Publications
2D MXene: From Synthesis to Storage - Exploring their Potential as Sparking Materials for Hydrogen Storage
Jul 2025
Publication
In the advancing landscape of sustainable energy the development of efficient and reversible hydrogen storage materials operable under ambient conditions remains a critical challenge for material scientists and the broader research community. Hydrogen owing to its exceptionally high energy density is regarded as a leading candidate for facilitating the transition from conventional fossil fuels to cleaner renewable energy systems. However alongside its production the safe and efficient storage of hydrogen presents a significant bottleneck due to its low volumetric density and associated safety concerns.<br/>Conventional storage techniques such as high-pressure compression and cryogenic liquefaction though widely used demand complex infrastructure and carry substantial safety risks. These limitations have steered growing interest toward solid-state hydrogen storage systems that rely on physisorption or chemisorption mechanisms preferably operating near ambient conditions. Consequently the pursuit of materials with favourable thermodynamics and kinetics for reversible hydrogen uptake and release has become imperative. Among the emerging candidates MXenes a class of two-dimensional (2D) materials comprising transition metal carbides nitrides or carbonitrides have garnered significant attention due to their high surface area tuneable surface chemistry and excellent conductivity.<br/>Despite the growing body of literature on hydrogen storage using MXenes a comprehensive evaluation that bridges the gap between theoretical predictions and experimental realities remains limited. This review addresses that gap by critically examining current strategies for solid-state hydrogen storage with a particular emphasis on MXene-based materials. It highlights the influence of synthesis techniques on structural properties discusses the mechanisms of hydrogen interaction with MXene surfaces and evaluates their practical implications in real-world applications. While the potential of MXenes in hydrogen storage is considerable it is not yet fully realized. This article provides an in-depth assessment of the current advancements challenges and future directions for MXene-based materials in the context of hydrogen storage offering valuable insights for both fundamental research and applied energy systems.
Numerical Simulation of the Transport and the Thermodynamic Properties of Imported Natural Gas Inected with Hydrogen in the Manifold
Nov 2023
Publication
Blending hydrogen with natural gas (NG) is an efficient method for transporting hydrogen on a large scale at a low cost. The manifold at the NG initial station is an important piece of equipment that enables the blending of hydrogen with NG. However there are differences in the components and component contents of imported NG from different countries. The components of hydrogen-blended NG can affect the safety and efficiency of transportation through pipeline systems. Therefore numerical simulations were performed to investigate the blending process and changes in the thermodynamic properties of four imported NGs and hydrogen in the manifold. The higher the heavy hydrocarbon content in the imported NG the longer the distance required for the gas to mix uniformly with hydrogen in the pipeline. Hydrogen blending reduces the temperature and density of NG. The gas composition is the main factor affecting the molar calorific value of a gas mixture and hydrogen blending reduces the molar calorific value of NG. The larger the content of high-molar calorific components in the imported NG the higher the molar calorific value of the gas after hydrogen blending. Increasing both the temperature and hydrogen mixing ratio reduces the Joule-Thomson coefficient of the hydrogen-blended NG. The results of this study provide technical references for the transport of hydrogen-blended NG.
An Estimation of Green Hydrogen Generation from Wind Energy: A Case Study from KSA
Sep 2023
Publication
Actually green hydrogen is viewed as a fundamental component in accelerating energy transition and empowering a sustainable future. The current study focuses on the estimation of green hydrogen generation by using wind energy via electrolysis in four sites located in Saudi Arabia. Results showed that the yearly amount of hydrogen that could be generated by using wind turbine ranges between 2542877 kg in Rafha and 3676925 kg in Dhahran. The hydrogen generated could be used to fuel vehicles and decrease the amount of GHG emission from vehicles in KSA. Also hydrogen may be used to store the excess of wind energy and to support the achievement of vision 2030 of the Kingdom. An economic assessment is carried out also in this paper. Results showed that the LCOH by using wind energy in KSA ranges from 2.82 $/kg to 3.81 $/kg.
Charting the Course: Navigating Decarbonisation Pathways in Greece, Germany, The Netherlands, and Spain’s Industrial Sectors
Jul 2024
Publication
In the quest for a sustainable future energy-intensive industries (EIIs) stand at the forefront of Europe’s decarbonisation mission. Despite their significant emissions footprint the path to comprehensive decarbonisation remains elusive at EU and national levels. This study scrutinises key sectors such as non-ferrous metals steel cement lime chemicals fertilisers ceramics and glass. It maps out their current environmental impact and potential for mitigation through innovative strategies. The analysis spans across Spain Greece Germany and the Netherlands highlighting sector-specific ecosystems and the technological breakthroughs shaping them. It addresses the urgency for the industry-wide adoption of electrification the utilisation of green hydrogen biomass bio-based or synthetic fuels and the deployment of carbon capture utilisation and storage to ensure a smooth transition. Investment decisions in EIIs will depend on predictable economic and regulatory landscapes. This analysis discusses the risks associated with continued investment in high-emission technologies which may lead to premature decommissioning and significant economic repercussions. It presents a dichotomy: invest in climate-neutral technologies now or face the closure and offshoring of operations later with consequences for employment. This open discussion concludes that while the technology for near-complete climate neutrality in EIIs exists and is rapidly advancing the higher costs compared to conventional methods pose a significant barrier. Without the ability to pass these costs to consumers the adoption of such technologies is stifled. Therefore it calls for decisive political commitment to support the industry’s transition ensuring a greener more resilient future for Europe’s industrial backbone.
Towards the Design of a Hydrogen-powered Ferry for Cleaner Passenger Transport
Aug 2024
Publication
The maritime transportation sector is a large and growing contributor of greenhouse gas and other emissions. Therefore stringent measures have been taken by the International Maritime Organization to mitigate the environmental impact of the international shipping. These lead to the adoption of new technical solutions involving clean fuels such as hydrogen and high efficiency propulsion technologies that is fuel cells. In this framework this paper proposes a methodological approach aimed at supporting the retrofit design process of a car-passenger ferry operating in the Greece’s western maritime zone whose conventional powertrain is replaced with a fuel cell hybrid system. To this aim first the energy/power requirements and the expected hydrogen consumption of the vessel are determined basing on a typical operational profile retrieved from data provided by the shipping company. Three hybrid powertrain configurations are then proposed where fuel cell and batteries are balanced out according to different design criteria. Hence a new vessel layout is defined for each of the considered options by taking into account on-board weight and space constraints to allocate the components of the new hydrogen-based propulsion systems. Finally the developed vessel configurations are simulated in a virtual towing tank environment in order to assess their hydrodynamic response and compare them with the original one thus providing crucial insights for the design process of new hydrogen-fueled vessel solutions. Findings from this study reveal that the hydrogen-based configurations of the vessel are all characterized by a slight reduction of the payload mainly due to the space required to allocate the hydrogen storage system; instead the hydrodynamic behavior of the H2 powered vessels is found to be similar to the one of the original Diesel configuration; also from a hydrodynamic point of view the results show that mid load operating conditions get relevance for the design process of the hybrid vessels.
The Role of Hydrogen in the Energy Mix: A Scenario Analysis for Turkey Using OSeMOSYS
Dec 2024
Publication
The urgent need to tackle climate change drives the research on new technologies to help the transition of energy systems. Hydrogen is under significant consideration by many countries as a means to reach zero-carbon goals. Turkey has also started to develop hydrogen projects. In this study the role of hydrogen in Turkey’s energy system is assessed through energy modeling using the cost optimization analytical tool Open Source Energy Modelling System (OSeMOSYS). The potential effects of hydrogen blending into the natural gas network in the Turkish energy system have been displayed by scenario development. The hydrogen is produced via electrolysis using renewable electricity. As a result by using hydrogen a significant reduction in carbon dioxide emissions was observed; however the accumulated capital investment value increased. Furthermore it was shown that hydrogen has the potential to reduce Turkey’s energy import dependency by decreasing natural gas demand.
