Greece
Sizing, Optimization, and Financial Analysis of a Green Hydrogen Refueling Station in Remote Regions
Jan 2022
Publication
Hydrogen (H2 ) can be a promising energy carrier for decarbonizing the economy and especially the transport sector which is considered as one of the sectors with high carbon emissions due to the extensive use of fossil fuels. H2 is a nontoxic energy carrier that could replace fossil fuels. Fuel Cell Electric Vehicles (FCEVs) can decrease air pollution and reduce greenhouse gases when H2 is produced from Renewable Energy Sources (RES) and at the same time being accessible through a widespread network of Hydrogen Refueling Stations (HRSs). In this study both the sizing of the equipment and financial analysis were performed for an HRS supplied with H2 from the excess electrical energy of a 10 MW wind park. The aim was to determine the optimum configuration of an HRS under the investigation of six different scenarios with various numbers of FCEVs and monthly demands as well as ascertaining the economic viability of each examined scenario. The effect of the number of vehicles that the installation can refuel to balance the initial cost of the investment and the fuel cost in remote regions was investigated. The results showed that a wind-powered HRS could be a viable solution when sized appropriately and H2 can be used as a storage mean for the rejected wind energy. It was concluded that scenarios with low FCEVs penetration have low economic performance since the payback period presented significantly high values.
CFD Evaluation Against a Large Scale Unconfined Hydrogen Deflagration
Oct 2015
Publication
In the present work CFD simulations of a large scale open deflagration experiment are performed. Stoichiometric hydrogen–air mixture occupies a 20 m hemisphere. Two combustion models are compared and evaluated against the experiment: the Eddy Dissipation Concept model and a multi-physics combustion model which calculates turbulent burning velocity based on Yakhot's equation. Sensitivity analysis on the value of fractal dimension of the latter model is performed. A semi-empirical relation which estimates the fractal dimension is also tested. The effect of the turbulence model on the results is examined. LES approach and k-ε models are used. The multi-physics combustion model with constant fractal dimension value equal to 2.3 using the RNG LES turbulence model achieves the best agreement with the experiment.
Comparison of Convective Schemes in Hydrogen Impinging Jet CFD Simulation
Oct 2015
Publication
Hydrogen impinging jets can be formed in the case of an accidental release indoors or outdoors. The CFD simulation of hydrogen impinging jets suffers from numerical errors resulting in a non-physical velocity and hydrogen concentration field with a butterfly like structure. In order to minimize the numerical errors and to avoid the butterfly effect high order schemes need to be used. The aim of this work is to give best practices guidelines for hydrogen impinging jet simulations. A number of different numerical schemes is evaluated. The number of cells which discretize the source is also examined.
Best Practice in Numerical Simulation and CFD Benchmarking. Results from the SUSANA Project
Sep 2017
Publication
Correct use of Computational Fluid Dynamics (CFD) tools is essential in order to have confidence in the results. A comprehensive set of Best Practice Guidelines (BPG) in numerical simulations for Fuel Cells and Hydrogen applications has been one of the main outputs of the SUSANA project. These BPG focus on the practical needs of engineers in consultancies and industry undertaking CFD simulations or evaluating CFD simulation results in support of hazard/risk assessments of hydrogen facilities as well as on the needs of regulatory authorities. This contribution presents a summary of the BPG document. All crucial aspects of numerical simulations are addressed such as selection of the physical models domain design meshing boundary conditions and selection of numerical parameters. BPG cover all hydrogen safety relative phenomena i.e. release and dispersion ignition jet fire deflagration and detonation. A series of CFD benchmarking exercises are also presented serving as examples of appropriate modelling strategies.
CFD Modeling for Helium Releases in a Private Garage Without Forced Ventilation.
