Applications & Pathways
Simulation and Techno-Economic Analysis of a Power-to-Hydrogen Process for Oxyfuel Glass Melting
Dec 2021
Publication
As an energy-intensive industry sector the glass industry is strongly affected by the increasingly stringent climate protection targets. As established combustion-based production systems ensure high process stability and glass quality an immediate switch to low greenhouse gas emission processes is difficult. To approach these challenges this work investigates a step-by-step integration of a Power-to-Hydrogen concept into established oxyfuel glass melting processes using a simulation approach. This is complemented by a case study for economic analysis on a selected German glass industry site by simulating the power production of a nearby renewable energy park and subsequent optimization of the power-to-hydrogen plant performance and capacities. The results of this study indicate that the proposed system can reduce specific carbon dioxide emissions by up to 60 % while increasing specific energy demand by a maximum of 25 %. Investigations of the impact of altered combustion and furnace properties like adiabatic flame temperature (+25 °C) temperature efficiency (∆ξ = −0.003) and heat capacity flow ratio (∆zHL = −0.009) indicate that pure hydrogen-oxygen combustion has less impact on melting properties than assumed so far. Within the case study high CO2 abatement costs of 295 €/t CO2-eq. were determined.. This is mainly due to the insufficient performance of renewable energy sources. The correlations between process scaling and economic parameters presented in this study show promising potential for further economic optimization of the proposed energy system in the future.
Green Hydrogen Value Chain in the Sustainability for Port Operations: Case Study in the Region of Valparaiso, Chile
Dec 2021
Publication
The paper presents a complete value chain for the use of green hydrogen in a port facility. The main objective was to propose the sizing of the main components that make up green hydrogen to ensure the supply of 1 MWe in replacing the diesel generator. The energy demand required for the port was determined by establishing the leading small and large-scale conventional energyconsuming equipment. Hence 60 kgH2 was required to ensure the power supply. The total electrical energy to produce all the hydrogen was generated from photovoltaic solar energy considering threegeneration scenarios (minimum maximum and the annual average). In all cases the energy supply in the electrolyzer was 3.08 MWe. In addition the effect of generating in the port facility using a diesel generator and a fuel cell was compared. The cost of 1 kgH2 could be 4.09 times higher than the cost of 1 L of diesel meaning that the output kWh of each system is economically similar. In addition the value of electrical energy through a Power Purchase Agreement (PPA) was a maximum of 79.79 times the value of a liter of diesel. Finally the Levelized Cost of Energy (LCOE) was calculated for two conditions in which the MWe was obtained from the fuel cell without and with the photovoltaic solar plant.
Design and Costs Analysis of Hydrogen Refuelling Stations Based on Different Hydrogen Sources and Plant Configurations
Jan 2022
Publication
In this study the authors present a techno-economic assessment of on-site hydrogen refuelling stations (450 kg/day of H2 ) based on different hydrogen sources and production technologies. Green ammonia biogas and water have been considered as hydrogen sources while cracking autothermal reforming and electrolysis have been selected as the hydrogen production technologies. The electric energy requirements of the hydrogen refuelling stations (HRSs) are internally satisfied using the fuel cell technology as power units for ammonia and biogas-based configurations and the PV grid-connected power plant for the water-based one. The hydrogen purification where necessary is performed by means of a Palladium-based membrane unit. Finally the same hydrogen compression storage and distribution section are considered for all configurations. The sizing and the energy analysis of the proposed configurations have been carried out by simulation models adequately developed. Moreover the economic feasibility has been performed by applying the life cycle cost analysis. The ammonia-based configurations are the best solutions in terms of hydrogen production energy efficiency (>71% LHV) as well as from the economic point of view showing a levelized cost of hydrogen (LCOH) in the range of 6.28 EUR/kg to 6.89 EUR/kg a profitability index greater than 3.5 and a Discounted Pay Back Time less than five years.
