Publications

China’s dual-carbon goals have positioned hydrogen as a central pillar of its energy transition. This review examines the recent development of China’s hydrogen supply chain with particular focus on manufacturing technologies for alkaline electrolysers high-pressure cylinders and diaphragm compressors. In 2024 China produced 36.5 million tons of hydrogen of which 77 % was grey and only 1 % derived from electrolysis. Storage and transportation account for nearly 30 % of end-use costs while reliance on imported compressors increases refuelling station expenses by approximately 40 %. We identify key bottlenecks including limited electrolyser efficiency the high cost of carbon fibres for Type III/IV cylinders and insufficient domestic capacity for highreliability compressors. To address these challenges targeted advances are proposed: membrane materials with engineered hydrophilicity advanced surface modifications and hydrophilic inhibitors; liner design incorporating grooved-liner braided layers with double-fibre configurations; and a three-layer diaphragm compressor architecture. By consolidating fragmented studies this review provides the integrated manufacturing perspective on China’s hydrogen supply chain offering both scientific insights and practical guidance for accelerating costeffective large-scale low-carbon hydrogen deployment.

Offshore hydrogen production offers a promising solution for harnessing wind energy far from shore by using hydrogen as an energy carrier instead of electrical cables. Flexibility in hydrogen production systems is crucial to maximising the conversion of intermittent wind energy into hydrogen. To improve the performance of lowpressure compressed gas buffer stores hybrid gas-hydride tanks have been identified as a viable solution increasing useable storage density from 1.2 kg m− 3 to 6.3 kg m− 3 with just a 5 vol% addition of hydride. This study evaluates the reduction in tank volume reduction in cost and enhancements in useable storage density achieved by integrating different hydrides under varying temperature conditions. Using hydrogen mass flow rate profiles a storage mass target was determined for optimisation. The results demonstrate that hybrid gas-hydride tanks can reduce tank size by around 80 % lowering costs by 24 % and achieve a 5.1-fold improvement in useable storage density.

With the transition to a fully renewable energy grid arises the need for a green source of stability and baseload support which classical renewable generation such as wind and solar cannot offer due to their uncertain and highly-variable generation. In this paper we study whether green hydrogen can close this gap as a source of supplemental generation and storage. We design a two-stage mixed-integer stochastic optimization model that accounts for uncertainties in renewable generation. Our model considers the investment in renewable plants and hydrogen storage as well as the operational decisions for running the hydrogen storage systems. For the data considered we observe that a fully renewable network driven by green hydrogen has a greater potential to succeed when wind generation is high. In fact the main investment priorities revealed by the model are in wind generation and in liquid hydrogen storage. This long-term storage is more valuable for taking full advantage of hydrogen than shorter-term intraday hydrogen gas storage. In addition we note that the main driver for the potential and profitability of green hydrogen lies in the electricity demand and prices as opposed to those for gas. Our model and the investment solutions proposed are robust with respect to changes in the investment costs. All in all our results show that there is potential for green hydrogen as a source of baseload support in the transition to a fully renewable-powered energy grid.

Green hydrogen offers a promising yet underexplored pathway for agricultural decarbonisation requiring technological readiness and coordinated action from policymakers industry and farmers. This paper integrates techno-economic modelling with stakeholder engagement (semi-structured interviews and an expert workshop) to assess its potential. Analyses were conducted for farms of 123 hectares and clusters of 10 farms complemented by seven interviews and a workshop with nine sector experts. Findings show both opportunities and barriers. While on-farm hydrogen production is technically feasible it remains economically uncompetitive due to high levelised costs shaped by seasonal demand variability and low utilisation of electrolysers and storage. Pooling demand across multiple users is essential to improve cost-effectiveness. Stakeholders identified three potential business models: fertiliser production via ammonia synthesis cooperative-based models and local refuelling stations. Of these cooperative hydrogen hubs emerged as the most promising enabling clusters of farms to jointly invest in renewable-powered electrolysers storage and refuelling facilities thereby reducing costs extending participation to smaller farms and mitigating risks through collective investment. By linking techno-economic feasibility with stakeholder perspectives and business model considerations the results contribute to socio-technical transition theory by showing how technological institutional and social factors interact in shaping hydrogen adoption in agriculture. With appropriate policy support cooperative hubs could lower costs ease concerns over affordability and complexity and position hydrogen as a practical driver of agricultural decarbonisation and rural resilience. Keywords: green