Exploring Decentralized Ammonia Synthesis for Hydrogen Storage and Transport: A Comprehensive CFD Investigation with Experimental Validation and Parametric Study
Sep 2023
Publication
Hydrogen energy plays a vital role in the transition towards a carbon-neutral society but faces challenges in storage and transport as well as in production due to fluctuations in renewable electricity generation. Ammonia (NH3 ) as a carbon-neutral hydrogen carrier offers a promising solution to the energy storage and transport problem. To realize its potential and support the development of a hydrogen economy exploring NH3 synthesis in a decentralized form that integrates with distributed hydrogen production systems is highly needed. In this study a computational fluid dynamics (CFD) model for the Ruthenium (Ru) catalysts-based Haber– Bosch reactor is developed. First a state-of-the-art kinetic model comprehensively describing the complex catalytic reaction is assessed for its sensitivity and applicability to temperature pressure and conversion. Then the kinetic model is integrated into the CFD model and its accuracy is verified through comparison with experimental data obtained from different Ru-based catalysts and operation conditions. Detailed CFD results for a given case are presented offering a visual understanding of thermal gradients and species distributions inside the reactor. Finally a CFD-based parametric study is performed to reveal the impacts of key operation parameters and optimize the NH3 synthesis reactor. The results show that the NH3 production rate is predominantly influenced by temperature with a two-fold difference observed for every 30 ◦C variation while pressure primarily affects the equilibrium. Additionally the affecting mechanism of space velocity is thoroughly discussed and the best value for efficient NH3 synthesis is found to be 180000 h−1. In conclusion the CFD model and simulation results provide valuable insights for the design and control of decentralized NH3 synthesis reactor and operation contributing to the advancement of sustainable energy technologies.
Real-Time Energy Management Strategy of Hydrogen Fuel Cell Hybrid Electric Vehicles Based on Power Following Strategy–Fuzzy Logic Control Strategy Hybrid Control
Nov 2023
Publication
Fuel cell hybrid electric vehicles have the advantages of zero emission high efficiency and fast refuelling etc. and are one of the key directions for vehicle development. The energy management problem of fuel cell hybrid electric vehicles is the key technology for power distribution. The traditional power following strategy has the advantage of a real-time operation but the power correction is usually based only on the state of charge of a lithium battery which causes the operating point of the fuel cell to be in the region of a low efficiency. To solve this problem this paper proposes a hybrid power-following-fuzzy control strategy where a fuzzy logic control strategy is used to optimise the correction module based on the power following strategy which regulates the state of charge while correcting the output power of the fuel cell towards the efficient operating point. The results of the joint simulation with Matlab + Advisor under the Globally Harmonised Light Vehicle Test Cycle Conditions show that the proposed strategy still ensures the advantages of real-time energy management and for the hydrogen fuel cell the hydrogen consumption is reduced by 13.5% and 4.1% compared with the power following strategy and the fuzzy logic control strategy and the average output power variability is reduced by 14.6% and 5.1% respectively which is important for improving the economy of the whole vehicle and prolonging the lifetime of fuel cell.
Feasibility Study on the Provision of Electricity and Hydrogen for Domestic Purposes in the South of Iran using Grid-connected Renewable Energy Plants
Dec 2018
Publication
This work presents a feasibility study on the provision of electricity and hydrogen with renewable grid connected and off-the-grid systems for Bandar Abbas City in the south of Iran. The software HOMER Pro® has been used to perform the analysis. A techno-enviro-economic study comparing a hybrid system consisting of the grid/wind turbine and solar cell is done. The wind turbine is analyzed using four types of commercially available vertical axis wind turbines (VAWTs). According to the literature review no similar study has been performed so far on the feasibility of using VAWTs and also no work exists on the use of a hybrid system in the studied area. The results indicated that the lowest price of providing the required hydrogen was $0.496 which was achieved using the main grid. Also the lowest price of the electricity generated was $1.55 which was obtained through using EOLO VAWT in the main grid/wind turbine/solar cell scenario. Also the results suggested that the highest rate of preventing CO2 emission which was also the lowest rate of using the national grid with 3484 kg/year was associated with EOLO wind turbines where only 4% of the required electricity was generated by the national grid.
Preliminary Assessment of a Hydrogen Farm Including Health and Safety and Capacity Needs
Dec 2024
Publication
The safety engineering design of hydrogen systems and infrastructure worker education and training regulatory compliance and engagement with other stakeholders are significant to the viability and public acceptance of hydrogen farms. The only way to ensure these are accomplished is for the field of hydrogen safety engineering (HSE) to grow and mature. HSE is described as the application of engineering and scientific principles to protect the environment property and human life from the harmful effects of hydrogen-related mishaps and accidents. This paper describes a whole hydrogen farm that produces hydrogen from seawater by alkaline and proton exchange membrane electrolysers then details how the hydrogen gas will be used: some will be stored for use in a combined-cycle gas turbine some will be transferred to a liquefaction plant and the rest will be exported. Moreover this paper describes the design framework and overview for ensuring hydrogen safety through these processes (production transport storage and utilisation) which include legal requirements for hydrogen safety safety management systems and equipment for hydrogen safety. Hydrogen farms are large-scale facilities used to create store and distribute hydrogen which is usually produced by electrolysis using renewable energy sources like wind or solar power. Since hydrogen is a vital energy carrier for industries transportation and power generation these farms are crucial in assisting the global shift to clean energy. A versatile fuel with zero emissions at the point of use hydrogen is essential for reaching climate objectives and decarbonising industries that are difficult to electrify. Safety is essential in hydrogen farms because hydrogen is extremely flammable odourless invisible and also has a small molecular size meaning it is prone to leaks which if not handled appropriately might cause fires or explosions. To ensure the safe and dependable functioning of hydrogen production and storage systems stringent safety procedures are required to safeguard employees infrastructure and the surrounding environment from any mishaps.
An Overview of Hydrogen’s Application for Energy Purposes in Lithuania
Nov 2023
Publication
Hydrogen has emerged as a promising climate-neutral energy carrier able to facilitate the processes of the European Union (EU) energy transition. Green hydrogen production through the electrolysis process has gained increasing interest recently for application in various sectors of the economy. As a result of the increasing renewable energy developments in the EU hydrogen is seen as one of the most promising solutions for energy storage challenges; therefore the leading countries in the energy sector are heavily investing in research of the technical obstacles for hydrogen applications and assessment of the current hydrogen market which in turn leads to the acceleration of the upscaling of hydrogen production. The main objective of this article was to provide a comprehensive overview of various green hydrogen production transportation and industrial application technologies and challenges in Europe with a separate analysis of the situation in Lithuania. Various water electrolysis technologies and their production costs are investigated along with recent developments in storage and transportation solutions. In addition the performances and limitations of electrochemical processes are presented and analysed research trends in the field are discussed and possible solutions for performance and cost improvements are overviewed. This paper proposes a discussion of perspectives in terms of future applications and research directions.
The Impact of Methane Leakage on the Role of Natural Gas in the European Energy Transition
Sep 2023
Publication
Decarbonising energy systems is a prevalent topic in the current literature on climate change mitigation but the additional climate burden caused by methane emissions along the natural gas value chain is rarely discussed at the system level. Considering a two-basket greenhouse gas neutrality objective (both CO2 and methane) we model cost-optimal European energy transition pathways towards 2050. Our analysis shows that adoption of best available methane abatement technologies can entail an 80% reduction in methane leakage limiting the additional environmental burden to 8% of direct CO2 emissions (vs. 35% today). We show that while renewable energy sources are key drivers of climate neutrality the role of natural gas strongly depends on actions to abate both associated CO2 and methane emissions. Moreover clean hydrogen (produced mainly from renewables) can replace natural gas in a substantial proportion of its end-uses satisfying nearly a quarter of final energy demand in a climate-neutral Europe.
Hazard Footprint of Alternative Fuel Storage Concepts for Hydrogen-powered Urban Buses
Nov 2023
Publication
Hydrogen mobility is a powerful strategy to fight climate change promoting the decarbonization of the transportation sector. However the higher flammability of hydrogen in comparison with traditional fuels raises issues concerning the safety of hydrogen-powered vehicles in particular when urban mobility in crowded areas is concerned. In the present study a comparative analysis of alternative hydrogen storage concepts for buses is carried out. A specific inherent safety assessment methodology providing a hazard footprint of alternative hydrogen storage technologies was developed. The approach provides a set of ex-ante safety performance indicators and integrates a sensitivity analysis performed by a Monte Carlo method. Integral models for consequence analysis and a set of baseline frequencies are used to provide a preliminary identification of the worstcase credible fire and explosion scenarios and to rank the inherent safety of alternative concepts. Cryocompressed storage in the supercritical phase resulted as the more hazardous storage concept while cryogenic storage in the liquid phase at ambient pressure scored the highest safety performance. The results obtained support risk-informed decision-making in the shift towards the promotion of sustainable mobility in urban areas.