High CO2 Absorption Capacity of Metal-Based Ionic Liquids: A Molecular Dynamics Study
Apr 2020
Publication
The absorption of CO2 is of importance in carbon capture utilization and storage technology for greenhouse gas control. In the present work we clarified the mechanism of how metal-based ionic liquids (MBILs) Bmim[XCln]m (X is the metal atom) enhance the CO2 absorption capacity of ILs via performing molecular dynamics simulations. The sparse hydrogen bond interaction network constructed by CO2 and MBILs was identified through the radial distribution function and interaction energy of CO2-ion pairs which increase the absorption capacity of CO2 in MBILs. Then the dynamical properties including residence time and self-diffusion coefficient confirmed that MBILs could also promote the diffusion process of CO2 in ILs. That's to say the MBILs can enhance the CO2 absorption capacity and the diffusive ability simultaneously. Based on the analysis of structural energetic and dynamical properties the CO2 absorption capacity of MBILs increases in the order Cl− → [ZnCl4]2-→ [CuCl4]2-→ [CrCl4]- → [FeCl4]- revealing the fact that the short metal–Cl bond length and small anion volume could facilitate the performance of CO2 absorbing process. These findings show that the metal–Cl bond length and effective volume of the anion can be the effective factors to regulate the CO2 absorption process which can also shed light on the rational molecular design of MBILs for CO2 capture and other key chemical engineering processes such as IL-based gas sensors nano-electrical devices and so on.
Hydrolysis Hydrogen Production Mechanism of Mg10Ni10Ce Alloy Surface Modified by SnO2 Nanotubes in Different Aqueous Systems
May 2020
Publication
(Mg-10wt.%Ni)-10wt.%Ce (Mg10Ni10Ce) was ball-milled with SnO2 nanotubes and Mg10Ni10Ce-xSnO2 (x=0 5 10 and 15wt.%) composites have been prepared. The phase compositions microstructures morphologies and hydrolysis H2 generation performance in different aqueous systems (distilled water tap water and simulated seawater) have been investigated and the corresponding hydrolysis mechanism of Mg10Ni10Ce and Mg10Ni10Ce-SnO2 has been proposed. Adding a small amount of SnO2 nanotubes can significantly enhance the hydrolysis reaction of Mg10Ni10Ce especially the initial hydrolysis kinetics and the final H2 generation yield. Unfortunately the Mg10Ni10Ce-xSnO2 hardly react with distilled water at room temperature. The hydrolysis reaction rate of Mg10Ni10Ce-5SnO2 composite in tap water is still very slow with only 17.3% generation yield after 1 hour at 303 K. Fortunately in simulated seawater (3.5wt.% NaCl solution) the hydrolytic H2 generation behavior of the Mg10Ni10Ce-5SnO2 composite has been greatly improved which can release as high as 468.6 mL/g H2 with about 60.9% generation yield within 30 s at 303 K. The Cl- destroys the passivation layer on Mg-Ni-Ce alloy surface and the added SnO2 nanotubes accelerate the hydrolysis reaction rate and enhance the H2 generation yield. The Mg10Ni10Ce-5SnO2 composite can rapidly generate a large amount of H2 in simulate seawater in a short time which is expected to be applied on portable H2 generators in the future.
The Status and Prospects of Hydrogen and Fuel Cell Technology in the Philippines
Jan 2022
Publication
As a developing country the Philippines must balance its rapid industrialization efforts with the realities and consequences of climate change on the country. A feasible option to achieve this is increasing the share of renewables in power generation coupled with energy storage technology. This paper examines the present situation and opportunities for development of hydrogen and fuel cell technology in the Philippines as promising alternatives with proven applications in niche energy demand sectors aside from renewables integration. Although the Philippines is considered a latecomer there is significant renewable resource potential available local experts and trained talents and enabling legislations in the country that provide opportunities in harnessing fuel cell technologies for the transition to energy self-sufficient and low-carbon society. Current advancement of the technology in the country is limited to an initial 5-year roadmap focused on component development from cheap and local materials. Provisions for large-scale hydrogen infrastructure have not yet been realized which is comparable to the early stages of development in other countries that are also pursuing fuel cell technology. Strong industry-academe partnerships should be pursued through a specific legislated agency to ensure future development of this technology for the country’s benefit. Lastly applications in distributed power generation poised to be a lucrative direction as demonstration and validation with other potential uses such as transportation remains a challenge.
Hydrogen Council Report- Decarbonization Pathways
Jan 2021
Publication
This report shows that low-carbon hydrogen supply at scale is economically and environmentally feasible and will have significant societal benefits if the right localised approach and best-practices for production are used. The report also demonstrates that there is not one single hydrogen production pathway to achieve low lifecycle greenhouse gas (GHG) emissions but rather the need for a fact-based approach that leverages regional resources and includes a combination of different production pathways. This will achieve both emission and cost reductions ultimately helping to decarbonize the energy system and limit global warming.
