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Hydrogen as an Energy Vector to Optimize the Energy Exploitation of a Self-consumption Solar Photovoltaic Facility in a Dwelling House
Nov 2019
Publication
Solar photovoltaic (PV) plants coupled with storage for domestic self-consumption purposes seem to be a promising technology in the next years as PV costs have decreased significantly and national regulations in many countries promote their installation in order to relax the energy requirements of power distribution grids. However electrochemical storage systems are still unaffordable for many domestic users and thus the advantages of self-consumption PV systems are reduced. Thus in this work the adoption of hydrogen systems as energy vectors between a PV plant and the energy user is proposed. As a preliminary study in this work the design of a PV and hydrogen-production self-consumption plant for a single dwelling is described. Then a technical and economic feasibility study conducted by modeling the facility within the Homer Energy Pro energy systems analysis tool is reported. The proposed system will be able to provide back not only electrical energy but also thermal energy through a fuel cell or refined water covering the fundamental needs of the householders (electricity heat or cooling and water). Results show that although the proposed system effectively increases the energy local use of the PV production and reduces significantly the energy injections or demands into/from the power grid avoiding power grid congestions and increasing the nano-grid resilience operation and maintenance costs may reduce its economic attractiveness for a single dwelling.
Synergies between Renewable Energy and Flexibility Investments: A Case of a Medium-Sized Industry
Nov 2021
Publication
Climate and energy policies are tools used to steer the development of a sustainable economy supplied by equally sustainable energy systems. End-users should plan their investments accounting for future policies such as incentives for system-oriented consumption emission prices and hydrogen economy to ensure long-term competitiveness. In this work the utilization of variable renewable energy and flexibility potentials in a case study of an an aggregate industry is investigated. An energy concept considering PV and battery expansion flexible production fuel cell electric trucks (FCEV) and hydrogen production is proposed and analysed under expected techno-economic conditions and policies of 2030 using an energy system optimization model. Under this concept total costs and emissions are reduced by 14% and 70% respectively compared to the business-as-usual system. The main benefit of PV investment is the lowered electricity procurement. Flexibility from schedule manufacturing and hydrogen production increases not only the self-consumption of PV generation from 51% to 80% but also the optimal PV capacity by 41%. Despite the expected cost reduction and efficiency improvement FCEV is still not competitive to diesel trucks due to higher investment and fuel prices i.e. its adoption increases the costs by 8%. However this is resolved when hydrogen can be produced from own surplus electricity generation. Our findings reveal synergistic effects between different potentials and the importance of enabling local business models e.g. regional hydrogen production and storage services. The SWOT analysis of the proposed concept shows that the pursuit of sustainability via new technologies entails new opportunities and risks. Lastly end-users and policymakers are advised to plan their investments and supports towards integration of multiple application consumption sectors and infrastructure.
Industrial Decarbonization Pathways: The Example of the German Glass Industry
Nov 2022
Publication
Mitigating anthropogenic climate change and achieving the Paris climate goals is one of the greatest challenges of the twenty-first century. To meet the Paris climate goals sector-specific transformation pathways need to be defined. The different transformation pathways are used to hypothetically quantify whether a defined climate target is achievable or not. For this reason a bottom-up model was developed to assess the extent of selected industrial decarbonization options compared to conventionally used technologies from an emissions perspective. Thereby the bottom-up model is used to analyze the German container and flat glass industries as an example. The results show that no transformation pathway can be compatible with the 1.5 °C based strict carbon dioxide budget target. Even the best case scenario exceeds the 1.5 °C based target by approximately +200%. The 2 °C based loose carbon dioxide budget target is only achievable via fuel switching the complete phase-out from natural gas to renewable energy carriers. Furthermore the results of hydrogen for flat glass production demonstrate that missing investments in renewable energy carriers may lead to the non-compliance with actually achievable 2 °C based carbon dioxide budget targets. In conclusion the phase-out from natural gas to renewable energies should be executed at the end of the life of any existing furnace and process emissions should be avoided in the long term to contribute to 1.5 °C based strict carbon dioxide budget target.