Lower-Carbon Hydrogen Production from Wastewater: A Comprehensive Review
Oct 2024
Publication
Hydrogen has the capability of being a potential energy carrier and providing a long-term solution for sustainable lower-carbon and ecologically benign fuel supply. Because lower-carbon hydrogen is widely used in chemical synthesis it is regarded as a fuel with no emissions for transportation. This review paper offers a novel technique for producing hydrogen using wastewater in a sustainable manner. The many techniques for producing hydrogen with reduced carbon emissions from wastewater are recognized and examined in detail taking into account the available prospects significant obstacles and potential future paths. A comparison of the assessment showed that water electrolysis and dark fermentation technologies are the most effective methods for hydrogen generation from wastewater with microbial electrolysis and photofermentation. Thus the incorporation of systems that are simultaneously producing lower-carbon hydrogen and meant for wastewater treatment is important for the minimization of emissions from greenhouse gases and recovering the energy utilized in the treatment of wastewater.
Simple Energy Model for Hydrogen Fuel Cell Vehicles: Model Development and Testing
Dec 2024
Publication
Hydrogen fuel cell vehicles (HFCVs) are a promising technology for reducing vehicle emissions and improving energy efficiency. Due to the ongoing evolution of this technology there is limited comprehensive research and documentation regarding the energy modeling of HFCVs. To address this gap the paper develops a simple HFCV energy consumption model using new fuel cell efficiency estimation methods. Our HFCV energy model leverages real-time vehicle speed acceleration and roadway grade data to determine instantaneous power exertion for the computation of hydrogen fuel consumption battery energy usage and overall energy consumption. The results suggest that the model’s forecasts align well with real-world data demonstrating average error rates of 0.0% and −0.1% for fuel cell energy and total energy consumption across all four cycles. However it is observed that the error rate for the UDDS drive cycle can be as high as 13.1%. Moreover the study confirms the reliability of the proposed model through validation with independent data. The findings indicate that the model precisely predicts energy consumption with an error rate of 6.7% for fuel cell estimation and 0.2% for total energy estimation compared to empirical data. Furthermore the model is compared to FASTSim which was developed by the National Renewable Energy Laboratory (NREL) and the difference between the two models is found to be around 2.5%. Additionally instantaneous battery state of charge (SOC) predictions from the model closely match observed instantaneous SOC measurements highlighting the model’s effectiveness in estimating real-time changes in the battery SOC. The study investigates the energy impact of various intersection controls to assess the applicability of the proposed energy model. The proposed HFCV energy model offers a practical versatile alternative leveraging simplicity without compromising accuracy. Its simplified structure reduces computational requirements making it ideal for real-time applications smartphone apps in-vehicle systems and transportation simulation tools while maintaining accuracy and addressing limitations of more complex models.
Energy Storage Strategy - Narrative
Feb 2023
Publication
This narrative document sets out the main rationale for hydrogen storage development at scale in the UK: - To meet net zero the UK will need considerable energy storage - Hydrogen storage will be a major and essential part of this - Physical hydrogen storage is needed in the UK - Only geological hydrogen storage can deliver at the scale needed within the timescales for net zero - Geological hydrogen storage should be supported through a viable business model now to ensure it comes online in the 2030s.
Reversible Solid Oxide Cell Coupled to an Offshore Wind Turbine as a Poly-generation Energy System for Auxiliary Backup Generaiton and Hydrogen Production
Nov 2022
Publication
The coupling of a reversible Solid Oxide Cell (rSOC) with an offshore wind turbine is investigated to evaluate the mutual benefits in terms of local energy management. This integrated system has been simulated with a dynamic model under a control algorithm which manages the rSOC operation in relation to the wind resource implementing a local hydrogen storage with a double function: (i) assure power supply to the wind turbine auxiliary systems during power shortages (ii) valorize the heat produced to cover the desalinization system needs. With an export-based strategy which maximize the rSOC capacity factor up to 15 tons of hydrogen could be produced for other purposes. The results show the compatibility between the auxiliary systems supply of a 2.3 MW wind turbine and a 120/21 kWe rSOC system which can cover the auxiliaries demand during wind shortages or maintenance. The total volume required by such a system occupy less than the 2% if compared with the turbine tower volume. Additionally thermal availability exceeds the desalination needs representing a promising solution for small-scale onsite desalination in offshore environments.
Solar Hydrogen Production and Storage in Solid Form: Prospects for Materials and Methods
Sep 2024
Publication
Climatic changes are reaching alarming levels globally seriously impacting the environment. To address this environmental crisis and achieve carbon neutrality transitioning to hydrogen energy is crucial. Hydrogen is a clean energy source that produces no carbon emissions making it essential in the technological era for meeting energy needs while reducing environmental pollution. Abundant in nature as water and hydrocarbons hydrogen must be converted into a usable form for practical applications. Various techniques are employed to generate hydrogen from water with solar hydrogen production—using solar light to split water—standing out as a cost-effective and environmentally friendly approach. However the widespread adoption of hydrogen energy is challenged by transportation and storage issues as it requires compressed and liquefied gas storage tanks. Solid hydrogen storage offers a promising solution providing an effective and low-cost method for storing and releasing hydrogen. Solar hydrogen generation by water splitting is more efficient than other methods as it uses self-generated power. Similarly solid storage of hydrogen is also attractive in many ways including efficiency and cost-effectiveness. This can be achieved through chemical adsorption in materials such as hydrides and other forms. These methods seem to be costly initially but once the materials and methods are established they will become more attractive considering rising fuel prices depletion of fossil fuel resources and advancements in science and technology. Solid oxide fuel cells (SOFCs) are highly efficient for converting hydrogen into electrical energy producing clean electricity with no emissions. If proper materials and methods are established for solar hydrogen generation and solid hydrogen storage under ambient conditions solar light used for hydrogen generation and utilization via solid oxide fuel cells (SOFCs) will be an efficient safe and cost-effective technique. With the ongoing development in materials for solar hydrogen generation and solid storage techniques this method is expected to soon become more feasible and cost-effective. This review comprehensively consolidates research on solar hydrogen generation and solid hydrogen storage focusing on global standards such as 6.5 wt% gravimetric capacity at temperatures between −40 and 60 ◦C. It summarizes various materials used for efficient hydrogen generation through water splitting and solid storage and discusses current challenges in hydrogen generation and storage. This includes material selection and the structural and chemical modifications needed for optimal performance and potential applications.
Green Hydrogen and its Unspoken Challenges for Energy Justice
Oct 2024
Publication
Green hydrogen is often promoted as a key facilitator for the clean energy transition but its implementation raises concerns around energy justice. This paper examines the socio-political and techno-economic challenges that green hydrogen projects may pose to the three tenets of energy justice: distributive procedural and recognition justice. From a socio-political perspective the risk of neocolonial resource extraction uneven distribution of benefits exclusion of local communities from decision-making and disregard for indigenous rights and cultures threaten all three justice tenets. Techno-economic factors such as water scarcity land disputes and resource-related conflicts in potential production hotspots further jeopardise distributive and recognition justice. The analysis framed by an adapted PEST model reveals that while green hydrogen holds promise for sustainable development its implementation must proactively address these justice challenges. Failure to do so could perpetuate injustices exploitation and marginalisation of vulnerable communities undermining the sustainability goals it aims to achieve. The paper highlights the need for inclusive and equitable approaches that respect local sovereignty integrate diverse stakeholders and ensure fair access and benefit-sharing. Only by centring justice considerations can the transition to green hydrogen catalyse positive social change and realise its full potential as a driver of sustainable energy systems.
Hydrogen Equipment Enclosure Risk Reduction through Earlier Detection of Component Failures
Sep 2023
Publication
Hydrogen component reliability and the hazard associated with failure rates is a critical area of research for the successful implementation and growth of hydrogen technology across the globe. The research team has partnered to quantify system risk reduction through earlier detection of hydrogen component failures. A model of hydrogen dispersion in a hydrogen equipment enclosure has been developed utilizing experimentally quantified hydrogen component leak rates as inputs. This model provides insight into the impact of hydrogen safety sensors and ventilation on the flammable mass within a hydrogen equipment enclosure. This model also demonstrates the change in safety sensor response time due to detector placement under various leak scenarios. The team looks to improve overall hydrogen system safety through an improved understanding of hydrogen component reliability and risk mitigation methods. This collaboration fits under the work program of IEA Hydrogen Task 43 Subtask E Hydrogen System Safety.
