Applications & Pathways

Hydrogen and fuel cell technologies have experienced cycles of high expectations followed by impractical realities. This time around however falling renewable energy and fuel cell prices stringent climate change requirements and the discrete involvement of China are step changes. The combination of these factors is leading to realistic potential for hydrogen’s role in the Grand Transition.<br/>Having conducted exploratory interviews with leaders from all around the globe the World Energy Council is featuring eight use cases which illustrate hydrogen’s potential. These range from decarbonising hard-to-abate sectors such as heat industry and transport to supporting the integration of renewables and providing an energy storage solution.<br/>Dr Angela Wilkinson Secretary General and former Senior Director Scenarios and Business Insights: “Green and blue hydrogen can refresh those parts of the energy system transition that electrification cannot reach.”<br/>This Innovation Insights Brief is part of a series of publications by the World Energy Council focused on Innovation. In a fast-paced era of disruptive changes this brief aims at facilitating strategic sharing of knowledge between the Council’s members and the other energy stakeholders and policy shapers.

With the application of new energy technology hybrid agricultural machinery has been developed. This article designs a hybrid tractor energy management method to solve the problem of high energy consumption caused by significant load fluctuation of the tractor in field operation. This article first analyzes the characteristics of the hydrogen fuel cell power battery and ultracapacitor and designs a hybrid energy system for the tractor. Second the energy management strategy (EMS) of multi-layer decoupling control based on the Haar wavelet and logic rule is designed to realize the multi-layer decoupling of high-frequency low-frequency and steady-state signals of load demand power. Then the EMS redistributes the decoupled power signals to each energy source. Finally a hardware-in-loop simulation experiment was carried out through the model. The results show that compared with single-layer control strategies such as fuzzy control and power-following control the multi-layer control strategy can allocate the demand power more reasonably and the efficiency of the hydrogen fuel cell is the highest. The average efficiency of the hydrogen fuel cell was increased by 2.87% and 1.2% respectively. Furthermore the equivalent hydrogen consumption of the tractor was reduced by 17.06% and 5.41% respectively within the experimental cycle. It is shown that the multi-layer control strategy considering power fluctuation can improve the vehicle economy based on meeting the power demanded by the whole vehicle load.

Currently most of the vehicles make use of fossil fuels for operations resulting in one of the largest sources of carbon dioxide emissions. The need to cut our dependency on these fossil fuels has led to an increased use of renewable energy sources (RESs) for mobility purposes. A technical and economic analysis of a one-stop charging station for battery electric vehicles (BEV) and fuel cell electric vehicles (FCEV) is investigated in this paper. The hybrid optimization model for electric renewables (HOMER) software and the heavy-duty refueling station analysis model (HDRSAM) are used to conduct the case study for a one-stop charging station at Technical University of Denmark (DTU)-Risø campus. Using HOMER a total of 42 charging station scenarios are analyzed by considering two systems (a grid-connected system and an off-grid connected system). For each system three different charging station designs (design A-hydrogen load; design B-an electrical load and design C-an integrated system consisting of both hydrogen and electrical load) are set up for analysis. Furthermore seven potential wind turbines with different capacity are selected from HOMER database for each system. Using HDRSAM a total 18 scenarios are analyzed with variation in hydrogen delivery option production volume hydrogen dispensing option and hydrogen dispensing option. The optimal solution from HOMER for a lifespan of twenty-five years is integrated into design C with the grid-connected system whose cost was $986065. For HDRSAM the optimal solution design consists of tube trailer as hydrogen delivery with cascade dispensing option at 350 bar together with high production volume and the cost of the system was $452148. The results from the two simulation tools are integrated and the overall cost of the one-stop charging station is achieved which was $2833465. The analysis demonstrated that the one-stop charging station with a grid connection is able to fulfil the charging demand cost-effectively and environmentally friendly for an integrated energy system with RESs in the investigated locations.

