Publications
Integrated Optimization of Hydrogen Production: Evaluating Scope 3 Emissions and Sustainable Pathways
Jul 2025
Publication
The U.S. produces 10 million metric tons (MMT) of hydrogen annually emitting about 41 MMT of carbon dioxide equivalents (CO2-eqs). With rising hydrogen demand and new emission regulations integrating conventional and novel hydrogen production systems is crucial. This study presents an integrated optimization framework to model diversified hydrogen economies as mixed integer linear programs (MILPs). Moreover the accounting of emissions extends to the system exterior (scope 3) thus providing a comprehensive sustainability assessment. The primary focus of the presented computational example is to analyze the impact of scope 3 emissions particularly material emissions during the construction phase on process system optimization while complying with stringent environmental constraints such as carbon limits. By evaluating emission reduction scenarios the model highlights the role of power purchase agreements (PPAs) from renewable sources and the trade-offs between conventional and novel hydrogen production technologies. The key findings indicate that while electrolyzer-based systems (PEM and AWE) offer potential for emission reduction their high energy demand and significant scope 3 material emissions pose challenges for a complete transition in the near term. The study identified two optimal design configurations: one utilizing PPAs as the primary energy source coupled with the conventional SMR-CCS process and another that combines both conventional (SMR-CCS) and novel hydrogen production technologies under a hybrid purview. Ultimately the findings contribute toward the ongoing efforts to achieve true net-carbon neutrality.
Development of a MILP Optimization Framework to Design Grid-connected Microgrids: Enhancing Operational Synergy Among Wind, Solar, Batteries, and Hydrogen Storage
Sep 2025
Publication
By integrating Renewable Energy Sources (RES) and storage devices Hybrid Energy Systems (HESs) represent a promising solution for decarbonizing isolated and remote communities. Proper sizing and management of systems comprising a variety of components requires however more advanced methods than conventional energy systems. This study proposes a novel Mixed Integer Linear Programming (MILP) framework for the simultaneous design of a grid-connected HES supported by renewable generators. Unlike the standard design approach based on parametric dispatch strategies this framework simultaneously optimizes the energy management of each system configuration under analysis. The novel approach is applied to size a combination of Li-Ion batteries an alkaline electrolyzer H2 tanks and a PEM fuel cell to maximize the NPV of a system including a wind turbine and a photovoltaic field. Managing thousands of variables at the same time the framework simultaneously optimizes how all components are used to fulfill the load and balance the input/export of power within a limited electrical network. Results show that the combination of BESS and H2 can provide for both the need for short- and long-term energy storage and that the MILP optimization can effectively allocate the energy flows and produce 558 k€ of revenues per year 15.5% of the initial investment cost of 3.6 M€. The investment cost of the system is recovered in six years and presents an NPV of 5.51 M€ after 20 years. Results from the proposed method are also compared to common approaches based on rule-based parametric dispatch strategies demonstrating the superiority of MILP for the design and management of complex HESs.
Hydrogen Barrier Coatings: Application and Assessment
Sep 2025
Publication
Hydrogen embrittlement (HE) threatens the structural integrity of industrial components exposed to hydrogenrich environments. This review critically explores hydrogen barrier coatings (HBCs) polymeric metallic ceramic and composite their application and assessment focusing on measured effectiveness in limiting hydrogen permeation and hydrogen embrittlement. Also coating application methods and permeation assessment techniques are evaluated. Recent advances in nanostructured and hybrid coatings are emphasized highlighting the pressing need for durable scalable and environmentally sustainable hydrogen barrier coatings to ensure the reliability of emerging hydrogen-based energy solutions. This comprehensive critical review further distinguishes itself by linking coating deposition methods to defect-driven transport behaviour critically assessing permeation test approaches. It also highlights the emerging role of polymeric and hybrid multilayer coatings with direct implications for advanced and reliable hydrogen production storage and transport infrastructure.