A Systematic Study on Techno-Economic Evaluation of Hydrogen Production
Sep 2023
Publication
This paper aims to perform a systematic review with a bibliometric approach of the technoeconomic evaluation studies of hydrogen production. To achieve this objective a comprehensive outline of hydrogen production processes from fossil and renewable sources is presented. The results reveal that electrolysis classified as water splitting is the most investigated process in the literature since it contributes to a reduction in greenhouse gas emissions and presents other advantages such as maturity and applicability energy efficiency flexibility and energy storage potential. In addition the processes of gasification classified as thermochemical and steam reforming classified as catalytic reforming are worth mentioning. Regarding the biological category there is a balance between research on photo fermentation and dark fermentation. The literature on the techno-economic evaluation of hydrogen production highlights significant gaps including a scarcity of comprehensive studies a lack of emphasis on commercial viability an absence of sensitivity analysis and the need for comparative analyses between production technologies.
Performance Analysis of Hybrid Solar/H2/Battery Renewable Energy System for Residential Electrification
Mar 2019
Publication
Due to the privileged location of Ecuador in terms of solar radiation the analysis and use of renewable energy system (RES) using solar energy has been of great interest during the last years. At the same time the supply support of RES in terms of direct current (DC) can be faced by using fuel cell (FC) systems which can give to the systems fully autonomy from fossil fuels. The aim of this paper is to propose the design of a hybrid photovoltaic-fuel cell-battery (PV-FC-B) system to supply the required electrical energy for residential use in the city of Guayaquil. The feasibility analysis constitutive elements of the system and adjusted variables are computed and presented using a computational tool. The results evidence that this system is not economically viable since the cost of energy (COE) in Ecuador is low compared to the COE of the proposed system. However a more detailed analysis considering the inherent benefits of no emission of pollutant gases is required to have a complete outlook.
Science and Technology of Ammonia Combustion
Nov 2018
Publication
This paper focuses on the potential use of ammonia as a carbon-free fuel and covers recent advances in the development of ammonia combustion technology and its underlying chemistry. Fulfilling the COP21 Paris Agreement requires the de-carbonization of energy generation through utilization of carbon-neutral and overall carbon-free fuels produced from renewable sources. Hydrogen is one of such fuels which is a potential energy carrier for reducing greenhouse-gas emissions. However its shipment for long distances and storage for long times present challenges. Ammonia on the other hand comprises 17.8% of hydrogen by mass and can be produced from renewable hydrogen and nitrogen separated from air. Furthermore thermal properties of ammonia are similar to those of propane in terms of boiling temperature and condensation pressure making it attractive as a hydrogen and energy carrier. Ammonia has been produced and utilized for the past 100 years as a fertilizer chemical raw material and refrigerant. Ammonia can be used as a fuel but there are several challenges in ammonia combustion such as low flammability high NOx emission and low radiation intensity. Overcoming these challenges requires further research into ammonia flame dynamics and chemistry. This paper discusses recent successful applications of ammonia fuel in gas turbines co-fired with pulverize coal and in industrial furnaces. These applications have been implemented under the Japanese ‘Cross-ministerial Strategic Innovation Promotion Program (SIP): Energy Carriers’. In addition fundamental aspects of ammonia combustion are discussed including characteristics of laminar premixed flames counterflow twin-flames and turbulent premixed flames stabilized by a nozzle burner at high pressure. Furthermore this paper discusses details of the chemistry of ammonia combustion related to NOx production processes for reducing NOx and validation of several ammonia oxidation kinetics models. Finally LES results for a gas-turbine-like swirl-burner are presented for the purpose of developing low-NOx single-fuelled ammonia gas turbine combustors.
A 500 kW Hydrogen Fuel Cell-powered Vessel: From Concept to Sailing
Sep 2024
Publication
This paper presents the “Three Gorges Hydrogen Boat No. 1” a novel green hydrogen-powered vessel that has been successfully delivered and is currently sailing. This vessel integrated with a hydrogen production and bunkering station at its dedicated dock achieves zero-carbon emissions. It stores 240 kg of 35 MPa gaseous hydrogen and has a fuel cell system rated at 500 kW. We analysed the engineering details of the marine hydrogen system including hydrogen bunkering storage supply fuel cell and the hybrid power system with lithium-ion batteries. In the first bunkering trial the vessel was safely refuelled with 200 kg of gaseous hydrogen in 156 min via a bunkering station 13 m above the water surface. The maximum hydrogen pressure and temperature recorded during bunkering were 35.05 MPa and 39.04 ◦C respectively demonstrating safe and reliable shore-toship bunkering. For the sea trial the marine hydrogen system operated successfully during a 3-h voyage achieving a maximum speed of 28.15 km/h (15.2 knots) at rated propulsion power. The vessel exhibited minimal noise and vibration and its dynamic response met load change requirements. To prevent rapid load changes to the fuel cells 68 s were used to reach 483 kW from startup and 62 s from 480 kW to zero. The successful bunkering and operation of this hydrogen-powered vessel demonstrates the feasibility of zero-carbon emission maritime transport. However four lessons were identified concerning bunkering speed hydrogen cylinder leakage hydrogen pressure regulator malfunctions and fuel cell room space. The novelty of this work lies in the practical demonstration of a fully operational hydrogen-powered maritime vessel achieving zero emissions encompassing its design building operation and lessons learned. These parameters and findings can be used as a baseline for further engineering research.
Bibliometric Analysis of Global Publications on Management, Trends, Energy, and the Innovation Impact of Green Hydrogen Production
Dec 2024
Publication
The aim of this bibliometric analysis was to evaluate the evolution of scientific research in hydrogen focusing on green hydrogen production storage and utilization. Articles from prominent databases were analyzed revealing a strong emphasis on sustainable hydrogen technologies through keywords like “hydrogen production” “green hydrogen” and “solar power generation”. Mature research areas include production methods and electrolysis while emerging topics such as energy efficiency and policy are gaining traction. The most-cited papers from Energy Conversion and Management to the International Journal of Hydrogen Energy cover techno-economic assessments and case studies on deploying hydrogen technologies. Key findings highlight the variability of the Levelized Cost of Hydrogen (LCOH) across technologies and regions. Deep learning applications including Fast Fourier Transform-based forecasting and explainable AI models are transforming production optimization while Life Cycle Assessment (LCA) emphasizes renewable energy’s role in reducing carbon intensity and resource consumption. Diverse strategies such as fiscal incentives for wind energy and use of urban waste underline the importance of local solutions. This analysis reflects the rapid growth of hydrogen research driven by international collaboration and innovations in sustainable production storage and optimization. It is hoped that this paper will help to shed more light on the current and future understanding of green hydrogen.
Hydrogen Storage Capacity of Salt Caverns and Deep Aquifers Versus Demand for Hydrogen Storage: A Case Study of Poland
Nov 2023
Publication
Geological structures in deep aquifers and salt caverns can play an important role in large-scale hydrogen storage. However more work needs to be done to address the hydrogen storage demand for zero-emission energy systems. Thus the aim of the article is to present the demand for hydrogen storage expressed in the number of salt caverns in bedded rock salt deposits and salt domes or the number of structures in deep aquifers. The analysis considers minimum and maximum hydrogen demand cases depending on future energy system configurations in 2050. The method used included the estimation of the storage capacity of salt caverns in bedded rock salt deposits and salt domes and selected structures in deep aquifers. An estimation showed a large hydrogen storage potential of geological structures. In the case of analyzed bedded rock salt deposits and salt domes the average storage capacity per cavern is 0.05–0.09 TWhH2 and 0.06–0.20 TWhH2 respectively. Hydrogen storage capacity in analyzed deep aquifers ranges from 0.016 to 4.46 TWhH2. These values indicate that in the case of the upper bound for storage demand there is a need for the 62 to 514 caverns depending on considered bedded rock salt deposits and salt domes or the 9 largest analyzed structures in deep aquifers. The results obtained are relevant to the discussion on the global hydrogen economy and the methodology can be used for similar considerations in other countries.