Current Research Progress in Magnesium Borohydride for Hydrogen Storage (A review)
Nov 2021
Publication
Hydrogen storage in solid-state materials is believed to be a most promising hydrogen-storage technology for high efficiency low risk and low cost. Mg(BH4)2 is regarded as one of most potential materials in hydrogen storage areas in view of its high hydrogen capacities (14.9 wt% and 145–147 kg cm3 ). However the drawbacks of Mg(BH4)2 including high desorption temperatures (about 250 C–580 C) sluggish kinetics and poor reversibility make it difficult to be used for onboard hydrogen storage of fuel cell vehicles. A lot of researches on improving the dehydrogenation reaction thermodynamics and kinetics have been done mainly including: additives or catalysts doping nanoconfining Mg(BH4)2 in nanoporous hosts forming reactive hydrides systems multi-cation/anion composites or other derivatives of Mg(BH4)2. Some favorable results have been obtained. This review provides an overview of current research progress in magnesium borohydride including: synthesis methods crystal structures decomposition behaviors as well as emphasized performance improvements for hydrogen storage.
An Innovative and Comprehensive Approach for the Consequence Analysis of Liquid Hydrogen Vessel Explosions
Oct 2020
Publication
Hydrogen is one of the most suitable solutions to replace hydrocarbons in the future. Hydrogen consumption is expected to grow in the next years. Hydrogen liquefaction is one of the processes that allows for increase of hydrogen density and it is suggested when a large amount of substance must be stored or transported. Despite being a clean fuel its chemical and physical properties often arise concerns about the safety of the hydrogen technologies. A potentially critical scenario for the liquid hydrogen (LH2) tanks is the catastrophic rupture causing a consequent boiling liquid expanding vapour explosion (BLEVE) with consequent overpressure fragments projection and eventually a fireball. In this work all the BLEVE consequence typologies are evaluated through theoretical and analytical models. These models are validated with the experimental results provided by the BMW care manufacturer safety tests conducted during the 1990’s. After the validation the most suitable methods are selected to perform a blind prediction study of the forthcoming LH2 BLEVE experiments of the Safe Hydrogen fuel handling and Use for Efficient Implementation (SH2IFT) project. The models drawbacks together with the uncertainties and the knowledge gap in LH2 physical explosions are highlighted. Finally future works on the modelling activity of the LH2 BLEVE are suggested.
Recent Application of Nanomaterials to Overcome Technological Challenges of Microbial Electrolysis Cells
Apr 2022
Publication
Microbial electrolysis cells (MECs) have attracted significant interest as sustainable green hydrogen production devices because they utilize the environmentally friendly biocatalytic oxidation of organic wastes and electrochemical proton reduction with the support of relatively lower external power compared to that used by water electrolysis. However the commercialization of MEC technology has stagnated owing to several critical technological challenges. Recently many attempts have been made to utilize nanomaterials in MECs owing to the unique physicochemical properties of nanomaterials originating from their extremely small size (at least <100 nm in one dimension). The extraordinary properties of nanomaterials have provided great clues to overcome the technological hurdles in MECs. Nanomaterials are believed to play a crucial role in the commercialization of MECs. Thus understanding the technological challenges of MECs the characteristics of nanomaterials and the employment of nanomaterials in MECs could be helpful in realizing commercial MEC technologies. Herein the critical challenges that need to be addressed for MECs are highlighted and then previous studies that used nanomaterials to overcome the technological difficulties of MECs are reviewed.
