Institution of Gas Engineers & Managers
Applied Simulation Study of a Metal Hydride Refrigeration System for Fuel Cell Trucks
Oct 2025
Publication
Refrigeration units in semi-trucks or rigged-body trucks have an energy demand of 8.2–12.4 MWh/y and emit 524.26 kt CO2e/y in Germany. Electrification with fuel cell systems reduces the CO2 emission but an increase of efficiency is necessary because of rapidly increasing hydrogen costs. A metal hydride refrigeration system can increase the efficiency. Even though it was already demonstrated in lab scale with 900 W this power is not sufficient to support a truck refrigeration system and the power output of the lab system was not controllable. Here we show the design and validation of a MATLAB© Simulink model of this metal hydride refrigeration system and its suitability for high power applications with a scaled-up reactor. It was scaled up to rated power of 5 kW and efficiency improvements with an advanced valve switching as well as a controlled cooling pump were implemented. Two application-relevant use cases with hydrogen mass flows from hydrogen fuel cell truck systems were analyzed. The simulation results of these use cases provide an average cooling power of 4.2 and 6.1 kW. Additionally the control of the coolant mass flow at different temperature levels a controlled hydrogen mass flow with a bypass system and an advanced valve switching mechanism increased the system efficiency of the total refrigeration system by 30 % overall.
A Systematic Analysis of Life Cycle Assessments in Hydrogen Energy Systems
Nov 2025
Publication
Hydrogen plays a central role in ensuring the fulfillment of the climate and energy goals established in the Paris Agreement. To implement sustainable and resilient hydrogen economies it is essential to analyze the entire hydrogen value chain following a Life Cycle Assessment (LCA) methodology. To determine the current methodologies approaches and research tendencies adopted when performing LCA of hydrogen energy systems a systematic literature analysis is carried out in the present study. The choices regarding the “goal and scope definition” “life cycle inventory analysis” and “life cycle impact assessment” in 70 scientific papers were assessed. Based on the collected information it was concluded that there are no similar LCA studies since specificities introduced in the system boundaries functional unit production storage transportation end-use technologies geographical specifications and LCA methodological approaches among others introduce differences among studies. This lack of harmonization triggers the need to define harmonization protocols that allow for a fair comparison between studies; otherwise the decision-making process in the hydrogen energy sector may be influenced by methodological choices. Although initial efforts have been made their adoption remains limited and greater promotion is needed to encourage wider implementation.
Energy Management of Hybrid Energy System Considering a Demand-Side Management Strategy and Hydrogen Storage System
Oct 2025
Publication
Nadia Gouda and
Hamed Aly
A hybrid energy system (HES) integrates various energy resources to attain synchronized energy output. However HES faces significant challenges due to rising energy consumption the expenses of using multiple sources increased emissions due to non-renewable energy resources etc. This study aims to develop an energy management strategy for distribution grids (DGs) by incorporating a hydrogen storage system (HSS) and demand-side management strategy (DSM) through the design of a multi-objective optimization technique. The primary focus is on optimizing operational costs and reducing pollution. These are approached as minimization problems while also addressing the challenge of achieving a high penetration of renewable energy resources framed as a maximization problem. The third objective function is introduced through the implementation of the demand-side management strategy aiming to minimize the energy gap between initial demand and consumption. This DSM strategy is designed around consumers with three types of loads: sheddable loads non-sheddable loads and shiftable loads. To establish a bidirectional communication link between the grid and consumers by utilizing a distribution grid operator (DGO). Additionally the uncertain behavior of wind solar and demand is modeled using probability distribution functions: Weibull for wind PDF beta for solar and Gaussian PDF for demand. To tackle this tri-objective optimization problem this work proposes a hybrid approach that combines well-known techniques namely the non-dominated sorting genetic algorithm II and multi-objective particle swarm optimization (Hybrid-NSGA-II-MOPSO). Simulation results demonstrate the effectiveness of the proposed model in optimizing the tri-objective problem while considering various constraints.
Decarbonising Sustainable Aviation Fuel (SAF) Pathways: Emerging Perspectives on Hydrogen Integration
Oct 2025
Publication
The growing demand for air connectivity coupled with the forecasted increase in passengers by 2040 implies an exigency in the aviation sector to adopt sustainable approaches for net zero emission by 2050. Sustainable Aviation Fuel (SAF) is currently the most promising short-term solution; however ensuring its overall sustainability depends on reducing the life cycle carbon footprints. A key challenge prevails in hydrogen usage as a reactant for the approved ASTM routes of SAF. The processing conversion and refinement of feed entailing hydrodeoxygenation (HDO) decarboxylation hydrogenation isomerisation and hydrocracking requires substantial hydrogen input. This hydrogen is sourced either in situ or ex situ with the supply chain encompassing renewables or non-renewables origins. Addressing this hydrogen usage and recognising the emission implications thereof has therefore become a novel research priority. Aside from the preferred adoption of renewable water electrolysis to generate hydrogen other promising pathways encompass hydrothermal gasification biomass gasification (with or without carbon capture) and biomethane with steam methane reforming (with or without carbon capture) owing to the lower greenhouse emissions the convincing status of the technology readiness level and the lower acidification potential. Equally imperative are measures for reducing hydrogen demand in SAF pathways. Strategies involve identifying the appropriate catalyst (monometallic and bimetallic sulphide catalyst) increasing the catalyst life in the deoxygenation process deploying low-cost iso-propanol (hydrogen donor) developing the aerobic fermentation of sugar to 14 dimethyl cyclooctane with the intermediate formation of isoprene and advancing aqueous phase reforming or single-stage hydro processing. Other supportive alternatives include implementing the catalytic and co-pyrolysis of waste oil with solid feedstocks and selecting highly saturated feedstock. Thus future progress demands coordinated innovation and research endeavours to bolster the seamless integration of the cutting-edge hydrogen production processes with the SAF infrastructure. Rigorous technoeconomic and life cycle assessments alongside technological breakthroughs and biomass characterisation are indispensable for ensuring scalability and sustainability
Coordinated Control Strategy for Island Power Generation System with Photovoltaic, Hydrogen-Fueled Gas Turbine and Hybrid Energy Storage
Oct 2025
Publication
Marine and island power systems usually incorporate various forms of energy supply which poses challenges to the coordinated control of the system under diverse irregular and complex load operation modes. To improve the stability and self-sufficiency of island-isolated microgrids with high penetration of renewable energy this study proposes a coordinated control strategy for an island microgrid with PV HGT and HESS combining primary power allocation via low-pass filtering with a fuzzy logic-based secondary correction. The fuzzy controller dynamically adjusts power distribution based on the states of charge of the battery and supercapacitor following a set of predefined rules. A comprehensive system model is developed in Matlab R2023b integrating PV generation an electrolyzer HGT and a battery–supercapacitor HESS. Simulation results across four operational cases demonstrate that the proposed strategy reduces DC bus voltage fluctuations to a maximum of 4.71% (compared to 5.63% without correction) with stability improvements between 0.96% and 1.55%. The HESS avoids overcharging and over-discharging by initiating priority charging at low SOC levels thereby extending service life. This work provides a scalable control framework for enhancing the resilience of marine and island microgrids with high renewable energy penetration.
Optimizing Green Hydrogen Cost with PV Energy and Storage
Oct 2025
Publication
This work develops a replicable method for designing the optimal renewable hydrogen production facility applicable to any site and based on technical parameters and actual equipment costs. The solution is based on the integration of photovoltaic (PV) energy with lithium-ion battery storage systems which maximizes electrolyzer operating hours and significantly reduces the Levelized Cost of Hydrogen (LCOH). This study shows that increasing the inclination of the photovoltaic modules reduces the need for storage optimizing operation and extending the electrolyzer’s annual operating hours. In the Seville case study with current costs and efficiencies a minimum LCOH of €4.43/kg was achieved a value well below market benchmarks opening the door to a potentially competitive industrial business. The analysis confirms that electrolyzer efficiency—particularly specific power consumption—is the most important factor in reducing costs while technological progress in photovoltaics storage and equipment promises further reductions in the coming years. Overall the proposed methodology offers a practical and scalable tool to accelerate the economic viability of green hydrogen in a variety of contexts.