0-D Dynamic Performance Simulation of Hydrogen-Fueled Turboshaft Engine
Oct 2024
Publication
In the last few decades the problem of pollution resulting from human activities has pushed research toward zero or net-zero carbon solutions for transportation. The main objective of this paper is to perform a preliminary performance assessment of the use of hydrogen in conventional turbine engines for aeronautical applications. A 0-D dynamic model of the Allison 250 C-18 turboshaft engine was designed and validated using conventional aviation fuel (kerosene Jet A-1). A dedicated experimental campaign covering the whole engine operating range was conducted to obtain the thermodynamic data for the main engine components: the compressor lateral ducts combustion chamber high- and low-pressure turbines and exhaust nozzle. A theoretical chemical combustion model based on the NASA-CEA database was used to account for the energy conversion process in the combustor and to obtain quantitative feedback from the model in terms of fuel consumption. Once the engine and the turbomachinery of the engine were characterized the work focused on designing a 0-D dynamic engine model based on the engine’s characteristics and the experimental data using the MATLAB/Simulink environment which is capable of replicating the real engine behavior. Then the 0-D dynamic model was validated by the acquired data and used to predict the engine’s performance with a different throttle profile (close to realistic request profiles during flight). Finally the 0-D dynamic engine model was used to predict the performance of the engine using hydrogen as the input of the theoretical combustion model. The outputs of simulations running conventional kerosene Jet A-1 and hydrogen using different throttle profiles were compared showing up to a 64% reduction in fuel mass flow rate and a 3% increase in thermal efficiency using hydrogen in flight-like conditions. The results confirm the potential of hydrogen as a suitable alternative fuel for small turbine engines and aircraft.
Assessment of Energy Footprint of Pure Hydrogen-Supplied Vehicles in Real Conditions of Long-Term Operation
Jul 2024
Publication
The desire to maintain CO2 concentrations in the global atmosphere implies the need to introduce ’new’ energy carriers for transport applications. Therefore the operational consumption of each such potential medium in the ’natural’ exploitation of vehicles must be assessed. A useful assessment method may be the vehicle’s energy footprint resulting from the theory of cumulative fuel consumption presented in the article. Using a (very modest) database of long-term use of hydrogen-powered cars the usefulness of this method was demonstrated. Knowing the energy footprint of vehicles of a given brand and type and the statistical characteristics of the footprint elements it is also possible to assess vehicle fleets in terms of energy demand. The database on the use of energy carriers such as hydrogen in the long-term operation of passenger vehicles is still relatively modest; however as it has been shown valuable data can be obtained to assess the energy demand of vehicles of a given brand and type. Access to a larger operational database will allow for wider use of the presented method.
Hydrogen Production from Methanol–Water Solution and Pure Water Electrolysis Using Nanocomposite Perfluorinated Sulfocationic Membranes Modified by Polyaniline
Oct 2022
Publication
In this work we report the preparation of Nafion membranes containing two different nanocomposite MF-4SC membranes modified with polyaniline (PANI) by the casting method through two different polyaniline infiltration procedures. These membranes were evaluated as a polymer electrolyte membrane for water electrolysis. Operating conditions were optimized in terms of current density stability and methanol concentration. A study was made on the effects on the cell performance of various parameters such as methanol concentration water and cell voltage. The energy required for pure water electrolysis was analyzed at different temperatures for the different membranes. Our experiments showed that PEM electrolyzers provide hydrogen production of 30 mL/min working at 160 mA/cm2 . Our composite PANI membranes showed an improved behavior over pristine perfluorinated sulfocationic membranes (around 20% reduction in specific energy). Methanol–water electrolysis required considerably less (around 65%) electrical power than water electrolysis. The results provided the main characteristics of aqueous methanol electrolysis in which the power consumption is 2.34 kW h/kg of hydrogen at current densities higher than 0.5 A/cm2 . This value is ~20-fold times lower than the electrical energy required to produce 1 kg of hydrogen by water electrolysis.
National Gas FutureGrid Phase 1 Closure Report
Jul 2024
Publication
This project an essential part of the National Gas HyNTS programme endeavours to align the NTS with GB’s net zero ambitions by demonstrating the operational viability of the system with varying hydrogen blends using decommissioned assets typical of the natural gas network today ultimately aiming for 100% hydrogen conveyance. Several desktop studies were undertaken within the HyNTS programme to confirm the theoretical potential of the NTS to transport hydrogen safely and reliably. Further to these studies practical demonstration was deemed necessary to bridge the knowledge gaps and ensure the system’s transition maintains the utmost safety and reliability standards. A range of tests on decommissioned assets were conducted offline in a controlled environment to ensure robust outcomes that will ultimately start to build the safety case for a hydrogen network. The key deliverables and testing achievements of FutureGrid included: • Operational testing with natural gas and 2% 5% 20% and 100% hydrogen to verify the network’s ability to transport hydrogen and varying blends. • Standalone offline testing modules complementing evidence gathered on the main test facility. These address specific areas of concern including material permeation flange integrity asset leakage and rupture consequence which are essential for risk mitigation and safety assurance. FutureGrid is a global first facility and a critical part of National Gas’ hydrogen programme providing physical evidence of the capability of our network to transport hydrogen. It provides key evidence for hydrogen blending alongside 100% hydrogen pipelines which are planned under Project Union our Hydrogen Backbone across GB. FutureGrid is pivotal in the journey to reaching Net Zero by 2050 and is a fully operational proven technical demonstrator. FutureGrid’s repurposed assets are representative of today’s live high pressure gas network and have been subjected to testing at different blends of natural gas with hydrogen and 100% hydrogen; this was achieved with no major findings in differences in terms of how the assets interact with hydrogen. The overall project completion date was delayed from November 2023 to February 2024 due to technical issues with the newly built hydrogen re‑compressor. There were no changes made to the project costs.
Advancing Life Cycle Assessment of Sustainable Green Hydrogen Production Using Domain-Specific Fine-Tuning by Large Language Models Augmentation
Nov 2024
Publication
Assessing the sustainable development of green hydrogen and assessing its potential environmental impacts using the Life Cycle Assessment is crucial. Challenges in LCA like missing environmental data are often addressed using machine learning such as artificial neural networks. However to find an ML solution researchers need to read extensive literature or consult experts. This research demonstrates how customised LLMs trained with domain-specific papers can help researchers overcome these challenges. By starting small by consolidating papers focused on the LCA of proton exchange membrane water electrolysis which produces green hydrogen and ML applications in LCA. These papers are uploaded to OpenAI to create the LlamaIndex enabling future queries. Using the LangChain framework researchers query the customised model (GPT-3.5-turbo) receiving tailored responses. The results demonstrate that customised LLMs can assist researchers in providing suitable ML solutions to address data inaccuracies and gaps. The ability to quickly query an LLM and receive an integrated response across relevant sources presents an improvement over manually retrieving and reading individual papers. This shows that leveraging fine-tuned LLMs can empower researchers to conduct LCAs more efficiently and effectively.
A Gis-based on Application of Monte Carlo and Multi-criteria Decision-making Approach for Site Suitability Analysis of Solar-hydrogen Production: Case of Cameroon
Dec 2024
Publication
This article analyzes and compares three methodologies for identifying suitable regions for solar hydrogen production using photovoltaic panels: AHP (Analytic Hierarchy Process) FAHP (Fuzzy Analytic Hierarchy Process) and MC-FAHP (Monte Carlo FAHP) integrated with GIS (Geographic Information Systems). The study employs ten criteria across technical (Global Horizontal Irra diance temperature slope elevation orientation) economic (distance from transportation and electrical networks) and social (population density proximity to residential areas) factors. Environmental and exclusion criteria define restrictive zones. The analysis reveals that while all three methods agree on areas of low suitability they diverge in their classification of "Suitable" "Highly Suitable" and "Most Suitable" regions. FAHP identifies 229.573 km2 as "Highly Suitable" compared to AHP’s 222.048 km2 and MC-FAHP’s 230.299 km2 for "Suitable" areas. Despite these differences the energy potential is consistent across methods totaling around 79000 TWh/year with MC-FAHP estimating the highest hydrogen production potential at 1.51 billion tons/year. The study concludes that fuzzy-based methods (FAHP and MC-FAHP) better handle uncertainties than traditional AHP. The MC-FAHP method in particular performs well in managing stochastic variability and yielding more reliable results. The findings are validated through a case study in Guider and Maroua highlighting the importance of socio-economic and environmental criteria in decision-making. A sensitivity analysis reveals that economic and social criteria significantly influence land suitability underscoring the importance of criteria selection in decision-making.
