the diagnostic process.
Evaluation of Heat Transfer Technologies for High Temperature Polymer Electrolyte Membrane Fuel Cells as Primary Power Source in a Regional Aircraft
Oct 2025
Publication
High-temperature proton exchange membrane fuel cells (HT-PEM FCs) represent a promising avenue for generating carbon dioxide-free electricity through the utilization of hydrogen fuel. These systems present numerous advantages and challenges for mobile applications positioning them as pivotal technologies for the realization of emission-free regional aircraft. Efficient thermal management of such fuel cell-powered systems is crucial for ensuring the safe and durable operation of the aircraft while concurrently optimizing system volume mass and minimizing parasitic energy consumption. This paper presents four distinct heat transfer principles tailored for the FC-system of a conceptual hydrogen-electric regional aircraft exemplified by DLR’s H2ELECTRA. The outlined approaches encompass conductive cooling air cooling liquid cooling phase change cooling and also included is the utilization of liquid hydrogen as a heat sink. Approaches are introduced with schematic cooling architectures followed by a comprehensive evaluation of their feasibility within the proposed drivetrain. Essential criteria pertinent to airborne applications are evaluated to ascertain the efficacy of each thermal management strategy. The following criteria are selected for evaluation: safety ease of integration reliability and life-cycle costs technology readiness and development as well as performance which is comprised of heat transfer weight volume and parasitic power consumption. Of the presented cooling methods two emerged to be functionally suitable for the application in MW-scale aircraft applications at their current state of the art: liquid cooling utilizing water under high pressure or other thermal carrier liquids and phase-change cooling. Air cooling and conductive cooling have a high potential due to their reduced system complexity and mass but additional studies investigating effects at architecture level in large-scale fuel cell stacks are needed to increase performance levels. These potentially suitable heat transfer technologies warrant further investigation to assess their potential for complexity and weight reduction in the aircraft drivetrain.
Marine Hydrogen Pressure Reducing Valves: A Review on Multi-Physics Coupling, Flow Dynamics, and Structural Optimization for Ship-Borne Storage Systems
Oct 2025
Publication
As a zero-carbon energy carrier hydrogen is playing an increasingly vital role in the decarbonization of maritime transportation. The hydrogen pressure reducing valve (PRV) is a core component of ship-borne hydrogen storage systems directly influencing the safety efficiency and reliability of hydrogen-powered vessels. However the marine environment— characterized by persistent vibrations salt spray corrosion and temperature fluctuations— poses significant challenges to PRV performance including material degradation flow instability and reduced operational lifespan. This review comprehensively summarizes and analyzes recent advances in the study of high-pressure hydrogen PRVs for marine applications with a focus on transient flow dynamics turbulence and compressible flow characteristics multi-stage throttling strategies and valve core geometric optimization. Through a systematic review of theoretical modeling numerical simulations and experimental studies we identify key bottlenecks such as multi-physics coupling effects under extreme conditions and the lack of marine-adapted validation frameworks. Finally we conducted a preliminary discussion on future research directions covering aspects such as the construction of coupled multi-physics field models the development of marine environment simulation experimental platforms the research on new materials resistant to vibration and corrosion and the establishment of a standardized testing system. This review aims to provide fundamental references and technical development ideas for the research and development of high-performance marine hydrogen pressure reducing valves with the expectation of facilitating the safe and efficient application and promotion of hydrogen-powered shipping technology worldwide.
Evaluating the Role of Hybrid Renewable Energy Systems in Supporting South Africa’s Energy Transition
Oct 2025
Publication
This report evaluates the role of Hybrid Renewable Energy Systems (HRESs) in supporting South Africa’s energy transition amidst persistent power shortages coal dependency and growing decarbonisation imperatives. Drawing on national policy frameworks including the Integrated Resource Plan (IRP 2019) the Just Energy Transition (JET) strategy and Net Zero 2050 targets this study analyses five major HRES configurations: PV–Battery PV–Diesel–Battery PV–Wind–Battery PV–Hydrogen and Multi-Source EMS. Through technical modelling lifecycle cost estimation and trade-off analysis the report demonstrates how hybrid systems can decentralise energy supply improve grid resilience and align with socio-economic development goals. Geographic application cost-performance metrics and policy alignment are assessed to inform region-specific deployment strategies. Despite enabling technologies and proven field performance the scale-up of HRESs is constrained by financial regulatory and institutional barriers. The report concludes with targeted policy recommendations to support inclusive and regionally adaptive HRES investment in South Africa.
Co-Optimization of Capacity and Operation for Battery-Hydrogen Hybrid Energy Storage Systems Based on Deep Reinforcement Learning and Mixed Integer Programming
Oct 2025
Publication
The hybrid energy storage system (HESS) that combines battery with hydrogen storage exploits complementary power/energy characteristics but most studies optimize capacity and operation separately leading to suboptimal overall performance. To address this issue this paper proposes a bi-level co-optimization framework that integrates deep reinforcement learning (DRL) and mixed integer programming (MIP). The outer layer employs the TD3 algorithm for capacity configuration while the inner layer uses the Gurobi solver for optimal operation under constraints. On a standalone PV–wind–load-HESS system the method attains near-optimal quality at dramatically lower runtime. Relative to GA + Gurobi and PSO + Gurobi the cost is lower by 4.67% and 1.31% while requiring only 0.52% and 0.58% of their runtime; compared with a direct Gurobi solve the cost remains comparable while runtime decreases to 0.07%. Sensitivity analysis further validates the model’s robustness under various cost parameters and renewable energy penetration levels. These results indicate that the proposed DRL–MIP cooperation achieves near-optimal solutions with orders of magnitude speedups. This study provides a new DRL–MIP paradigm for efficiently solving strongly coupled bi-level optimization problems in energy systems.
Hydrogen Vehicle Adoption: Perceptions, Barriers, and Global Strategies
Oct 2025
Publication
This paper analyzes the potential of hydrogen technologies in transport placing it within the context of global environmental and energy challenges. Its primary purpose is to eval‑ uate the prospects for the implementation of these technologies at international and na‑ tional levels including Poland. This study utilizes a literature review and an analysis of the results of a highly limited exploratory pilot survey measuring public perception of hydrogen technology in transport. It is critical to note that the survey was conducted on a small non‑representative sample and exhibited a strong geographical bias primarily collecting responses from Europe (50 people) and North America (30 people). This study also details hydrogen vehicle types (FCEV HICE) and the essential infrastructure required (HRS). Despite solid technological foundations the development of hydrogen technology heavily relies on non‑technical factors such as infrastructure development support pol‑ icy and social acceptance. Globally the number of vehicles and stations is growing but remains limited with the pace of development correlating with the involvement of coun‑ tries. The pilot survey revealed a generally positive perception of the technology (mainly due to environmental benefits) but highlighted three key barriers: limited availability of refueling infrastructure—51.5% of respondents strongly agreed on this obstacle high pur‑ chase and maintenance costs and insufficient public awareness. Infrastructure subsidies and tax breaks were identified as effective incentives. Hydrogen technology offers a poten‑ tially competitive and sustainable transport solution but it demands significant systemic support intensive investment in large‑scale infrastructure expansion and comprehensive educational activities. Further governmental engagement is crucial. The severe limitations resulting from the pilot nature of the survey should be rigorously taken into account dur‑ ing interpretation.
