Publications

In many processes of steel industrial including steel manufacture storage and service hydrogen could be absorbed into metallic materials and the absorbed hydrogen seriously impaired its corrosion resistance. This paper provides a comprehensive review on the effects of hydrogen on passive film anodic dissolution pitting corrosion and stress corrosion cracking and based on the review the mechanism by which hydrogen promotes corrosion of steel and subsequently leads to cracking has been discussed. It is envisaged that hydrogen harms the stability of the passive film and as a result escalates anode’s activation of steel eventually leading to pitting and stress corrosion cracking.

For our first episode of 2022 we invited Jørn Helge Dahl Global Director of Sales&Marketing at Hexagon Purus to talk about hydrogen storage with the EAH podcast and to explain the types of solutions available today Hexagon's history and plans for the future alongside some commentary on US hydrogen strategy from the gang.

The podcast can be found on their website

The world is undergoing a substantial energy transition with an increasing share of intermittent sources of energy on the grid which is increasing the challenges to operate the power grid reliably. An option that has been receiving much focus after the COVID pandemic is the development of a hydrogen economy. Challenges for a hydrogen economy are the high investment costs involved in compression storage and long-distance transportation. This paper analyses an innovative proposal for the creation of hydrogen ocean links. It intends to fill existing gaps in the creation of a hydrogen economy with the increase in flexibility and viability for hydrogen production consumption compression storage and transportation. The main concept behind the proposals presented in this paper consists of using the fact that the pressure in the deep sea is very high which allows a thin and cheap HDPE tank to store and transport large amounts of pressurized hydrogen in the deep sea. This is performed by replacing seawater with pressurized hydrogen and maintaining the pressure in the pipes similar to the outside pressure. Hydrogen Deep Ocean Link has the potential of increasing the interconnectivity of different regional energy grids into a global sustainable interconnected energy system.

In the second episode of EAH's Season 3 Patrick Andrew and Chris sit down with Maria Fennis CEO of HyET. HyET Hydrogen is a leading SME in the field of electrochemical hydrogen compression founded in 2008. HyET has introduced the first commercially viable Electrochemical Hydrogen Compressor (EHPC) the HCS 100 in 2017. HyET enters partnerships with key stakeholders to develop products with a focus on application. Maria is a leading voice in the compression arena and it is a pleasure to have her on the show!

The podcast can be found on their website

In the debate on the decarbonisation of heat renewable electricity tends to play a much more dominant role than green gases despite the potential advantages of gas in terms of utilising existing transportation networks and end-use appliances. Informed comparisons are hampered by information asymmetry; the renewable electricity has seen a huge grid level deployment whereas low-carbon hydrogen or bio-methane have been limited to some small stand-alone trials. This paper explores the regulatory and commercial challenges of implementing the first UK neighbourhood level 100% low-carbon hydrogen demonstration project. We draw on existing literature and action research to identify the key practical barriers currently hindering the ability of strategically important actors to accelerate the substitution of natural gas with low carbon hydrogen in local gas networks. This paper adds much needed contextual depth to existing generic and theoretical understandings of low-carbon hydrogen for heat transition feasibility. The learnings from pilot projects about the exclusion of hydrogen calorific value from the Local Distribution Zone calorific value calculation Special Purpose Vehicle companies holding of liability and future costs to consumers need to be quickly transferred into resilient operational practice or gas repurposing projects will continue to be less desirable than electrification using existing regulations and with more rapid delivery

On this weeks episode the team discuss the Hydrogen Council the global stakeholder forum that has been at the forefront of efforts to advance the role of hydrogen and fuel cell technologies globally. We are excited to have as our guests Pierre-Etienne Franc Vice President for the Hydrogen Energy World Business Unit at Air Liquide and Stephan Herbst General Manager at Toyota Motor Europe. On the show we discuss why Air Liquide and Toyota decided to engage with the Council its strategy vision and perspective on the role that hydrogen can play in the energy transition and how companies can work with policymakers to enable this process. All this and more on the show!

The podcast can be found on their website

Decentralisation and sector coupling are becoming increasingly crucial for the decarbonisation of the energy system. Resources such as waste and water have high energy recovery potential and are required as inputs for various conversion technologies; however waste and water have not yet been considered in sector coupling approaches but only in separate examinations. In this work an open-source sector coupling optimisation model considering all of these resources and their utilisation is developed and applied in a test-bed in an Israeli city. Our investigations include an impact assessment of energy recovery and resource utilisation in the transition to a hydrogen economy with regard to the inclusion of greywater and consideration of emissions. Additionally sensitivity analyses are performed in order to assess the complexity level of energy recovery. The results demonstrate that waste and water energy recovery can provide high contributions to energy generation. Furthermore greywater use can be vital to cover the water demands in scarcity periods thus saving potable water and enabling the use of technology. Regarding the transition to hydrogen technologies resource energy recovery and management have an even higher effect than in the original setup. However without appropriate resource management a reduction in emissions cannot be achieved. Furthermore the sensitivity analyses indicate the existence of complex relationships between energy recovery technologies and other energy system operations.

