United Kingdom
Propulsion of a Hydrogen-fuelled LH2 Tanker Ship
Mar 2022
Publication
This study aims to present a philosophical and quantitative perspective of a propulsion system for a large-scale hydrogen-fuelled liquid-hydrogen (LH2) tanker ship. Established methods are used to evaluate the design and performance of an LH2-carrier propulsion system for JAMILA a ship designed with four cylindrical LH2 tanks bearing a total capacity of ~280000 m3 along with cargo and using the boil-off as propulsion and power fuel. Additionally the ship propulsion system is evaluated based on the ship resistance requirements and a hydrogen-fuelled combined-cycle gas turbine is modelled to achieve the dual objectives of high efficiency and zero-carbon footprint. The required inputs primarily involve the off-design and degraded performance of the gas-turbine topping cycle and the proposed power plant operates with a total output power of 50 M.W. The results reveal that the output power allows ship operation at a great speed even with a degraded engine and adverse ambient conditions.
SGN Aberdeen Vision Project: Final Report
May 2020
Publication
The Aberdeen Vision Project could deliver CO2 savings of 1.5MtCO2/y compared with natural gas. A dedicated pipeline from St Fergus to Aberdeen would enable the phased transfer of the Aberdeen regional gas distribution system to 20% then 100% hydrogen.
The study has demonstrated that 2% hydrogen can be injected into the National Transmission System (NTS) at St Fergus and its distribution through the system into the gas distribution network. Due to unique regional attributes the Aberdeen region could lead the UK in the conversion to largescale clean hydrogen. A 200MW hydrogen generation plant is planned to suit 2% blend into the NTS followed by a build out to supply the Aberdeen gas networks and to enable low cost hydrogen transport applications.
This report and any attachment is freely available on the ENA Smarter Networks Portal here. IGEM Members can download the report and any attachment directly by clicking on the pdf icon above.
The study has demonstrated that 2% hydrogen can be injected into the National Transmission System (NTS) at St Fergus and its distribution through the system into the gas distribution network. Due to unique regional attributes the Aberdeen region could lead the UK in the conversion to largescale clean hydrogen. A 200MW hydrogen generation plant is planned to suit 2% blend into the NTS followed by a build out to supply the Aberdeen gas networks and to enable low cost hydrogen transport applications.
This report and any attachment is freely available on the ENA Smarter Networks Portal here. IGEM Members can download the report and any attachment directly by clicking on the pdf icon above.
Integration of Experimental Facilities: A Joint Effort for Establishing a Common Knowledge Base in Experimental Work on Hydrogen Safety
Sep 2009
Publication
With regard to the goals of the European HySafe Network research facilities are essential for the experimental investigation of relevant phenomena for testing devices and safety concepts as well as for the generation of validation data for the various numerical codes and models. The integrating activity ‘Integration of Experimental Facilities (IEF)’ has provided basic support for jointly performed experimental work within HySafe. Even beyond the funding period of the NoE HySafe in the 6th Framework Programme IEF represents a long lasting effort for reaching sustainable integration of the experimental research capacities and expertise of the partners from different research fields. In order to achieve a high standard in the quality of experimental data provided by the partners emphasis was put on the know-how transfer between the partners. The strategy for reaching the objectives consisted of two parts. On the one hand a documentation of the experimental capacities has been prepared and analysed. On the other hand a communication base has been established by means of biannual workshops on experimental issues. A total of 8 well received workshops has been organised covering topics from measurement technologies to safety issues. Based on the information presented by the partners a working document on best practice including the joint experimental knowledge of all partners with regard to experiments and instrumentation was created. Preserving the character of a working document it was implemented in the IEF wiki website which was set up in order to provide a central communication platform. The paper gives an overview of the IEF network activities over the last 5 years.
