Publications
Hydrogen Storage Potential in Underground Coal Gasification Cavities: A MD Simulation of Hydrogen Adsorption and Desorption Behavior in Coal Nanopores
May 2025
Publication
Underground hydrogen storage (UHS) in geological formations presents a viable option for long-term large-scale H2 storage. A physical coal model was constructed based on experimental tests and a MD simulation was used to investigate the potential of UHS in underground coal gasification (UCG) cavities. We investigated H2 behavior under various conditions including temperatures ranging from 278.15 to 348.15 K pressures in the range of 5–20 MPa pore sizes ranging from 1 to 20 nm and varying water content. We also examined the competitive adsorption dynamics of H2 in the presence of CH4 and CO2 . The findings indicate that the optimal UHS conditions for pure H2 involve low temperatures and high pressures. We found that coal nanopores larger than 7.5 nm optimize H2 diffusion. Additionally higher water content creates barriers to hydrogen diffusion due to water molecule clusters on coal surfaces. The preferential adsorption of CO2 and CH4 over H2 reduces H2 -coal interactions. This work provides a significant understanding of the microscopic behaviors of hydrogen in coal nanopores at UCG cavity boundaries under various environmental factors. It also confirms the feasibility of underground hydrogen storage (UHS) in UCG cavities.
Effect of Hydrogen Co-Firing with Natural Gas on Thermal Efficiency and CO2 Emissions in Gas Turbine Power Plant
Mar 2025
Publication
The Indonesian government has established an energy transition policy for decarbonization including the target of utilizing hydrogen for power generation through a co-firing scheme. Several studies indicate that hydrogen co-firing in gas-fired power plants can reduce CO2 emissions while improving efficiency. This study develops a simulation model for hydrogen co-firing in an M701F gas turbine at the Cilegon power plant using Aspen HYSYS. The impact of different hydrogen volume fractions (5–30%) on thermal efficiency and CO2 emissions is analyzed under varying operational loads (100% 75% and 50%). The simulation results show an increase in thermal efficiency with each 5% increment in the hydrogen fraction averaging 0.32% at 100% load 0.34% at 75% load and 0.37% at 50% load. The hourly CO2 emission rate decreased by an average of 2.16% across all operational load variations for every 5% increase in the hydrogen fraction. Meanwhile the average reduction in CO2 emission intensity at the 100% 75% and 50% operational loads was 0.017 0.019 and 0.023 kg CO2/kWh respectively.
Exploring Natural Hydrogen Potential in Alberta's Western Canadian Sedimentary Basin
Oct 2025
Publication
Natural hydrogen or "white hydrogen" has recently garnered attention as a viable and cost-effective energy resource due to its low-carbon footprint and high energy density positioning it as a key contributor to the transition towards a sustainable low-carbon energy system. This study represents Alberta’s first systematic effort to evaluate natural hydrogen potential in the province using publicly available geological geospatial and gas composition datasets. By mapping hydrogen occurrences against key geological features in the Western Canadian Sedimentary Basin (WCSB) we identify regions with strong geological potential for natural hydrogen generation migration and accumulation while addressing data uncertainties. Within the WCSB formations like the Montney Cardium Bearpaw Manville Belly River McMurray and Lea Park are identified as zones likely for hydrogen generation by prominent mechanisms including hydrocarbon decomposition water-rock reactions with iron-rich sediments and organic pyrolysis. Formation proximity to the underlying Canadian Shield may also suggest potential for basement-derived hydrogen migration via deep-seated faults and shear zones. Salt deposits (Elk Point Group - Prairie evaporites Cold Lake and Lotsberg) and deep shales (e.g. Kaskapau Lea Park Wapiabi) provide effective cap rock potential while reservoirs like porous sandstone (e.g. Dunvegan Spirit River Cardium) and fractured carbonate (e.g. Keg River) formations offer favorable accumulation conditions. Hydrogen occurrences in relation to geological features identify Southern Eastern and West-Central plains as prominent natural Hydrogen generation and accumulation areas. Alberta’s established energy infrastructure as well as subsurface expertise positions it as a potential leader in natural hydrogen exploration. As Alberta’s first systematic investigation this study provides a preliminary assessment of natural hydrogen potential and outlines recommended next steps to guide future exploration and research. Targeted research on specific generation and accumulation mechanisms and source identification through isotopic and geochemical fingerprinting will be crucial for exploration de-risking and viability assessment in support of net-zero emission initiatives.
Enhancing Durability of Raney-Ni-based Electrodes for Hydrogen Evolution Reaction in Alkaline Water Electrolysis: Mitigating Reverse Current and H2 Bubble Effects using a NiP Protective Layer
Oct 2025
Publication
Raney Ni (R-Ni) electrodes are used as hydrogen evolution reaction catalysts in alkaline water electrolysis (AWE). However they are not durable because of reverse current-induced oxidation and catalyst damage from H2 bubbles. Reverse current triggers Ni phase changes and mechanical stress leading to catalyst delamination while bubbles block active sites increase resistance and cause structural damage. These issues have been addressed individually but not simultaneously. In this study a P-doped Ni (NiP) protective layer is electroplated on the R-Ni electrode to overcome both challenges. The NiP protective layer inhibits oxidation reducing Ni phase changes and preventing catalyst delamination. Enhanced surface wettability minimizes nucleation and facilitates faster bubble detachment reducing bubble-related damage. Electrochemical tests reveal that NiP/R-Ni exhibits a 26 mV lower overpotential than that of R-Ni at −400 mA cm−2 indicating higher catalytic activity. Accelerated degradation tests (ADTs) demonstrate the retention of the NiP/R-Ni catalyst layer with only a 25 mV increase in overpotential after ADT which is significantly less than that of R-Ni. Real-time impedance analysis reveals the presence of small rapidly detaching bubbles on NiP/R-Ni. Overall the NiP protective layer on R-Ni simultaneously mitigates both reverse current and H2 bubble-induced degradation improving catalytic activity and durability during AWE.
A Configuration and Scheduling Optimization Method for Integrated Energy Systems Considering Massive Flexible Load Resources
Mar 2025
Publication
Introduction: With the increasing demand for energy utilization efficiency and minimization of environmental carbon emissions in industrial parks optimizing the configuration and scheduling of integrated energy systems has become crucial. This study focuses on integrated energy systems with massive flexible load resources aiming to maximize energy utilization efficiency while reducing environmental impact. Methods: To model the uncertainties in wind and solar power outputs we employed three-parameter Weibull distribution models and Beta distribution models. Flexible loads were categorized into three types to match different electricity consumption patterns. Additionally an enhanced Kepler Optimization Algorithm (EKOA) was proposed incorporating chaos mapping and adaptive learning rate strategies to improve search scope convergence speed and solution efficiency. The effectiveness of the proposed optimization scheduling and configuration methods was validated through a case study of an industrial park located in a coastal area of southeastern China. Results: The results show that using three-parameter Weibull distribution models and Beta distribution models more accurately reflects the variations in actual wind speeds and solar irradiance levels achieving peak shaving and valley filling effects and enhancing renewable energy utilization. The EKOA algorithm significantly reduced curtailment rates of wind and solar power generation while achieving substantial economic benefits. Compared with other operation modes of hydrogen the daily average cost is reduced by 12.92% and external electricity purchases are reduced by an average of 20.2 MW h/day. Discussion: Although our approach shows potential in improving energy utilization efficiency and economic gains this paper only considered hydrogen energy for single-use pathways and did not account for the economic benefits from selling hydrogen in the market. Future research will further incorporate hydrogen demand response mechanisms and optimize the output of integrated energy systems from the perspective of spot markets. These findings provide valuable references for relevant engineering applications.
Gamified Learning for Sustainability: An Innovative Approach to Enhance Hydrogen Literacy and Environmental Awareness Through Simulation-Based Education
Mar 2025
Publication
The transition to sustainable energy systems presents a critical challenge for the 21st century necessitating both technological advancements and transformative educational strategies to foster awareness and knowledge. Hydrogen technologies are pivotal for decarbonization yet public understanding and acceptance remain limited. This study introduces and evaluates a novel gamified educational framework uniquely integrating simulationbased learning collaborative problem-solving and adaptive instructional scaffolding to enhance hydrogen literacy and sustainability awareness. Unlike traditional pedagogical approaches this method actively engages learners in real-world decision-making scenarios bridging the gap between theoretical knowledge and practical applications. This study involved adolescents aged 13–15 from two distinct educational and cultural contexts one in Europe and one in the Middle East. A pre–post study design assessed knowledge acquisition gamification engagement and environmental awareness shifts. Findings reveal statistically significant improvements in technical knowledge and strong positive perceptions of gamified learning as an effective sustainability education tool across both cultural groups (Europe and the Middle East). Variations in engagement across cultural contexts suggest the need for adaptive context-sensitive educational frameworks. While the findings indicate significant short-term knowledge gains this study does not assess long-term knowledge retention which remains an important area for future research. This research contributes to sustainability education by demonstrating how strategically designed gamification can foster behavioral engagement enhance environmental literacy and support the global energy transition agenda. This study offers a pioneering perspective on integrating interactive learning methodologies to cultivate sustainability competencies among younger generations.
Integrated Energy Storage and Transmission Solutions: Evaluating hydrogen, Ammonia, and Compressed Air for Offshore Wind Power Delivery
Mar 2025
Publication
This paper introduces a novel dual-purpose transmission system that integrates power transmission and energy storage using hydrogen ammonia and compressed air—an area largely unexplored in the literature. Unlike conventional cable transmission which requires separate storage infrastructure the proposed approach leverages the transmission medium itself as an energy storage solution enhancing system efficiency and reducing costs. By incorporating a defined storage allocation factor this study examines the delivery of offshore-generated power to onshore locations calculating the necessary media flow rates and evaluating the required transportation infrastructure including tunnels and pipelines. A comparative cost-effectiveness analysis is conducted to determine optimal conditions under which storage-integrated transmission outperforms conventional cable transmission. Various transmission powers storage fractions pressures and distances are analysed to assess feasibility and economic viability. The findings indicate that for a 75 % storage allocation factor compressed air can transmit up to 450 MW over 300 km more cost-effectively than cables while hydrogen enables 230 MW transmission beyond 310 km. Ammonia proves to be the most efficient facilitating the transmission of over 2000 MW across distances exceeding 140 km at a lower cost than cables all without requiring onshore storage. Moreover for a 500-km transmission line compressed air hydrogen and ammonia can store the equivalent of 62 58 and 152 h of wind farm output respectively significantly reducing the need for additional onshore storage. This study fills a critical research gap by optimizing offshore wind power delivery through an innovative cost-effective and scalable transmission and storage approach.
Synergies Between Green Hydrogen and Renewable Energy in South Africa
Aug 2025
Publication
South Africa has excellent conditions for renewable energy generation making it well placed to produce green hydrogen for both domestic use and export. In building a green hydrogen economy around export markets it will face competition from countries with equivalent or better resources and/or that are located closer to export markets (e.g. in North Africa and the Middle East) or have lower capital costs (developed markets like Australia and Canada). South Africa however has an extensive energy system with unserved electricity demand. The ability to trade electricity with the national grid (feeding into the grid during times of peak dedicated renewable energy supply and extracting from the grid during times of low dedicated renewable energy availability) could reduce the cost of producing green hydrogen by as much as 10–25 %. This paper explores the opportunity for South African green hydrogen producers presented by the electricity supply crisis that has been ongoing since 2007. It highlights the potential for a mutually reinforcing growth cycle between renewable energy and green hydrogen to be established which will contribute not only to the mitigation of greenhouse gas emissions but to the local economy and broader society.
Progress on Research and Application of Energy and Power Systems for Inland Waterway Vessels: A Case Study of the Yangtze River in China
Aug 2025
Publication
This study focuses on the power systems of inland waterway vessels in Chinese Yangtze River systematically outlining the low-carbon technology pathways for different power system types. A comparative analysis is conducted on the technical feasibility emission reduction potential and economic viability of LNG methanol ammonia pure electric and hybrid power systems revealing the bottlenecks hindering the large-scale application of each system. Key findings indicate that: (1) LNG and methanol fuels offer significant short-term emission reductions in internal combustion engine power systems yet face constraints from methane slip and insufficient green methanol production capacity respectively; (2) ammonia enables zero-carbon operations but requires breakthroughs in combustion stability and synergistic control of NOX; (3) electric vessels show high decarbonization potential but battery energy density limits their range while PEMFC lifespan constraints and SOFC thermal management deficiencies impede commercialization; (4) hybrid/range-extended power systems with superior energy efficiency and lower retrofitting costs serve as transitional solutions for existing vessels though challenged by inadequate energy management strategies and multi-equipment communication protocol interoperability. A phased transition pathway is proposed: LNG/methanol engines and hybrid systems dominate during 2025–2030; ammonia-powered systems and solid-state batteries scale during 2030–2035; post-2035 operations achieve zero-carbon shipping via green hydrogen/ammonia.
Hydrogen Mole Fraction Distributions Inferred from Inverse-LIF Measurements on High-pressure Hydrogen Injections
Oct 2025
Publication
The mixing of fuel and ambient in a compression-igniting combustion engine is a critical process affecting ignition delay burn duration and cycle efficiency. This study aims to visualize and quantify hydrogen mole fraction distributions resulting from high-pressure (10 MPa) hydrogen injections into an inert pressurized (1 MPa) nitrogen ambient at room temperature. Using inverse planar laser-induced fluorescence in which the ambient rather than the jet is seeded with a fluorescent tracer two different injectors (nozzle hole sizes of 0.55 and 0.65 mm) and two different tracers (toluene and acetone) are compared. It is concluded that a non-intensified CCD camera for fluorescence detection is superior to the use of an intensified one due to the linear behavior on contrast. The two injectors produce similar jets in terms of jet penetration and angle. Jet penetration derived from inverse-LIF measurements agree with Schlieren data on nominally the same jets but the hydrogen mole fractions are generally 2.5-5 percent lower than those obtained by planar Rayleigh scattering. Quasi-steadiness and self-similarity were found for ensemble-averaged mole fraction distributions of both injectors which aligns with theory and highlights the importance of using RANS simulations or time-averaged experiments for future comparisons.
Multi-Fuel SOFC System Modeling for Ship Propulsion: Comparative Performance Analysis and Feasibility Assessment of Ammonia, Methanol and Hydrogen as Marine Fuels
Oct 2025
Publication
To reduce fossil fuel dependency in shipping adopting alternative fuels and innovative propulsion systems is essential. Solid Oxide Fuel Cells (SOFC) powered by hydrogen carriers represent a promising solution. This study investigates a multi-fuel SOFC system for ocean-going vessels capable of operating with ammonia methanol or hydrogen thus enhancing bunkering flexibility. A thermodynamic model is developed to simulate the performance of a 3 kW small-scale system subsequently scaling up to a 10 MW configuration to meet the power demand of a container ship used as the case study. Results show that methanol is the most efficient fueling option reaching a system efficiency of 58% while ammonia and hydrogen reach slightly lower values of about 55% and 51% respectively due to higher auxiliary power consumption. To assess technical feasibility two installation scenarios are considered for accommodating multiple fuel tanks. The first scenario seeks the optimal fuel share equivalent to the diesel tank’s chemical energy (17.6 GWh) minimizing mass increase. The second scenario optimizes the fuel share within the available tank volume (1646 m3 ) again minimizing mass penalties. In both cases feasibility results have highlighted that changes are needed in terms of cargo reduction equal to 20.3% or alternatively in terms of lower autonomy with an increase in refueling stops. These issues can be mitigated by the benefits of increased bunkering flexibility
Quantifying Natural Hydrogen Generation Rates and Volumetric Potential in Onshore Serpentinization
Mar 2025
Publication
This study explores the generation of natural hydrogen through the serpentinization of onshore ultramafic rocks highlighting its potential as a clean energy resource. By investigating critical factors such as mineral composition temperature and pressure the research develops an empirical model using multiple regression analysis to predict hydrogen generation rates under varying geological conditions. A novel five-stage volumetric calculation methodology is introduced to estimate hydrogen production from ultramafic rock bodies. The application of this framework to the Giles Complex an ultramafic-mafic intrusion in Australia suggests a hydrogen generation potential of approximately 2.24 × 1013 kg of hydrogen through partial serpentinization. This estimate is based on the assumed mineral composition depth and temperature conditions within the intrusion which influence the extent of serpentinization reactions. The findings demonstrate the significant potential of ultramafic complexes for natural hydrogen production and provide a foundation for advancing natural hydrogen exploration refining predictive models and supporting sustainable energy development.
