Poland
Multi-Criteria Comparative Analysis of Clean Hydrogen Production Scenarios
Aug 2020
Publication
Different hydrogen production scenarios need to be compared in regard to multiple and often distinct aspects. It is well known that hydrogen production technologies based on environmentally-friendly renewable energy sources have higher values of the economic indicators than methods based on fossil fuels. Therefore how should this decision criterion (environmental) prevail over the other types of decision criteria (technical and economic) to make a scenario where hydrogen production only uses renewable energy sources the most attractive option for a decision-maker? This article presents the results of a multi-variant comparative analysis of scenarios to annually produce one million tons of pure hydrogen (99.999%) via electrolysis in Poland. The compared variants were found to differ in terms of electricity sources feeding the electrolyzers. The research demonstrated that the scenario where hydrogen production uses energy from photovoltaics only becomes the best option for the environmental criterion weighting value at 61%. Taking the aging effect of photovoltaic installation (PV) panels and electrolyzers after 10 years of operation into account the limit value of the environmental criterion rises to 63%. The carried out analyses may serve as the basis for the creation of systems supporting the development of clean and green hydrogen production technologies.
Prediction of Gaseous Products from Refuse Derived Fuel Pyrolysis Using Chemical Modelling Software - Ansys Chemkin-Pro
Nov 2019
Publication
There can be observed global interest in waste pyrolysis technology due to low costs and availability of raw materials. At the same time there is a literature gap in forecasting environmental effects of thermal waste treatment installations. In the article was modelled the chemical composition of pyrolysis gas with main focus on the problem in terms of environmental hazards. Not only RDF fuel was analysed but also selected waste fractions included in its composition. This approach provided comprehensive knowledge about the chemical composition of gaseous pyrolysis products which is important from the point of view of the heterogeneity of RDF fuel. The main goal of this article was to focus on the utilitarian aspect of the obtained calculation results. Final results can be the basis for estimating ecological effects both for existing and newly designed installations.
Pyrolysis process was modelled using Ansys Chemkin-Pro software. The investigation of the process were carried out for five different temperatures (700 750 800 850 and 900 °C). As an output the mole fraction of H2 H2O CH4 C2H2C2H4 C3H6 C3H8 CO CO2 HCl and H2S were presented. Additionally the reaction pathways for selected material were presented.
Based on obtained results it was established that the residence time did not influenced on the concentration of products contrary to temperature. The chemical composition of pyrolytic gas is closely related to wastes origin. The application of Chemkin-Pro allowed the calculation of formation for each products at different temperatures and formulation of hypotheses on the reaction pathways involved during pyrolysis process. Further based on the obtained results confirmed the possibilities of using pyrolysis gas from RDF as a substitute for natural gas in energy consumption sectors. Optimization of the process can be conducted with low financial outlays and reliable results by using calculation tools. Moreover it can be predicted negative impact of obtained products on the future installation.
Pyrolysis process was modelled using Ansys Chemkin-Pro software. The investigation of the process were carried out for five different temperatures (700 750 800 850 and 900 °C). As an output the mole fraction of H2 H2O CH4 C2H2C2H4 C3H6 C3H8 CO CO2 HCl and H2S were presented. Additionally the reaction pathways for selected material were presented.
Based on obtained results it was established that the residence time did not influenced on the concentration of products contrary to temperature. The chemical composition of pyrolytic gas is closely related to wastes origin. The application of Chemkin-Pro allowed the calculation of formation for each products at different temperatures and formulation of hypotheses on the reaction pathways involved during pyrolysis process. Further based on the obtained results confirmed the possibilities of using pyrolysis gas from RDF as a substitute for natural gas in energy consumption sectors. Optimization of the process can be conducted with low financial outlays and reliable results by using calculation tools. Moreover it can be predicted negative impact of obtained products on the future installation.
Microalgal Hydrogen Production in Relation to Other Biomass‐Based Technologies—A Review
Sep 2021
Publication
Hydrogen is an environmentally friendly biofuel which if widely used could reduce atmospheric carbon dioxide emissions. The main barrier to the widespread use of hydrogen for power generation is the lack of technologically feasible and—more importantly—cost‐effective methods of production and storage. So far hydrogen has been produced using thermochemical methods (such as gasification pyrolysis or water electrolysis) and biological methods (most of which involve anaerobic digestion and photofermentation) with conventional fuels waste or dedicated crop biomass used as a feedstock. Microalgae possess very high photosynthetic efficiency can rapidly build biomass and possess other beneficial properties which is why they are considered to be one of the strongest contenders among biohydrogen production technologies. This review gives an account of present knowledge on microalgal hydrogen production and compares it with the other available biofuel production technologies.