In 2020 more than 15 countries launched major hydrogen plans and policies and industry players announced new projects of more than 35GW until 2030. As this hydrogen momentum accelerates it is increasingly clear that decision makers must put the focus on decarbonization to ensure hydrogen can fulfil its potential as a key solution in the global clean energy transition making a significant contribution to net zero emissions. To support this effort the two-part Hydrogen Council report provides new data based on an assessment of the GHG emissions generated through different hydrogen supply pathways and the lifecycle GHG emissions for different hydrogen applications (see report part 1 – A Life-cycle Assessment). In addition the report explores 3 hypothetical hydrogen supply scenarios to measure the feasibility and impact of deploying renewable and low-carbon hydrogen at scale (report part 2 – Potential Supply Scenarios).
The report outlines that there are many ways of producing hydrogen and although GHG emissions vary widely very high CO2 savings can be achieved across a broad range of different hydrogen production pathways and end-uses. For example while “green” hydrogen produced through water electrolysis with renewable power achieves the lowest emissions “blue” hydrogen produced from natural gas with high CO2 capture rate and storage can also achieve low emissions if best technologies are used and best practices are followed. Across eight illustrative pathways explored in the report analysis shows that if hydrogen is used significant GHG emission reductions can be made: as much as 60-90% or more compared to conventional fossil alternatives. The study also looked into the gross water demand of hydrogen supply pathways. Water electrolysis has a very low specific water demand of 9 kg per kg of hydrogen compared to cooling of thermal power plants (hundreds of kg/kg) or biomass cultivation (hundreds to thousands of kg/kg).
Furthermore low-carbon hydrogen supply at scale is fully achievable. Having investigated two hypothetical boundary scenarios (a “green-only” and a “blue-only” scenario) to assess the feasibility and impact of decarbonized hydrogen supply the report found that both scenarios are feasible: they are not limited by the world’s renewables potential or carbon sequestration (CCS) capacities and they do not exceed the speed at which industry can scale. In the Hydrogen Council’s “Scaling up” study a demand of 21800 TWh hydrogen has been identified for the year 2050. To achieve this a compound annual growth rate of 30-35% would be needed for electrolysers and CCS. This deployment rate is in line with the growth of the offshore wind and solar PV industry over the last decade.
Hydrogen Council data released in January 2020 showed that a wide range of hydrogen applications can become competitive by 2030 driven also by falling costs of renewable and low-carbon hydrogen[1]. The new study indicates that a combination of “green” and “blue” production pathways would lead to hydrogen cost reductions relative to either boundary scenario. By making use of the near-term cost advantage of “blue” while also scaling up “green” hydrogen as the most cost-efficient option in many regions in the medium and long-term the combined approach lowers average hydrogen costs between now and 2050 relative to either boundary scenario.
Part 1 – A Life-cycle Assessment
You can download the full reports from the Hydrogen Council website
Hydrogen Council Report- Decarbonization Pathways Part 1: Life Cycle Assessment here
Hydrogen Council Report-Decarbonization Pathways Part 2: Supply Scenarios here
An executive summary of the whole project can be found here
In 2020 more than 15 countries launched major hydrogen plans and policies and industry players announced new projects of more than 35GW until 2030. As this hydrogen momentum accelerates it is increasingly clear that decision makers must put the focus on decarbonization to ensure hydrogen can fulfil its potential as a key solution in the global clean energy transition making a significant contribution to net zero emissions. To support this effort the two-part Hydrogen Council report provides new data based on an assessment of the GHG emissions generated through different hydrogen supply pathways and the lifecycle GHG emissions for different hydrogen applications (see report part 1 – A Life-cycle Assessment). In addition the report explores 3 hypothetical hydrogen supply scenarios to measure the feasibility and impact of deploying renewable and low-carbon hydrogen at scale (report part 2 – Potential Supply Scenarios).