The Link Between Microstructural Heterogeneity and Hydrogen Redistribution
Jul 2025
Publication
Green hydrogen is likely to play a major role in decarbonising the aviation industry. It is crucial to understand the effects of microstructure on hydrogen redistribution which may be implicated in the embrittlement of candidate fuel system metals. We have developed a multiscale finite element modelling framework that integrates micromechanical and hydrogen transport models such that the dominant microstructural effects can be efficiently accounted for at millimetre length scales. Our results show that microstructure has a significant effect on hydrogen localisation in elastically anisotropic materials which exhibit an interesting interplay between microstructure and millimetre-scale hydrogen redistribution at various loading rates. Considering 316L stainless steel and nickel a direct comparison of model predictions against experimental hydrogen embrittlement data reveals that the reported sensitivity to loading rate may be strongly linked with rate-dependent grain scale diffusion. These findings highlight the need to incorporate microstructural characteristics in hydrogen embrittlement models.
Modeling and Simulation of Coupled Biochemical and Two-phase Compositional Flow in Underground Hydrogen Storage
Aug 2025
Publication
Integrating microbial activity into underground hydrogen storage models is crucial for simulating longterm reservoir behavior. In this work we present a coupled framework that incorporates bio-geochemical reactions and compositional flow models within the Matlab Reservoir Simulation Toolbox (MRST). Microbial growth and decay are modeled using a double Monod formulation with populations influenced by hydrogen and carbon dioxide availability. First a refined Equation of State (EoS) is employed to accurately capture hydrogen dissolution thereby improving phase behavior and modeling of microbial activity. The model is then discretized using a cell-centered finite-volume method with implicit Euler time discretization. A fully coupled fully implicit strategy is considered. Our implementation builds upon MRST’s compositional module by incorporating the Søreide–Whitson EoS microbial reaction kinetics and specific effects such as bio-clogging and molecular diffusion. Through a series of 1D 2D and 3D simulations we analyze the effects of microbialinduced bio-geochemical transformations on underground hydrogen storage in porous media.These results highlight that accounting for bio-geochemical effects can substantially impact hydrogen loss purity and overall storage performance.
Comprehensive Review of Emerging Trends in Thermal Energy Storage Mechanisms, Materials and Applications
Aug 2025
Publication
Thermal energy storage (TES) technologies are emerging as key enablers of sustainable energy systems by providing flexibility and efficiency in managing thermal resources across diverse applications. This review comprehensively examines the latest advancements in TES mechanisms materials and structural designs including sensible heat latent heat and thermochemical storage systems. Recent innovations in nano-enhanced phase change materials (PCMs) hybrid TES configurations and intelligent system integration are highlighted. The role of advanced computational methods such as digital twins and AI-based optimization in enhancing TES performance is also explored. Applications in renewable energy systems industrial processes district heating networks and green hydrogen production are discussed along with associated challenges and future research directions. This review aims to synthesize current knowledge while identifying pathways for accelerating the development and practical deployment of next-generation TES technologies.
Feasibility of Using Rainwater for Hydrogen Production via Electrolysis: Experimental Evaluation and Ionic Analysis
Oct 2025
Publication
This study evaluates the feasibility of employing rainwater as an alternative feedstock for hydrogen production via electrolysis. While conventional systems typically rely on high-purity water—such as deionized or distilled variants—these can be cost-prohibitive and environmentally intensive. Rainwater being naturally available and minimally treated presents a potential sustainable alternative. In this work a series of comparative experiments was conducted using a proton exchange membrane electrolyzer system operating with both deionized water and rainwater collected from different Austrian locations. The chemical composition of rainwater samples was assessed through inductively coupled plasma ion chromatography and visual rapid tests to identify impurities and ionic profiles. The electrolyzer’s performance was evaluated under equivalent operating conditions. Results indicate that rainwater in some cases yielded comparable or marginally superior efficiency compared to deionized water attributed to its inherent ionic content. The study also examines the operational risks linked to trace contaminants and explores possible strategies for their mitigation.
Hydrogen-Based Solutions for Enhancing Frequency Stability in Renewable Energy-Integrated Power Systems
Mar 2025
Publication
With the increasing adoption of renewable energy sources such as solar and wind power it is essential to achieve carbon neutrality. However several shortcomings including their intermittence pose significant challenges to the stability of the electrical grid. This study explores hydrogen-based technologies such as fuel cells and water electrolysis systems as an effective solution to improve frequency stability and address the problems of power grid reliability. Using power system analysis programs modeling and simulations performed on IEEE-25 Bus and Jeju Island systems demonstrate the potential of these technologies to mitigate reductions reduce transmission constraints and stabilize frequencies. The results show that hydrogen-based systems are important factors enabling sustainable energy transition.
Market Readiness Analysis: Expected Uptake of Alternative Fuel Heavy-duty Vehicles until 2030 and their Corresponding Infrastructure Needs
Jun 2025
Publication
This report assesses the market readiness of zero-emission heavy-duty vehicles and the required infrastructure to meet the 45% emission reduction targets set by the revised CO2 standards by 2030. Achieving these goals requires the widespread adoption of zero-emission vehicles and a robust recharging and hydrogen refuelling infrastructure Three main aspects are investigated: the market readiness of the vehicles considering both the demand and supply side the corresponding infrastructure requirements and the barriers. Building on the inputs of the stakeholders a ‘study scenario’ is developed. This scenario shows a concrete picture of what the zero-emission heavy-duty vehicle fleet and its infrastructure requirement could look like by 2030. There are however key barriers that need to be overcome such as high total cost of ownership limited electricity grid capacity lengthy permitting processes and uncertainty in hydrogen availability and pricing. Stakeholders also emphasize the importance of policy drivers such as emissions trading systems and tolling and tax reforms to stimulate demand. In conclusion achieving the 2030 targets demands a coordinated approach involving manufacturers operators and policymakers to address infrastructure gaps market barriers and policy incentives ensuring the transition to a zero-emission HDV fleet.
A Study on Thermal Management Systems for Fuel-Cell Powered Regional Aircraft
Jun 2025
Publication
This work studies the feasibility of integrating a hydrogen-powered propulsion system in a regional aircraft at the conceptual design level. The developed system consists of fuel cells which will be studied at three technological levels and batteries also studied for four hybridization factors (X = 0 0.05 0.10 0.20). Hydrogen can absorb great thermal loads since it is stored in the tank at cryogenic temperatures and is used as fuel in the fuel cells at around 80 ◦C. Taking advantage of this characteristic two thermal management system (TMS) architectures were developed to ensure the proper functioning of the aircraft during the designated mission: A1 which includes a vapor compression system (VCS) and A2 which omits it for a simpler design. The models were developed in MATLAB® and consist of different components and technologies commonly used in such systems. The analysis reveals that A2 due to the exclusion of the VCS outperformed A1 in weight (10–23% reduction) energy consumption and drag. A1’s TMS required significantly more energy due to the VCS compressor. Hybridization with batteries increased system weight substantially (up to 37% in A2) and had a greater impact on energy consumption in A2 due to additional fan work. Hydrogen’s heat sink capacity remained underutilized and the hydrogen tank was deemed suitable for a non-integral fuselage design. A2 had the lowest emissions (10–20% lower than A1 for X = 0) but hybridization negated these benefits significantly increasing emissions in pessimistic scenarios.
Hydrogen Storage Potential of Unlined Granite Rock Caverns: Experimental and Numerical Investigations on Geochemical Interactions
Jun 2025
Publication
Underground Hydrogen Storage (UHS) offers a promising solution for large-scale energy storage yet suitable geological formations are often scarce. Unlined rock caverns (URCs) constructed in crystalline rocks like granite present a novel alternative particularly in regions where salt caverns or porous media are unsuitable. Despite their potential URCs remain largely unexplored for hydrogen storage. This study addresses this gap by providing one of the first comprehensive investigations into the geochemical interactions between hydrogen and granite host rock using a combined experimental and numerical approach. Granite powder samples were exposed to hydrogen and inert gas (N₂) in brine at room temperature and 5 MPa pressure for 14 weeks. Results showed minimal reactivity of silicate minerals with hydrogen indicated by negligible differences in elemental concentrations between H₂ and N₂ atmospheres. A validated geochemical model demonstrated that existing thermodynamic databases can accurately predict silicate‑hydrogen interactions. Additionally a kinetic batch model was developed to simulate long-term hydrogen storage under commercial URC conditions at Haje. The model predicts a modest 0.65 % increase in mineral volume over 100 years due to mineral precipitation which decreases net porosity and potentially enhances hydrogen containment by limiting leakage pathways. These findings support the feasibility of granite URCs for UHS providing a stable long-term storage option in regions lacking traditional geological formations. By filling a critical knowledge gap this study advances scalable hydrogen storage solutions contributing to the development of resilient renewable energy infrastructure.
Modeling Homogeneous, Stratified, and Diffusion Combustion in Hydrogen SI Engines Using the Wiebe Approach
Jun 2025
Publication
The use of hydrogen as a fuel for piston engines enables environmentally friendly and efficient operation. However several challenges arise in the combustion process limiting the development of hydrogen engines. These challenges include abnormal combustion the high burning velocity of hydrogen-enriched mixtures increased nitrogen oxide emissions and others. A rational organization of hydrogen combustion can partially or fully mitigate these issues through the use of advanced methods such as late direct injection charge stratification dual injection jet-guided operation and others. However mathematical models describing hydrogen combustion for these methods are still under development complicating the optimization and refinement of hydrogen engines. Previously we proposed a mathematical model based on Wiebe functions to describe premixed and diffusion combustion as well as relatively slow combustion in lean-mixture zones behind the flame front and near-wall regions. This study further develops the model by accounting for the combined influence of the mixture composition and engine speed mixture stratification and the effects of injection and ignition parameters on premixed and diffusion combustion. Special attention is given to combustion modeling in an engine with single injection and jet-guided operation.
Experimental Study on the Effects of Injection Pressure and Injection Timing on Combustion and Emissions in a Direct-injection Hydrogen Engine
Oct 2025
Publication
Hydrogen internal combustion engines are pivotal components of the power industry for achieving zero-carbon emissions. However the development of hydrogen engines is still in its infancy and experimental research on their injection strategies lacks systematization. In this study the individual impacts of hydrogen injection pressure (within low-pressure ranges) and injection timing as well as their coupling effects on combustion characteristics engine efficiency and exhaust emissions were experimentally investigated. Results show that under fixed timing an injection pressure of 25–27.5 bar yields the highest and earliest peak in-cylinder pressures whereas at 15 bar the ignition delay increases to 14.7°CA the flame development duration extends to 8.57°CA and the late combustion duration shortens to 41.37°CA; the exhaust gas temperature peaks at 628 K at 20 bar and NOX peaks at 537 ppm at 25 bar. BTE (brake thermal efficiency) exhibits a U-shaped relationship with pressure with the minimum efficiency occurring near 25 bar when timing is held constant; advancing start of injection from 130° BTDC to 170° BTDC reduces both NOX and exhaust gas temperature with the optimal fuel economy at 140° BTDC and a peak in-cylinder pressure that is approximately 7 % higher and occurs 2–3°CA earlier at 130–140° BTDC. In the pressure–timing maps IMEP (indicated mean effective pressure) is maximized at 30 bar and 90° BTDC; BTE reaches 33.5 % at 25 bar and 100° BTDC; NOX attains a minimum at 25 bar and 110° BTDC while the exhaust gas temperature is lowest at 25 bar and 120° BTDC. Injection pressure is the primary lever for regulating fuel economy and emissions while injection timing mainly adjusts combustion phasing and IMEP. The results provide clear guidance for calibrating low-pressure hydrogen injection systems supply benchmark data for model validation and support the development of practical control strategies for hydrogen engines.
Potential Vulnerability of US Green Hydrogen in a World of Interdependent Networks
Jul 2025
Publication
Green hydrogen is viewed as a promising pathway to future decarbonized energy systems. However hydrogen production depends on a few critical minerals particularly platinum and iridium. Here we examine how the supply of these minerals is subject to vulnerabilities hidden in interdependent global networks of trade and investment. We develop an index to quantify these vulnerabilities for a combination of a target country an investing country an intermediary country and a commodity. Focusing on the US as the target country for the import of platinum and iridium we show how vulnerability-inducing investing countries changed between 2010 and 2019. We find that the UK is consistently among investing countries that can potentially induce US vulnerabilities via intermediary exporters of platinum and iridium with South Africa being the primary intermediary country. Future research includes incorporating geopolitical factors and technological innovations to move the index closer from potential to real-world vulnerabilities.
Equipment Sizing and Operation Strategy of Photovoltaic-Powered Hydrogen Refueling Station Based on AE-PEM Coupled Hydrogen Production
Mar 2025
Publication
With the global commercialization of hydrogen fuel cell vehicles the number of hydrogen refueling stations is steadily increasing. On-site hydrogen production stations are expected to play a key role in future power systems by absorbing renewable energy and supplying electricity during peak grid loads aiding in peak shaving and load leveling. However renewable energy sources like photovoltaic (PV) systems have highly fluctuating power generation curves making it difficult to provide stable energy for hydrogen production. Traditional stations mainly use alkaline electrolyzers (AE) which are sensitive to power fluctuations leading to operational instability. To address this this paper proposes using capacitors and energy storage batteries to mitigate PV fluctuations and introduces a combined AE and Proton Exchange Membrane (PEM) electrolyzer hydrogen production method. Study cases demonstrate that capacitors and energy storage batteries reduce the variance of PV power output by approximately 0.02. Building on this the hybrid approach leverages the low cost of AE and the rapid response of PEM electrolyzers to better adapt to PV fluctuations and maximize PV absorption. The model is mathematically formulated and the station’s equipment planning and operational strategy are optimized using CPLEX. The results show that compared to pure AE and PEM hydrogen production the combined AE and PEM hydrogen production method reduces the total annual cost of the hydrogen refueling station by 4.3% and 5.9% respectively.
Machine Learning for the Optimization and Performance Prediction of Solid Oxide Electrolysis Cells: A Review
Mar 2025
Publication
Solid oxide electrolysis cells (SOECs) represent a promising technology because they have the potential to achieve greater efficiency than existing electrolysis methods making them a strong candidate for sustainable hydrogen production. SOECs utilize a solid oxide electrolyte which facilitates the migration of oxygen ions while maintaining gas impermeability at temperatures between 600 ◦C and 900 ◦C. This review provides an overview of the recent advancements in research and development at the intersection of machine learning and SOECs technology. It emphasizes how data-driven methods can improve performance prediction facilitate material discovery and enhance operational efficiency with a particular focus on materials for cathode-supported cells. This paper also addresses the challenges associated with implementing machine learning for SOECs such as data scarcity and the need for robust validation techniques. This paper aims to address challenges related to material degradation and the intricate electrochemical behaviors observed in SOECs. It provides a description of the reactions that may be involved in the degradation mechanisms taking into account thermodynamic and kinetic factors. This information is utilized to construct a fault tree which helps categorize various faults and enhances understanding of the relationship between their causes and symptoms.