Synthesis of Activated Carbon from Zhundong Coal and its Hydrogen Storage Application
May 2025
Publication
Activated carbon as a hydrogen storage material possesses advantages such as low cost high safety lightweight and good cycling performance. Zhundong coal characterized by low calorific value high volatility and elevated reaction activity stands out as an exceptional raw material for the production of activated carbon. This study employed Zhundong coal for the synthesis of hydrogen storage activated carbon exploring the impact of acid treatment and varied activation conditions on Zhundong coal. The specific surface area of sample ZD-HK3-AC is 1980 m2 /g and the gravimetric hydrogen storage density reaches 0.91 wt% under the condition of 80bar at room temperature. The adsorption–desorption isotherms nearly overlapped demonstrating excellent cycling performance and high mechanical strength. At the same time the relationship between the pore structure parameters of activated carbon and hydrogen storage density was explored revealing the mechanism of activated carbon adsorption and hydrogen storage. These findings hold significant guiding implications for the preparation and research of hydrogen storage materials utilizing activated carbon.
Advancing Electrochemical Modelling of PEM Electrolyzers through Robust Parameter Estimation with the Weighted Mean of Vectors Algorithm
Jul 2025
Publication
The electrochemical modelling of proton exchange membrane electrolyzers (PEMEZs) relies on the precise determination of several unknown parameters. Achieving this accuracy requires addressing a challenging optimization problem characterized by nonlinearity multimodality and multiple interdependent variables. Thus a novel approach for determining the unknown parameters of a detailed PEMEZ electrochemical model is proposed using the weighted mean of vectors algorithm (WMVA). An objective function based on mean square deviation (MSD) is proposed to quantify the difference between experimental and estimated voltages. Practical validation was carried out on three commercial PEMEZ stacks from different manufacturers (Giner Electrochemical Systems and HGenerators™). The first two stacks were tested under two distinct pressure-temperature settings yielding five V–J data sets in total for assessing the WMVA-based model. The results demonstrate that WMVA outperforms all optimizers achieving MSDs of 1.73366e−06 1.91934e−06 1.09306e−05 6.18248e−05 and 4.41586e−06 corresponding to improvements of approximately 88% 82.9% 82.4% 54.5% and 59.5% over the poorest-performing algorithm in each case respectively. Moreover comparative analyses statistical studies and convergence curves confirm the robustness and reliability of the proposed optimizer. Additionally the effects of temperature and hydrogen pressure variations on the electrical and physical steady-state performance of the PEMEZ are carefully investigated. The findings are further reinforced by a dynamic simulation that illustrates the impact of temperature and supplied current on hydrogen production. Accordingly the article facilitates better PEMEZ modelling and optimizing hydrogen production performance across various operating conditions.
Numerical Modelling of Gas Mixing in Salt Caverns During Cyclic Hydrogen Storage
Oct 2025
Publication
This study presents the development of a robust numerical model for simulating underground hydrogen storage (UHS) in salt caverns with a particular focus on the interactions between original gas-methane (CH4) and injected gas represented by hydrogen (H2). Using the Schlumberger Eclipse 300 compositional reservoir simulator the cavern was modelled as a highly permeable porous medium to accurately represent gas flow dynamics. Two principal mixing mechanisms were investigated: physical dispersion modelled by numerical dispersion and molecular diffusion. Multiple cavern configurations and a range of dispersion–diffusion coefficients were assessed. The results indicate that physical dispersion is the primary factor affecting hydrogen purity during storage cycles while molecular diffusion becomes more significant during long-term gas storage. Gas mixing was shown to directly impact the calorific value and quality of withdrawn hydrogen. This work demonstrates the effectiveness of commercial reservoir simulators for UHS analysis and proposes a methodological framework for evaluating hydrogen purity in salt cavern storage operations.