A thorough techno-economic analysis where inherent carbon capture is examined against state-of-the-art blue hydrogen production configurations for large (100000 Nm3 /h) and very large (333000 Nm3 /h) capacities. Advanced solvent-based technologies based on post-combustion capture and auto-thermal reformer combined with a gas heated reformer are simulated with process flowsheet software and compared with the emerging chemical looping process. A network of dynamically operated packed bed reactors has been designed and modelled using an in-house code and key parameters generating uncertainties in the results have been examined in a sensitivity analysis. The chemical looping reforming process presents a higher net reforming efficiency than the benchmark cases (8.2 % higher at large scale and 1.5 % higher at very large scale) ranged 75.4–75.7 % while the specific energy for CO2 avoidance is negative in the range of − 0.78 to − 0.85 MJ/kgCO2. In the carbon capture cases the chemical looping reforming in packed beds technology generated a levelised cost of hydrogen of 168.9 £/kNm3 H2 for the large scale and 159.1 £/kNm3 H2 for the very large scale with the values for the benchmark cases being higher at 196.4 and 166.6 £/kNm3 H2 respectively while the levelised cost of hydrogen values are 1 % higher in the benchmark cases where carbon emission price is accounted for. The carbon capture ratio is 99.9 % for the chemical looping reforming cases compared to 90–91 % for the benchmark ones thus providing a significant foreground for the scale-up and implementation of chemical looping reforming technologies for hydrogen production.

Using vehicles powered by alternative fuels such as electricity hydrogen and biofuels have been envisioned as the ideal way to curb noxious vehicular emissions. However the availability of resources for the sustainable use of these alternative fuels the possible risks and their fate at the end of their life are frequently questioned necessitating a detailed assessment of factors influencing the use of all three alternative fuels for vehicular use. Though the vehicles powered by batteries and fuel cells are “locally” zero-emission vehicles (ZEVs) they have resource scarcity infrastructure limitations and are relatively expensive thus restricting their market penetration and consumer acceptance. Biofuels though can be used in the existing vehicles procuring the required amounts of feedstock and mitigating food-versus-fuel issues is still a challenge. Overcoming these challenges is a crucial and critical step for the sustained use of these alternative fuels as primary vehicular fuels. To accomplish this all these challenges need to be categorized and a comparative analysis among them is necessary to address them. This work can therefore serve as a ready reference for researchers and policy makers to take appropriate and informed decisions for long-term action to achieve the goals of the Paris agreement to reduce global temperature.

The North Sea region located in the Northwest of Europe is expected to be a frontrunner in the European energy transition. This paper aims to analyse different optimal system configurations in order to meet net-zero emission targets in 2050. Overall the paper presents two main contributions: first we develop and introduce the IESA-NS model. The IESA-NS model is an optimization integrated energy system model written as a linear problem. The IESA-NS model optimizes the long-term investment planning and short-term operation of seven North Sea region countries (Belgium Denmark Germany the Netherlands Norway Sweden and the United Kingdom). The model can optimize multiple years simultaneously accounts for all the national GHG emissions and includes a thorough representation of all the sectors of the energy system. Second we run several decarbonisation scenarios with net-zero emission targets in 2050. Relevant parameters varied to produce the scenarios include biomass availability VRE potentials low social acceptance of onshore VRE ban of CCUS or mitigation targets in international transport and industry feedstock. Results show a large use of hydrogen when international transport emissions are considered in the targets (5.6 EJ to 7.3 EJ). Electrolysis is the preferred pathway for hydrogen production (up to 6.4 EJ) far ahead of natural gas reforming (up to 2.2 EJ). Allowing offshore interconnectors (e.g. meshed offshore grid between the Netherlands Germany and the United Kingdom) permits to integrate larger amounts of offshore wind (122 GW to 191 GW of additional capacity compared to reference scenarios) while substantially increasing the cross-border interconnection capacities (up to 120 GW). All the biomass available is used in the scenarios across multiple end uses including biofuel production (up to 3.5 EJ) high temperature heat (up to 2.5 EJ) feedstock for industry (up to 2 EJ) residential heat (up to 600 PJ) and power generation (up to 900 PJ). In general most of the results justify the development of multinational energy system models in which the spatial coverage lays between national and continental models.