Wind-coupled Hydrogen Integration for Commercial Greenhouse Food and Power Production: A Case Study
Oct 2024
Publication
This study investigates the feasibility of using green hydrogen technology produced via Proton Exchange Membrane (PEM) electrolysis powered by a 200 MW wind farm for a commercial Greenhouse in Ontario Canada. Nine different scenarios are analyzed exploring various approaches to hydrogen (H2) production transportation and utilization for electricity generation. The aim is to transition from using natural gas to using varying combinations of H2 and natural gas that include 10 % 20 % and 100 % of H2 with 90 % 80 % and 0 % of natural gas to generate 13.3 MW from Combined Heat and Power (CHP) engines. The techno-economic parameters considered for the study are the levelized cost of hydrogen (LCOH) payback period (PBT) internal rate of return (IRR) and discounted payback period (DPB). The study found that a 10 % H2-Natural Gas blend using existing wired or transmission line (W-10H2) with 5 days of storage capacity and 2190 h of CHP operation per year had the lowest cost with a LCOH of USD 3.69/kg. However 100 % of H2 using existing wired or transmission line (W-100H2) with the same storage and operation hours revealed better PBT IRR and DPB with values of 6.205 years 15.16 % and 7.993 years respectively. It was found impractical to build a new pipeline or transport H2 via tube trailer from wind farm site to greenhouse. A sensitivity analysis was also conducted to understand what factors affect the LCOH value the most.
Hydrogen as an Energy Source: A Review of Production Technologies and Challenges of Fuel Cell Vehicles
Oct 2024
Publication
The significant growth of both the global population and economy in recent years has led to a rise in global energy demand. Fossil fuels have a significant contribution to generating energy which has raised concerns about sustainability and environmental impact. There are widespread efforts to find alternative sources in order to reduce dependence on fossil fuels and mitigate their environmental consequences. Among the alternative sources hydrogen has emerged as a promising option due to its potential to be a clean and sustainable energy source. Hydrogen possesses several advantages such as a high calorific value a high reaction rate various sources and the ability to integrate with other renewable energy sources and existing systems. These attributes render hydrogen a stable and reliable energy resource which can help reduce greenhouse gas emissions (GHG) and transition towards a sustainable future. In this review paper distinct hydrogen production technologies such as conventional renewable and nuclear energy are investigated and compared. In addition the challenges and limitations of the application of hydrogen fuel cells on vehicles and hydrogen circulation components are explored. Finally the environmental impact of hydrogen vehicles specifically their role in promoting sustainable development is investigated.
Overview and Prospects of Low-emissions Hydrogen (H2) Energy Systems: Roadmap for a Sustainable H2 Economy
Jul 2024
Publication
Hydrogen (2 ) has a big role to play in energy transition to achieve net-zero carbon emissions by 2050. For 2 to compete with other fuels in the energy market more research is required to mitigate key issues like greenhouse gas (GHG) emissions safety and end-use costs. For these reasons a software-supported technical overview of 2 production storage transportation and utilisation is introduced. Drawbacks and mitigation approaches for 2 technologies were highlighted. The recommended areas include solar thermal or renewable-powered plasma systems for feedstock preheating and oxy-hydrogen combustion to meet operating temperatures and heat duties due to losses; integration of electrolysis of 2 into hydrocarbon reforming methods to replace air separation unit (ASU); use of renewable power sources for electrical units and the introduction of thermoelectric units to maximise the overall efficiency. Furthermore a battolyser system for small-scale energy storage; new synthetic hydrides with lower absorption and desorption energy; controlled parameters and steam addition to the combustor/cylinder and combustors with fitted heat exchangers to reduce emissions and improve the overall efficiency are also required. This work also provided detailed information on any of these systems implementations based on location factors and established a roadmap for 2 production and utilisation. The proposed 2 production technologies are hybrid pyrolysis-electrolysis and integrated AD-MEC and DR systems using renewable bioelectrochemical and low-carbon energy systems. Production and utilisation of synthetic natural gas (NG) using renewablepowered electrolysis of 2 oxy-fuel and direct air capture (DAC) is another proposed 2 energy system for a sustainable 2 economy. By providing these factors and information researchers can work towards pilot development and further efficiency enhancement.
Everything About Hydrogen Podcast: "Stat of the Union" with EAH Hosts
May 2024
Publication
This week’s episode is a discussion between EAH hosts Patrick Molloy Alicia Eastman and Chris Jackson. The team cover the current status of hydrogen regulation innovation financing markets and consolidation. Hanging over most conversations in the decarbonization or future fuels space is the perpetual question: When will investors actually step up with significant capital to help companies make it through the development desert instead of letting promising companies languish in the double dunes of despair? There has been a lot of talk but not a lot of action. Listen to the team unpack recent developments and hopes for the future.
The podcast can be found on their website.
The podcast can be found on their website.
Stakeholder Perspectives on the Scale-up of Green Hydrogen and Electrolyzers
Nov 2023
Publication
Green hydrogen is a promising alternative to fossil fuels. However current production capacities for electrolyzers and green hydrogen are not in line with national political goals and projected demand. Considering these issues we conducted semi-structured interviews to determine the narratives of different stakeholders during this transformation as well as challenges and opportunities for the green hydrogen value chain. We interviewed eight experts with different roles along the green hydrogen value chain ranging from producers and consumers of green hydrogen to electrolyzer manufacturers and consultants as well as experts from the political sphere. Most experts see the government as necessary for scale-up by setting national capacity targets policy support and providing subsidies. However the experts also accuse the governments of delaying development through overregulation and long implementation times for regulations. The main challenges that were identified are the current lack of renewable electricity and demand for green hydrogen. Demand for green hydrogen is influenced by supply costs which partly depend on prices for electrolyzers. However one key takeaway of the interviews is the skeptical assessments by the experts on the currently discussed estimates for price reduction potential of electrolyzers. While demand supply and prices are all factors that influence each other they result in feedback loops in investment decisions for the energy and manufacturing industries. A second key takeaway is that according to the experts current investment decisions in new production capacities are not solely dependent on short-term financial gains but also based on expected first mover advantages. These include experience and market share which are seen as factors for opportunities for future financial gains. Summarized the results present several challenges and opportunities for green hydrogen and electrolyzers and how to address them effectively. These insights contribute to a deeper understanding of the dynamics of the emerging green hydrogen value chain.
Innovative Hybrid Energy Storage Systems with Sustainable Integration of Green Hydrogen and Energy Management Solutions for Standalone PV Microgrids Based on Reduced Fractional Gradient Descent Algorithm
Oct 2024
Publication
This paper investigates innovative solutions to enhance the performance and lifespan of standalone photovoltaic (PV)-based microgrids with a particular emphasis on off-grid communities. A major challenge in these systems is the limited lifespan of batteries. To overcome this issue researchers have created hybrid energy storage systems (HESS) along with advanced power management strategies. This study introduces innovative multi-level HESS approaches and a related energy management strategy designed to alleviate the charge/discharge stress on batteries. Comprehensive Matlab Simulink models of various HESS topologies within standalone PV microgrids are utilized to evaluate system performance under diverse weather conditions and load profiles for rural site. The findings reveal that the proposed HESS significantly extends battery life expectancy compared to existing solutions. Furthermore the paper presents a novel energy management strategy based on the Reduced Fractional Gradient Descent (RFGD) algorithm optimization tailored for hybrid systems that include photovoltaic fuel cell battery and supercapacitor components. This strategy aims to minimize hydrogen consumption of Fuel Cells (FCs) thereby supporting the production of green ammonia for local industrial use. The RFGD algorithm is selected for its minimal user-defined parameters and high convergence efficiency. The proposed method is compared with other algorithms such as the Lyrebird Optimization Algorithm (LOA) and Osprey Optimization Algorithm (OOA). The RFGD algorithm exhibits superior accuracy in optimizing energy management achieving a 15% reduction in hydrogen consumption. Its efficiency is evident from the reduced computational time compared to conventional algorithms. Although minor losses in computational resources were observed they were substantially lower than those associated with traditional optimization techniques. Overall the RFGD algorithm offers a robust and efficient solution for enhancing the performance of hybrid energy systems.
Techno-economic Analysis for Advanced Methods of Green Hydrogen Production
May 2024
Publication
In the ongoing effort to reduce carbon emissions on a worldwide scale green hydrogen which is generated through environmentally responsible processes has emerged as a significant driving force. As the demand for clean energy continues to rise it is becoming increasingly important to have a solid understanding of the technological and economic elements of modern techniques of producing green hydrogen. In the context of green hydrogen generation understanding green hydrogen production's techno-economic features is necessary to reduce carbon emissions and transition to a low-carbon economy. associated with breakthroughs in technology the present study examines the most fascinating and relevant aspects of techno-economic analysis. Despite challenges green hydrogen can help the world move to a cleaner more sustainable energy future with solid analytical frameworks and legislation.