Sep 2005
Publication
In the course towards a safe future hydrogen based society one of the tasks to be considered is the investigation of the conditions under which the use or storage of hydrogen systems inside buildings becomes too dangerous to be accepted. One of the relevant scenarios which is expected to have a relatively high risk is a slow (and long lasting) hydrogen release from a vehicle stored in a closed private garage without any forced ventilation i.e. only with natural ventilation. This scenario has been earlier investigated experimentally (by M. Swain) using He (helium) to simulate the hydrogen behavior. In the present work the CFD code ADREA-HF is used to simulate three of the abovementioned experiments using the standard k- turbulence model. For each case modeled the predicted concentration (by vol.) time series are compared against the experimental at the given sensor locations. In addition the structure of the flow is investigated by presenting the helium concentration field.
Benchmark Exercise on Risk Assessment Methods Applied to a Virtual Hydrogen Refuelling Station
Sep 2009
Publication
A benchmarking exercise on quantitative risk assessment (QRA) methodologies has been conducted within the project HyQRA under the framework of the European Network of Excellence (NoE) HySafe. The aim of the exercise was basically twofold: (i) to identify the differences and similarities in approaches in a QRA and their results for a hydrogen installation between nine participating partners representing a broad spectrum of background in QRA culture and history and (ii) to identify knowledge gaps in the various steps and parameters underlying the risk quantification. In the first step a reference case was defined: a virtual hydrogen refuelling station (HRS) in virtual surroundings comprising housing school shops and other vulnerable objects. All partners were requested to conduct a QRA according to their usual approach and experience. Basically participants were free to define representative release cases to apply models and frequency assessments according their own methodology and to present risk according to their usual format. To enable inter-comparison a required set of results data was prescribed like distances to specific thermal radiation levels from fires and distances to specific overpressure levels. Moreover complete documentation of assumptions base data and references was to be reported. It was not surprising that a wide range of results was obtained both in the applied approaches as well as in the quantitative outcomes and conclusions. This made it difficult to identify exactly which assumptions and parameters were responsible for the differences in results as the paper will show. A second phase was defined in which the QRA was determined by a more limited number of release cases (scenarios). The partners in the project agreed to assess specific scenarios in order to identify the differences in consequence assessment approaches. The results of this phase provide a better understanding of the influence of modelling assumptions and limitations on the eventual conclusions with regard to risk to on-site people and to the off-site public. This paper presents the results and conclusions of both stages of the exercise.
Indoor Use of Hydrogen, Knowledge Gaps and Priorities for the Improvement of Current Standards on Hydrogen, a Presentation of HyIndoor European Project
Sep 2013
Publication
To develop safety strategies for the use of hydrogen indoors the HyIndoor project is studying the behaviour of a hydrogen release deflagration or non-premixed flame in an enclosed space such as a fuel cell or its cabinet a room or a warehouse. The paper proposes a safety approach based on safety objectives that can be used to take various scenarios of hydrogen leaks into account for the safe design of Hydrogen and Fuel Cell (HFC) early market applications. Knowledge gaps on current engineering models and unknown influence of specific parameters were identified and prioritized thereby re-focusing the objectives of the project test campaign and numerical simulations. This approach will enable the improvement of the specification of openings and use of hydrogen sensors for enclosed spaces. The results will be disseminated to all stakeholders including hydrogen industry and RCS bodies.
Removing the Disrupting Wind Effect in Single Vented Enclosure Exposed to External Wind
Oct 2015
Publication
We are addressing hydrogen release into a single-vented facility with wind blowing onto the opposite side of the vent wall. Earlier work based on tests performed by HSL with wind (within the HyIndoor project) and comparative CFD simulations with and without wind ([1]within the H2FC project) has shown that the hydrogen concentrations inside the enclosure are increased compared to the case with no wind. This was attributed to the fact that wind is disrupting the passive ventilation. The present work is based on the GAMELAN tests (within the HyIndoor project) performed with one vent and no wind. For this enclosure simulations were performed with and without wind and reproduced the disrupting wind effect. In order to remove this effect and enhance the ventilation additional simulations were performed by considering different geometrical modifications near the vent. A simple geometrical layout around the vent is here proposed that leads to elimination of the disrupting wind effect. The analysis has been performed using the ADREA-HF code earlier validated both for the HSL and the GAMELAN tests. The current work was performed partly within HyIndoor project
Simulation of Hydrogen Dispersion under Cryogenic Release Conditions
Sep 2013
Publication
The use of hydrogen as fuel should always be accompanied by a safety assessment in case of an accidental release. To evaluate the potential hazards in a spill accident both experiments and simulations are performed. In the present work the CFD code ADREA-HF is used to simulate the liquefied hydrogen (LH2) spill experiments (test 5 6 7) conducted by the Health and Safety Laboratory (HSL). In these tests LH2 was spilled at a fixed rate of 60lt/min in several directions and for several durations. The factors that influence the vapor dispersion under cryogenic release conditions that were examined in this study are: the air humidity the wind direction and the slip effect of droplets formed by both the cryogenic liquid and the condensation of air humidity. The numerical results were compared with the experimental measurements and the effect of each abovementioned factors in the vapor dispersion is being discussed.
