United Kingdom
Optimal Energy Management System Using Biogeography Based Optimization for Grid-connected MVDC Microgrid with Photovoltaic, Hydrogen System, Electric Vehicles and Z-source Converters
Oct 2021
Publication
Currently the technology associated with charging stations for electric vehicles (EV) needs to be studied and improved to further encourage its implementation. This paper presents a new energy management system (EMS) based on a Biogeography-Based Optimization (BBO) algorithm for a hybrid EV charging station with a configuration that integrates Z-source converters (ZSC) into medium voltage direct current (MVDC) grids. The EMS uses the evolutionary BBO algorithm to optimize a fitness function defining the equivalent hydrogen consumption/generation. The charging station consists of a photovoltaic (PV) system a local grid connection two fast charging units and two energy storage systems (ESS) a battery energy storage (BES) and a complete hydrogen system with fuel cell (FC) electrolyzer (LZ) and hydrogen tank. Through the use of the BBO algorithm the EMS manages the energy flow among the components to keep the power balance in the system reducing the equivalent hydrogen consumption and optimizing the equivalent hydrogen generation. The EMS and the configuration of the charging station based on ZSCs are the main contributions of the paper. The behaviour of the EMS is demonstrated with three EV connected to the charging station under different conditions of sun irradiance. In addition the proposed EMS is compared with a simpler EMS for the optimal management of ESS in hybrid configurations. The simulation results show that the proposed EMS achieves a notable improvement in the equivalent hydrogen consumption/generation with respect to the simpler EMS. Thanks to the proposed configuration the output voltage of the components can be upgraded to MVDC while reducing the number of power converters compared with other configurations without ZSC.
Progress and Challenges on the Thermal Management of Electrochemical Energy Conversion and Storage Technologies: Fuel Cells, Electrolysers, and Supercapacitors
Oct 2021
Publication
It is now well established that electrochemical systems can optimally perform only within a narrow range of temperature. Exposure to temperatures outside this range adversely affects the performance and lifetime of these systems. As a result thermal management is an essential consideration during the design and operation of electrochemical equipment and can heavily influence the success of electrochemical energy technologies. Recently significant attempts have been placed on the maturity of cooling technologies for electrochemical devices. Nonetheless the existing reviews on the subject have been primarily focused on battery cooling. Conversely heat transfer in other electrochemical systems commonly used for energy conversion and storage has not been subjected to critical reviews. To address this issue the current study gives an overview of the progress and challenges on the thermal management of different electrochemical energy devices including fuel cells electrolysers and supercapacitors. The physicochemical mechanisms of heat generation in these electrochemical devices are discussed in-depth. Physics of the heat transfer techniques currently employed for temperature control are then exposed and some directions for future studies are provided.
Sorption-enhanced Steam Methane Reforming for Combined CO2 Capture and Hydrogen Production: A State-of-the-Art Review
Oct 2021
Publication
The European Commission have just stated that hydrogen would play a major role in the economic recovery of post-COVID-19 EU countries. Hydrogen is recognised as one of the key players in a fossil fuel-free world in decades to come. However commercially practiced pathways to hydrogen production todays are associated with a considerable amount of carbon emissions. The Paris Climate Change Agreement has set out plans for an international commitment to reduce carbon emissions within the forthcoming decades. A sustainable hydrogen future would only be achievable if hydrogen production is “designed” to capture such emissions. Today nearly 98% of global hydrogen production relies on the utilisation of fossil fuels. Among these steam methane reforming (SMR) boasts the biggest share of nearly 3 50% of the global generation. SMR processes correspond to a significant amount of carbon emissions at various points throughout the process. Despite the dark side of the SMR processes they are projected to play a major role in hydrogen production by the first half of this century. This that a sustainable yet clean short/medium-term hydrogen production is only possible by devising a plan to efficiently capture this co-produced carbon as stated in the latest International Energy Agency (IEA) reports. Here we have carried out an in-depth technical review of the processes employed in sorption-enhanced steam methane reforming (SE-SMR) an emerging technology in low-carbon SMR for combined carbon capture and hydrogen production. This paper aims to provide an in-depth review on two key challenging elements of SE-SMR i.e. the advancements in catalysts/adsorbents preparation and current approaches in process synthesis and optimisation including the employment of artificial intelligence in SE-SMR processes. To the best of the authors‟ knowledge there is a clear gap in the literature where the above areas have been scrutinised in a systematic and coherent fashion. The gap is even more pronounced in the application of AI in SE-SMR technologies. As a result this work aims to fill this gap within the scientific literature.
CFD Simulations of Large Scale LH2 Dispersion in Open Environment
Sep 2021
Publication
An inter-comparison among partners’ CFD simulations has been carried out within the EU-funded project PRESLHY to investigate the dispersion of the mixture cloud formed from large scale liquid hydrogen release. Rainout experiments performed by Health and Safety Executive (HSE) have been chosen for the work. From the HSE experimental series trial-11 was selected forsimulation due to its conditions where only liquid flow at the nozzle was achieved. During trial-11 liquid hydrogen is spilled horizontally 0.5 m above a concrete pad from a 5 barg tank pressure through a 12 mm (1/2 inch) nozzle. The dispersion takes place outdoors and thus it is imposed to variant wind conditions. Comparison of the CFD results with the measurements at several sensors is presented and useful conclusions are drawn.
Current Status of Automotive Fuel Cells for Sustainable Transport
May 2019
Publication
Automotive proton-exchange membrane fuel cells (PEMFCs) have finally reached a state of technological readiness where several major automotive companies are commercially leasing and selling fuel cell electric vehicles including Toyota Honda and Hyundai. These now claim vehicle speed and acceleration refueling time driving range and durability that rival conventional internal combustion engines and in most cases outperform battery electric vehicles. The residual challenges and areas of improvement which remain for PEMFCs are performance at high current density durability and cost. These are expected to be resolved over the coming decade while hydrogen infrastructure needs to become widely available. Here we briefly discuss the status of automotive PEMFCs misconceptions about the barriers that platinum usage creates and the remaining hurdles for the technology to become broadly accepted and implemented.
A Numerical and Graphical Review of Energy Storage Technologies
Dec 2014
Publication
More effective energy production requires a greater penetration of storage technologies. This paper takes a looks at and compares the landscape of energy storage devices. Solutions across four categories of storage namely: mechanical chemical electromagnetic and thermal storage are compared on the basis of energy/power density specific energy/power efficiency lifespan cycle life self-discharge rates capital energy/power costs scale application technical maturity as well as environmental impact. It’s noted that virtually every storage technology is seeing improvements. This paper provides an overview of some of the problems with existing storage systems and identifies some key technologies that hold promise.
Calibration of Hydrogen Coriolis Flow Meters Using Nitrogen and Air and Investigation of the Influence of Temperature on Measurement Accuracy
Feb 2021
Publication
The performance of four Coriolis flow meters designed for use in hydrogen refuelling stations was evaluated with air and nitrogen by three members of the MetroHyVe JRP consortium; NEL METAS and CESAME EXADEBIT.<br/>A wide range of conditions were tested overall with gas flow rates ranging from (0.05–2) kg/min and pressures ranging from (20–86) bar. The majority of tests were conducted at nominal pressures of either 20 bar or 40 bar in order to match the density of hydrogen at 350 bar and 20 °C or 700 bar and −40 °C. For the conditions tested pressure did not have a noticeable influence on meter performance.<br/>When the flow meters were operated at ambient temperatures and within the manufacturer's recommended flow rate ranges errors were generally within ±1%. Errors within ±0.5% were achievable for the medium to high flow rates.<br/>The influence of temperature on meter performance was also studied with testing under both stable and transient conditions and temperatures as low as −40 °C.<br/>When the tested flow meters were allowed sufficient time to reach thermal equilibrium with the incoming gas temperature effects were limited. The magnitude and spread of errors increased but errors within ±2% were achievable at moderate to high flow rates. Conversely errors as high as 15% were observed in tests where logging began before temperatures stabilised and there was a large difference in temperature between the flow meter and the incoming gas.<br/>One of the flow meters tested with nitrogen was later installed in a hydrogen refuelling station and tested against the METAS Hydrogen Field Test Standard (HFTS). Under these conditions errors ranged from 0.47% to 0.91%. Testing with nitrogen at the same flow rates yielded errors of −0.61% to −0.82%.