Vented Confined Explosions Involving Methane/Hydrogen Mixtures
Sep 2009
Publication
The EC funded Naturalhy project is assessing the potential for using the existing gas infrastructure for conveying hydrogen as a mixture with natural gas (methane). The hydrogen could then be removed at a point of use or the natural gas/hydrogen mixture could be burned in gas-fired appliances thereby providing reduced carbon emissions compared to natural gas. As part of the project the impact on the safety of the gas system resulting from the addition of hydrogen is being assessed. A release of a natural gas/hydrogen mixture within a vented enclosure (such as an industrial housing of plant and equipment) could result in a flammable mixture being formed and ignited. Due to the different properties of hydrogen the resulting explosion may be more severe for natural gas/hydrogen mixtures compared to natural gas. Therefore a series of large scale explosion experiments involving methane/hydrogen mixtures has been conducted in a 69.3 m3 enclosure in order to assess the effect of different hydrogen concentrations on the resulting explosion overpressures. The results showed that adding up to 20% by volume of hydrogen to the methane resulted in a small increase in explosion flame speeds and overpressures. However a significant increase was observed when 50% hydrogen was added. For the vented confined explosions studied it was also observed that the addition of obstacles within the enclosure representing congestion caused by equipment and pipework etc. increased flame speeds and overpressures above the levels measured in an empty enclosure. Predictions of the explosion overpressure and flame speed were also made using a modified version of the Shell Global Solutions model SCOPE. The modifications included changes to the burning velocity and other physical properties of methane/hydrogen mixtures. Comparisons with the experimental data showed generally good agreement.
Ignition Energy and Ignition Probability of Methane-Hydrogen-Air Mixtures
Sep 2009
Publication
The European Commission are funding an investigation of the feasibility of using existing natural gas infrastructures to transport and distribute hydrogen as a mixture of natural gas and hydrogen from the point of hydrogen production to the point of use. Since hydrogen has different chemical and physical properties to that of natural gas and these will affect the integrity and durability of the pipeline network and the ignition and combustion behaviour of released gas it is necessary to assess the change in risk to the public that would result. The subject of this paper is an experimental study of the effect of the hydrogen content of the natural gas-hydrogen mixture on the minimum energy required for ignition and the probability of achieving ignition given a particular level of energy discharge. It was possible to normalize the results for ignition energy such that given information on the minimum ignition energy and the equivalence ratio at which the minimum ignition energy occurs the lowest ignition energy for any other equivalence ratio can be predicted. The results also showed that the ignition process has a probabilistic element and that the probability of ignition is related to the equivalence ratio and the energy level of the source. It was observed that the probability of ignition increased with increasing energy of the source and that the rate of rise in probability was steepest for the equivalence ratios close to the equivalence ratio at which the minimum ignition energy occurs.
Numerical Simulation of Large Scale Hydrogen Detonation
Sep 2009
Publication
The present work is concerned with numerical simulations of large scale hydrogen detonations. Euler equations have been solved along with a single step reaction for the chemistry. Total variation diminishing (TVD) numerical schemes are used for shock capturing. The equations are solved in parallel in a decomposed domain. Predictions were firstly conducted with a small domain to ensure that the reaction scheme has been properly tuned to capture the correct detonation pressure and velocity. On this basis simulations were set up for the detonation tests carried out at the RUT tunnel facilities in Russia. This is one of the standard benchmark test cases selected for HYSAFE [1]. Comparison is made between the predictions and measurements. Reasonably good agreement has been obtained on pressure decay and the propagation speed of detonation. Further simulations were then conducted for a hypothetical hydrogen-air cloud in the open to assess the impulse as well as overpressure. The effects of cloud height width were investigated in the safety context.
A Comparison Exercise on the CFD Detonation Simulation in Large Scale Confined Volumes
Sep 2009
Publication
The use of hydrogen as an energy carrier is going to widen exponentially in the next years. In order to ensure the public acceptance of the new fuel not only the environmental impact has to be excellent but also the risk management of its handling and storage must be improved. As a part of modern risk assessment procedure CFD modeling of the accident scenario development must provide reliable data on the possible pressure loads resulted from explosion processes. The expected combustion regimes can be ranged from slow flames to deflagration-to-detonation transition and even to detonation. In the last case the importance of the reliability of simulation results is particularly high since detonation is usually considered as a worst case state of affairs. A set of large-scale detonation experiments performed in Kurchatov Institute at RUT facility was selected as benchmark. RUT has typical industry-relevant characteristic dimensions. The CFD codes possibilities to correctly describe detonation in mixtures with different initial and boundary conditions were surveyed. For the modeling two detonation tests HYD05 and HYD09 were chosen; both tests were carried out in uniform hydrogen/air mixtures; first one with concentration of 20.0% vol. and the second one with 25.5% vol. In the present exercise three CFD codes using a number of different models were used to simulate these experiments. A thorough inter-comparison between the CFD results including codes models and obtained pressure predictions was carried out and reported. The results of this inter comparison should provide a solid basis for the further code development and detonation models’ validation thus improving CFD predictive capabilities.