Development of a Model Evaluation Protocol for CFD Analysis of Hydrogen Safety Issues – The SUSANA Project
Oct 2015
Publication
The “SUpport to SAfety aNAlysis of Hydrogen and Fuel Cell Technologies (SUSANA)” project aims to support stakeholders using Computational Fluid Dynamics (CFD) for safety engineering design and assessment of FCH systems and infrastructure through the development of a model evaluation protocol. The protocol covers all aspects of safety assessment modelling using CFD from release through dispersion to combustion (self-ignition fires deflagrations detonations and Deflagration to Detonation Transition - DDT) and not only aims to enable users to evaluate models but to inform them of the state of the art and best practices in numerical modelling. The paper gives an overview of the SUSANA project including the main stages of the model evaluation protocol and some results from the on-going benchmarking activities.
CFD Benchmark Based on Experiments of Helium Dispersion in a 1m3 Enclosure–intercomparisons for Plumes
Sep 2013
Publication
In the context of the French DIMITRHY project ANR-08-PANH006 experiments have been carried out to measure helium injections in a cubic 1 m3 box - GAMELAN in a reproducible and quantitative manner. For the present work we limit ourselves to the unique configuration of a closed box with a small hole at its base to prevent overpressure. This case leads to enough difficulties of modelisations to deserve our attention. The box is initially filled with air and injections of helium through a tube of diameter 20 mm is operated. The box is instrumented with catharometres to measure the helium volume concentration within an accuracy better than 0.1%. We present the CFD (Fluent and CASTEM ANSYS-CFX and ADREA-HF) calculations results obtained by 5 different teams participating to the benchmark in the following situation: the case of a plume release of helium in a closed box (4NL/min). Parts of the CFD simulations were performed in the European co-funded project HyIndoor others were performed in the French ANR-08-PANH006 DimitrHy project.
LES Modelling Of Hydrogen Release and Accumulation Within a Non-Ventilated Ambient Pressure Garage Using The Adrea-HF CFD Code
Sep 2011
Publication
Computational Fluid Dynamics (CFD) has already proven to be a powerful tool to study the hydrogen dispersion and help in the hydrogen safety assessment. In this work the Large Eddy Simulation (LES) recently incorporated into the ADREA-HF CFD code is evaluated against the INERIS-6C experiment of hydrogen leakage in a supposed garage which provides detailed experimental measurements visualization of the flow and availability of previous CFD results from various institutions (HySafe SBEP-V3). The short-term evolution of the hydrogen concentrations in this confined space is examined and comparison with experimental data is provided along with comments about the ability of LES to capture the transient phenomena occurring during hydrogen dispersion. The influence of the value of the Smagorinsky constant on the resolved and on the unresolved turbulence is also presented. Furthermore the renormalization group (RNG) LES methodology is also tested and its behaviour in both highly-turbulent and less-turbulent parts of the flow is highlighted.