Narratives for Natural Gas in a Decarbonising European Energy Market
Feb 2019
Publication
The advocacy narrative of the European Union gas community which focused on coal to gas switching and backing up renewables has failed to convince governments NGOs and media commentators that it can achieve post-2030 decarbonisation targets. The gas community therefore needs to develop decarbonisation narratives showing how it will develop commercial scale projects for biogas biomethane and hydrogen from power to gas (electrolysis) and reformed methane. COP21 carbon targets require an accelerating decline in EU methane demand starting around 2030. In 2050 the maximum projected availability of renewable gas is equivalent to 25 per cent of current EU gas demand. Maintaining current demand levels will therefore require very substantial volumes of hydrogen from reformed methane with carbon capture and storage (CCS). Pipeline gas and LNG suppliers will need to progressively decarbonise their product if it is to remain saleable in Europe. However networks face an existential threat unless they can maintain existing throughput while simultaneously adapting to a decarbonised product. Significant threats and challenges to these narratives include: short term geopolitical concerns stemming from dependence on Russian gas ‘hydrocarbon rejectionism’ and an inability of companies to invest for a post-2030 decarbonised future. Governments will need to shift current policy and regulatory frameworks from competition to decarbonisation which will require a ‘regulatory revolution’. In addition to government funding and regulatory support there will need to be very substantial corporate investment in projects for which there is currently no business case. Failure of the gas community to create and deliver credible decarbonisation narratives is likely to result in the adoption of electrification rather than gas decarbonisation options.
Challenges to the Future of LNG: Decarbonisation, Affordability, and Profitability
Oct 2019
Publication
Decarbonisation should be very much on the radar of new LNG projects currently taking FID commissioning around 2024-25 and planning to operate up to 2050. The LNG community needs to replace an `advocacy’ message – based on the generality of emissions from combustion of natural gas being lower than from other fossil fuels – with certified data on carbon and methane emissions from specific elements of the value chain for individual projects. As carbon reduction targets tighten over the coming decade LNG cargoes which do not have value chain emissions certified by accredited authorities or which fail to meet defined emission levels run the risk of progressively being deemed to have a lower commercial value and eventually being excluded from jurisdictions with the strictest standards. There will be no place in this process for confidentiality; nothing less than complete transparency of data and methodologies will be acceptable.<br/>In relation to affordability prospects for new projects look much better than they did three years ago. Cost estimates for most new projects suggest that they will be able to deliver profitably to most established and anticipated import markets at or below the wholesale prices prevailing in those markets over the past decade although affordability in south Asian countries may be challenging. But new projects need to factor in costs related to future decarbonisation requirements in both exporting and importing countries. To the extent that LNG suppliers can meet standards through relatively low-cost offsets – forest projects low-cost biogas and biomethane – this may not greatly impact their commercial viability. However any requirement to transform methane into hydrogen with CCS in either the exporting or importing country would substantially impact project economics and the affordability of LNG relative to other energy choices.
A Mountain to Climb? Tracking Progress in Scaling Up Renewable Gas Production in Europe
Oct 2019
Publication
In the last couple of years there has been increasing recognition by key players in the European gas industry that to mitigate the risk of terminal decline in the context of a decarbonising energy system there will need to be rapid scale up of decarbonised gas. This has led to several projections of the scale of decarbonised gas which could potentially be supplied by 2030 2040 or 2050. This paper joint with the Sustainable Gas Institute at Imperial College London considers the very significant rate of scale up and the significant cost reductions contemplated by such projections. Based on a database of actual announced projects (both committed and in earlier stages of development) for production of decarbonised gas it then considers the extent to which project activity is consistent with meeting the ambitious projections. It identifies a significant gap in current levels of activity largely because there is not yet sufficient economic incentive for investors to develop the required projects. It is intended that this paper will form the basis of continued tracking of the level of activity over the coming years to help inform industry players of further actions which may be required.
Hy4Heat Annex To Site Specific Safety Case for Hydrogen Community Demonstration - Work Package 7
May 2021
Publication
The Hy4Heat Safety Assessment has focused on assessing the safe use of hydrogen gas in certain types of domestic properties and buildings. The summary reports (the Precis and the Safety Assessment Conclusions Report) bring together all the findings of the work and should be looked to for context by all readers. The technical reports should be read in conjunction with the summary reports. While the summary reports are made as accessible as possible for general readers the technical reports may be most accessible for readers with a degree of technical subject matter understanding. All of the safety assessment reports have now been reviewed by the HSE<br/>Annex prepared to support Site Specific Safety Cases for hydrogen gas community demonstrations based on work undertaken by the Hy4Heat programme. It covers a collection of recommended risk reduction measures for application downstream of the Emergency Control Valve (ECV)
Thermoacoustic Instability Considerations for High Hydrogen Combustion in Lean Premixed Gas Turbine Combustors: A Review
Jan 2021
Publication
Hydrogen is receiving increasing attention as a versatile energy vector to help accelerate the transition to a decarbonised energy future. Gas turbines will continue to play a critical role in providing grid stability and resilience in future low-carbon power systems; however it is recognised that this role is contingent upon achieving increased thermal efficiencies and the ability to operate on carbon-neutral fuels such as hydrogen. An important consideration in the development of gas turbine combustors capable of operating with pure hydrogen or hydrogen-enriched natural gas are the significant changes in thermoacoustic instability characteristics associated with burning these fuels. This article provides a review of the effects of burning hydrogen on combustion dynamics with focus on swirl-stabilised lean-premixed combustors. Experimental and numerical evidence suggests hydrogen can have either a stabilising or destabilising impact on the dynamic state of a combustor through its influence particularly on flame structure and flame position. Other operational considerations such as the effect of elevated pressure and piloting on combustion dynamics as well as recent developments in micromix burner technology for 100% hydrogen combustion have also been discussed. The insights provided in this review will aid the development of instability mitigation strategies for high hydrogen combustion.
Study of Activity and Super-Capacitance Exhibited by Bifunctional Raney 2.0 Catalyst for Alkaline Water-Splitting Electrolysis
Dec 2020
Publication
Low-cost high-performance coatings for hydrogen production via electrolytic water-splitting are of great importance for de-carbonising energy. In this study the Raney2.0 coating was analysed using various electrochemical techniques to assess its absolute performance and it was confirmed to have an extremely low overpotential for hydrogen evolution of just 28 mV at 10 mA/cm2. It was also confirmed to be an acceptable catalyst for oxygen evolution making it the highest performing simple bifunctional electrocatalyst known. The coating exhibits an extremely high capacitance of up to 1.7 F/cm2 as well as being able to store 0.61 J/cm2 in the form of temporary hydride deposits. A new technique is presented that performs a best-fit of a transient simulation of an equivalent circuit containing a constant phase element to cyclic voltammetry measurements. From this the roughness factor of the coating was calculated to be approximately 40000 which is the highest figure ever reported for this type of material. The coating is therefore an extremely useful improved bifunctional coating for the continued roll-out of alkaline electrolysis for large-scale renewable energy capture via hydrogen production.
Delivering Net-zero Carbon Heat: Technoeconomic and Whole-system Comparisons of Domestic Electricity- and Hydrogen-driven Technologies in the UK
Apr 2022
Publication
Proposed sustainable transition pathways for moving away from natural gas in domestic heating focus on two main energy vectors: electricity and hydrogen. Electrification would be implemented by using vapourcompression heat pumps which are currently experiencing market growth in many countries. On the other hand hydrogen could substitute natural gas in boilers or be used in thermally–driven absorption heat pumps. In this paper a consistent thermodynamic and economic methodology is developed to assess the competitiveness of these options. The three technologies along with the option of district heating are for the first time compared for different weather/ambient conditions and fuel-price scenarios first from a homeowner’s and then from a wholeenergy system perspective. For the former two-dimensional decision maps are generated to identify the most cost-effective technologies for different combinations of fuel prices. It is shown that in the UK hydrogen technologies are economically favourable if hydrogen is supplied to domestic end-users at a price below half of the electricity price. Otherwise electrification and the use of conventional electric heat pumps will be preferred. From a whole-energy system perspective the total system cost per household (which accounts for upstream generation and storage as well as technology investment installation and maintenance) associated with electric heat pumps varies between 790 and 880 £/year for different scenarios making it the least-cost decarbonisation pathway. If hydrogen is produced by electrolysis the total system cost associated with hydrogen technologies is notably higher varying between 1410 and 1880 £/year. However this total system cost drops to 1150 £/year with hydrogen produced cost-effectively by methane reforming and carbon capture and storage thus reducing the gap between electricity- and hydrogen-driven technologies.