A Cost-Optimizing Analysis of Energy Storage Technologies and Transmission Lines for Decarbonizing the UK Power System by 2035
Mar 2025
Publication
The UK net zero strategy aims to fully decarbonize the power system by 2035 anticipating a 40–60% increase in demand due to the growing electrification of the transport and heating sectors over the next thirteen years. This paper provides a detailed technical and economic analysis of the role of energy storage technologies and transmission lines in balancing the power system amidst large shares of intermittent renewable energy generation. The analysis is conducted using the cost-optimizing energy system modelling framework REMix developed by the German Aerospace Center (DLR). The obtained results of multiple optimization scenarios indicate that achieving the lowest system cost with a 73% share of electricity generated by renewable energy sources is feasible only if planning rules in England and Wales are flexible enough to allow the construction of 53 GW of onshore wind capacity. This flexibility would enable the UK to become a net electricity exporter assuming an electricity trading market with neighbouring countries. Depending on the scenario 2.4–11.8 TWh of energy storage supplies an average of 11% of the electricity feed-in with underground hydrogen storage representing more than 80% of that total capacity. In terms of storage converter capacity the optimal mix ranges from 32 to 34 GW of lithium-ion batteries 13 to 22 GW of adiabatic compressed air energy storage 4 to 24 GW of underground hydrogen storage and 6 GW of pumped hydro. Decarbonizing the UK power system by 2035 is estimated to cost $37–56 billion USD with energy storage accounting for 38% of the total system cost. Transmission lines supply 10–17% of the total electricity feed-in demonstrating that when coupled with energy storage it is possible to reduce the installed capacity of conventional power plants by increasing the utilization of remote renewable generation assets and avoiding curtailment during peak generation times.
The Hydrogen Challenge: Addressing Storage, Safety, and Environmental Concerns in the Hydrogen Economy
Aug 2025
Publication
As part of global decarbonization efforts hydrogen has emerged as a key energy carrier that can achieve deep emission reductions in various sectors. This review critically assesses the role of hydrogen in the low-carbon energy transition and highlights the interlinked challenges within the Techno-Enviro-Socio-Political (TESP) framework. It examines key aspects of deployment including production storage safety environmental impacts and socio-political factors to present an integrated view of the opportunities and barriers to large-scale adoption. Despite growing global interest over 90 % of the current global hydrogen production originated from fossilbased processes resulting in around 920 Mt of CO2 emissions two-thirds of which were attributable to fossil fuels. The Life Cycle Assessment (LCA) shows that coal-based electrolysis resulted in the highest GHG emission (144 - 1033 g CO2-eq/MJ) and an energy consumption (1.55–10.33 MJ/MJ H2). Without a switch to low-carbon electricity electrolysis cannot deliver significant climate benefits. Conversely methanol steam reforming based on renewable feedstock offered the lowest GHG intensity (23.17 g CO2-eq/MJ) and energy demand (0.23 MJ/ MJ) while biogas reforming proved to be a practical short-term option with moderate emissions (51.5 g CO2-eq/ MJ) and favourable energy figures. Catalytic ammonia cracking which is suitable for long-distance transport represents a compromise between low energy consumption (2.93 MJ/MJ) and high water intensity (8.34 L/km). The thermophysical properties of hydrogen including its low molecular weight high diffusivity and easy flammability lead to significant safety risks during storage and distribution which are exacerbated by its sensitivity to ignition and jet pulse effects. The findings show that a viable hydrogen economy requires integrated strategies that combine decarbonised production scalable storage harmonised safety protocols and cross-sector stakeholder engagement for better public acceptance. This review sets out a multi-dimensional approach to guide technological innovation policy adaptation and infrastructure readiness to support a scalable and environmentally sustainable hydrogen economy.
Understanding the Framing of Hydrogen Technology: A Cross-national Content Analysis of Newspaper Coverage in Germany, Saudi Arabia, UAE, and Egypt
Jul 2025
Publication
Introduction: The implementation of national hydrogen strategies targeting zero-emission goals has sparked public discussions regarding energy and environmental communication. However gaining societal acceptance for hydrogen technology poses a significant challenge in numerous countries. Hence this research investigates the framing of hydrogen technology through a comparative analysis of opinion-leading newspapers in Germany Saudi Arabia the United Arab Emirates and Egypt. Methods: Utilizing a quantitative framing analysis based on Entman’s framing approach this research systematically identifies media frames and comprehend their development through specific frame characteristics. A factor analysis identified six distinct frames: Hydrogen as a Sustainable Energy Solution Benefits of Economic and Political Collaboration Technological and Scientific Challenges Governance Issues and Energy Security Industrial and Climate Solutions and Economic Risk. Results: The findings reveal that newspapers frames vary significantly due to contextual factors such as national hydrogen strategies media systems political ideologies article types and focusing events. Specifically German newspapers display diverse and balanced framing in line with its pluralistic media environment and national emphasis on green hydrogen and energy security while newspapers from MENA countries primarily highlight economic and geopolitical benefits aligned with their national strategies and state-controlled media environments. Additionally the political orientation of newspapers affects the diversity of frames particularly in Germany. Moreover non-opinion articles in Germany exhibit greater framing diversity compared to opinion pieces while in the MENA region the framing remains uniform regardless of article type due to centralized media governance. A notable shift in media framing in Germany was found after a significant geopolitical event which changed the frame from climate mitigation to energy security. Discussion: This study underscores the necessity for theoretical and methodological thoroughness in identifying frames as well as the considerable impact of contextual factors on the media representation of emerging sustainable technologies.
A Review on Green Hydrogen Production by Aqueous Phase Reforming of Lignocellulose and Derivatives
Mar 2025
Publication
With the intensification of the global energy crisis hydrogen has attracted significant attention as a high-energy-density and zero-emission clean energy source. Traditional hydrogen production methods are dependent on fossil fuels and simultaneously contribute to environmental pollution. The aqueous phase reforming (APR) of renewable biomass and its derivatives has emerged as a research hotspot in recent years due to its ability to produce green hydrogen in an environmentally friendly manner. This review provides an overview of the advancements in APR of lignocellulosic biomass as a sustainable and environmentally friendly method for hydrogen production. It focuses on the reaction pathways of various biomass feedstocks (such as glucose cellulose and lignin) as well as the types and performance of catalysts used in the APR process. Finally the current challenges and future prospects in this field are briefly discussed.
Simulation of a Hybrid Plant with ICE/HT-PEMFC and On-Site Hydrogen Production from Methane Steam Reforming
Oct 2025
Publication
Hydrogen-based technologies prominently fuel cells are emerging as strategic solutions for decarbonization. They offer an efficient and clean alternative to fossil fuels for electricity generation making a tangible contribution to the European Green Deal climate objectives. The primary issue is the production and transportation of hydrogen. An on-site hydrogen production system that includes CO2 capture could be a viable solution. The proposed power system integrates an internal combustion engine (ICE) with a steam methane reformer (SMR) equipped with a CO2 capture and energy storage system to produce “blue hydrogen”. The hydrogen fuels a high-temperature polymer electrolyte membrane (HTPEM) fuel cell. A battery pack incorporated into the system manages rapid fluctuations in electrical load ensuring stability and continuity of supply and enabling the fuel cell to operate at a fixed point under nominal conditions. This hybrid system utilizes natural gas as its primary source reducing climate-altering emissions and representing an efficient and sustainable solution. The simulation was conducted in two distinct environments: Thermoflex code for the integration of the engine reformer and CO2 capture system; and Matlab/Simulink for fuel cell and battery pack sizing and dynamic system behavior analysis in response to user-demanded load variations with particular attention to energy flow management within the simulated electrical grid. The main results show an overall efficiency of the power system of 39.9% with a 33.5% reduction in CO2 emissions compared to traditional systems based solely on internal combustion engines.
Which Offers Greater Techno-Economic Potential: Oil or Hydrogen Production from Light Oil Reservoirs?
Jun 2025
Publication
The global emphasis on clean energy has increased interest in producing hydrogen from petroleum reservoirs through in situ combustion-based processes. While field practices have demonstrated the feasibility of co-producing hydrogen and oil the question of which offers greater economic potential oil or hydrogen remains central to ongoing discussions especially as researchers explore ways to produce hydrogen exclusively from petroleum reservoirs. This study presents the first integrated techno-economic model comparing oil and hydrogen production under varying injection strategies using CMG STARS for reservoir simulations and GoldSim for economic modeling. Key technical factors including injection compositions well configurations reservoir heterogeneity and formation damage (issues not addressed in previous studies) were analyzed for their impact on hydrogen yield and profitability. The results indicate that CO2-enriched injection strategies enhance hydrogen production but are economically constrained by the high costs of CO2 procurement and recycling. In contrast air injection although less efficient in hydrogen yield provides a more cost-effective alternative. Despite the technological promise of hydrogen oil revenue remains the dominant economic driver with hydrogen co-production facing significant economic challenges unless supported by policy incentives or advancements in gas lifting separation and storage technologies. This study highlights the economic trade-offs and strategic considerations crucial for integrating hydrogen production into conventional petroleum extraction offering valuable insights for optimizing hydrogen co-production in the context of a sustainable energy transition. Additionally while the present work focuses on oil reservoirs future research should extend the approach to natural gas and gas condensate reservoirs which may offer more favorable conditions for hydrogen generation.
Hydrogen Gas Blending in Gasoline GDI Engines: Combustion Analysis and Emission Control
Jun 2025
Publication
This study investigates the effects of varying hydrogen percentages in fuel blends on combustion dynamics engine performance and emissions. Experimental data and analytical equations were used to evaluate combustion parameters such as equivalent lambda in-cylinder pressure heat release rate and ignition timing. The findings demonstrate that hydrogen blending enhances combustion stability shortens ignition delay and shifts peak heat release to be closer to the top dead center (TDC). These changes improve thermal efficiency and reduce cycle-to-cycle variation. Hydrogen blending also significantly lowers carbon dioxide (CO2) and hydrocarbon (HC) emissions particularly at higher blend levels (H0–H5) while lower blends increase nitrogen oxides (NOx) emissions and risk pre-ignition due to advanced start of combustion (SOC). Engine performance improved with an average hydrogen energy contribution of 12% under a constant load. However the optimal hydrogen blending range is crucial to balancing efficiency gains and emission reductions. These results underline the potential of hydrogen as a cleaner additive fuel and the importance of optimizing blend ratios to harness its benefits effectively.
An Expert Opinion-based Perspective on Emerging Policy and Economic Research Priorities for Advancing the Low-carbon Hydrogen Sector
Jun 2025
Publication
This perspective sheds light on emerging research priorities crucial for advancing the low-carbon hydrogen sector considered critical for achieving net zero greenhouse gas emissions targets especially for hard-to-abate sectors. Our analysis follows a five-step process including drawing from news media academic discourse and expert consultations. We identify twenty-one major research challenges. Among the top priorities highlighted by experts are: (i) Evaluating the trade-offs of hydrogen-fueled power generation compared to hydrocarbon fuels and renewables with alternative storage solutions and the feasibility of co-firing hydrogen and ammonia with hydrocarbon fuels for backup or independent power generation; (ii) Exploring how global hydrogen trade could be shaped by market forces such as price volatility geopolitical dynamics and international collaborations; (iii) Examining the financial considerations for investors from developed nations pursuing hydrogen projects in resource-rich developing countries balancing costs investment risks and expected returns. We find statistically significant differences in opinions on hydrogen/ammonia co-firing for power generation between experts from China and those from the U.S. and Germany.
Macroeconomic and Environmental Impacts of Two Decarbonization Options for the Dutch Steel Industry: Green Relocation Versus Green Hydrogen Imports
Jun 2025
Publication
Decarbonizing the steel industry will require a shift towards renewable energy. However costs and emissions associated with the long-distance transport of renewable energy carriers may incentivize the relocation of steel production closer to renewable energy sources. This “green relocation” would affect regional economic structures and global trade patterns. Nevertheless the macroeconomic and environmental impacts of alternative industry location options remain underexplored. This study compares the impacts on value-added prices and emissions under two options for decarbonizing the Dutch steel industry: importing green hydrogen from Brazil to produce green steel in the Netherlands versus relocating production to Brazil and transporting green steel to the Netherlands. Impacts are analyzed by combining a price and a quantity model within an environmentally extended multiregional input-output (EE-MRIO) framework. Results suggest that the relocation option brings the greatest synergies between climate and economic goals at the global level as it leads to lower production costs smaller price effects and greater emissions reductions. However relocation also results in stronger distributive impacts across global regions. Higher carbon prices would be insufficient to counteract relocation incentives. This calls for policymakers in industrialized countries to systematically consider the possibility of green relocation when designing decarbonization and industrial competitiveness strategies.
Sustainable Hydrogen Production from Nuclear Energy
Aug 2025
Publication
The rapid increase in global warming requires that sustainable energy choices aimed at achieving net-zero greenhouse gas emissions be implemented as soon as possible. This objective emerging from the European Green Deal and the UN Climate Action could be achieved by using clean and efficient energy sources such as hydrogen produced from nuclear power. “Renewable” hydrogen plays a fundamental role in decarbonizing both the energy-intensive industrial and transport sectors while addressing the global increase in energy consumption. In recent years several strategies for hydrogen production have been proposed; however nuclear energy seems to be the most promising for applications that could go beyond the sole production of electricity. In particular nuclear advanced reactors that operate at very high temperatures (VHTR) and are characterized by coolant outlet temperatures ranging between 550 and 1000 ◦C seem the most suitable for this purpose. This paper describes the potential use of nuclear energy in coordinated and coupled configurations to support clean hydrogen production. Operating conditions energy requirements and thermodynamic performance are described. Moreover gaps that require additional technology and regulatory developments are outlined. The intermediate heat exchanger which is the key component for the integration of nuclear hybrid energy systems was studied by varying the thermal power to determine physical parameters needed for the feasibility study. The latter consisting of the comparative cost evaluation of some nuclear hydrogen production methods was carried out using the HEEP code developed by the IAEA. Preliminary results are presented and discussed.
Feasibility Assessment and Response Surface Optimisation of a Fuel Cell-integrated Sustainable Wind Farm in Italy
Sep 2025
Publication
This study explores the design and feasibility of a novel fuel cell-powered wind farm for residential electricity hydrogen/oxygen production and cooling/heating via a compression chiller. Wind turbine energy powers Proton Exchange Membrane (PEM) electrolyzers and a compression chiller unit. The proposed system was modeled using EES thermodynamic software and its economic viability was assessed. A case study across seven Italian regions with varying wind potentials evaluated the system’s feasibility in diverse weather conditions. Multi-objective optimization using Response Surface Methodology (RSM) determined the number of wind turbines as optimum number of electrolyzers & fuel cell units. Optimization results indicated that 37 wind turbines 1 fuel cell unit and 2 electrolyzer units yielded an exergy efficiency of 27.98 % and a cost rate of 619.9 $/h. TOPSIS analysis suggested 32 wind turbines 2 electrolyzers and 2 reverse osmosis units as an alternative configuration. Further twelve different scenarios were examined to enhance the distribution of wind farmgenerated electricity among the grid electrolyzers and reverse osmosis systems. revealing that directing 25 % to reverse osmosis 20 % to electrolyzers and 55 % to grid sales was optimal. Performance analysis across seven Italian cities (Turin Bologna Florence Palermo Genoa Milan and Rome) identified Genoa Palermo and Bologna as the most suitable locations due to favorable wind conditions. Implementing the system in Genoa the optimal site could produce 28435 MWh of electricity annually prevent 5801 tons of CO2 emissions (equivalent to 139218 $). Moreover selling this clean electricity to the grid could meet the annual clean electricity needs of approximately 5770 people in Italy
Cooperative Control of Hydrogen-energy Storage Microgrid System Based on Disturbance-rejection Model Predictive Control
Mar 2025
Publication
Model predictive control (MPC) requires high accuracy of the model. However the actual power system has complex dynamic characteristics. There must be unmodeled dynamics in the system modeling process which makes it difficult for MPC to perform the function of optimal control. ESO has the ability to observe and suppress errors combining the both can solve this problem. Thus this paper proposes a coordinated control strategy of hydrogen-energy storage system based on disturbance-rejection model predictive controller. Firstly this paper constructs the state-space model of the system and improves MPC. By connecting ESO and MPC in series this paper designs a matched disturbance-rejection model predictive controller and analyzes the robustness of the research system. Finally this paper verifies the effectiveness and feasibility of the disturbance-rejection model predictive controller under various working conditions. Compared with the method using only MPC the dynamic response time of the system frequency regulation under the proposed strategy in this paper is increased by about 29.9 % and the frequency drop rate is slowed down by 13.5 %. In addition under the AGC command and continuous load disturbance working conditions the maximum frequency deviation of the system under the proposed strategy is reduced by about 54.01 % and 48.96 %. The results clearly show that the proposed strategy in this paper significantly improves the dynamic response ability of the system and reduces the frequency fluctuation of the system after disturbance.
