Russian Federation

There exists no single optimal way for transporting hydrogen and other hydrogen carriers from one port to the other globally. Its delivery depends on several factors such as the quantity distance economics and the availability of the required infrastructure for its transportation. Europe has a strategy to invest in the production of green hydrogen in Africa to meet its needs. This study assessed the economic viability of shipping liquefied hydrogen (LH2 ) and hydrogen carriers to Germany from six African countries that have been identified as countries with great potential in the production of hydrogen. The results obtained suggest that the shipping of LH2 to Europe (Germany) will cost between 0.47 and 1.55 USD/kg H2 depending on the distance of travel for the ship. Similarly the transportation of hydrogen carriers could range from 0.19 to 0.55 USD/kg H2 for ammonia 0.25 to 0.77 USD/kg H2 for LNG 0.24 to 0.73 USD/kg H2 for methanol and 0.43 to 1.28 USD/kg H2 for liquid organic hydrogen carriers (LOHCs). Ammonia was found to be the ideal hydrogen carrier since it recorded the least transportation cost. A sensitivity analysis conducted indicates that an increase in the economic life by 5 years could averagely decrease the cost of LNG by some 13.9% NH3 by 13.2% methanol by 7.9% LOHC by 8.03% and LH2 by 12.41% under a constant distance of 6470 nautical miles. The study concludes with a suggestion that if both foreign and local participation in the development of the hydrogen market is increased in Africa the continent could supply LH2 and other hydrogen carriers to Europe at a cheaper price using clean fuel.

Magnesium hydride owns the largest share of publications on solid materials for hydrogen storage. The “Magnesium group” of international experts contributing to IEA Task 32 “Hydrogen Based Energy Storage” recently published two review papers presenting the activities of the group focused on magnesium hydride based materials and on Mg based compounds for hydrogen and energy storage. This review article not only overviews the latest activities on both fundamental aspects of Mg-based hydrides and their applications but also presents a historic overview on the topic and outlines projected future developments. Particular attention is paid to the theoretical and experimental studies of Mg-H system at extreme pressures kinetics and thermodynamics of the systems based on MgH₂ nanostructuring new Mg-based compounds and novel composites and catalysis in the Mg based H storage systems. Finally thermal energy storage and upscaled H storage systems accommodating MgH₂ are presented.

The objective of this work is to investigate the effect of hydrogen-induced fracture of TiNi-based alloy. In this report we performed the first studies comparing inelastic properties and fracture of the specimens of the binary alloy of TiNi wire under the action of hydrogen with coarse-grained (CG) and ultrafine-grained (UFG) microstructure. It is shown that hydrogen embrittlement (HE) occurs irrespective of the grain size in the studied specimens at approximately equal strain values. However compared to the specimens with CG structure those with UFG structure accumulate two to three times more hydrogen for the same hydrogenation time. It is found that hydrogen has a much smaller effect on the inelastic properties of specimens with UFG structure as compared to those with CG structure.

Regularities of steel structure degradation of the “Novopskov-Aksay-Mozdok” gas main pipelines (Nevinnomysskaya CS) as well as the “Gorky-Center” pipelines (Gavrilovskaya CS) were studied. The revealed peculiarities of their degradation after long-term operation are suggested to be treated as a particular case of the damage accumulation classification (scheme) proposed by prof. H.M. Nykyforchyn. It is shown that the fracture surface consists of sections of ductile separation and localized zones of micro-spalling. The presence of the latter testifies to the hydrogen-induced embrittlement effect. However the steels under investigation possess sufficiently high levels of the mechanical properties required for their further safe exploitation both in terms of durability and cracking resistance.

Autothermal reforming of bioethanol (ATR of C2H5OH) over promoted Ni/Ce0.8La0.2O1.9 catalysts was studied to develop carbon-neutral technologies for hydrogen production. The regulation of the functional properties of the catalysts was attained by adjusting their nanostructure and reducibility by introducing various types and content of M promoters (M = Pt Pd Rh Re; molar ratio M/Ni = 0.003–0.012). The composition–characteristics–activity correlation was determined using catalyst testing in ATR of C2H5OH thermal analysis N2 adsorption X-ray diffraction transmission electron microscopy and EDX analysis. It was shown that the type and content of the promoter as well as the preparation mode (combined or sequential impregnation methods) determine the redox properties of catalysts and influence the textural and structural characteristics of the samples. The reducibility of catalysts improves in the following sequence of promoters: Re < Rh < Pd < Pt with an increase in their content and when using the co-impregnation method. It was found that in ATR of C2H5OH over bimetallic Ni-M/Ce0.8La0.2O1.9 catalysts at 600 ◦C the hydrogen yield increased in the following row of promoters: Pt < Rh < Pd < Re at 100% conversion of ethanol. The introduction of M leads to the formation of a NiM alloy under reaction conditions and affects the resistance of the catalyst to oxidation sintering and coking. It was found that for enhancing Ni catalyst performance in H2 production through ATR of C2H5OH the most effective promotion is with Re: at 600 ◦C over the optimum 10Ni-0.4Re/Ce0.8La0.2O1.9 catalyst the highest hydrogen yield 65% was observed.

