Publications
Research on Energy Management Method of Fuel Cell/Supercapacitor Hybrid Trams Based on Optimal Hydrogen Consumption
Jul 2023
Publication
In this paper based on the operating states and characteristics of fuel cell/supercapacitor hybrid trams an optimal hydrogen energy management method is proposed. This method divides the operating states into two parts: traction state and non-traction state. In the traction state the real-time loss function of the hybrid power system which is used to obtain the fuel cell optimal output power under the different demand powers and supercapacitor voltage is established. In the non-traction state the constant-power charging method which is obtained by solving the power-voltage charging model is used to ensure the supercapacitor voltage of the beginning-state and the end-state in an entire operation cycle are the same. The RT-LAB simulation platform is used to verify that the proposed method has the ability to control the hybrid real-time system. Using the comparative experiment between the proposed method and power-follow method the results show that the proposed method offers a significant improvement in both fuel cell output stability and hydrogen consumption in a full operation cycle.
Precise Dynamic Modelling of Real-World Hybrid Solar-Hydrogen Energy Systems for Grid-Connected Buildings
Jul 2023
Publication
Hybrid renewable hydrogen energy systems could play a key role in delivering sustainable solutions for enabling the Net Zero ambition; however the lack of exact computational modelling tools for sizing the integrated system components and simulating their real-world dynamic behaviour remains a key technical challenge against their widespread adoption. This paper addresses this challenge by developing a precise dynamic model that allows sizing the rated capacity of the hybrid system components and accurately simulating their real-world dynamic behaviour while considering effective energy management between the grid-integrated system components to ensure that the maximum possible proportion of energy demand is supplied from clean sources rather than the grid. The proposed hybrid system components involve a solar PV system electrolyser pressurised hydrogen storage tank and fuel cell. The developed hybrid system model incorporates a set of mathematical models for the individual system components. The developed precise dynamic model allows identifying the electrolyser’s real-world hydrogen production levels in response to the input intermittent solar energy production while also simulating the electrochemical behaviour of the fuel cell and precisely quantifying its real-world output power and hydrogen consumption in response to load demand variations. Using a university campus case study building in Scotland the effectiveness of the developed model has been assessed by benchmarking comparison between its results versus those obtained from a generic model in which the electrochemical characteristics of the electrolyser and fuel cell systems were not taken into consideration. Results from this comparison have demonstrated the potential of the developed model in simulating the real-world dynamic operation of hybrid solar hydrogen energy systems for grid-connected buildings while sizing the exact capacity of system components avoiding oversizing associated with underutilisation costs and inaccurate simulation.
Benchmark Study for the Simulation of Underground Hydrogen Storage Operations
Aug 2022
Publication
While the share of renewable energy sources increased within the last years with an ongoing upward trend the energy sector is facing the problem of storing large amounts of electrical energy properly. To compensate daily and seasonal fluctuations a sufficient storage system has to be developed. The storage of hydrogen in the subsurface referred to as Underground Hydrogen Storage (UHS) shows potential to be a solution for this problem. Hydrogen produced from excess energy via electrolysis is injected into a subsurface reservoir and withdrawn when required. As hydrogen possesses unique thermodynamic properties many commonly used correlations can not be simply transferred to a system with a high hydrogen content. Mixing processes with the present fluids are essential to be understood to achieve high storage efficiencies. Additionally in the past microbial activity e.g. by methanogenic archaea was observed leading to a changing fluid composition over time. To evaluate the capability of reservoir simulators to cover these processes the present study establishes a benchmark scenario of an exemplary underground hydrogen storage scenario. The benchmark comprises of a generic sandstone gas reservoir and a typical gas storage schedule is defined. Based on this benchmark the present study assesses the capabilities of the commercial simulator Schlumberger ECLIPSE and the open-source simulator DuMux to mimic UHS related processes such as hydrodynamics but also microbial activity. While ECLIPSE offers a reasonable mix of user-friendliness and computation time DuMux allows for a better adjustment of correlations and the implementation of biochemical reactions. The corresponding input data (ECLIPSE format) and relevant results are provided in a repository to allow this simulation study’s reproduction and extension.
Analyzing the Future Potential of Defossilizing Industrial Specialty Glass Production with Hydrogen by LCA
Mar 2022
Publication
The glass industry is part of the energy-intensive industry with most of the energy needed to melt the raw materials. To produce glass temperatures between 1000 and 1600 °C are necessary. Presently mostly fossil natural gas is the dominant energy source. As direct electrification is not always possible in this paper a Life Cycle Assessment (LCA) for specialty glass production is conducted where the conventional fossil-based reference process is compared to a hydrogen-fired furnace. This hydrogen can be produced on-site in an water electrolyzer using not only the hydrogen for the combustion but also the produced oxygen. Hydrogen can be produced alternatively off-site in a large scale electrolyzer to facilitate economy of scale. For the transport and distribution of this hydrogen different options are available. A rather new option are liquid organic hydrogen carriers (LOHC) which bind the hydrogen in a chemical substance. However temperatures around 300 °C are necessary to separate the hydrogen from the LOHC after transport. At the glass trough waste heat is available at the required temperature level to facilitate the dehydrogenation. The comparison is completed by the production of off-site hydrogen transported to the glass trough as conventional liquefied hydrogen in cooling tanks by truck or in hydrogen pipelines. In this assessment to power the electrolyzers the national grid mix of Germany is used. A time frame from 2020 till 2050 and its changing energy system towards defossilisation is analyzed. Regarding climate change on-site hydrogen production causes the least impact for specialty glass production in 2050. However negative trade-offs for other environmental impact categories e.g. Metal depletion are recorded.
Numerical Investigation of a Fuel Cell-Powered Agricultural Tractor
Nov 2022
Publication
In recent years growing awareness about environmental issues is pushing humankind to explore innovative technologies to reduce the anthropogenic sources of pollutants. Among these sources internal combustion engines in non-road mobile machinery (NRMM) such as agricultural tractors are one of the most important. The aim of this work is to explore the possibility of replacing the conventional diesel engine with an electric powertrain powered by a hybrid storage system consisting of a small battery pack and a fuel-cell system. The battery pack (BP) is necessary to help the fuel cell manage sudden peaks in power demands. Numerical models of the conventional powertrain and a fuel-cell tractor were carried out. To compare the two powertrains work cycles derived from data collected during real operative conditions were exploited and simulated. For the fuel-cell tractor a control strategy to split the electric power between the battery pack and the fuel cell was explored. The powertrains were compared in terms of greenhouse gas emissions (GHG) according to well-to-wheel (WTW) equivalent CO2 emission factors available in the literature. Considering the actual state-of-the-art hydrogen production methods the simulation results showed that the fuel-cell/battery powertrain was able to accomplish the tasks with a reduction of about 50% of the equivalent CO2 emissions compared to traditional diesel-powered vehicles.
Insights into Decision-making for Offshore Green Hydrogen Infrastructure Developments
Apr 2023
Publication
Green hydrogen is a key element that has the potential to play a critical role in the global pursuit of a resilient and sustainable future. However like other energy production methods hydrogen comes with challenges including high costs and safety concerns across its entire value chain. To overcome these low-cost productions are required along with a promised market. Offshore renewables have an enormous potential to facilitate green hydrogen production on a large scale. Their plummeting cost technological advances and rising cost of carbon pave a pathway where green hydrogen can be cost-competitive against fossil-fuel-based hydrogen. Offshore industries including oil and gas aquaculture and shipping are looking for cleaner energy solutions to decarbonize their systems/operations and can serve as a substantial market. Offshore industrial nexus moreover can assist the production storage and transmission of green hydrogen through infrastructure sharing and logistical support. The development of offshore green hydrogen production facilities is in its infancy and requires a deeper insight into the key elements that govern decision-making during their life-cycle. This includes the parameters that reflect the performance of hydrogen technology with technical socio-political financial and environmental considerations. Therefore this study provides critical insight into the influential factors discovered through a comprehensive analysis that governs the development of an offshore green hydrogen system. Insights are also fed into the requirements for modelling and analysis of these factors considering the synergy of hydrogen production with the offshore industries coastal hydrogen hub and onshore energy demand. The results of this critical review will assist the researchers and developers in establishing and executing an effective framework for offshore site selection in largely uncertain and hazardous ocean environments. Overall the study will facilitate the stakeholders and researchers in developing decision-making tools to ensure sustainable and safe offshore green hydrogen facilities.