Impact of Plastic Composition on the Performance of the Integrated Process of Pyrolysis and Oxidative Steam Reforming for Hydrogen Production
Aug 2025
Publication
The pyrolysis and oxidative steam reforming (P-OSR) of different types of plastics (HDPE PP PET and PS) has been carried out in a two reactor system provided with a conical spouted bed reactor (CSBR) and a fluidized bed reactor (FBR). The effect plastic composition has on the oxidative steam reforming step has been analyzed using two space time values (3.1 gcatalyst min gplastic − 1 and 12.5 gcatalyst min gplastic − 1 ) at a reforming temperature of 700 ◦C S/P ratio of 3 and ER of 0.2 (optimum conditions for autothermal reforming). The different composition of the plastics leads to differences in the yields and compositions of pyrolysis products and consequently in the performance of the oxidative steam reforming step. High conversions (> 97 %) have been achieved by using a space time of 12.5 gcat min gplastic − 1 with H2 production increasing as follows: PET ≪ PS < HDPE ≤ PP. A maximum H2 production of 25.5 wt% has been obtained by using PP which is lower than that obtained in the process of pyrolysis and in line conventional steam reforming (P-SR) of the same feedstock (34.8 wt%). The lowest H2 production (10.5 wt%) has been achieved when PET was used due to the high oxygen content of this plastic. The results obtained in this study prove that P-OSR performs very well with different feedstock thereby confirming the versatility and efficiency of this process to produce a hydrogen-rich gas.
The Financial Results of Energy Sector Companies in Europe and Their Involvement in Hydrogen Production
Jun 2025
Publication
In response to growing environmental concerns hydrogen production has emerged as a critical element in the transition to a sustainable global economy. We evaluate the impact of hydrogen production on both the financial performance and market value of energy sector companies using balanced panel data from 288 European-listed firms over the period of 2018 to 2022. The findings reveal a paradox. While hydrogen production imposes significant financial constraints it is positively recognized by market participants. Despite short-term financial challenges companies engaged in hydrogen production experience higher market value as investors view these activities as a long-term growth opportunity aligned with global sustainability goals. We contribute to the literature by offering empirical evidence on the financial outcomes and market valuation of hydrogen engagement distinguishing between production and storage activities and further categorizing production into green blue and gray hydrogen. By examining these nuances we highlight the complex relationship between financial market results. While hydrogen production may negatively impact short-term financial performance its potential for long-term value creation driven by decarbonization efforts and sustainability targets makes it attractive to investors. Ultimately this study provides valuable insights into how hydrogen engagement shapes corporate strategies within the evolving European energy landscape.
A Multi-objective Decision-making Framework for Renewable Energy Transportation
Aug 2025
Publication
The mismatch in renewable energy generation potential levelized cost and demand across different geographies highlight the potential of a future global green energy economy through the trade of green fuels. This potential and need call for modeling frameworks to make informed decisions on energy investments operations and regulations. In this work we present a multi-objective optimization framework for modeling and optimizing energy transmission strategies considering different generation locations transportation modes and often conflicting objectives of cost environmental impact and transportation risk. An illustrative case study on supplying renewable energy to Germany demonstrates the utility of the framework across diverse options and trade-offs. Sensitivity analysis reveals that the optimal energy carrier and transmission strategy depend on distance demand and existing infrastructure that can be re-purposed. The framework is adaptable across geographies and scales to offer actionable insights to guide investment operational and regulatory decisions in renewable energy and hydrogen supply chains.
Towards Decarbonizing Gas: A Generic Optimal Gas Flow Model with Linepack Constraints for Assessing the Feasibility of Hydrogen Blending in Existing Gas Networks
Aug 2025
Publication
Hydrogen blending into natural gas networks is a promising pathway to decarbonize the gas sector but requires bespoke fluid-dynamic models to accurately capture the properties of hydrogen and assess its feasibility. This paper introduces a generalizable optimal transient gas flow model for transporting homogeneous natural gashydrogen mixtures in large-scale networks. Designed for preliminary planning the model assesses whether a network can operate under a given hydrogen blending ratio without violating existing constraints such as pressure limits pipeline and compressor capacity. A distinguishing feature of the model is a multi-day linepack management strategy that engenders realistic linepack profiles by precluding mathematically feasible but operationally unrealistic solutions thereby accurately reflecting the flexibility of the gas system. The model is demonstrated on Western Australia’s 7560 km transmission network using real system topology and demand data from several representative days in 2022. Findings reveal that the system can accommodate up to 20 % mol hydrogen potentially decarbonizing 7.80 % of gas demand.
MOF-Derived Electrocatalysts for High-Efficiency Hydrogen Production via Water Electrolysis
Jun 2025
Publication
Water electrolysis for hydrogen production has garnered significant attention in the context of increasing global energy demands and the “dual-carbon” strategy. However practical implementation is hindered by challenges such as high overpotentials high catalysts costs and insufficient catalytic activity. In this study three mono and bimetallic metal−organic framework (MOFs)-derived electrocatalysts Fe-MOFs Fe/Co-MOFs and Fe/Mn-MOFs were synthesized via a one-step hydrothermal method using nitroterephthalic acid (NO2-BDC) as the ligand and NN-dimethylacetamide (DMA) as the solvent. Electrochemical tests demonstrated that the Fe/Mn-MOFs catalyst exhibited superior performance achieving an overpotential of 232.8 mV and a Tafel slope of 59.6 mV·dec−1 alongside the largest electrochemical active surface area (ECSA). In contrast Fe/Co-MOFs displayed moderate catalytic activity while Fe-MOFs exhibited the lowest efficiency. Stability tests revealed that Fe/Mn-MOFs retained 92.3% of its initial current density after 50 h of continuous operation highlighting its excellent durability for the oxygen evolution reaction (OER). These findings emphasize the enhanced catalytic performance of bimetallic MOFs compared to monometallic counterparts and provide valuable insights for the development of high-efficiency MOF-based electrocatalysts for sustainable hydrogen production.
Design and Optimization of a Solar Parabolic Dish for Steam Generation in a Blue Hydrogen Production Plant
Oct 2025
Publication
The integration of renewable energy into industrial processes is crucial for reducing the carbon footprint of conventional hydrogen production. This work presents detailed design optical–thermal simulation and performance analysis of a solar parabolic dish (SPD) system for supplying high-temperature steam to a Steam Methane Reforming (SMR) plant. A 5 m diameter dish with a focal length of 3 m was designed and optimized using COMSOL Multiphysics (version 6.2) and MATLAB (version R2023a). Optical ray tracing confirmed a geometric concentration ratio of 896× effectively focusing solar irradiation onto a helical cavity receiver. Thermal–fluid simulations demonstrated the system’s capability to superheat steam to 551 ◦C at a mass flow rate of 0.0051 kg/s effectively meeting the stringent thermal requirements for SMR. The optimized SPD system with a 5 m dish diameter and 3 m focal length was designed to supply 10% of the total process heat (≈180 GJ/day). This contribution reduces natural gas consumption and leads to annual fuel savings of approximately 141000 SAR (Saudi Riyal) along with a substantial reduction in CO2 emissions. These quantitative results confirm the SPD as both a technically reliable and economically attractive solution for sustainable blue hydrogen production.
Real-Time Energy Management of a Microgrid Using MPC-DDQN-Controlled V2H and H2V Operations with Renewable Energy Integration
Aug 2025
Publication
This paper presents the design and implementation of an Intelligent Home Energy Management System in a smart home. The system is based on an economically decentralized hybrid concept that includes photovoltaic technology a proton exchange membrane fuel cell and a hydrogen refueling station which together provide a reliable secure and clean power supply for smart homes. The proposed design enables power transfer between Vehicle-to-Home (V2H) and Home-to-Vehicle (H2V) systems allowing electric vehicles to function as mobile energy storage devices at the grid level facilitating a more adaptable and autonomous network. Our approach employs Double Deep Q-networks for adaptive control and forecasting. A Multi-Agent System coordinates actions between home appliances energy storage systems electric vehicles and hydrogen power devices to ensure effective and cost-saving energy distribution for users of the smart grid. The design validation is carried out through MATLAB/Simulink-based simulations using meteorological data from Tunis. Ultimately the V2H/H2V system enhances the utilization reliability and cost-effectiveness of residential energy systems compared with other management systems and conventional networks.
Optimal Control of an Over-actuated Spark-Ignited Hydrogen Engine
Jun 2025
Publication
The spark-ignited (SI) hydrogen combustion engine has the potential to noticeably reduce greenhouse gas emissions from passenger cars. To prevent nitrogen oxide emissions and to increase fuel efficiency and power output complex air paths and operating strategies are utilized. This makes the engine control problem more complex challenging the conventional engine calibration process. This work combines and extends the state-of-the-art in real-time combustion engine modeling and optimal control presenting a novel control concept for the efficient operation of a hydrogen combustion engine. The extensive experimental validation with a 1.5 l three-cylinder hydrogen SI engine and a dynamically operated engine test bench with emission and in-cylinder pressure measurements provides a comprehensible comparison to conventional engine control. The results demonstrate that the proposed optimal control decreased the load tracking errors by a factor of up to 2.8 and increased the engine efficiency during lean operation by up to 10 percent while decreasing the calibration effort compared to conventional engine control.
Towards Net-Zero: Comparative Analysis of Hydrogen Infrastructure Development in USA, Canada, Singapore, and Sri Lanka
Sep 2025
Publication
This paper compares national hydrogen (H2) infrastructure plans in Canada the United States (the USA) Singapore and Sri Lanka four countries with varying geographic and economic outlooks but shared targets for reaching net-zero emissions by 2050. It examines how each country approaches hydrogen production pipeline infrastructure policy incentives and international collaboration. Canada focuses on large-scale hydrogen production utilizing natural resources and retrofitted natural gas pipelines supplemented by carbon capture technology. The USA promotes regional hydrogen hubs with federal investment and intersectoral collaboration. Singapore suggests an innovation-based import-dominant strategy featuring hydrogen-compatible infrastructure in a land-constrained region. Sri Lanka maintains an import-facilitated pilot-scale model facilitated by donor funding and foreign collaboration. This study identifies common challenges such as hydrogen embrittlement leakages and infrastructure scalability as well as fundamental differences based on local conditions. Based on these findings strategic frameworks are proposed including scalability adaptability partnership policy architecture digitalization and equity. The findings highlight the importance of localized hydrogen solutions supported by strong international cooperation and international partnerships.
Dissociative Adsorption of Hydrogen in Hydrogen-Blended Natural Gas Pipelines: A First Principles and Thermodynamic Analysis
Jun 2025
Publication
This study employs first principles calculations and thermodynamic analyses to investigate the dissociative adsorption of hydrogen on the Fe(110) surface. The results show that the adsorption energies of hydrogen at different sites on the iron surface are −1.98 eV (top site) −2.63 eV (bridge site) and −2.98 eV (hollow site) with the hollow site being the most stable adsorption position. Thermodynamic analysis further reveals that under operational conditions of 25 ◦C and 12 MPa the Gibbs free energy change (∆G) for hydrogen dissociation is −1.53 eV indicating that the process is spontaneous under pipeline conditions. Moreover as temperature and pressure increase the spontaneity of the adsorption process improves thus enhancing hydrogen transport efficiency in pipelines. These findings provide a theoretical basis for optimizing hydrogen transport technology in natural gas pipelines and offer scientific support for mitigating hydrogen embrittlement improving pipeline material performance and developing future hydrogen transportation strategies and safety measures.
Design and Analysis of Small‑Scale Hydrogen Valleys Success Factors: A Stratified Network‑Based Hybrid Fuzzy Approach
Sep 2025
Publication
Hydrogen energy one of the renewable energy sources plays a crucial role in combating climate change since its usage aims to reduce carbon emissions and enhance energy security. As the global energy trend moves toward cleaner alternatives countries start to adapt their energy strategies. In this transition hydrogen is one of the energy sources with the potential to increase long-term energy security. Developing countries face challenges such as high energy import dependency rising industrial demand and the need for infrastructure modernization making hydrogen valleys one of the viable solutions since they integrate hydrogen production storage distribution and utilization at one facility. However establishing small-scale hydrogen valleys requires a comprehensive decision-making strategy consisting of technical financial environmental social and political factors while addressing uncertainties in the system. To systematically manage the process this study proposes a Z-numberbased fuzzy cognitive mapping approach which models the interdependencies among success factors supported by Z-number Decision-Making Trial and Evaluation Laboratory for structured prioritization with a multi-expert perspective. The results indicate that Financial Factors emerged as the most critical category with Government Incentives Infrastructure Investment Cost and Land Acquisition Cost ranking as the top three sub-success factors. Availability of Skilled Workforce and Regional Energy Supply followed in importance which demonstrates the importance of social and technical dimensions in the hydrogen valley development. These findings demonstrate the critical role of policy support infrastructure readiness and workforce availability in the design process. Sensitivity analyses are also conducted to present robustness of the given decisions for the analysis of the results. Based on the results and analyses possible implications based on the policy and practical dimensions are also discussed. By integrating fuzzy logic and Z-numbers the study aims to minimize loss of information enhances the analytical background for decision-making and provides a strategic roadmap for hydrogen valley development.
A Fuzzy Multi-Criteria Framework for Sustainability Assessment of Wind–Hydrogen Energy Projects: Method and Case Application
Oct 2025
Publication
This study develops a comprehensive framework for assessing the sustainability performance of wind power systems integrated with hydrogen storage (WPCHS). Unlike previous works that mainly emphasized economic or environmental indicators our approach incorporates a balanced set of economic environmental and social criteria supported by expert evaluation. To address the uncertainty in human judgment we introduce an interval-valued fuzzy TOPSIS model that provides a more realistic representation of expert assessments. A case study in Manjil Iran demonstrates the application of the model highlighting that project A4 outperforms other alternatives. The findings show that both economic factors (e.g. levelized cost of energy) and social aspects (e.g. poverty alleviation) strongly influence project rankings. Compared with earlier studies in Europe and the Middle East this work contributes by extending the evaluation scope beyond financial and environmental metrics to include social sustainability thereby enhancing decision-making relevance for policymakers and investors.
Capacity Configuration and Benefit Assessment of Deep-Sea Wind–Hydrogen System Considering Dynamic Hydrogen Price
Sep 2025
Publication
Against the backdrop of the global transition towards clean energy deep-sea wind-power hydrogen production integrates offshore wind with green hydrogen technology. Addressing the technical coupling complexity and the impact of uncertain hydrogen prices this paper develops a capacity optimization model. The model incorporates floating wind turbine output the technical distinctions between alkaline (ALK) electrolyzers and proton exchange membrane (PEM) electrolyzers and the synergy with energy storage. Under three hydrogen price scenarios the results demonstrate that as the price increases from 26 CNY/kg to 30 CNY/kg the optimal ALK capacity decreases from 2.92 MW to 0.29 MW while the PEM capacity increases from 3.51 MW to 5.51 MW. Correspondingly the system’s Net Present Value (NPV) exhibits an upward trend. To address the limitations of traditional methods in handling multi-dimensional benefit correlations and information ambiguity a comprehensive benefit evaluation framework encompassing economic technical environmental and social synergies was constructed. Sensitivity analysis indicates that the comprehensive benefit level falls within a relatively high-efficiency interval. The numerical characteristics an entropy value of 3.29 and a hyper-entropy of 0.85 demonstrate compact result distribution and robust stability validating the applicability and stability of the proposed offshore wind–hydrogen benefit assessment model.