The search for alternatives to fossil fuels has led to hydrogen becoming an important factor in the powering means of transportation. Its most effective application is in fuel cells. A single fuel cell is not a sufficient source of power which is why a stack of fuel cells is the more common solution. Fuel cells are tested using single units as this allows all cell parameters (the current density flow rates and efficiency) to be evaluated. Therefore the scalability of fuel cells is an essential factor. This paper analyses the scalability of fuel cells with a power of approximately 100 kW and 1.2 kW. Road tests of the fuel cells were compared with stationary tests which allowed the load to be reproduced and scaled. This provided a representation of the scaled current and the scalable power of the fuel cell. The research provided voltage–current characteristics of fuel cell stacks and their individual equivalents. It was concluded that regardless of the power scaling or current values the characteristics obtain similar patterns. A very important element of the research is the awareness of the properties of these cells (the number of cells and active charge exchange area) in order to compare the unit characteristics of fuel cells.

This study employs computational thermodynamics to evaluate the feasibility of replacing methane with hydrogen as both burner fuel and reductant during blister copper deoxidation aiming to enhance deoxidation efficiency and reduce CO2 emissions. A comprehensive thermodynamic model was developed using FactSage 8.3 for dilute Cu–O and Cu–S–O melts containing trace impurities (Fe Ni Pb Zn) incorporating methane thermal decomposition and temperature-dependent variations in liquid copper density with oxygen and sulfur content. Model parameters were optimized against over 105 deoxidation simulation data points yielding temperature- and composition-dependent expressions for rapid density estimates. Benchmarking against existing literature models demonstrated improved accuracy. Key findings include: (1) increasing impurities contents from electronics waste recycling (Fe Ni Pb Zn) reduces oxygen activity deteriorating the deoxidation efficiency; (2) under global equilibrium methane provides greater reducing power per mole than hydrogen due to full thermal cracking but real-world mass transfer limitations render hydrogen more consistently effective up to 1200 C with methane gas needing to achieve at least 472 C to match hydrogen’s performance; (3) adiabatic flame equilibrium studies show that O2/H2 ratios of 0.5 to 1 yield liquid copper oxygen activities comparable to industrial O2/CH4 ratios of 2 to 3 supporting the direct substitution of methane with hydrogen in oxy-fuel anode furnace burners without compromising metal quality.

To reduce the amount of harmful gases produced by fossil fuels more environmentally friendly and sustainable alternatives are being proposed around the world. As a result technologies for manufacturing hydrogen fuel cells and producing green hydrogen are becoming more widespread with an impact on energy production and environmental protection. In many countries around the world and in Africa in particular leaders scientists and populations are considering switching from fossil fuels to so-called green energies. Hydrogen is therefore an interesting alternative that deserves to be explored especially since both rural and urban populations have shown an interest in using it in the near future which would reduce pollution and the proliferation of greenhouse gases thereby mitigating global warming. The aim of this paper is to determine the hybrid energy system best suited to addressing the energy problem in the study area and then to make successive substitutions of different energy sources starting with the most polluting in order to assess the possibilities for transitioning the energy used in the area to green hydrogen. To this end this study began with a technical and economic analysis which based on climatic parameters led to the proposal of a PV/DG-BATTery system configuration with a Net Present Cost (NPC) of USD 19267 and an average Cost Of Energy (COE) of USD 0.4 and with a high proportion of CO2 emissions compared with the PV/H2GEN-BATT and H2GEN systems. The results of replacing fossil fuel generators with hydrogen generators are beneficial in terms of environmental protection and lead to a reduction in energy-related expenses of around 2.1 times the cost of diesel and a reduction in mass of around 2.7 times the mass of diesel. The integration of H2GEN at high duty percentages increases the Cost Of Energy whether in a hybrid PV/H2GEN system or an H2GEN system. This shows the interest in the study country in using favorable duty proportions to make the use of hydrogen profitable.