The report outlines that there are many ways of producing hydrogen and although GHG emissions vary widely very high CO2 savings can be achieved across a broad range of different hydrogen production pathways and end-uses. For example while “green” hydrogen produced through water electrolysis with renewable power achieves the lowest emissions “blue” hydrogen produced from natural gas with high CO2 capture rate and storage can also achieve low emissions if best technologies are used and best practices are followed. Across eight illustrative pathways explored in the report analysis shows that if hydrogen is used significant GHG emission reductions can be made: as much as 60-90% or more compared to conventional fossil alternatives. The study also looked into the gross water demand of hydrogen supply pathways. Water electrolysis has a very low specific water demand of 9 kg per kg of hydrogen compared to cooling of thermal power plants (hundreds of kg/kg) or biomass cultivation (hundreds to thousands of kg/kg).
Furthermore low-carbon hydrogen supply at scale is fully achievable. Having investigated two hypothetical boundary scenarios (a “green-only” and a “blue-only” scenario) to assess the feasibility and impact of decarbonized hydrogen supply the report found that both scenarios are feasible: they are not limited by the world’s renewables potential or carbon sequestration (CCS) capacities and they do not exceed the speed at which industry can scale. In the Hydrogen Council’s “Scaling up” study a demand of 21800 TWh hydrogen has been identified for the year 2050. To achieve this a compound annual growth rate of 30-35% would be needed for electrolysers and CCS. This deployment rate is in line with the growth of the offshore wind and solar PV industry over the last decade.
Hydrogen Council data released in January 2020 showed that a wide range of hydrogen applications can become competitive by 2030 driven also by falling costs of renewable and low-carbon hydrogen[1]. The new study indicates that a combination of “green” and “blue” production pathways would lead to hydrogen cost reductions relative to either boundary scenario. By making use of the near-term cost advantage of “blue” while also scaling up “green” hydrogen as the most cost-efficient option in many regions in the medium and long-term the combined approach lowers average hydrogen costs between now and 2050 relative to either boundary scenario.
Part 1 – A Life-cycle Assessment
- The life-cycle assessment (LCA) analysis in this study addresses every aspect of the supply chain from primary energy extraction to end use. Eight primary-energy-to-hydrogen value chains have been selected for illustrative purposes.
- Across the hydrogen pathways and applications depicted very high to high GHG emission reduction can be demonstrated using green (solar wind) and blue hydrogen.
- In the LCA study renewables + electrolysis shows strongest GHG reduction of the different hydrogen supply pathways assessed in this study with a best-case blue hydrogen pathway also coming into the same order of magnitude.
- Currently the vast majority of hydrogen is produced by fossil pathways. To achieve a ten-fold build-out of hydrogen supply by 2050 as envisaged by the Hydrogen Council in its ‘Scaling Up’ report (2017) the existing use of hydrogen – and all its many potential new roles – need to be met by decarbonized sources.
- Three hypothetical supply scenarios with decarbonized hydrogen sources are considered in the study: 1) a “green-only” renewables-based world; 2) a “blue-only” world relying on carbon sequestration; and 3) a combined scenario that uses a region-specific combination of green and blue hydrogen based on the expected regional cost development of each source.
- The study finds that a decarbonized hydrogen supply is possible regardless of the production pathway: while both the green and blue boundary scenario would be highly ambitious regarding the required speed of scale-up they do not exceed the world’s resources on either renewable energy or carbon sequestration capabilities.
- A combination of production pathways would result in the least-cost global supply over the entire period of scale-up. It does so by making best use of the near-term cost advantage of “blue” in some regions while simultaneously achieving a scale-up in electrolysis.
- In reality the decarbonized supply scenario will combine a range of different renewable and low-carbon hydrogen production pathways that are optimally suited to local conditions political and societal preferences and regulations as well as industrial and cost developments for different technologies.
You can download the full reports from the Hydrogen Council website
Hydrogen Council Report- Decarbonization Pathways Part 1: Life Cycle Assessment here
Hydrogen Council Report-Decarbonization Pathways Part 2: Supply Scenarios here
An executive summary of the whole project can be found here
The Emotional Dimensions of Energy Projects: Anger, Fear, Joy and Pride About the First Hydrogen Fuel Station in the Netherlands
May 2018
Publication
Citizens’ emotional responses to energy technology projects influence the success of the technology’s implementation. Contrary to popular belief these emotions can have a systematic base. Bringing together insights from appraisal theory and from technology acceptance studies this study develops and tests hypotheses regarding antecedents of anger fear joy and pride about a local hydrogen fuel station (HFS). A questionnaire study was conducted among 271 citizens living near the first publicly accessible HFS in the Netherlands around the time of its implementation. The results show that anger is significantly explained by (from stronger to weaker effects) perceived procedural and distributive unfairness and fear by distributive unfairness perceived safety procedural unfairness gender and prior awareness. Joy is significantly explained by perceived environmental outcomes and perceived usefulness and pride by prior awareness perceived risks trust in industry and perceived usefulness. The study concludes that these predictors are understandable practical and moral considerations which can and should be taken into account when developing and executing a project.