Sustainable Aviation Fuels: A Review of Current Techno Economic Viability and Life Cycle Impacts
Oct 2025
Publication
Australia has set a new climate target of reducing emissions by 62–70% below 2005 levels by 2035 with sustainable aviation fuel (SAF) central to achieving this goal. This review critically examines techno-economic analysis (TEA) and life cycle assessment (LCA) of Powerto-Liquid (PtL) electrofuels (e-fuels) which synthesize atmospheric CO2 and renewable hydrogen (H2) via Fischer-Tropsch (FT) synthesis. Present PtL pathways require ~0.8 kg of H2 and 3.1 kg of CO2 per kg SAF with ~75% kerosene yield. While third-generation feedstocks could cut greenhouse gas emissions by up to 93% (as low as 8 gCO2e/MJ) real world reductions have been limited (~1.5%) due to variability in technology rollout and feedstock variability. Integrated TEA–LCA studies demonstrate up to 20% energy efficiency improvements and 40% cost reductions but economic viability demands costs below $3/kg. In Australia abundant solar resources vast transport networks and supportive policy frameworks present both opportunities and challenges. This review provides the first comprehensive assessment of PtL-FT SAF for Australian conditions highlighting that large-scale development will require technological advancement feedstock development infrastructure investment and coordinated policy support.
Risk Assessment of Offshore Wind–Solar–Current Energy Coupling Hydrogen Production Project Based on Hybrid Weighting Method and Aggregation Operator
Oct 2025
Publication
Under the dual pressures of global climate change and energy structure transition the offshore wind–solar–current energy coupling hydrogen production (OCWPHP) system has emerged as a promising integrated energy solution. However its complex multi-energy structure and harsh marine environment introduce systemic risks that are challenging to assess comprehensively using traditional methods. To address this we develop a novel risk assessment framework based on hesitant fuzzy sets (HFS) establishing a multidimensional risk criteria system covering economic technical social political and environmental aspects. A hybrid weighting method integrating AHP entropy weighting and consensus adjustment is proposed to determine expert weights while minimizing risk information loss. Two aggregation operators—AHFOWA and AHFOWG—are applied to enhance uncertainty modeling. A case study of an OCWPHP project in the East China Sea is conducted with the overall risk level assessed as “Medium.” Comparative analysis with the classical Cumulative Prospect Theory (CPT) method shows that our approach yields a risk value of 0.4764 closely aligning with the CPT result of 0.4745 thereby confirming the feasibility and credibility of the proposed framework. This study provides both theoretical support and practical guidance for early-stage risk assessment of OCWPHP projects.
A Comparative Study of Alternative Polymer Binders for the Hydrogen Evolution Reaction
Aug 2025
Publication
Given the economic industrial and environmental value of green dihydrogen (H2) optimization of water electrolysis as a means of producing H2 is essential. Binders are a crucial component of electrocatalysts yet they remain largely underdeveloped with a significant lack of standardization in the field. Therefore targeted research into the development of alternative binder systems is essential for advancing performance and consistency. Binders essentially act as the key to regulating the electrode (support)–catalyst–electrolyte interfacial junctions and contribute to the overall reactivity of the electrocatalyst assembly. Therefore alternative binders were explored with a focus on cost efficiency and environmental compatibility striving to achieve desirable activity and stability. Herein the alkaline hydrogen evolution reaction (HER) was investigated and the sluggish water dissociation step was targeted. Controlled hydrophilic poly(vinyl alcohol)-based hydrogel binders were designed for this application. Three hydrogel binders were evaluated without incorporated electrocatalysts namely PVA145 PVA145-blend-bPEI1.8 and PVA145-blend-PPy. Interestingly the study revealed that the hydrophilicity of the binders exhibited an enhancing effect on the observed activity resulting in improved performance compared to the commercial binder Nafion™. Notably the PVA145 system stands out with an overpotential of 224 mV at−10 mA·cm−2 (geometric) in 1.0 M KOH compared to the 238 mV exhibited by Nafion™. Inclusion of Pt as active material in PVA145 as binder exhibited a synergistic increase in performance achieving a mass activity of 1.174 A.cm−2.mg−1 Pt in comparison to Nafion™’s 0.344 A.cm−2.mg−1 Pt measured at−150 mV vs RHE. Our research aimed to contribute to the development of cost-effective and efficient binder systems stressing the necessity to challenge the dominance of the commercially available binders.
AI-driven Advances in Composite Materials for Hydrogen Storage Vessels: A Review
Sep 2025
Publication
This review provides a comprehensive examination of artificial intelligence methods applied to the design optimization and performance prediction of composite-based hydrogen storage vessels with a focus on composite overwrapped pressure vessels. Targeted at researchers engineers and industrial stakeholders in materials science mechanical engineering and renewable energy sectors the paper aims to bridge traditional mechanical modeling with evolving AI tools while emphasizing alignment with standardization and certification requirements to enhance safety efficiency and lifecycle integration in hydrogen infrastructure. The review begins by introducing HSV types their material compositions and key design challenges including high-pressure durability weight reduction hydrogen embrittlement leakage prevention and environmental sustainability. It then analyzes conventional approaches such as finite element analysis multiscale modeling and experimental testing which effectively address aspects like failure modes fracture strength liner damage dome thickness winding angle effects crash behavior crack propagation charging/discharging dynamics burst pressure durability reliability and fatigue life. On the other hand it has been shown that to optimize and predict the characteristics of hydrogen storage vessels it is necessary to combine the conventional methods with artificial intelligence methods as conventional methods often fall short in multi-objective optimization and rapid predictive analytics due to computational intensity and limitations in handling uncertainty or complex datasets. To overcome these gaps the paper evaluates hybrid frameworks that integrate traditional techniques with AI including machine learning deep learning artificial neural networks evolutionary algorithms and fuzzy logic. Recent studies demonstrate AI’s efficacy in failure prediction design optimization to mitigate structural risks structural health monitoring material property evaluation burst pressure forecasting crack detection composite lay-up arrangement weight minimization material distribution enhancement metal foam ratio optimization and optimal material selection. By synthesizing these advancements this work underscores AI’s potential to accelerate development reduce costs and improve HSV performance while advocating for physics-informed models robust datasets and regulatory alignment to facilitate industrial adoption.
Biohydrogen Production from Industrial Waste: The Role of Pretreatment Methods
Oct 2025
Publication
This study aimed to investigate the effectiveness of dark fermentation in biohydrogen production from agro-industrial wastes including apple pomace brewer’s grains molasses and potato powder subjected to different pretreatment methods. The experiments were conducted at a laboratory scale using 1000 cm3 anaerobic reactors at a temperature of 35 ◦C and anaerobic sludge as the inoculum. The highest yield of hydrogen was obtained from pre-treated apple pomace (101 cm3/g VS). Molasses a less complex substrate compared to the other raw materials produced 25% more hydrogen yield following pretreatment. Methanogens are sensitive to high temperatures and low-pH conditions. Nevertheless methane constituted 1–6% of the total biogas under these conditions. The key factor was appropriate treatment of the inoculum to limit competition from methanogens. Increasing the inoculum dose from 150 cm3/dm3 to 250 cm3/dm3 had no further effect on biogas production. The physicochemical parameters and VFA data confirmed the stability and usefulness of activated sludge as a source of microbial cultures for H2 production via dark fermentation.
Sustainable Refining: Integrating Renewable Energy and Advanced Technologies
Aug 2025
Publication
Crude oil distillation is one of the most energy-intensive processes in petroleum refining consuming up to 20% of total refinery energy. Improving the energy efficiency of crude distillation units (CDUs) is essential for reducing costs lowering emissions and achieving sustainable refining. Current studies often examine energy savings operational flexibility or renewable energy integration separately. This review brings these aspects together focusing on heat integration advanced control systems and renewable energy options such as solar-assisted preheating and green hydrogen. Advanced column designs including dividing-wall and hybrid systems can cut energy use by 15–30% while AI-based optimization improves process stability and flexibility. Solar-assisted preheating can reduce fossil fuel demand by up to 20% and green hydrogen offers strong potential for decarbonization. Our findings highlight that integrated strategies including advanced simulation tools and machine learning significantly improve CDU performance. We recommend exploring hybrid algorithms renewable energy integration and sustainable technologies to address these challenges and achieve long-term environmental and economic benefits.
Modeling and Optimization Control of SOEC with Flexible Adjustment Capabilities
Jul 2025
Publication
Due to the random fluctuations in power experienced by high-temperature green electric hydrogen production systems further deterioration of spatial distribution characteristics such as temperature voltage/current and material concentration inside the solid oxide electrolysis cell (SOEC) stack may occur. This has a negative impact on the system’s flexibility and the corresponding control capabilities. In this paper based on the SOEC electrolytic cell model a comprehensive optimization method using an adaptive incremental Kriging surrogate model is proposed. The reliability of this method is verified by accurately analyzing the dynamic performance of the SOEC and the spatial characteristics of various physical quantities. Additionally a thermal dynamic analysis is performed on the SOEC and an adaptive time-varying LPV-MPC optimization control method is established to ensure the temperature stability of the electrolysis cell stack aiming to maintain a stable efficient and sustainable SOEC operation. The simulation analysis of SOEC hydrogen production adopting a variable load operation has demonstrated the advantages of this method over conventional PID control in stabilizing the temperature of the stack. It allows for a rapid adjustment in the electrolysis voltage and current and improves electrolysis efficiency. The results highlighted that the increase in the electrolysis load increases the current density while the water vapor electrolysis voltage and H2 flow rate significantly decrease. Finally the SOEC electrolytic hydrogen production module is introduced for optimization scheduling of energy consumption in Xinjiang China. The findings not only confirmed that the SOEC can transition to the current load operating point at each scheduling period but also demonstrated higher effectiveness in stabilizing the stack temperature and improving electrolysis efficiency.
Influence of Hydrogen-Based Direct Reduction Shaft Furnace Interior Structure on Shaft Furnace Performance
Oct 2025
Publication
Hydrogen-based direct reduction of iron ore is a promising route to reduce CO2 emissions in steelmaking where uniform particle flow inside shaft furnaces is essential for efficient operation. In this study a full-scale three-dimensional Discrete Element Method (DEM) model of a shaft furnace was developed to investigate the effects of a diverter device on granular flow. By systematically varying the radial width and top/bottom diameters of the diverter particle descent velocity residence time compressive force distribution and collision energy dissipation were analyzed. The results demonstrate that introducing a diverter effectively suppresses funnel flow prolongs residence time and improves radial flow uniformity. Among the tested configurations the smaller central diameter diverter showed the most favorable performance achieving a faster and more uniform descent reduced compressive force concentration and lower collision energy dissipation. These findings highlight the critical role of diverter design in regulating particle dynamics and provide theoretical guidance for optimizing shaft furnace structures to enhance the efficiency of hydrogen-based direct reduction processes.
Zero-emission Traction for Rail
Jul 2025
Publication
Replacing the energy density and convenience of diesel fuel for all forms of fossil fuel-powered trains presents significant challenges. Unlike the traditional evolutions of rail which has largely self-optimised to different fuels and cost structures over 150 years the challenges now present with a timeline of just a few decades. Fortunately unlike the mid-1800s simulation and modelling tools are now quite advanced and a full range of scenarios of operations and train trips can be simulated before new traction systems are designed. Full trip simulations of large heavy haul trains or high speed passenger trains are routinely completed controlled by emulations of human drivers or automated control systems providing controls of the “virtual train”. Recent developments in digital twins can be used to develop flexible and dynamic models of passenger and freight rail systems to support the new complexities of decarbonisation efforts. Interactions between many different traction components and the train multibody system can be considered as a system of systems. Adopting this multi-modelling paradigm enables the secure and integrated interfacing of diverse models. This paper demonstrates the application of the multi-modelling approach to develop digital twins for rail decarbonisation traction and it presents physics-based multi-models that include key components required for studying rail decarbonisation problems. Specifically the challenge of evaluating zero-emission options is addressed by adding further layers of modelling to the existing fully detailed multibody dynamics simulations. The additional layers detail control options energy storage the alternate traction system components and energy management systems. These traction system components may include both electrical system and inertia dynamics models to accurately represent the driveline and control systems. This paper presents case study examples of full trip scenarios of both long haul freight trains and higher speed passenger trains. These results demonstrate the many complex scenarios that are difficult to anticipate. Flowing on from this risks can be assessed and practical designs of zero-emission systems can be proposed along with the required recharging or refuelling systems.
Maximization and Efficient Production Rates of Different Zero Carbon Electrofuels using Dry Alkaline Electroyzers
Aug 2025
Publication
The present work focused on the comparison between HHO and hydrogen electrolyzers in design gas production and various parameters which affect the performance and efficiency of alkaline electrolyzers. The primary goal is to generate the highest possible hydrogen and HHO gas flow rates. Hydrogen and HHO were produced using 3 mm electrode of stainless steel 316L with 224 cm2 surface area. Hydroxy and hydrogen rates were affected by electrolyte content cell connection electric current operating time electrolyte temperature and voltage. Maximum HHO generation values were 1020 1076 1125 and 1175 mL min−1 n at 5 10 15 and 20 g L−1 of sodium hydroxide (NaOH) with supply currents of 15 15.3 15.6 and 16 A respectively. Once it stabilized after 30 min the temperature increased to 26 30 35 and 38 °C respectively and remained there. With currents of 18 18.45 18.7 19.2 19.5 and 19.8 A hydrogen output peak values after 60 min. stayed constant at 680 734 785 846 897 and 945 mL min-1. at 5 10 15 and 20 g L−1 NaOH catalyst concentrations. At 5 10 15 and 20 g L−1 catalyst ratios the temperatures were elevated to constant values of 28.5 32 37.9 40.5 41.4 and 43 °C respectively. With cell design [4C3A19N] electrolyte concentration of 5 g L−1 NaOH and current of 14 A maximum HHO productivity was 866 mL min−1. and 74.23% efficiency. In a cell design of [4C5A17N] with catalyst content of 10 g L−1 maximum productivity was 680 mL min−1 for hydrogen and highest production efficiency of 72.85% was attained at 18 A.
Optimization Using RSM of Combined Cycle of Power, NG, and Hydrogen Production by a Bi-geothermal Energy Resource and LNG Heat Sink
Aug 2025
Publication
This study presents a comprehensive optimization of a tri-generation system that integrates dual geothermal wells Liquefied Natural Gas (LNG) cold energy recovery and hydrogen production using an advanced Response Surface Methodology (RSM) approach. The system combines two geothermal wells with different temperature profiles power generation via an Organic Rankine Cycle (ORC) and hydrogen production through a Proton Exchange Membrane (PEM) electrolyzer enhanced by integrated LNG regasification for improved energy recovery. The primary novelty of this work lies in the first application of RSM for multi-objective optimization of geothermal-based tri-generation systems moving beyond the conventional single-objective approaches. A 40-run experimental design is employed to simultaneously optimize three critical performance indicators: exergy efficiency power-specific cost and hydrogen production rate considering six key operating parameters. The RSM framework enables systematic exploration of parameter interactions and delivers statistically validated predictive models offering a robust and computationally efficient optimization strategy. The optimized system achieves outstanding performance with an exergy efficiency of 44.60% a competitive power-specific cost of 19.70 $/GJ and a hydrogen production rate of 5.15 kg/hr. Comparative analysis against prior studies confirms the superiority of the RSM-based approach demonstrating a 1% improvement in exergy efficiency (44.60% vs. 44.16%) a significant 44.1% increase in hydrogen production rate (5.15 kg/hr vs. 3.575 kg/hr) and a 0.81% reduction in power-specific cost compared to genetic algorithm-based optimization.
Research on the Optimization Decision Method for Hydrogen Load Aggregators to Participate in Peak Shaving Market
Oct 2025
Publication
Zhenya Lei,
Libo Gu,
Zhen Hu and
Tao Shi
This article takes the perspective of Hydrogen Load Aggregator (HLA) to optimize the declaration strategy of peak shaving market improve the flexible regulation capability of power system and HLA economy as the research objectives and proposes an optimization strategy method for HLA to participate in peak shaving market. Firstly an improved Convolutional Neural Networks–Long Short-Term Memory (CNN-LSTM) time series prediction model is developed to address peak shaving demand uncertainty. Secondly a bidding strategy model incorporating dynamic pricing is constructed by comprehensively considering electrolyzer regulation costs market supply–demand relationships and system constraints. Thirdly a market clearing model for peak shaving markets with HLA participation is designed through analysis of capacity contribution and marginal costs among different regulation resources. Finally the capacity allocation model is designed with the goal of minimizing the total cost of peak shaving among various stakeholders within HLA and the capacity won by HLA in the peak shaving market is reasonably allocated. Simulations conducted on a Python3.12-based experimental platform demonstrate the following: the improved CNN-LSTM model exhibits strong adaptability and robustness the bidding model effectively enhances HLA market competitiveness and the clearing model reduces system operator costs by 5.64%.