This work is aimed at solving the problem of converting diesel power drives to diesel– hydrogen fuels which are more environmentally friendly and less expensive alternatives to diesel fuel. The method of increasing the energy efficiency of diesel fuels has been improved. The thermochemical essence of using methanol as an alternative fuel to increase energy efficiency based on the provisions of thermotechnics is considered. Alternative methanol fuel has been chosen as the initial product for the hydrogen conversion process and its energy value cost and temperature conditions have been taken into account. Calculations showed that the caloric effect from the combustion of the converted mixture of hydrogen H2 and carbon monoxide CO exceeds the effect from the combustion of the same amount of methanol fuel. Engine power and fuel energy were increased due to the thermochemical regeneration of engine exhaust gas heat. An experimental setup was created to study the operation of a converted diesel engine on diesel–hydrogen products. Experimental studies of power and environmental parameters of a diesel engine converted for diesel–hydrogen products were performed. The studies showed that the conversion of diesel engines to operate using diesel– hydrogen products is technically feasible. A reduction in energy consumption was accompanied by an improvement in the environmental performance of the diesel–hydrogen engine working together with a chemical methanol conversion thermoreactor. The formation of carbon monoxide occurred in the range of 52–62%; nitrogen oxides in the exhaust gases decreased by 53–60% according to the crankshaft speed and loading on the experimental engine. In addition soot emissions were reduced by 17% for the engine fueled with the diesel–hydrogen fuel. The conversion of diesel engines for diesel–hydrogen products is very profitable because the price of methanol is on average 10–20% of the cost of petroleum fuel.

Hydrogen-yielding fermentation conducted in bioreactors is an alternative method of hydrogen production. However unfavourable processes can seriously inhibit bio-hydrogen generation during the acidogenic step of anaerobic digestion. Here ascomycetous yeasts were identified as a major factor inhibiting the production of bio-hydrogen by fermentation. Changes in the performance of hydrogen-producing bioreactors including metabolic shift quantitative changes in the fermentation products decreased pH instability of the microbial community and consequently a dramatic drop in bio-hydrogen yield were observed following yeast infection. Ascomycetous yeasts from the genera Candida Kazachstania and Geotrichum were isolated from hydrogen-producing bioreactors. Yeast metabolites secreted into the growth medium showed antibacterial activity. Our studies indicate that yeast infection of hydrogen-producing microbial communities is one of the serious obstacles to use dark fermentation as an alternative method of bio-hydrogen production. It also explains why studies on hydrogen fermentation are still limited to the laboratory or pilot-scale systems.

As an energy-intensive industry sector the glass industry is strongly affected by the increasingly stringent climate protection targets. As established combustion-based production systems ensure high process stability and glass quality an immediate switch to low greenhouse gas emission processes is difficult. To approach these challenges this work investigates a step-by-step integration of a Power-to-Hydrogen concept into established oxyfuel glass melting processes using a simulation approach. This is complemented by a case study for economic analysis on a selected German glass industry site by simulating the power production of a nearby renewable energy park and subsequent optimization of the power-to-hydrogen plant performance and capacities. The results of this study indicate that the proposed system can reduce specific carbon dioxide emissions by up to 60 % while increasing specific energy demand by a maximum of 25 %. Investigations of the impact of altered combustion and furnace properties like adiabatic flame temperature (+25 °C) temperature efficiency (∆ξ = −0.003) and heat capacity flow ratio (∆zHL = −0.009) indicate that pure hydrogen-oxygen combustion has less impact on melting properties than assumed so far. Within the case study high CO2 abatement costs of 295 €/t CO2-eq. were determined.. This is mainly due to the insufficient performance of renewable energy sources. The correlations between process scaling and economic parameters presented in this study show promising potential for further economic optimization of the proposed energy system in the future.

This study aims to present a philosophical and quantitative perspective of a propulsion system for a large-scale hydrogen-fuelled liquid-hydrogen (LH2) tanker ship. Established methods are used to evaluate the design and performance of an LH2-carrier propulsion system for JAMILA a ship designed with four cylindrical LH2 tanks bearing a total capacity of ~280000 m3 along with cargo and using the boil-off as propulsion and power fuel. Additionally the ship propulsion system is evaluated based on the ship resistance requirements and a hydrogen-fuelled combined-cycle gas turbine is modelled to achieve the dual objectives of high efficiency and zero-carbon footprint. The required inputs primarily involve the off-design and degraded performance of the gas-turbine topping cycle and the proposed power plant operates with a total output power of 50 M.W. The results reveal that the output power allows ship operation at a great speed even with a degraded engine and adverse ambient conditions.

This study investigated a pre-cooled turbojet engine for a Mach 5 class hypersonic transport aircraft. The engine was demonstrated under takeoff and Mach 2 flight conditions and a Mach 5 propulsion wind tunnel test is planned. The engine is composed of a pre-cooler a core engine and an afterburner. The engine was tested under simulated Mach 4 conditions using an air supply facility. High-temperature air under high pressure was supplied to the engine components through an airflow control valve and an orifice flow meter and liquid hydrogen was supplied to the pre-cooler and the core engine. The results confirmed that the starting sequence of the engine components was effective under simulated Mach 4 conditions using liquid hydrogen fuel. The pre-cooling effect caused no damage to the rotating parts of the core engine in the experiment.

