Norway
Publication Handbook for Hydrogen Fuelled Vessels
Jun 2021
Publication
Green hydrogen could play a crucial role in the maritime industry’s journey towards decarbonization. Produced through electrolysis hydrogen is emission free and could be widely available across the globe in future – as a marine fuel or a key enabler for synthetic fuels. Many in shipping recognize hydrogen’s potential as a fuel but the barriers to realizing this potential are substantial.<br/>The 1st Edition of the ‘Handbook for Hydrogen-fuelled Vessels’ offers a road map towards safe hydrogen operations using fuel cells. It details how to navigate the complex requirements for design and construction and it covers the most important aspects of hydrogen operations such as safety and risk mitigation engineering details for hydrogen systems and implementation phases for maritime applications based on the current regulatory Alternative Design process framework.<br/>This publication is the result of the 1st phase of the DNV-led Joint Industry Project MarHySafe which has brought together a consortium of 26 leading company and associations. The project is ongoing and this publication will be continually updated to reflect the latest industry expertise on hydrogen as ship fuel.
Alkaline Fuel cell Technology - A review
Apr 2021
Publication
The realm of alkaline-based fuel cells has with the arrival of anionic exchange membrane fuel cells (AEMFCs) taken a great step to replace traditional liquid electrolyte alkaline fuel cells (AFCs). The following review summarises progress bottleneck issues and highlights the most recent research trends within the field. The activity of alkaline catalyst materials has greatly advanced however achieving long-term stability remains a challenge. Great AEMFC performances are reported though these are generally obtained through the employment of platinum group metals (PGMs) thus emphasising the importance of R&D related to non-PGM materials. Thorough design strategies must be utilised for all components to avoid a mismatch of electrochemical properties between electrode components. Lastly AEMFC optimisation challenges on the system-level will also have to be assessed as few application-size AEMFCs have been built and tested.
Experimental Study of Hydrogen Production Using Electrolyte Nanofluids with a Simulated Light Source
Dec 2021
Publication
In this research we conducted water electrolysis experiments of a carbon black (CB) based sodium sulfate electrolyte using a Hoffman voltameter. The main objective was to investigate hydrogen production in such systems as well as analyse the electrical properties and thermal properties of nanofluids. A halogen lamp mimicking solar energy was used as a radiation source and a group of comparative tests were also conducted with different irradiation areas. The results showed that by using CB and light it was possible to increase the hydrogen production rate. The optimal CB concentration was 0.1 wt %. At this concentration the hydrogen production rate increased by 30.37% after 20 min of electrolysis. Hence we show that using CB in electrolytes irradiated by solar energy could save the electrical energy necessary for electrolysis processes.
Finding Synergy Between Renewables and Coal: Flexible Power and Hydrogen Production from Advanced IGCC Plants with Integrated CO2 Capture
Feb 2021
Publication
Variable renewable energy (VRE) has seen rapid growth in recent years. However VRE deployment requires a fleet of dispatchable power plants to supply electricity during periods with limited wind and sunlight. These plants will operate at reduced utilization rates that pose serious economic challenges. To address this challenge this paper presents the techno-economic assessment of flexible power and hydrogen production from integrated gasification combined cycles (IGCC) employing the gas switching combustion (GSC) technology for CO2 capture and membrane assisted water gas shift (MAWGS) reactors for hydrogen production. Three GSC-MAWGS-IGCC plants are evaluated based on different gasification technologies: Shell High Temperature Winkler and GE. These advanced plants are compared to two benchmark IGCC plants one without and one with CO2 capture. All plants utilize state-of-the-art H-class gas turbines and hot gas clean-up for maximum efficiency. Under baseload operation the GSC plants returned CO2 avoidance costs in the range of 24.9–36.9 €/ton compared to 44.3 €/ton for the benchmark. However the major advantage of these plants is evident in the more realistic mid-load scenario. Due to the ability to keep operating and sell hydrogen to the market during times of abundant wind and sun the best GSC plants offer a 6–11%-point higher annual rate of return than the benchmark plant with CO2 capture. This large economic advantage shows that the flexible GSC plants are a promising option for balancing VRE provided a market for the generated clean hydrogen exists.