Mapping Green Hydrogen Research in North Africa: A Bibliometric Approach for Strategic Foresight
Oct 2025
Publication
This bibliometric analysis aims to map the evolution disciplinary structure and collaboration dynamics of green hydrogen (GH) research in North Africa from 2019 to 2025. Drawing on a corpus of ~39000 global publications indexed in Scopus and analysed through SciVal we isolate and examine the contributions of Egypt Morocco Algeria Tunisia and Libya. Egypt leads the region with 842 publications and a field-weighted citation impact of 2.42 followed by Morocco (232 Pubs. FWCI 2.30) and Algeria (184 Pubs. FWCI 1.65). Notably Tunisia exhibits the highest growth factor (41 times since 2019) while Libya remains marginal with only 18 publications in the GH field. The region is well represented in Energy and Environmental fields but is underrepresented in trendy areas such as Materials and Chemical Engineering highlighting critical gaps in consistency sophistication and technical infrastructure. While international collaboration exceeds 69% for most countries it rarely translates into a high impact compared to the global average. Conversely the limited industrial collaboration shows the highest citation impact (e.g. Tunisia: 68 citations/publications). A thematic analysis reveals shared strengths in electrolytic hydrogen production and renewable energy integration with Egypt showing diversification into microalgae and nanocomposites and Morocco excelling in techno-economic assessments and ammonia-based systems. By revealing patterns in research quality collaboration and thematic positioning this study offers evidence-based insights to inform national science strategies enhance regional cooperation and position North Africa more strategically in the emerging global green hydrogen economy.
Integrated Modeling of Steam Methane Reforming and Carbon Capture for Blue Hydrogen Production
Nov 2025
Publication
The increasing global demand for clean energy highlights hydrogen as a strategic energy carrier due to its high energy density and carbon-free utilization. Currently steam methane reforming (SMR) is the most widely applied method for hydrogen production; however its high CO2 emissions undermine the environmental benefits of hydrogen. Blue hydrogen production integrates carbon capture and storage (CCS) technologies to overcome this drawback in the SMR process significantly reducing greenhouse gas emissions. This study integrated a MATLAB-R2025b-based plug flow reactor (PFR) model for SMR kinetics with an Aspen HYSYS-based CCS system. The effects of reformer temperature (600–1000 ◦C) and steam-to-carbon (S/C) ratio (1–5) on hydrogen yield and CO2 emission intensity were investigated. Results show that hydrogen production increases with temperature reaching maximum conversion at 850–1000 ◦C while the optimum performance is achieved at S/C ratios of 2.5–3.0 balancing high hydrogen yield and minimized methane slip. Conventional SMR generates 9–12 kgCO2/kgH2 emissions whereas SMR + CCS reduces this to 2–3 kgCO2/kgH2 achieving more than 75% reduction. The findings demonstrate that SMR + CCS integration effectively mitigates emissions and provides a sustainable bridging technology for blue hydrogen production supporting the transition toward lowcarbon energy systems.
Computational Fluid Dynamic Modeling and Parametric Optimization of Hydrogen Adsorption in Stationary Hydrogen Tanks
Nov 2025
Publication
A. Ousegui and
B. Marcos
This study investigates hydrogen storage enhancement through adsorption in porous materials by coupling the Dubinin–Astakhov (D-A) adsorption model with H2 conservation equations (mass momentum and energy). The resulting system of partial differential equations (PDEs) was solved numerically using the finite element method (FEM). Experimental work using activated carbon as an adsorbent was carried out to validate the model. The comparison showed good agreement in terms of temperature distribution average pressure of the system and the amount of adsorbed hydrogen (H2). Further simulations with different adsorbents indicated that compact metal–organic framework 5 (MOF-5) is the most effective material in terms of H2 adsorption. Additionally the pair (273 K 800 s) remains the optimal combination of injection temperature and time. The findings underscore the prospective advantages of optimized MOF-5-based systems for enhanced hydrogen storage. These systems offer increased capacity and safety compared to traditional adsorbents. Subsequent research should investigate multi-objective optimization of material properties and system geometry along with evaluating dynamic cycling performance in practical operating conditions. Additionally experimental validation on MOF-5-based storage prototypes would further reinforce the model’s predictive capabilities for industrial applications.
Analysis of Fuel Cell Electric Vehicle Performance Under Standard Electric Vehicle Driving Protocol
Nov 2025
Publication
The paper studies and analyzes electric vehicle engines powered by hydrogen under the WLTP standard driving protocol. The driving range extension is estimated using a specific protocol developed for FCEV compared with the standard value for battery electric vehicles. The driving range is extended by 10 km averaging over the four protocols with a maximum of 11.6 km for the FTP-75 and a minimum of 7.7 km for the WLTP. This driving range extension represents a 1.8% driving range improvement on average. Applying the FCEV current weight the driving range is extended to 18.9 km and 20.4 km on average when using power source energy capacity standards for BEVs and FCEVs.
Advancing Sustainable Energy Transitions: Insights on Finance, Policy, Infrastructure, and Demand-side Integration
Nov 2025
Publication
Achieving the 1.5 ◦C global temperature target and reaching net-zero emissions by 2050 require a fundamental transformation of energy systems driven by the rapid deployment of renewable energy technologies and underpinned by systemic policy financial and infrastructural reform. The manuscript adopts a literature-driven approach synthesizing findings from existing scholarly sources that shape the transition to sustainable energy systems. It begins by outlining global progress toward climate targets emphasizing the critical role of renewable energy in decarbonizing electricity industry and transport sectors. The manuscript explores recent technological advancements and trends in solar wind hydrogen and emerging clean technologies highlighting their impact on global energy supply chains and production models. Particular attention is given to the complexities of integrating renewable energy into existing infrastructure including grid modernization digitaliation and storage technologies. On the demand side the article examines changing consumption patterns electrification and the role of distributed generation in shaping future energy landscapes. Investment and finance emerge as central challenges with the paper analyzing the disparities in capital costs between developed and developing economies and the need for innovative green finance instruments to de-risk investment. The manuscript further identifies structural barriers including policy uncertainty supply chain constraints and permitting delays as key impediments to progress. Nonetheless the article outlines significant opportunities for scaling up renewable deployment through international cooperation targeted subsidies and public-private partnerships. The manuscript concludes by emphasizing the necessity of coherent and enforceable policy frameworks to align national commitments with global climate goals. It calls for an integrated multi-stakeholder approach to ensure that finance infrastructure demand and governance evolve in tandem thereby enabling a just inclusive and resilient global energy transition.
Rooftop Agrivoltaic Powered Onsite Hydrogen Production for Insulated Gasochromic Smart Glazing and Hydrogen Vehicles: A Holistic Approach to Sustainable Residential Building
Nov 2025
Publication
The study focused on designing a sustainable building involving rooftop agrivoltaics advanced glazing technologies and onsite hydrogen production for a residential property in Birmingham UK where green hydrogen produced by harnessing electricity generated by agrivoltaics system on rooftop of the building is employed to change the transparency of vacuum gasochromic glazing and refuel hydrogen-powered fuel cell vehicle using storage hydrogen for a sustainable building approach. The change in the transparency of the glazing reduces the energy requirement of the building according to the occupant’s requirement and weather conditions. This research investigates the performance of various rooftop agrivoltaic systems including vertical optimal 30◦ tilt and dome setups for both monofacial and bifacial agrivoltaic consisting of tomato farming. Promising results were observed for agrivoltaic systems with consistent tomato production of 0.31 kg/m2 with varying shading experienced due to the different photovoltaic setups. Maximum electricity is produced by bifacial 30◦ with 7919 kWh though the lowest LCOE can be observed by monofacial 30◦ with £0.061/kWh. It also compares the efficiency of vacuum gasochromic windows against double glazing vacuum double glazing electrochromic and gasochromic options which can play an essential role in energy saving and reduced carbon emission. Vacuum gasochromic demonstrated the lowest U-value of 1.32 Wm2 K though it has the highest thickness with 24.6 mm. Additionally the study examines the feasibility of small-scale green hydrogen production from the electricity generated by agrivoltaics to fuel hydrogen vehicles and glazing considering the economic viability. The results suggested that the hydrogen required by the glazing accounts for 52.56 g annually and the maximum distance that can be covered theoretically is by bifacial 30◦ which is approximately 64.23 km per day. The interdisciplinary approach aims to optimise land use enhance energy efficiency and promote sustainable urban agriculture to contribute to the UK’s goal of increasing solar energy capacity and achieving net-zero emissions while addressing food security concerns. The findings of this study have potential implications for urban planning renewable energy integration especially solar and sustainable residential design.