The bipolar plate (BPP) is a component with vast cost-reduction potential in proton exchange membrane fuel cells (PEMFCs). Apart from mechanical and heat transfer requirements the most desired BPP properties are high corrosion and low electrical contact resistance. In this study we confirm that due to ionic decoupling between BPPs and electrodes the surface potentials of the BPPs remain stable even at varying operation loads. These mild potentials in combination with low metal-ion leeching due to passive-transpassive-passive dissolution in stainless steels suggest that low-cost carbon-coated stainless steel can readily be used as a BPP in PEMFCs. To prove this single-fuel cell tests were carried out under realistic driving conditions including electrochemical analysis in-situ contact-resistance measurements and post-mortem investigation of the membrane electrode assembly (MEA) by inductively coupled plasma trace-metal analysis combined with electron microscopy and Auger spectroscopy of the BPPs. The results show that due to the ionic decoupling conditions at the BPP surfaces are much less corrosive than previously thought. Furthermore carbon-coated stainless-steel BPPs prove to be unaffected by global hydrogen starvation which causes severe MEA degradation independent of the presence or absence of BPPs.

Since the beginning of the twenty-first century the limitations of the fossil age with regard to the continuing growth of energy demand the peaking mining rate of oil the growing impact of CO₂ emissions on the environment and the dependency of the economy in the industrialized world on the availability of fossil fuels became very obvious. A major change in the energy economy from fossil energy carriers to renewable energy fluxes is necessary. The main challenge is to efficiently convert renewable energy into electricity and the storage of electricity or the production of a synthetic fuel. Hydrogen is produced from water by electricity through an electrolyser. The storage of hydrogen in its molecular or atomic form is a materials challenge. Some hydrides are known to exhibit a hydrogen density comparable to oil; however these hydrides require a sophisticated storage system. The system energy density is significantly smaller than the energy density of fossil fuels. An interesting alternative to the direct storage of hydrogen are synthetic hydrocarbons produced from hydrogen and CO₂ extracted from the atmosphere. They are CO₂ neutral and stored like fossil fuels. Conventional combustion engines and turbines can be used in order to convert the stored energy into work and heat.

Link to document download on Royal Society Website 

The work is dedicated to the possibility of using hydrogen-powered vehicles in urban transport systems. Due to the need to look for alternative solutions for vehicles with conventional drive in cities hydrogen-powered cars are one of the practical possibilities of realizing the sustainable transport assumptions and independence from oil imports - which is one of the main priorities of the European Union. This paper presents a literature analysis the analysis of the current state and development of use hydrogen-powered vehicles in the world.<br/>The article refers to the possibilities of use hydrogen-vehicles in different ways of mobility: individual vehicles taxis and shared mobility. In addition the author focused on showing the advantages and disadvantages of using hydrogen-powered vehicles in urban transport systems.

The transition to a more sustainable personal transportation sector requires the widespread adoption of electric vehicles. However a dominant design has not yet emerged and a standards battle is being fought between battery and hydrogen fuel cell powered electric vehicles. The aim of this paper is to analyze which factors are most likely to influence the outcome of this battle thereby reducing the uncertainty in the industry regarding investment decisions in either of these technologies. We examine the relevant factors for standard dominance and apply a multi-criteria decision-making method best worst method to determine the relative importance of these factors. The results indicate that the key factors include technological superiority compatibility and brand reputation and credibility. Our findings show that battery powered electric vehicles have a greater chance of winning the standards battle. This study contributes to theory by providing further empirical evidence that the outcome of standards battles can be explained and predicted by applying factors for standard success. We conclude that technology dominance in the automotive industry is mostly driven by technological characteristics and characteristics of the format supporter.