The Sector Coupling Concept: A Critical Review
Jun 2020
Publication
Pursued climate goals require reduced greenhouse gas emissions by substituting fossil fuels with energy from renewable sources in all energy-consuming processes. On a large-scale this can mainly be achieved through electricity from wind and sun which are subject to intermittency. To efficiently integrate this variable energy a coupling of the power sector to the residential transport industry and commercial/trade sector is often promoted called sector coupling (SC). Nevertheless our literature review indicates that SC is frequently misinterpreted and its scope varies among available research from exclusively considering the use of excess renewable electricity to a rather holistic view of integrated energy systems including excess heat or even biomass sources. The core objective of this article is to provide a thorough understanding of the SC concept through an analysis of its origin and its main purpose as described in the current literature. We provide a structured categorization of SC derived from our findings and critically discuss its remaining challenges as well as its value for renewable energy systems. We find that SC is rooted in the increasing use of variable renewable energy sources and its main assets are the flexibility it provides for renewable energy systems decarbonization potential for fossil-fuel-based end-consumption sectors and consequently reduced dependency on oil and gas extracting countries. However the enabling technologies face great challenges in their economic feasibility because of the uncertain future development of competing solutions.
Technoeconomic Analysis for Green Hydrogen in Terms of Production, Compression, Transportation and Storage Considering the Australian Perspective
Jul 2023
Publication
This current article discusses the technoeconomics (TE) of hydrogen generation transportation compression and storage in the Australian context. The TE analysis is important and a prerequisite for investment decisions. This study selected the Australian context due to its huge potential in green hydrogen but the modelling is applicable to other parts of the world adjusting the price of electricity and other utilities. The hydrogen generation using the most mature alkaline electrolysis (AEL) technique was selected in the current study. The results show that increasing temperature from 50 to 90 ◦C and decreasing pressure from 13 to 5 bar help improve electrolyser performance though pressure has a minor effect. The selected range for performance parameters was based on the fundamental behaviour of water electrolysers supported with literature. The levelised cost of hydrogen (LCH2 ) was calculated for generation compression transportation and storage. However the majority of the LCH2 was for generation which was calculated based on CAPEX OPEX capital recovery factor hydrogen production rate and capacity factor. The LCH2 in 2023 was calculated to be 9.6 USD/kgH2 using a base-case solar electricity price of 65–38 USD/MWh. This LCH2 is expected to decrease to 6.5 and 3.4 USD/kgH2 by 2030 and 2040 respectively. The current LCH2 using wind energy was calculated to be 1.9 USD/kgH2 lower than that of solar-based electricity. The LCH2 using standalone wind electricity was calculated to be USD 5.3 and USD 2.9 in 2030 and 2040 respectively. The LCH2 predicted using a solar and wind mix (SWM) was estimated to be USD 3.2 compared to USD 9.6 and USD 7.7 using standalone solar and wind. The LCH2 under the best case was predicted to be USD 3.9 and USD 2.1 compared to USD 6.5 and USD 3.4 under base-case solar PV in 2030 and 2040 respectively. The best case SWM offers 33% lower LCH2 in 2023 which leads to 37% 39% and 42% lower LCH2 in 2030 2040 and 2050 respectively. The current results are overpredicted especially compared with CSIRO Australia due to the higher assumption of the renewable electricity price. Currently over two-thirds of the cost for the LCH2 is due to the price of electricity (i.e. wind and solar). Modelling suggests an overall reduction in the capital cost of AEL plants by about 50% in the 2030s. Due to the lower capacity factor (effective energy generation over maximum output) of renewable energy especially for solar plants a combined wind- and solar-based electrolysis plant was recommended which can increase the capacity factor by at least 33%. Results also suggest that besides generation at least an additional 1.5 USD/kgH2 for compression transportation and storage is required.
Recent Challenges and Development of Technical and Technoeconomic Aspects for Hydrogen Storage, Insights at Different Scales; A State of Art Review
May 2024
Publication
The importance of the energy transition and the role of green hydrogen in facilitating this transition cannot be denied. Therefore it is crucial to pay close attention to and thoroughly understand hydrogen storage which is a critical aspect of the hydrogen supply chain. In this comprehensive review paper we have undertaken the task of categorising and evaluating various hydrogen storage technologies across three different scales. These scales include small-scale and laboratory-based methods such as metal-based hydrides physical adsorbents and liquid organic hydrogen carriers. Also we explore medium and large-scale approaches like compressed gaseous hydrogen liquid cryogenic hydrogen and cryocompressed hydrogen. Lastly we delve into very large-scale options such as salt caverns aquifers depleted gas/oil reservoirs abandoned mines and hard rock caverns. We have thoroughly examined each storage technology from technical and maturity perspectives as well as considering its techno-economic viability. It is worth noting that development has been ongoing for each storage mechanism; however numerous technical and economic challenges persist in most areas. Particularly the cost per kilogramme of hydrogen for most current technologies demands careful consideration. It is recommended that small-scale hydrogen storage technologies such as metal hydrides (e.g. MgH2 LiBH4) need ongoing research to enhance their performance. Physical adsorbents have limited capacity except for activated carbon. Some liquid organic hydrogen carriers (LCOHs) are suitable for medium-scale storage in the near term. Ammonia-borane (AB) with its high gravimetric and volumetric properties is a promising choice for medium-scale storage pending effective dehydrogenation. It shows potential as a hydrogen carrier due to its high storage capacity stability and solubility surpassing DOE targets for storage capabilities. Medium-scale storage utilising compressed gas cylinders and advancements in liquefied and cryocompressed hydrogen storage requires cost reduction measures and a strategic supply chain. Large-scale storage options include salt caverns aquifers and depleted gas/oil reservoirs with salt caverns offering pure hydrogen need further technoeconomic analysis and deployment projects to mature but storage costs are reasonable ranging mostly from €0.25/kg to €1.5/kg for location specific large-scale options.
Global Green Hydrogen-based Steel Opportunities Surrounding High Quality Renewable Energy and Iron Ore Deposits
May 2023
Publication
The steel sector currently accounts for 7% of global energy-related CO2 emissions and requires deep reform to disconnect from fossil fuels. Here we investigate the market competitiveness of one of the widely considered decarbonisation routes for primary steel production: green hydrogen-based direct reduction of iron ore followed by electric arc furnace steelmaking. Through analysing over 300 locations by combined use of optimisation and machine learning we show that competitive renewables-based steel production is located nearby the tropic of Capricorn and Cancer characterised by superior solar with supplementary onshore wind in addition to high-quality iron ore and low steelworker wages. If coking coal prices remain high fossil-free steel could attain competitiveness in favourable locations from 2030 further improving towards 2050. Large-scale implementation requires attention to the abundance of suitable iron ore and other resources such as land and water technical challenges associated with direct reduction and future supply chain configuration.