A Comprehensive Review on the Compatability of Polymeric Materials for Hydrogen Transportation and Storage
Nov 2025
Publication
This review evaluates the current state of the art on polymeric materials for hydrogen transportation and storage highlighting the importance of developing a sustainable hydrogen infrastructure worldwide. It analyses different polymeric materials used for hydrogen transportation and storage applications including high-density polyethylene (HDPE) polytetrafluoroethylene (PTFE) polyimides (PI) polyether ether ketone (PEEK) polyamide ethylene propylene diene monomer (EPDM) polyvinylidene fluoride (PVDF) and fluorinated ethylene propylene (FEP). These materials are assessed using key characteristics such as hydrogen permeability mechanical strength chemical resistance and thermal stability. The review finds that while PEEK and polyimides exhibit the highest thermal stability (up to 400 °C) and pressure resistance (300–400 bar) HDPE remains the most cost-effective option for low-pressure applications. PTFE and FEP offer the lowest hydrogen permeability (<0.01 cm3 mm/m2·day·bar) making them ideal for sealing and lining in hydrogen storage systems. Furthermore key research gaps are identified and suggestions for future research and development directions are outlined. This comprehensive review is a valuable resource for researchers and engineers working towards sustainable hydrogen infrastructure development.
Unlocking Hydrogen Carrier Potential of the Yangtze River in China
Oct 2025
Publication
The Yangtze River as the world’s largest clean energy corridor links key economic regions and plays a crucial role in inland waterway transportation. However few studies have comprehensively evaluated the potential of the Yangtze River for cross-regional hydrogen transport. Here we develop a comprehensive integrated power and hydrogen supply chain (IPHSC) optimization model to evaluate the potential of cross-regional hydrogen transport via the Yangtze River. The IPHSC optimization model covers the entire hydrogen production-storage-transportation-utilization chain through cross-sector modeling of energy transportation water scheduling and environmental protection. Results show that in the 2060 carbon neutrality scenario the deployment of 62.2 kilotons of 574 differentiated liquid hydrogen (LH2) carrier ships could enable the transportation of 5018 kilotons (1512 million ton-km) of hydrogen annually meeting nearly 20% of the total electrolytic hydrogen demand across eight riverine provinces. Unlike west-to-east electricity transmission in China the central Yangtze River region is expected to become the main hub for hydrogen exports in the future. Compared with alternative methods such as transmission lines or pipelines LH2 carrier ships offer the lowest energy supply costs at 3 US cents/kWh for electricity and 5 US cents/kWh for hydrogen. Additionally a full-parameter attribution analysis of over 40 factors is conducted to assess variations in supply costs. Our study offers a thorough evaluation of the feasibility and economic benefits of hydrogen transportation via inland waterways providing a comprehensive multi-sectoral coupling assessment framework for regions with well-established inland waterway networks such as Europe and the United States.
Interfacial Damage Evolution in Hygrothermally Aged CF/PPA Composites used in Type V Hydrogen Tanks: A Multi-scale Approach
Nov 2025
Publication
This paper presents a multi-scale experimental investigation into the damage mechanisms in carbon fiberreinforced polyphthalamide (CF/PPA) composites subjected to hygrothermal aging. The study specifically targets their suitability for structural components in advanced hydrogen storage systems such as Type V pressure vessels. Polyphthalamides (PPAs) as semi-aromatic polyamides offer superior thermal stability chemical resistance and mechanical performance compared to conventional aliphatic polyamides making them promising candidates for structural components exposed to harsh environments. In order to simulate more severe environmental exposure accelerated hygrothermal aging tests were conducted at 50 ◦C in immersion. A range of microscopic to macroscopic characterization techniques were used to assess changes in mechanical performance and microstructural integrity. The analysis revealed that the CF/PPA composites retained good matrix ductility even after aging indicating the resilience of the semi-aromatic polyamide matrix under hygrothermal stress. Multi-scale damage analysis has been performed on both unaged and aged samples at 50 ◦C for various aging times. The dominant damage mechanism identified was decohesion at the fiber/matrix interface rather than bulk matrix degradation. This interfacial debonding has a significant impact on mechanical performance and is attributed to moisture-induced weakening of interfacial interactions. These findings emphasize the potential of CF/PPA composites for use in high-performance hydrogen storage applications while highlighting the critical need for interface-tailored designs to enhance environmental durability.
Methanol Steam Reforming with Samarium-stabilized Copper Sites for Efficient Hydrogen Production
Nov 2025
Publication
The rational design of Cu-based catalysts with tailored interfacial structures and electronic states remains challenging yet essential for advancing hydrogen production via methanol steam reforming (MSR). Here we developed a samarium-mediated strategy to construct a 30Sm-CuAl catalyst. The introduction of Sm promotes Cu dispersion and induces strong metal-support interactions resulting in the formation of Sm2O3- encapsulated Cu nanoparticles enriched with Cu+ -O-Sm interfaces. The optimized 30Sm-CuAl demonstrates exceptional MSR performance achieving a hydrogen production rate of 1126 mmol gcat− 1 h− 1 at 250◦C. Mechanistic studies revealed that the reaction follows the formate pathway in xSm-CuAl with formate accumulation identified as the primary reason for the deactivation of 30Sm-CuAl. Dynamic regeneration of 30SmCuAl through redox treatment restores its activity thereby enabling cyclic operation. These findings provide insights into rare-earth oxide regulation of Cu-based catalysts and lay the foundation for targeted resolution of formate intermediate accumulation to enhance MSR stability.
Interleaved Parallel VDCM Improves Stability Control of Wind Power-hydrogen Coupled Integrated System
Nov 2025
Publication
Aiming at the problems of poor transient characteristics of converter output DC voltage and large DC current ripple caused by alkaline electrolyzer (AEL) switching operation in the wind power-hydrogen coupled integrated system this paper proposes an interleaved parallel VDCM control method to improve the stable operation of the system. Firstly a refined mathematical-physical model of the wind power-hydrogen coupled integrated system including HD-PMSG interleaved parallel buck and AEL is constructed. Then the VDCM control strategy is introduced into the interleaved parallel buck converter which provides reliable inertia and damping support for the output voltage of the hydrogen production system by simulating the DC motor power regulation characteristics and effectively improving the current ripple of the output current. Meanwhile the influence of rotational inertia and the damping coefficient on the dynamic stability of the system in the control strategy is analyzed based on the small signal method. Finally the proposed method is validated through MATLAB/SIMULINK simulation experiments and RCP + HIL hardware-in-the-loop experiments. The results show that the proposed method can improve the dynamic stability of the wind power-hydrogen coupled integrated system effectively.
Quantifying Conservatism in ASME B31.12 Option A for Hydrogen Pipeline Repurposing
Nov 2025
Publication
Hydrogen is a key enabler of the energy transition and repurposing existing natural gas pipelines offers a costeffective pathway for large-scale hydrogen transport. However hydrogen embrittlement raises integrity concerns and current design standards such as ASME B31.12 Option A adopt highly conservative safety margins without a quantified reliability basis. This study evaluates whether the conservative safety margins in ASME B31.12 Option A for hydrogen pipelines can be safely relaxed. A semi-elliptical flaw (depth 0.25t length 1.5t) is assessed using the Failure Assessment Diagram (FAD) method and Monte Carlo simulations with up to 2.5 × 107 iterations. Fracture toughness is fixed at 69.3 MPa√m while wall thickness and yield strength vary statistically. Three design scenarios explore safety factor products from 0.388 to 0.720 at 0 ◦C and 20 ◦C. Results show that flaw acceptability is maintained in all deterministic cases and the probability of failure remains below 10− 6 . No failures occur when the safety factor product drops below 0.637. The analysis uses only codified flaw assumptions and public material data. These findings confirm that Option A provides a highly conservative envelope and demonstrate the value of a reliability-based approach for assessing hydrogen pipeline repurposing while addressing the gap between prescriptive standards and quantified reliability. This integrated FAD–probabilistic framework demonstrates that Option A includes significant conservatism and supports a reliability-based approach to evaluate hydrogen pipeline repurposing without experimental inputs.