Hydrogen Tank Rupture in Fire in the Open Atmosphere: Hazard Distance Defined by Fireball
Feb 2021
Publication
The engineering correlations for assessment of hazard distance defined by a size of fireball after either liquid hydrogen spill combustion or high-pressure hydrogen tank rupture in a fire in the open atmosphere (both for stand-alone and under-vehicle tanks) are presented. The term “fireball size” is used for the maximum horizontal size of a fireball that is different from the term “fireball diameter” applied to spherical or semi-spherical shape fireballs. There are different reasons for a fireball to deviate from a spherical shape e.g. in case of tank rupture under a vehicle the non-instantaneous opening of tank walls etc. Two conservative correlations are built using theoretical analysis numerical simulations and experimental data available in the literature. The theoretical model for hydrogen fireball size assumes complete isobaric combustion of hydrogen in air and presumes its hemispherical shape as observed in the experiments and the simulations for tank rupturing at the ground level. The dependence of the fireball size on hydrogen mass and fireball’s diameter-to-height ratio is discussed. The correlation for liquid hydrogen release fireball is based on the experiments by Zabetakis (1964). The correlations can be applied as engineering tools to access hazard distances for scenarios of liquid or gaseous hydrogen storage tank rupture in a fire in the open atmosphere
The Path to Net Zero and Progress on Reducing Emissions in Wales
Dec 2020
Publication
These two joint reports required under the Environment (Wales) Act 2016 provide ministers with advice on Wales’ climate targets between now and 2050 and assess progress on reducing emissions to date. Our advice to the Welsh Government is set out in two parts:
Advice Report: The path to a Net Zero Wales provides recommendations on the actions that are needed in Wales including the legislation of a Net Zero target and package of policies to deliver it.
Progress Report: Reducing emissions in Wales looks back at the progress made in Wales since the 2016 Environment (Wales) Act was passed and assesses whether Wales is on track to meet its currently legislated emissions reductions targets.
This work is based on an extensive programme of analysis consultation and consideration by the Committee and its staff building on the evidence published last year for our Net Zero report. It is compatible with our advice on the UK’s Sixth Carbon Budget. In support of the advice in this report we have also published:
Advice Report: The path to a Net Zero Wales provides recommendations on the actions that are needed in Wales including the legislation of a Net Zero target and package of policies to deliver it.
Progress Report: Reducing emissions in Wales looks back at the progress made in Wales since the 2016 Environment (Wales) Act was passed and assesses whether Wales is on track to meet its currently legislated emissions reductions targets.
This work is based on an extensive programme of analysis consultation and consideration by the Committee and its staff building on the evidence published last year for our Net Zero report. It is compatible with our advice on the UK’s Sixth Carbon Budget. In support of the advice in this report we have also published:
- All the charts and data behind the report as well as a separate dataset for the scenarios which sets out more details and data on the pathways than can be included in this report.
- A public Call for Evidence several new research projects three expert advisory groups and deep dives into the roles of local authorities and businesses.
EU Hydrogen Strategy: A Case for Urgent Action Towards Implementation
Jul 2020
Publication
Interest in hydrogen as one route to the decarbonisation of energy systems has risen rapidly over the past few years with the publication of a number of hydrogen strategies from countries across the global energy economy. The momentum in Europe has increased sharply this month with the publication of an EU strategy to incorporate hydrogen into its plans for a net zero emission future. This Comment reviews the key elements of this strategy and provides an initial commentary on the main goals. We highlight the challenges that will be faced in meeting hydrogen production targets in particular via the “green hydrogen” route and analyse the plans for expanding the consumption of hydrogen in Europe. We also assess the infrastructure questions that will need to be answered if and when hydrogen takes on a greater role in the region and note the extensive state support that will be needed in the early years of the implementation of the strategy. Despite this though we applaud the ambition laid out by the EU and look forward to the provision of more detailed plans over the coming months and years.
Link to document on OIES website
Link to document on OIES website
A Review of Technical Advances, Barriers, and Solutions in the Power to Hydrogen Roadmap
Oct 2020
Publication
Power to hydrogen (P2H) provides a promising solution to the geographic mismatch between sources of renewable energy and the market due to its technological maturity flexibility and the availability of technical and economic data from a range of active demonstration projects. In this review we aim to provide an overview of the status of P2H analyze its technical barriers and solutions and propose potential opportunities for future research and industrial demonstrations. We specifically focus on the transport of hydrogen via natural gas pipeline networks and end-user purification. Strong evidence shows that an addition of about 10% hydrogen into natural gas pipelines has negligible effects on the pipelines and utilization appliances and may therefore extend the asset value of the pipelines after natural gas is depleted. To obtain pure hydrogen from hydrogen-enriched natural gas (HENG) mixtures end-user separation is inevitable and can be achieved through membranes adsorption and other promising separation technologies. However novel materials with high selectivity and capacity will be the key to the development of industrial processes and an integrated membrane-adsorption process may be considered in order to produce high-purity hydrogen from HENG. It is also worth investigating the feasibility of electrochemical separation (hydrogen pumping) at a large scale and its energy analysis. Cryogenics may only be feasible when liquefied natural gas (LNG) is one of the major products. A range of other technological and operational barriers and opportunities such as water availability byproduct (oxygen) utilization and environmental impacts are also discussed. This review will advance readers’ understanding of P2H and foster the development of the hydrogen economy.
The Future of Gas Networks – Key Issues for Debate
Sep 2019
Publication
The Oxford Institute for Energy Studies held a Workshop on “The Future of Gas Networks” to examine decarbonisation plans and the impact of the potential growth in the use of renewable and decarbonised gases in Europe. Participants included representatives from nine European gas network companies (both transmission and distribution) technical experts in decarbonisation regulators government officials and academics. This document summarises the seven key issues for debate arising from the Workshop discussions:
- The major gas networks recognise the need to prepare for and facilitate decarbonisation.
- The route to decarbonisation can take many forms though hydrogen is likely to feature in most networks. In larger countries solutions are likely to be regional rather than national.
- There are a number of pilot projects and targets/aspirations for 2050 – there is less clarity on how the targets will be achieved or on who will lead.
- Regulation is a key issue. In most countries existing regulatory objectives may need changing in order to align with government decarbonisation aspirations and the achievement of targets.
- There is a lack of consensus on whether and how market models might need to adapt.
- Detailed stakeholder analysis – and in particular customer attitudes – will be required.
- There are a range of important technical issues including standardisation data quality and transparency verification and certification to be considered.
Towards Net-zero Smart System: An Power Synergy Management Approach of Hydrogen and Battery Hybrid System with Hydrogen Safety Consideration
May 2022
Publication
The building system is one of key energy consumption sector in the market and low-carbon building will make a significant contribution for the worldwide carbon emission reduction. The multiple energy systems including renewable generations hydrogen energy and energy storage is the perspective answer to the net-zero building system. However the research gap lies in the synergy power management among the renewable flexible loads batteries and hydrogen energy systems and at the same time taking the unique characteristic of different energy sectors into account by power managing. This paper proposed the power management approach based on the game theory by which the different characteristics of the energy players are described via creating the competing relationship against net-zero emission objective so that to achieve the power synergy. Under the proposed power management method the hydrogen and battery hybrid system including the fuel cell electrolyzer and battery is designed and investigated as to unlock the power management regions and control constraints within the building system. Particularly for the hydrogen system within the hybrid system the safe and long-lifetime operation is considered respectively by high-efficiency and pressure constraints within the power management. Simulation results show that providing the same energy storage services for the building system the fuel cell with the proposed power management method sustains for 9.9 years much longer than that of equivalent consumption minimization (4.98) model predictive control (4.61) and rule-based method (7.69). Moreover the maximum tank temperature of the hydrogen tank is reduced by 3.4 K and 2.9 K compared with consumption minimization strategy and model predictive control. Also the real-time of the proposed power management is verified by a scaled-down experiment platform.