Modeling of Cryogenic Hydrogen jets
Oct 2015
Publication
In the present work the CFD modeling of cryogenic hydrogen releases in quiescent environment is presented. Two tests from the series of experiments performed in the ICESAFE facility at KIT (Karlsruhe Institute for Technology) have been simulated within the SUSANA project. During these tests hydrogen at temperature of 37K and 36K and at pressure of 19 and 29 bars respectively is released horizontally. The release at the nozzle is sonic and the modeling of the under-expanded jet was performed using two different approaches: the Ewan and Moodie approach and a modification of the Ewan and Moodie approach (modified Ewan and Moodie) that is introduced here and employs the momentum balance to calculate the velocity in the under-expanded jet. Using these approaches a pseudo-diameter is calculated and this diameter is set as source boundary in the simulation. Predictions are consistent with measurements for both experiments with both approaches. However the Ewan and Moodie approach seems to perform better.
Evaluation of the ADREA-HF CFD Code Against a Hydrogen Deflagration in a Tunnel
Sep 2013
Publication
In the present work the capabilities of the computational fluid dynamics (CFD) code ADREA-HF to predict deflagration in homogenous near stoichiometric hydrogen-air mixture in a model of a tunnel were tested. The tunnel is 78.5 m long. Hydrogen-air mixture is located in a 10 m long region in the middle of the tunnel. Two cases are studied: one with a complete empty tunnel and one with the presence of four vehicles near the center of the tunnel. The combustion model is based on the turbulent flame speed concept. The turbulent flame speed is a modification of Yakhot's equation in order to account for additional physical mechanisms. A sensitivity analysis for the parameter of the combustion model and for the mesh resolution was made for the empty tunnel case. The agreement between experimental and computational results concerning the value of the maximum pressure and the time it appears is satisfactory in both cases. The sensitivity analysis for the parameter of the combustion model showed that even small changes in it can have impact on the simulating results whereas the sensitivity analysis of the mesh resolution did not reveal any significant differences.
CFD Validation Against Large Scale Liquified Helium Release
Sep 2019
Publication
The ADREA-HF CFD code is validated against a large scale liquefied helium release experiment on flat ground performed by INERIS in the past. The predicted release and dispersion behavior is evaluated against the experimental using temperature time histories at sensors deployed at various distances and heights downstream the source. For the selected sensors the temperature predictions are generally in good agreement with the experimental with a tendency to under-predict temperature as the source is approached.
Assessment of the Impact of Material Selection on Aviation Sustainability, from a Circular Economy Perspective
Jan 2022
Publication
Climate change and global warming pose great sustainability challenges to the aviation industry. Alternatives to petroleum-based fuels (hydrogen natural gas etc.) have emerged as promising aviation fuels for future aircraft. The present study aimed to contribute to the understanding of the impact of material selection on aviation sustainability accounting for the type of fuel implemented and circular economy aspects. In this context a decision support tool was introduced to aid decisionmakers and relevant stakeholders to identify and select the best-performing materials that meet their defined needs and preferences expressed through a finite set of conflicting criteria associated with ecological economic and circularity aspects. The proposed tool integrates life-cycle-based metrics extending to both ecological and economical dimensions and a proposed circular economy indicator (CEI) focused on the material/component level and linked to its quality characteristics which also accounts for the quality degradation of materials which have undergone one or more recycling loops. The tool is coupled with a multi-criteria decision analysis (MCDA) methodology in order to reduce subjectivity when determining the importance of each of the considered criteria.
Status of the Pre-normative Research Project PRESLHY for the Safe Use of LH2
Sep 2019
Publication
Liquid hydrogen (LH2) compared to compressed gaseous hydrogen offers advantages for large scale transport and storage of hydrogen with higher densities and potentially better safety performance. Although the gas industry has good experience with LH2 only little experience is available for the new applications of LH2 as an energy carrier. Therefore the European FCH JU funded project PRESLHY conducts pre-normative research for the safe use of cryogenic LH2 in non-industrial settings. The work program consists of a preparatory phase where the state of the art before the project has been summarized and where the experimental planning was adjusted to the outcome of a research priorities workshop. The central part of the project consists of 3 phenomena oriented work packages addressing Release Ignition and Combustion with analytical approaches experiments and simulations. The results shall improve the general understanding of the behavior of LH2 in accidents and thereby enhance the state-of-the-art what will be reflected in appropriate recommendations for development or revision of specific international standards. The paper presents the status of the project at the middle of its terms.