Assessment of Regional Hydrogen Refueling Station Layout Planning and Carbon Reduction Benefits Based on Multi-Dimensional Factors of Population, Land, and Demand
Oct 2025
Publication
The urgent global transition toward low-carbon energy systems has highlighted the need for systematic planning of hydrogen refueling stations (HRS) to facilitate clean energy adoption. This study develops an integrated framework for regional HRS layout optimization and carbon emission assessment considering population distribution land area and hydrogen demand. Using Hainan Province as a case study the model estimates regional hydrogen demand determines optimal HRS deployment evaluates spatial coverage and refueling distances and quantifies potential carbon emission reductions under various renewable energy scenarios. Model validation with Haikou demonstrates its reliability and applicability at the regional scale. Results indicate pronounced spatial disparities in hydrogen demand and infrastructure requirements emphasizing that prioritizing station deployment in densely populated urban areas can enhance accessibility and maximize emission reduction. The framework offers a practical data-efficient tool for policymakers and planners to guide early-stage hydrogen infrastructure development and supports strategies for regional decarbonization and sustainable energy transitions.
Methodology for Evaluating and Comparing Different Sustainable Energy Generation and Storage Systems for Residential Buildings—Application to the Case of Spain
Nov 2025
Publication
This paper focuses on assessing different sustainable energy generation and storage systems for residential buildings in Spain identifying the best-performing system according to the end-user requirements. As outlined by the consulted literature the authors have selected two types of hybrid configurations—a Photovoltaic System with Battery Backup (PSBB) and a Photovoltaic System with Hydrogen Hybrid Storage Backup (PSHB)—and a Grid-Based System with Renewable Hydrogen Contribution (GSHC) is proposed. A Fuzzy Analytical Hierarchy Process methodology (FAHP) is employed for evaluating the hybrid power systems from a multi-criteria approach: acquisition operational and environmental. The main requirements for selecting the optimal system are organized under these criteria and evaluated using key performance indicators. This methodology allows the selection of the best option considering objective and subjective system performance indicators. Beyond establishing the ranking a sensitivity analysis was conducted to provide insights into how individual criteria influence the ranking of the hybrid power systems alternatives. The results demonstrate that the selection of hybrid power systems for a residential building is highly dependent on consumer preferences but the PSBB system scores highly in operation and acquisition criteria while the GSHC has good performance in all the criteria.
Deployment of Modular Renewable Energy Sources and Energy Storage Schemes in a Renewable Energy Valley
Nov 2025
Publication
While community energy initiatives and pilot projects have demonstrated technical feasibility and economic benefits their site-specific nature limits transferability to systematic scalable investment models. This study addresses this gap by proposing a modular framework for Renewable Energy Valleys (REVs) developed from real-world Community Energy Lab (CEL) demonstrations in Crete Greece which is an island with pronounced seasonal demand fluctuation strong renewable potential and ongoing hydrogen valley initiatives. Four modular business schemes are defined each representing different sectoral contexts by combining a baseline of 50 residential units with one representative large consumer (hotel rural households with thermal loads municipal swimming pool or hydrogen bus). For each scheme a mixed-integer linear programming model is applied to optimally size and operate integrated solar PV wind battery (BAT) energy storage and hydrogen systems across three renewable energy penetration (REP) targets: 90% 95% and 99.9%. The framework incorporates stochastic demand modeling sector coupling and hierarchical dispatch schemes. Results highlight optimal technology configurations that minimize dependency on external sources and curtailment while enhancing reliability and sustainability under Mediterranean conditions. Results demonstrate significant variation in optimal configurations across sectors and targets with PV capacity ranging from 217 kW to 2840 kW battery storage from 624 kWh to 2822 kWh and hydrogen systems scaling from 65.2 kg to 192 kg storage capacity. The modular design of the framework enables replication beyond the specific context of Crete supporting the scalable development of Renewable Energy Valleys that can adapt to diverse sectoral mixes and regional conditions.
Feasibility and Sensitivity Analysis of an Off-Grid PV/Wind Hybrid Energy System Integrated with Green Hydrogen Production: A Case Study of Algeria
Nov 2025
Publication
Algeria’s transition toward sustainable energy requires the exploitation of its abundant solar and wind resources for green hydrogen production. This study assesses the technoeconomic feasibility of an off-grid PV/wind hybrid system integrated with a hydrogen subsystem (electrolyzer fuel cell and hydrogen storage) to supply both electricity and hydrogen to decentralized sites in Algeria. Using HOMER Pro five representative Algerian regions were analyzed accounting for variations in solar irradiation wind speed and groundwater availability. A deferrable water-extraction and treatment load was incorporated to model the water requirements of the electrolyzer. In addition a comprehensive sensitivity analysis was conducted on solar irradiation wind speed and the capital costs of PV panels and wind turbines to capture the effects of renewable resource and investment cost fluctuations. The results indicate significant regional variation with the levelized cost of energy (LCOE) ranging from 0.514 to 0.868 $/kWh the levelized cost of hydrogen (LCOH) between 8.31 and 12.4 $/kg and the net present cost (NPC) between 10.28 M$ and 17.7 M$ demonstrating that all cost metrics are highly sensitive to these variations.
Benefit Allocation Strategies for Electric–Hydrogen Coupled Virtual Power Plants with Risk–Reward Tradeoffs
Nov 2025
Publication
Driven by carbon neutrality goals electric–hydrogen coupled virtual power plants (EHCVPPs) integrate renewable hydrogen production with power system flexibility resources emerging as a critical technology for large-scale renewable integration. As distributed energy resources (DERs) within EHCVPPs diversify heterogeneous resources generate diversified market values. However inadequate benefit allocation mechanisms risk reducing participation incentives destabilizing cooperation and impairing operational efficiency. To address this benefit allocation must balance fairness and efficiency by incorporating DERs’ regulatory capabilities risk tolerance and revenue contributions. This study proposes a multi-stage benefit allocation framework incorporating risk–reward tradeoffs and an enhanced optimization model to ensure sustainable EHCVPP operations and scalability. The framework elucidates bidirectional risk–reward relationships between DERs and EHCVPPs. An individualized risk-adjusted allocation method and correction mechanism are introduced to address economic-centric inequities while a hierarchical scheme reduces computational complexity from diverse DERs. The results demonstrate that the optimized scheme moderately reduces high-risk participants’ shares increasing operator revenue by 0.69% demand-side gains by 3.56% and reducing generation-side losses by 1.32%. Environmental factors show measurable yet statistically insignificant impacts. The framework meets stakeholders’ satisfaction and minimizes deviation from reference allocations.
A Review on Electric Vehicle Charging Station Planning: Infrastructure Placement, Sizing, Upgrades, and Uncertainties
Nov 2025
Publication
Electric Vehicles (EVs) are rapidly expanding resulting in increased demand on power systems and transportation networks. This study reviews recent advancements in planning EV Charging Stations (EVCSs) focusing on siting sizing grid upgrades and managing uncertainty. Analysis suggests that while many studies optimize either the location or the size of these stations few consider their combined effects resulting in missed opportunities for synergy. A lack of attention to cross-sector integration with hydrogen inadequate treatment of grid reinforcement and fragmented approaches to modeling uncertainties such as EV behavior renewable energy variability and market dynamics is also observed. To address these gaps a synthesis of the interdependencies between siting and sizing is provided along with a review of multi-energy integration opportunities an evaluation of Vehicle-to-Grid technology and smart charging including technical benefits and challenges strategies that link the deployment of EVCS to grid upgrades and a taxonomy of uncertainty sources along with advanced stochastic and data-driven solutions. This review emphasizes the importance of integrated data-informed planning in the development of EV charging infrastructure.