How EU Legislation Can Drive an Uptake of Sustainable Advanced Fuels in Aviation
Jul 2020
Publication
The report calls for a focus on new advanced alternative fuels in particular synthetic kerosene (efuels) which have the capacity to substantially reduce emissions and be scaled up to meet the fuel demands of the sector.
For aviation to reach zero emissions sustainable advanced fuels are needed to replace fossil kerosene currently used by the sector. The European Green Deal (EGD) includes a legislative proposal which would bring about a long overdue development and uptake of such fuels for the sector that legislative proposal is now being developed under the EU’s ReFuelEU initiative. However this initiative will only succeed if its support is limited to those fuels which can truly deliver emission reductions and which can be scaled up sustainably to meet the demand from the aviation sector. The paper recommends how such objectives can be achieved.
The ReFuelEU proposal should focus on these fuels with an ambitious programme combining mandates with financial support so that Europe's aviation sector is put on a pathway to net zero emissions.
Link to document download on Transport & Environment Website
For aviation to reach zero emissions sustainable advanced fuels are needed to replace fossil kerosene currently used by the sector. The European Green Deal (EGD) includes a legislative proposal which would bring about a long overdue development and uptake of such fuels for the sector that legislative proposal is now being developed under the EU’s ReFuelEU initiative. However this initiative will only succeed if its support is limited to those fuels which can truly deliver emission reductions and which can be scaled up sustainably to meet the demand from the aviation sector. The paper recommends how such objectives can be achieved.
The ReFuelEU proposal should focus on these fuels with an ambitious programme combining mandates with financial support so that Europe's aviation sector is put on a pathway to net zero emissions.
Link to document download on Transport & Environment Website
A Portfolio of Powertrains for the UK: An Energy Systems Analysis
Jul 2014
Publication
There has recently been a concerted effort to commence a transition to fuel cell vehicles (FCVs) in Europe. A coalition of companies released an influential McKinsey-coordinated report in 2010 which concluded that FCVs are ready for commercial deployment. Public–private H2Mobility programmes have subsequently been established across Europe to develop business cases for the introduction of FCVs. In this paper we examine the conclusions of these studies from an energy systems perspective using the UK as a case study. Other UK energy system studies have identified only a minor role for FCVs after 2030 but we reconcile these views by showing that the differences are primarily driven by different data assumptions rather than methodological differences. Some energy system models do not start a transition to FCVs until around 2040 as they do not account for the time normally taken for the diffusion of new powertrains. We show that applying dynamic growth constraints to the UK MARKAL energy system model more realistically represents insights from innovation theory. We conclude that the optimum deployment of FCVs from an energy systems perspective is broadly in line with the roadmap developed by UK H2Mobility and that a transition needs to commence soon if FCVs are to become widespread by 2050.
Electrocatalysts Based on Metal@carbon Core@shell Nanocomposites: An Overview
Aug 2018
Publication
Developing low-cost high-performance catalysts is of fundamental significance for electrochemical energy conversion and storage. In recent years metal@carbon core@shell nanocomposites have emerged as a unique class of functional nanomaterials that show apparent electrocatalytic activity towards a range of reactions such as hydrogen evolution reaction oxygen evolution reaction oxygen reduction reaction and CO2 reduction reaction that are important in water splitting fuel cells and metal-air batteries. The activity is primarily attributed to interfacial charge transfer from the metal core to the carbon shell that manipulate the electronic interactions between the catalyst surface and reaction intermediates and varies with the structures and morphologies of the metal core (elemental composition core size etc.) and carbon shell (doping layer thickness etc.). Further manipulation can be achieved by the incorporation of a third structural component. A perspective is also included highlighting the current gap between theoretical modeling and experimental results and technical challenges for future research.