Extreme Energetic Materials at Ultrahigh Pressures
Jul 2020
Publication
Owing to their extremely high energy density single-bonded polymeric nitrogen and atomic metallic hydrogen are generally regarded as the ultimate energetic materials. Although their syntheses normally require ultrahigh pressures of several hundred gigapascals (GPa) which prohibit direct materials application research on their stability metastability and fundamental properties are valuable for seeking extreme energetic materials through alternative synthetic routes. Various crystalline and amorphous polymeric nitrogens have been discovered between 100 and 200 GPa. Metastability at ambient conditions has been demonstrated for some of these phases. Cubic-gauche and black-phosphorus polymorphs of single-bonded nitrogen are two particularly interesting phases. Their large hystereses warrant further application-inspired basic research of nitrogen. In contrast although metallic hydrogen contains the highest-estimated energy density its picosecond lifetime and picogram quantity make its practical material application impossible at present. “Metallic hydrogen” remains a curiosity-driven basic research pursuit focusing on the pressure-induced evolution of the molecular hydrogen crystal and its electronic band structure from a low-density insulator with a very wide electronic band gap to a semiconductor with a narrow gap to a dense molecular metal and atomic metal and eventually to a previously unknown exotic state of matter. This great experimental challenge is driving relentless advancement in ultrahigh-pressure science and technology.
Hy4Heat Safety Assessment: Precis - Work Package 7
May 2021
Publication
The Hy4Heat Safety Assessment has focused on assessing the safe use of hydrogen gas in certain types of domestic properties and buildings. The summary reports (the Precis and the Safety Assessment Conclusions Report) bring together all the findings of the work and should be looked to for context by all readers. The technical reports should be read in conjunction with the summary reports. While the summary reports are made as accessible as possible for general readers the technical reports may be most accessible for readers with a degree of technical subject matter understanding. All of the safety assessment reports have now been reviewed by the HSE.<br/><br/>This document is an overview of the Safety Assessment work undertaken as part of the Hy4Heat programme
Methane Emissions from Natural Gas and LNG Imports: An Increasingly Urgent Issue for the Future of Gas in Europe
Nov 2020
Publication
Pressure is mounting on the natural gas and LNG community to reduce methane emissions and this is most urgent in EU countries following the adoption of much tougher greenhouse gas reduction targets of 2030 and the publication of the European Commission’s Methane Strategy. With rapidly declining indigenous EU production and therefore rising import dependence there are increasing calls for emissions from imported pipeline gas and LNG to be quantified and based on actual measurements as opposed to standard emission factors. The Methane Strategy promises to be a significant milestone in that process. Companies which are supplying (or intending to supply) natural gas to the EU – the largest global import market for pipeline gas and a very significant market for LNG – would be well advised to pay close attention to how the regulation of methane emissions is unfolding and to make an immediate and positive response. Failure to do so could accelerate the demise of natural gas in European energy balances faster than would otherwise have been the case and shorten the time available for transition to decarbonised gases – specifically hydrogen – using existing natural gas infrastructure.<br/>This EU initiative will (and arguably already has) attracted attention from non-EU governments and companies involved in global gas and LNG trade. We have already seen deliveries of `carbon neutral’ LNG cargos to Asia as well as a long-term LNG contract in which the greenhouse gas content of cargos will be measured reported and verified (MRV) according to an agreed methodology. Natural gas and LNG exports if based on these standards or those set out in the EU Methane Strategy may be able to command premium prices from buyers eager to demonstrate their own GHG reduction credentials to governments customers and civil society.
Decarbonising UK Transport: Implications for Electricity Generation, Land Use and Policy
Dec 2022
Publication
To ensure the UK’s net zero targets are met the transition from conventionally fueled transport to low emission alternatives is necessary. The impact from increased decarbonised electricity generation on ecosystem services (ES) and natural capital (NC) are not currently quantified with decarbonisation required to minimise impacts from climate change. This study aims to project the future electric and hydrogen energy demand between 2020 and 2050 for car bus and train to better understand the land/sea area that would be required to support energy generation. In this work predictions of the geospatial impact of renewable energy (onshore/offshore wind and solar) nuclear and fossil fuels on ES and NC were made considering generation mix number of generation installations and energy density. Results show that electric transport will require ~136599 GWh for all vehicle types analysed in 2050 much less than hydrogen transport at ~425532 GWh. We estimate that to power electric transport at least 1515 km2 will be required for solar 1672 km2 for wind and 5 km2 for nuclear. Hydrogen approximately doubles this requirement. Results provide an approximation of the future demands from the transport sector on land and sea area use indicating that a combined electric and hydrogen network will be needed to accommodate a range of socio-economic requirements. While robust assessments of ES and NC impacts are critical in future policies and planning significant reductions in energy demands through a modal shift to (low emission) public transport will be most effective in ensuring a sustainable transport future.
Can the Current EU Regulatory Framework Deliver Decarbonisation of Gas?
Jun 2020
Publication
This Energy Insight examines the current regulatory framework and challenges facing the natural gas industry (producers transporters suppliers and consumers) during the transition to a zero-carbon economy. The EU has declared its intention to be climate neutral by 2050 which means that the current level of natural gas usage will no longer be possible. However natural gas is a crucial component of energy supply representing 24 per cent of primary energy supply for the EU27+UK and 36 per cent of residential energy consumption. In some countries the use of natural gas is much higher – around 40 per cent of primary energy supply in Netherlands UK and Italy. The current framework impacting gas addresses two different market failures – natural monopolies for gas transportation and the externalities of Greenhouse Gas Emissions. The framework will not deliver decarbonisation of gas as it does not stimulate either supply or demand for alternatives such as hydrogen nor create the conditions to enable gas networks to transition to a decarbonised future. Policy makers need to prioritise their objectives to take account of the trade-offs involved in designing a new framework. Exclusion of certain low carbon technologies risks driving away investors and reduces the chances of targets being met whilst “picking winners” involves risks because of the many uncertainties involved such as future costs and time required to build new value chains.
Link to Document on Oxford Institute for Energy Studies website
Link to Document on Oxford Institute for Energy Studies website
Carbon Capture, Usage and Storage: An Update on Business Models for Carbon Capture, Usage and Storage
Dec 2020
Publication
An update on the proposed commercial frameworks for transport and storage power and industrial carbon capture business models.
Materials for End to End Hydrogen Roadmap
Jun 2021
Publication
This report is commissioned by the Henry Royce Institute for advanced materials as part of its role around convening and supporting the UK advanced materials community to help promote and develop new research activity. The overriding objective is to bring together the advanced materials community to discuss analyse and assimilate opportunities for emerging materials research for economic and societal benefit. Such research is ultimately linked to both national and global drivers namely Transition to Zero Carbon Sustainable Manufacture Digital & Communications Circular Economy as well as Health & Wellbeing.
This paper can be download from their website
This paper can be download from their website
Fuel Cell Industry Review 2019 - The Year of the Gigawatt
Jan 2020
Publication
E4tech’s 6th annual review of the global fuel cell industry is now available here. Using primary data straight from the main players and free to download it quantifies shipments by fuel cell type by application and by region of deployment and summarises industry developments over the year.
2019 saw shipments globally grow significantly to 1.1 GW. Numbers grew slightly to around 70000 units. The growth in capacity came mainly from cars Hyundai with its NEXO and Toyota with its Mirai together accounting for around two-thirds of shipments by capacity. Unit numbers are still dominated by Japan’s ene-Farm cogeneration appliances at around 45000 shipments. Large numbers of trucks and buses are now manufactured and shipped in China though numbers deployed are limited by the availability of refuelling infrastructure. But growth in China is uncertain as policy changes are under discussion.
2020 looks like it will be an even bigger year again dominated by Hyundai and Toyota. The Japanese fuel cell market is expected also to grow partly on the back of the Tokyo ‘Hydrogen Olympics’. Korea is another growth story buoyed by its latest roadmap which aims to shift large swathes of its economy to hydrogen energy by 2040. Elsewhere much of the supply chain development is in heavy duty vehicles and big supply chain players like Cummins Weichai and Michelin are making significant investments.