In-service and Repair Welding of Pressurized Hydrogen Pipelines - A Review on Current Challenges and Strategies
Aug 2025
Publication
Hydrogen is the energy carrier for a sustainable future without fossil fuels. As this requires a reliable transportation infrastructure the conversion of existing natural gas (NG) grids is an essential part of the worldwide individual national hydrogen strategies in addition to newly erected pipelines. In view of the known effect of hydrogen embrittlement the compatibility of the materials already in use (typically low-alloy steels in a wide range of strengths and thicknesses) must be investigated. Initial comprehensive studies on the hydrogen compatibility of pipeline materials indicate that these materials can be used to a certain extent. Nevertheless the material compatibility for hydrogen service is currently of great importance. However pipelines require frequent maintenance and repair work. In some cases it is necessary to carry out welding work on pipelines while they are under pressure e.g. the well-known tapping of NG grids. This in-service welding brings additional challenges for hydrogen operations in terms of additional hydrogen absorption during welding and material compatibility. The challenge can be roughly divided into two parts: (1) the possible austenitization of the inner piping material exposed to hydrogen which can lead to additional hydrogen absorption and (2) the welding itself causes an increased temperature range. Both lead to a significantly increased hydrogen solubility in the respective materials compared to room temperature. In that connection the knowledge on hot tapping on hydrogen pipelines is rare so far due to the missing service experiences. Fundamental experimental investigations are required to investigate the possible transferability of the state-of-the-art concepts from NG to hydrogen pipeline grids. This is necessary to ensure that no critical material degradation occurs due to the potentially increased hydrogen uptake. For this reason the paper introduces the state of the art in pipeline hot tapping encompassing current research projects and their individual solution strategies for the problems that may arise for future hydrogen service. Methods of material testing their limitations and possible solutions will be presented and discussed.
Hydrogen-Enabled Microgrids for Railway Applications: A Seasonal Energy Storage Solution for Switch-Point Heating
Sep 2025
Publication
Switch-point heating systems are essential for railway reliability and safety in winter but present logistical and economic challenges in remote regions. This study presents a novel application of a hydrogen-enabled microgrid as an off-grid energy solution for powering a switch-point heating system at a rural Austrian railway station offering an alternative to conventional grid-based electricity with a specific focus on enhancing the share of renewable energy sources. The proposed system integrates photovoltaics (PV) optional wind energy and hydrogen storage to address the seasonal mismatch between a high energy supply in the summer and peak winter demand. Three energy supply scenarios are analysed and compared based on local conditions technical simplicity and economic viability. Energy flow modelling based on site-specific climate and operational data is used to determine hydrogen production rates storage capacity requirements and system sizing. A comprehensive cost analysis of all major subsystems is conducted to assess economic viability. The study demonstrates that hydrogen is a highly effective solution for seasonal energy storage with a PV-only configuration emerging as the most suitable option under current site conditions. Thus it offers a replicable framework for decarbonising critical stationary railway infrastructure.
An Integrated AI-driven Framework for Maximizing the Efficiency of Heterostructured Nanomaterials in Photocatalytic Hydrogen Production
Jul 2025
Publication
The urgency for sustainable and efficient hydrogen production has increased interest in heterostructured nanomaterials known for their excellent photocatalytic properties. Traditional synthesis methods often rely on trial-and-error resulting in inefficiencies in material discovery and optimization. This work presents a new AI-driven framework that overcomes these challenges by integrating advanced machine-learning techniques specific to heterostructured nanomaterials. Graph Neural Networks (GNNs) enable accurate representations of atomic structures predicting material properties like bandgap energy and photocatalytic efficiency within ±0.05 eV. Reinforcement Learning optimises synthesis parameters reducing experimental iterations by 40% and boosting hydrogen yield by 15–20%. Physics-Informed Neural Networks (PINNs) successfully predict reaction pathways and intermediate states minimizing synthesis errors by 25%. Variational Autoencoders (VAEs) generate novel material configurations improving photocatalytic efficiency by up to 15%. Additionally Bayesian Optimisation enhances predictive accuracy by 30% through efficient hyperparameter tuning. This holistic framework integrates material design synthesis optimization and experimental validation fostering a synergistic data flow. Ultimately it accelerates the discovery of novel heterostructured nanomaterials enhancing efficiency scalability and yield thus moving closer to sustainable hydrogen production with improvements in photolytic efficiency setting a benchmark for AI-assisted research.