Concepts for Preventing Metal Dissolution From Stainless-steel Bipolar Plates in PEM Fuel Cells
Dec 2021
Publication
The bipolar plate (BPP) is a component with vast cost-reduction potential in proton exchange membrane fuel cells (PEMFCs). Apart from mechanical and heat transfer requirements the most desired BPP properties are high corrosion and low electrical contact resistance. In this study we confirm that due to ionic decoupling between BPPs and electrodes the surface potentials of the BPPs remain stable even at varying operation loads. These mild potentials in combination with low metal-ion leeching due to passive-transpassive-passive dissolution in stainless steels suggest that low-cost carbon-coated stainless steel can readily be used as a BPP in PEMFCs. To prove this single-fuel cell tests were carried out under realistic driving conditions including electrochemical analysis in-situ contact-resistance measurements and post-mortem investigation of the membrane electrode assembly (MEA) by inductively coupled plasma trace-metal analysis combined with electron microscopy and Auger spectroscopy of the BPPs. The results show that due to the ionic decoupling conditions at the BPP surfaces are much less corrosive than previously thought. Furthermore carbon-coated stainless-steel BPPs prove to be unaffected by global hydrogen starvation which causes severe MEA degradation independent of the presence or absence of BPPs.
Improvement of Low Temperature Activity and Stability of Ni Catalysts with Addition of Pt for Hydrogen Production Via Steam Reforming of Ethylene Glycol
Nov 2018
Publication
Hydrogen production by steam reforming of ethylene glycol (EG) at 300 °C was investigated over SiO2 and CeO2 supported Pt–Ni bimetallic catalysts prepared by incipient wetness impregnation methods. It was observed that impregnation sequence of Pt and Ni can affect the performance of catalysts apparently. Catalyst with Pt first and then Ni addition showed higher EG conversion and H2 yield owing to the Ni enrichment on the surface and the proper interaction between Pt and Ni. It was observed that although SiO2 supported catalysts exhibited better activity and H2 selectivity CeO2 supported ones had better stability. This is attributed to the less coke formation on CeO2. Increasing Pt/Ni ratio enhanced the reaction activity and Pt3–Ni7 catalysts with 3 wt% Pt and 7 wt% Ni showed the highest activity and stability. Ni surficial enrichment facilitated the C—C bond rupture and water gas shift reactions; and Pt addition inhibited methanation reaction. Electron transfer and hydrogen spillover from Pt to Ni suppressed carbon deposition. These combined effects lead to the excellent performance of Pt3–Ni7 supported catalysts.
Progress in Power-to-Gas Energy Systems
Dec 2022
Publication
Hydrogen is expected to become a key component in the decarbonized energy systems of the future. Its unique chemical characteristics make hydrogen a carbon-free fuel that is suitable to be used as broadly as fossil fuels are used today. Since hydrogen can be produced by splitting water molecules using electricity as the only energy input needed hydrogen offers the opportunity to produce a fully renewable fuel if the electricity input also only stems from renewable sources. Once renewable electricity is converted into hydrogen it can be stored over long periods of time and transported over long even intercontinental distances. Underground hydrogen storage pipelines compressors liquefaction-units and transportation ships are infrastructures and suitable technologies to establish a global hydrogen energy system. Several chemical synthesis routes exist to produce more complex products from green hydrogen to fulfil the demands of various end-users and industries. One exemplary power-to-gas product is methane which can be used as a natural gas substitute. Furthermore ammonia alcohols kerosene and all other important products from hydrocarbon chemistry can be synthesized using green hydrogen.
Hydrogen for Heating? Decarbonization Options for Households in the United Kingdom in 2050
Dec 2020
Publication
The heating sector makes up 10% of the United Kingdom’s carbon footprint and residential homes account for a majority of demand. At present central heating from a natural gas-fired boiler is the most common system in the UK but low or zero-carbon hydrogen and renewable electricity are the two primary energy replacement options to reduce the carbon footprint. An important consideration is how using either energy source would affect heating costs. This assessment projects the costs for a typical single-family UK household and climate performance in 2050 using low-GHG or GHG-neutral hydrogen renewable electricity or a combination of both. The cost of using boilers or fuel cells in 2050 with two types of hydrogen are assessed: produced via steam-methane reforming (SMR) combined with carbon capture and storage (CCS) and electrolysis using zero-carbon renewable electricity. The costs of heat pumps the most promising heating technology for the direct use of renewable electricity are also assessed in two scenarios: a heat pump only and a hybrid heat pump with an auxiliary hydrogen boiler.