Total Cost of Ownership and Its Potential Consequences for the Development of the Hydrogen Fuel Cell Powered Vehicle Market in Poland
Apr 2021
Publication
Electromobility is a growing technology for land transport constituting an important element of the concept of sustainable economic development. The article presents selected research results concerning one of the segments of this market-vehicles powered by hydrogen fuel cells. The subject of the research was to gain extensive knowledge on the economic factors influencing the future purchasing decisions of the demand side in relation to this category of vehicles. The research was based on a numerical experiment. For this purpose a comparative analysis of purchase prices in relation to the TCO of the vehicle after 3–5 years of use was performed. The research included selected models that are powered by both conventional and alternative fuels. The use of this method will allow to assess the real costs associated with the hydrogen vehicle. The authors emphasize the important role of economic factors in the form of the TCO index for the development of this market. The experimental approach may be helpful in understanding the essence of economic relations that affect the development of the electro-mobility market and the market demand for hydrogen fuel cell-powered vehicles in Poland.
Response Time Measurement of Hydrogen Sensors
Sep 2017
Publication
The efficiency of gas sensor application for facilitating the safe use of hydrogen depends considerably on the sensor response to a change in hydrogen concentration. Therefore the response time has been measured for five different-type commercially available hydrogen sensors. Experiments showed that all these sensors surpass the ISO 26142 standard; for the response times t90 values of 2 s to 16 s were estimated. Results can be fitted with an exponential or sigmoidal function. It can be demonstrated that the results on transient behaviour depend on both the operating parameters of sensors and investigation methods as well as on the experimental conditions: gas change rate and concentration jump.
Remarkable Visible-light Induced Hydrogen Generation with ZnIn2S4 Microspheres/CuInS2 Quantum Dots Photocatalytic System
Oct 2020
Publication
A new and active material in the form of ZnIn2S4 microspheres decorated by CuInS2 quantum dots have been obtained by hydrothermal method for the first time. The optimum amount of CuInS2 quantum dots (1.13 wt.%) introduced into rection medium during ZnIn2S4 microspheres synthesis increased the photocatalytic H2 generation rate by 2.5 times than that of bare ZnIn2S4 photocatalysis under visible light irradiation. This sample exhibited strong photoactivity in the extended visible range up to 540 nm with 30.6% apparent quantum efficiency (λ = 420 nm).
Thermodynamic Assessment of the Novel Concept of the Energy Storage System Using Compressed Carbon Dioxide, Methanation and Hydrogen Generator
Jul 2021
Publication
The main aim of this paper is to characterize the concept of a novel energy storage system based on compressed CO2 storage installation that uses an infrastructure of depleted coal mines to provide required volume of tanks and additionally hydrogen generators and a methanation installation to generate synthetic natural gas that can be used within the system or taken out of it e.g. to a gas grid. A detailed mathematical model of the proposed solution was built using own codes and Aspen Plus software. Thermodynamic evaluation aiming at determining parameters composition and streams in all the most important nodes of the system for the nominal point and when changing a defined decision variable δ (in the range from 0.1 to 0.9) was made. The evaluation was made based on the storage efficiency volume of the tanks and flows of energy within the system. The storage efficiency in the nominal point reached 45.08% but was changing in the range from 35.06% (for δ = 0.1) to 63.93% (for δ = 0.9). For the nominal value of δ equal to 0.5 volume of the low-pressure tank (LPT) was equal to 132869 m3 while of the high pressure tank (HPT) to 1219 m3 . When changing δ these volumes were changing from 101900 m3 to 190878 m3 (for LPT) and from 935 to 1751 m3 (for HPT) respectively. Detailed results are presented in the paper and indicate high storage potential of the proposed solution in regions with underground mine infrastructure.