Techno-Economic Assessment of Natural Gas Pyrolysis in Molten Salts
Jan 2022
Publication
Steam methane reforming with CO2 capture (blue hydrogen) and water electrolysis based on renewable electricity (green hydrogen) are commonly assumed to be the main supply options in a future hydrogen economy. However another promising method is emerging in the form of natural gas pyrolysis (turquoise hydrogen) with pure carbon as a valuable by-product. To better understand the potential of turquoise hydrogen this study presents a techno-economic assessment of a molten salt pyrolysis process. Results show that moderate reactor pressures around 12 bar are optimal and that reactor size must be limited by accepting reactor performance well below the thermodynamic equilibrium. Despite this challenge stemming from slow reaction rates the simplicity of the molten salt pyrolysis process delivers high efficiencies and promising economics. In the long-term carbon could be produced for 200–300 €/ton granting access to high-volume markets in the metallurgical and chemical process industries. Such a scenario makes turquoise hydrogen a promising alternative to blue hydrogen in regions with public resistance to CO2 transport and storage. In the medium-term expensive first-of-a-kind plants could produce carbon around 400 €/ton if hydrogen prices are set by conventional blue hydrogen production. Pure carbon at this cost level can access smaller high-value markets such as carbon anodes and graphite ensuring profitable operation even for first movers. In conclusion the economic potential of molten salt pyrolysis is high and further demonstration and scale-up efforts are strongly recommended.
Moving Toward the Low-carbon Hydrogen Economy: Experiences and Key Learnings from National Case Studies
Sep 2022
Publication
The urgency to achieve net-zero carbon dioxide (CO2) emissions by 2050 as first presented by the IPCC special report on 1.5°C Global Warming has spurred renewed interest in hydrogen to complement electrification for widespread decarbonization of the economy. We present reflections on estimates of future hydrogen demand optimization of infrastructure for hydrogen production transport and storage development of viable business cases and environmental impact evaluations using life cycle assessments. We highlight challenges and opportunities that are common across studies of the business cases for hydrogen in Germany the UK the Netherlands Switzerland and Norway. The use of hydrogen in the industrial sector is an important driver and could incentivise large-scale hydrogen value chains. In the long-term hydrogen becomes important also for the transport sector. Hydrogen production from natural gas with capture and permanent storage of the produced CO2 (CCS) enables large-scale hydrogen production in the intermediate future and is complementary to hydrogen from renewable power. Furthermore timely establishment of hydrogen and CO2 infrastructures serves as an anchor to support the deployment of carbon dioxide removal technologies such as direct air carbon capture and storage (DACCS) and biohydrogen production with CCS. Significant public support is needed to ensure coordinated planning governance and the establishment of supportive regulatory frameworks which foster the growth of hydrogen markets.
Renewable Hydrogen Supply Chains: A Planning Matrix and an Agenda for Future Research
Oct 2022
Publication
Worldwide energy systems are experiencing a transition to more sustainable systems. According to the Hydrogen Roadmap Europe (FCH EU 2019) hydrogen will play an important role in future energy systems due to its ability to support sustainability goals and will account for approximately 13% of the total energy mix in the coming future. Correct hydrogen supply chain (HSC) planning is therefore vital to enable a sustainable transition. However due to the operational characteristics of the HSC its planning is complicated. Renewable hydrogen supply can be diverse: Hydrogen can be produced de-centrally with renewables such as wind and solar energy or centrally by using electricity generated from a hydro power plant with a large volume. Similarly demand for hydrogen can also be diverse with many new applications such as fuels for fuel cell electrical vehicles and electricity generation feedstocks in industrial processes and heating for buildings. The HSC consists of various stages (production storage distribution and applications) in different forms with strong interdependencies which further increase HSC complexity. Finally planning of an HSC depends on the status of hydrogen adoption and market development and on how mature technologies are and both factors are characterised by high uncertainties. Directly adapting the traditional approaches of supply chain planning for HSCs is insufficient. Therefore in this study we develop a planning matrix with related planning tasks leveraging a systematic literature review to cope with the characteristics of HSCs. We focus only on renewable hydrogen due to its relevance to the future low-carbon economy. Furthermore we outline an agenda for future research from the supply chain management perspective in order to support HSC development considering the different phases of HSCs adoption and market development.