A Pathway to Decarbonizing Cement Manufacturing via Solar-driven Green Hydrogen Systems
Nov 2025
Publication
The cement industry a foundation of infrastructure development is responsible for nearly 7 % of global CO2 emissions highlighting an urgent need for scalable decarbonization strategies. This study investigates the technoeconomic feasibility of integrating on-site solar-powered green hydrogen production into cement manufacturing processes. A mixed-integer linear programming (MILP) model optimizes the design and operation of solar photovoltaics (PV) proton exchange membrane (PEM) electrolyzer and hydrogen storage for a representative cement plant in Texas. Five hydrogen substitution scenarios (10–30 % of thermal demand) were evaluated based on net present cost (NPC) levelized cost of hydrogen (LCOH) cost of CO2 avoided and greenhouse gas (GHG) emissions reduction. Hydrogen integration up to 30 % is technically viable but economically constrained with LCOH rising non-linearly from $58.7 to $95.3 GJ− 1 due to escalating component costs. Environmentally a 30 % hydrogen share could reduce total U.S. cement sector emissions by 22 %. While significant this confirms at present the solar-driven hydrogen serves as a partial solution rather than a standalone pathway to deep decarbonization suggesting it must complement other strategies like carbon capture electrification and other complementary technologies. The economic viability of this approach is entirely contingent on financial incentives as the investment tax credits of 80 % or higher are essential to enable cost parity with fossil fuels. This work provides a comprehensive techno-economic and environmental framework concluding immense economic barriers and that aggressive policy support is indispensable for enabling the transition to low-carbon cement manufacturing.
Heat Recovery Unit Integrated with Biomass Gasification for Producing Hydrogen/Power/Heat Using a Novel Cascaded ORC with Biphenyl/Diphenyl Oxide Mixture; ML Optimsation and Economic Evaluation
Nov 2025
Publication
This work provides a detailed evaluation of a novel biomass-fueled multigeneration system conceived to contribute to the growing emphasis on sustainable energy solutions. The architecture comprises a biomass gasifier an innovative cascaded organic Rankine cycle (CORC) incorporating a high-temperature mixture in the top cycle a proton exchange membrane electrolyzer (PEME) a Brayton cycle and waste heat utilization units all operating together to deliver electricity hydrogen (H2) and thermal output. A comprehensive thermodynamic modeling framework is established to evaluate the system’s performance across various operational scenarios. The framework emphasizes critical metrics including exergy efficiency levelized total emissions (LTE) and payback period (PP). These indicators ensure a holistic assessment of energy exergy economic and environmental considerations. Parametric studies demonstrate that enhancements in biomass mass flow rate and combustion chamber temperature significantly increase power output and H2 production while reducing the payback period underscoring the system’s flexibility and economic feasibility. Furthermore the study employs sophisticated machine learning optimization methods combining artificial neural networks (ANNs) with genetic algorithms (GA) to determine optimal operating conditions with minimal computational effort and maximum efficiency. When evaluated at nominal parameters the system records an exergy efficiency of 23.72 % achieves a PP of 5.61 years and yields an LTE value of 0.34 ton/GJ. However under optimized conditions these values improve to 35.01 % 3.78 years and 0.241 ton/GJ respectively.
Techno-economic Analysis of Energy Micro-grids with Hydrogen Storage and Fuel Cell in Moroccan Farming Systems
Nov 2025
Publication
This study evaluates the techno-economic performance of hybrid renewable microgrids integrating hydrogen storage and fuel cells in two Moroccan pilot farms: a grid-connected site (BLFARM) and an off-grid site (RIMSAR). Real meteorological and load data were analyzed in HOMER Pro to assess feasibility. In 2024 BLFARM achieved a Levelized Cost of Energy (LCOE) of e1.63/kWh and a Renewable Fraction (Ren Frac) of 83.9% while RIMSAR reached e4.32/kWh with 100% renewable contribution. Hydrogen use remained limited due to low demand and high costs. Assuming 2050 hydrogen-technology reductions LCOE decreased to e0.160/kWh (BLFARM) and e0.425/kWh (RIMSAR) while hydrogen components were still underutilized. Aggregating demand from 5-80 farms reduced LCOE by over 50% from e0.093 to e0.045/kWh (BLFARM) and from e0.142 to e0.074/kWh (RIMSAR) while increasing electrolyzer and fuelcell operation. Community-networked hydrogen microgrids thus enhance component utilization energy resilience and cost effectiveness in rural Moroccan agriculture.
Designing and Long-term Planning for Household Hydrogen Supply Chain in Australia
Nov 2025
Publication
This study presents the development of the long-term Household Hydrogen Supply Chain (HHSC) model aimed at supporting the decarbonisation of household energy consumption. Structured across three strategic phases: foundation expansion and maturation the model facilitates the systematic phase-out of liquefied petroleum gas (LPG) by 2045 and natural gas (NG) by 2080. Employing demand estimation methodologies grounded in historical data and exponential decay functions the study forecasts long-term hydrogen adoption trajectories and allocates regional demand to optimise infrastructure placement. A network optimisation model identifies the optimal locations and capacities of national regional and local distribution centres (NDCs RDCs and LDCs). This staged development ensures operational scalability geographic equity and financial viability. A key finding is the substantial increase in profitability from $479 million in 2026 to $88.26 billion by 2090 driven by infrastructure growth and increasing hydrogen demand. Sensitivity analyses indicate that the adoption during the mid years (2040–2060) is particularly vulnerable to cost fluctuations. The model supports net-zero 2050 goals and aligns with several Sustainable Development Goals (SDGs) including SDGs 7 9 and 13. While the HHSC provides a structured pathway for long-term hydrogen transition future research should focus on enhancing the resilience of the HHSC by incorporating real-time data integration assessing vulnerability to supply chain disruptions and developing risk mitigation strategies to ensure continuity and scalability in hydrogen delivery under uncertain operating conditions.
Multi-criteria Analysis Framework for the Optimal Localization of Power-to-gas Plants: A Case Study for Germany
Nov 2025
Publication
A well-developed hydrogen infrastructure is a key element for the global energy transition. The strategic implementation of this infrastructure is challenging due to the wide range of different criteria which need to be considered and analyzed. This paper presents a novel multi-criteria analysis framework for the optimal localization of power-to-gas (PtG) plants. The framework considers criteria such as renewable energy availability hydrogen demand proximity to existing gas infrastructure and groundwater availability. A techno-economic model is integrated into the framework to evaluate the levelized cost of hydrogen (LCOH) for different electrolyzer technologies. Applying the developed framework to Germany the potential of northern and northwestern Germany as suitable locations becomes apparent. In addition LCOH for PtG plants at selected locations in Germany are evaluated depending on the year of commissioning. The large differences between present LCOH ranging from 16.8 €/kg to 9.1 €/kg illustrate the importance of an integrated techno-economic model.
Design and Simulation of an Automated and Safe Hydrogen Fuel Cell Refueling System
Nov 2025
Publication
Hydrogen fuel cells (HFCs) are an efficient clean energy solution that performs well in backup or remote application but requires an uninterrupted supply of hydrogen. Current manual refueling procedures are laborintensive pose safety risks due to hydrogen’s explosive nature and can lead to power interruption if neglected. An automated system that manages the refueling procedure safely using computer simulations has been designed and demonstrated. The system employs a pressure sensor to monitor hydrogen levels and the microcontroller scans the safety of the environment by sensing leaks and ensuring there is no risk of over-pressure activates an electric solenoid valve when the pressure falls to or below a specified low threshold of 20 bar (P_low). The valve automatically closes when the tank reaches a high-pressure value of 280 bar(P_high) or immediately upon detection of anomalies such as a sensed leak excessive pressure exceeding 320 bar(Pmax_safe) or a prolonged refilling duration beyond 400 seconds. The whole system has been simulated using MATLAB/Simulink executing five distinct test scenarios including normal operation leaks over-pressure and time-out conditions. Simulation results indicate the design is robust with all safety features performing as intended. Furthermore a roadmap for the physical prototyping and testing of the system beginning with inert gases is presented. The automated system has the potential to enhance the ease and safety of operating stationary HFCs.