Optimizing Green Hydrogen Strategies in Tunisia: A Combined SWOT-MCDM Approach
Oct 2024
Publication
Tunisia's rapid industrial expansion and population growth have created a pressing energy deficit despite the country's significant yet largely untapped renewable energy potential. This study addressed this challenge by developing a comprehensive framework to identify and evaluate strategies for promoting green hydrogen production from renewable energy sources in Tunisia. A Strength Weakness Opportunity and Threat (SWOT) analysis incorporating social economic and environmental dimensions was conducted to formulate potential solutions. The Step-wise Weight Assessment Ratio Analysis (SWARA) method facilitated the weighting of SWOT factors and subfactors. Subsequently a multi-criteria decision-making approach employing the gray technique for order preference by similarity to ideal solution (TOPSIS-G) method (validated by gray additive ratio assessment (ARAS-G) gray complex proportional assessment (COPRAS-G) and gray multi-objective optimization by ratio analysis (MOORA-G) was used to rank the identified strategies. The SWOT analysis revealed "Strengths" as the most influential factor with a relative weight of 47.3% followed by "Weaknesses" (26.5%) "Threats" (15.6%) and "Opportunities" (10.6%). Specifically experts emphasized Tunisia's renewable energy potential (21.89%) and robust power system (12.11%) as primary strengths. Conversely high investment costs (11.2%) and political instability (7.77%) posed substantial threat. Positive socio-economic impacts represented a key opportunity with a score of 5.2%. As for the strategies prioritizing criteria production cost ranked first with a score of 13.5% followed by environmental impact (12.8%) renewable energy potential (12.0%) and mitigation costs (11.3%). The gray TOPSIS analysis identified two key strategies: leveraging Tunisia's wind and solar resources and fostering regional cooperation for project implementation. The robustness of these strategies is confirmed by the strong correlation between TOPSIS-G ARAS-G COPRAS-G and MOORA-G results. Overall the study provides a comprehensive roadmap and expert-informed decision-support tools offering valuable insights for policymakers investors and stakeholders in Tunisia and other emerging economies facing similar energy challenges.
Numerical Modelling of Hydrogen Release and Dispersion
Jul 2021
Publication
Hydrogen is the most abundant element on earth being a low polluting and high efficiency fuel that can be used for various applications such as power generation heating or transportation. As a reaction to climate change authorities are working for determining the most promising applications for hydrogen one of the best examples of crossborder initiative being the IPCEI (Important Project of Common European Interest) on Hydrogen under development at EU level. Given the large interest for future uses of hydrogen special safety measures have to be implemented for avoiding potential accidents. If hydrogen is stored and used under pressure accidental leaks from pressure vessels may result in fires or explosions. Worldwide researchers are investigating possible accidents generated by hydrogen leaks. Special attention is granted to the atmospheric dispersion after the release so that to avoid fires or explosions. The use of consequence modelling software within safety and risk studies has shown its’ utility worldwide. In this paper there are modelled the consequences of the accidental release and atmospheric dispersion of hydrogen from a pressure tank using state-of-the-art QRA software. The simulation methodology used in this paper uses the “leak” model for carrying out discharge calculations. This model calculates the release rate and state of the gas after its expansion to atmospheric pressure. Accidental release of hydrogen is modelled by taking into account the process and meteorological conditions and the properties of the release point. Simulation results can be used further for land use planning or may be used for establishing proper protection measures for surrounding facilities. In this work we analysed two possible accident scenarios which may occur at an imaginary hydrogen refuelling station accidents caused by the leaks of the pressure vessel with diameters of 10 and 20 mm for a pressure tank filled with hydrogen at 35 MPa / 70 MPa. Process Hazard Analysis Software Tool 8.4 has been used for assessing the effects of the scenarios and for evaluating the hazardous extent around the analysed installation. Accident simulation results have shown that the leak size has an important effect on the flammable/explosive ranges. Also the jet fire’s influence distance is strongly influenced by the pressure and actual size of the accidental release.
Management of Hybrid Wind and Photovoltaic System Electrolyzer for Green Hydrogen Production and Storage in the Presence of a Small Fleet of Hydrogen Vehicles— An Economic Assessment
Dec 2023
Publication
Nowadays with the need for clean and sustainable energy at its historical peak new equipment strategies and methods have to be developed to reduce environmental pollution. Drastic steps and measures have already been taken on a global scale. Renewable energy sources (RESs) are being installed with a growing rhythm in the power grids. Such installations and operations in power systems must also be economically viable over time to attract more investors thus creating a cycle where green energy e.g. green hydrogen production will be both environmentally friendly and economically beneficial. This work presents a management method for assessing wind–solar– hydrogen (H2 ) energy systems. To optimize component sizing and calculate the cost of the produced H2 the basic procedure of the whole management method includes chronological simulations and economic calculations. The proposed system consists of a wind turbine (WT) a photovoltaic (PV) unit an electrolyzer a compressor a storage tank a fuel cell (FC) and various power converters. The paper presents a case study of green hydrogen production on Sifnos Island in Greece through RES together with a scenario where hydrogen vehicle consumption and RES production are higher during the summer months. Hydrogen stations represent H2 demand. The proposed system is connected to the main power grid of the island to cover the load demand if the RES cannot do this. This study also includes a cost analysis due to the high investment costs. The levelized cost of energy (LCOE) and the cost of the produced H2 are calculated and some future simulations correlated with the main costs of the components of the proposed system are pointed out. The MATLAB language is used for all simulations.
A Two-Stage Robust Optimization Strategy for Long-Term Energy Storage and Cascaded Utilization of Cold and Heat Energy in Peer-to-Peer Electricity Energy Trading
Jan 2025
Publication
This study addresses the optimization of urban integrated energy systems (UIESs) under uncertainty in peer-to-peer (P2P) electricity trading by introducing a two-stage robust optimization strategy. The strategy includes a UIES model with a photovoltaic (PV)–green roof hydrogen storage and cascading cold/heat energy subsystems. The first stage optimizes energy trading volume to maximize social welfare while the second stage maximizes operational profit considering uncertainties in PV generation and power prices. The Nested Column and Constraint Generation (NC&CG) algorithm enhances privacy and solution precision. Case studies with three UIESs show that the model improves economic performance energy efficiency and sustainability increasing profits by 1.5% over non-P2P scenarios. Adjusting the robustness and deviation factors significantly impacts P2P transaction volumes and profits allowing system operators to optimize profits and make risk-aligned decisions.
A Holistic Green System Coupling Hydrogen Production with Wastewater Valorisation
May 2022
Publication
Green hydrogen represents a critical underpinning technology for achievingcarbon neutrality. Although researchers often fixate on its energy inputs atruly ‘green’ hydrogen production process would also be sustainable in termsof water and materials inputs. To address this holistic challenge we demon-strate a new green hydrogen production system which can utilize secondarywastewater as the input (preserving scarce fresh water supplies for drinkingand sanitation). The enabling feature of the proposed system is a self-grownbifunctional CoNi electrode which consists of ultrathin spontaneously depos-ited CoNi nanosheets on a three-dimensional nickel foam. As such a greensynthesis process was developed using an immersion procedure at room-temperature with zero net energy input. Testing revealed that the synthesizedCoNi electrodes can reach a current density of 10 mA cm2 at a small overpo-tential of 197 mV for the hydrogen evolution reaction and 315 mV for the oxy-gen evolution reaction in alkalified wastewater. The values are 16.5%and 6.5% smaller than that from precious catalysts (20 wt% Pt/C and RuO 2 respectively). Importantly this CoNi catalyst offers outstanding durability foroverall wastewater splitting. A prototype solar-energy-powered rooftop waste-water splitting system was constructed and can produce more than 100 Lhydrogen on a sunny day in Sydney Australia. Taken together these resultsindicate that it is promising to unlock holistically green routes for hydrogenproduction by wastewater uplifting with regards to water energy and mate-rials synthesis.
Study on the Performance of Membrane Reactor Using Steam Methane Reforming for Hydrogen Production Heated by HTGR
Jun 2025
Publication
Using High-Temperature Gas-cooled Reactor (HTGR) for hydrogen production through steam methane reforming (SMR) offers advantages such as high hydrogen yield methane savings relatively low cost and ease of scale-up. However due to the limitation of the temperature of the heating helium gas the methane conversion ratio of SMR using HTGR is much lower than that of traditional SMR. The membrane reactor (MR) with its high conversion efficiency compact structure and low cost is a suitable way to improve the methane conversion ratio. This study establishes a one-dimensional reaction flow model for MR heated by the helium gas from HTGR. And the model is validated and applied to analyze the performance of MR. The results show that compared to the original reformer tube MR demonstrates superior performance especially at higher methane conversion ratio and hydrogen yield. And the significant impact of sweep gas and membrane thickness on the performance of MR is discussed in detail. This work offers a new insight into highly enhancing the efficiency of SMR for hydrogen production using HTGR.