For the transition to emission-free or low-emission energy hydrogen is a promising energy carrier and fuel of the future with the possibility of long-term storage. Due to its specific properties it poses certain safety risks; therefore it is necessary to have a comprehensive understanding of hydrogen. This review article contains ten main chapters and provides by synthesizing current findings primarily from standards and scientific studies (predominantly from 2023 to 2024) the theoretical basis for further research directed toward safe hydrogen infrastructure.

From an environmental standpoint carbon-free energy carriers such as ammonia and hydrogen are essential for future energy systems. However their hightemperature chemical behavior remains insufficiently understood posing challenges for the development and optimization of advanced combustion technologies. Ammonia in particular is globally available and cost-effective especially for energy-intensive industries. The addition of ammonia or hydrogen to methane significantly reduces the accuracy of existing predictive models. Therefore validated and detailed data are urgently needed to enable reliable design and performance predictions. This review highlights the compatibility of ammonia with existing combustion infrastructure facilitating a smoother transition to more sustainable heating methods without the need for entirely new systems. Applications in high-temperature heating processes such as metal processing ceramics and glass production and power generation are of particular interest. This review focuses on the systematic assessment of alternative fuel mixtures comprising ammonia and hydrogen as well as natural gas with particular consideration of existing safety-related parameters and combustion characteristics. Fundamental quantities such as the laminar burning velocity are discussed in the context of their relevance for fuel mixtures and their scalability toward turbulent flame propagation which is of critical importance for industrial burner and reactor design. The influence of fuel composition on ignition limits is examined as these are essential parameters for safety margin definitions and operational boundary conditions. Furthermore flame stability in mixed-fuel systems is addressed to evaluate the practical feasibility and robustness of combustion under varying process conditions. A detailed overview of current diagnostic and analysis methods follows encompassing both pollutant measurement techniques and the detection of key radical species. These diagnostics form the experimental basis for reaction kinetics modeling and mechanism validation. Given the importance of emission formation in combustion systems a dedicated subsection summarizes major emission trends even though a comprehensive treatment would exceed the scope of this review. Thermal radiation effects which are highly relevant for heat transfer and system efficiency in large-scale applications are then reviewed. In parallel current developments in numerical simulation approaches for industrial-scale combustion systems are presented including aspects of model accuracy boundary conditions and computational efficiency. The review also incorporates insights from materials engineering particularly regarding high-temperature material performance corrosion resistance and compatibility with combustion products. Based on these interdisciplinary findings operational strategies for high-temperature furnaces are outlined and selected industrial reference systems are briefly presented. This integrated approach aims to support the design optimization and safe operation of next-generation combustion technologies utilizing carbon-free or low-carbon fuels.

As a pivotal clean energy carrier for achieving carbon neutrality green hydrogen technology has attracted growing global attention. This review systematically examines four mainstream water electrolysis technologies—alkaline electrolysis proton exchange membrane electrolysis solid oxide electrolysis and anion exchange membrane electrolysis—analyzing their fundamental principles material challenges and development trends. It further classifies and compares power electronic converter topologies including non-isolated and isolated DC–DC converters as well as AC–DC converter architectures and summarizes advanced control strategies such as dynamic power regulation and fault-tolerant operation aimed at enhancing system efficiency and stability. A holistic “electrolyzer–power converter–control strategy” integration framework is proposed to provide tailored technological solutions for diverse application scenarios. Finally the challenges and future prospects of green hydrogen across the energy transportation and industrial sectors are discussed underscoring its potential to accelerate the global transition toward a sustainable low-carbon energy system.