You can download this document from the International Council On Clean Transportation website linked here
You can download this document from the International Council On Clean Transportation website linked here
Genome-wide Transcriptome Analysis of Hydrogen Production in the Cyanobacterium Synechocystis: Towards the Identification of New Players
Dec 2012
Publication
We report the development of new tools and methods for facile integration and meaningful representation of high throughput data generated by genome-wide analyses of the model cyanobacterium Synechocystis PCC6803 for future genetic engineering aiming at increasing its level of hydrogen photoproduction. These robust tools comprise new oligonucleotide DNA microarrays to monitor the transcriptomic responses of all 3725 genes of Synechocystis and the SVGMapping method and custom-made templates to represent the metabolic reprogramming for improved hydrogen production. We show for the first time that the AbrB2 repressor of the hydrogenase-encoding operon also regulates metal transport and protection against oxidative stress as well as numerous plasmid genes which have been overlooked so far. This report will stimulate the construction and global analysis of hydrogen production mutants with the prospect of developing powerful cell factories for the sustainable production of hydrogen as well as investigations of the probable role of plasmids in this process.
Decarbonising Ships, Planes and Trucks: An Analysis of Suitable Low-carbon Fuels for the Maritime, Aviation and Haulage Sectors
Jan 2021
Publication
The high environmental impacts of transport mean that there is an increasing interest in utilising low-carbon alternative energy carriers and powertrains within the sector. While electricity has been mooted as the energy carrier of choice for passenger vehicles as the mass and range of the vehicle increases electrification becomes more difficult. This paper reviews the shipping aviation and haulage sectors and a range of low-carbon energy carriers (electricity biofuels hydrogen and electro fuels) that can be used to decarbonise them. Energy carriers were assessed based on their energy density specific energy cost lifecycle greenhouse gas emissions and land-use. In terms of haulage current battery electric vehicles may be technically feasible however the specific energy of current battery technology reduces the payload capacity and range when compared to diesel. To alleviate these issues biomethane represents a mature technology with potential co-benefits while hydrogen is close to competitiveness but requires significant infrastructure. Energy density issues preclude the use of batteries in shipping which requires energy dense liquids or compressed gaseous fuels that allow for retrofits/current hull designs with methanol being particularly appropriate here. Future shipping may be achieved with ammonia or hydrogen but hull design will need to be changed significantly. Regulations and aircraft design mean that commercial aviation is dependant on drop-in jet fuels for the foreseeable future with power-to-liquid fuels being deemed the most suitable option due to the scales required. Fuel costs and a lack of refuelling infrastructure were identified as key barriers facing the uptake of alternatives with policy and financial incentives required to encourage the uptake of low-carbon fuels.
Recent Developments in Carbon-Based Nanocomposites for Fuel Cell Applications: A Review
Jan 2022
Publication
Carbon-based nanocomposites have developed as the most promising and emerging materials in nanoscience and technology during the last several years. They are microscopic materials that range in size from 1 to 100 nanometers. They may be distinguished from bulk materials by their size shape increased surface-to-volume ratio and unique physical and chemical characteristics. Carbon nanocomposite matrixes are often created by combining more than two distinct solid phase types. The nanocomposites that were constructed exhibit unique properties such as significantly enhanced toughness mechanical strength and thermal/electrochemical conductivity. As a result of these advantages nanocomposites have been used in a variety of applications including catalysts electrochemical sensors biosensors and energy storage devices among others. This study focuses on the usage of several forms of carbon nanomaterials such as carbon aerogels carbon nanofibers graphene carbon nanotubes and fullerenes in the development of hydrogen fuel cells. These fuel cells have been successfully employed in numerous commercial sectors in recent years notably in the car industry due to their cost-effectiveness eco-friendliness and long-cyclic durability. Further; we discuss the principles reaction mechanisms and cyclic stability of the fuel cells and also new strategies and future challenges related to the development of viable fuel cells.