Coordinated Operation Mechanism of Electric-hydrogen-traffic Coupling System that Considers Carbon Emissions and Uncertainties
Nov 2025
Publication
During the critical period of energy transition the collaborative optimization of the electricity-hydrogentransportation coupling system is of vital importance for achieving efficient energy utilization and sustainable development.This paper proposes a collaborative operation mechanism of Distributed Robust Optimization (DRO) considering carbon emissions. Firstly a Stackelberg game dynamic pricing strategy is constructed for the integrated energy station (IES) and the electricity-hydrogen hybrid charging station (HRS) where the upper-level IES optimizes the electricity price setting strategy and the lower-level HRS dynamically adjusts the electricity purchase-hydrogen production plan. Secondly the Wasserstein distance is used to describe the uncertainties of hydrogen vehicle loads and wind-solar power generation and a bisection algorithm-column constraint generation (BA-C&CG) hybrid algorithm is designed to solve the model. Finally the numerical example verification shows that the daily operation cost of HRS under the proposed mechanism is as low as 1108.53 EUR which is 10.58 % and 7.38 % lower than that of the commonly used stochastic optimization (SO) and robust optimization (RO) respectively. The variance analysis (F = 536.05P < 0.001) confirms that the cost advantage is statistically significant. In terms of carbon emission reduction effect the DRO-Stackelberg game model has the lowest daily carbon cost (6.98EUR). This mechanism effectively balances the economic and robustness of the system and the single dispatch calculation time is only 112.09 s meeting the real-time operation requirements of engineering. It provides technical support for the low-carbon collaborative operation of the electricity-hydrogen-transportation coupling system.
Inverse Design and Porous Metal Printing of GDL-integrated Flow Field Plates for High-temperature Hydrogen Fuel Cells
Nov 2025
Publication
High-temperature (HT) proton exchange membrane (PEM) fuel cells (FC) offer key advantages for sustainable transportation especially in heavy-duty applications due to their improved thermal efficiency and water management. This study introduces an inverse design framework to develop flow field plates integrated with a gas diffusion layer (GDL) enabling scalable electrochemical performance from the unit cell to the plate level. A reduced-order homogenization-based multiphysics model is developed to evaluate designs with approximately 1000× faster computation. Flow channel orientation is optimized using a tensor field method and dehomogenized into manufacturable geometries. Optimized designs validated through high-fidelity 3D simulations show up to 12% higher average current density and 88% lower pressure drop compared to conventional parallel and mesh configurations. To address fabrication challenges solid-to-porous metal additive manufacturing is employed producing monolithic structures that integrate flow channels with a porous metal GDL. Both numerical and physical tests confirm high permeability and improved power output compared to carbon-based GDLs. These findings highlight the effectiveness of combining advanced computational modeling with metal 3D printing to enhance the performance and manufacturability of high-temperature PEMFC supporting their broader adoption in sustainable energy applications.
Reliability and Risk Assessment of Hydrogen-Powered Marine Propulsion Systems Based on the Integrated FAHP-FMECA Framework
Nov 2025
Publication
With the IMO’s 2050 decarbonization target hydrogen is a key zero-carbon fuel for shipping but the lack of systematic risk assessment methods for hydrogen-powered marine propulsion systems (under harsh marine conditions) hinders its large-scale application. To address this gap this study proposes an integrated risk evaluation framework by fusing Failure Mode Effects and Criticality Analysis (FMECA) with the Fuzzy Analytic Hierarchy Process (FAHP)—resolving the limitation of traditional single evaluation tools and adapting to the dynamic complexity of marine environments. Scientific findings from this framework confirm that hydrogen leakage high-pressure storage tank valve leakage and inverter overload are the three most critical failure modes with hydrogen leakage being the primary risk source due to its high severity and detection difficulty. Further hazard matrix analysis reveals two key risk mechanisms: one type of failure (e.g. insufficient hydrogen concentration) features “high severity but low detectability” requiring real-time monitoring; the other (e.g. distribution board tripping) shows “high frequency but controllable impact” calling for optimized operations. This classification provides a theoretical basis for precise risk prevention. Targeted improvement measures (e.g. dual-sealed valves redundant cooling circuits AI-based regulation) are proposed and quantitatively validated reducing the system’s overall risk value from 4.8 (moderate risk) to 1.8 (low risk). This study’s core contribution lies in developing a universally applicable scientific framework for marine hydrogen propulsion system risk assessment. It not only fills the methodological gap in traditional evaluations but also provides a theoretical basis for the safe promotion of hydrogen shipping supporting the scientific realization of the IMO’s decarbonization goal.
Techno-economic Feasibility of Centralized and Decentralized Ammonia Production in the United States
Nov 2025
Publication
Ammonia is a cornerstone of modern agriculture supplying the nitrogen essential for crops that nourish nearly half the global population. Yet its production is responsible for ~2 % of global greenhouse gas emissions. To meet climate and food security goals sustainable low-carbon and resilient ammonia production systems are needed. Here we develop a spatially explicit techno-economic model to compare centralized and decentralized ammonia production pathways across the U.S. a major global ammonia producer and consumer spanning the full supply chain from hydrogen production to fertilizer delivery. We integrate high-resolution supply and demand data and apply linear optimization to estimate delivered ammonia costs accounting for geographic mismatches and transportation. Our results show that decentralized ammonia production whether powered by grid electricity or solar energy is substantially more expensive than centralized production from natural gas or coal. Centralized natural gas-based ammonia has a median production cost of 326 USD/tonne NH3 compared to 499 USD/tonne for coal. Decentralized grid-powered systems range from 659 to 1634 USD/tonne and solar-powered systems from 1077 to 2266 USD/tonne. Transportation costs for centralized production range from 7 to 85 USD/tonne with a median of 40 USD/tonne resulting in a delivered cost of 343 USD/tonne. Median delivered costs for decentralized grid- and solar-powered systems are 1069 and 1494 USD/tonne respectively. Decentralized systems require electricity prices below 19 USD/MWh (grid) and 17 USD/MWh (solar) to achieve cost parity well below 2024 U S. averages of 117 USD/MWh. These results highlight the economic challenges facing decentralized ammonia production and the importance of electricity cost reductions tax credits carbon pricing or further technological breakthroughs for broader viability.
Simulation of the Refuelling Process for an LH2-powered Commercial Aircraft Part 1 - Modelling and Validation
Nov 2025
Publication
Liquid hydrogen (LH2) is a promising candidate for zero emission aviation but its cryogenic properties make the refuelling process fundamentally different from that of conventional jet fuels. Although previous studies have addressed LH2 storage and system integration detailed modelling of the refuelling process remains limited. This paper presents the first part of a two-part study focused on simulation of the refuelling process for an LH2-powered commercial aircraft. An existing tank model is substantially modified to more accurately capture relevant physical phenomena including heat transfer and droplet dynamics during top-fill spray injection. Newly available experimental data on LH2 no-vent filling enables direct validation of the model under conditions that match the experimental setup. A sensitivity analysis identifies the most influential parameters that affect model precision including loss coefficient droplet diameter radiative heat ingress and vent-closing pressure. The validated model forms the basis for Part 2 of this study in which it is applied to a representative LH2-powered commercial aircraft to simulate refuelling times quantify venting losses and assess the impact of key operational settings. These results support the design of efficient LH2 refuelling systems for future aircraft and airport infrastructure.