Vision for a European Metrology Network for Energy Gases
Mar 2022
Publication
As Europe moves towards decarbonising its energy infrastructure new measurement needs will arise that require collaborative efforts between European National Metrology Institutes and Designated Institutes to tackle. Such measurement needs include flow metering of hydrogen or hydrogen enriched natural gas in the gas grid for billing quality assurance of hydrogen at refuelling stations and equations of state for carbon dioxide in carbon capture and storage facilities. The European metrology network for energy gases for the first time provides a platform where metrology institutes can work together to develop a harmonised strategy prioritise new challenges and share expertise and capabilities to support the European energy gas industry to meet stringent EU targets for climate change and emissions reductions
The Potential of Zero-carbon Bunker Fuels in Developing Countries
Apr 2015
Publication
To meet the climate targets set forth in the International Maritime Organization’s Initial GHG Strategy the maritime transport sector needs to abandon the use of fossil-based bunker fuels and turn toward zero-carbon alternatives which emit zero or at most very low greenhouse gas (GHG) emissions throughout their lifecycles. This report “The Potential of Zero-Carbon Bunker Fuels in Developing Countries” examines a range of zero-carbon bunker fuel options that are considered to be major contributors to shipping’s decarbonized future: biofuels hydrogen and ammonia and synthetic carbon-based fuels. The comparison shows that green ammonia and green hydrogen strike the most advantageous balance of favorable features due to their lifecycle GHG emissions broader environmental factors scalability economics and technical and safety implications. Furthermore the report finds that many countries including developing countries are very well positioned to become future suppliers of zero-carbon bunker fuels—namely ammonia and hydrogen. By embracing their potential these countries would be able to tap into an estimated $1+ trillion future fuel market while modernizing their own domestic energy and industrial infrastructure. However strategic policy interventions are needed to unlock these potentials.
Carbon-neutral Cement: The Role of Green Hydrogen
Mar 2024
Publication
Business-as-usual (BAU) cement production is associated with a linear model that contributes significantly to global warming and is dependent on volatile energy markets. A novel circular model is proposed by adding three power-to-gas system components to current production systems: a calcium-looping (CaL) CO2 capture unit; water electrolysis for hydrogen and oxygen generation; and a methanation unit for synthetic natural gas (SNG) production. The paper presents the first analysis of the combined industrial-scale operation of these components in a closed loop where the SNG fuels the cement kiln and the CaL unit while the O2 produced feeds it. The circular hybrid and BAU models are compared in three feasibility scenarios. It is concluded that the circular model outperforms the other alternatives environmentally opening a potential pathway for the cement industry to achieve near net-zero CO2 emissions reduce energy dependence and improve economic efficiency.
Delivering a Reliable Decarbonised Power System
Mar 2023
Publication
This report illustrates what a reliable resilient decarbonised electricity supply system could look like in 2035 and the steps required to achieve it. It provides new insights and new advice on how such a system can be achieved by 2035 using real weather data and hourly analysis of Great Britain’s power system (Northern Ireland is part of the all-Ireland system). It also looks at the implications for hydrogen.
Improvement of MC Method in SAE J2601 Hydrogen Refuelling Protocol Using Dual-zone Dual-Temperature Model
Sep 2023
Publication
The MC method refuelling protocol in SAE J2601 has been published by the Society of Automotive Engineers (SAE) in order to safely and quickly refuel hydrogen vehicles. For the calculation method of the pressure target to control the refuelling stop we introduced a dual-zone dual-temperature model that distinguishes the hydrogen temperature in the tank from the wall temperature to replace the dual-zone single-temperature model of the original MC method. The total amount of heat transferred by convection between hydrogen and the inner tank wall during the filling process was expressed as an equation of final hydrogen temperature final wall temperature final refuelling time tank inner surface area and the correction factor. The correction factor equations were determined by fitting simulation data from the 0D1D model where hydrogen inside the tank is lumped parameter model (0D) and the tank wall is a one-dimensional model (1D). For the correction factor of the linear equation its first-order coefficient and constant term have a linear relationship with the initial pressure of the storage tank and their R2 values obtained from the fitting are greater than 0.99. Finally we derived a new equation to calculate the final hydrogen temperature which can be combined with the 100% SOC inside the vehicle tank to determine the pressure target. The simulation results show that the final SOC obtained are all greater than 96% using the modified pressure target and the correction factor of the linear equation.
China's Hydrogen Development: A Tale of Three Cities
Mar 2023
Publication
China is the world’s largest producer and consumer of hydrogen. The country has adopted a domestic strategy that targets significant growth in hydrogen consumption and production. Given the importance of hydrogen in the low-carbon energy transition it is critical to understand China’s hydrogen policies and their implementation as well as the extent to which these contribute to the country’s low-carbon goals.<br/>Existing research has focused on understanding policies and regulations in China and their implications for the country’s hydrogen prospects. This study aims to improve our understanding of central-government initiatives and look at how China’s hydrogen policies are implemented at the local level. The paper examines the three cities of Zhangjiakou (in China’s renewable-rich Hebei province) Datong (in the country’s coal-heartland of Shanxi province) and Chengdu which is rich in hydropower and natural gas. To be sure the three cities analysed in this paper do not cover all regional plans and initiatives but they offer a useful window into local hydrogen policy implementation. They also illustrate the major challenges facing green hydrogen as it moves beyond the narrow highly subsidized field of fuel cell vehicles (FCVs). Indeed costs as well as water land availability and technology continue to be constraints.<br/>The hydrogen policies and road maps reviewed in this paper offer numerous targets—often setting quantitative goals for FCVs hydrogen refuelling stations hydrogen supply chain revenue and new hydrogen technology companies—aligning with the view that hydrogen development is currently more of an industrial policy than a decarbonisation strategy. Indeed hydrogen’s potential to decarbonise sectors such as manufacturing and chemicals is of secondary importance if mentioned at all. But as the cities analysed here view hydrogen as part of their industrial programmes economic development and climate strategies support is likely to remain significant even as the specific incentive schemes will likely evolve.<br/>Given this local hydrogen development model rising demand for hydrogen in China could ultimately increase rather than decrease CO₂ emissions from fossil fuels in the short run. At the same time even though the central government’s hydrogen targets (as laid out in its 2022 policy documents) seem relatively conservative Chinese cities’ appetite for new sources of growth and the ability to fund various business models are worth watching.
Influence of Longitudinal Wind on Hydrogen Leakage and Hydrogen Concentration Sensor Layout of Fuel Cell Vehicles
Jul 2023
Publication
Hydrogen has the physical and chemical characteristics of being flammable explosive and prone to leakage and its safety is the main issue faced by the promotion of hydrogen as an energy source. The most common scene in vehicle application is the longitudinal wind generated by driving and the original position of hydrogen concentration sensors (HCSs) did not consider the influence of longitudinal wind on the hydrogen leakage trajectory. In this paper the computational fluid dynamics (CFD) software STAR CCM 2021.1 is used to simulate the hydrogen leakage and diffusion trajectories of fuel cell vehicles (FCVs) at five different leakage locations the longitudinal wind speeds of 0 km/h 37.18 km/h and 114 km/h and it is concluded that longitudinal wind prolongs the diffusion time of hydrogen to the headspace and reduces the coverage area of hydrogen in the headspace with a decrease of 81.35%. In order to achieve a good detection effect of fuel cell vehicles within the longitudinal wind scene based on the simulated hydrogen concentration–time matrix the scene clustering method based on vector similarity evaluation was used to reduce the leakage scene set by 33%. Then the layout position of HCSs was optimized according to the proposed multi-scene full coverage response time minimization model and the response time was reduced from 5 s to 1 s.