2019 saw shipments globally grow significantly to 1.1 GW. Numbers grew slightly to around 70000 units. The growth in capacity came mainly from cars Hyundai with its NEXO and Toyota with its Mirai together accounting for around two-thirds of shipments by capacity. Unit numbers are still dominated by Japan’s ene-Farm cogeneration appliances at around 45000 shipments. Large numbers of trucks and buses are now manufactured and shipped in China though numbers deployed are limited by the availability of refuelling infrastructure. But growth in China is uncertain as policy changes are under discussion.
2020 looks like it will be an even bigger year again dominated by Hyundai and Toyota. The Japanese fuel cell market is expected also to grow partly on the back of the Tokyo ‘Hydrogen Olympics’. Korea is another growth story buoyed by its latest roadmap which aims to shift large swathes of its economy to hydrogen energy by 2040. Elsewhere much of the supply chain development is in heavy duty vehicles and big supply chain players like Cummins Weichai and Michelin are making significant investments.
Reference Standard for Low Pressure Hydrogen Utilisation
May 2021
Publication
This standard has been created for the specific purposes of the Hy4Heat programme. The standard was commissioned in 2018 and this version was considered and approved by the relevant IGEM committees in May of 2020. This version of the standard was developed using the latest publicly available information at that time and may include some conservative requirements which further research may deem not necessary. The supplement will be updated regularly following the publication of new research into the application of hydrogen.
This Reference Standard aims to identify and discuss the principles required for the safety and integrity of Hydrogen installation and utilisation in premises.
This document intends to:
The standard is available to download through the IGEM website here.
This Reference Standard aims to identify and discuss the principles required for the safety and integrity of Hydrogen installation and utilisation in premises.
This document intends to:
- provide a point of reference for those requiring an understanding of the implications of using hydrogen as a distributed gas in properties
- detail the characteristics of Hydrogen
- detail the comparisons between hydrogen and Natural Gas (NG)
- discuss the safety implications of using hydrogen
- discuss the implications for materials when using hydrogen
- discuss the implications for the installation and use of using hydrogen in domestic & smaller commercial buildings.
The standard is available to download through the IGEM website here.
The Future Role of Gas in Transport
Mar 2021
Publication
This is a Network Innovation Allowance funded project overseen by a steering group comprising the UK and Ireland gas network operators (Cadent Gas Networks Ireland National Grid Northern Gas Networks SGN Wales and West). The project follows on from previous studies that modelled the role of green gases in decarbonising the GB economy. The role of this study is to understand the transition from the GB economy today to a decarbonised economy in 2050 focusing on how the transition is achieved and the competing and complementary nature of different low and zero emission fuels and technologies over time.
While the project covers the whole economy it focuses on transport especially trucks as an early adopter of green gases and as a key enabler of the transition. The study and resulting report are aimed at the gas industry and government and tries to build a green gas decarbonisation narrative supported by a wide range of stakeholders in order clarify the path ahead and thereby focus future efforts on delivering decarbonisation through green gases as quickly as possible.
The objectives of the study are:
Green gases
This report discusses the future role of ‘green gases’ which are biomethane and hydrogen produced from low- and zero-carbon sources each produced via two main methods:
Biomethane from Anaerobic Digestion (AD): A mature technology for turning biological material into a non-fossil form of natural gas (methane). AD plants produce biogas which must then be upgraded to biomethane.
Biomethane from Bio-Substitute Natural Gas (Bio-SNG): This technology is at an earlier stage of development than AD but has the potential to unlock other feedstocks for biomethane production such as waste wood and residual household waste.
Blue Hydrogen: Hydrogen from reformation of natural gas which produces hydrogen and carbon monoxide. 90-95% of the carbon is captured and stored making this a low-carbon form of hydrogen.
Green Hydrogen: Water is split into hydrogen and oxygen via electrolysis using electricity generated by renewables. No carbon emissions are produced so this is zero-carbon hydrogen."
While the project covers the whole economy it focuses on transport especially trucks as an early adopter of green gases and as a key enabler of the transition. The study and resulting report are aimed at the gas industry and government and tries to build a green gas decarbonisation narrative supported by a wide range of stakeholders in order clarify the path ahead and thereby focus future efforts on delivering decarbonisation through green gases as quickly as possible.
The objectives of the study are:
- Analyse the complete supply chain production distribution and use of electricity biomethane bio-SNG and hydrogen to understand the role of each fuel and the timeline for scaling up of their use.
- Develop a narrative based on these findings to show how the use of these fuels scales up over time and how they compete and complement one another.
Green gases
This report discusses the future role of ‘green gases’ which are biomethane and hydrogen produced from low- and zero-carbon sources each produced via two main methods:
Biomethane from Anaerobic Digestion (AD): A mature technology for turning biological material into a non-fossil form of natural gas (methane). AD plants produce biogas which must then be upgraded to biomethane.
Biomethane from Bio-Substitute Natural Gas (Bio-SNG): This technology is at an earlier stage of development than AD but has the potential to unlock other feedstocks for biomethane production such as waste wood and residual household waste.
Blue Hydrogen: Hydrogen from reformation of natural gas which produces hydrogen and carbon monoxide. 90-95% of the carbon is captured and stored making this a low-carbon form of hydrogen.
Green Hydrogen: Water is split into hydrogen and oxygen via electrolysis using electricity generated by renewables. No carbon emissions are produced so this is zero-carbon hydrogen."
Contrasting European Hydrogen Pathways: An Analysis of Differing Approaches in Key Markets
Mar 2021
Publication
European countries approach the market ramp-up of hydrogen very differently. In some cases the economic and political starting points differ significantly. While the probability is high that some countries such as Germany or Italy will import hydrogen in the long term other countries such as United Kingdom France or Spain could become hydrogen exporters. The reasons for this are the higher potential for renewable energies but also a technology-neutral approach on the supply side.
Unpacking Leadership-driven Global Scenarios Towards the Paris Agreement: Report Prepared for the UK Committee on Climate Change
Dec 2020
Publication
Outline
This independent report by Vivid Economics and University College London was commissioned to support the Climate Change Committee’s (CCC) 2020 report The Sixth Carbon Budget -The path to Net Zero. This research provided supporting information for Chapter 7 of the CCC’s report which considered the UK’s contribution to the global goals of the Paris Agreement.
Key recommendations
The report models ‘leadership-driven’ global scenarios that could reduce global emissions rapidly to Net Zero and analyses the levers available to developed countries such as the UK to help accelerate various key aspects of the required global transition.
It highlights a set of opportunities for the UK alongside other developed countries to help assist global decarbonisation efforts alongside achieving it’s domestic emissions reduction targets
This independent report by Vivid Economics and University College London was commissioned to support the Climate Change Committee’s (CCC) 2020 report The Sixth Carbon Budget -The path to Net Zero. This research provided supporting information for Chapter 7 of the CCC’s report which considered the UK’s contribution to the global goals of the Paris Agreement.
Key recommendations
The report models ‘leadership-driven’ global scenarios that could reduce global emissions rapidly to Net Zero and analyses the levers available to developed countries such as the UK to help accelerate various key aspects of the required global transition.
It highlights a set of opportunities for the UK alongside other developed countries to help assist global decarbonisation efforts alongside achieving it’s domestic emissions reduction targets
Hydrogen Generation by Photocatalytic Reforming of Potential Biofuels: Polyols, Cyclic Alcohols, and Saccharides
Jan 2018
Publication
We have studied hydrogen gas production using photocatalysis from C2-C5 carbon chain polyols cyclic alcohols and mono and di-saccharides using palladium nanoparticles supported on a TiO2 catalyst. For many of the polyols the hydrogen evolution rate is found to be dictated by the number of hydroxyl groups and available a-hydrogens in the structure. However the rule only applies to polyols and cyclic alcohols while the sugar activity is limited by the bulky structure of those molecules. There was also evidence of ring opening in photocatalytic reforming of cyclic alcohols that involved dehydrogenation and decarbonylation of a CC bond.
Transport Pathway to Hydrogen webinar
Mar 2021
Publication
Webinar to accompany the launch of the Cadent Future Role of Gas in Transport report which can be found here
H21- Phase 1 Technical Summary Report
May 2021
Publication
The UK Government signed legislation on 27th June 2019 committing the UK to a legally binding target of Net Zero emissions by 2050. Climate change is one of the most significant technical economic social and business challenges facing the world today.