Energy transition is a part of a much wider Grand Transition which is not all about energy. Energy transition cannot be achieved all at once or by any one actor. Relying only on better energy modelling and forecasting to guide successful transition will be fatal even in a data-rich era.<br/>It is timely for energy leaders to ask:<br/>Are global energy scenarios achieving their potential in opening up action on new energy futures?<br/>How do the Council’s World Energy Scenarios compare with global energy outlooks scenarios and normative visions used by others and what can we learn by contrasting the increasing richness of energy futures thinking?<br/>In anticipation of the 24th World Energy Congress the Council is refreshing its global energy foresight and updating its global scenarios narratives. The focus is on an ‘innovation twist to 2040’ and the use of scenarios to explore and navigate new exponential growth opportunities for accelerating successful energy transition in an era of epic and disruptive innovation.<br/>As a part of the refresh the Council has conducted a comparison study of global energy scenarios in order to test the continued plausibility relevance and challenge of its own existing scenario set the World Energy Scenarios 2016 launched at the 23rd World Energy Congress in Istanbul in 2016.<br/>By comparing the methods narratives and assumptions associated with a benchmarkable set of global energy futures initiatives and studies the Council seeks to provide our members with clearer understanding and new insights on energy transition while preparing them to better engage with leadership dialogues which pivot on visions of a new energy future.<br/>The review also provides an opportunity to reflect on the challenges and obstacles for utilising global energy scenarios to drive impact and the challenges in bridging agile and flexible qualitative storytelling with long term quantitative energy modelling."

Jordan's energy diversification strategy is centred around renewables which are expected will provide the low-cost reliable secure and environmentally sustainable energy required to power its new engines of economic growth – manufacturing transport construction and agriculture.

The National Energy Strategy 2020–2030 presents the evolution of the energy sector under its vision for stimulating demand achieving efficiency and improving electricity system flexibility.

This Renewables Readiness Assessment (RRA) highlights key actions for the short and medium-term that could create more conductive conditions for renewable energy development. It aims to help unlock Jordan's renewable energy potential and provide the means to meet the energy diversification goals of its national strategy.

The study was undertaken by the Ministry of Energy and Mineral Resources (MEMR) in collaboration with the International Renewable Energy Agency (IRENA).

Key recommendations:

• Provide the necessary conditions for renewables growth in the power sector.
• Foster continued growth of renewable power generation.
• Plan the integration of higher shares of renewable power.
• Incentivise the use of renewables for heating and cooling.
• Support renewable transport and mobility options.
• Catalyse renewable energy investment. Strengthen local industries and create jobs in renewables.

Short refuelling time and high final state of charge are among the main hydrogen car user's requirements. To meet these requirements without exceeding the tank materials safety limits hydrogen precooling is needed. Filling experiments with different inlet gas temperatures and mass flow rates have been executed using two different types of on-board tanks (type 3 and 4). State of charge has a strong dependency on the inlet gas temperature. This dependency is more visible for type 4 tanks. Lowest precooling temperature (−40 °C) is not always required in order to meet user's requirements so energy savings can be achieved if the initial conditions of the tank are correctly identified. The results of the experiments performed have been compared with the SAE J2601 look-up tables for non-communication fillings. A big safety margin has been observed in these tables. Refuelling could be performed faster and with less demanding precooling requirements if the initial conditions and the configuration of the hydrogen storage system are well known.

Production of iron and steel releases seven percent of the global greenhouse gas (GHG) emissions. Incremental changes in present primary steel production technologies would not be sufficient to meet the emission reduction targets. Replacing coke used in the blast furnaces as a reducing agent with hydrogen produced from water electrolysis has the potential to reduce emissions from iron and steel production substantially. Mass and energy flow model based on an open-source software (Python) has been developed in this work to explore the feasibility of using hydrogen direct reduction of iron ore (HDRI) coupled with electric arc furnace (EAF) for carbon-free steel production. Modeling results show that HDRI-EAF technology could reduce specific emissions from steel production in the EU by more than 35% at present grid emission levels (295 kgCO2/MWh). The energy consumption for 1 ton of liquid steel (tls) production through the HDRI-EAF route was found to be 3.72 MWh which is slightly more than the 3.48 MWh required for steel production through the blast furnace (BF) basic oxygen furnace route (BOF). Pellet making and steel finishing processes have not been considered. Sensitivity analysis revealed that electrolyzer efficiency is the most important factor affecting the system energy consumption while the grid emission factor is strongly correlated with the overall system emissions.

Hydrogen is widely recognised as an important option for future road transportation but a widespread infrastructure must be developed if the potential for hydrogen is to be achieved. This paper and related appendices which can be downloaded as Supplementary material present a mixed-integer linear programming model (called SHIPMod) that optimises a hydrogen supply chains for scenarios of hydrogen fuel demand in the UK including the spatial arrangement of carbon capture and storage infrastructure. In addition to presenting a number of improvements on past practice in the literature the paper focuses attention on the importance of assumptions regarding hydrogen demand. The paper draws on socio-economic data to develop a spatially detailed scenario of possible hydrogen demand. The paper then shows that assumptions about the level and spatial dispersion of hydrogen demand have a significant impact on costs and on the choice of hydrogen production technologies and distribution mechanisms.