CFD Simulations on Small Hydrogen Releases Inside a Ventilated Facility and Assessment of Ventilation Efficiency
Sep 2009
Publication
The use of stationary H2 and fuel cell systems is expected to increase rapidly in the future. In order to facilitate the safe introduction of this new technology the HyPer project funded by the EC developed a public harmonized Installation Permitting Guidance (IPG) document for the installation of small stationary H2 and fuel cell systems for use in various environments. The present contribution focuses on the safety assessment of a facility inside which a small H2 fuel cell system (4.8 kWe) is installed and operated. Dispersion experiments were designed and performed by partner UNIPI. The scenarios considered cover releases occurring inside the fuel cell at the valve of the inlet gas pipeline just before the pressure regulator which controls the H2 flow to the fuel cell system. H2 was expected to leak out of the fuel cell into the facility and then outdoors through the ventilation system. The initial leakage diameter was chosen based on the Italian technical guidelines for the enforcement of the ATEX European directive. Several natural ventilation configurations were examined. The performed tests were simulated by NCSRD using the ADREA-HF code. The numerical analysis took into account the full interior of the fuel cell in order to investigate for any potential accumulation effects. Comparisons between predicted and experimental H2 concentrations at 4 sensor locations inside the facility are reported. Finally an overall assessment of the ventilation efficiency was made based on the simulations and experiments.
Ia-HySafe Standard Benchmark Exercise Sbep-V21- Hydrogen Release and Accumulation within a Non-Ventilated Ambient Pressure Garage at Low Release Rates
Sep 2011
Publication
The successful Computational Fluid Dynamics (CFD) benchmarking activity originally started within the EC-funded Network of Excellence HySafe (2004-2009) continues within the research topics of the recently established “International Association of Hydrogen Safety” (IA-HySafe). The present contribution reports the results of the standard benchmark problem SBEP-V21. Focus is given to hydrogen dispersion and accumulation within a non-ventilated ambient pressure garage both during the release and post-release periods but for very low release rates as compared to earlier work (SBEP-V3). The current experiments were performed by CEA at the GARAGE facility under highly controlled conditions. Helium was vertically released from the centre of the 5.76 m (length) x 2.96 m (width) x 2.42 m (height) facility 22 cm from the floor from a 29.7 mm diameter opening at a volumetric rate of 18 L/min (0.027 g/s equivalent hydrogen release rate compared to 1 g/s for SBEP-V3) and for a period of 3740 seconds. Helium concentrations were measured with 57 catharometric sensors at various locations for a period up to 1.1 days. The simulations were performed using a variety of CFD codes and turbulence models. The paper compares the results predicted by the participating partners and attempts to identify the reasons for any observed disagreements.
Evaluation of an Improved Vented Deflagration CFD Model Against Nine Experimental Cases
Sep 2019
Publication
In the present work a newly developed CFD deflagration model incorporated into the ADREA-HF code is evaluated against hydrogen vented deflagrations experiments carried out by KIT and FM-Global in a medium (1 m3) and a real (63.7 m3) scale enclosure respectively. A square vent of 0.5 m2 and 5.4 m2 respectively is located in the center of one of side walls. In the case of the medium scale enclosure the 18% v/v homogeneous hydrogen-air mixture and back-wall ignition case is examined. In the case of the real scale enclosure the examined cases cover different homogeneous mixture concentrations (15% and 18% v/v) different ignition locations (back-wall and center) and different levels of initial turbulence. The CFD model accounts for flame instabilities that develop as the flame propagates inside the chamber and turbulence that mainly develops outside the vent. Pressure predictions are compared against experimental measurements revealing a very good performance of the CFD model for the back-wall ignition cases. For the center ignition cases the model overestimates the maximum overpressure. The opening of the vent cover is identified as a possible reason for the overprediction. The analysis indicates that turbulence is the main factor which enhances external explosion strength causing the sudden pressure increase confirming previous findings.
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