Techno-economic Assessment of Hythane-fueled Industrial SOFC Systems
Nov 2025
Publication
Solid oxide fuel cell (SOFC) systems offer high-efficiency conversion of the chemical energy of fuel gases into electrical energy. To meet market and policy targets such systems must be able of operating on an industrial scale and be compatible with environmentally friendly fuels. This study models the scale-up of a 750 W naturalgas-fueled SOFC to a 240 kW system with various gas-path configurations evaluating the impact of blending up to 30 vol% of hydrogen (H2) into the methane feed. Aspen Plus simulations coupled with pressure-loss and carbon-deposition models were used to optimize recirculation ratio and reactant utilization for maximum efficiency. The parallel configuration achieved the highest electrical efficiency of 64.0 % while series-connected and intermediate systems suffered from increased pressure losses. H2 admixture simulations confirm that operation is feasible without loss of efficiency in the small- and large-scale systems due to reduced carbondeposition potential. A techno-economic analysis indicates a 91.7 % cost reduction through scale-up and a 1.6 % cost increase for adjusting the system to H2 admixtures. The economic viability of the large-scale system was evaluated for all tested fuel compositions (0.201–0.204 €/kWh) with payback times under 20 years at market-relevant electricity prices. These results demonstrate the technical and economic feasibility of large-scale H2-adapted SOFC systems for industrial decarbonization.
Direct Injection Hydrogen Combustion under Leaner Conditions in an Optical Engine using Optical/Laser Diagnostics
Nov 2025
Publication
Hydrogen’s increasing potential as an alternative fuel for heavy-duty transport has led to the conversion of conventional diesel compression-ignition engines to spark-ignition hydrogen operation. Hydrogen’s broad flammability range enables leaner operation achieving both higher engine efficiency and near-zero emissions. In particular direct injection hydrogen combustion improves volumetric efficiency and reduces problems including pre-ignition and knock related to hydrogen port-fuel injection. In the present work we performed an optical investigation of direct injection (DI) hydrogen combustion under leaner mixture conditions. The study was conducted using a heavy-duty optical diesel engine modified for spark-ignition operation. Bottom-view natural flame luminosity and OH-PLIF imaging were conducted along with in-cylinder pressure measurements. Experiments were conducted at three air-excess ratios (3 3.4 and 3.8) with spark timings (ST) varied from − 15 ◦CA aTDC to − 30 ◦CA aTDC. Hydrogen injection ended at − 30 ◦CA aTDC with the start of injection adjusted accordingly to achieve the desired lambda conditions. The maximum IMEPg corresponded to the lowest COV of the IMEPg indicating optimal spark timing for lean DI hydrogen combustion. The optimized spark timing for λ = 3 λ = 3.4 and λ = 3.8 were occurred at − 25 ◦CA aTDC − 25 ◦CA aTDC and − 30 ◦CA aTDC respectively. The corresponding COV of IMEPg values were below 5 % indicating stable combustion. The flame kernel first initiates at the spark plug and then propagates toward the piston’s outer boundary however the flame propagation does not remain as a continuous front unlike port-fuel injected hydrogen combustion. The effect of fuel stratification is evident in combustion luminosity and OH-PLIF images showing pockets of varying intensity within the combustion chamber. Natural flame luminosity images reveal incomplete flame coverage and asymmetric combustion emphasizing the need for metal engine experiments to further quantify the unburned hydrogen and associated combustion losses.
OH* Chemiluminescence in Non-premixed Industrial Natural Gas/hydrogen Flames under Air-fuel and Oxy-fuel Conditions: Kinetic Modeling and Experimental Validation
Oct 2025
Publication
The application of OH* chemiluminescence diagnostics is becoming increasingly prevalent in the combustion characterization of hydrogen. As the current literature is lacking a systematic study of OH* chemiluminescence in non-premixed turbulent natural gas (NG) and hydrogen (H2 ) flames the present work was designed to address this research gap. Therefore extensive experiments were performed on a semi-industrial burner operating at 50–100 kW in NG/H2–Air/O2 combustion modes which were complemented by comprehensive numerical simulations including 1D laminar counterflow diffusion flamelet calculations and full 3D CFD simulations of the semi-industrial furnace setup. In this way an OH* chemistry model is presented that accurately predicts the global reaction zone characteristics and their difference between CH4 and H2 in air-fired and oxygen-fired flames. The comprehensive numerical approach in conjunction with the subsequent study of different operating conditions yielded novel insights into both combustion modeling and the underlying thermochemical phenomena providing an essential contribution to the transition of the thermal energy sector towards hydrogen as an alternative carbon-free fuel.
Towards the Decarbonization of the Maritime Industry: Design of a Novel Methodology for the Sustainable Strategy Assessment
Oct 2025
Publication
The growing concern about the increase in European Union (EU)’s total CO2 emissions due to maritime activities and the ambitious goal of net zero emissions they are asked to fulfil by 2050 are leading the way to the adoption of new sustainable strategies. In this article a novel methodology for the classification of the sustainable actions is proposed. Moreover new indicators have been designed to compare the level of sustainable development of each port. Among them a new coefficient for the assessment of the Ports’ Potential Sustainability (PPS) have been designed. Main results showed that 56% of the actions were in the improvement and environmentally sustainable group while 19% were shift-economic actions related to the installation of technologies. As a matter of the fact all European ports under analysis have adopted cold ironing system which can reduce up to 4% of the global shipping emissions. Similarly 50% of them have already integrated renewables energies and prioritize equipment electrification in their processes. Finally the most relevant projects to optimize the energy consumption of daily operations and the main challenges that still need to be addressed have been analyzed showing the current trends maritime sector is undertaking to advance towards the sustainable development.
Life Cycle and Economic Viability Assessment of Clean Hydrogen as a Fuel in Corn Drying
Oct 2025
Publication
This study presents a comparative life cycle and economic assessment of using clean hydrogen as a sustainable alternative to natural gas and propane for corn grain drying. The study compares the environmental performance limited to GWP100 and cost-effectiveness of hydrogen from various renewable sources (hydro wind solar) and plasma pyrolysis of natural gas against conventional fossil fuels under two delivery scenarios: pipeline and trucking. A life cycle assessment is conducted using Open LCA to quantify the carbon intensity of each fuel from cradle to combustion at multiple energy requirements based on four burner efficiencies across each scenario. In parallel economic analysis is conducted by calculating the fuel cost required per ton of dried corn grains at each efficiency across both scenarios. The results indicate that green hydrogen consistently outperforms current fuels in terms of emissions but it is generally more expensive at lower burner efficiencies and in trucking scenarios. However the cost competitiveness of green hydrogen improves significantly at higher efficiency and with pipeline infrastructure development it can become more economical when compared to propane. Hydrogen produced via plasma pyrolysis offers high environmental and economic costs due to its electricity and natural gas requirements. Sensitivity analysis further explores the impact of a 50% reduction in hydrogen production and transportation costs revealing that hydrogen could become a viable option for grain drying in both pipeline and trucking scenarios. This study highlights the long-term potential of hydrogen in reducing carbon emissions and offers insights into the economic feasibility of hydrogen adoption in agricultural drying processes. The findings suggest that strategic investments in hydrogen infrastructure could significantly enhance the sustainability of agricultural practices paving the way for a greener future in food production.
Hydrogen Strategies Under Uncertainty: Risk-Averse Choices for Green Hydrogen Pathways
Oct 2025
Publication
The last decade has been characterized by a growing environmental awareness and the rise of climate change concerns. Continuous advancement of renewable energy technologies in this context has taken a central stage on the global agenda leading to a diverse array of innovations ranging from cutting-edge green energy production technologies to advanced energy storage solutions. In this evolving context ensuring the sustainability of energy systems—through the reduction of carbon emissions enhancement of energy resilience and responsible resource integration—has become a primary objective of modern energy planning. The integration of hydrogen technologies for power-to-gas (P2G) and power-topower (P2P) and energy storage systems is one of the areas where the most remarkable progress is being made. However real case implementations are lagging behind expectations due to large-scale investments needed which under high energy price uncertainty act as a barrier to widespread adoption. This study proposes a risk-averse approach for sizing an Integrated Hybrid Energy System considering the uncertainty of electricity and gas prices. The problem is formulated as a mixed-integer program and tested on a real-world case study. The analysis sheds light on the value of synergies and innovative solutions that hold the promise of a cleaner more sustainable future for generations to come.