In this research we conducted water electrolysis experiments of a carbon black (CB) based sodium sulfate electrolyte using a Hoffman voltameter. The main objective was to investigate hydrogen production in such systems as well as analyse the electrical properties and thermal properties of nanofluids. A halogen lamp mimicking solar energy was used as a radiation source and a group of comparative tests were also conducted with different irradiation areas. The results showed that by using CB and light it was possible to increase the hydrogen production rate. The optimal CB concentration was 0.1 wt %. At this concentration the hydrogen production rate increased by 30.37% after 20 min of electrolysis. Hence we show that using CB in electrolytes irradiated by solar energy could save the electrical energy necessary for electrolysis processes.

Hydrogen sensors especially those operating at high temperatures are essential tools for the emerging hydrogen economy. Monitoring hydrogen under process conditions to control the reactions for detecting confined species is crucial to the safe widespread use and public acceptance of hydrogen as fuel. Hydrogen sensors must have a sensitivity ranging from traces of hydrogen (parts per million (ppm)) up to levels near the lower explosive limit (LEL = 4% H2 in the air) for safety reasons. Furthermore they need to operate in cryogenic ambient and high-temperature environments. Herein emphasis is given to hydrogen sensors based on solid oxide electrolytes (operating at high temperatures) in particular oxygen ion and proton conductors. The review is devoted to potentiometric amperometric and combined amperometric-potentiometric hydrogen sensors. Experimental results already reported in the international literature are presented and analyzed to reveal the configuration principle of operation and the applied solid electrolytes and electrodes of the high-temperature hydrogen sensors. Additionally an amperometric sensor able to detect hydrogen and steam in atmospheric air through a two-stage procedure is presented and thoroughly discussed. The discussion reveals that high-temperature hydrogen sensors face different challenges in terms of the electrodes and solid electrolytes to be used depending on the operating principle of each sensor type.

Some aspects of damage accumulation modelling and brittle fracture processes mechanisms under the combined effect of mechanical loading and hydrogen has been discussed in the article. New mechanism of brittle fracture for metallic materials based on dislocation and phonon structure fingerprints and lattice hydrogen content under the static and dynamic loading at low temperature condition has been proposed. The mechanism based on theoretical research and experimental and numerical studies. The experiments include the energy spectrum of internal friction determination and impact toughness testing for low-temperature brittle-ductile transition revealing. The numerical study based on damage accumulation modeling under the influence of up-hill diffusion in the elastic-plastic problem of solid state by finite element method. A new simple activation model of low temperature and hydrogen influence on damage accumulation process has been proposed. The model shows the rate of damage strong dependence of stress level and hydrogen content and test temperature. The combination of low temperature and high hydrogen content is most dangerous so the weld structures in extreme environment such as the Arctic and Subarctic regions have a high risk of breakage. So it is possible to estimate the energy and phonon spectrum of crystal lattice and predict the properties of microcrystalline and nanostructured materials with the high cold-short threshold on the base of such the approach. There are the recommendations propose to improve the cold resistance of steels and alloys by controlling the characteristics of the dislocation structure of new materials with polycrystalline and ultrafine-grained structure.

Free quasi-two-dimensional outward propagation of the ultra-lean hydrogen-air flames was studied in a horizontal closed flat channel in order to minimize the influences of gravity and natural convection. Experiments were carried out with a sequential change of initial hydrogen concentration in the premixed gaseous  hydrogen-air  mixtures  in  the  range  from  3  to  12  vol.  %  H2   under  normal  pressure  and temperature   conditions.   Two   types   of   critical   (in   term   of   concentration   threshold   behavior) morphological phenomena were observed - formation of a pre-flame kernel and primary bifurcation of the pre-flame kernel and the higher order (secondary tertiary etc.) bifurcations of the individual locally spherical and restricted in space flame fronts. For the given initial ambient conditions (channel thickness initial gas mixture pressure and temperature) variation of initial mixture stoichiometry results in a few substantial changes in overall flame shape. These changes were recorded at the specific concentration limits  which   delineate  three  characteristic  macroscopic  morphological  forms  (morphotypes)  of  the ultra-lean  hydrogen-air  flame's  ""trails""  -  ""ray-like""  ""dendritic""  and  ""quasi-uniform"".   Transitions between the revealed basic flame morphotypes took place in different ways. The ""pre-flame kernel-to- rays"" and ""rays-to-dendrites"" transitions were abrupt and resembled the first order transitions in physics. -to-quasi-uniform morphology"" were significantly blurred and can be regarded as analogue to the second order transitions.