Optimal Operation and Market Integration of a Hybrid Farm with Green Hydrogen and Energy Storage: A Stochastic Approach Considering Wind and Electricity Price Uncertainties
Mar 2024
Publication
In recent years growing interest has emerged in investigating the integration of energy storage and green hydrogen production systems with renewable energy generators. These integrated systems address uncertainties related to renewable resource availability and electricity prices mitigating profit loss caused by forecasting errors. This paper focuses on the operation of a hybrid farm (HF) combining an alkaline electrolyzer (AEL) and a battery energy storage system (BESS) with a wind turbine to form a comprehensive HF. The HF operates in both hydrogen and day-ahead electricity markets. A linear mathematical model is proposed to optimize energy management considering electrolyzer operation at partial loads and accounting for degradation costs while maintaining a straightforward formulation for power system optimization. Day-ahead market scheduling and real-time operation are formulated as a progressive mixed-integer linear program (MILP) extended to address uncertainties in wind speed and electricity prices through a two-stage stochastic optimization model. A bootstrap sampling strategy is introduced to enhance the stochastic model’s performance using the same sampled data. Results demonstrate how the strategies outperform traditional Monte Carlo and deterministic approaches in handling uncertainties increasing profits up to 4% per year. Additionally a simulation framework has been developed for validating this approach and conducting different case studies.
Risk Management of Energy Communities with Hydrogen Production and Storage Technologies
Jul 2023
Publication
The distributed integration of renewable energy sources plays a central role in the decarbonization of economies. In this regard energy communities arise as a promising entity to coordinate groups of proactive consumers (prosumers) and incentivize investment on clean technologies. However the uncertain nature of renewable energy generation residential loads and trading tariffs pose important challenges both at the operational and economic levels. We study how this management can be directly undertaken by an arbitrageur that making use of an adequate price-based demand response (real-time pricing) system serves as an intermediary with the central electricity market to coordinate different types of prosumers under risk aversion. In particular we consider a sequential futures and spot market where the aggregated shortage or excess of energy within the community can be traded. We aim to study the impact of new hydrogen production and storage technologies on community operation and risk management. These interactions are modeled as a game theoretical setting in the form of a stochastic two-stage bilevel optimization problem which is later reformulated without approximation as a single-level mixed-integer linear problem (MILP). An extensive set of numerical experiments based on real data is performed to study the operation of the energy community under different technical and economical conditions. Results indicate that the optimal involvement in futures and spot markets is highly conditioned by the community’s risk aversion and self-sufficiency levels. Moreover the external hydrogen market has a direct effect on the community’s internal price-tariff system and depending on the market conditions may worsen the utility of individual prosumers.
How Hydrogen (H2) Can Support Food Security: From Farm to Fork
Mar 2024
Publication
Molecular hydrogen (H2 ) is a low-molecular-weight non-polar and electrochemically neutral substance that acts as an effective antioxidant and cytoprotective agent with research into the effects of H2 incorporation into the food chain at various stages rapidly gaining momentum. H2 can be delivered throughout the food growth production delivery and storage systems in numerous ways including as a gas as hydrogen-rich water (HRW) or with hydrogen-donating food supplements such as calcium (Ca) or magnesium (Mg). In plants H2 can be exploited as a seedpriming agent during seed germination and planting during the latter stages of plant development and reproduction as a post-harvest treatment and as a food additive. Adding H2 during plant growth and developmental stages is noted to improve the yield and quality of plant produce through modulating antioxidant pathways and stimulating tolerance to such environmental stress factors as drought stress enhanced tolerance to herbicides (paraquat) and increased salinity and metal toxicity. The benefits of pre- and post-harvest application of H2 include reductions in natural senescence and microbial spoilage which contribute to extending the shelf-life of animal products fruits grains and vegetables. This review collates empirical findings pertaining to the use of H2 in the agri-food industry and evaluates the potential impact of this emerging technology.
Research on Power Optimization for Energy System of Hydrogen Fuel Cell Wheel-Driven Electric Tractor
Apr 2024
Publication
Hydrogen fuel cell tractors are emerging as a new power source for tractors. Currently there is no mature energy management control method available. Existing methods mostly rely on engineers’ experience to determine the output power of the fuel cell and the power battery resulting in relatively low energy utilization efficiency of the energy system. To address the aforementioned problems a power optimization method for the energy system of hydrogen fuel cell wheel-driven electric tractor was proposed. A dynamic model of tractor ploughing conditions was established based on the system dynamics theory. From this based on the equivalent hydrogen consumption theory the charging and discharging of the power battery were equivalent to the fuel consumption of the hydrogen fuel cell forming an equivalent hydrogen consumption model for the tractor. Using the state of charge (SOC) of the power battery as a constraint and with the minimum equivalent hydrogen consumption as the objective function an instantaneously optimized power allocation method based on load demand in the energy system is proposed by using a traversal algorithm. The optimization method was simulated and tested based on the MATLAB simulation platform and the results showed under ploughing conditions compared with the rule-based control strategy the proposed energy system power optimization method optimized the power output of hydrogen fuel cells and power batteries allowing the energy system to work in a high-efficiency range reducing the equivalent hydrogen consumption of the tractor by 7.79% and solving the energy system power distribution problem.
Fluid-dynamics Analyses and Economic Investigation of Offshore Hydrogen Transport via Steel and Composite Pipelines
Apr 2024
Publication
One of the challenges associated with the use of hydrogen is its storage and transportation. Hydrogen pipelines are an essential infrastructure for transporting hydrogen from offshore production sites to onshore distribution centers. This paper presents an innovative analysis of the pressure drops velocity profile and levelized cost of hydrogen (LCOH) in various hydrogen transportation scenarios examining the influence of pipeline type (steel vs. composite) diameter and outlet pressure. The role of the compressor and the pipeline individually and together was assessed for 1000 and 100 tons of hydrogen. Notably the LCOH was highly sensitive to these parameters with the compressor contribution ranging between 21.52% and 85.11% and the pipeline’s share varying from 14.89% to 78.48%. The outflow pressure and diameter of the pipeline have a significant impact on the performance: when 1000 tons of hydrogen is transported the internal pressure drop ranges from 2 to 30 bar and the flow velocity can vary between 2 and 25 m/s. For equivalent hydrogen quantities the composite pipeline exhibits the same trends but with minor variations in the specific values.
Technical Performance and Environmental Assessment of an Ionic Liquid-based CCS Process for Hydrogen Production
Apr 2023
Publication
Hydrogen (H2) production combined with carbon capture and storage (CCS) is anticipated to be an important technology contributing to reduce the carbon footprint of current fossil-based H2 production systems. This work addresses for the first time the techno-environmental assessment of a CCS process based on the ionic liquid [Bmim][Acetate] for H2 production by steam methane reforming (SMR) and the comparison to conventional amine-based systems. Two different SMR plants using MDEA or [Bmim][Acetate] for CO2 capture were rigorously modelled using Aspen Plus to compute material and energy needs and emissions. Literature and simulation results were then used to perform a life cycle impact assessment (LCIA) of these processes based on the ReCiPe model. Solvent synthesis CCS process and hydrogen production stages were considered for the cradle-to-gate analysis. Results showed that although [Bmim][Acetate] is a priori more harmful to the environment than amines (in a kg-to-kg comparison) LCIAs carried out for both CCS processes showed from 5 to 17 % lower environmental impacts values for all estimated categories when using [Bmim][Acetate] due to a 9.4 % more energy-efficient performance than MDEA which also reduced a 17.4 % the total utility cost. Indeed if a typical amine loss rate of 1.6 kg/tCO2 is assumed the values of the environmental impacts increase up to 14 % for the IL-based CCS plant but still maintaining its favorable results over MDEA. As consequence the SMR plant with the IL-based CCS system exhibited 3–20 % lower values for most of the studied impact categories. These results contribute to shed some light on evaluating the sustainability of ILs with respect to conventional solvents for CO2 capture and to guide the synthesis of new more sustainable ILs but also they would be used to compare the environmental burdens from the synthesis and process performance of other promising ILs for CO2 capture that are not environmentally assed yet.