The debate on low-carbon heat in Europe has become focused on a narrow range of technological options and has largely neglected hydrogen and fuel cell technologies despite these receiving strong support towards commercialisation in Asia. This review examines the potential benefits of these technologies across different markets particularly the current state of development and performance of fuel cell micro-CHP. Fuel cells offer some important benefits over other low-carbon heating technologies and steady cost reductions through innovation are bringing fuel cells close to commercialisation in several countries. Moreover fuel cells offer wider energy system benefits for high-latitude countries with peak electricity demands in winter. Hydrogen is a zero-carbon alternative to natural gas which could be particularly valuable for those countries with extensive natural gas distribution networks but many national energy system models examine neither hydrogen nor fuel cells for heating. There is a need to include hydrogen and fuel cell heating technologies in future scenario analyses and for policymakers to take into account the full value of the potential contribution of hydrogen and fuel cells to low-carbon energy systems.

The chemical looping process where an oxygen carrier is reduced and oxidized in a cyclic manner offers a promising option for hydrogen production through splitting water because of the much higher water splitting efficiency than solar electrocatalytic and photocatalytic process. A typical oxygen carrier has to comprise a significant amount of inert support to maintain stability in multiple redox cycles thereby resulting in a trade-off between the reaction reactivity and stability. Herein we proposed the use of ion-conductive yttria-stabilized zirconia (YSZ) support Fe2O3 to prepare oxygen carriers materials. The obtained Fe2O3/YSZ composites showed high reactivity and stability. Particularly Fe2O3/YSZ-20 (oxygen storage capacity 24.13%) exhibited high hydrogen yield of ∼10.30 mmol·g-1 and hydrogen production rate of ∼0.66 mmol·g-1·min-1 which was twice as high as that of Fe2O3/Al2O3. Further the transient pulse test indicated that active oxygen diffusion was the rate-limiting step during the redox process. The electrochemical impedance spectroscopy (EIS) measurement revealed that the YSZ support addition facilitated oxygen diffusion of materials which contributed to the improved hydrogen production performance. The support effect obtained in this work provides a potentially efficient route for the modification of oxygen carrier materials.

The co-combustion of diesel fuel with H2 presents a promising route to reduce the adverse effects of diesel engine exhaust pollutants on the environment and human health. This paper presents the results of H2-diesel co-combustion experiments carried out on two different research facilities a light duty and a heavy duty diesel engine. For both engines H2 was supplied to the engine intake manifold and aspirated with the intake air. H2 concentrations of up to 20% vol/vol and 8% vol/vol were tested in the light duty and heavy duty engines respectively. Exhaust gas circulation (EGR) was also utilised for some of the tests to control exhaust NOx emissions.<br/>The results showed NOx emissions increase with increasing H2 in the case of the light duty engine however in contrast for the heavy duty engine NOx emissions were stable/reduced slightly with H2 attributable to lower in-cylinder gas temperatures during diffusion-controlled combustion. CO and particulate emissions were observed to reduce as the intake H2 was increased. For the light duty H2 was observed to auto-ignite intermittently before diesel fuel injection had started when the intake H2 concentration was 20% vol/vol. A similar effect was observed in the heavy duty engine at just over 8% H2 concentration.

Searching for efficient and robust non-noble electrocatalysts for hydrogen generation is extremely desirable for future green energy systems. Here we present the synthesis of integrated Ni-P-S nanosheets array including Ni2P and NiS on nickel foam by a simple simultaneous phosphorization and sulfurization strategy. The resultant sample with optimal composition exhibits superior electrocatalytic performance for hydrogen evolution reaction (HER) in a wide pH range. In alkaline media it can generate current densities of 10 20 and 100 mA cm−2 at low overpotentials of only −101.9 −142.0 and −207.8 mV with robust durability. It still exhibits high electrocatalytic activities even in acid or neutral media. Such superior electrocatalytic performances can be mainly attributed to the synergistic enhancement of the hybrid Ni-P-S nanosheets array with integration microstructure. The kind of catalyst gives a new insight on achieving efficient and robust hydrogen generation.