Powering Europe with North Sea Offshore Wind: The Impact of Hydrogen Investments on Grid Infrastructure and Power Prices
Oct 2022
Publication
Hydrogen will be a central cross-sectoral energy carrier in the decarbonization of the European energy system. This paper investigates how a large-scale deployment of green hydrogen production affects the investments in transmission and generation towards 2060 analyzes the North Sea area with the main offshore wind projects and assesses the development of an offshore energy hub. Results indicate that the hydrogen deployment has a tremendous impact on the grid development in Europe and in the North Sea. Findings indicate that total power generation capacity increases around 50%. The offshore energy hub acts mainly as a power transmission asset leads to a reduction in total generation capacity and is central to unlock the offshore wind potential in the North Sea. The effect of hydrogen deployment on power prices is multifaceted. In regions where power prices have typically been lower than elsewhere in Europe it is observed that hydrogen increases the power price considerably. However as hydrogen flexibility relieves stress in high-demand periods for the grid power prices decrease in average for some countries. This suggests that while the deployment of green hydrogen will lead to a significant increase in power demand power prices will not necessarily experience a large increase.
Operating Hydrogen-Based Energy Storage Systems in Wind Farms for Smooth Power Injection: A Penalty Fees Aware Model Predictive Control
Aug 2022
Publication
Smooth power injection is one of the possible services that modern wind farms could provide in the not-so-far future for which energy storage is required. Indeed this is one among the three possible operations identified by the International Energy Agency (IEA)-Hydrogen Implementing Agreement (HIA) within the Task 24 final report that may promote their integration into the main grid in particular when paired to hydrogen-based energy storages. In general energy storage can mitigate the inherent unpredictability of wind generation providing that they are deployed with appropriate control algorithms. On the contrary in the case of no storage wind farm operations would be strongly affected as well as their economic performances since the penalty fees wind farm owners/operators incur in case of mismatches between the contracted power and that actually delivered. This paper proposes a Model Predictive Control (MPC) algorithm that operates a Hydrogen-based Energy Storage System (HESS) consisting of one electrolyzer one fuel cell and one tank paired to a wind farm committed to smooth power injection into the grid. The MPC relies on Mixed-Logic Dynamic (MLD) models of the electrolyzer and the fuel cell in order to leverage their advanced features and handles appropriate cost functions in order to account for the operating costs the potential value of hydrogen as a fuel and the penalty fee mechanism that may negatively affect the expected profits generated by the injection of smooth power. Numerical simulations are conducted by considering wind generation profiles from a real wind farm in the center-south of Italy and spot prices according to the corresponding market zone. The results show the impact of each cost term on the performances of the controller and how they can be effectively combined in order to achieve some reasonable trade-off. In particular it is highlighted that a static choice of the corresponding weights can lead to not very effective handling of the effects given by the combination of the system conditions with the various exogenous’ while a dynamic choice may suit the purpose instead. Moreover the simulations show that the developed models and the set-up mathematical program can be fruitfully leveraged for inferring indications on the devices’ sizing.
Perspective on the Hydrogen Economy as a Pathway to Reach Net-zero CO2 Emissions in Europe
Jan 2022
Publication
The envisioned role of hydrogen in the energy transition – or the concept of a hydrogen economy – has varied through the years. In the past hydrogen was mainly considered a clean fuel for cars and/or electricity production; but the current renewed interest stems from the versatility of hydrogen in aiding the transition to CO2 neutrality where the capability to tackle emissions from distributed applications and complex industrial processes is of paramount importance. However the hydrogen economy will not materialise without strong political support and robust infrastructure design. Hydrogen deployment needs to address multiple barriers at once including technology development for hydrogen production and conversion infrastructure co-creation policy market design and business model development. In light of these challenges we have brought together a group of hydrogen researchers who study the multiple interconnected disciplines to offer a perspective on what is needed to deploy the hydrogen economy as part of the drive towards net-zero-CO2 societies. We do this by analysing (i) hydrogen end-use technologies and applications (ii) hydrogen production methods (iii) hydrogen transport and storage networks (iv) legal and regulatory aspects and (v) business models. For each of these we provide key take home messages ranging from the current status to the outlook and needs for further research. Overall we provide the reader with a thorough understanding of the elements in the hydrogen economy state of play and gaps to be filled.