The experimental data on hydrogen adsorption on five nanoporous activated carbons (ACs) of various origins measured over the temperature range of 303–363 K and pressures up to 20 MPa were compared with the predictions of hydrogen density in the slit-like pores of model carbon structures calculated by the Dubinin theory of volume filling of micropores. The highest amount of adsorbed hydrogen was found for the AC sample (ACS) prepared from a polymer mixture by KOH thermochemical activation characterized by a biporous structure: 11.0 mmol/g at 16 MPa and 303 K. The greatest volumetric capacity over the entire range of temperature and pressure was demonstrated by the densest carbon adsorbent prepared from silicon carbide. The calculations of hydrogen density in the slit-like model pores revealed that the optimal hydrogen storage depended on the pore size temperature and pressure. The hydrogen adsorption capacity of the model structures exceeded the US Department of Energy (DOE) target value of 6.5 wt.% starting from 200 K and 20 MPa whereas the most efficient carbon adsorbent ACS could achieve 7.5 wt.% only at extremely low temperatures. The initial differential molar isosteric heats of hydrogen adsorption in the studied activated carbons were in the range of 2.8–14 kJ/mol and varied during adsorption in a manner specific for each adsorbent.

The rapid development of science technology and engineering in the 21st century has offered a remarkable rise in our living standards. However at the same time serious environmental issues have emerged such as acid rain and the greenhouse effect which are associated with the ever-increasing need for energy consumption 85% of which comes from fossil fuels combustion. From this combustion process except for energy the main greenhouse gases-carbon dioxide and steam-are produced. Moreover during industrial processes many hazardous gases are emitted. For this reason gas-detecting devices such as electrochemical gas sensors able to analyze the composition of a target atmosphere in real time are important for further improving our living quality. Such devices can help address environmental issues and inform us about the presence of dangerous gases. Furthermore as non-renewable energy sources run out there is a need for energy saving. By analyzing the composition of combustion emissions of automobiles or industries combustion processes can be optimized. This review deals with electrochemical gas sensors based on solid oxide electrolytes which are employed for the detection of hazardous gasses at high temperatures and aggressive environments. The fundamentals the principle of operation and the configuration of potentiometric amperometric combined (amperometric-potentiometric) and mixed-potential gas sensors are presented. Moreover the results of previous studies on carbon oxides (COx) nitrogen oxides (NOx) hydrogen (H2 ) oxygen (O2 ) ammonia (NH3 ) and humidity (steam) electrochemical sensors are reported and discussed. Emphasis is given to sensors based on oxygen ion and proton-conducting electrolytes.

A comprehensive methodology for estimating the technological strength of welded joints are developed based on parameters reflecting the welding technology weldability hydrogen force and deformation conditions for welding and other informative parameters that correlate with the characteristics of the welded joint as well as improving existing methods for estimating the technological strength of welded joints connections through the introduction of modern equipment and non-destructive testing systems. It has been established that the proposed comprehensive estimation methodology will allow reaching a new qualitative level in assessing the technological strength of a welded joint using modern equipment and measuring instruments. According to the results of the experimental work it was found that when welding at low temperatures the increase in the probability of the formation and development of cold cracks is mainly determined by the critical content of diffusible hydrogen in the weld metal depending on the structural and force parameters of the welded joints.

The 21st century is characterized not only by large-scale transformations but also by the speed with which they occur. Transformations—political economic social technological environmental and legal-in synergy have always been a catalyst for reactions in society. The field of energy supply like many others is extremely susceptible to the external influence of such factors. To a large extent this applies to remote (especially from the position of energy supply) regions. The authors outline an approach to justifying the development of the Arctic energy infrastructure through an analysis of the demand for the amount of energy consumed and energy sources taking into account global trends. The methodology is based on scenario modeling of technological demand. It is based on a study of the specific needs of consumers available technologies and identified risks. The paper proposes development scenarios and presents a model that takes them into account. Modeling results show that in all scenarios up to 50% of the energy balance in 2035 will take gas but the role of carbon-free energy sources will increase. The mathematical model allowed forecasting the demand for energy types by certain types of consumers which makes it possible to determine the vector of development and stimulation of certain types of resources for energy production in the Arctic. The model enables considering not only the growth but also the decline in demand for certain types of consumers under different scenarios. In addition authors’ forecasts through further modernization of the energy sector in the Arctic region can contribute to the creation of prerequisites that will be stimulating and profitable for the growth of investment in sustainable energy sources to supply consumers. The scientific significance of the work lies in the application of a consistent hybrid modeling approach to forecasting demand for energy resources in the Arctic region. The results of the study are useful in drafting a scenario of regional development taking into account the Sustainable Development Goals as well as identifying areas of technology and energy infrastructure stimulation.