Consequences of Catastrophic Releases of Ignited and Unignited Hydrogen Jet Releases
Sep 2009
Publication
The possibility of using a risk based approach for the safe installation and siting of stationary fuel cell systems depends upon the availability of normative data and guidance on potential hazards and the probabilities of their occurrence. Such guidance data is readily available for most common hydrocarbon fuels. For hydrogen however data is still required on the hazards associated with different release scenarios. This data can then be related to the probability of different types of scenarios from historical fault data to allow safety distances to be defined and controlled using different techniques. Some data on releases has started to appear but this data generally relates to hydrogen vehicle refuelling systems that are designed for larger throughput higher pressures and the general use of larger pipe diameters than are likely to be used for small fuel cell systems.
Prediction of Third Party Damage Failure Frequency for Pipelines Transporting Mixtures of Natural Gas and Hydrogen
Sep 2009
Publication
As Europe is gradually moving towards a hydrogen based society it has been acknowledged that adding certain amount of hydrogen as a clean energy carrier to the existing natural gas pipeline will help reduce the CO2 emissions which contribute to the greenhouse effect. On the other hand hydrogen has been demonstrated to be able to change the behaviour of the pipeline steel such as lower toughness and faster crack growth due to hydrogen embrittlement. Therefore it is necessary that the risks associated with the failure of the pipeline carrying mixtures of natural gas and hydrogen be assessed.<br/>The study reported in this paper is part of European NATURALHY project whose aim is to investigate the possibility of using the existing natural gas transmission pipelines to convey natural gas/hydrogen mixtures. According to the EGIG database the most common cause of failure for the existing natural gas pipelines is third party damage which mainly refers to a gouge a dent/gouge combination of known geometry. Among third party damage failures 90% are the result of immediate failure i.e. leakage or rupture of the pipeline and only 10% of them are the result of delayed failure. While its not expected that hydrogen will impact the immediate failure it could increase the vulnerability of the pipe to delayed failure through the initiation or activation of crack like defects.<br/>This paper will present a methodology to predict the probability of increased failures and describe a software tool that has been developed to perform the calculations.
Benchmark Exercise on Risk Assessment Methods Applied to a Virtual Hydrogen Refuelling Station
Sep 2009
Publication
A benchmarking exercise on quantitative risk assessment (QRA) methodologies has been conducted within the project HyQRA under the framework of the European Network of Excellence (NoE) HySafe. The aim of the exercise was basically twofold: (i) to identify the differences and similarities in approaches in a QRA and their results for a hydrogen installation between nine participating partners representing a broad spectrum of background in QRA culture and history and (ii) to identify knowledge gaps in the various steps and parameters underlying the risk quantification. In the first step a reference case was defined: a virtual hydrogen refuelling station (HRS) in virtual surroundings comprising housing school shops and other vulnerable objects. All partners were requested to conduct a QRA according to their usual approach and experience. Basically participants were free to define representative release cases to apply models and frequency assessments according their own methodology and to present risk according to their usual format. To enable inter-comparison a required set of results data was prescribed like distances to specific thermal radiation levels from fires and distances to specific overpressure levels. Moreover complete documentation of assumptions base data and references was to be reported. It was not surprising that a wide range of results was obtained both in the applied approaches as well as in the quantitative outcomes and conclusions. This made it difficult to identify exactly which assumptions and parameters were responsible for the differences in results as the paper will show. A second phase was defined in which the QRA was determined by a more limited number of release cases (scenarios). The partners in the project agreed to assess specific scenarios in order to identify the differences in consequence assessment approaches. The results of this phase provide a better understanding of the influence of modelling assumptions and limitations on the eventual conclusions with regard to risk to on-site people and to the off-site public. This paper presents the results and conclusions of both stages of the exercise.