In the Green? Perceptions of Hydrogen Production Methods Among the Norwegian Public
Feb 2023
Publication
This article presents findings from a representative survey fielded through the Norwegian Citizen Panel examining public perceptions of hydrogen fuel and its different production methods. Although several countries including Norway have strategies to increase the production of hydrogen fuel our results indicate that hydrogen as an energy carrier and its different production methods are still unknown to a large part of the public. A common misunderstanding seems to be confusing ‘hydrogen fuel’ in general with environmentally friendly ‘green hydrogen’. Results from a survey experiment (N = 1906) show that production method is important for public acceptance. On a five-point acceptance scale respondents score on average 3.9 for ‘green’ hydrogen which is produced from renewable energy sources. The level of acceptance is significantly lower for ‘blue’ (3.2) and ‘grey’ (2.3) hydrogen when respondents are informed that these are produced from coal oil or natural gas. Public support for hydrogen fuel in general as well as the different production methods is also related to their level of worry about climate change gender and political affiliation. Widespread misunderstandings regarding ‘green’ hydrogen production could potentially fuel public resistance as new ‘blue’ or ‘grey’ projects develop. Our results indicate a need for clearer communication from the government and developers regarding production methods to avoid distrust and potential public backfire.
Effect of Relative Permeability Hysteresis on Reservoir Simulation of Underground Hydrogen Storage in an Offshore Aquifer
Mar 2023
Publication
Underground hydrogen storage (UHS) in porous media is proposed to balance seasonal fluctuations between demand and supply in an emerging hydrogen economy. Despite increasing focus on the topic worldwide the understanding of hydrogen flow in porous media is still not adequate. In particular relative permeability hys teresis and its impact on the storage performance require detailed investigations due to the cyclic nature of H2 injection and withdrawal. We focus our analysis on reservoir simulation of an offshore aquifer setting where we use history matched relative permeability to study the effect of hysteresis and gas type on the storage efficiency. We find that omission of relative permeability hysteresis overestimates the annual working gas capacity by 34 % and the recovered hydrogen volume by 85 %. The UHS performance is similar to natural gas storage when using hysteretic hydrogen relative permeability. Nitrogen relative permeability can be used to model the UHS when hysteresis is ignored but at the cost of the accuracy of the bottom-hole pressure predictions. Our results advance the understanding of the UHS reservoir modeling approaches.
Underground Hydrogen Storage in Caverns: Challenges of Impure Salt Stuctures
Oct 2023
Publication
Hydrogen is expected to play a key role in the future as a clean energy source that can mitigate global warming. It can also contribute significantly to reducing the imbalance between energy supply and demand posed by deploying renewable energy. However the infrastructure is not ready for the direct use of hydrogen and largescale storage facilities are needed to store the excess hydrogen production. Geological formations particularly salt caverns seem to be a practical option for this large-scale storage as there is already good experience storing hydrocarbons in caverns worldwide. Salt is known to be ductile impermeable and inert to natural gas. Some cases of hydrogen storage in salt caverns in the United States the United Kingdom and Germany reinforce the idea that salt caverns could be a viable option for underground hydrogen storage especially when the challenges and uncertainties associated with hydrogen storage in porous media are considered. However cavern con struction and management can be challenging when salt deposits are not completely pure and mixed with nonsoluble strata. This review summarises the challenges associated with hydrogen storage in salt caverns and suggests some potential mitigation strategies linked to geomechanical and geochemical interactions. The Zechstein salt group in Northern Europe seems to be a feasible geological site for hydrogen storage but the effect of salt impurity particularly at deep offshore sites such as in the Norwegian North Sea should be carefully analysed. It appears that mechanical integrity geochemical reactions hydrogen loss by halophilic bacteria leaching issues and potential hydrogen diffusion are among the major issues when the internal structure of the salt is not pure.