Buoyancy Effects on Combustion Products from High-pressure Hydrogen Jet Flames
Nov 2025
Publication
Due to the lower radiative fraction and typically higher storage pressures gas temperatures can often result in longer safety distances compared to radiative heat transfer for hydrogen jet flames. The high temperatures however also lead to a low density causing the flow to rise at a certain distance from the release. Unfortunately a model to determine this distance similar to what is available for unignited releases is currently not available which this paper aim to provide. An experimental study was conducted investigating the buoyancy effect on ignited horizontal hydrogen jet releases with different release diameters. The invisible hydrogen plume was visualized using a Background Oriented Schlieren technique (BOS). The transition of the initial momentumdriven jet into a fully buoyancy-driven jet was estimated by following the gradient of the centerline of the plume. A model based on the Froude number of the release similar to the model for unignited releases was developed and the distance showed a very similar dependence on the Froude number but giving consistently approximately 39% shorter distances.
Analysis of Anion Exchange Membrane Water Electrolyzer Performance and its Evolution Over Time
Dec 2025
Publication
Understanding water evolved gas and ionic transport in membrane-electrode-assemblies (MEAs) is essential for the development of high performance and durable anion exchange membrane water electrolyzers (AEMWEs). This study evaluates the MEA conditioning process operating conditions and short-term stability in a 1 M potassium hydroxide (KOH) electrolyte focusing on the underlying transport phenomena. We observe a significant initial voltage loss in continuous cell operation which could be associated with gas bubble accumulation transport layer or flow field passivation and changes in the catalyst oxidation state. Further we investigate the effects of materials and operational configurations including the membrane type and thickness and the electrolyte flow rate including KOH being fed to both electrodes as well as to the anode only. Furthermore the effect of membrane drying temperature on ex situ as well as in situ electrochemical performance is evaluated. Finally we discuss 700 h of AEMWE operation at 1 A/cm2 highlighting the underlying degradation phenomena.
Evaluation of Heat Transfer Technologies for High Temperature Polymer Electrolyte Membrane Fuel Cells as Primary Power Source in a Regional Aircraft
Oct 2025
Publication
High-temperature proton exchange membrane fuel cells (HT-PEM FCs) represent a promising avenue for generating carbon dioxide-free electricity through the utilization of hydrogen fuel. These systems present numerous advantages and challenges for mobile applications positioning them as pivotal technologies for the realization of emission-free regional aircraft. Efficient thermal management of such fuel cell-powered systems is crucial for ensuring the safe and durable operation of the aircraft while concurrently optimizing system volume mass and minimizing parasitic energy consumption. This paper presents four distinct heat transfer principles tailored for the FC-system of a conceptual hydrogen-electric regional aircraft exemplified by DLR’s H2ELECTRA. The outlined approaches encompass conductive cooling air cooling liquid cooling phase change cooling and also included is the utilization of liquid hydrogen as a heat sink. Approaches are introduced with schematic cooling architectures followed by a comprehensive evaluation of their feasibility within the proposed drivetrain. Essential criteria pertinent to airborne applications are evaluated to ascertain the efficacy of each thermal management strategy. The following criteria are selected for evaluation: safety ease of integration reliability and life-cycle costs technology readiness and development as well as performance which is comprised of heat transfer weight volume and parasitic power consumption. Of the presented cooling methods two emerged to be functionally suitable for the application in MW-scale aircraft applications at their current state of the art: liquid cooling utilizing water under high pressure or other thermal carrier liquids and phase-change cooling. Air cooling and conductive cooling have a high potential due to their reduced system complexity and mass but additional studies investigating effects at architecture level in large-scale fuel cell stacks are needed to increase performance levels. These potentially suitable heat transfer technologies warrant further investigation to assess their potential for complexity and weight reduction in the aircraft drivetrain.
Marine Hydrogen Pressure Reducing Valves: A Review on Multi-Physics Coupling, Flow Dynamics, and Structural Optimization for Ship-Borne Storage Systems
Oct 2025
Publication
As a zero-carbon energy carrier hydrogen is playing an increasingly vital role in the decarbonization of maritime transportation. The hydrogen pressure reducing valve (PRV) is a core component of ship-borne hydrogen storage systems directly influencing the safety efficiency and reliability of hydrogen-powered vessels. However the marine environment— characterized by persistent vibrations salt spray corrosion and temperature fluctuations— poses significant challenges to PRV performance including material degradation flow instability and reduced operational lifespan. This review comprehensively summarizes and analyzes recent advances in the study of high-pressure hydrogen PRVs for marine applications with a focus on transient flow dynamics turbulence and compressible flow characteristics multi-stage throttling strategies and valve core geometric optimization. Through a systematic review of theoretical modeling numerical simulations and experimental studies we identify key bottlenecks such as multi-physics coupling effects under extreme conditions and the lack of marine-adapted validation frameworks. Finally we conducted a preliminary discussion on future research directions covering aspects such as the construction of coupled multi-physics field models the development of marine environment simulation experimental platforms the research on new materials resistant to vibration and corrosion and the establishment of a standardized testing system. This review aims to provide fundamental references and technical development ideas for the research and development of high-performance marine hydrogen pressure reducing valves with the expectation of facilitating the safe and efficient application and promotion of hydrogen-powered shipping technology worldwide.
Threats and Challenges Associated with Ammonia Transport via Pipeline Systems
Oct 2025
Publication
Ammonia due to its favorable physicochemical properties is considered an effective hydrogen carrier enabling the storage of surplus energy generated from renewable sources. Large-scale implementation of this concept requires the safe transport of ammonia over long distances commonly achieved through pipeline systems—a practice with global experience dating back to the 1960s. However operational history demonstrates that failures in such infrastructures remain inevitable often leading to severe environmental consequences. This article reviews both passive and active methods for preventing and mitigating incidents in ammonia pipeline systems. Passive measures include the assessment of material compatibility with ammonia and the designation of adequate buffer zones. Active methods focus on leak detection techniques such as balance-based systems acoustic monitoring and ammonia-specific sensors. Additionally the article highlights the potential environmental risks associated with ammonia release emphasizing its contribution to the greenhouse effect as well as its adverse impacts on soil surface and groundwater and human health. By integrating historical lessons with modern safety technologies the article contributes to the development of reliable ammonia transport infrastructure for the hydrogen economy.
Evaluating the Role of Hybrid Renewable Energy Systems in Supporting South Africa’s Energy Transition
Oct 2025
Publication
This report evaluates the role of Hybrid Renewable Energy Systems (HRESs) in supporting South Africa’s energy transition amidst persistent power shortages coal dependency and growing decarbonisation imperatives. Drawing on national policy frameworks including the Integrated Resource Plan (IRP 2019) the Just Energy Transition (JET) strategy and Net Zero 2050 targets this study analyses five major HRES configurations: PV–Battery PV–Diesel–Battery PV–Wind–Battery PV–Hydrogen and Multi-Source EMS. Through technical modelling lifecycle cost estimation and trade-off analysis the report demonstrates how hybrid systems can decentralise energy supply improve grid resilience and align with socio-economic development goals. Geographic application cost-performance metrics and policy alignment are assessed to inform region-specific deployment strategies. Despite enabling technologies and proven field performance the scale-up of HRESs is constrained by financial regulatory and institutional barriers. The report concludes with targeted policy recommendations to support inclusive and regionally adaptive HRES investment in South Africa.
Co-Optimization of Capacity and Operation for Battery-Hydrogen Hybrid Energy Storage Systems Based on Deep Reinforcement Learning and Mixed Integer Programming
Oct 2025
Publication
The hybrid energy storage system (HESS) that combines battery with hydrogen storage exploits complementary power/energy characteristics but most studies optimize capacity and operation separately leading to suboptimal overall performance. To address this issue this paper proposes a bi-level co-optimization framework that integrates deep reinforcement learning (DRL) and mixed integer programming (MIP). The outer layer employs the TD3 algorithm for capacity configuration while the inner layer uses the Gurobi solver for optimal operation under constraints. On a standalone PV–wind–load-HESS system the method attains near-optimal quality at dramatically lower runtime. Relative to GA + Gurobi and PSO + Gurobi the cost is lower by 4.67% and 1.31% while requiring only 0.52% and 0.58% of their runtime; compared with a direct Gurobi solve the cost remains comparable while runtime decreases to 0.07%. Sensitivity analysis further validates the model’s robustness under various cost parameters and renewable energy penetration levels. These results indicate that the proposed DRL–MIP cooperation achieves near-optimal solutions with orders of magnitude speedups. This study provides a new DRL–MIP paradigm for efficiently solving strongly coupled bi-level optimization problems in energy systems.