Two Generations of Hydrogen Powertrain—An Analysis of the Operational Indicators in Real Driving Conditions (RDC)
Jun 2022
Publication
Hydrogen fuel cells are systems that can be successfully used to partially replace internal combustion propulsion systems. For this reason the article presents an operational analysis of energy flow along with an analysis of individual energy transmission systems. Two generations of the Toyota Mirai vehicle were used for the tests. The operational analyses were carried out on the same route (compliant with RDE test requirements) assessing the system’s operation in three driving sections (urban rural and motorway). Both generations of the drive system with fuel cells are quite different which affects the obtained individual systems operation results as well as the overall energy flow. Research was carried out on the energy flow in the fuel cells FC converter battery and electric motor using a dedicated data acquisition system. The analyses were carried out in relation to the energy of fuel cells battery energy and recovered braking energy. It was found that in the urban drive section of the second-generation system (due to its much larger mass) a slightly higher energy consumption value was obtained (by about 2%). However in the remaining phases of the test consumption was lower (the maximum difference was 18% in the rural phase). Total energy consumption in the research test was 19.64 kWh/100 km for the first-generation system compared to 18.53 kWh/100 km for the second-generation system. Taking into account the increased mass of the second-generation vehicle resulted in significantly greater benefits in the second-generation drive (up to 37% in individual drive sections and about 28% in the entire drive test).
The Perspectives for the Use of Hydrogen for Electricity Storage Considering the Foreign Experience
Mar 2017
Publication
Over the last years the European Union has seen a rapid increase in installed capacity of generating units based on renewable energy sources (RES). The most significant increase in installed capacity was recorded in 2015 in wind farms and solar PV installations. One of the most serious is the volatile character of RES on a time basis. Therefore for a further expected increase in the use of RES and their effectiveness improvements investments are needed allowing for electricity to be stored. One of the electricity storage options is to use excess electricity in order to produce hydrogen by electrolysis of water. Although this process plays a marginal role in obtaining hydrogen on a worldwide basis due to high costs experience in recent years has shown that periodically low (negative) electricity prices developing on the power exchanges in the situation where there is surplus electricity available affect economic requirements for hydrogen production technologies. The paper shows activities undertaken by European countries (mainly Germany) aiming at making it possible for hydrogen to be stored in the natural gas grids. A particular attention is given to material resource issues and possible operational problems that might arise while blending natural gas with hydrogen into the grid. The experiences of selected European countries are of particular interest from the Polish perspective having regard to significant increase of RES in electricity generation during the last few years and adopted objectives for the growing importance of RES in the Poland’s energy balance.
Mobile Nuclear-Hydrogen Synergy in NATO Operations
Nov 2021
Publication
An uninterrupted chain of energy supplies is the core of every activity without exception for the operations of the North Atlantic Treaty Organization. A robust and efficient energy supply is fundamental for the success of missions and a guarantee of soldier safety. However organizing a battlefield energy supply chain is particularly challenging because the risks and threats are particularly high. Moreover the energy supply chain is expected to be flexible according to mission needs and able to be moved quickly if necessary. In line with ongoing technological changes the growing popularity of hydrogen is undeniable and has been noticed by NATO as well. Hydrogen is characterised by a much higher energy density per unit mass than other fuels which means that hydrogen fuel can increase the range of military vehicles. Consequently hydrogen could eliminate the need for risky refuelling stops during missions as well as the number of fatalities associated with fuel delivery in combat areas. Our research shows that a promising prospect lies in the mobile technologies based on hydrogen in combination with use of the nuclear microreactors. Nuclear microreactors are small enough to be easily transported to their destinations on heavy trucks. Depending on the design nuclear microreactors can produce 1–20 MW of thermal energy that could be used directly as heat or converted to electric power or for non-electric applications such as hydrogen fuel production. The aim of the article is to identify a model of nuclear-hydrogen synergy for use in NATO operations. We identify opportunities and threats related to mobile energy generation with nuclear-hydrogen synergy in NATO operations. The research presented in this paper identifies the best method of producing hydrogen using a nuclear microreactor. A popular and environmentally “clean” solution is electrolysis due to the simplicity of the process. However this is less efficient than chemical processes based on for example the sulphur-iodine cycle. The results of the research presented in this paper show which of the methods and which cycle is the most attractive for the production of hydrogen with the use of mini-reactors. The verification criteria include: the efficiency of the process its complexity and the residues generated as a result of the process (waste)—all taking into account usage for military purposes.