The absorption of CO2 is of importance in carbon capture utilization and storage technology for greenhouse gas control. In the present work we clarified the mechanism of how metal-based ionic liquids (MBILs) Bmim[XCln]m (X is the metal atom) enhance the CO2 absorption capacity of ILs via performing molecular dynamics simulations. The sparse hydrogen bond interaction network constructed by CO2 and MBILs was identified through the radial distribution function and interaction energy of CO2-ion pairs which increase the absorption capacity of CO2 in MBILs. Then the dynamical properties including residence time and self-diffusion coefficient confirmed that MBILs could also promote the diffusion process of CO2 in ILs. That's to say the MBILs can enhance the CO2 absorption capacity and the diffusive ability simultaneously. Based on the analysis of structural energetic and dynamical properties the CO2 absorption capacity of MBILs increases in the order Cl− → [ZnCl4]2-→ [CuCl4]2-→ [CrCl4]- → [FeCl4]- revealing the fact that the short metal–Cl bond length and small anion volume could facilitate the performance of CO2 absorbing process. These findings show that the metal–Cl bond length and effective volume of the anion can be the effective factors to regulate the CO2 absorption process which can also shed light on the rational molecular design of MBILs for CO2 capture and other key chemical engineering processes such as IL-based gas sensors nano-electrical devices and so on.

Hydrogen production by steam reforming of ethylene glycol (EG) at 300 °C was investigated over SiO2 and CeO2 supported Pt–Ni bimetallic catalysts prepared by incipient wetness impregnation methods. It was observed that impregnation sequence of Pt and Ni can affect the performance of catalysts apparently. Catalyst with Pt first and then Ni addition showed higher EG conversion and H2 yield owing to the Ni enrichment on the surface and the proper interaction between Pt and Ni. It was observed that although SiO2 supported catalysts exhibited better activity and H2 selectivity CeO2 supported ones had better stability. This is attributed to the less coke formation on CeO2. Increasing Pt/Ni ratio enhanced the reaction activity and Pt3–Ni7 catalysts with 3 wt% Pt and 7 wt% Ni showed the highest activity and stability. Ni surficial enrichment facilitated the C—C bond rupture and water gas shift reactions; and Pt addition inhibited methanation reaction. Electron transfer and hydrogen spillover from Pt to Ni suppressed carbon deposition. These combined effects lead to the excellent performance of Pt3–Ni7 supported catalysts.

In Europe electrification is considered a key option to obtain a cleaner production of steel at the same time as the electricity system production portfolio is expected to consist of an increasing share of varying renewable electricity (VRE) generation mainly in the form of solar PV and wind power. We investigate cost-efficient designs of hydrogen-based steelmaking in electricity systems dominated by VRE. We develop and apply a linear cost-minimization model with an hourly time resolution which determines cost-optimal operation and sizing of the units in hydrogen-based steelmaking including an electrolyser direct reduction shaft electric arc furnace as well as storage for hydrogen and hot-briquetted iron pellets. We show that the electricity price following steelmaking leads to savings in running costs but to increased capital cost due to investments in the overcapacity of steel production units and storage units for hydrogen and hot-briquetted iron pellets. For two VRE-dominated regions we show that the electricity price following steel production reduces the total steel production cost by 23% and 17% respectively as compared to continuous steel production at a constant level. We also show that the cost-optimal design of the steelmaking process is dependent upon the electricity system mix.

In this study the authors present a techno-economic assessment of on-site hydrogen refuelling stations (450 kg/day of H2 ) based on different hydrogen sources and production technologies. Green ammonia biogas and water have been considered as hydrogen sources while cracking autothermal reforming and electrolysis have been selected as the hydrogen production technologies. The electric energy requirements of the hydrogen refuelling stations (HRSs) are internally satisfied using the fuel cell technology as power units for ammonia and biogas-based configurations and the PV grid-connected power plant for the water-based one. The hydrogen purification where necessary is performed by means of a Palladium-based membrane unit. Finally the same hydrogen compression storage and distribution section are considered for all configurations. The sizing and the energy analysis of the proposed configurations have been carried out by simulation models adequately developed. Moreover the economic feasibility has been performed by applying the life cycle cost analysis. The ammonia-based configurations are the best solutions in terms of hydrogen production energy efficiency (>71% LHV) as well as from the economic point of view showing a levelized cost of hydrogen (LCOH) in the range of 6.28 EUR/kg to 6.89 EUR/kg a profitability index greater than 3.5 and a Discounted Pay Back Time less than five years.