Hydrogen Vehicle Adoption: Perceptions, Barriers, and Global Strategies
Oct 2025
Publication
This paper analyzes the potential of hydrogen technologies in transport placing it within the context of global environmental and energy challenges. Its primary purpose is to eval‑ uate the prospects for the implementation of these technologies at international and na‑ tional levels including Poland. This study utilizes a literature review and an analysis of the results of a highly limited exploratory pilot survey measuring public perception of hydrogen technology in transport. It is critical to note that the survey was conducted on a small non‑representative sample and exhibited a strong geographical bias primarily collecting responses from Europe (50 people) and North America (30 people). This study also details hydrogen vehicle types (FCEV HICE) and the essential infrastructure required (HRS). Despite solid technological foundations the development of hydrogen technology heavily relies on non‑technical factors such as infrastructure development support pol‑ icy and social acceptance. Globally the number of vehicles and stations is growing but remains limited with the pace of development correlating with the involvement of coun‑ tries. The pilot survey revealed a generally positive perception of the technology (mainly due to environmental benefits) but highlighted three key barriers: limited availability of refueling infrastructure—51.5% of respondents strongly agreed on this obstacle high pur‑ chase and maintenance costs and insufficient public awareness. Infrastructure subsidies and tax breaks were identified as effective incentives. Hydrogen technology offers a poten‑ tially competitive and sustainable transport solution but it demands significant systemic support intensive investment in large‑scale infrastructure expansion and comprehensive educational activities. Further governmental engagement is crucial. The severe limitations resulting from the pilot nature of the survey should be rigorously taken into account dur‑ ing interpretation.
Assessment of Regional Hydrogen Refueling Station Layout Planning and Carbon Reduction Benefits Based on Multi-Dimensional Factors of Population, Land, and Demand
Oct 2025
Publication
The urgent global transition toward low-carbon energy systems has highlighted the need for systematic planning of hydrogen refueling stations (HRS) to facilitate clean energy adoption. This study develops an integrated framework for regional HRS layout optimization and carbon emission assessment considering population distribution land area and hydrogen demand. Using Hainan Province as a case study the model estimates regional hydrogen demand determines optimal HRS deployment evaluates spatial coverage and refueling distances and quantifies potential carbon emission reductions under various renewable energy scenarios. Model validation with Haikou demonstrates its reliability and applicability at the regional scale. Results indicate pronounced spatial disparities in hydrogen demand and infrastructure requirements emphasizing that prioritizing station deployment in densely populated urban areas can enhance accessibility and maximize emission reduction. The framework offers a practical data-efficient tool for policymakers and planners to guide early-stage hydrogen infrastructure development and supports strategies for regional decarbonization and sustainable energy transitions.
Degradation Heterogeneity in Active X70 Pipeline Welds Microstructure-Property Coupling Under Multiphysics Environments of Hydrogen-Blended Natural Gas
Oct 2025
Publication
This study investigates the performance degradation of X70 steel weld material in highpressure natural gas pipelines in the Sichuan-Chongqing region and its impact on pipeline safety by investigating their behavior under multiphysics environments including varying gas media (nitrogen methane hydrogen-blended) pressure conditions (0.1–10 MPa) and material regions (base metal vs. weld). A key novelty of this work is the introduction of a “degradation rate” metric to quantitatively assess the deterioration of weld mechanical properties. A key novelty of this work is the explicit introduction of a “degradation rate” metric to quantitatively assess the deterioration of weld mechanical properties. Slow strain rate tensile tests combined with fracture morphology and microstructure analysis reveal that welds exhibit inferior mechanical properties due to microstructural inhomogeneity and residual stresses including a yield stress reduction of 15.2–18.7%. The risk of brittle fracture was highest in the hydrogen-blended environment while nitrogen exhibited the most benign effect. Material region changes were identified as the most significant factor affecting degradation. This research provides crucial data and theoretical support for pipeline safety design and material performance optimization.
Enhanced Performance of TiO2 Composites for Solar Cells and Photocatalytic Hydrogen Production
Oct 2025
Publication
Xue Bai,
Jian Chen,
Shengxi Du and
Yan Xiong
Titanium dioxide (TiO2) is widely used in solar cells and photocatalysts given its excellent photoactivity low cost and high structural electronic and optical stability. Here a novel TiO2 composite was prepared by coating TiO2 inverse opal (IO) with TiO2 nanorods (NRs). With a porous three-dimensional network structure the composite exhibited higher light absorption; enhanced the separation of the electron–hole pairs; deepened the infiltration of the electrolyte; better transported and collected charge carriers; and greatly improved the power conversion efficiency (PCE) of the quantum-dot sensitized solar cells (QDSSCs) based on it while also boosting its own photocatalytic hydrogen generation efficiency. A very high PCE of 12.24% was achieved by QDSSCs utilizing CdS/CdSe sensitizer. Furthermore the TiO2 composite exhibited high photocatalytic activity with a H2 release rate of 1080.2 µ mol h−1 g −1 several times that of bare TiO2 IO or TiO2 NRs.
Transient Analysis of Solar Driven Hydrogen Generation System Using Industrial Waste Water
Oct 2025
Publication
This study investigates an integrated solar-powered system for wastewater treatment and hydrogen production combining solar PV a humidification–dehumidification (HDH) system solar thermal collectors and electrolysis. The objective is to evaluate the feasibility of utilizing industrial wastewater for both clean water production and green hydrogen generation. A transient analysis is conducted using TRNSYS and EES software modeling a system designed to process 4000 kg of wastewater daily. The results indicate that the HDH system produces 300 kg of clean water per hour while the electrolyzer generates approximately 66.5 kg of hydrogen per hour. The solar PV system operates under the weather conditions of Kohat Pakistan. This integrated approach demonstrates significant potential for sustainable wastewater treatment and renewable energy production offering a promising solution for industrial applications.
A Review on Combustion Instability of Hydrogen-Enriched Marine Gas Turbines
Nov 2025
Publication
Hydrogen is widely regarded as a promising carbon-free alternative fuel. However the development of low-emission marine gas turbine combustion systems has been hindered by the associated risks of combustion instability also termed as thermoacoustic oscillations. Although there is sufficient literature on hydrogen fuel and combustion instability systematic reviews addressing the manifestations and mechanisms of these instabilities remain limited. The present study aims to provide a comprehensive review of combustion instabilities in hydrogen-enriched marine gas turbines with a particular focus on elucidating the characteristics and underlying mechanisms. The review begins with a concise overview of recent progress in understanding the fundamental combustion properties of hydrogen and then details various instability phenomena in hydrogen-enriched methane flames. The mechanisms by which hydrogen enrichment affects combustion instabilities are extensively discussed particularly in relation to the feedback loop in thermoacoustic combustion systems. The paper concludes with a summary of the key combustion instability challenges associated with hydrogen addition to methane flames and offers prospects for future research. In summary the review highlights the interaction between hydrogenenriched methane flames and thermoacoustic phenomena providing a foundation for the development of stable low-emission combustion systems in industrial marine applications incorporating hydrogen enrichment.
Methodology for Evaluating and Comparing Different Sustainable Energy Generation and Storage Systems for Residential Buildings—Application to the Case of Spain
Nov 2025
Publication
This paper focuses on assessing different sustainable energy generation and storage systems for residential buildings in Spain identifying the best-performing system according to the end-user requirements. As outlined by the consulted literature the authors have selected two types of hybrid configurations—a Photovoltaic System with Battery Backup (PSBB) and a Photovoltaic System with Hydrogen Hybrid Storage Backup (PSHB)—and a Grid-Based System with Renewable Hydrogen Contribution (GSHC) is proposed. A Fuzzy Analytical Hierarchy Process methodology (FAHP) is employed for evaluating the hybrid power systems from a multi-criteria approach: acquisition operational and environmental. The main requirements for selecting the optimal system are organized under these criteria and evaluated using key performance indicators. This methodology allows the selection of the best option considering objective and subjective system performance indicators. Beyond establishing the ranking a sensitivity analysis was conducted to provide insights into how individual criteria influence the ranking of the hybrid power systems alternatives. The results demonstrate that the selection of hybrid power systems for a residential building is highly dependent on consumer preferences but the PSBB system scores highly in operation and acquisition criteria while the GSHC has good performance in all the criteria.