Geological Hydrogen Storage: Geochemical Reactivity of Hydrogen with Sandstone Reservoirs
Jun 2022
Publication
The geological storage of hydrogen is necessary to enable the successful transition to a hydrogen economy and achieve net-zero emissions targets. Comprehensive investigations must be undertaken for each storage site to ensure their long-term suitability and functionality. As such the systematic infrastructure and potential risks of large-scale hydrogen storage must be established. Herein we conducted over 250 batch reaction experiments with different types of reservoir sandstones under conditions representative of the subsurface reflecting expected time scales for geological hydrogen storage to investigate potential reactions involving hydrogen. Each hydrogen experiment was paired with a hydrogen-free control under otherwise identical conditions to ensure that any observed reactions were due to the presence of hydrogen. The results conclusively reveal that there is no risk of hydrogen loss or reservoir integrity degradation due to abiotic geochemical reactions in sandstone reservoirs.
Everything About Hydrogen Podcast: Building Hydrogen Infrastructure with Black & Veatch
Feb 2020
Publication
On this weeks episode the team are talking all things hydrogen with Maryline Daviaud Lewett Director of Business Development for Transformative Technologies at Black & Veatch (B&V). On the show we discuss the role that Engineering Procurement and Construction (EPC) firms are playing in developing hydrogen and fuel cell infrastructure as well as discussing the unique aspects of developing projects in North America. As the leading EPC for hydrogen refuelling stations in North America and a wealth of experience across electric vehicle charging and hydrogen Maryline brings a uniquely well rounded perspective to the discussion and shares a wealth of insights for how the market may evolve. All this and more on the show!
The podcast can be found on their website
The podcast can be found on their website
Carbon Capture from Biogas by Deep Eutectic Solvents A COSMO Study to Evaluate the Effect of Impurities on Solubility and Selectivity
Jun 2021
Publication
Deep eutectic solvents (DES) are compounds of a hydrogen bond donor (HBD) and a hydrogen bond acceptor (HBA) that contain a depressed melting point compared to their individual constituents. DES have been studied for their use as carbon capture media and biogas upgrading. However contaminants’ presence in biogas might affect the carbon capture by DES. In this study conductor-like screening model for real solvents (COSMO-RS) was used to determine the effect of temperature pressure and selective contaminants on five DES’ namely choline chloride-urea choline chloride-ethylene glycol tetra butyl ammonium chloride-ethylene glycol tetra butyl ammonium bromide-decanoic acid and tetra octyl ammonium chloride-decanoic acid. Impurities studied in this paper are hydrogen sulfide ammonia water nitrogen octamethyltrisiloxane and decamethylcyclopentasiloxane. At infinite dilution CO2 solubility dependence upon temperature in each DES was examined by means of Henry’s Law constants. Next the systems were modeled from infinite dilution to equilibrium using the modified Raoults’ Law where CO2 solubility dependence upon pressure was examined. Finally solubility of CO2 and CH4 in the various DES were explored with the presence of varying mole percent of selective contaminants. Among the parameters studied it was found that the HBD of the solvent is the most determinant factor for the effectiveness of CO2 solubility. Other factors affecting the solubility are alkyl chain length of the HBA the associated halogen and the resulting polarity of the DES. It was also found that choline chloride-urea is the most selective to CO2 but has the lowest CO2 solubility and is the most polar among other solvents. On the other hand tetraoctylammonium chloride-decanoic acid is the least selective has the highest maximum CO2 solubility is the least polar and is the least affected by its environment.