Advanced Steam Reforming of Bio-Oil with Carbon Capture: A Techno-Economic and CO2 Emissions Analysis
Apr 2022
Publication
A techno-economic analysis has been used to evaluate three processes for hydrogen production from advanced steam reforming (SR) of bio-oil as an alternative route to hydrogen with BECCS: conventional steam reforming (C-SR) C-SR with CO2 capture (C-SR-CCS) and sorption-enhanced chemical looping (SE-CLSR). The impacts of feed molar steam to carbon ratio (S/C) temperature pressure the use of hydrodesulphurisation pretreatment and plant production capacity were examined in an economic evaluation and direct CO2 emissions analysis. Bio-oil C-SR-CC or SE-CLSR may be feasible routes to hydrogen production with potential to provide negative emissions. SE-CLSR can improve process thermal efficiency compared to C-SR-CCS. At the feed molar steam to carbon ratio (S/C) of 2 the levelised cost of hydrogen (USD 3.8 to 4.6 per kg) and cost of carbon avoided are less than those of a C-SR process with amine-based CCS. However at higher S/C ratios SE-CLSR does not have a strong economic advantage and there is a need to better understand the viability of operating SE-CLSR of bio-oil at high temperatures (>850 ◦C) with a low S/C ratio (e.g. 2) and whether the SE-CLSR cycle can sustain low carbon deposition levels over a long operating period.
Predicting Radiative Characteristics of Hydrogen and Hythane Jet Fires Using Firefoam
Sep 2013
Publication
A possible consequence of pressurized hydrogen release is an under-expanded jet fire. Knowledge of the flame length radiative heat flux and fraction as well as the effects of variations in ground reflectance is important for safety assessment. The present study applies an open source CFD code FireFOAM to study the radiation characteristics of hydrogen and hydrogen/methane jet fires. For combustion the eddy dissipation concept for multi-component fuels recently developed by the authors in the large eddy simulation (LES) framework is used. The radiative heat is computed with the finite volume discrete ordinates model in conjunction with the weighted-sum-of-gray-gases model for the absorption/emission coefficient. The pseudo-diameter approach is used in which the corresponding parameters are calculated using the correlations of Birch et al. [22]. The predicted flame length and radiant fraction are in good agreement with the measurements of Schefer et al. [2] Studer et al. [3] and Ekoto et al. [6]. In order to account for the effects of variation in ground surface reflectance the emissivity of hydrogen flames was modified following Ekoto et al. [6]. Four cases with different ground reflectance are computed. The predictions show that the ground surface reflectance only has minor effect on the surface emissive power of the hydrogen jet fire. The radiant fractions fluctuate from 0.168 to 0.176 close to the suggested value of 0.16 by Ekoto et al.[6] based on the analysis of their measurements.
Computational Analysis of Hydrogen Diffusion in Polycrystalline Nickel and Anisotropic Polygonal Micro, Nano Grain Size Effects
Sep 2013
Publication
The effect of irregular polygonal grain size and random grain boundary on hydrogen diffusion in polycrystalline nickel is investigated. Hydrogen diffusion behavior in micropolycrystalline nickel is compared with that in nanopolycrystalline nickel through numerical analysis. The two dimensional computational finite element microstructural and nanostructural analyses are based on Fick's law corresponding to heterogeneous polycrystalline model geometry. The heterogeneous polycrystalline model consists of random irregular polygonal grains. These grains are divided into internal grain and grain boundary regions the size of which is determined from the grain size. The computational analysis results show that hydrogen diffusion in nanostructural irregular polycrystalline nickel is higher in magnitude than the microstructural irregular polycrystalline nickel. However models of voids traps and micro and nano clustered grains are yet to be included.
State-of-the-Art and Research Priorities in Hydrogen Safety
Sep 2013
Publication
On October 16-17 2012 the International Association for Hydrogen Safety (HySafe) in cooperation with the Institute for Energy and Transport of the Joint Research Centre of the European Commission (JRC IET Petten) held a two-day workshop dedicated to Hydrogen Safety Research Priorities. The workshop was hosted by Federal Institute for Materials Research and Testing (BAM) in Berlin Germany. The main idea of the Workshop was to bring together stakeholders who can address the existing knowledge gaps in the area of the hydrogen safety including identification and prioritization of such gaps from the standpoint of scientific knowledge both experimental and theoretical including numerical. The experience highlighting these gaps which was obtained during both practical applications (industry) and risk assessment should serve as reference point for further analysis. The program included two sections: knowledge gaps as they are addressed by industry and knowledge gaps and state-of-the-art by research. In the current work the main results of the workshop are summarized and analysed.