Decarbonizing Primary Steel Production : Techno-economic Assessment of a Hydrogen Based Green Steel Production Plant in Norway
Mar 2022
Publication
High electricity cost is the biggest challenge faced by the steel industry in transitioning to hydrogen based steelmaking. A steel plant in Norway could have access to cheap emission free electricity high-quality iron ore skilled manpower and the European market. An open-source model for conducting techno-economic assessment of a hydrogen based steel manufacturing plant operating in Norway has been developed in this work. Levelized cost of production (LCOP) for two plant configurations; one procuring electricity at a fixed price and the other procuring electricity from the day-ahead electricity markets with different electrolyzer capacity were analyzed. LCOP varied from $622/tls to $722/tls for the different plant configurations. Procuring electricity from the day-ahead electricity markets could reduce the LCOP by 15%. Increasing the electrolyzer capacity reduced the operational costs but increased the capital investments reducing the overall advantage. Sensitivity analysis revealed that electricity price and iron ore price are the major contributors to uncertainty for configurations with fixed electricity prices. For configurations with higher electrolyzer capacity changes in the iron ore price and parameters related to capital investment were found to affect the LCOP significantly.
Dynamic Process Modeling of Topside Systems for Evaluating Power Consumption and Possibilities of Using Wind Power
Dec 2022
Publication
Norwegian offshore wind farms may be able to supply power to offshore oil and gas platforms in the near future thanks to the expeditious development of offshore wind technology. This would result in a reduction in CO2 emissions from oil and gas offshore installations which are currently powered predominantly by gas turbines. The challenge with using wind power is that offshore oil and gas installations require a fairly constant and stable source of power whereas wind power typically exhibits significant fluctuations over time. The purpose of this study is to perform a technical feasibility evaluation of using wind power to supply an offshore oil and gas installation on the basis of dynamic process simulations. Throughout the study only the topside processing system is considered since it is the most energy-intensive part of an oil and gas facility. An offshore field on the Norwegian Continental Shelf is used as a case study. The results indicate that when the processing system operates in steady-state conditions it cannot be powered solely by wind energy and another power source is required to compensate for low wind power generation intervals. An alternative would be to store wind energy during periods of high generation (e.g. by producing hydrogen or ammonia) and use it during periods of low generation. Utilizing energy storage methods wind energy can be continuously used for longer periods of time and provide a suitable constant power source for the studied case. Higher constant power can also be provided by increasing the efficiency of energy recovery and storage processes. Alternatively these two technologies may be integrated with gas turbines if the required storage cannot be provided or higher power is required. It was estimated that the integration of wind energy could result in noticeable reductions in CO2 emissions for the case study. Additionally according to the results the production storage and reuse of hydrogen and ammonia on-site may be viable options for supplying power.
Pore-scale Dynamics for Underground Porous Media Hydrogen Storage
Mar 2022
Publication
Underground hydrogen storage (UHS) has been launched as a catalyst to the low-carbon energy transitions. The limited understanding of the subsurface processes is a major obstacle for rapid and widespread UHS implementation. We use microfluidics to experimentally describe pore-scale multiphase hydrogen flow in an aquifer storage scenario. In a series of drainage-imbibition experiments we report the effect of capillary number on hydrogen saturations displacement/trapping mechanisms dissolution kinetics and contact angle hysteresis. We find that the hydrogen saturation after injection (drainage) increases with increasing capillary number. During hydrogen withdrawal (imbibition) two distinct mechanisms control the displacement and residual trapping – I1 and I2 imbibition mechanisms respectively. Local hydrogen dissolution kinetics show dependency on injection rate and hydrogen cluster size. Dissolved global hydrogen concentration corresponds up to 28 % of reported hydrogen solubility indicating pore-scale non-equilibrium dissolution. Contact angles show hysteresis and vary between 17 and 56°. Our results provide key UHS experimental data to improve understanding of hydrogen multiphase flow behavior.