Hydrogen Production Intensification by Energy Demand Management in High-Temperature Electrolysis
Aug 2025
Publication
Solid oxide electrolysers (SOEs) can decarbonise H2 supply when powered by renewable electricity but remain constrained by high electrical demand and integration penalties. Our objective is to minimise the electrical (Pel) and thermal (Qth) energy demand per mole of H2 by jointly tuning cell temperature steam fraction steam utilisation pressure and current density. Compared with prior single-variable or thermo-neutral-constrained studies we develop and validate a steady-state process-level optimisation framework that couples an Aspen Plus SOE model with electrochemical post-processing and heat caused by ohmic resistance recovery. A Box–Behnken design explores five key operating parameters to capture synergies and trade-offs between Qth and Pel energy inputs. Single-objective optimisation yields Pel = 170.1 kJ mol⁻¹ H2 a 41.4% reduction versus literature baselines. Multi-objective optimisation using an equal-weighted composite desirability function aggregating thermal and electrical demands further reduces Pel by 21.2% while balancing thermal input 4–8% lower than single-objective baselines at moderate temperature (~781 °C) and pressure (~17.5 bar). Findings demonstrate a clear process intensification advantage over previous studies by simultaneously leveraging operating parameter synergies and heat-integration. However results are bounded by steady-state perfectly mixed isothermal assumptions. The identified operating windows are mechanistically grounded targets that warrant stack-scale and plantlevel validation.
Cyclic Liquid Organic Hydrogen Carriers for Efficient Hydrogen Storage using Mesoporous Catalytic Systems
Jul 2025
Publication
Liquid organic hydrogen carriers (LOHCs) are a promising class of hydrogen storage media in which hydrogen is reversibly bound to organic molecules. In this work we focus explicitly on cyclic LOHCs (both homocyclic and heterocyclic organic compounds) and their catalytic dehydrogenation. We clarify that other carriers (e.g. alcohols like methanol or carboxylic acids like formic acid) exist but are not the focus here; these alternatives are discussed only in comparative context. Cyclic LOHCs typically enable safe ambient-temperature hydrogen storage with hydrogen contents around 6–8 wt%. Key challenges include the high dehydrogenation temperatures (often 200–350 °C) catalyst costs and catalyst deactivation via coke formation. We introduce a comparative analysis table contrasting cyclic LOHCs with alternative carriers in terms of hydrogen density operating conditions catalyst types toxicity and cost. We also expand the catalyst discussion to highlight coke formation mechanisms and the use of mesoporous metal-oxide supports to mitigate deactivation. Finally a techno-economic analysis is provided to address system costs of LOHC storage and regeneration. Finally we underscore the viability and limitations of cyclic LOHCs including practical storage capacities catalyst life and projected costs.
Can Hydrogen-powered Air Travel Grow within the Planetary Limits?
Aug 2025
Publication
Air travel demand is rising rapidly and the aviation sector is relying on technology to decouple environmental impacts from its growth. Using Sweden as a case study we assessed the absolute environmental sustainability of medium-distance air travel in 2050 positioning the aviation sector's environmental impacts in relation to the planetary limits. We employed a novel framework that integrates prospective life cycle assessment and absolute environmental sustainability assessment methodologies. Our findings suggest that projected medium-distance air travel powered by e-kerosene or liquid hydrogen could have life cycle environmental impacts that overshoot global climate change and biodiversity loss thresholds by several orders of magnitude. Based on our case results for Sweden for aviation to develop within the planetary limits we recommend cross-sector collaboration to address environmental impacts from fossil-free energy supplies and the establishment of integrated targets that incorporate broader environmental issues. Given the unlikelihood of decoupling growth from environmental impacts policymakers and the aviation sector should consider concurrently supporting technological development and implementing measures to manage air travel demand.