The consumption of hydrogen could increase by sixfold in 2050 compared to 2020 levels reaching about 530 Mt. Against this backdrop the proton exchange membrane fuel cell (PEMFC) has been a major research area in the field of energy engineering. Several reviews have been provided in the existing corpus of literature on PEMFC but questions related to their evolutionary nuances and research hotspots remain largely unanswered. To fill this gap the current review uses bibliometric analysis to analyze PEMFC articles indexed in the Scopus database that were published between 2000–2021. It has been revealed that the research field is growing at an annual average growth rate of 19.35% with publications from 2016 to 2012 alone making up 46% of the total articles available since 2000. As the two most energy-consuming economies in the world the contributions made towards the progress of PEMFC research have largely been from China and the US. From the research trend found in this investigation it is clear that the focus of the researchers in the field has largely been to improve the performance and efficiency of PEMFC and its components which is evident from dominating keywords or phrases such as ‘oxygen reduction reaction’ ‘electrocatalysis’ ‘proton exchange membrane’ ‘gas diffusion layer’ ‘water management’ ‘polybenzimidazole’ ‘durability’ and ‘bipolar plate’. We anticipate that the provision of the research themes that have emerged in the PEMFC field in the last two decades from the scientific mapping technique will guide existing and prospective researchers in the field going forward.

About 95% of current hydrogen production uses technologies involving primary fossil resources. A minor part is synthesized by low-carbon and close-to-zero-carbon-footprint methods using RESs. The significant expansion of low-carbon hydrogen energy is considered to be a part of the “green transition” policies taking over in technologically leading countries. Projects of hydrogen synthesis from natural gas with carbon capture for subsequent export to European and Asian regions poor in natural resources are considered promising by fossil-rich countries. Quality changes in natural resource use and gas grids will include (1) previously developed scientific groundwork and production facilities for hydrogen energy to stimulate the use of existing natural gas grids for hydrogen energy transport projects; (2) existing infrastructure for gas filling stations in China and Russia to allow the expansion of hydrogen-fuel-cell vehicles (HFCVs) using typical “mini-plant” projects of hydrogen synthesis using methane conversion technology; (3) feasibility testing for different hydrogen synthesis plants at medium and large scales using fossil resources (primarily natural gas) water and atomic energy. The results of this study will help focus on the primary tasks for quality changes in natural resource and gas grid use. Investments made and planned in hydrogen energy are assessed.

Alternative fuel opportunities can satisfy energy security and reduce carbon emissions. In this regard the hydrogen fuel is derived from the source of environmental pollutants like sewage and algae wastewater through hydrothermal gasification technique using a KOH catalyst with varied gasification process parameters of duration and temperature of 6–30 min and 500-800 ◦C. The novelty of the work is to identify the optimum gasification process parameter for obtaining the maximum hydrogen yield using a KOH catalyst as an alternative fuel for agricultural engine applications. Influences of gasification processing time and temperature on H2 selectivity Carbon gasification efficiency (CE) Lower heating value (LHV) Hydrogen yield potential (HYP) and gasification efficiency (GE) were studied. Its results showed that the gasifier operated at 800 ◦C for 30 min offering maximum hydrogen yield (26 mol/kg) and gasification efficiency (58 %). The synthesized H2 was an alternative fuel blended with diesel fuel/TiO2 nanoparticles. It was experimentally studied using an internal combustion engine. Influences of H2 on engine perfor mance like brake-specific fuel consumption brake thermal efficiency and emission performances were measured and compared with diesel fuel. The results showed that DH20T has the least (420g/kWh) brake-specific fuel consumption (BSFC) and superior brake thermal efficiency of about 25.2 %. The emission results revealed that the DH20T blend showed the NOX value increased by almost 10.97 % compared to diesel fuel whereas the CO UHC and smoke values reduced by roughly 31.25 28.34 and 42.35 %. The optimum fuel blend (DH20T) result is rec ommended for agricultural engine applications.