Additive Manufacturing for Proton Exchange Membrane (PEM) Hydrogen Technologies: Merits, Challenges, and Prospects
Jul 2023
Publication
With the growing demand for green technologies hydrogen energy devices such as Proton Exchange Membrane (PEM) fuel cells and water electrolysers have received accelerated developments. However the materials and manufacturing cost of these technologies are still relatively expensive which impedes their widespread commercialization. Additive Manufacturing (AM) commonly termed 3D Printing (3DP) with its advanced capabilities could be a potential pathway to solve the fabrication challenges of PEM parts. Herein in this paper the research studies on the novel AM fabrication methods of PEM components are thoroughly reviewed and analysed. The key performance properties such as corrosion and hydrogen embrittlement resistance of the additively manufactured materials in the PEM working environment are discussed to emphasise their reliability for the PEM systems. Additionally the major challenges and required future developments of AM technologies to unlock their full potential for PEM fabrication are identified. This paper provides insights from the latest research developments on the significance of advanced manufacturing technologies in developing sustainable energy systems to address the global energy challenges and climate change effects.
Efficiency and Optimal Load Capacity of E-Fuel-Based Energy Storage Systems
Apr 2023
Publication
This work evaluates the effectiveness of chemical-based solutions for storing large amounts of renewable electricity. Four “Power-to-X-to-Power” pathways are examined comprising hydrogen methane methanol and ammonia as energy carriers. The pathways are assessed using a model scenario where they are produced with electricity from an onshore wind farm stored in suitable facilities and then reconverted to electricity to meet the energy demand of a chemical site. An energy management and storage capacity estimation tool is used to calculate the annual load coverage resulting from each pathway. All four pathways offer a significant increase in load coverage compared to a scenario without storage solution (56.19%). The hydrogen-based pathway has the highest load coverage (71.88%) and round-trip efficiency (36.93%) followed by the ammonia-based (69.62% 31.37%) methanol-based (67.85% 27.00%) and methane-based (67.64% 26.47% respectively) pathways. The substantially larger storage capacity required for gaseous energy carriers to ensure a steady supply to the consumer could be a decisive factor. The hydrogen pathway requires a storage volume up to 10.93 times larger than ammonia and 16.87 times larger than methanol. Notably ammonia and methanol whose load coverages are only 2.26 and 4.03 percentage points lower than that of hydrogen offer the possibility of implementing site-specific storage solutions avoiding potential bottlenecks due to limited pipeline and cavern capacities.
Massive Green Hydrogen Production Using Solar and Wind Energy: Comparison between Europe and the Middle East
Jul 2023
Publication
This comparative study examines the potential for green hydrogen production in Europe and the Middle East leveraging 3MWp solar and wind power plants. Experimental weather data from 2022 inform the selection of two representative cities namely Krakow Poland (Europe) and Diyala Iraq (Middle East). These cities are chosen as industrial–residential zones representing the respective regions’ characteristics. The research optimizes an alkaline water electrolyzer capacity in juxtaposition with the aforementioned power plants to maximize the green hydrogen output. Economic and environmental factors integral to green hydrogen production are assessed to identify the region offering the most advantageous conditions. The analysis reveals that the Middle East holds superior potential for green hydrogen production compared to Europe attributed to a higher prevalence of solar and wind resources coupled with reduced land and labor costs. Hydrogen production costs in Europe are found to range between USD 9.88 and USD 14.31 per kilogram in contrast to the Middle East where costs span from USD 6.54 to USD 12.66 per kilogram. Consequently the Middle East emerges as a more feasible region for green hydrogen production with the potential to curtail emissions enhance air quality and bolster energy security. The research findings highlight the advantages of the Middle East industrial–residential zone ‘Diyala’ and Europe industrial–residential zone ‘Krakow’ in terms of their potential for green hydrogen production.
Coordinated Planning and Operation of Inter Seasonal Heat Storage and P2G Devices Integrated to Urban Multi-energy System
Mar 2023
Publication
With the urbanization construction and the advancement of the carbon peaking and carbon neutrality goals urban energy systems are characterized by coupling multi-energy networks and a high proportion of renewable energy. Urban energy systems need to improve the quality of energy use as well as to achieve energy conservation and emission reduction. Inter-seasonal heat technology has satisfactory engineering application prospects in promoting renewable energy consumption and the energy supply of urban multi-energy systems. Considering inter-seasonal heat storage and electric hydrogen production a joint optimization method of planning and operation is proposed for the urban multi-energy flow system. First the operation framework of inter-seasonal heat storage and electric hydrogen production system is established which clarifies the energy flow of the urban multi-energy system. Secondly aiming at the goals of minimizing the equipment’s annual investment cost and the multi-energy system annual operation cost combined with the time series period division method a planning operation model has been established considering multi-objectives. Through case study it is shown that the proposed model can promote the renewable energy consumption and reduce the operation cost of the whole system.
THyGA - Test Report on Mitigation Solutions for Residential Natural Gas Appliances Not Designed for Hydrogen Admixture
Apr 2023
Publication
This report from the WP5 “Mitigation” provides information and test results regarding perturbations that hydrogen could cause to gas appliances when blended to natural gas especially on anatural draught for exhaust fumes or acidity for the condensates. The important topic of on-site adjustment is also studied with test results on alternative technologies and proposals of mitigation approaches.
Emerging Borophene Two-dimensional Nanmaterials for Hydrogen Storage
May 2023
Publication
The growing demand for energy and the need to reduce the carbon footprint has made green hydrogen a promising alternative to traditional fossil fuels. Green hydrogen is produced using renewable energy sources making it a sustainable and environmentally friendly energy source. Solid-state hydrogen storage aims to store hydrogen in a solid matrix offering potential advantages such as higher safety and improved energy density compared to traditional storage methods such as compressed gas or liquid hydrogen. However the development of efficient and economically viable solid-state storage materials is still a challenge and research continues in this field. Borophene is a two-dimensional material that offers potential as an intermediate hydrogen storage material due to its moderate binding energy and reversible behavior. Its unique geometry and electronic properties also allow for higher hydrogen adsorption capacity than metal-based complex hydrides surpassing the goals set by the U.S. Department of Energy. Borophene has shown great potential for hydrogen storage but it is still not practical for commercial use. In this review borophene nanomaterials chemical and physical properties are discussed related to hydrogen storage and binding energy. The importance of borophene for hydrogen storage the challenges it faces and its future prospects are also being discussed.
A Techno-economic Analysis of Cross-regional Renewable Hydrogen Supply Routes in China
Jun 2023
Publication
The cross-regional renewable hydrogen supply is significant for China to resolve the uneven distribution of renewable energy and decarbonize the transportation sector. Yet the economic comparison of various hydrogen supply routes remains obscure. This paper conducts a techno-economic analysis on six hydrogen supply routes for hydrogen refueling stations including gas-hydrogen tube-trailer gas-hydrogen pipeline liquid-hydrogen truck natural gas pipeline MeOH truck and NH3 truck. Furthermore the impacts of three critical factors are examined including electrolyzer selection transportation distance and electricity price. The results indicate that with a transport distance of 2000 km the natural gas pipeline route offers the lowest cost while the gas-hydrogen tube-trailer route is not economically feasible. The gas-hydrogen pipeline route shows outstanding cost competitiveness between 200 and 2000 km while it is greatly influenced by the utilization rate. The liquid-hydrogen truck route demonstrates great potential with the electricity price decreasing. This study may provide guidance for the development of the cross-regional renewable hydrogen supply for hydrogen refueling stations in China.
Research Progress of Hydrogen Production Technology and Related Catalysts by Electrolysis of Water
Jun 2023
Publication
As a clean and renewable energy source for sustainable development hydrogen energy has gained a lot of attention from the general public and researchers. Hydrogen production by electrolysis of water is the most important approach to producing hydrogen and it is also the main way to realize carbon neutrality. In this paper the main technologies of hydrogen production by electrolysis of water are discussed in detail; their characteristics advantages and disadvantages are analyzed; and the selection criteria and design criteria of catalysts are presented. The catalysts used in various hydrogen production technologies and their characteristics are emphatically expounded aiming at optimizing the existing catalyst system and developing new high-performance high-stability and low-cost catalysts. Finally the problems and solutions in the practical design of catalysts are discussed and explored.