Deployment of Modular Renewable Energy Sources and Energy Storage Schemes in a Renewable Energy Valley
Nov 2025
Publication
While community energy initiatives and pilot projects have demonstrated technical feasibility and economic benefits their site-specific nature limits transferability to systematic scalable investment models. This study addresses this gap by proposing a modular framework for Renewable Energy Valleys (REVs) developed from real-world Community Energy Lab (CEL) demonstrations in Crete Greece which is an island with pronounced seasonal demand fluctuation strong renewable potential and ongoing hydrogen valley initiatives. Four modular business schemes are defined each representing different sectoral contexts by combining a baseline of 50 residential units with one representative large consumer (hotel rural households with thermal loads municipal swimming pool or hydrogen bus). For each scheme a mixed-integer linear programming model is applied to optimally size and operate integrated solar PV wind battery (BAT) energy storage and hydrogen systems across three renewable energy penetration (REP) targets: 90% 95% and 99.9%. The framework incorporates stochastic demand modeling sector coupling and hierarchical dispatch schemes. Results highlight optimal technology configurations that minimize dependency on external sources and curtailment while enhancing reliability and sustainability under Mediterranean conditions. Results demonstrate significant variation in optimal configurations across sectors and targets with PV capacity ranging from 217 kW to 2840 kW battery storage from 624 kWh to 2822 kWh and hydrogen systems scaling from 65.2 kg to 192 kg storage capacity. The modular design of the framework enables replication beyond the specific context of Crete supporting the scalable development of Renewable Energy Valleys that can adapt to diverse sectoral mixes and regional conditions.
Evaluating Greenhouse Gas Reduction Efficiency Through Hydrogen Ecosystem Implementation from a Life-Cycle Perspective
Nov 2025
Publication
With growing global demand for sustainable decarbonization hydrogen energy systems have emerged as a key pillar in achieving carbon neutrality. This study assesses the greenhouse gas (GHG) reduction efficiency of Republic of Korea’s hydrogen ecosystem from a life-cycle perspective focusing on production and utilization stages. Using empirical data—including the national hydrogen supply structure fuel cell electric vehicle (FCEV) deployment and hydrogen power generation records the analysis compares hydrogenbased systems with conventional fossil fuel systems. Results show that current hydrogen production methods mainly by-product and reforming-based hydrogen emit an average of 6.31 kg CO2-eq per kg H2 providing modest GHG benefits over low-carbon fossil fuels but enabling up to a 77% reduction when replacing high-emission sources like anthracite. In the utilization phase grey hydrogen-fueled stationary fuel cells emit more GHGs than the national grid. By contrast FCEVs demonstrate a 58.2% GHG reduction compared to internal combustion vehicles with regional variability. Importantly this study omits the distribution phase (storage and transport) due to data heterogeneity and a lack of reliable datasets which limits the comprehensiveness of the LCA. Future research should incorporate sensitivity or scenario-based analyses such as comparisons between pipeline transport and liquefied hydrogen transport to better capture distribution-phase impacts. The study concludes that the environmental benefit of hydrogen systems is highly dependent on production pathways end-use sectors and regional conditions. Strategic deployment of green hydrogen regional optimization and the explicit integration of distribution and storage in future assessments are essential to enhancing hydrogen’s contribution to national carbon neutrality goals.
Feasibility and Sensitivity Analysis of an Off-Grid PV/Wind Hybrid Energy System Integrated with Green Hydrogen Production: A Case Study of Algeria
Nov 2025
Publication
Algeria’s transition toward sustainable energy requires the exploitation of its abundant solar and wind resources for green hydrogen production. This study assesses the technoeconomic feasibility of an off-grid PV/wind hybrid system integrated with a hydrogen subsystem (electrolyzer fuel cell and hydrogen storage) to supply both electricity and hydrogen to decentralized sites in Algeria. Using HOMER Pro five representative Algerian regions were analyzed accounting for variations in solar irradiation wind speed and groundwater availability. A deferrable water-extraction and treatment load was incorporated to model the water requirements of the electrolyzer. In addition a comprehensive sensitivity analysis was conducted on solar irradiation wind speed and the capital costs of PV panels and wind turbines to capture the effects of renewable resource and investment cost fluctuations. The results indicate significant regional variation with the levelized cost of energy (LCOE) ranging from 0.514 to 0.868 $/kWh the levelized cost of hydrogen (LCOH) between 8.31 and 12.4 $/kg and the net present cost (NPC) between 10.28 M$ and 17.7 M$ demonstrating that all cost metrics are highly sensitive to these variations.
Benefit Allocation Strategies for Electric–Hydrogen Coupled Virtual Power Plants with Risk–Reward Tradeoffs
Nov 2025
Publication
Driven by carbon neutrality goals electric–hydrogen coupled virtual power plants (EHCVPPs) integrate renewable hydrogen production with power system flexibility resources emerging as a critical technology for large-scale renewable integration. As distributed energy resources (DERs) within EHCVPPs diversify heterogeneous resources generate diversified market values. However inadequate benefit allocation mechanisms risk reducing participation incentives destabilizing cooperation and impairing operational efficiency. To address this benefit allocation must balance fairness and efficiency by incorporating DERs’ regulatory capabilities risk tolerance and revenue contributions. This study proposes a multi-stage benefit allocation framework incorporating risk–reward tradeoffs and an enhanced optimization model to ensure sustainable EHCVPP operations and scalability. The framework elucidates bidirectional risk–reward relationships between DERs and EHCVPPs. An individualized risk-adjusted allocation method and correction mechanism are introduced to address economic-centric inequities while a hierarchical scheme reduces computational complexity from diverse DERs. The results demonstrate that the optimized scheme moderately reduces high-risk participants’ shares increasing operator revenue by 0.69% demand-side gains by 3.56% and reducing generation-side losses by 1.32%. Environmental factors show measurable yet statistically insignificant impacts. The framework meets stakeholders’ satisfaction and minimizes deviation from reference allocations.
Changes in the Operating Conditions of Distribution Gas Networks as a Function of Altitude Conditions and the Proportion of Hydrogen in Transported Natural Gas
Nov 2025
Publication
The article presents a comparison between the pressure conditions of a real low-pressure gas network and the results of hydraulic calculations obtained using various simulation programs and empirical equations. The calculations were performed using specialized gas network analysis software: STANET (ver 10.0.26) SimNet SSGas 7 and SONET. Additionally the simulation results were compared with calculations based on the empirical Darcy–Weisbach and Renouard equations. In the first part of the analysis two calculation models were compared. In one model the geodetic elevation of individual network nodes was included (elevation-aware model) while in the second calculations were performed without considering node elevation (flat model). For low-pressure gas networks accounting for elevation is critical due to the presence of the pressure recovery phenomenon which does not occur in medium- and high-pressure networks. Furthermore considering the growing need to increase the share of renewable energy the study also examined the network’s operating conditions when using natural gas–hydrogen mixtures. The following hydrogen concentrations were considered: 2.5% 5.0% 10.0% 20.0% and 50.0%. The results confirm the importance of incorporating elevation data in the modeling of low-pressure gas networks. This is supported by the small differences between calculated results and actual pressure measurements taken from the operating network. Moreover increasing the hydrogen content in the mixture intensifies the pressure recovery effect. The hydraulic results obtained using different computational tools were consistent and showed only minor discrepancies.