The H21 NIC Phase 1 project delivered an optimally designed experimentation and testing programme supported by the HSE Science Division and DNV GL with the aim to collect quantifiable evidence to support that the UK distribution network of 2032 will be comparably as safe operating on 100% hydrogen as it currently is on
natural gas. This innovative project begins to fill critical safety evidence gaps surrounding the conversion of the UK gas network to 100% hydrogen. This will facilitate progression towards H21 Phase 2 Operational Safety Demonstrations and the H21 Phase 3 Live Trials to promote customer acceptability and ultimately aid progress towards a government policy decision on heat.
DNV GL and HSE Science Division were engaged to undertake the experimentation testing and QRA update programme of work. DNV GL and HSE Science Division also peer reviewed each other’s programme of work at various stages throughout the project undertaking a challenge and review of the experimental data and results to provide confidence in the conclusions.
A strategic set of tests was designed to cover the range of assets represented across the Great Britain gas distribution networks. The assets used in the testing were mostly recovered from the distribution network as part of the ongoing Iron Mains Risk Reduction Replacement Programme. Controlled testing against a well-defined master testing plan with both natural gas and 100% hydrogen was then undertaken to provide the quantitative evidence to forecast any change to background leakage levels in a 100% hydrogen network.
Key Findings from Phase 1a:
The H21 NIC Phase 1 project delivered an optimally designed experimentation and testing programme supported by the HSE Science Division and DNV GL with the aim to collect quantifiable evidence to support that the UK distribution network of 2032 will be comparably as safe operating on 100% hydrogen as it currently is on
natural gas. This innovative project begins to fill critical safety evidence gaps surrounding the conversion of the UK gas network to 100% hydrogen. This will facilitate progression towards H21 Phase 2 Operational Safety Demonstrations and the H21 Phase 3 Live Trials to promote customer acceptability and ultimately aid progress towards a government policy decision on heat.
DNV GL and HSE Science Division were engaged to undertake the experimentation testing and QRA update programme of work. DNV GL and HSE Science Division also peer reviewed each other’s programme of work at various stages throughout the project undertaking a challenge and review of the experimental data and results to provide confidence in the conclusions.
A strategic set of tests was designed to cover the range of assets represented across the Great Britain gas distribution networks. The assets used in the testing were mostly recovered from the distribution network as part of the ongoing Iron Mains Risk Reduction Replacement Programme. Controlled testing against a well-defined master testing plan with both natural gas and 100% hydrogen was then undertaken to provide the quantitative evidence to forecast any change to background leakage levels in a 100% hydrogen network.
Key Findings from Phase 1a:
- Of the 215 assets tested 41 of them were found to leak 19 of them provided sufficient data to be able to compare hydrogen and methane leak rates.
- The tests showed that assets that were gas tight on methane were also gas tight on hydrogen. Assets that leaked on hydrogen also leaked
- on methane including repaired assets.
- The ratio of the hydrogen to methane volumetric leak rates varied between 1.1 and 2.2 which is largely consistent with the bounding values expected for laminar and turbulent (or inertial) flow which gave ratios of 1.2 and 2.8 respectively.
- None of the PE assets leaked; cast ductile and spun iron leaked to a similar degree (around 26-29% of all iron assets leaked) and the proportion of leaking steel assets was slightly less (14%).
- Four types of joint were responsible for most of the leaks on joints: screwed lead yarn bolted gland and hook bolts.
- All of the repairs that sealed methane leaks also were effective when tested with hydrogen.
Energy System Requirements of Fossil-free Steelmaking using Hydrogen Direct Reduction
May 2021
Publication
The iron and steel industry is one of the world’s largest industrial emitters of greenhouse gases. One promising option for decarbonising the industry is hydrogen direct reduction of iron (H-DR) with electric arc furnace (EAF) steelmaking powered by zero carbon electricity. However to date little attention has been given to the energy system requirements of adopting such a highly energy-intensive process. This study integrates a newly developed long-term energy system planning tool with a thermodynamic process model of H-DR/EAF steelmaking developed by Vogl et al. (2018) to assess the optimal combination of generation and storage technologies needed to provide a reliable supply of electricity and hydrogen. The modelling tools can be applied to any country or region and their use is demonstrated here by application to the UK iron and steel industry as a case study. It is found that the optimal energy system comprises 1.3 GW of electrolysers 3 GW of wind power 2.5 GW of solar 60 MW of combined cycle gas with carbon capture 600 GWh/600 MW of hydrogen storage and 30 GWh/130 MW of compressed air energy storage. The hydrogen storage requirements of the industry can be significantly reduced by maintaining some dispatchable generation for example from 600 GWh with no restriction on dispatchable generation to 140 GWh if 20% of electricity demand is met using dispatchable generation. The marginal abatement costs of a switch to hydrogen-based steelmaking are projected to be less than carbon price forecasts within 5–10 years.
Wax: A Benign Hydrogen-storage Material that Rapidly Releases H2-rich Gases Through Microwave-assisted Catalytic Decomposition
Oct 2016
Publication
Hydrogen is often described as the fuel of the future especially for application in hydrogen powered fuel-cell vehicles (HFCV’s). However its widespread implementation in this role has been thwarted by the lack of a lightweight safe on-board hydrogen storage material. Here we show that benign readily available hydrocarbon wax is capable of rapidly releasing large amounts of hydrogen through microwave-assisted catalytic decomposition. This discovery offers a new material and system for safe and efficient hydrogen storage and could facilitate its application in a HFCV. Importantly hydrogen storage materials made of wax can be manufactured through completely sustainable processes utilizing biomass or other renewable feedstocks.
Approaches and Methods to Demonstrate Repurposing of the UK's Local Transmission System (LTS) Pipelines for Transportation of Hydrogen
Sep 2021
Publication
Hydrogen has the potential as an energy solution to contribute to decarbonisation targets as it has the capability to deliver low-carbon energy at the scale required. For this to be realised the suitability of the existing natural gas pipeline networks for transporting hydrogen must be established. The current paper describes a feasibility study that was undertaken to assess the potential for repurposing the UK’s Local Transmission System (LTS) natural gas pipelines for hydrogen service. The analysis focused on SGN’s network which includes 3000 km of LTS pipelines in Scotland and the south of England. The characteristics of the LTS pipelines in terms of materials of construction and operation were first evaluated. This analysis showed that a significant percentage of SGN’s LTS network consists of lower strength grades of steel pipeline that operate at low stresses which are factors conducive to a pipeline’s suitability for hydrogen service. An assessment was also made of where existing approaches in pipeline operation may require modifications for hydrogen. The effects of changes in mechanical properties of steel pipelines on integrity and lifetime as a result of potential hydrogen degradation were demonstrated using fitness-for-purpose analysis. A review of pipeline risk assessment and Land-Use Planning (LUP) zone calculations for hydrogen was undertaken to identify any required changes. Case studies on selected sections of the LTS pipeline were then carried out to illustrate the potential changes to LUP zones. The work concluded with a summary of identified gaps that require addressing to ensure safe pipeline repurposing for hydrogen which cover materials performance inspection risk assessment land use planning and procedures.
Preliminary Analysis of Compression System Integrated Heat Management Concepts Using LH2-Based Parametric Gas Turbine Model
Apr 2021
Publication
The investigation of the various heat management concepts using LH2 requires the development of a modeling environment coupling the cryogenic hydrogen fuel system with turbofan performance. This paper presents a numerical framework to model hydrogen-fueled gas turbine engines with a dedicated heat-management system complemented by an introductory analysis of the impact of using LH2 to precool and intercool in the compression system. The propulsion installations comprise Brayton cycle-based turbofans and first assessments are made on how to use the hydrogen as a heat sink integrated into the compression system. Conceptual tubular compact heat exchanger designs are explored to either precool or intercool the compression system and preheat the fuel to improve the installed performance of the propulsion cycles. The precooler and the intercooler show up to 0.3% improved specific fuel consumption for heat exchanger effectiveness in the range 0.5–0.6 but higher effectiveness designs incur disproportionately higher pressure losses that cancel-out the benefits.