Development of a Tangential Neutron Radiography System for Monitoring the Fatigue Cracks in Hydrogen Fuel Tanks
Jun 2016
Publication
Purpose- To present an overview of the research and development carried out in a European funded framework 7 (FP7) project called SafeHPower for the implementation of neutron radiography to inspect fatigue cracks in vehicle and storage hydrogen fuel tanks. Project background– Hydrogen (H2) is the most promising replacement fuel for road transport due to its abundance efficiency low carbon footprint and the absence of harmful emissions. For the mass market of hydrogen to take off the safety issue surrounding the vehicle and storage hydrogen tanks needs to be addressed. The problem is the residual and additional stresses experienced by the tanks during the continuous cyclic loading between ambient and storage pressure which can result in the development of fatigue cracks. Steel tanks used as storage containers at service stations and depots and/or the composite tanks lined with steel are known to suffer from hydrogen embrittlement (HE). Another issue is the explosive nature of hydrogen (when it is present in the 18-59% range) where it is mixed with oxygen which can lead to catastrophic consequences including loss of life. Monitoring systems that currently exist in the market impose visual examination tests pressure tests and hydrostatic tests after the tank installation [1] [2]. Three inspection systems have been developed under this project to provide continuous monitoring solutions. Approach and scope- One of the inspection systems based on the neutron radiography (NR) technology that was developed in different phases with the application of varied strategies has been presented here. Monte Carlo (MCNP) simulation results to design and develop a bespoke collimator have been presented. A limitation of using an inertial electrostatic Deuterium-Tritium (D-T) pulsed neutron generator for fast neutron radiography has been discussed. Radiographs from the hydrogen tank samples obtained using thermal neutrons from a spallation neutron source at ISIS Rutherford laboratory UK have been presented. Furthermore radiograph obtained using thermal neutrons from a portable D-T neutron generator has been presented. In conclusion a proof in principle has been made to show that the defects in the hydrogen fuel tank can be detected using thermal neutron radiography.
A Hot Syngas Purification System Integrated with Downdraft Gasification of Municipal Solid Waste
Jan 2019
Publication
Gasification of municipal solid waste (MSW) with subsequent utilization of syngas in gas engines/turbines and solid oxide fuel cells can substantially increase the power generation of waste-to-energy facilities and optimize the utilization of wastes as a sustainable energy resources. However purification of syngas to remove multiple impurities such as particulates tar HCl alkali chlorides and sulfur species is required. This study investigates the feasibility of high temperature purification of syngas from MSW gasification with the focus on catalytic tar reforming and desulfurization. Syngas produced from a downdraft fixed-bed gasifier is purified by a multi-stage system. The system comprises of a fluidized-bed catalytic tar reformer a filter for particulates and a fixed-bed reactor for dechlorination and then desulfurization with overall downward cascading of the operating temperatures throughout the system. Novel nano-structured nickel catalyst supported on alumina and regenerable Ni-Zn desulfurization sorbent loaded on honeycomb are synthesized. Complementary sampling and analysis methods are applied to quantify the impurities and determine their distribution at different stages. Experimental and thermodynamic modeling results are compared to determine the kinetic constraints in the integrated system. The hot purification system demonstrates up to 90% of tar and sulfur removal efficiency increased total syngas yield (14%) and improved cold gas efficiency (12%). The treated syngas is potentially applicable in gas engines/turbines and solid oxide fuel cells based on the dew points and concentration limits of the remaining tar compounds. Reforming of raw syngas by nickel catalyst for over 20 h on stream shows strong resistance to deactivation. Desulfurization of syngas from MSW gasification containing significantly higher proportion of carbonyl sulfide than hydrogen sulfide traces of tar and hydrogen chloride demonstrates high performance of Ni-Zn sorbents.
Wind Resource Assessment and Techno-economic Analysis of Wind Energy and Green Hydrogen Production in the Republic of Djibouti
Jul 2022
Publication
The ever increasing energy demand of the Republic of Djibouti leads to the diversification of energy sources. While a few studies have explored the prospects of green hydrogen production from wind energy in developing countries and particularly in Africa the economic risk analysis of wind power production for electricity generation and green hydrogen production has not been assessed for African countries. This study evaluates for the first time the potential of wind energy for electricity and green hydrogen production in the Republic of Djibouti. In this study wind speed characteristics were analyzed using wind data measured at five meteorological stations from 2015 to 2019. The technoeconomic analysis of five wind farms with a total capacity of 450 MW is performed. Levelized cost of energy production (LCOE) levelized cost of green hydrogen production (LCOH) sensitivity analysis Monte Carlo simulation and economic performance indicators are presented. Results reveal that the annual wind speed varies between 5.52 m/s and 9.01 m/s for the five sites. ERA5 wind reanalysis indicates that the seasonal variability of wind is stable between different years. The proposed wind farms estimate 1739 GWh per year of electrical energy with LCOE ranging from 6.94 to 13.30 US cents/kWh which is less than the locale electricity tariff. The production cost of green hydrogen was competitive with LCOH ranging from 1.79 to 3.38 US $/kg H2. The sensitivity analysis shows that the most relevant parameters in the economic analysis are the initial investment cost the interest rate and the factor capacity.