Investigating Ammonia as an Alternative Marine Fuel: A SWOT Analysis Using the Best–Worst Method
Oct 2025
Publication
The shipping industry remains heavily dependent on heavy fuel oils which account for approximately 77% of fuel consumption and contribute significantly to greenhouse gas (GHG) emissions. In line with the IMO’s decarbonization targets ammonia has emerged as a promising carbon-free alternative. This study evaluates the strategic viability of ammonia especially green production as a marine fuel through a hybrid SWOT–Best–Worst Method (BWM) analysis combining literature insights with expert judgment. Data were collected from 17 maritime professionals with an average of 15.7 years of experience ensuring robust sectoral representation and methodological consistency. The results highlight that opportunities hold the greatest weight (0.352) particularly the criteria “mandatory carbonfree by 2050” (O3:0.106) and “ammonia–hydrogen climate solution” (O2:0.080). Weaknesses rank second (0.270) with “higher toxicity than other marine fuels” (W5:0.077) as the most critical concern. Strengths (0.242) underscore ammonia’s advantage as a “carbonfree and sulfur-free fuel” (S1:0.078) while threats (0.137) remain less influential though “costly green ammonia” (T3:0.035) and “uncertainty of green ammonia” (T1:0.034) present notable risks. Overall the analysis suggests that regulatory imperatives and environmental benefits outweigh safety technical and economic challenges. Ammonia demonstrates strong potential to serve as viable marine fuel in achieving the maritime sector’s long-term decarbonization goals.
Underground Hydrogen Storage in Salt Cavern: A Review of Advantages, Challenges, and Prospects
Jun 2025
Publication
The transition to a sustainable energy future hinges on the development of reliable large-scale hydrogen storage solutions to balance the intermittency of renewable energy and decarbonize hard-to-abate industries. Underground hydrogen storage (UHS) in salt caverns emerged as a technically and economically viable strategy leveraging the unique geomechanical properties of salt formations—including low permeability self-healing capabilities and chemical inertness—to ensure safe and high-purity hydrogen storage under cyclic loading conditions. This review provides a comprehensive analysis of the advantages of salt cavern hydrogen storage such as rapid injection and extraction capabilities cost-effectiveness compared to other storage methods (e.g. hydrogen storage in depleted oil and gas reservoirs aquifers and aboveground tanks) and minimal environmental impact. It also addresses critical challenges including hydrogen embrittlement microbial activity and regulatory fragmentation. Through global case studies best operational practices for risk mitigation in real-world applications are highlighted such as adaptive solution mining techniques and microbial monitoring. Focusing on China’s regional potential this study evaluates the hydrogen storage feasibility of stratified salt areas such as Jiangsu Jintan Hubei Yunying and Henan Pingdingshan. By integrating technological innovation policy coordination and cross-sector collaboration salt cavern hydrogen storage is poised to play a pivotal role in realizing a resilient hydrogen economy bridging the gap between renewable energy production and industrial decarbonization.
Evaluation of Passenger Train Safety in the Event of a Liquid Hydrogen Release from a Freight Train in a Tunnel Along an Italian High-Speed/High-Capacity Rail Line
Oct 2025
Publication
The global shift towards cleaner energy sources is driving the adoption of hydrogen as an environmentally friendly alternative to fossil fuels. Among the forms currently available Liquid Hydrogen (LH2) offers high energy density and efficient storage making it suitable for large-scale transport by rail. However the flammability of hydrogen poses serious safety concerns especially when transported through confined spaces such as railway tunnels. In case of an accidental LH2 release from a freight train the rapid accumulation and potential ignition of hydrogen could cause catastrophic consequences especially if freight and passenger trains are present simultaneously in the same tunnel tube. In this study a three-dimensional computational fluid dynamics model was developed to simulate the dispersion and explosion of LH2 following an accidental leak from a freight train’s cryo-container in a single-tube double-track railway tunnel when a passenger train queues behind it on the same track. The overpressure results were analyzed using probit functions to estimate the fatality probabilities for the passenger train’s occupants. The analysis suggests that a significant number of fatalities could be expected among the passengers. However shorter users’ evacuation times from the passenger train’s wagons and/or longer distances between the two types of trains might reduce the number of potential fatalities. The findings by providing additional insight into the risks associated with LH2 transport in railway tunnels indicate the need for risk mitigation measures and/or traffic management strategies.
Economic and Environmental Assessment of Different Energy Storage Methods for Hybrid Energy Systems
Jul 2025
Publication
Due to the environmental impact of fossil fuels renewable energy such as wind and solar energy is rapidly developed. In energy systems energy storage units are important which can regulate the safe and stable operation of the power system. However different energy storage methods have different environmental and economic impacts in renewable energy systems. This paper proposed three different energy storage methods for hybrid energy systems containing different renewable energy including wind solar bioenergy and hydropower meanwhile. Based on Homer Pro software this paper compared and analyzed the economic and environmental results of different methods in the energy system through the case of a residential community in Baotou City. The result showed that (1) the use of batteries as energy storage in communities posed the lowest energy costs whose NPC was $197396 and LCOE was $0.159 consisting of 20 batteries 19.3 kW PV 6 wind turbines a 12.6 kW converter. (2) Lower fuel cell prices mean lower NPC and the increase in the Electric Load Scaled Average implied a decrease in LCOE and the increase of the NPC. (3) The use of fuel cells also had impacts on the environment such as resulting CO2 and SO2.
Process Integration and Exergy-based Assessment of High-temperature Solid Oxide Electrolysis Configurations
Sep 2025
Publication
Solid oxide electrolysis (SOEL) is considered an efficient option for largely emission-free hydrogen production and thus for supporting the decarbonization of the process industry. The thermodynamic advantages of high-temperature operation can be utilized particularly when heat integration from subsequent processes is realized. As the produced hydrogen is usually required at a higher pressure level the operating pressure of the electrolysis is a relevant design parameter. The study compares pressurized and near-atmospheric designs of 126 MW SOEL systems with and without the integration of process heat from a downstream ammonia synthesis and the inefficiencies that occur in the processes. Furthermore process improvements by sweep-air utilization are investigated. Pinch analysis is applied to determine the potential of internal heat recovery and the minimum external heating and cooling demand. It is shown that pressurized SOEL operation does not necessarily decrease the overall power consumption for compression due to the high power requirement of the sweep-air compressor. The exergetic efficiencies of the standalone SOEL processes achieve similar values of = 81 %. Results further show that integrating the heat of reaction from ammonia synthesis can replace almost the entire electrically supplied thermal energy thereby improving the overall exergetic efficiency by up to 3.5 percentage points. However the exergetic efficiency strongly depends on the applied air ratio. The highest exergetic efficiency of 86 % can be achieved by employing sweep-air utilization with an expander. The results demonstrate that integrating downstream process heat and applying sweep-air utilization can significantly enhance overall efficiency and thus reduce external energy requirements.
Design and Assessment of an Integrated PV-based Hydrogen Production Facility
Jun 2025
Publication
This study develops a photovoltaic (PV)-based hydrogen production system specifically designed for university campuses which is expected to lead in sustainability efforts. The proposed system aims to meet the electricity demand of a Hydrogen Research Center while supplying energy to an electric charging station and a hydrogen refueling station for battery-electric and fuel-cell electric vehicles operating within the campus. In this integrated system the electricity generation capacity of PV panels installed on the research center’s roof is determined and the surplus electricity after meeting the energy demand is allocated to cover the varying proportions needed for both electric charging station and hydrogen production system. The green hydrogen produced by the system is compressed to 100 350 and 700 bar with intermediate cooling stages where the heat generated at the compressor outlet is absorbed by a cooling fluid and repurposed in a condenser for domestic hot water production. A full thermodynamic analysis of this entirely renewable energy-powered system is conducted by considering a 9-hour daily operational period from 8:00 AM to 5:00 PM. The average incoming solar radiation is determined to be 484.63 W/m2 resulting in an annual electricity generation capacity of 494.86 MWh. Based on the assumptions and data considered the energy and exergy efficiencies of the proposed system are calculated as 17.71 % and 17.01 % respectively with an annual hydrogen production capacity of 3.642 tons. Various parametric studies are performed for varying solar intensity values and PV surface areas to investigate how the overall system capacities and efficiencies are affected. The results show that an integration of hydrogen production systems with solar energy offers significant advantages including mitigating intermittency issues found in standalone renewable systems reducing carbon emissions compared to fossil-based alternatives and enhancing the flexibility of energy systems.
Grid Infrastructure and Renewables Integration for Singapore Energy Transition
Oct 2025
Publication
Considering rising environmental concerns and the energy transition towards sustainable energy Singapore’s power sector stands at a crucial juncture. This study explores the integration of grid infrastructure with both generated and imported renewable energy (RE) sources as a strategic pathway for the city-state’s energy transition to reach net-zero carbon emissions by 2050. Employing a combination of simulation modeling and data analysis for energy trading and advanced energy management technologies we examine the current and new grid infrastructure’s capacity to assimilate RE sources particularly solar photovoltaic and energy storage systems. The findings reveal that with strategic upgrades and smart grid technologies; Singapore’s grid can efficiently manage the variability and intermittency of RE sources. This integration is pivotal in achieving a higher penetration of renewables as well as contributing significantly to Singapore’s commitment to the Paris Agreement and sustainable development goals. While the Singapore’s power system has links to the Malay Peninsula the planned ASEAN regional interconnection might alter the grid operation in Singapore and possibly make Singapore a new green energy hub. The study also highlights the key challenges and opportunities associated with cross-border energy trade with ASEAN countries including the need for harmonized regulatory frameworks and incentives to foster public–private partnerships. The insights from this study could guide policymakers industry stakeholders and researchers offering a roadmap for a sustainable energy transition in Singapore towards meeting its 2050 carbon emission goals.
Techno-economic and Environmental Optimization of Hydrogen-based Hybrid Energy Systems for Remote Off-grid Australian Communities
Jun 2025
Publication
This study presents a techno-economic and environmental optimization of hydrogen-based hybrid energy systems (HESs) for Broken Hill City Council in New South Wales Australia. Two configurations are evaluated: Configuration 1 includes solar PV battery fuel cell electrolyzer and hydrogen storage while Configuration 2 includes solar PV fuel cell electrolyzer and hydrogen storage but excludes the battery. The system is optimized using advanced metaheuristic algorithms such as Harris Hawks Algorithm (HHA) Red-Tailed Hawk Algorithm and Non-Dominated Sorting Genetic Algorithm-II while ensuring real-time supply–demand balance and system stability through a robust energy management strategy. This integrated approach simultaneously determines the optimal sizes of PV arrays battery storage (where applicable) fuel cells electrolyzers and hydrogen storage units and maintains reliable energy supply. Results show that HHA Configuration 1 achieves the lowest net present cost of $338111 a levelized cost of electricity of $0.185/kWh and a levelized cost of hydrogen of $4.60/kg. Sensitivity analysis reveals that PV module and hydrogen storage costs significantly impact system economics while improving fuel cell efficiency from 40% to 60% can reduce costs by up to 40%. Beyond cost-effectiveness life cycle analysis demonstrates annual CO2 emission reductions exceeding 500000 kg compared to an equivalent diesel generator system meeting the same load demand. Socio-economic assessments further indicate that the HES can support improvements in the Human Development Index by enhancing access to healthcare education and economic opportunities while also creating local jobs in PV installation battery maintenance and hydrogen infrastructure. These findings establish hydrogen-based HES as a scalable cost-effective and environmentally sustainable solution for energy access in remote areas.
Opportunities for Emission Reduction in the Transformation of Petroleum Refining
Sep 2025
Publication
Crude oil accounts for approximately 40% of global energy consumption and the refining sector is a major contributor to greenhouse gas (GHG) emissions particularly through the production of hard-to-abate fuels such as aviation fuel and fuel oil. This study disaggregates the refinery into its key process units to identify decarbonization opportunities along the entire production chain. Units are categorized into combustion-based processes— including crude and vacuum distillation hydrogen production coking and fluid catalytic cracking—and non-combustion processes which exhibit lower emission intensities. The analysis reveals that GHG emissions can be reduced by up to 60% with currently available technologies without requiring major structural changes. Electrification residual heat recovery renewable hydrogen for desulfurization and process optimization through digital twins are identified as priority measures many of which are also economically viable in the short term. However achieving full decarbonization and alignment with net-zero targets will require the deployment of carbon capture technologies. These results highlight the significant potential for emission reduction in refineries and reinforce their strategic role in enabling the transition toward low-carbon fuels.
Optimal Configuration of Hydrogen Energy Storage Systems Considering the Operational Efficiency Characteristics of Multi-Stack Electrolyzers
Sep 2025
Publication
Enhancing the economics of microgrid systems and achieving a balance between energy supply and demand are critical challenges in capacity allocation research. Existing studies often neglect the optimization of electrolyzer efficiency and multi-stack operation leading to inaccurate assessments of system benefits. This paper proposes a capacity allocation model for wind-PV-hydrogen integrated microgrid systems that incorporates hydrogen production efficiency optimization. This paper analyzes the relationship between the operating efficiency of the electrolyzer and the output power regulates power generation-load mismatches through a renewable energy optimization model and establishes a double-layer optimal configuration framework. The inner layer optimizes electrolyzer power allocation across periods to maximize operational efficiency while the outer layer determines configuration to maximize daily system revenue. Based on the data from a demonstration project in Jiangsu Province China a case study is conducted to verify that the proposed method can improve system benefits and reduce hydrogen production costs.
Numerical Simulation of Natural Gas/Hydrogen Combustion in a Novel Laboratory Combustor
Jun 2025
Publication
Hydrogen is a promising fuel in the current transition to zero-net CO2 emissions. However most practical combustion equipment is not yet ready to burn pure hydrogen without adaptation. In the meantime blending hydrogen with natural gas is an interesting option. This work reports a computational study of the performance of swirl-stabilized natural gas/hydrogen flames in a novel combustion chamber design. The combustor employs an air-staging strategy introducing secondary air through a top-mounted plenum in a direction opposite to the fuel jet. The thermal load is fixed at 5 kW and the effects of fuel composition (hydrogen molar fraction ranging from zero to one) excess air coefficient (λ = 1.3 1.5 or 1.7) and primary air fraction (α = 50–100%) on the velocity temperature and emissions are analysed. The results show that secondary air changes the flow pattern reducing the central recirculation zone and lowering the temperature in the primary reaction zone while increasing it further downstream. Secondary air improves the performance of the combustor for pure hydrogen flames reducing NO emissions to less than 50 ppm for λ = 1.3 and 50% primary air. For natural gas/hydrogen blends a sufficiently high excess air level is required to keep CO emissions within acceptable limits.
Increasing Public Acceptance of Fuel Cell Vehicles in Germany: A Perspective on Pioneer Users
Jun 2025
Publication
Fuel cell vehicles (FCVs) represent an intriguing alternative to battery electric vehicles (BEVs). While the acceptance of BEVs has been widely discussed acceptance-based recommendations for promoting adoption of FCVs remain ambiguous. This paper aims to improve our understanding by reporting results from a pioneer study based on the standardized Unified Theory of Acceptance and Use of Technology 2 (UTAUT2). The sample consists of n1 = 258 registered customers of H2mobility in Germany. For effect control another n2 = 294 participant sample was drawn from the baseline population. Data were analyzed using SmartPLS 4 and importance-performance mapping (IPMA). Results demonstrate that FCV acceptance primarily relies on Perceived Usefulness Perceived Conditions and Normative Influence while surprisingly hypotheses involving Perceived Risk and Green Attitude are rejected. Finally a discussion reveals ways to increase the level of public acceptance. Three practical strategies emerge. For future acceptance analyses the authors suggest incorporating the young concept of ‘societal readiness’.