Modeling Hydrogen-Assisted Combustion of Liquid Fuels in Compression-Ignition Engines Using a Double-Wiebe Function
Oct 2025
Publication
This article discusses the potential of using the double-Wiebe function to model combustion in a compression-ignition engine fueled by diesel fuel or its substitutes such as hydrotreated vegetable oil (HVO) and rapeseed methyl ester (RME) and hydrogen injected into the engine intake manifold. The hydrogen amount ranged from 0 to 35% of the total energy content of the fuels burned. It was found that co-combustion of liquid fuel with hydrogen is characterized by two distinct combustion phases: premixed and diffusion combustion. The premixed phase occurring just after ignition is characterized by a rapid combustion rate which increases with an increase in hydrogen injected. The novelty in this work is the modified formula for a double-Wiebe function and the proposed parameters of this function depending on the amount of hydrogen added for co-combustion with liquid fuel. To model this combustion process the modified double-Wiebe function was proposed which can model two phases with different combustion rates. For this purpose a normalized HRR was calculated and based on this curve coefficients for the double-Wiebe function were proposed. Satisfactory consistency with the experiment was achieved at a level determined by the coefficient of determination (R-squared) of above 0.98. It was concluded that the presented double-Wiebe function can be used to model combustion in 0-D and 1-D models for fuels: RME and HVO with hydrogen addition.
Insights from Swirl Number and Ambient Pressure Variations with a Hydrogen/Ammonia Swirl Stabilized Diffusion Flame
Oct 2025
Publication
Contemporary research into decarbonized fuels such as H2/NH3 has highlighted complex challenges with applied combustion with marked changes in thermochemical properties leading to significant issues such as limited operational range flashback and instability particularly when attempts are made to optimize emissions production in conventional lean-premixed systems. Non-premixed configurations may address some of these issues but often lead to elevated NOx production particularly when ammonia is retained in the fuel mixture. Optimized fuel injection and blending strategies are essential to mitigate these challenges. This study investigates the application of a 75 %/25 %mol H2/NH3 blend in a swirl-stabilized combustor operated at elevated conditions of inlet temperature (500 K) and ambient pressure (0.11–0.6 MPa). A complex nonmonotonic relationship between swirl number and increasing ambient combustor pressure is demonstrated highlighting the intricate interplay between swirling flow structures and reaction kinetics which remains poorly understood. At medium swirl (SN = 0.8) an increase in pressure initially reduces NO emissions diminishing past ~0.3 MPa with an opposing trend evident for high swirl (SN = 2.0) as NO emissions fall rapidly when combustor pressure approaches 0.6 MPa. High-fidelity numerical modeling is presented to elucidate these interactions in detail. Numerical data generated using Detached Eddy Simulations (DES) were validated against experimental results to demonstrate a change in flame anchoring on the axial shear layer and marked change in recirculated flow structure successfully capturing the features of higher swirl number flows. Favorable comparisons are made with optical data and a reduction in NO emissions with increasing pressure is demonstrated to replicate changes to the swirling flame chemical kinetics. Findings provide valuable insights into the combustion behavior of hydrogen-rich ammonia flames contributing to the development of cleaner combustion technologies.
Hybrid Renewable Energy Systems for Off-Grid Electrification: A Comprehensive Review of Storage Technologies, Metaheuristic Optimization Approaches and Key Challenges
Nov 2025
Publication
Hybrid Renewable Energy Systems (HRESs) are a practical solution for providing reliable low-carbon electricity to off-grid and remote communities. This review examines the role of energy storage within HRESs by systematically comparing electrochemical mechanical thermal and hydrogen-based technologies in terms of technical performance lifecycle cost operational constraints and environmental impact. We synthesize findings from implemented off-grid projects across multiple countries to evaluate real-world performance metrics including renewable fraction expected energy not supplied (EENS) lifecycle cost and operation & maintenance burdens. Special attention is given to the emerging role of hydrogen as a long-term and cross-sector energy carrier addressing its technical regulatory and financial barriers to widespread deployment. In addition the paper reviews real-world implementations of off-grid HRES in various countries summarizing practical outcomes and lessons for system design and policy. The discussion also includes recent advances in metaheuristic optimization algorithms which have improved planning efficiency system reliability and cost-effectiveness. By combining technological operational and policy perspectives this review identifies current challenges and future directions for developing sustainable resilient and economically viable HRES that can accelerate equitable electrification in remote areas. Finally the review outlines key limitations and future directions calling for more systematic quantitative studies long-term field validation of emerging technologies and the development of intelligent Artificial Intelligence (AI)-driven energy management systems within broader socio-techno-economic frameworks. Overall this work offers concise insights to guide researchers and policymakers in advancing the practical deployment of sustainable and resilient HRES.
Hydrogen Blending as a Transitional Solution for Decarbonizing the Jordanian Electricity Generation Sector
Nov 2025
Publication
While renewable energy deployment has accelerated in recent years fossil fuels continue to play a dominant role in electricity generation worldwide. This necessitates the development of transitional strategies to mitigate greenhouse gas emissions from this sector while gradually reducing reliance on fossil fuels. This study investigates the potential of blending green hydrogen with natural gas as a transitional solution to decarbonize Jordan’s electricity sector. The research presents a comprehensive techno-economic and environmental assessment evaluating the compatibility of the Arab Gas Pipeline and major power plants with hydrogen–natural gas mixtures considering blending limits energy needs environmental impacts and economic feasibility under Jordan’s 2030 energy scenario. The findings reveal that hydrogen blending between 5 and 20 percent can be technically achieved without major infrastructure modifications. The total hydrogen demand is estimated at 24.75 million kilograms per year with a reduction of 152.7 thousand tons of carbon dioxide per annum. This requires 296980 cubic meters of water per year equivalent to only 0.1 percent of the National Water Carrier’s capacity indicating a negligible impact on national water resources. Although technically and environmentally feasible the project remains economically constrained requiring a carbon price of $1835.8 per ton of carbon dioxide for economic neutrality.
Green Hydrogen as a Decarbonization Pathway for Steel Industry in Pakistan
Nov 2025
Publication
The global steel industry emits 1.92 tons of CO2 per ton of output and faces urgent pressure to decarbonize. In Pakistan the sector accounts for 0.29 tons of CO2 per ton of output with limited mitigation frameworks in place. Green hydrogen (GH2)-based steelmaking offers a strategic pathway toward decarbonization. However realizing its potential depends on access to renewable energy. Despite Pakistan’s substantial technical wind potential of 340 GW grid limitations currently restrict wind power to only 4% of national electricity generation. This study explores GH2 production through sector coupling and power wheeling repurposing curtailed wind energy from Sindh to supply Karachi’s steel industry and proposing a phased roadmap for GH enabling fossil fuel substitution industrial resilience and alignment with global carbon-border regulations.