Hydrogen as a Panacea for Decarbonising Everything? Exploring Contested Hydrogen Pathways in Germany
Oct 2023
Publication
Technological change is often seen as part of the solution to problems of global sustainability. A wide-ranging literature on how path dependent—often fossil fuel-based—socio-technical configurations can be overcome by more sustainable configurations has emerged over the last two decades. One potential transition pathway to transform electricity heat and mobility systems as well as industrial production is the use of hydrogen. In recent years hydrogen has received increasing attention as part of decarbonisation strategies in many countries as well as by international organisations such as the International Energy Agency or the International Renewable Energy Agency. Also in Germany it has become a central component of climate change policy and is seen by some actors almost as a kind of panacea where the use of hydrogen is expected to decarbonise a wide range of sectors. Policy makers have the ambition for Germany to become a leader in hydrogen development and therefore help to contribute to what Grubler called ‘grand patterns of technological change’. The aim of this paper is to analyse whether relevant actors share expectations for transition pathways based on hydrogen which would foster wide diffusion. Our empirical analysis shows that there are multiple contested pathways both in terms of how hydrogen is produced as well as in which applications or sectors it is to be used. This causes uncertainty and slows down hydrogen developments in Germany. We contribute to an emerging literature on the politics of contested transition pathways and also critically engage with Grubler’s ‘grand patterns’ argument. Results support the idea that the concept of socio-technical pathways allows to expose tensions between competing values and interests. The German government is under considerable pressure regarding competing visions on hydrogen transition pathways. A targeted political prioritisation of hydrogen applications could mitigate tensions and support a shared vision.
Prediction of Hydrogen Production in Proton Exchange Membrane Water Electrolysis via Neural Networks
Sep 2024
Publication
Advancements in water electrolysis technologies are crucial for green hydrogen production. Proton exchange membrane water electrolysis (PEMWE) is characterized by its efficiency and environmental benefits. The pre diction and optimization of hydrogen production rates (HPRs) in PEMWE systems is difficult and still challenging because of the complexity of the system as well as the operational parameters. The integration of artificial in telligence (AI) and machine learning (ML) appears to be effective in optimization within the energy sector. Hence this work employs the artificial neural network (ANN) to develop a model that accurately predicts HPR in PEMWE setups. A novel approach is introduced by employing the Levenberg–Marquardt backpropagation (LMBP) algorithm for training the ANN. This model is designed to predict HPR based on critical operational parameters including anode and cathode areas (mm2 ) cell voltage (V) and current (A) water flow rate (mL/ min) power (W) and temperature (K). The optimized ANN configuration features an architecture with 7 input nodes two hidden layers of 64 neurons each and a single output node. The performance of the ANN model was evaluated against conventional regression models using key metrics: mean squared error (MSE) coefficient of determination (R2 ) and mean absolute error (MAE). The findings of this study reveal that the developed ANN model significantly outperforms traditional models achieving an R2 value of 0.9989 and an MAE of 0.012. In comparison random forest (R2 = 0.9795) linear regression (R2 = 0.9697) and support vector machines (R2 = − 0.4812) show lower predictive accuracy underscoring the ANN model’s superior performance. This work demonstrates the efficiency of the LMBP in enhancing hydrogen production forecasts and sets a foundation for future improvements in PEMWE efficiency. By enabling precise control and optimization of operational pa rameters this study contributes to the broader goal of advancing green hydrogen production as a viable and scalable alternative to fossil fuels offering both immediate and long-term benefits to sustainable energy initiatives.
Enabling Large-scale Enhanced Hydrogen Production in Deep Underground Coal Gasification in the Context of a Hydrogen Economy
Dec 2024
Publication
Underground coal gasification (UCG) is an emerging clean energy technology with significant potential for enhanced hydrogen production especially when coupled with water injection. Previous lab-scale studies have explored this potential but the mechanisms driving water-assisted hydrogen enhancement in large-scale deep UCG settings remain unclear. This study addresses this gap using numerical simulations of a large-scale deep coal model designed for hydrogen-oriented UCG. We investigated single-point and multipoint water injection stra tegies to optimize hydrogen production. Additionally we developed a retractable water injection technique to ensure sustained hydrogen output and effective cavity control. Our results indicate that the water–gas shift re action is crucial for increasing hydrogen production. Multipoint injection has been proven to be more effective than single-point injection increasing hydrogen production by 11% with an equal amount of steam. The introduction of retractable injection allows for continuous and efficient hydrogen generation with daily hydrogen production rates of approximately five times that of a conventional injection scheme and an increase in cumulative hydrogen production of approximately 105% over the same time period. Importantly the mul tipoint injection method also helped limit vertical cavity growth mitigating the risk of aquifer contamination. These findings support the potential of UCG as a low-carbon energy source in the transition to a hydrogen economy
Towards Sustainable Hydrogen Production: An Integrated Approach for Sustainability, Complexity, and Systems Thinking in the Energy Sector
Mar 2024
Publication
The energy sector constitutes a dynamic and complex system indicating that its actions are influenced not just by its individual components but also by the emergent behavior resulting from interactions among them. Moreover there are crucial limitations of previous approaches for addressing the sustainability challenge of the energy sector. Changing transforming and integrating paradigms are the most relevant leverage points for transforming a given system. In other words nowadays the integration of new predominant paradigms in order to provide a unified framework could aim at this actual transformation looking for a sustainable future. This research aims to develop a new unified framework for the integration of the following three paradigms: (1) Sustainability (2) Complexity and (3) Systems Thinking which will be applied to achieving sustainable energy production (using hydrogen production as a case study). The novelty of this work relies on providing a holistic perspective through the integration of the aforementioned paradigms considering the multiple and complex interdependencies among the economy the environment and the economy. For this purpose an integrated seven-stage approach is introduced which explores from the starting point of the integration of paradigms to the application of this integration to sustainable energy production. After applying the Three-Paradigm approach for sustainable hydrogen production as a case study 216 feedback loops are identified due to the emerged complexity linked to the analyzed system. Additionally three system dynamics-based models are developed (by increasing the level of complexity) as part of the application of the Three-Paradigm approach. This research can be of interest to a broad professional audience (e.g. engineers policymakers) as looks into the sustainability of the energy sector from a holistic perspective considering a newly developed Three-Paradigm model considering complexity and using a Systems Thinking approach.
The Future Technological Potential of Hydrogen Fuel Cell Systems for Aviation and Preliminary Co-design of a Hybrid Regional Aircraft Powertrain Through a Mathematical Tool
Feb 2023
Publication
The growing demand for air travel in the commercial sector leads to an increase in global emissions whose mitigation entails transitioning from the current fossil-fuel based generation of aircrafts to a cleaner one within a short timeframe. The use of hydrogen and fuel cells has the potential to reach zero emissions in the aerospace sector provided that required innovation and research efforts are substantially accomplished. Development programs investments and new regulations are needed for this technology to be safe and economical. In this context it makes sense to develop a model-based preliminary design methodology for a hybrid regional aircraft assisted by a battery hybridized fuel cell powertrain. The technological assumptions underlying the study refer to both current and expected data for 2035. The major contribution of the proposed methodology is to provide a mathematical tool that considers the interactions between the choice of components in terms of installed power and energy management. This simultaneous study is done because of the availability of versatile control maps. The tool was then deployed to define current and future technological scenarios for fuel cell battery and hydrogen storage systems by quickly adapting control strategies to different sizing criteria and technical specifications. In this way it is possible to facilitate the estimation of the impact of different sizing criteria and technological features at the aircraft level on the onboard electrical system the management of in-flight power the propulsion methods the impact of the masses on consumption and operational characteristics in a typical flight mission. The proposed combination of advanced sizing and energy management strategies allowed meeting mass and volume constraints with state-of-the-art PEM fuel cell and Li-ion battery specifications. Such a solution corresponds to a high degree of hybridization between the fuel cell system and battery pack (i.e. 300 kW and 750 kWh) whereas projected 2035 specs were demonstrated to help reduce mass and volume by 23 % and 40 % respectively.
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