Optimal Pathways for the Decarbonisation of the Transport Sector: Trade-offs Between Battery and Hydrogen Technologies Using a Whole Energy System Perspective
Jun 2023
Publication
Several countries have revised their targets in recent years to reach net-zero CO2 emissions across all sectors by 2050 and the transport sector is responsible for a significant share of these emissions. This study compares possible pathways to decarbonise the transport sector through electrification including passenger cars light commercial vehicles and heavy commercial vehicles. To do so we explore 125 scenarios by varying the share of battery and hydrogen-based fuel cell electric vehicles in each of the three categories above independently. We further model the decarbonisation of the industrial hydrogen demand using electrolysers with hydrogen storage. To explore the potential role of electric and hydrogen transport as well as their trade-offs we use GRIMSEL an open-source sector coupling energy system model of Switzerland which includes the residential commercial industrial and transport sectors with four energy carriers namely electricity heat hot water and hydrogen. The total costs are minimised from a social planner perspective. We find that the full electrification of the transport sector could lead on average to a 12% increase in costs by 2050 and 1.3 MtCO2/year which represents a 90% CO2 emissions reduction for the whole sector. Second the transport energy self-sufficiency (i.e. the share of domestic electricity generation in final transport demand) may reach up to 50% for the scenarios with the largest share of battery electric vehicles mainly due to a smaller energy demand than with hydrogen vehicles. Third more than three quarters of the industrial hydrogen production is met by local photovoltaic electricity coupled with battery at minimum costs i.e. green hydrogen. Finally the use of hydrogen as an energy carrier to store electricity over a long period is not cost-optimal.
Hydrogen Storage by Liquid Hydrogen Carriers: Catalyst, Renewable Carrier, and Technology - A Review
Mar 2023
Publication
Hydrogen has attracted widespread attention as a carbon-neutral energy source but developing efficient and safe hydrogen storage technologies remains a huge challenge. Recently liquid organic hydrogen carriers (LOHCs) technology has shown great potential for efficient and stable hydrogen storage and transport. This technology allows for safe and economical large-scale transoceanic transportation and long-cycle hydrogen storage. In particular traditional organic hydrogen storage liquids are derived from nonrenewable fossil fuels through costly refining procedures resulting in unavoidable environmental contamination. Biomass holds great promise for the preparation of LOHCs due to its unique carbon-balance properties and feasibility to manufacture aromatic and nitrogen-doped compounds. According to recent studies almost 100% conversion and 92% yield of benzene could be obtained through advanced biomass conversion technologies showing great potential in preparing biomass-based LOHCs. Overall the present LOHCs systems and their unique applications are introduced in this review and the technical paths are summarized. Furthermore this paper provides an outlook on the future development of LOHCs technology focusing on biomass-derived aromatic and N-doped compounds and their applications in hydrogen storage.
Green Hydrogen Futures: Tensions of Energy and Justice Within Sociotechnical Imaginaries
May 2024
Publication
As a reformist approach to low-carbon transitions green hydrogen is often promoted as an easy replacement for fossil fuels. This substitution narrative makes this technology compelling as it offers to reduce emissions while continuing the contemporary energy system. Using ‘sociotechnical imaginaries’ this paper explores the underlying political processes on what appears to be a mostly technical vision of green hydrogen. Analysis through expert interviews in Aotearoa New Zealand revealed two contrasting energy visions one emphasizing the technical role of green hydrogen in New Zealand's transition—the green hydrogen imaginary and the other which advocated for a future motivated by social change—the alternative energy imaginary. Comparing the tensions through a lens of hydrogen justice exposed the assumptions and exclusions present in the emerging green hydrogen imaginary. This paper argues that the technocratic business as usual approach of green hydrogen depoliticizes the social nature of energy and thus risks perpetuating inequalities and harms present in the current energy system. However these critiques also suggest that there is hope for green hydrogen to be reimagined in more ethical and just ways.
Energy and Environmental Costs in Transitioning to Zero and Low Emission Trucks for the Australian Truck Fleet: An Industry Perspective
May 2024
Publication
Modernising Australia’s old truck fleet and adopting a more stringent standard to reduce emissions and air pollutants is a primary objective for the Australian truck sector. Various strategies worldwide have been introduced to cut emissions and pollutants in the truck sector such as a low-emission strategy supported by strict diesel standards and a zero-emission strategy to shift to battery-electric or hydrogen trucks. The paper focuses on emissions and local air pollutants of trucks under various transition scenarios at both the tailpipe and the wider supply chain including domestic power generation and hydrogen production. In contrast for diesel we focus on tailpipe outputs following fuel standards in Australia given diesel is imported other than in some limited refineries. We compare and recommend actions that government and truck operators may take in the near to longer term in transitioning to cleaner energy. We tested a number of scenarios using a decision support system incorporating all the latest information on costs and emissions for all truck classes using diesel electric or hydrogen. A key finding from our scenario tests is that the current electricity mix has high carbon emissions and air pollutants due to fossil fuel-fired sources for power generation. Without improvement in using renewable energy sources in the future transitioning to electric trucks implies more carbon emissions and air pollutants in the atmosphere from power plants even though electric trucks generate zero tailpipe emissions. The main motivation for switching to zero-emission trucks is energy cost savings. We urge the government to decide on a clear roadmap for the truck sector before the sector is in a position to take action to shift to low or zero-emission trucks without totally relying on the likely reduction of emission intensity in electricity and renewable energy production.
Wind Farm Control for Improved Battery Lifetime in Green Hydrogen Systems without a Grid Connection
Jul 2023
Publication
Green hydrogen is likely to play an important role in meeting the net-zero targets of countries around the globe. One potential option for green hydrogen production is to run electrolysers directly from offshore wind turbines with no grid connection and hence no expensive cabling to shore. In this work an innovative proof of concept of a wind farm control methodology designed to reduce variability in wind farm active power output is presented. Smoothing the power supplied by the wind farm to the battery reduces the size and number of battery charge cycles and helps to increase battery lifetime. This work quantifies the impact of the wind farm control method on battery lifetime for wind farms of 1 4 9 and 16 wind turbines using suitable wind farm battery and electrolyser models. The work presented shows that wind farm control for smoothing wind farm power output could play a critical role in reducing the levelised cost of green hydrogen produced from wind farms with no grid connection by reducing the damaging load cycles on batteries in the system. Hence this work paves the way for the design and testing of a full implementation of the wind farm controller.
Linking Geological and Infrastructural Requirements for Large-scale Underground Hydrogen Storage in Germany
Jun 2023
Publication
Hydrogen storage might be key to the success of the hydrogen economy and hence the energy transition in Germany. One option for cost-effective storage of large quantities of hydrogen is the geological subsurface. However previous experience with underground hydrogen storage is restricted to salt caverns which are limited in size and space. In contrast pore storage facilities in aquifers -and/or depleted hydrocarbon reservoirs- could play a vital role in meeting base load needs due to their wide availability and large storage capacity but experiences are limited to past operations with hydrogen-bearing town gas. To overcome this barrier here we investigate hydrogen storage in porous storage systems in a two-step process: 1) First we investigate positive and cautionary indicators for safe operations of hydrogen storage in pore storage systems. 2) Second we estimate hydrogen storage capacities of pore storage systems in (current and decommissioned) underground natural gas storage systems and saline aquifers. Our systematic review highlights that optimal storage conditions in terms of energy content and hydrogen quality are found in sandstone reservoirs in absence of carbonate and iron bearing accessory minerals at a depth of approx. 1100 m and a temperature of at least 40°C. Porosity and permeability of the reservoir formation should be at least 20% and 5 × 10−13 m2 (~500 mD) respectively. In addition the pH of the brine should fall below 6 and the salinity should exceed 100 mg/L. Based on these estimates the total hydrogen storage capacity in underground natural gas storages is estimated to be up to 8 billion cubic meters or (0.72 Mt at STP) corresponding to 29 TWh of energy equivalent of hydrogen. Saline aquifers may offer additional storage capacities of 81.6–691.8 Mt of hydrogen which amounts to 3.2 to 27.3 PWh of energy equivalent of hydrogen the majority of which is located in the North German basin. Pore storage systems could therefore become a crucial element of the future German hydrogen infrastructure especially in regions with large industrial hydrogen (storage) demand and likely hydrogen imports via pipelines and ships.