An Effective Integrated Optimal Day-ahead and Real-time Power Scheduling Approach for Hydrogen-based Microgrid
Oct 2025
Publication
The increasing penetration of renewable energy sources in power systems poses significant challenges for maintaining grid reliability mainly due to the variability and uncertainty of solar and demand profiles. Microgrids equipped with diverse storage technologies have emerged as a promising solution to address these issues.This paper proposes an integrated day-ahead and real-time power scheduling approach for grid-connected microgrids equipped with both conventional and hydrogen-based ESSs. While existing strategies often address day-ahead and real-time scheduling separately or rely on a single storage technology this work introduces a unified framework that exploits the complementary characteristics of batteries and hydrogen systems. The proposed approach is based on a novel two-stage stochastic optimization model embedded within a hierarchical optimization framework to address these two intertwined problems efficiently. For the day-ahead scheduling a two-stage stochastic programming energy management model is solved to optimize the microgrid schedule based on forecasted load demand and PV production profiles. Building upon the day-ahead schedule another optimization model is solved which addresses real-time power imbalances caused by deviations in actual PV production and load demand power profiles with respect to the forecasted ones with the aim of minimizing operational disruptions. Simulation results demonstrate the validity of the proposed approach achieving both cost reductions and minimal power imbalances. By dynamically adjusting energy flows and using both conventional batteries and hydrogen systems the proposed approach ensures improved reliability reduced operational costs and enhanced integration of RES in microgrids. These findings highlight the potential of the proposed hierarchical framework to support the large-scale deployment of RES while ensuring resilient and cost-effective microgrid operations.
Blockchain-based Traceability and Certifications of Hydrogen Refueling Station Components
Oct 2025
Publication
As hydrogen gains prominence in energy systems its adoption as an energy source for fuel cell electric vehicles (FCEVs) necessitates the establishment of hydrogen refueling stations (HRS). These stations contain critical compo-nents including nozzles storage tanks heat exchangers and compressors which must be certified by regulatory agen-cies to ensure safety and public trust. Current certification processes are fragmented and manually intensive creating inefficiencies and limiting transparency across the infrastructure lifecycle. In this paper we propose a blockchain-based solution that creates a secure and auditable network for certifying key HRS components. The system integrates an EVM-compatible blockchain decentralized storage and a modular suite of smart contracts (SCs) that formalize registration bidding accreditation certification and governance. Each contract encodes a distinct actor-driven work-flow enabling traceable and role-specific operations. A Decentralized Application (DApp) interface supports real-time and role-based interaction across the ecosystem. We present and evaluate the SCs and their underlying algorithms us-ing gas usage analysis load testing and security auditing. Load testing across the certification lifecycle shows stable transaction throughput and predictable cost profiles under increasing actor activity. A static security analysis con-firms resilience against common vulnerabilities. Our cost analysis indicates that while the framework is technically deployable on public blockchains the execution costs of certain functions make it more cost-effective for private blockchains or Layer 2 networks. We also compare our framework with existing systems to highlight its novelty and technical advantages. Our SCs DApp interface and load testing scripts are publicly available on GitHub.
Uncertainty Ahead: Should Stand-alone Energy Systems Bet on Hydrogen Backup?
Oct 2025
Publication
Achieving net zero by 2050 will require decarbonising stand-alone energy applications. Hydrogen is increasingly viewed as a promising energy carrier but its economic viability remains uncertain due to the lack of consensus on future demand and limited deployment of key components such as fuel cells in stationary stand-alone applications. This study investigates whether hybridising batteries with hydrogen can deliver meaningful cost benefits under future cost trajectories. Using a Monte Carlo framework we simulate 8000 scenarios across constant and seasonal load profiles varying the capital costs of batteries fuel cells electrolysers and hydrogen tanks based on 2025 estimates and 2050 projections. Our results show that hydrogen integration only becomes economically attractive when multiple component costs decline simultaneously. The fuel cell-to-battery power capital cost ratio emerges as the dominant driver of levelised cost of energy (LCOE) improvements. For constant loads median LCOE savings remain below 12 % with more than 5 % savings only achieved when the fuel cell cost is less than 7 times that of the battery. Seasonal nighttime loads offer a wider theoretical LCOE savings range (0–156 %) but substantial gains occur only under unrealistic cost mixes where battery costs remain high and fuel cell costs fall sharply. These findings highlight the sensitivity of hydrogen viability to load profile characteristics and cost interdependencies. They underscore the need for targeted cost reduction strategies particularly for fuel cells to justify added system complexity. These findings are important considerations for future investment and policy decisions.
Life Cycle Assessment of Hydrogen-based Fuels Use in Internal Combustion Engines of Container Ships until 2050
Oct 2025
Publication
Hydrogen-based fuels are potential candidates to help international shipping achieve net-zero greenhouse gas (GHG) emissions by around 2050. This paper quantifies the environmental impacts of liquid hydrogen liquid ammonia and methanol used in a Post-Panamax container ship from 2020 to 2050. It considers cargo capacity changes electricity decarbonization and hydrogen production transitions under two International Energy Agency scenarios: the Stated Policies Scenario (STEPS) and the Net Zero Emissions by 2050 Scenario (NZE). Results show that compared to the existing HFO ship hydrogen-based propulsion systems can decrease cargo weight capacity by 0.3 % to 25 %. In the NZE scenario hydrogen-based fuels can reduce GHG emissions per tonne-nautical mile by 48 %–65 % compared to heavy fuel oil by 2050. Even with fully renewable hydrogenbased fuels 18 %–31 % of GHG emissions would still remain. Using hydrogen-based fuels in internal combustion engines requires attention to minimize environmental trade-offs.
Modeling Electrochemical Impedance Spectroscopy of Hydrogen Complexes During Hydrogen Evolution on Single-stom Electrocatalysts
Nov 2025
Publication
Single Atom Catalysts (SACs) are an emerging frontier in heterogeneous electrocatalysis. They are made of metal atoms atomically dispersed on a matrix. A lot of attention has been dedicated to the study of Hydrogen Evolution Reaction (HER) mechanism due to its relevance in energy conversion technologies both with computational and experimental methods. The classical HER mechanism can be described by a Volmer–Heyrovsky–Tafel mechanism where the two desorption steps are competitive. The Volmer-Heyrovsky mechanism is conventionally proposed for single-atom catalysts. It has been computationally demonstrated that hydrogen complexes can form on SACs due to their analogy with homogeneous catalysts. Unfortunately it is hard to “visualize” these species experimentally. Electrochemical Impedance Spectroscopy (EIS) could be the most promising approach to study electrocatalytic mechanisms. In this work we present microkinetic and Electrochemical Impedance Spectroscopy models for HER on SACs describing Volmer-Heyrovsky and a mechanism mediated by the formation of hydrogen complexes. Our simulated data applied to a case study based on Pd@TiN show that Tafel plots will not suffice in the visualization of hydrogen complexes formation and will need the support of electrochemical impedance spectra in order to clarify the correct mechanism.
The Development of an Analysis Framework for the Integration of Low-carbon Hydrogen into Multi-regional Natural Gas Energy Systems
Nov 2025
Publication
In 2023 global carbon dioxide emissions reached 40 billion tonnes 60 % more than in 1990 intensifying climate concerns. This study explores hydrogen-natural gas blending as a transitional strategy for decarbonization across several regions and energy sectors – residential commercial industrial and agricultural. A multi-regional analysis framework evaluates integration of 20 % by volume low-carbon hydrogen blending into natural gas systems by identifying hydrogen producers importers and exporters based on production and import costs. Applied to Canada 528 scenarios (2026–2050) assess inter-regional hydrogen trade within Canadian provinces. The lowest-cost scenario involves Alberta exporting hydrogen produced through autothermal reforming with 91 % carbon capture and storage and British Columbia producing its own. The grid electrolysis scenario achieves the highest GHG reductions with a 4.5 % GHG mitigation in Canada with full energy system representation. These findings provide insights for policymakers and stakeholders in advancing hydrogen infrastructure and decarbonization strategies.