Durable Pt-Decorated NiFe-LDH for High-Current-Density Electrocatalytic Water Splitting Under Alkaline Conditions
Nov 2025
Publication
The development of durable and efficient catalysts capable of driving both hydrogen and oxygen evolution reactions is essential for advancing sustainable hydrogen production through overall water electrolysis. In this study we developed a corrosion-mediated approach where Ni ions originate from the self-corrosion of the nickel foam (NF) substrate to construct Pt-modified NiFe layered double hydroxide (Pt-NiFeOxHy@NiFe-LDH) under ambient conditions. The obtained catalyst exhibits a hierarchical architecture with abundant defect sites which favor the uniform distribution of Pt clusters and optimized electronic configuration. The Pt-NiFeOxHy@NiFe-LDH catalyst constructed through the interaction between Pt sites and defective NiFe layered double hydroxide (NiFe-LDH) demonstrates remarkable hydrogen evolution reaction (HER) activity delivering an overpotential as low as 29 mV at a current density of 10 mA·cm−2 and exhibiting a small tafel slope of 34.23 mV·dec−1 in 1 M KOH together with excellent oxygen evolution reaction (OER) performance requiring only 252 mV to reach 100 mA·cm−2 . Moreover the catalyst demonstrates outstanding activity and durability in alkaline seawater maintaining stable operation over long-term tests. The Pt-NiFeOxHy@NiFe-LDH electrode when integrated into a two-electrode system demonstrates operating voltages as low as 1.42 and 1.51 V for current densities of 10 and 100 mA·cm−2 respectively and retains outstanding stability under concentrated alkaline conditions (6 M KOH 70 ◦C). Overall this work establishes a scalable and economically viable pathway toward high-efficiency bifunctional electrocatalysts and deepens the understanding of Pt-LDH interfacial synergy in promoting water-splitting catalysis.
Correlation Development for Para-to-Ortho Hydrogen Catalytic Conversion in Vapor-Cooled Shields of Hydrogen Tanks
Nov 2025
Publication
The cooling effect from the para-ortho hydrogen conversion (POC) combined with a vaporcooled shield (VCS) and multi-layer insulation (MLI) can effectively extend the storage duration of liquid hydrogen in cryogenic tanks. However there is currently no effective and straightforward empirical correlation available for predicting the catalytic POC efficiency in VCS pipelines. This study focuses on the development of correlations for the catalytic conversion of para-hydrogen to ortho-hydrogen in pipelines particularly in the context of cryogenic hydrogen storage systems. A model that incorporates the Langmuir adsorption characteristics of catalysts and introduces the concept of conversion efficiency to quantify the catalytic process’s performance is introduced. Experimental data were obtained in the temperature range of 141.9~229.9 K from a cryogenic hydrogen catalytic conversion facility where the effects of temperature pressure and flow rate on the catalytic conversion efficiency were analyzed. Based on a validation against the experimental data the proposed model offers a reliable method for predicting the cooling effects and optimizing the catalytic conversion process in VCS pipelines which may contribute to the improvement of liquid hydrogen storage systems enhancing both the efficiency and duration of storage.
A Review on Electric Vehicle Charging Station Planning: Infrastructure Placement, Sizing, Upgrades, and Uncertainties
Nov 2025
Publication
Electric Vehicles (EVs) are rapidly expanding resulting in increased demand on power systems and transportation networks. This study reviews recent advancements in planning EV Charging Stations (EVCSs) focusing on siting sizing grid upgrades and managing uncertainty. Analysis suggests that while many studies optimize either the location or the size of these stations few consider their combined effects resulting in missed opportunities for synergy. A lack of attention to cross-sector integration with hydrogen inadequate treatment of grid reinforcement and fragmented approaches to modeling uncertainties such as EV behavior renewable energy variability and market dynamics is also observed. To address these gaps a synthesis of the interdependencies between siting and sizing is provided along with a review of multi-energy integration opportunities an evaluation of Vehicle-to-Grid technology and smart charging including technical benefits and challenges strategies that link the deployment of EVCS to grid upgrades and a taxonomy of uncertainty sources along with advanced stochastic and data-driven solutions. This review emphasizes the importance of integrated data-informed planning in the development of EV charging infrastructure.
Coordinated Operation Mechanism of Electric-hydrogen-traffic Coupling System that Considers Carbon Emissions and Uncertainties
Nov 2025
Publication
During the critical period of energy transition the collaborative optimization of the electricity-hydrogentransportation coupling system is of vital importance for achieving efficient energy utilization and sustainable development.This paper proposes a collaborative operation mechanism of Distributed Robust Optimization (DRO) considering carbon emissions. Firstly a Stackelberg game dynamic pricing strategy is constructed for the integrated energy station (IES) and the electricity-hydrogen hybrid charging station (HRS) where the upper-level IES optimizes the electricity price setting strategy and the lower-level HRS dynamically adjusts the electricity purchase-hydrogen production plan. Secondly the Wasserstein distance is used to describe the uncertainties of hydrogen vehicle loads and wind-solar power generation and a bisection algorithm-column constraint generation (BA-C&CG) hybrid algorithm is designed to solve the model. Finally the numerical example verification shows that the daily operation cost of HRS under the proposed mechanism is as low as 1108.53 EUR which is 10.58 % and 7.38 % lower than that of the commonly used stochastic optimization (SO) and robust optimization (RO) respectively. The variance analysis (F = 536.05P < 0.001) confirms that the cost advantage is statistically significant. In terms of carbon emission reduction effect the DRO-Stackelberg game model has the lowest daily carbon cost (6.98EUR). This mechanism effectively balances the economic and robustness of the system and the single dispatch calculation time is only 112.09 s meeting the real-time operation requirements of engineering. It provides technical support for the low-carbon collaborative operation of the electricity-hydrogen-transportation coupling system.
Building a Hydrogen Economy: Does France have the Industrial Capacity for a Low-carbon Transition?
Oct 2025
Publication
The energy transition towards low-carbon hydrogen (H2) in France is expected to require deep industrial planning to develop electrolysis and H2 production infrastructure. This study employs an input–output method to simulate a new sector of electrolysis-produced hydrogen (e-H2) that supplies two-hydrogen intensive sectors petroleum refining and ammonia. We construct two input–output models a demand-driven model for e-H2 sector development (the investment phase) and a mixed model for e-H2 production (the operation phase). The results demonstrate that the e-H2 sector depends on industries such as machinery electrical equipment construction and metal products manufacturing in the investment phase with strong backward linkages to the power sector in the exploitation phase. The results reveal that the energy shock (350 kt of e-H2 per year) generates significant growth (€1.3 Bn of gross domestic product) and jobs (3600) but strongly depends on industries’ capability to expand and recruit. Recommendations advise public policy development to address the need to reinforce key industries to support e-H2 production due to inter-industry dependence and the need for more attractive skilled and technician jobs in sectors that are already experiencing recruitment tensions. At much higher e-H2 shocks in the steel sector (700 kt e-H2) and other industries (415 kt e-H2) even greater amounts of domestic resources would be required. Therefore de-carbonising the entire H2 sector require ambitious policy planning to support industrial empowerment research programmes and labour training so that H2 becomes an enabling technology of the energy transition.
Tailored Heat Treatments to Characterise the Fracture Resistance of Critical Weld Regions in Hydrogen Transmission Pipelines
Nov 2025
Publication
A new protocol is presented to directly characterise the toughness of microstructural regions present within the weld heat-affected zone (HAZ) the most vulnerable location governing the structural integrity of hydrogen transport pipelines. Heat treatments are tailored to obtain bulk specimens that replicate predominantly ferriticbainitic bainitic and martensitic microstructures present in the HAZ. These are applied to a range of pipeline steels to investigate the role of manufacturing era (vintage versus modern) chemical composition and grade. The heat treatments successfully reproduce the hardness levels and microstructures observed in the HAZ of existing natural gas pipelines. Subsequently fracture experiments are conducted in air and pure H2 at 100 bar revealing a reduced fracture resistance and higher hydrogen embrittlement susceptibility of the HAZ microstructures with initiation toughness values as low as 32 MPa√ m. The findings emphasise the need to adequately consider the influence of microstructure and hard brittle zones within the HAZ.
Catalysts for Unlocking H2 Production from NH3: A Process Design Perspective
Nov 2025
Publication
NH3 cracking is gaining attention as a promising route for on-demand carbon-free H2 production particularly in off-grid or distributed energy applications. Nevertheless its practical implementation hinges on the development of catalysts not only highly active but also cost-effective and thermally efficient. Starting from the state-of-theart catalyst for NH3 decomposition (nickel-based) the most promising catalytic systems (ruthenium-based) are critically reviewed with a focus on the interplay between catalyst activation energy thermal duty and operating conditions. In view of discussing whether the implementation of noble-based catalysts can be practical or not a technical analysis of the cracking furnace with different Ru-based catalytic systems is presented referring to a decentralized application representative of compact yet industrially relevant units. The trade-off between technical and economic performance is quantified with the aim of offering design guidelines for developing scalable NH3 cracking.
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