Effect of Anion Exchange Ionomer Content on Electrode Performance in AEM Water Electrolysis
Aug 2020
Publication
Anion exchange membrane water electrolysis (AEMWE) has acquired substantial consideration as a cost-effective hydrogen production technology. The anion ionomer content in the catalyst layers during hydrogen and oxygen evolution reaction (HER and OER) is of ultimate significance. Herein an in-situ half-cell analysis with reference electrodes was carried out for simultaneous potential measurements and identification of the influence of the anion exchange ionomer (AEI) content on anode and cathode performance. The measured half-cell potentials proved the influence of AEI content on the catalytic activity of HER and OER which was supported by the rotating disk electrode (RDE) measurements. Cathode overpotential of Ni/C was not negligible and more affected by the AEI content than anode with the optimized AEI content of 10 wt% while NiO anode OER overpotential was independent of the AEI content. For the same AEI content PGM catalysts showed higher electroactivity than Ni-based catalysts for HER and OER and the cathode catalyst's intrinsic activity is of high importance in the AEM electrolysis operation. Post-mortem analysis by SEM mapping of both AEI and catalyst distributions on the electrode surface showed the effect of AEI loading on the catalyst morphology which could be related to the electrode performance.
Modelling and Simulation of a Zero-emission Hybrid Power Plant for a Domestic Ferry
Jan 2021
Publication
This paper presents a simulation tool for marine hybrid power-plants equipped with polymer exchange membrane fuel cells and batteries. The virtual model through the combination of operational data and dynamically modelled subsystems can simulate power-plants of different sizes and configurations in order to analyze the response of different energy management strategies. The model aims to replicate the realistic behavior of the components included in the vessel's grid to asses if the hardware selected by the user is capable of delivering the power set-point requested by the energy management system. The model can then be used to optimize key factors such as hydrogen consumption. The case study presented in the paper demonstrates how the model can be used for the evaluation of a retrofitting operation replacing a diesel electric power-plant with fuel cells and batteries. The vessel taken into consideration is a domestic ferry operating car and passenger transport in Denmark. The vessel is outfitted with a diesel electric plant and an alternative hybrid power-plant is proposed. The hybrid configuration is tested using the model in a discrete time-domain.
Palladium (Pd) Membranes as Key Enabling Technology for Pre-combustion CO2 Capture and Hydrogen Production
Aug 2017
Publication
Palladium (Pd) membranes are a promising enabling technology for power generation and hydrogen production with CO2 capture. SINTEF has developed and patented a flexible technology to produce Pd-alloy membranes that significantly improves flux and thereby reduces material costs. Reinertsen AS and SINTEF aim to demonstrate the Pd membrane technology for H2 separation on a side stream of the Statoil Methanol Plant at Tjeldbergodden Norway. In the present article we present the upscaling of the membrane manufacturing process together with the membrane module and skid design and construction.
Pressure Peaking Phenomena: Unignited Hydrogen Releases in Confined Spaces – Large-scale Experiments
Sep 2020
Publication
The aim of this study was to validate a model for predicting overpressure arising from accidental hydrogen releases in areas with limited ventilation. Experiments were performed in a large-scale setup that included a steel-reinforced container of volume 14.9 m3 and variable ventilation areas and mass flow rates. The pressure peaking phenomenon characterized as transient overpressure with a characteristic peak in a vented enclosure was observed during all the experiments. The model description presented the relationship between the ventilation area mass flow rate enclosure volume and discharge coefficient. The experimental results were compared with two prediction models representing a perfect mix and the real mix. The perfect mix assumed that all the released hydrogen was well stirred inside the enclosure during the releases. The real mix prediction s used the hydrogen concentration and temperature data measured during experiments. The prediction results with both perfect mix and real mix showed possible hazards during unignited hydrogen releases.
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