Developing countries including Ghana face challenges ensuring access to clean and reliable cooking fuels and technologies. Traditional biomass sources mainly used in most developing countries for cooking contribute to deforestation and indoor air pollution necessitating a shift towards environmentally friendly alternatives. The study’s primary objective is to evaluate the economic viability of using solar PV-based green hydrogen as a sustainable fuel for cooking in Ghana. The study adopted well-established equations to investigate the economic performance of the proposed system. The findings revealed that the levelized cost of hydrogen using the discounted cash flow approach is about 89% 155% and 190% more than electricity liquefied petroleum gas (LPG) and charcoal. This implies that using the hydrogen produced for cooking fuel is not cost-competitive compared to LPG charcoal and electricity. However with sufficient capital subsidies to lower the upfront costs the analysis suggests solar PV-based hydrogen could become an attractive alternative cooking fuel. In addition switching from firewood to solar PVbased hydrogen for cooking yields the highest carbon dioxide (CO2) emissions savings across the cities analysed. Likewise replacing charcoal with hydrogen also offers substantial CO2 emissions savings though lower than switching from firewood. Correspondingly switching from LPG to hydrogen produces lower CO2 emissions savings than firewood and charcoal. The study findings could contribute to the growing body of knowledge on sustainable energy solutions offering practical insights for policymakers researchers and industry stakeholders seeking to promote clean cooking adoption in developing economies.

The circular economy and the clean-energy transition are inextricably linked and interdependent. One of the most important areas of the energy transition is the development of hydrogen energy. This study aims to review and systematize the data available in the literature on the environmental and economic parameters of hydrogen storage and transportation technologies (both mature and at high technological readiness levels). The study concluded that salt caverns and pipeline transportation are the most promising methods of hydrogen storage and transportation today in terms of a combination of all parameters. These methods are the most competitive in terms of price especially when transporting hydrogen over short distances. Thus the average price of storage will be 0.35 USD/kg and transportation at a distance of up to 100 km is 0.3 USD/kg. Hydrogen storage underground in a gaseous state and its transportation by pipelines have the least consequences for the environment: emissions and leaks are insignificant and there is no environmental pollution. The study identifies these methods as particularly viable given their lower environmental impact and potential for seamless integration into existing energy systems therefore supporting the transition to a more sustainable and circular economy.

Hydrogen globally recognized as the most efficient and clean energy carrier holds the potential to transform future energy systems through its use as a fuel and chemical resource. Although progress has been made in reversible hydrogen adsorption and release challenges in storage continue to impede widespread adoption. This review explores recent advancements in hydrogen storage materials and synthesis methods emphasizing the role of nanotechnology and innovative synthesis techniques in enhancing storage performance and addressing these challenges to drive progress in the field. The review provides a comprehensive overview of various material classes including metal hydrides complex hydrides carbon materials metal-organic frameworks (MOFs) and porous materials. Over 60 % of reviewed studies focused on metal hydrides and alloys for hydrogen storage. Additionally the impact of nanotechnology on storage performance and the importance of optimizing synthesis parameters to tailor material properties for specific applications are summarized. Various synthesis methods are evaluated with a special emphasis on the role of nanotechnology in improving storage performance. Mechanical milling emerges as a commonly used and cost-effective method for fabricating intermetallic hydrides capable of adjusting hydrogen storage properties. The review also explores hydrogen storage tank embrittlement mechanisms particularly subcritical crack growth and examines the advantages and limitations of different materials for various applications supported by case studies showcasing real-world implementations. The challenges underscore current limitations in hydrogen storage materials highlighting the need for improved storage capacity and kinetics. The review also explores prospects for developing materials with enhanced performance and safety providing a roadmap for ongoing advancements in the field. Key findings and directions for future research in hydrogen storage materials emphasize their critical role in shaping future energy systems.

This study introduces the Smart Grid Hybrid Electrolysis-and-Combustion System (SGHE-CS) designed to seamlessly integrate hydrogen production storage and utilization within smart grid operations to maximize renewable energy use and maintain grid stability. The system achieves a hydrogen production efficiency of 98.5% indicating the effective conversion rate of electrical energy to hydrogen via PEM electrolysis. Combustion efficiency reaches 98.1% reflecting the proportion of hydrogen energy successfully converted into usable power through advanced staged combustion. Storage and transportation efficiency is 96.3% accounting for energy losses during hydrogen compression storage and delivery. Renewable integration efficiency is 97.3% representing the system’s capacity to utilize variable renewable energy inputs without curtailment. Operational versatility is 99.3% denoting the system’s ability to maintain high performance across load demands and grid conditions. Real-time monitoring and adaptive control strategies ensure reliability and resilience positioning SGHE-CS as a promising solution for sustainable low-carbon energy infrastructure.