Neutron Scattering and Hydrogen Storage
Nov 2009
Publication
Hydrogen has been identified as a fuel of choice for providing clean energy for transport and other applications across the world and the development of materials to store hydrogen efficiently and safely is crucial to this endeavour. Hydrogen has the largest scattering interaction with neutrons of all the elements in the periodic table making neutron scattering ideal for studying hydrogen storage materials. Simultaneous characterisation of the structure and dynamics of these materials during hydrogen uptake is straightforward using neutron scattering techniques. These studies will help us to understand the fundamental properties of hydrogen storage in realistic conditions and hence design new hydrogen storage materials.
Co-gasification of Refuse-derived Fuels and Bituminous Coal with Oxygen/steam Blend to Hydrogen Rich Gas
May 2022
Publication
The gasification technology of refuse-derived fuels (RDF) can represent a future alternative to the global hydrogen production and a pathway for the development of the circular economy. The paper presents an innovative way of utilizing RDF through their oxygen/steam co-gasification with bituminous coal to hydrogen rich gas. Five different RDF samples (RDF1÷RDF5) were investigated. The in-depth analyses of the co-gasification of bituminous coal blends with different amounts of RDF (10 15 and 20%w/w) under various temperature conditions were conducted with the application of Hierarchical Clustering Analysis (HCA). The results of the research study revealed a decrease in the total gas yield as well as in the hydrogen yield observed with the increase in the RDF fraction in the fuel blend. The lowest hydrogen yield and the highest carbon conversion were noted for the co-gasification tests of coal blends with 20%w/w for all the studied RDFs. The SEM-EDS (Scanning Electron Microscopy with Energy Dispersive Spectroscopy) and WDXRF (Wavelength Dispersive X-ray Fluorescence) results showed a significantly higher H2 yield in RDF2 co-gasification with coal in comparison with all the remaining RDFs due to the higher concentration of calcium in the sample. The molecular structure analysis of polymers using Fourier transform infrared spectroscopy (FTIR) demonstrated that the most prevalent synthetic polymers in RDF2 are polyethylene terephthalate and polyvinyl chloride characterized by the lowest thermal stability compared to polyethylene and polypropylene.
Fuel Cells and Hydrogen Observatory 2019 EU and National Policies Report
Sep 2021
Publication
The policy module of the FCHO presents an overview of EU and national policies across various hydrogen and fuel cell related sectors. It provides a snapshot of the current state of hydrogen legislation and policy. Scope: While FCHO covers 38 entities around the world due to the completeness of the data at the moment of writing this report covers 29 entities. The report reflects data collected January 2019 – December 2019. Key Findings: Hydrogen policies are relatively commonplace among European countries but with large differences between member states. EU hydrogen leaders do not lag behind global outliers such as South Korea or Japan.