HydroGenerally - Episode 2: Where Should Hydrogen Be Used?
Apr 2022
Publication
The Innovate UK KTN Hydrogen Innovation Network is bringing you this second episode with Steffan Eldred and Simon Buckley from Innovate UK KTN who continue their ‘back to basics' approach and delve deeper to understand where hydrogen should be used with their special guest Joanna Richart Head of Hydrogen Business at Ricardo. As with any technology or fuel discussions can get carried away implying they are the solution to all things but at Innovate UK KTN we strongly believe that we should ensure hydrogen is used where it can be most effective for decarbonising energy industrial and chemical industries.
The podcast can be found on their website
The podcast can be found on their website
Hydrogen Generation on Orkney: Integrating Established Risk Management Best Practice to Emerging Clean Energy Sector
Sep 2021
Publication
The European Marine Energy Centre’s (EMEC) ITEG project (Integrating Tidal Energy into the European Grid) funded by Interreg NWE combines a tidal energy and hydrogen production solution to address grid constraints on the island of Eday in Orkney. The project will install a 0.5MW electrolyser at EMEC’s existing hydrogen production plant. EMEC and Risktec collaboratively applied best practice risk assessment and management techniques to assess and manage hydrogen safety. Hazard identification (HAZID) workshops were conducted collaboratively with design engineers through which a comprehensive hazard register was developed. Risktec applied bowtie analysis to each major accident hazard identified from the hazard register via virtual workshop with design engineers. The bowties promoted a structured review of each hazard’s threat and consequence identifying and reviewing the controls in place against good practice standards. The process revealed some recommendations for further improvement and risk reduction exemplifying a systematic management of risks associated with hydrogen hazards to as low as reasonably practicable (ALARP). Hardware based barriers preventing or mitigating loss of control of these hazards were logged as safety critical elements (SCE) and procedural barriers as safety critical activities (SCA). To ensure that all SCEs and SCAs identified through the risk assessment process are managed throughout the facility’s operational lifetime a safety management system is created giving assurance of overall safety management system continued effectiveness. The process enables the demonstration that design risks are managed to ALARP during design and throughout operational lifetime. More importantly enabling ITEG to progress to construction and operation in 2021.
Chemical Inhibition of Premixed Hydrogen-air Flames: Experimental Investigation using a 20-litre Vessel
Sep 2021
Publication
Throughout the history of the mining petroleum process and nuclear industries continuous efforts have been made to develop and improve measures to prevent and mitigate accidental explosions. Over the coming decades energy systems are expected to undergo a transition towards sustainable use of conventional hydrocarbons and an increasing share of renewable energy sources in the global energy mix. The variable and intermittent supply of energy from solar and wind points to energy systems based on hydrogen or hydrogen-based fuels as the primary energy carriers. However the safety-related properties of hydrogen imply that it is not straightforward to achieve and document the same level of safety for hydrogen systems compared to similar systems based on established fuels such as petrol diesel and natural gas. Compared to the conventional fuels hydrogen-air mixtures have lower ignition energy higher combustion reactivity and a propensity to undergo deflagration-to-detonation-transition (DDT) under certain conditions. To achieve an acceptable level of safety it is essential to develop effective measures for mitigating the consequences of hydrogen explosions in systems with certain degree of congestion and confinement. Extensive research over the last decade have demonstrated that chemical inhibition or partial suppression can be used for mitigating the consequences of vapour cloud explosions (VCEs) in congested process plants. Total and cooperation partners have demonstrated that solid flame inhibitors injected into flammable hydrocarbon-air clouds represent an effective means of mitigating the consequences of VCEs involving hydrocarbons. For hydrogen-air explosions these same chemicals inhibitors have not proved effective. It is however well-known that hydrocarbons can affect the burning velocity of hydrogen-air mixtures greatly. This paper gives an overview over previous work on chemical inhibitors. In addition experiments in a 20-litre vessel have been performed to investigate the effect of combinations of hydrocarbons and alkali salts on hydrogen/air mixtures.
Nanoporous Polymer-based Composites for Enhanced Hydrogen Storage
May 2019
Publication
The exploration and evaluation of new composites possessing both processability and enhanced hydrogen storage capacity are of signifcant interest for onboard hydrogen storage systems and fuel cell based electric vehicle development. Here we demonstrate the fabrication of composite membranes with sufcient mechanical properties for enhanced hydrogen storage that are based on a polymer of intrinsic microporosity (PIM-1) matrix containing nano-sized fllers: activated carbon (AX21) or metal–organic framework (MIL-101). This is one of the frst comparative studies of diferent composite systems for hydrogen storage and in addition the frst detailed evaluation of the difusion kinetics of hydrogen in polymer-based nanoporous composites. The composite flms were characterised by surface area and porosity analysis hydrogen adsorption measurements mechanical testing and gas adsorption modelling. The PIM-1/AX21 composite with 60 wt% AX21 provides enhanced hydrogen adsorption kinetics and a total hydrogen storage capacity of up to 9.35 wt% at 77 K; this is superior to the US Department of Energy hydrogen storage target. Tensile testing indicates that the ultimate stress and strain of PIM-1/ AX21 are higher than those of the MIL-101 or PAF-1 containing composites and are sufcient for use in hydrogen storage tanks. The data presented provides new insights into both the design and characterisation methods of polymer-based composite membranes. Our nanoporous polymer-based composites ofer advantages over powders in terms of safety handling and practical manufacturing with potential for hydrogen storage applications either as means of increasing storage or decreasing operating pressures in high-pressure hydrogen storage tanks.
Producing Low Carbon Gas- Future Gas Series part 2
Jul 2018
Publication
Of all the sectors in the UK decarbonising heat remains one of the most challenging. Heat used for industrial domestic and commercial purposes generates around a third of all UK carbon emissions 70% of which is due to burning natural gas. In order to meet our legally binding national climate change targets unabated natural gas use for heat must be phased out. Low carbon gas - including hydrogen and biogases - is one option to replace it. The Future Gas Series examines the opportunities and challenges associated with using low carbon gas to help decarbonise the UK economy.<br/><br/>This is the second report in the three-part Future Gas Series. Part 1: Next Steps for the Gas Grid explored the potential to decarbonise the existing gas grid. The report Part 2: the Production of Low Carbon Gas focuses on the issues related to the production of low carbon gas. It considers the different production technologies the potential scale of deployment of each method and the potential feedstocks. It also discusses issues related to bulk transport and storage of gas. Put together from expert evidence from across industry and academia it provides a balanced guide for policy makers in this area. It was a co-chaired by James Heappey MP (Conservative) Alan Whitehead MP (Labour) and Alistair Carmichael MP (SNP).<br/><br/>Carbon Connect suggests that biogases- such as biomethane and bioSNG- provide low regrets opportunities in the near term to provide low carbon heat and could also potentially make use of waste that would otherwise go to landfill. However they require further support to allow them to continue contributing to decarbonising the UK economy. Hydrogen could provide huge decarbonisation opportunities and has applications across the energy system from putting hydrogen in the gas grid to be burnt for heat in homes to hydrogen buses and trains. However to realise this potential a market for hydrogen must be built up. This should incentivise business to invest in hydrogen technologies reward those who use hydrogen and build up hydrogen infrastructure.<br/><br/>
Overview of First Outcomes of PNR Project HYTUNNEL-CS
Sep 2021
Publication
Dmitry Makarov,
Donatella Cirrone,
Volodymyr V. Shentsov,
Sergii Kashkarov,
Vladimir V. Molkov,
Z. Xu,
Mike Kuznetsov,
Alexandros G. Venetsanos,
Stella G. Giannissi,
Ilias C. Tolias,
Knut Vaagsaether,
André Vagner Gaathaug,
Mark R. Pursell,
Wayne M. Rattigan,
Frank Markert,
Luisa Giuliani,
L.S. Sørensen,
A. Bernad,
Mercedes Sanz Millán,
U. Kummer,
Christian Brauner,
Paola Russo,
J. van den Berg,
F. de Jong,
Tom Van Esbroeck,
M. Van De Veire,
Didier Bouix,
Gilles Bernard-Michel,
Sergey Kudriakov,
Etienne Studer,
Domenico Ferrero,
Joachim Grüne and
G. Stern
The paper presents the first outcomes of the experimental numerical and theoretical studies performed in the funded by Fuel Cell and Hydrogen Joint Undertaking (FCH2 JU) project HyTunnel-CS. The project aims to conduct pre-normative research (PNR) to close relevant knowledge gaps and technological bottlenecks in the provision of safety of hydrogen vehicles in underground transportation systems. Pre normative research performed in the project will ultimately result in three main outputs: harmonised recommendations on response to hydrogen accidents recommendations for inherently safer use of hydrogen vehicles in underground traffic systems and recommendations for RCS. The overall concept behind this project is to use inter-disciplinary and inter-sectoral prenormative research by bringing together theoretical modelling and experimental studies to maximise the impact. The originality of the overall project concept is the consideration of hydrogen vehicle and underground traffic structure as a single system with integrated safety approach. The project strives to develop and offer safety strategies reducing or completely excluding hydrogen-specific risks to drivers passengers public and first responders in case of hydrogen vehicle accidents within the currently available infrastructure.