Techno-economic Analysis of Technologies for Decarbonizing Low- and Medium-Temperature Industrial Heat
Dec 2025
Publication
Decarbonizing industrial heat is critical for achieving climate targets. This study evaluates the economic viability of technologies for decarbonizing industrial heat in Europe through a techno-economic analysis. High-temperature heat pumps (HTHPs) and electric hydrogen and biomass boilers are compared in terms of levelized cost of heat (LCOH) under various scenarios including the impact of thermal storage leveraging dynamic electricity prices. In scenarios for the year 2030 we show that HTHPs leveraging free excess heat achieve LCOH values at least 30% to 60% lower than hydrogen boilers and up to 37% lower than biomass boilers. Integrating daily thermal storage reduces LCOH by up to 15% for heat pumps and 27% for electric boilers. By 2050 anticipated cost and efficiency improvements further enhance the competitiveness of heat pumps. These results highlight the economic advantage of HTHPs particularly when integrating excess heat and thermal storage.
Hydrogen Reduction of Combusted Iron Powder: Role of the Fluidization Regime on the Conversion
Nov 2025
Publication
Fluidized bed systems play a crucial role in industrial processes such as combustion and gasification. In the Iron Power Cycle fluidized bed systems are essential for enabling the reduction of combusted iron back to iron making them a critical component in the regeneration step of the cycle. This study investigates the impact of operating gas velocity on conversion by performing reduction experiments at three distinct fluidization numbers (us/umf): 16 (bubbling regime) 55 (transition region) and 100 (fully turbulent regime). Experiments were conducted to determine the appropriate velocities for each regime ensuring optimal fluidization conditions across reduction temperatures ranging from 500 to 700 ⚬C. The results reveal that conversion rates increase significantly with gas velocities. At 500 ⚬C operating at approximately six times higher velocity leads to a sixfold improvement in conversion when using iron-oxide particles with a Sauter mean diameter of 61 µm. However while enhanced velocities improve reaction efficiency challenges remain at elevated temperatures (T ≥ 500 ⚬C) where iron undergoes defluidization when exposed to hydrogen. Once defluidization occurs refluidization proves impossible with either hydrogen or nitrogen raising concerns about process stability. These insights highlight the potential for optimizing fluidized bed reduction through velocity control while also underscoring the need for additional measures to mitigate unstable fluidization during high-temperature iron oxide reduction.
Techno-economic Assessment of Retrofitted Combined-cycles for Power-to-hydrogen-to-power Systems in European Electricity Markets
Oct 2025
Publication
This paper investigates the performance and economic viability of Combined Cycle Gas Turbines (CCGT) operating on natural gas (NG) and hydrogen within the context of evolving electricity markets. The study is structured into several sections beginning with a benchmark analysis to establish baseline performance metrics including break-even prices and price margins for CCGTs running on NG. The research then explores various base cases and sensitivity analyses focusing on different CCGT capacity factors and the uncertainties surrounding key parameters. The study also compares the performance of CCGTs across different European countries highlighting the impact of increased price fluctuations in forecasted electricity markets. Additionally the paper examines Power-to-X-to-Power (P2X2P) configurations assessing the economic feasibility of hydrogen production and its integration into CCGT operations. The analysis considers scenarios where hydrogen is sourced externally or produced on-site using renewable energy or grid electricity during off-peak hours. The results provide insights into the competitiveness and adaptability of CCGTs in a transitioning energy landscape emphasizing the potential role of hydrogen as a flexible and sustainable energy carrier.
Applied Simulation Study of a Metal Hydride Refrigeration System for Fuel Cell Trucks
Oct 2025
Publication
Refrigeration units in semi-trucks or rigged-body trucks have an energy demand of 8.2–12.4 MWh/y and emit 524.26 kt CO2e/y in Germany. Electrification with fuel cell systems reduces the CO2 emission but an increase of efficiency is necessary because of rapidly increasing hydrogen costs. A metal hydride refrigeration system can increase the efficiency. Even though it was already demonstrated in lab scale with 900 W this power is not sufficient to support a truck refrigeration system and the power output of the lab system was not controllable. Here we show the design and validation of a MATLAB© Simulink model of this metal hydride refrigeration system and its suitability for high power applications with a scaled-up reactor. It was scaled up to rated power of 5 kW and efficiency improvements with an advanced valve switching as well as a controlled cooling pump were implemented. Two application-relevant use cases with hydrogen mass flows from hydrogen fuel cell truck systems were analyzed. The simulation results of these use cases provide an average cooling power of 4.2 and 6.1 kW. Additionally the control of the coolant mass flow at different temperature levels a controlled hydrogen mass flow with a bypass system and an advanced valve switching mechanism increased the system efficiency of the total refrigeration system by 30 % overall.
Energy Management of Hybrid Energy System Considering a Demand-Side Management Strategy and Hydrogen Storage System
Oct 2025
Publication
Nadia Gouda and
Hamed Aly
A hybrid energy system (HES) integrates various energy resources to attain synchronized energy output. However HES faces significant challenges due to rising energy consumption the expenses of using multiple sources increased emissions due to non-renewable energy resources etc. This study aims to develop an energy management strategy for distribution grids (DGs) by incorporating a hydrogen storage system (HSS) and demand-side management strategy (DSM) through the design of a multi-objective optimization technique. The primary focus is on optimizing operational costs and reducing pollution. These are approached as minimization problems while also addressing the challenge of achieving a high penetration of renewable energy resources framed as a maximization problem. The third objective function is introduced through the implementation of the demand-side management strategy aiming to minimize the energy gap between initial demand and consumption. This DSM strategy is designed around consumers with three types of loads: sheddable loads non-sheddable loads and shiftable loads. To establish a bidirectional communication link between the grid and consumers by utilizing a distribution grid operator (DGO). Additionally the uncertain behavior of wind solar and demand is modeled using probability distribution functions: Weibull for wind PDF beta for solar and Gaussian PDF for demand. To tackle this tri-objective optimization problem this work proposes a hybrid approach that combines well-known techniques namely the non-dominated sorting genetic algorithm II and multi-objective particle swarm optimization (Hybrid-NSGA-II-MOPSO). Simulation results demonstrate the effectiveness of the proposed model in optimizing the tri-objective problem while considering various constraints.