Novel Fuzzy Control Energy Management Strategy for Fuel Cell Hybrid Electric Vehicles Considering State of Health
Oct 2021
Publication
Due to the low efficiency and high pollution of conventional internal combustion engine vehicles the fuel cell hybrid electric vehicles are expected to play a key role in the future of clean energy transportation attributed to the long driving range short hydrogen refueling time and environmental advantages. The development of energy management strategies has an important impact on the economy and durability but most strategies ignore the aging of fuel cells and the corresponding impact on hydrogen consumption. In this paper a rule-based fuzzy control strategy is proposed based on the constructed data-driven online estimation model of fuel cell health. Then a genetic algorithm is used to optimize this fuzzy controller where the objective function is designed to consider both the economy and durability by combining the hydrogen consumption cost and the degradation cost characterized by the fuel cell health status. Considering that the rule-based strategy is more sensitive to operating conditions this paper uses an artificial neural network for predictive control. The results are compared with those obtained from the genetic algorithm optimized fuzzy controller and are found to be very similar where the prediction accuracy is assessed using MAPE RMSE and 10-fold cross-validation. Experiments show that the developed strategy has a good generalization capability for variable driving cycles.
Effects of Quantum Confinement of Hydrogen in Nanocavities – Experimental INS Results and New Insights
Jun 2020
Publication
Current developments of non-relativistic quantum mechanics appear to predict and reveal counter-intuitive dynamical effects of hydrogen in nanostructured materials that are of considerable importance for basic research as well as for technological applications. In this review the experimental focus is on H2O and H molecules in carbon nanotubes and other nanocavities that have been experimentally investigated using the well-established technique of incoherent inelastic neutron scattering (INS). For instance the momentum and energy transfers as obtained from the commonly used standard data analysis techniques from a
(I) H2 molecule in a C-nanotube resulting in a roto-translational motion along the nanotube axis seems to (1) either violate the standard conservation laws or (2) to attribute to the H molecule undergoing translation the effective mass a.m.u. (atomic mass units) instead of the expected 2 a.m.u. A similar striking anomalous effect has been found in the neutron-H scattering from the
(II) H2O molecules in nano-channels of some solid materials in which O-H stretching vibrations along the channel axis are created.
The results of this scattering process seem to once again either violate the standard conservation laws or to attribute to the effective mass of the struck H2 molecule as a.m.u. instead of the expected value of 1 a.m.u. We show that these counterintuitive observations from the INS studies have no conventional interpretation within the standard non-relativistic scattering theory. However they can be qualitatively interpreted “from first principles” within the framework of modern theories of
(III) time-symmetric quantum dynamics as provided by the weak values (WV) and two-state- vector formalism (TSVF)
and/or
(IV) quantum correlations especially quantum discord (QD) and quantum thermodynamics (QTD).
The theoretical analysis provides an intuitive understanding of the experimental results gives strong evidence that the nano-structured cavities do represent quantum systems which participate significantly in the dynamics of the neutron-H scattering and surprisingly shows that new physical information can be derived from the experimental data. This latter point may also have far-reaching consequences for technology and material sciences (e.g. fuel cells H storage materials etc.). Moreover novel insights into the short-lived quantum dynamics and/or quantum information theory can be gained.
(I) H2 molecule in a C-nanotube resulting in a roto-translational motion along the nanotube axis seems to (1) either violate the standard conservation laws or (2) to attribute to the H molecule undergoing translation the effective mass a.m.u. (atomic mass units) instead of the expected 2 a.m.u. A similar striking anomalous effect has been found in the neutron-H scattering from the
(II) H2O molecules in nano-channels of some solid materials in which O-H stretching vibrations along the channel axis are created.
The results of this scattering process seem to once again either violate the standard conservation laws or to attribute to the effective mass of the struck H2 molecule as a.m.u. instead of the expected value of 1 a.m.u. We show that these counterintuitive observations from the INS studies have no conventional interpretation within the standard non-relativistic scattering theory. However they can be qualitatively interpreted “from first principles” within the framework of modern theories of
(III) time-symmetric quantum dynamics as provided by the weak values (WV) and two-state- vector formalism (TSVF)
and/or
(IV) quantum correlations especially quantum discord (QD) and quantum thermodynamics (QTD).
The theoretical analysis provides an intuitive understanding of the experimental results gives strong evidence that the nano-structured cavities do represent quantum systems which participate significantly in the dynamics of the neutron-H scattering and surprisingly shows that new physical information can be derived from the experimental data. This latter point may also have far-reaching consequences for technology and material sciences (e.g. fuel cells H storage materials etc.). Moreover novel insights into the short-lived quantum dynamics and/or quantum information theory can be gained.
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