Domestic Gas Meter Durability in Hydrogen and Natural Gas Mixtures
Nov 2021
Publication
Blending hydrogen into the natural gas infrastructure is becoming a very promising practice to increase the exploitation of renewable energy sources which can be used to produce “green” hydrogen. Several research projects and field experiments are currently aimed at evaluating the risks associated with utilization of the gas blend in end-use devices such as the gas meters. In this paper the authors present the results of experiments aimed at assessing the effect of hydrogen injection in terms of the durability of domestic gas meters. To this end 105 gas meters of different measurement capabilities and manufacturers both brand-new and withdrawn from service were investigated in terms of accuracy drift after durability cycles of 5000 and 10000 h with H2NG mixtures and H2 concentrations of 10% and 15%. The obtained results show that there is no metrologically significant or statistically significant influence of hydrogen content on changes in gas meter indication errors after subjecting the meters to durability testing with a maximum of 15% H2 content over 10000 h. A metrologically significant influence of the long-term operation of the gas meters was confirmed but it should not be made dependent on the hydrogen content in the gas. No safety problems related to the loss of external tightness were observed for either the new or 10-year-old gas meters.
Hydrogen Storage in Geological Formations—The Potential of Salt Caverns
Jul 2022
Publication
Hydrogen-based technologies are among the most promising solutions to fulfill the zero-emission scenario and ensure the energy independence of many countries. Hydrogen is considered a green energy carrier which can be utilized in the energy transport and chemical sectors. However efficient and safe large-scale hydrogen storage is still challenging. The most frequently used hydrogen storage solutions in industry i.e. compression and liquefaction are highly energy-consuming. Underground hydrogen storage is considered the most economical and safe option for large-scale utilization at various time scales. Among underground geological formations salt caverns are the most promising for hydrogen storage due to their suitable physicochemical and mechanical properties that ensure safe and efficient storage even at high pressures. In this paper recent advances in underground storage with a particular emphasis on salt cavern utilization in Europe are presented. The initial experience in hydrogen storage in underground reservoirs was discussed and the potential for worldwide commercialization of this technology was analyzed. In Poland salt deposits from the north-west and central regions (e.g. Rogóźno Damasławek Łeba) are considered possible formations for hydrogen storage. The Gubin area is also promising where 25 salt caverns with a total capacity of 1600 million Nm3 can be constructed.
The Potential of Fuel Cells as a Drive Source of Maritime Transport
Nov 2017
Publication
The state of environmental pollution brought about as a result of the modern civilization has been monitored in the interests of the environment and human health since the seventies of the last century. Ensuring the energy security is one of the most basic existential requirements for a functional civilized society. The growing civilizational needs caused by broadly understood development generate demand for the production of all kinds of goods in all sectors of the economy as well as world-wide information transfer. The current energy demand is mostly covered using fossil fuels such as coal oil and natural gas. Some of the energy demand is covered by the energy generated in nuclear reactions and a small part of it comes from renewable energy sources. Energy derived from fossil fuels is inevitably associated with fuel oxidation processes. These processes in addition to generating heat are responsible for the emission of harmful compounds to the atmosphere: carbon monoxide carbon dioxide nitrogen oxides hydrocarbons and particulate matter. These pollutants pose a serious threat to the people as well as the environment in which they live. Due to the large share of fossil fuel energy generation in the process of combustion it becomes necessary to seek other means of obtaining the so-called "clean energy". Fuel cells may have a very high potential in this respect. Their development has enabled attempts to use them in all modes of transport. An important factor in the development of fuel cells is their relatively high efficiency and the coinciding strictening of the emission norms from internal combustion engines used to power maritime transport. Therefore the aim of this article has been to assess the potential of fuel cells as a main source of propulsion power source. A review of the designs of fuel cell systems and their use was performed. The article summarizes the assessment of the potential role of fuel cells as a power source of maritime transport.