OIES Podcast - Hydrogen Storage for a Net-zero Carbon Future
May 2023
Publication
In this podcast David Ledesma engages in a conversation with Alex Patonia and Rahmat Poudineh on their recent paper focusing on hydrogen storage for a net-zero carbon future. The podcast delves into the various types of hydrogen storage options highlighting their relative strengths and drawbacks.
In order for a hydrogen economy to be established several key factors must be addressed including efficient and decarbonized production adequate transportation infrastructure and the deployment of suitable hydrogen storage facilities. However hydrogen presents unique challenges when it comes to storage and handling. Due to its extremely low volumetric energy density under ambient conditions hydrogen cannot be efficiently or economically stored without undergoing compression liquefaction or conversion into other more manageable substances.
At present there exist several hydrogen storage solutions at different levels of technology market and commercial readiness each with varying applications depending on specific circumstances.
Additionally the podcast explores the primary barriers that hinder investment in hydrogen storage and the essential components of a viable business model that can address the primary risks to which potential hydrogen storage investors are exposed.
The podcast can be found on their website.
In order for a hydrogen economy to be established several key factors must be addressed including efficient and decarbonized production adequate transportation infrastructure and the deployment of suitable hydrogen storage facilities. However hydrogen presents unique challenges when it comes to storage and handling. Due to its extremely low volumetric energy density under ambient conditions hydrogen cannot be efficiently or economically stored without undergoing compression liquefaction or conversion into other more manageable substances.
At present there exist several hydrogen storage solutions at different levels of technology market and commercial readiness each with varying applications depending on specific circumstances.
Additionally the podcast explores the primary barriers that hinder investment in hydrogen storage and the essential components of a viable business model that can address the primary risks to which potential hydrogen storage investors are exposed.
The podcast can be found on their website.
The Potential Role of a Hydrogen Network in Europe
Jul 2023
Publication
Europe’s electricity transmission expansion suffers many delays despite its significance for integrating renewable electricity. A hydrogen network reusing the existing gas network could not only help to supply the demand for low-emission fuels but could also balance variations in wind and solar energies across the continent and thus avoid power grid expansion. Our investigation varies the allowed expansion of electricity and hydrogen grids in net-zero CO2 scenarios for a sector-coupled European energy system capturing transmission bottlenecks renewable supply and demand variability and pipeline retrofitting and geological storage potentials. We find that a hydrogen network connecting regions with low-cost and abundant renewable potentials to demand centers electrofuel production and cavern storage sites reduces system costs by up to 26 bnV/a (3.4%). Although expanding both networks together can achieve the largest cost reductions by 9.9% the expansion of neither is essential for a net-zero system as long as higher costs can be accepted and flexibility options allow managing transmission bottlenecks.
Renewable Hydrogen: Modular Concepts from Production over Storage to the Consumer
Jan 2021
Publication
A simulation tool called HYDRA to optimize individual hydrogen infrastructure layouts is presented. The different electrolyzer technologies namely proton exchange membrane electrolysis anion exchange membrane electrolysis alkaline electrolysis and solid oxide electrolysis as well as hydrogen storage possibilities are described in more detail and evaluated. To illustrate the application opportunities of HYDRA three project examples are discussed. The examples include central and decentral applications while taking the usage of hydrogen into account.
Simulation and Control Strategy Study of the Hydrogen Supply System of a Fuel Cell Engine
Jun 2023
Publication
The hydrogen supply system is one of the important components of a hydrogen fuel cell engine and its performance has an important impact on the economy and power of the engine system. In this paper a hydrogen supply system based on cyclic mode is designed for a hydrogen fuel cell stack with a full load power of 150 kW and the corresponding hydrogen fuel cell engine simulation model is built and validated. The control strategy of the fuel cell hydrogen supply system is developed and its effect is verified through bench tests. The results show that the developed control strategy can keep the volume fraction of nitrogen below 6% the hydrogen excess ratio does not exceed 1.5 under medium and high operating conditions the anode pressure is relatively stable and the stack can operate efficiently and reliably.
Comparative Exergy and Environmental Assessment of the Residual Biomass Gasification Routes for Hydrogen and Ammonia Production
Jul 2023
Publication
The need to reduce the dependency of chemicals on fossil fuels has recently motivated the adoption of renewable energies in those sectors. In addition due to a growing population the treatment and disposition of residual biomass from agricultural processes such as sugar cane and orange bagasse or even from human waste such as sewage sludge will be a challenge for the next generation. These residual biomasses can be an attractive alternative for the production of environmentally friendly fuels and make the economy more circular and efficient. However these raw materials have been hitherto widely used as fuel for boilers or disposed of in sanitary landfills losing their capacity to generate other by-products in addition to contributing to the emissions of gases that promote global warming. For this reason this work analyzes and optimizes the biomass-based routes of biochemical production (namely hydrogen and ammonia) using the gasification of residual biomasses. Moreover the capture of biogenic CO2 aims to reduce the environmental burden leading to negative emissions in the overall energy system. In this context the chemical plants were designed modeled and simulated using Aspen plus™ software. The energy integration and optimization were performed using the OSMOSE Lua Platform. The exergy destruction exergy efficiency and general balance of the CO2 emissions were evaluated. As a result the irreversibility generated by the gasification unit has a relevant influence on the exergy efficiency of the entire plant. On the other hand an overall negative emission balance of −5.95 kgCO2/kgH2 in the hydrogen production route and −1.615 kgCO2/kgNH3 in the ammonia production route can be achieved thus removing from the atmosphere 0.901 tCO2/tbiomass and 1.096 tCO2/tbiomass respectively.
Techno-Economic Assessment of a Full-Chain Hydrogen Production by Offshore Wind Power
May 2024
Publication
Offshore wind power stands out as a promising renewable energy source offering substantial potential for achieving low carbon emissions and enhancing energy security. Despite its potential the expansion of offshore wind power faces considerable constraints in offshore power transmission. Hydrogen production derived from offshore wind power emerges as an efficient solution to overcome these limitations and effectively transport energy. This study systematically devises diverse hydrogen energy supply chains tailored to the demands of the transportation and chemical industries meticulously assessing the levelized cost of hydrogen (LCOH). Our findings reveal that the most cost-efficient means of transporting hydrogen to the mainland is through pipelines particularly when the baseline distance is 50 km and the baseline electricity price is 0.05 USD/kWh. Notably delivering hydrogen directly to the port via pipelines for chemical industries proves considerably more economical than distributing it to hydrogen refueling stations with a minimal cost of 3.6 USD/kg. Additionally we assessed the levelized cost of hydrogen (LCOH) for supply chains that transmit electricity to ports via submarine cables before hydrogen production and subsequent distribution to chemical plants. In comparison to offshore hydrogen production routes these routes exhibit higher costs and reduced competitiveness. Finally a sensitivity analysis was undertaken to scrutinize the impact of delivery distance and electricity prices on LCOH. The outcomes underscore the acute sensitivity of LCOH to power prices highlighting the potential for substantial reductions in hydrogen prices through concerted efforts to lower electricity costs.