Indoor Use of Hydrogen, Knowledge Gaps and Priorities for the Improvement of Current Standards on Hydrogen, a Presentation of HyIndoor European Project
Sep 2013
Publication
To develop safety strategies for the use of hydrogen indoors the HyIndoor project is studying the behaviour of a hydrogen release deflagration or non-premixed flame in an enclosed space such as a fuel cell or its cabinet a room or a warehouse. The paper proposes a safety approach based on safety objectives that can be used to take various scenarios of hydrogen leaks into account for the safe design of Hydrogen and Fuel Cell (HFC) early market applications. Knowledge gaps on current engineering models and unknown influence of specific parameters were identified and prioritized thereby re-focusing the objectives of the project test campaign and numerical simulations. This approach will enable the improvement of the specification of openings and use of hydrogen sensors for enclosed spaces. The results will be disseminated to all stakeholders including hydrogen industry and RCS bodies.
HyDeploy Webinar - Unlocking the Deployment of Hydrogen in the Grid
May 2020
Publication
A project overview of HyDeploy project led by Cadent Gas and supported by Northern Gas Networks Progressive Energy Ltd Keele University HSE – Science Division and ITM Power.
First Phase:
HyDeploy at Keele is the first stage of this three stage programme. In November 2019 the UK Health & Safety Executive gave permission to run a live test of blended hydrogen and natural gas on part of the private gas network at Keele University campus in Staffordshire. HyDeploy is the first project in the UK to inject hydrogen into a natural gas network.
Second and Third Phases;
Once the Keele stage has been completed HyDeploy will move to a larger demonstration on a public network in the North East. After that HyDeploy will have another large demonstration in the North West. These are designed to test the blend across a range of networks and customers so that the evidence is representative of the UK as a whole. With HSE approval and success at Keele these phases will go ahead in the early 2020s.
The longer term goal:
Once the evidence has been submitted to Government policy makers we very much expect hydrogen to take its place alongside other forms of zero carbon energy in meeting the needs of the UK population.
First Phase:
HyDeploy at Keele is the first stage of this three stage programme. In November 2019 the UK Health & Safety Executive gave permission to run a live test of blended hydrogen and natural gas on part of the private gas network at Keele University campus in Staffordshire. HyDeploy is the first project in the UK to inject hydrogen into a natural gas network.
Second and Third Phases;
Once the Keele stage has been completed HyDeploy will move to a larger demonstration on a public network in the North East. After that HyDeploy will have another large demonstration in the North West. These are designed to test the blend across a range of networks and customers so that the evidence is representative of the UK as a whole. With HSE approval and success at Keele these phases will go ahead in the early 2020s.
The longer term goal:
Once the evidence has been submitted to Government policy makers we very much expect hydrogen to take its place alongside other forms of zero carbon energy in meeting the needs of the UK population.
Hydrogen Impact on Gas Engine CHP - Cadent Ltd
Feb 2019
Publication
The key project objectives include:
The output from this project will also inform the HyDeploy NIC project in relation to potential hydrogen content limits. The project will be presented at the IGEM Gas Quality Working Group (IGEM GQWG).
This report and any attachment is freely available on the ENA Smarter Networks Portal here. IGEM Members can download the report and any attachment directly by clicking on the pdf icon above.
- Understand the range size type mode of operation and control system of installed gas engines in the UK. This will include equipment for CHP and for stand-by power operation.
- Produce data sets on the impact of hydrogen on gas engine operational performance.
- Develop knowledge on the impact of hydrogen content on the operation of the gas engine including overall efficiency changes to emissions profiles overall system operability.
- Providing outline guidance on a potential hydrogen limit that should be considered regarding use of natural gas/hydrogen mixed fuels in gas engines.
- Outlining a high-level view on the reliability and impact on maintenance and replacement regimes if gas engines operate on natural gas/hydrogen mixed fuels for extended time periods.
- Highlight any existing barriers to use of natural gas and hydrogen blends in gas engine and through contact with OEMs develop an understanding of future technology developments that may be needed to enable the use of “high” hydrogen blends.