A Comprehensive Review of Advances in Bioenergy including Emerging Trends and Future Directions
Aug 2025
Publication
Bioenergy is a promising alternative to fossil fuels-based energy with significant potential to transform global energy systems and promote environmental sustainability. This review provides a comprehensive overview of the evolution of bioenergy emphasizing its role in the global transition to sustainable energy. It explores a diverse range of biomass sources including forest and agricultural residues algae and industrial by-products and their conversion into energy via thermochemical biochemical and physicochemical pathways. The paper also highlights recent technological advancements and assesses the environmental sustainability of bioenergy systems. Additionally it examines key challenges hindering bioenergy development such as feedstock logistics technological limitations economic viability and policy gaps that need resolution to fully realise its potential. By synthesizing literature from 2010 to 2025 the review identifies strategic priorities for research and deployment aiming to inform efforts that align bioenergy utilization with global decarbonization goals.
Optimizing Vietnam's Hydrogen Strategy: A Life-cycle Perspective on Technology Choices, Environmental Impacts, and Cost Trade-offs
Sep 2025
Publication
Vietnam recognizes hydrogen as a key fuel for decarbonization under its National Hydrogen Strategy. Here we quantified the environmental and economic performance of Vietnam’s optimal hydrogen-production pathways by evaluating combinations of green and blue hydrogen under varying demand scenarios using life-cycle assessment and optimization modeling techniques. The environmental performance of hydrogen production proved highly sensitive to the electricity source with water electrolysis powered by renewable energy offering the most favorable outcomes. Although green hydrogen production reduced carbon emissions it shifted environmental burdens toward increased resource extraction. Producing 20 Mt of hydrogen by 2050 would require 741.56 TWh of electricity 178 Mt of water and USD 294 billion in investment and it would emit 50.48 Mt CO2. These findings highlight the importance of strategic hydrogen planning and resource strategy aligned with national priorities for energy transition to navigate trade-offs among technology selection emissions costs and resource consumption.
Investigating the Effects of Flow Regime on Hydrogen Transport in Salt Rock
Jun 2025
Publication
Underground hydrogen storage (UHS) in salt caverns is emerging as a promising solution for the transition to a sustainable energy future. However a thorough understanding of hydrogen flow mechanisms through salt rock is essential to ensure safe and efficient storage operations. In this study we conducted hydrogen flow experiments in salt rocks using the pressure pulse decay (PPD) method covering a range of hydrogen pore pressures from 0.4 MPa to 7.5 MPa within the slip and transitional flow regimes (Knudsen numbers between 0.04 and 1.5). The Knudsen numbers were determined by measuring the pore size distribution (PSD) of the salt rock samples and assigning an average pore size to each sample based on the measured PSD. Our results indicate that the intrinsic permeability of the tested salt rock samples ranges from 5 × 10− 21 m2 to 1.0 × 10− 20 m2 . However a significant enhancement in apparent permeability up to 10 times the intrinsic permeability was observed particularly at lower pressures. This permeability enhancement is attributed to the nanoscale pore structure of salt rocks where the mean free path of hydrogen becomes comparable to the pore sizes leading to a shift from slip flow to the transitional flow regime. The results further reveal that the first-order slip model underestimates the apparent permeability in the transitional flow regime despite its satisfactory accuracy in the slip region. Moreover the higher-order slip model demonstrates acceptable accuracy across both the slip and transitional flow regimes.
Alternative Fuels in Aero Engine Performance Calculations
Oct 2025
Publication
This paper presents a method for gas turbine performance calculations with alternative fuels with a particular focus on their use in aircraft engines. The effects of various alternative aviation fuels on fuel consumption CO2 emissions and contrail formation are examined in a comparative study. We use the GasTurb performance software and calculate heat release and hot section gas properties using a chemical equilibrium solver. Fuels with complex compositions are included in the calculation via surrogates of a limited number of known species that mimic the relevant properties of the real fuel. An automated method is used for the fuel surrogate formulation. We compare the results of this rigorous approach with the simplified approach of calculating the heat release using an alternative fuel’s heating value while still using the gas properties of conventional Jet A-1. The results show that the latter approach systematically overpredicts fuel consumption by up to 0.2% for aromaticsfree synthetic kerosene (e.g. “biofuels”). Overall aircraft engines running on alternative fuels tend to be more fuel efficient due to their often higher hydrogen contents and thus fuel heating values. We find reductions in fuel consumption of up to 2.8% during cruise when using aromatics-free synthetic kerosene. We further assess how alternative fuels affect contrail formation based on the Schmidt-Appleman criterion. Contrails can form 200 m lower under cruise conditions when burning aromatics-free synthetic kerosene instead of Jet A-1 with identical thrust requirements and under the same atmospheric conditions mainly due to their higher hydrogen content. In summary we present a flexible yet easy-to-use method for studying fuel effects in performance calculations that avoids small but systematic errors by rigorously calculating the heat release and hot section gas properties for each fuel.
Numerical Investigation of Hydrogen Leakage Quantification and Dispersion Characteristics in Buried Pipelines
Sep 2025
Publication
As a clean energy carrier hydrogen is essential for global low-carbon energy transitions due to its unique combination of safe transport properties and energy density. This investigation employs computational fluid dynamics (ANSYS Fluent) to systematically characterize hydrogen dispersion through soil media from buried pipelines. The research reveals three fundamental insights: First leakage orifices smaller than 2 mm demonstrate restricted hydrogen migration regardless of directional orientation. Second dispersion patterns remain stable under both low-pressure conditions (below 1 MPa) and minimal thermal gradients with pipeline temperature variations limited to 63 K and soil fluctuations under 40 K. Third dispersion intensity increases proportionally with higher leakage pressures (exceeding 1 MPa) greater soil porosity and larger particle sizes while inversely correlating with burial depth. The study develops a predictive model through Sequential Quadratic Programming (SQP) optimization demonstrating exceptional accuracy (mean absolute error below 10%) for modeling continuous hydrogen flow through moderateporosity soils under medium-to-high pressure conditions with weak inertial effects. These findings provide critical scientific foundations for designing safer hydrogen transmission infrastructure establishing robust risk quantification frameworks and developing effective early-warning systems thereby facilitating the practical implementation of hydrogen energy systems.
Efficiently Coupling Water Electrolysis with Solar PV for Green Hydrogen Production
Aug 2025
Publication
Solar-driven water electrolysis has emerged as a prominent technology for the production of green hydrogen facilitated by advancements in both water electrolyzers and solar cells. Nevertheless the majority of integrated solar-to-hydrogen systems still struggle to exceed 20% efficiency particularly in large-scale applications. This limitation arises from suboptimal coupling methodologies and system-level inefficiencies that have rarely been analyzed. To address these challenges this study investigates the fundamental principles of solar hydrogen production and examines key energy losses in photovoltaic-electrolyzer systems. Subsequently it systematically discusses optimization strategies across three dimensions: (1) enhancing photovoltaic (PV) system output under variable irradiance (2) tailoring electrocatalysts and electrolyzer architectures for high-performance operation and (3) minimizing coupling losses through voltage-matching technologies and energy storage devices. Finally we review existing large-scale solar hydrogen infrastructure and propose strategies to overcome barriers related to cost durability and scalability. By integrating material innovation with system engineering this work offers insights to advance solar-powered electrolysis toward industrial applications.
Liquid Hydrogen Application for Aero-Engine More-Electrical System: Current Status, Challenges and Future Prospects
Mar 2025
Publication
The integration of more-electric technologies into aero-engines has revolutionized their multi-power architectures substantially improving system maintainability and operational reliability. This advancement has established more-electric systems as a cornerstone of modern aerospace electrification research. Concurrently liquid hydrogen (LH2) emerges as a transformative solution for next-generation power generation systems particularly in enabling the transition from 100 kW to megawatt-class propulsion systems. Beyond its superior energy density LH2 demonstrates dual functionality in thermal management: it serves as both an efficient coolant for power electronics (e.g. controllers) and a cryogenic source for superconducting motor applications. This study systematically investigates the electrification pathway for LH2-fueled aero-engine multi-electric systems. First we delineate the technical framework elucidating its architectural characteristics and associated challenges. Subsequently we conduct a comprehensive analysis of three critical subsystems including LH2 storage and delivery systems cryogenic cooling systems for superconducting motors and Thermal management systems for high-power electronics. Finally we synthesize current research progress and propose strategic directions to accelerate the development of LH2-powered more-electric aero-engines addressing both technical bottlenecks and future implementation scenarios.
A Critical Review of China's Hydrogen Supply Chain and Equipment
Sep 2025
Publication
China’s dual-carbon goals have positioned hydrogen as a central pillar of its energy transition. This review examines the recent development of China’s hydrogen supply chain with particular focus on manufacturing technologies for alkaline electrolysers high-pressure cylinders and diaphragm compressors. In 2024 China produced 36.5 million tons of hydrogen of which 77 % was grey and only 1 % derived from electrolysis. Storage and transportation account for nearly 30 % of end-use costs while reliance on imported compressors increases refuelling station expenses by approximately 40 %. We identify key bottlenecks including limited electrolyser efficiency the high cost of carbon fibres for Type III/IV cylinders and insufficient domestic capacity for highreliability compressors. To address these challenges targeted advances are proposed: membrane materials with engineered hydrophilicity advanced surface modifications and hydrophilic inhibitors; liner design incorporating grooved-liner braided layers with double-fibre configurations; and a three-layer diaphragm compressor architecture. By consolidating fragmented studies this review provides the integrated manufacturing perspective on China’s hydrogen supply chain offering both scientific insights and practical guidance for accelerating costeffective large-scale low-carbon hydrogen deployment.
Hydrogen Storage Systems at Ports for Enhanced Safety and Sustainability: A Review
Sep 2025
Publication
With the increasing demand for clean energy and the global push toward carbon neutrality hydrogen has emerged as a promising alternative fuel. Ports are critical nodes in the hydrogen supply chain that are increasingly being utilized as long-term hydrogen storage hubs. However integrating hydrogen storage systems into port infrastructure presents unique technical environmental and safety challenges. This review systematically examines current technologies used for hydrogen storage in port environments—including compressed gas cryogenic liquid cryocompressed gas ammonia liquid organic hydrogen carriers solid-state hydrides and underground storage. Each technology is evaluated based on performance infrastructure requirements accident risks environmental impact and cost. The study also assesses port-specific infrastructure vulnerabilities under operational stress and climate change conditions and explores strategies for accident prevention emergency response and postincident recovery. A comprehensive framework is proposed to enhance the resilience and safety of hydrogen storage systems at ports. This study offers valuable insights for stakeholders and researchers by addressing technical gaps regulatory challenges and future directions for sustainable and safe hydrogen storage in port facilities
Feasibility Assessment into the Use of Hybrid Gas-hydride Tanks for Use in Improving the Flexibility of Offshore Hydrogen Production using Wind Power
Oct 2025
Publication
Offshore hydrogen production offers a promising solution for harnessing wind energy far from shore by using hydrogen as an energy carrier instead of electrical cables. Flexibility in hydrogen production systems is crucial to maximising the conversion of intermittent wind energy into hydrogen. To improve the performance of lowpressure compressed gas buffer stores hybrid gas-hydride tanks have been identified as a viable solution increasing useable storage density from 1.2 kg m− 3 to 6.3 kg m− 3 with just a 5 vol% addition of hydride. This study evaluates the reduction in tank volume reduction in cost and enhancements in useable storage density achieved by integrating different hydrides under varying temperature conditions. Using hydrogen mass flow rate profiles a storage mass target was determined for optimisation. The results demonstrate that hybrid gas-hydride tanks can reduce tank size by around 80 % lowering costs by 24 % and achieve a 5.1-fold improvement in useable storage density.
The Trans-critical Process Control of Hydrogen Based on a Flow Distribution Method for Enhancement of Heat Transfer
Aug 2025
Publication
The heat transfer performance of the thermal management system plays a crucial role in the hydrogen-powered aviation engine cycle. As an exceptional fuel the thermophysical parameters of hydrogen change drastically with temperature in the trans-critical state. While previous studies on heat transfer enhancement mainly focused on changing the geometrical structure few studies have been conducted on realizing heat transfer enhancement based on the properties of the fluid itself. Utilizing the drastic changes in thermophysical parameters of hydrogen in the trans-critical state to achieve heat transfer enhancement could greatly contribute to the thermal management system of the hydrogen-powered cycle. In this study a trans-critical process control method for heat transfer enhancement based on multidirectional impact flow distribution is proposed. The distributions and variation patterns of temperature density specific heat capacity and equivalent thermal conductivity along the flow directions were investigated the flow and heat transfer performance of the channel optimized by the proposed method was numerically simulated and the control of the trans-critical process and the mechanism of heat transfer enhancement were analyzed. The effects of the key design parameters such as flow distribution ratio number and spacing of gaps on the flow and heat transfer performance of the heat transfer unit were comparatively analyzed by taking various factors into account and finally a relatively optimal combination of key design parameters was obtained.
Green Hydrogen Viability in the Transition to a Fully-Renewable Energy Grid
Sep 2025
Publication
With the transition to a fully renewable energy grid arises the need for a green source of stability and baseload support which classical renewable generation such as wind and solar cannot offer due to their uncertain and highly-variable generation. In this paper we study whether green hydrogen can close this gap as a source of supplemental generation and storage. We design a two-stage mixed-integer stochastic optimization model that accounts for uncertainties in renewable generation. Our model considers the investment in renewable plants and hydrogen storage as well as the operational decisions for running the hydrogen storage systems. For the data considered we observe that a fully renewable network driven by green hydrogen has a greater potential to succeed when wind generation is high. In fact the main investment priorities revealed by the model are in wind generation and in liquid hydrogen storage. This long-term storage is more valuable for taking full advantage of hydrogen than shorter-term intraday hydrogen gas storage. In addition we note that the main driver for the potential and profitability of green hydrogen lies in the electricity demand and prices as opposed to those for gas. Our model and the investment solutions proposed are robust with respect to changes in the investment costs. All in all our results show that there is potential for green hydrogen as a source of baseload support in the transition to a fully renewable-powered energy grid.
A Review of Caprock Integrity in Underground Hydrogen Storage Sites: Implication of Wettability, Interfacial Tension, and Diffusion
Oct 2025
Publication
As industry moves from fossil fuels to green energy substituting hydrocarbons with hydrogen as an energy carrier seems promising. Hydrogen can be stored in salt caverns depleted hydrocarbon fields and saline aquifers. Among other criteria these storage solutions must ensure storage safety and prevent leakage. The ability of a caprock to prevent fluid from flowing out of the reservoir is thus of utmost importance. In this review the main factors influencing fluid flow are examined. These are the wettability of the caprock formation the interfacial tension (IFT) between the rock and the gas or liquid phases and the ability of gases to diffuse through it. To achieve effective sealing the caprock formation should possess low porosity a disconnected or highly complicated pore system low permeability and remain strongly water-wet regardless of pressure and temperature conditions. In addition it must exhibit low rock–liquid IFT while presenting high rock–gas and liquid–gas IFT. Finally the effective diffusion coefficient should be the lowest possible. Among all of the currently reviewed formations and minerals the evaporites low-organic-content shales mudstones muscovite clays and anhydrite have been identified as highly effective caprocks offering excellent sealing capabilities and preventing hydrogen leakages.