Decarbonising Sustainable Aviation Fuel (SAF) Pathways: Emerging Perspectives on Hydrogen Integration
Oct 2025
Publication
The growing demand for air connectivity coupled with the forecasted increase in passengers by 2040 implies an exigency in the aviation sector to adopt sustainable approaches for net zero emission by 2050. Sustainable Aviation Fuel (SAF) is currently the most promising short-term solution; however ensuring its overall sustainability depends on reducing the life cycle carbon footprints. A key challenge prevails in hydrogen usage as a reactant for the approved ASTM routes of SAF. The processing conversion and refinement of feed entailing hydrodeoxygenation (HDO) decarboxylation hydrogenation isomerisation and hydrocracking requires substantial hydrogen input. This hydrogen is sourced either in situ or ex situ with the supply chain encompassing renewables or non-renewables origins. Addressing this hydrogen usage and recognising the emission implications thereof has therefore become a novel research priority. Aside from the preferred adoption of renewable water electrolysis to generate hydrogen other promising pathways encompass hydrothermal gasification biomass gasification (with or without carbon capture) and biomethane with steam methane reforming (with or without carbon capture) owing to the lower greenhouse emissions the convincing status of the technology readiness level and the lower acidification potential. Equally imperative are measures for reducing hydrogen demand in SAF pathways. Strategies involve identifying the appropriate catalyst (monometallic and bimetallic sulphide catalyst) increasing the catalyst life in the deoxygenation process deploying low-cost iso-propanol (hydrogen donor) developing the aerobic fermentation of sugar to 14 dimethyl cyclooctane with the intermediate formation of isoprene and advancing aqueous phase reforming or single-stage hydro processing. Other supportive alternatives include implementing the catalytic and co-pyrolysis of waste oil with solid feedstocks and selecting highly saturated feedstock. Thus future progress demands coordinated innovation and research endeavours to bolster the seamless integration of the cutting-edge hydrogen production processes with the SAF infrastructure. Rigorous technoeconomic and life cycle assessments alongside technological breakthroughs and biomass characterisation are indispensable for ensuring scalability and sustainability
Coordinated Control Strategy for Island Power Generation System with Photovoltaic, Hydrogen-Fueled Gas Turbine and Hybrid Energy Storage
Oct 2025
Publication
Marine and island power systems usually incorporate various forms of energy supply which poses challenges to the coordinated control of the system under diverse irregular and complex load operation modes. To improve the stability and self-sufficiency of island-isolated microgrids with high penetration of renewable energy this study proposes a coordinated control strategy for an island microgrid with PV HGT and HESS combining primary power allocation via low-pass filtering with a fuzzy logic-based secondary correction. The fuzzy controller dynamically adjusts power distribution based on the states of charge of the battery and supercapacitor following a set of predefined rules. A comprehensive system model is developed in Matlab R2023b integrating PV generation an electrolyzer HGT and a battery–supercapacitor HESS. Simulation results across four operational cases demonstrate that the proposed strategy reduces DC bus voltage fluctuations to a maximum of 4.71% (compared to 5.63% without correction) with stability improvements between 0.96% and 1.55%. The HESS avoids overcharging and over-discharging by initiating priority charging at low SOC levels thereby extending service life. This work provides a scalable control framework for enhancing the resilience of marine and island microgrids with high renewable energy penetration.
Analysis of Fuel Cell Electric Vehicle Performance Under Standard Electric Vehicle Driving Protocol
Nov 2025
Publication
The paper studies and analyzes electric vehicle engines powered by hydrogen under the WLTP standard driving protocol. The driving range extension is estimated using a specific protocol developed for FCEV compared with the standard value for battery electric vehicles. The driving range is extended by 10 km averaging over the four protocols with a maximum of 11.6 km for the FTP-75 and a minimum of 7.7 km for the WLTP. This driving range extension represents a 1.8% driving range improvement on average. Applying the FCEV current weight the driving range is extended to 18.9 km and 20.4 km on average when using power source energy capacity standards for BEVs and FCEVs.
Rooftop Agrivoltaic Powered Onsite Hydrogen Production for Insulated Gasochromic Smart Glazing and Hydrogen Vehicles: A Holistic Approach to Sustainable Residential Building
Nov 2025
Publication
The study focused on designing a sustainable building involving rooftop agrivoltaics advanced glazing technologies and onsite hydrogen production for a residential property in Birmingham UK where green hydrogen produced by harnessing electricity generated by agrivoltaics system on rooftop of the building is employed to change the transparency of vacuum gasochromic glazing and refuel hydrogen-powered fuel cell vehicle using storage hydrogen for a sustainable building approach. The change in the transparency of the glazing reduces the energy requirement of the building according to the occupant’s requirement and weather conditions. This research investigates the performance of various rooftop agrivoltaic systems including vertical optimal 30◦ tilt and dome setups for both monofacial and bifacial agrivoltaic consisting of tomato farming. Promising results were observed for agrivoltaic systems with consistent tomato production of 0.31 kg/m2 with varying shading experienced due to the different photovoltaic setups. Maximum electricity is produced by bifacial 30◦ with 7919 kWh though the lowest LCOE can be observed by monofacial 30◦ with £0.061/kWh. It also compares the efficiency of vacuum gasochromic windows against double glazing vacuum double glazing electrochromic and gasochromic options which can play an essential role in energy saving and reduced carbon emission. Vacuum gasochromic demonstrated the lowest U-value of 1.32 Wm2 K though it has the highest thickness with 24.6 mm. Additionally the study examines the feasibility of small-scale green hydrogen production from the electricity generated by agrivoltaics to fuel hydrogen vehicles and glazing considering the economic viability. The results suggested that the hydrogen required by the glazing accounts for 52.56 g annually and the maximum distance that can be covered theoretically is by bifacial 30◦ which is approximately 64.23 km per day. The interdisciplinary approach aims to optimise land use enhance energy efficiency and promote sustainable urban agriculture to contribute to the UK’s goal of increasing solar energy capacity and achieving net-zero emissions while addressing food security concerns. The findings of this study have potential implications for urban planning renewable energy integration especially solar and sustainable residential design.
Interleaved Parallel VDCM Improves Stability Control of Wind Power-hydrogen Coupled Integrated System
Nov 2025
Publication
Aiming at the problems of poor transient characteristics of converter output DC voltage and large DC current ripple caused by alkaline electrolyzer (AEL) switching operation in the wind power-hydrogen coupled integrated system this paper proposes an interleaved parallel VDCM control method to improve the stable operation of the system. Firstly a refined mathematical-physical model of the wind power-hydrogen coupled integrated system including HD-PMSG interleaved parallel buck and AEL is constructed. Then the VDCM control strategy is introduced into the interleaved parallel buck converter which provides reliable inertia and damping support for the output voltage of the hydrogen production system by simulating the DC motor power regulation characteristics and effectively improving the current ripple of the output current. Meanwhile the influence of rotational inertia and the damping coefficient on the dynamic stability of the system in the control strategy is analyzed based on the small signal method. Finally the proposed method is validated through MATLAB/SIMULINK simulation experiments and RCP + HIL hardware-in-the-loop experiments. The results show that the proposed method can improve the dynamic stability of the wind power-hydrogen coupled integrated system effectively.
A Pathway to Decarbonizing Cement Manufacturing via Solar-driven Green Hydrogen Systems
Nov 2025
Publication
The cement industry a foundation of infrastructure development is responsible for nearly 7 % of global CO2 emissions highlighting an urgent need for scalable decarbonization strategies. This study investigates the technoeconomic feasibility of integrating on-site solar-powered green hydrogen production into cement manufacturing processes. A mixed-integer linear programming (MILP) model optimizes the design and operation of solar photovoltaics (PV) proton exchange membrane (PEM) electrolyzer and hydrogen storage for a representative cement plant in Texas. Five hydrogen substitution scenarios (10–30 % of thermal demand) were evaluated based on net present cost (NPC) levelized cost of hydrogen (LCOH) cost of CO2 avoided and greenhouse gas (GHG) emissions reduction. Hydrogen integration up to 30 % is technically viable but economically constrained with LCOH rising non-linearly from $58.7 to $95.3 GJ− 1 due to escalating component costs. Environmentally a 30 % hydrogen share could reduce total U.S. cement sector emissions by 22 %. While significant this confirms at present the solar-driven hydrogen serves as a partial solution rather than a standalone pathway to deep decarbonization suggesting it must complement other strategies like carbon capture electrification and other complementary technologies. The economic viability of this approach is entirely contingent on financial incentives as the investment tax credits of 80 % or higher are essential to enable cost parity with fossil fuels. This work provides a comprehensive techno-economic and environmental framework concluding immense economic barriers and that aggressive policy support is indispensable for enabling the transition to low-carbon cement manufacturing.
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