The Role of Hydrogen in the Visegrad Group Approach to Energy Transition
Oct 2022
Publication
Hydrogen is an energy carrier in which hopes are placed for an easier achievement of climate neutrality. Together with electrification energy efficiency development and RES hydrogen is expected to enable the ambitious energy goals of the European Green Deal. Hence the aim of the article is to query the development of the hydrogen economy in the Visegrad Group countries (V4). The study considers six diagnostic features: sources of hydrogen production hydrogen legislation financial mechanisms objectives included in the hydrogen strategy environmental impact of H2 and costs of green hydrogen investments. The analysis also allowed to indicate the role that hydrogen will play in the energy transition process of the V4 countries. The analysis shows that the V4 countries have similar approaches to the development of the hydrogen market but the hydrogen strategies published by each of the Visegrad countries are not the same. Each document sets goals based on the hydrogen production to date and the specifics of the domestic energy and transport sectors as there are no solutions that are equally effective for all. Poland’s hydrogen strategy definitely stands out the strongest.
Assessment of the Economic Efficiency of the Operation of Low-Emission and Zero-Emission Vehicles in Public Transport in the Countries of the Visegrad Group
Nov 2021
Publication
Transport is one of the key sectors of the European economy. However the intensive development of transport caused negative effects in the form of an increase in the emission of harmful substances. The particularly dramatic situation took place in the V4 countries. This made it necessary to implement solutions reducing emissions in transport including passenger transport. Such activities can be implemented in the field of implementation of low-emission and zero-emission vehicles for use. That is why the European Union and the governments of the Visegrad Group countries have developed numerous recommendations communications laws and strategies that order carriers to implement low- and zero-emission mobility. Therefore transport organizers and communication operators faced the choice of the type of buses. From an economic point of view each entrepreneur is guided by the economic efficiency of the vehicles used. Hence the main aim of the article was to conduct an economic evaluation of the operational efficiency of ecological vehicles. As more than 70% of vehicles in use in the European Union are still diesel driven the economic efficiency assessment was also made for vehicles with traditional diesel drive. To conduct the research the method of calculating the total cost of ownership of vehicles in operation was used. As a result of the research it was found that electric buses are the cheapest in the entire period of use (15 years) and then those powered by CNG. On the other hand the cost of using hydrogen buses is the highest. This is due to the high purchase prices of these vehicles. However the EU as well as the governments of individual countries support enterprises and communication operators by offering them financing for investments. The impact of the forecasted fuel and energy prices and the planned inflation on operating costs was also examined. In this case the analyses showed that the forecasted changes in fuel and energy prices as well as the expected inflation will significantly affect the costs of vehicle operation and the economic efficiency of using various types of drives. These changes will have a positive impact on the implementation of zero-emission vehicles into exploitation. Based on the analyses it was found that in 2035 hydrogen buses will have the lowest operating costs.
How Long Will Combustion Vehicles Be Used? Polish Transport Sector on the Pathway to Climate Neutrality
Nov 2021
Publication
Transformation of road transport sector through replacing of internal combustion vehicles with zero-emission technologies is among key challenges to achievement of climate neutrality by 2050. In a constantly developing economy the demand for transport services increases to ensure continuity in the supply chain and passenger mobility. Deployment of electric technologies in the road transport sector involves both businesses and households its pace depends on the technological development of zero-emission vehicles presence of necessary infrastructure and regulations on emission standards for new vehicles entering the market. Thus this study attempts to estimate how long combustion vehicles will be in use and what the state of the fleet will be in 2050. For obtainment of results the TR3E partial equilibrium model was used. The study simulates the future fleet structure in passenger and freight transport. The results obtained for Poland for the climate neutrality (NEU) scenario show that in 2050 the share of vehicles using fossil fuels will be ca. 30% in both road passenger and freight transport. The consequence of shifts in the structure of the fleet is the reduction of CO2 emissions ca. 80% by 2050 and increase of the transport demand for electricity and hydrogen.
Fuel Cell Electric Vehicle (FCEV) Energy Flow Analysis in Real Driving Conditions (RDC)
Aug 2021
Publication
The search for fossil fuels substitutes forces the use of new propulsion technologies applied to means of transportation. Already widespread hybrid vehicles are beginning to share the market with hydrogen-powered propulsion systems. These systems are fuel cells or internal combustion engines powered by hydrogen fuel. In this context road tests of a hydrogen fuel cell drive were conducted under typical traffic conditions according to the requirements of the RDE test. As a result of the carried-out work energy flow conditions were presented for three driving phases (urban rural and motorway). The different contributions to the vehicle propulsion of the hydrogen system and the electric system in each phase of the driving route are indicated. The characteristic interaction of power train components during varying driving conditions was presented. A wide variation in the contribution of the fuel cell and the battery to the vehicle’s propulsion was identified. In urban conditions the share of the fuel cell in the vehicle’s propulsion is more than three times that contributed by the battery suburban—7 times highway—28 times. In the entire test the ratio of FC/BATT use was more than seven while the energy consumption was more than 22 kWh/100 km. The amounts of battery energy used and recovered were found to be very close to each other under RDE test conditions.