Decarbonising Agriculture with Green Hydrogen: A Stakeholder Guided Feasibility Study
Oct 2025
Publication
Green hydrogen offers a promising yet underexplored pathway for agricultural decarbonisation requiring technological readiness and coordinated action from policymakers industry and farmers. This paper integrates techno-economic modelling with stakeholder engagement (semi-structured interviews and an expert workshop) to assess its potential. Analyses were conducted for farms of 123 hectares and clusters of 10 farms complemented by seven interviews and a workshop with nine sector experts. Findings show both opportunities and barriers. While on-farm hydrogen production is technically feasible it remains economically uncompetitive due to high levelised costs shaped by seasonal demand variability and low utilisation of electrolysers and storage. Pooling demand across multiple users is essential to improve cost-effectiveness. Stakeholders identified three potential business models: fertiliser production via ammonia synthesis cooperative-based models and local refuelling stations. Of these cooperative hydrogen hubs emerged as the most promising enabling clusters of farms to jointly invest in renewable-powered electrolysers storage and refuelling facilities thereby reducing costs extending participation to smaller farms and mitigating risks through collective investment. By linking techno-economic feasibility with stakeholder perspectives and business model considerations the results contribute to socio-technical transition theory by showing how technological institutional and social factors interact in shaping hydrogen adoption in agriculture. With appropriate policy support cooperative hubs could lower costs ease concerns over affordability and complexity and position hydrogen as a practical driver of agricultural decarbonisation and rural resilience. Keywords: green
Development of Sustainability Assessment Framework for Preliminary Design of Chemical Process: Hydrogen Production as Case Study
Aug 2025
Publication
Sustainable process design has become increasingly important in transitioning from conventional to sustainable chemical production yet comprehensive sustainability assessment at the preliminary design stage remains a challenge. This study addresses this gap by proposing a hierarchical framework that integrates the Principles Criteria and Indicators (PC&I) method with multi-criteria decision-making (MCDM) tools including entropy weighting TOPSIS and weighted addition. The framework guides the systematic selection of sustainability indicators across economic environmental and social dimensions. To validate its applicability a case study on hydrogen production via four process routes natural gas reforming biomass-derived syngas methanol purge gas recovery and alkaline electrolysis is conducted. Results show that the methanol purge gas process exhibits the best overall sustainability followed by biomass syngas and alkaline electrolysis. The case demonstrates the framework’s capability to differentiate between alternatives under conflicting sustainability dimensions. This work provides a structured and replicable approach to support sustainable decision-making in early-stage chemical process design.
Scaling of Automotive Fuel Cells in Terms of Operating Indicators
Oct 2025
Publication
The search for alternatives to fossil fuels has led to hydrogen becoming an important factor in the powering means of transportation. Its most effective application is in fuel cells. A single fuel cell is not a sufficient source of power which is why a stack of fuel cells is the more common solution. Fuel cells are tested using single units as this allows all cell parameters (the current density flow rates and efficiency) to be evaluated. Therefore the scalability of fuel cells is an essential factor. This paper analyses the scalability of fuel cells with a power of approximately 100 kW and 1.2 kW. Road tests of the fuel cells were compared with stationary tests which allowed the load to be reproduced and scaled. This provided a representation of the scaled current and the scalable power of the fuel cell. The research provided voltage–current characteristics of fuel cell stacks and their individual equivalents. It was concluded that regardless of the power scaling or current values the characteristics obtain similar patterns. A very important element of the research is the awareness of the properties of these cells (the number of cells and active charge exchange area) in order to compare the unit characteristics of fuel cells.
Numerical Investigation on the Diffusion and Ventilation Characteristics of Hydrogen-Blended Natural Gas Leakage in Indoor Spaces
Oct 2025
Publication
The blending of hydrogen significantly impacts the diffusion and safety characteristics of natural gas within indoor environments. This study employs ANSYS Fluent 2021 R1 to numerically investigate the diffusion and ventilation characteristics of hydrogen-blended natural gas (HBNG) leakage in indoor spaces. A physical and mathematical model of gas leakage from pipelines is established to study hazardous areas flammable regions ventilation characteristics alarm response times safe ventilation rates and the concentration distribution of leaked gas. The effects of hydrogen blending ratio (HBR) ventilation conditions and space dimensions on leakage diffusion and safety are analyzed. Results indicate that HBNG leakage forms vertical concentration stratification in indoor spaces with ventilation height being negatively correlated with gas concentration and flammable regions. In the indoor space conditions of this study by improving ventilation conditions the hazardous area can be reduced by up to 92.67%. Increasing HBR substantially expands risk zones—with pure hydrogen producing risk volumes over five times greater than natural gas. Mechanical ventilation significantly enhances indoor safety. Safe ventilation rates escalate with hydrogen content providing quantitative safety criteria for HBNG implementation. The results underscore the critical influence of HBR and ventilation strategy on risk assessment providing essential insights for the safe indoor deployment of HBNG.
Thermochemical Aspects of Substituting Natural Gas by Hydrogen in Blister Copper Deoxidation
Aug 2025
Publication
This study employs computational thermodynamics to evaluate the feasibility of replacing methane with hydrogen as both burner fuel and reductant during blister copper deoxidation aiming to enhance deoxidation efficiency and reduce CO2 emissions. A comprehensive thermodynamic model was developed using FactSage 8.3 for dilute Cu–O and Cu–S–O melts containing trace impurities (Fe Ni Pb Zn) incorporating methane thermal decomposition and temperature-dependent variations in liquid copper density with oxygen and sulfur content. Model parameters were optimized against over 105 deoxidation simulation data points yielding temperature- and composition-dependent expressions for rapid density estimates. Benchmarking against existing literature models demonstrated improved accuracy. Key findings include: (1) increasing impurities contents from electronics waste recycling (Fe Ni Pb Zn) reduces oxygen activity deteriorating the deoxidation efficiency; (2) under global equilibrium methane provides greater reducing power per mole than hydrogen due to full thermal cracking but real-world mass transfer limitations render hydrogen more consistently effective up to 1200 C with methane gas needing to achieve at least 472 C to match hydrogen’s performance; (3) adiabatic flame equilibrium studies show that O2/H2 ratios of 0.5 to 1 yield liquid copper oxygen activities comparable to industrial O2/CH4 ratios of 2 to 3 supporting the direct substitution of methane with hydrogen in oxy-fuel anode furnace burners without compromising metal quality.
Analysis of the Efficiency of Hydrogen Fuel Cell Vehicle (HFCV) Applications in Manufacturing Processes Using Computer Simulation
Oct 2025
Publication
Implementing innovative solutions in the internal transport of manufacturing enterprises is becoming an important element of improving operational efficiency and reducing greenhouse gas emissions. This article assesses the potential of hydrogen fuel cell (HFCV) forklifts in a steel products manufacturing plant. The verification was carried out using a computer simulation which enabled the comparison of electric combustion and HFCV fleets under identical logistical conditions. The results showed that the HFCV fleet allowed for shorter process execution times and higher utilization compared to electric and combustion variants mainly due to the elimination of charging and refueling interruptions. Additionally when powered by green hydrogen the HFCV fleet offered clear environmental benefits and lower operating costs. The study confirms that HFCV technology can improve the efficiency of internal transport and reduce energy-related operating expenses although the costs of hydrogen refueling infrastructure were not included and should be addressed in future research.
Techno-Economic Optimization of Hybrid Renewable Energy Systems (HRESs) and Feasibility Study on Replacing Diesel and Photovoltaic Systems with Hydrogen for Electrical and Small Deferrable Loads: Case Study of Cameroon
Oct 2025
Publication
To reduce the amount of harmful gases produced by fossil fuels more environmentally friendly and sustainable alternatives are being proposed around the world. As a result technologies for manufacturing hydrogen fuel cells and producing green hydrogen are becoming more widespread with an impact on energy production and environmental protection. In many countries around the world and in Africa in particular leaders scientists and populations are considering switching from fossil fuels to so-called green energies. Hydrogen is therefore an interesting alternative that deserves to be explored especially since both rural and urban populations have shown an interest in using it in the near future which would reduce pollution and the proliferation of greenhouse gases thereby mitigating global warming. The aim of this paper is to determine the hybrid energy system best suited to addressing the energy problem in the study area and then to make successive substitutions of different energy sources starting with the most polluting in order to assess the possibilities for transitioning the energy used in the area to green hydrogen. To this end this study began with a technical and economic analysis which based on climatic parameters led to the proposal of a PV/DG-BATTery system configuration with a Net Present Cost (NPC) of USD 19267 and an average Cost Of Energy (COE) of USD 0.4 and with a high proportion of CO2 emissions compared with the PV/H2GEN-BATT and H2GEN systems. The results of replacing fossil fuel generators with hydrogen generators are beneficial in terms of environmental protection and lead to a reduction in energy-related expenses of around 2.1 times the cost of diesel and a reduction in mass of around 2.7 times the mass of diesel. The integration of H2GEN at high duty percentages increases the Cost Of Energy whether in a hybrid PV/H2GEN system or an H2GEN system. This shows the interest in the study country in using favorable duty proportions to make the use of hydrogen profitable.
Transforming Ports for a Low-carbon Future: Nexus Modeling of Hydrogen Infrastructure, Employment, and Resource Management in Contrasting Climates
Aug 2025
Publication
This research study highlights a transformative approach to port development for a lowcarbon future by integrating Climate Land Energy and Water Systems (CLEWs) and Water-Energy-Food (WEF) frameworks. The proposed nexus model integrates the hydrogen infrastructure with green employment and resource management in contrasting climates. The scenarios analyzed include Business As Usual (BAU) Balanced Reduction Approach (BRA) and Maximal Sustainability Push (MSP) which focuses mainly on energy efficiency resource utilization and workforce sustainability. By BRA it is estimated that carbon emissions will decline by 30% in cold climates and 20% in warm climates without changing renewable power plants producing 45% and 30% of the electricity supply mix. In the MSP scenario emission reductions rise to 90% in cold and 40% in warm climates with renewables providing 62% and 40% of the electricity mix. Under the whole capacity of Municipal Solid Waste (MSW) and fish waste under anaerobic digestion and fish waste rendering by 2040 across all BRA and MSP scenarios. In transport 44% replacement of marine vehicles and 87% of land vehicles with hydrogen electric and carbon capture and storage (CCS)-equipped vehicles is made under the BRA scenario. These percentages increase to 100% under the MSP scenario in cold climates while remaining at 87% in warm climates. By this integrated framework the present study demonstrates the potential of ports to be powerful engines for sustainable economic growth optimized resource efficiency and the creation of resilient green employment systems in diverse environmental contexts.
Hydrogen Safety in Energy Infrastructure: A Review
Oct 2025
Publication
For the transition to emission-free or low-emission energy hydrogen is a promising energy carrier and fuel of the future with the possibility of long-term storage. Due to its specific properties it poses certain safety risks; therefore it is necessary to have a comprehensive understanding of hydrogen. This review article contains ten main chapters and provides by synthesizing current findings primarily from standards and scientific studies (predominantly from 2023 to 2024) the theoretical basis for further research directed toward safe hydrogen infrastructure.
Study on the Thermodynamic Behavior of Large Volume Liquid Hydrogen Bottle Under the Coupling of Different Motion States and Operational Parameters
Oct 2025
Publication
To investigate the variations in the thermodynamic behavior of large-volume liquid hydrogen tanks under different influencing factors a numerical model for liquid hydrogen tanks was developed. The changes in thermodynamic behavior in vehicle-mounted liquid hydrogen bottles under different motion states different operational pressures and different insulation thicknesses and their mutual coupling scenarios were studied. The results show that the movement makes the phase state in the liquid hydrogen bottle more uniform the pressure drop rate faster and the temperature lower: the heating rate in the liquid hydrogen bottle at 0.85 MPa operational pressure is lower than that at 0.5 MPa and 1.2 MPa. When the operational pressure is coupled with the motion state the influence of the motion state on the thermodynamic behavior of the fluid is dominant: the temperature near the wall rises rapidly. The temperature near the tank wall rises rapidly; however as the thickness of the insulation layer increases both the heating rate inside the liquid hydrogen tank and the temperature difference within the tank gradually tend to stabilize and become uniform.
Exploring the Potential of Ammonia as a Fuel: Advances in Combustion Understanding and Large-scale Furnace Applications
Sep 2025
Publication
From an environmental standpoint carbon-free energy carriers such as ammonia and hydrogen are essential for future energy systems. However their hightemperature chemical behavior remains insufficiently understood posing challenges for the development and optimization of advanced combustion technologies. Ammonia in particular is globally available and cost-effective especially for energy-intensive industries. The addition of ammonia or hydrogen to methane significantly reduces the accuracy of existing predictive models. Therefore validated and detailed data are urgently needed to enable reliable design and performance predictions. This review highlights the compatibility of ammonia with existing combustion infrastructure facilitating a smoother transition to more sustainable heating methods without the need for entirely new systems. Applications in high-temperature heating processes such as metal processing ceramics and glass production and power generation are of particular interest. This review focuses on the systematic assessment of alternative fuel mixtures comprising ammonia and hydrogen as well as natural gas with particular consideration of existing safety-related parameters and combustion characteristics. Fundamental quantities such as the laminar burning velocity are discussed in the context of their relevance for fuel mixtures and their scalability toward turbulent flame propagation which is of critical importance for industrial burner and reactor design. The influence of fuel composition on ignition limits is examined as these are essential parameters for safety margin definitions and operational boundary conditions. Furthermore flame stability in mixed-fuel systems is addressed to evaluate the practical feasibility and robustness of combustion under varying process conditions. A detailed overview of current diagnostic and analysis methods follows encompassing both pollutant measurement techniques and the detection of key radical species. These diagnostics form the experimental basis for reaction kinetics modeling and mechanism validation. Given the importance of emission formation in combustion systems a dedicated subsection summarizes major emission trends even though a comprehensive treatment would exceed the scope of this review. Thermal radiation effects which are highly relevant for heat transfer and system efficiency in large-scale applications are then reviewed. In parallel current developments in numerical simulation approaches for industrial-scale combustion systems are presented including aspects of model accuracy boundary conditions and computational efficiency. The review also incorporates insights from materials engineering particularly regarding high-temperature material performance corrosion resistance and compatibility with combustion products. Based on these interdisciplinary findings operational strategies for high-temperature furnaces are outlined and selected industrial reference systems are briefly presented. This integrated approach aims to support the design optimization and safe operation of next-generation combustion technologies utilizing carbon-free or low-carbon fuels.
Catalytic Hydrogen Combustion as Heat Source for the Dehydrogenation of Liquid Organic Hydrogen Carriers using a Novel Compact Autothermal Reactor
Sep 2025
Publication
The experimental performance of an autothermal hydrogen release unit comprising a perhydro benzyltoluene (H12-BT) dehydrogenation chamber and a catalytic hydrogen combustion (CHC) chamber in thermal contact is discussed. In detail the applied set-up comprised a multi-tubular CHC heating based on seven parallel tubes with the reactor shell containing a commercial dehydrogenation catalyst. In this way the CHC heated the endothermal LOHC dehydrogenation using a part of the hydrogen generated in the dehydrogenation. The proposed heating concept for autothermal LOHC dehydrogenation offers several advantages over state-of-the-art heating concepts including minimized space consumption high efficiency and zero NOx emissions. During performance tests the process reached a minimum hydrogen combustion fraction of 37 % while the minimum heat requirement for the dehydrogenation reaction for industrial scale plants is 33 %. The reactor orientation (vertical vs horizontal) and the flow configuration (counter-current vs. co-current) showed very little influence on the performance demonstrating the robustness of the proposed reactor design.
A Comprehensive Review of Green Hydrogen Technology: Electrolysis Methods, Topologies and Control Strategies, Applications
Oct 2025
Publication
As a pivotal clean energy carrier for achieving carbon neutrality green hydrogen technology has attracted growing global attention. This review systematically examines four mainstream water electrolysis technologies—alkaline electrolysis proton exchange membrane electrolysis solid oxide electrolysis and anion exchange membrane electrolysis—analyzing their fundamental principles material challenges and development trends. It further classifies and compares power electronic converter topologies including non-isolated and isolated DC–DC converters as well as AC–DC converter architectures and summarizes advanced control strategies such as dynamic power regulation and fault-tolerant operation aimed at enhancing system efficiency and stability. A holistic “electrolyzer–power converter–control strategy” integration framework is proposed to provide tailored technological solutions for diverse application scenarios. Finally the challenges and future prospects of green hydrogen across the energy transportation and industrial sectors are discussed underscoring its potential to accelerate the global transition toward a sustainable low-carbon energy system.
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