Policy and Pricing Barriers to Steel Industry Decarbonisation: A UK Case Study
Aug 2022
Publication
Global climate targets have highlighted the need for a whole-systems approach to decarbonisation one that includes targeted national policy and industry specific change. Situated within this context this research examines policy and pricing barriers to decarbonisation of the UK steel industry. Here the techno-economic modelling of UK green steelmaking provides a technical contribution to analysis of pricing barriers and policy solutions to these barriers in the UK specifically but also to the broader industrial decarbonisation literature. Estimated costs and associated emissions projections reveal relevant opportunities for UK steel in contributing to national climate and emissions targets. Modelling demonstrates that green steelmaking options have been put at price disadvantages compared to emissions-intensive incumbents and that fossil-free hydrogen-based steel-making has lower emissions and lower levelised costs than carbon capture and storage options including top gas recycling blast furnace (TGR-BF) with CCS and HIsarna smelter with CCS. Two primary policy recommendations are made: the removal of carbon pricing discrepancies and reductions in industrial electricity prices that would level the playing field for green steel producers in the UK. The research also provides relevant policy considerations for the international community in other industrial decarbonisation efforts and the policies that must accompany these decarbonisation choices.
Milford Haven: Energy Kingdom - System Architecture Report: A Prospering from the Energy Revolution Project
Nov 2021
Publication
Milford Haven: Energy Kingdom is a two-year project exploring what a decarbonised smart local energy system could look like for Milford Haven Pembroke and Pembroke Dock.
The project explores the potential of hydrogen as part of a multi-vector approach to decarbonisation. Central to the project and to achieving Net Zero is a commitment to engage with the community and local industry providing insight and opportunities for growth.
The ambition is to gather detailed insight into the whole energy system around Milford Haven to identify and design a future smart local energy system based on a truly multi-vector approach and comprehensive energy systems architecture.
The transition to Net Zero requires action across the economy. As the UK’s largest energy port Milford Haven is an industrial cluster that can handle 30% of total UK gas demand is home to Europe’s largest gas power station powering 3.5 million homes and businesses has ambitions to build 90MW of floating offshore wind supports 5000 jobs and injects £324m to the Pembrokeshire economy.
This work describes the outcomes of the effort to define designs of future energy system architectures combining; technology the interconnectivity between them and data; with markets trading platforms and policies; with business models and defined organisational governance. The aim of these designs is to provide:
The project explores the potential of hydrogen as part of a multi-vector approach to decarbonisation. Central to the project and to achieving Net Zero is a commitment to engage with the community and local industry providing insight and opportunities for growth.
The ambition is to gather detailed insight into the whole energy system around Milford Haven to identify and design a future smart local energy system based on a truly multi-vector approach and comprehensive energy systems architecture.
The transition to Net Zero requires action across the economy. As the UK’s largest energy port Milford Haven is an industrial cluster that can handle 30% of total UK gas demand is home to Europe’s largest gas power station powering 3.5 million homes and businesses has ambitions to build 90MW of floating offshore wind supports 5000 jobs and injects £324m to the Pembrokeshire economy.
This work describes the outcomes of the effort to define designs of future energy system architectures combining; technology the interconnectivity between them and data; with markets trading platforms and policies; with business models and defined organisational governance. The aim of these designs is to provide:
- The basis for a roadmap for the next phases of development and implementation
- Confidence to innovators and investors in the future longevity of investments in hydrogen and
- A common basis of understanding for all stakeholders wishing to contribute to the Milford Haven: Energy Kingdom.
HydroGenerally - Episode 4: Hydrogen in a Global Maritime Industry: Plain Sailing or a Rough Ride?
May 2022
Publication
In this fourth episode Simon Buckley and Matthew Moss from Innovate UK KTN are exploring the use of hydrogen in the global maritime industry alongside their special guest Chester Lewis Business Development Manager at Ryze Hydrogen.
This podcast can be found on their website
This podcast can be found on their website
The Upfront Cost of Decarbonising Your Home
Nov 2021
Publication
The objective of this report is to analyse the upfront capital costs facing consumers when considering the installation of new low carbon heating technology solutions for their homes today including the cost of any associated home upgrades that will likely be required. The UK Government have recently published its Heat and Buildings Strategy which sets out plans to significantly cut carbon emissions from the existing housing stock and new homes. Whilst the Strategy points to a future role for a variety of technologies such as heat pumps hydrogen and heat networks the success of this Strategy will largely be determined by the ability to achieve installed cost reductions for heat pumps of at least 25-50% by 2025 with the view to achieving cost parity with a gas boiler by 2030. The purpose of this report is to launch a series which tracks the upfront costs of these respective technologies over time to establish whether the cost reduction targets mooted by government and heat pump stakeholders are being delivered and the implications this has on our ability to decarbonise the UK housing stock.
Mitigation of CO Poisoning Hazard in Malfunctioning Gas Appliances Through Use of Hydrogen Blended Gas
Sep 2021
Publication
The HyDeploy project [1] has undertaken an extensive research programme to assess safety and performance of the existing UK gas appliances population fueled with natural gas / hydrogen admixtures (hydrogen blended gas). The first stage of this work [2] focused on well maintained and normally functioning appliances. This work demonstrated that unmodified gas appliances can operate safely with hydrogen blended gas (up to 20 vol% hydrogen) and the key hazard areas of carbon monoxide (CO) production light back and flame out and the operation of flame failure devices are unaffected. It is widely recognized that due to aging and variable degrees of maintenance that the combustion performance of a gas appliance will depreciate over time. In extreme cases this can lead to situations where high levels of CO may be released back into the dwelling resulting in CO poisoning to the occupants. To obtain a universal appreciation of the effect of hydrogen addition on the safety and performance of all gas appliances operation under sub optimal conditions is required and therefore it is important that the operation of malfunctioning appliances fuelled with hydrogen blended gas is assessed. A review of failure modes identified six key scenarios where the composition of the fuel gas may lead to changes in safety performance - these primarily related to the resulting composition of the flue gas but also included delayed ignition. Gas appliance faults that will increase the CO production were tested through a series of experiments to simulate fault conditions and assess the effect of hydrogen blended gas. The fault modes examined included linting flame chilling incorrect appliance set up and modification of gas valve operation. The programme utilized six different appliances tested with three methane-hydrogen fuel blends (containing 0 20 and 28.4 vol% hydrogen). In all cases the switch to hydrogen blended gas reduced CO production. The change in CO production when using hydrogen blended gas is a consequence of a decrease in the theoretical air requirement to achieve complete combustion. In some cases the amount of CO produced was identical to the nonfault baseline performance on methane thereby fully mitigating the consequence of the malfunction. In the case of very high CO production a 90% reduction was recorded when using 20 vol% hydrogen blended gas. In situations such as non-optimal boiler set up the addition of hydrogen to the gas supply would prevent the production of high levels of CO. The findings here together with the results from HyDeploy 1 [2] indicate that the safety and performance of unmodified existing UK gas appliances are not detrimentally affected when using hydrogen blended gas. Furthermore the addition of hydrogen to the fuel gas has been shown to reduce CO production under fault conditions therefore the introduction of hydrogen into the gas network may serve to mitigate the hazard posed by existing faulty appliances that are producing elevated levels of CO.
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