Vision for a European Metrology Network for Energy Gases
Mar 2022
Publication
As Europe moves towards decarbonising its energy infrastructure new measurement needs will arise that require collaborative efforts between European National Metrology Institutes and Designated Institutes to tackle. Such measurement needs include flow metering of hydrogen or hydrogen enriched natural gas in the gas grid for billing quality assurance of hydrogen at refuelling stations and equations of state for carbon dioxide in carbon capture and storage facilities. The European metrology network for energy gases for the first time provides a platform where metrology institutes can work together to develop a harmonised strategy prioritise new challenges and share expertise and capabilities to support the European energy gas industry to meet stringent EU targets for climate change and emissions reductions
THyGA - Intermediate Report on the Test of Technologies by Segment – Impact of the Different H2 Concentrations on Safety, Efficiency, Emissions and Correct Operation
Jan 2022
Publication
This report is the very first version of the document that will present the THyGA short-term test. These tests are carried out to observe how appliances react in the short term (few minutes to few hours) on different H2NG mixtures and long-term test are observing behaviour over several weeks. The analysis is based on the test of about 20 appliances only and is not yet covering extensively all the segments of the project. However most of the aspects of the testing are included in the present version that shall be considered as a draft working document to prepare the final report. We have tried to incorporate all aspects that are important to us but there may be more aspects and more analyses that could be added and will be added in the light of the comments and corrections we will gather after the dissemination of the document.
Towards Electrochemical Hydrogen Storage in Liquid Organic Hydrogen Carriers via Proton-coupled Electron Transfers
Jun 2022
Publication
Green hydrogen is identified as one of the prime clean energy carriers due to its high energy density and a zero emission of CO2. A possible solution for the transport of H2 in a safe and low-cost way is in the form of liquid organic hydrogen carriers (LOHCs). As an alternative to loading LOHC with H2 via a two-step procedure involving preliminary electrolytic production of H2 and subsequent chemical hydrogenation of the LOHC we explore here the possibility of electrochemical hydrogen storage (EHS) via conversion of proton of a proton donor into a hydrogen atom involved in covalent bonds with the LOHC (R) via a proton-coupled electron transfer (PCET) reaction: . 2 + +2 ― + ox↔ 0 2red We chose 9-fluorenone/fluorenol (Fnone/Fnol) conversion as such a model PCET reaction. The electrochemical activation of Fnone via two sequential electron transfers was monitored with in-situ and operando spectroscopies in absence and in presence of different alcohols as proton donors of different reactivity which enabled us to both quantify and get the mechanistic insight on PCET. The possibility of hydrogen extraction from the loaded carrier molecule was illustrated by chemical activation.
Review of the Liquid Hydrogen Storage Tank and Insulation System for the High-Power Locomotive
Jun 2022
Publication
Hydrogen has been attracting attention as a fuel in the transportation sector to achieve carbon neutrality. Hydrogen storage in liquid form is preferred in locomotives ships drones and aircraft because these require high power but have limited space. However liquid hydrogen must be in a cryogenic state wherein thermal insulation is a core problem. Inner materials including glass bubbles multi-layer insulation (MLI) high vacuum and vapor-cooled shields are used for thermal insulation. An analytic study is preferred and proceeds liquid hydrogen tanks due to safety regulations in each country. This study reviewed the relevant literature for thermodynamic modeling. The literature was divided into static dynamic and systematic studies. In summary the authors summarized the following future research needs: The optimal design of the structure including suspension baffle and insulation system can be studied to minimize the boil-off gas (BOG). A dynamic study of the pressure mass flow and vaporizer can be completed. The change of the components arrangement from the conventional diesel–electric locomotive is necessary.
State-of-the-art Expansion Planning of Integrated Power, Natural Gas, and Hydrogen Systems
Apr 2022
Publication
Renewable hydrogen is considered key in the transition towards a carbon-neutral future. This is due to its spatio-temporal storage and sector coupling potential which has seen it referred to as energy vector. However many unresolved issues remain regarding hydrogen's large-scale deployment e.g. least-cost production optimal facility siting and overall implications on power and energy systems. Expansion planning provides an option to study these issues in the holistic context of energy systems. To this end this article presents a comprehensive review on state-of-the-art expansion planning models that consider integrated power natural gas and hydrogen systems. We cluster the existing literature in terms of modelling themes and scope study the applied systematic modelling characteristics and conduct an in-depth analysis of the technical model features regarding hydrogen technologies and natural gas infrastructure. Finally we identify and discuss research gaps in the existing literature.
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