A Comprehensive Resilience Assessment Framework for Hydrogen Energy Infrastructure Development
Jun 2023
Publication
In recent years sustainable development has become a challenge for many societies due to natural or other disruptive events which have disrupted economic environmental and energy infrastructure growth. Developing hydrogen energy infrastructure is crucial for sustainable development because of its numerous benefits over conventional energy sources. However the complexity of hydrogen energy infrastructure including production utilization and storage stages requires accounting for potential vulnerabilities. Therefore resilience needs to be considered along with sustainable development. This paper proposes a decision-making framework to evaluate the resilience of hydrogen energy infrastructure by integrating resilience indicators and sustainability contributing factors. A holistic taxonomy of resilience performance is first developed followed by a qualitative resilience assessment framework using a novel Intuitionistic fuzzy Weighted Influence Nonlinear Gauge System (IFWINGS). The results highlighted that Regulation and legislation Government preparation and Crisis response budget are the most critical resilience indicators in the understudy hydrogen energy infrastructure. A comparative case study demonstrates the practicality capability and effectiveness of the proposed approach. The results suggest that the proposed model can be used for resilience assessment in other areas.
Options for Methane Fuel Processing in PEMFC System with Potential Maritime Applications
Nov 2022
Publication
Proton-exchange membrane fuel cells (PEMFCs) are low-temperature fuel cells that have excellent starting performance due to their low operating temperature can respond quickly to frequent load fluctuations and can be manufactured in small packages. Unlike existing studies that mainly used hydrogen as fuel for PEMFCs in this study methane is used as fuel for PEMFCs to investigate its performance and economy. Methane is a major component of natural gas which is more economically competitive than hydrogen. In this study methane gas is reformed by the steam reforming method and is applied to the following five gas post-treatment systems: (a) Case 1—water– gas shift only (WGS) (b) Case 2—partial oxidation reforming only (PROX) (c) Case 3—methanation only (d) Case 4—WGS + methanation (e) Case 5—WGS + PROX. In the evaluation the carbon monoxide concentration in the gas did not exceed 10 ppm and the methane component which has a very large greenhouse effect was not regenerated in the post-treated exhaust gas. As a result Case 5 (WGS and PROX) is the only case that satisfied both criteria. Therefore we propose Case 5 as an optimized post-treatment system for methane reforming gas in ship PEMFCs.
Thermodynamic and Emission Analysis of a Hydrogen/Methane Fueled Gas Turbine
May 2023
Publication
The importance of hydrogen in the effort to decarbonize the power sector has grown immensely in recent years. Previous studies have investigated the effects of mixing hydrogen into natural gas for gas turbine combustors but limited studies have examined the resulting effects hydrogen addition has on the entire system. In this work a thermodynamic model of a gas turbine with combustion chemical kinetics integrated is created and the effects hydrogen addition (0-100 volume percent addition) has on the system performance emissions and combustion kinetics are analyzed. The maximum system performance is achieved when the maximum turbine inlet temperature is reached and the resulting optimal fuel/air equivalence ratio is determined. As hydrogen is added to the fuel mixture the optimal equivalence ratio shifts leaner causing non-linearity in emissions and system performance at optimal conditions. An analysis of variance is conducted and it is shown that isentropic efficiencies of the turbine and compressor influences the system performance the most out of any system parameter. While isentropic efficiencies of the turbine and compressor increase towards 100% an operating regime where the optimal system efficiency cannot be achieved is discovered due to the lower flammability limit of the fuel being reached. This can be overcome by mixing hydrogen into the fuel.
Technology Portfolio Assessment for Near-zero Emission Iron and Steel Industry in China
May 2023
Publication
China aims to peak CO2 emissions before 2030 and to achieve carbon neutrality before 2060; hence industrial sectors in China are keen to figure out appropriate pathways to support the national target of carbon neutrality. The objective of this study is to explore near-zero emission pathways for the steel industry of China through a detailed technology assessment. The innovative technology development has been simulated using the AIM-China/steel model developed by including material-based technologies and optimal cost analysis. Six scenarios have been given in terms of different levels of production output emission reduction and carbon tax. Near-zero emission and carbon tax scenarios have shown that China’s steel industry can achieve near-zero emission using electric furnaces and hydrogen-based direct reduction iron technologies with policy support. Based on these technologies minimised production costs have been calculated revealing that the steel produced by these technologies is cost-effective. Moreover the feedstock cost can play a key role in these technology portfolios especially the cost of scrap iron ore and hydrogen. In addition the feedstock supply can have strong regional effects and can subsequently impact the allocation of steelmaking in the future. Therefore China can achieve near-zero emissions in the steel industry and electric furnace and hydrogen-based direct reduction iron technologies are crucial to achieving them.
Techno-economic Assessment on Hybrid Energy Storage Systems Comprising Hydrogen and Batteries: A Case Study in Belgium
Jun 2023
Publication
This paper introduces a Techno-Economic Assessment (TEA) on present and future scenarios of different energy storage technologies comprising hydrogen and batteries: Battery Energy Storage System (BESS) Hydrogen Energy Storage System (H2ESS) and Hybrid Energy Storage System (HESS). These three configurations were assessed for different time horizons: 2019 2022 and 2030 under both on-grid and off-grid conditions. For 2030 a sensitivity analysis under different energy scenarios was performed covering other trends in on-grid electric consumption and prices CO2 taxation and the evolution of hydrogen technology prices from 2019 until 2030. The selected case study is the Research Park Zellik (RPZ) a CO2- neutral sustainable Local Energy Community (LEC) in Zellik Belgium. The software HOMER (Hybrid Optimisation Model for Electric Renewable) has been selected to design model and optimise the defined case study. The results showed that BESS was the most competitive when the electric grid was available among the three possible storage options. Additionally HESS was overall more competitive than H2ESS-only regardless of the grid connection mode. Finally as per HESS hydrogen was proved to play a complementary role when combined with batteries enhancing the flexibility of the microgrid and enabling deeper decarbonisation by reducing the electricity bought from the grid increasing renewable energy production and balancing toward an island operating mode.
Key Considerations for Evaluating Underground Hydrogen Storage (UHS) Potential in Five Contrasting Australian Basins
Apr 2024
Publication
Hydrogen gas can provide baseload energy as society decarbonizes through the energy transition. Underground Hydrogen Storage (UHS) will be secure convenient and scalable to accommodate excess hydrogen production or compensate temporary shortfalls in energy supply. Hydrogen is a gas under all viable subsurface conditions so is invasive mobile and low-density. Methane and CO2 are also stored underground but storage parameters differ for each affecting the balance of geological storage risks. UHS in Australia is most likely to utilise conventional sedimentary reservoir rocks bound by conventional trapping closures. Hydrogen energy density will affect the competitiveness of UHS against purpose-built surface storage or solution-mined salt cavities. This study presents an overview of key considerations when screening for UHS opportunities and evaluates them for five Australian sedimentary basins. A threshold storage depth mapped across them reveals that the most prospective UHS basins will have to function as integrated energy fluid resource systems.
Evaluation of Surplus Hydroelectricity Potential in Nepal until 2040 and its Use for Hydrogen Production Via Electrolysis
May 2023
Publication
The abundant hydro resources in Nepal have resulted in the generation of electricity almost exclusively from hydropower plants. Several hydropower plants are also currently under construction. There is no doubt that the surplus electricity will be significantly high in the coming years. Given the previous trend in electricity consumption it will be a challenge to maximize the use of surplus electricity. In this work the potential solutions to maximize the use of this surplus electricity have been analysed. Three approached are proposed: (i) increasing domestic electricity consumption by shifting the other energy use sectors to electricity (ii) cross-border export of electricity and (iii) conversion of electricity to hydrogen via electrolysis. The current state of energy demand and supply patterns in the country are presented. Future monthly demand forecasts and surplus electricity projections have been made. The hydrogen that can be produced with the surplus electricity via electrolysis is determined and an economic assessment is carried out for the produced hydrogen. The analysis of levelized cost of hydrogen (LCOH) under different scenarios resulted values ranging from 3.8 €/kg to 4.5 €/kg.
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