The output from this project will also inform the HyDeploy NIC project in relation to potential hydrogen content limits. The project will be presented at the IGEM Gas Quality Working Group (IGEM GQWG).
This report and any attachment is freely available on the ENA Smarter Networks Portal here. IGEM Members can download the report and any attachment directly by clicking on the pdf icon above.
HyDeploy Webinar - Public Perceptions
May 2020
Publication
HyDeploy is a pioneering hydrogen energy project designed to help reduce UK CO2 emissions and reach the Government’s net zero target for 2050.
As the first ever live demonstration of hydrogen in homes HyDeploy aims to prove that blending up to 20% volume of hydrogen with natural gas is a safe and greener alternative to the gas we use now. It is providing evidence on how customers don’t have to change their cooking or heating appliances to take the blend which means less disruption and cost for them. It is also confirming initial findings that customers don’t notice any difference when using the hydrogen blend.
As the first ever live demonstration of hydrogen in homes HyDeploy aims to prove that blending up to 20% volume of hydrogen with natural gas is a safe and greener alternative to the gas we use now. It is providing evidence on how customers don’t have to change their cooking or heating appliances to take the blend which means less disruption and cost for them. It is also confirming initial findings that customers don’t notice any difference when using the hydrogen blend.
A Portfolio of Powertrains for the UK: An Energy Systems Analysis
Jul 2014
Publication
There has recently been a concerted effort to commence a transition to fuel cell vehicles (FCVs) in Europe. A coalition of companies released an influential McKinsey-coordinated report in 2010 which concluded that FCVs are ready for commercial deployment. Public–private H2Mobility programmes have subsequently been established across Europe to develop business cases for the introduction of FCVs. In this paper we examine the conclusions of these studies from an energy systems perspective using the UK as a case study. Other UK energy system studies have identified only a minor role for FCVs after 2030 but we reconcile these views by showing that the differences are primarily driven by different data assumptions rather than methodological differences. Some energy system models do not start a transition to FCVs until around 2040 as they do not account for the time normally taken for the diffusion of new powertrains. We show that applying dynamic growth constraints to the UK MARKAL energy system model more realistically represents insights from innovation theory. We conclude that the optimum deployment of FCVs from an energy systems perspective is broadly in line with the roadmap developed by UK H2Mobility and that a transition needs to commence soon if FCVs are to become widespread by 2050.
Pressure Effects of an Ignited Release from Onboard Storage in a Garage with a Single Vent
Sep 2017
Publication
This work is driven by the need to understand the hazards resulting from the rapid ignited release of hydrogen from onboard storage tanks through a thermally activated pressure relief device (TPRD) inside a garage-like enclosure with low natural ventilation i.e. the consequences of a jet fire which has been immediately ignited. The resultant overpressure is of particular interest. Previous work [1] focused on an unignited release in a garage with minimum ventilation. This initial work demonstrated that high flow rates of unignited hydrogen through a thermally activated pressure relief device (TPRD) in ventilated enclosures with low air change per hour can generate overpressures above the limit of 10- 15 kPa which a typical civil structure like a garage could withstand. This is due to the pressure peaking phenomenon. Both numerical and phenomenological models were developed for an unignited release and this has been recently validated experimentally [2]. However it could be expected that the majority of unexpected releases through a TPRD may be ignited; leading to even greater overpressures and to date whilst there has been some work on fires in enclosures the pressure peaking phenomenon for an ignited release has yet to be studied or compared with that for an equivalent unignited release. A numerical model for ignited releases in enclosures has been developed and computational fluid dynamics has then been used to examine the pressure dynamics of an ignited hydrogen release in a real scale garage. The scenario considered involves a high mass flow rate release from an onboard hydrogen storage tank at 700 bar through a 3.34 mm diameter orifice representing the TPRD in a small garage with a single vent equivalent in area to small window. It is shown that whilst this vent size garage volume and TPRD configuration may be considered “safe” from overpressures in the event of an unignited release the overpressure resulting from an ignited release is two orders of magnitude greater and would destroy the structure. Whilst further investigation is needed the results clearly indicate the presence of a highly dangerous situation which should be accounted for in regulations codes and standards. The hazard relates to the volume of hydrogen released in a given timeframe thus the application of this work extends beyond TPRDs and is relevant where there is a rapid ignited release of hydrogen in an enclosure with limited ventilation.
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