Investigation on Green Hydrogen Generation Devices Dedicated for Integrated Renewable Energy Farm: Solar and Wind
Oct 2022
Publication
This study presents a comprehensive methodology to evaluate plants that integrate renewable energy sources and hydrogen generation devices. The paper focuses on presenting the methods for devices’ operation assessment taking into account the annual operation. Multiple effectiveness indices have been presented. On the basis of experimental investigation with the hydrogen generator the methods for assessing its operation during start-up phase and sudden change in the supply current were proposed. The results of the experiments and the provided mathematical models show that dynamics of the hydrogen generator should be taken into account when selecting the suitable device for cooperation with variable renewable energy. It is especially important for multiple start-ups throughout the day due to significant differences in the amount of hydrogen produced by devices characterized by the same efficiency yet various time constants. Methodology for selecting the optimal nominal power for hydrogen generator to cooperate with given renewable sources was developed. It was proven the optimal power depends on the type of the renewable source and minimal load of the hydrogen generator. Several case studies including the integration of wind and solar energy farms to yield a 10 MW renewable energy farm were considered and the minimal load of the hydrogen generator impacts the annual operation of the device has been presented. The paper provides a set of tools to contribute to the development of sustainable energy plants. The methods proposed in this paper are universal and can be used for various renewable energy sources.
Renewable Hydrogen Implementations for Combined Energy Storage, Transportation and Stationary Applications
Dec 2019
Publication
The purpose of this paper is to discuss the potential of hydrogen obtained from renewable sources for energy generation and storage systems. The first part of analysis will address such issues as various methods of green hydrogen production storage and transportation. The review of hydrogen generation methods will be followed by the critical analysis and the selection of production method. This selection is justified by the results of the comparative research on alternative green hydrogen generation technologies with focus on their environmental impacts and costs. The comparative analysis includes the biomass-based methods as well as water splitting and photo-catalysis methods while water electrolysis is taken as a benchmark. Hydrogen storage and transportation issues will be further discussed in purpose to form the list of recommended solutions. In the second part of the paper the technology readiness and technical feasibility for joint hydrogen applications will be analysed. This will include the energy storage and production systems based on renewable hydrogen in combination with hydrogen usage in mobility systems as well as the stationary applications in buildings such as combined heat and power (CHP) plants or fuel cell electric generators. Based on the analysis of the selected case studies the author will discuss the role of hydrogen for the carbon emission reduction with the stress on the real value of carbon footprint of hydrogen depending on the gas source storage transportation and applications.
Towards Computer-Aided Graphene Covered TiO2-Cu(CuxOy) Composite Design for the Purpose of Photoinduced Hydrogen Evolution
May 2021
Publication
In search a hydrogen source we synthesized TiO2-Cu-graphene composite photocatalyst for hydrogen evolution. The catalyst is a new and unique material as it consists of copper-decorated TiO2 particles covered tightly in graphene and obtained in a fluidized bed reactor. Both reduction of copper from Cu(CH3COO) at the surface of TiO2 particles and covering of TiO2-Cu in graphene thin layer by Chemical Vapour Deposition (CVD) were performed subsequently in the flow reactor by manipulating the gas composition. Obtained photocatalysts were tested in regard to hydrogen generation from photo-induced water conversion with methanol as sacrificial agent. The hydrogen generation rate for the most active sample reached 2296.27 µmol H2 h−1 gcat−1. Combining experimental and computational approaches enabled to define the optimum combination of the synthesis parameters resulting in the highest photocatalytic activity for water splitting for green hydrogen production. The results indicate that the major factor affecting hydrogen production is temperature of the TiO2-Cu-graphene composite synthesis which in turn is inversely correlated to photoactivity.
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