Techno-Economic Optimization of a Hybrid Renewable Energy System with Seawater-Based Pumped Hydro, Hydrogen, and Battery Storage for a Coastal Hotel
Oct 2025
Publication
This study presents the design and techno-economic optimization of a hybrid renewable energy system (HRES) for a coastal hotel in Manavgat Türkiye. The system integrates photovoltaic (PV) panels wind turbines (WT) pumped hydro storage (PHS) hydrogen storage (electrolyzer tank and fuel cell) batteries a fuel cell-based combined heat and power (CHP) unit and a boiler to meet both electrical and thermal demands. Within this broader optimization framework six optimal configurations emerged representing gridconnected and standalone operation modes. Optimization was performed in HOMER Pro to minimize net present cost (NPC) under strict reliability (0% unmet load) and renewable energy fraction (REF > 75%) constraints. The grid-connected PHS–PV–WT configuration achieved the lowest NPC ($1.33 million) and COE ($0.153/kWh) with a renewable fraction of ~96% and limited excess generation (~21%). Off-grid PHS-based and PHS–hydrogen configurations showed competitive performance with slightly higher costs. Hydrogen integration additionally provides complementary storage pathways coordinated operation waste heat utilization and redundancy under component unavailability. Battery-only systems without PHS or hydrogen storage resulted in 37–39% higher capital costs and ~53% higher COE confirming the economic advantage of long-duration PHS. Sensitivity analyses indicate that real discount rate variations notably affect NPC and COE particularly for battery-only systems. Component cost sensitivity highlights PV and WT as dominant cost drivers while PHS stabilizes system economics and the hydrogen subsystem contributes minimally due to its small scale. Overall these results confirm the techno-economic and environmental benefits of combining seawater-based PHS with optional hydrogen and battery storage for sustainable hotel-scale applications.
The Role of Financial Mechanisms in Advancing Renewable Energy and Green Hydrogen
Jun 2025
Publication
Europe’s transition toward a low-carbon energy system relies on the deployment of hydrogen produced with minimized carbon emissions; however regulatory requirements increase system costs and create financial barriers. This study investigates the financial implications of enforcing European Commission rules for renewable hydrogen production from 2024 to 2048. Using a scenario-based modeling approach that draws on European power system investments in renewable energy the results show that immediate compliance leads to an additional cost of approximately eighty billion euros over twenty-four years corresponding to a 3.6 percent increase in total system costs. To address this investment gap the study employs a segmentation analysis of support mechanisms based on existing policies and market practices identifying seven categories that range from investment incentives and production subsidies to infrastructure and financial instruments. Among these hydrogen offtake support and infrastructure funding are identified as the most effective measures for reducing risk and enabling private investment. These findings provide strategic insights for policymakers seeking to align their regulatory ambitions with financially viable pathways for integrating renewable energy.
Degradation Mechanisms of a Proton Exchange Membrane Water Electrolyzer Stack Operating at High Current Densities
Sep 2025
Publication
On the path to an emission free energy economy proton exchange membrane water electrolysis (PEMWE) is a promising technology for a sustainable production of green hydrogen at high current densities and thus high production rates. Long lifetime increasing the current density and the reduction of platinum group metal loadings are major challenges for a widespread implementation of PEMWE. In this context this work investigates the aging of a PEMWE stack operating at 4 A cm-2 which is twice the nominal current density of commercial electrolyzers. Specifically an 8-cells PEMWE stack using catalyst coated membranes (CCMs) with different platinum group metal (PGM) loading was operated for 2200 h. To understand degradation phenomena physical ex-situ analyses such as scanning electron microscopy (SEM) atomic force microscopy (AFM) and X-ray photoelectron spectroscopy (XPS) were carried out. The same aging mechanism were observed in all cells independent on their position in stack or the specific PGM loading of the membrane electrode assembly (CCM): (i) a decrease of ohmic resistance over time related to membrane thinning (ii) a significant loss of ionomer at anodes (iii) loss of noble metal from the electrodes leading to deposition of small Ir and Pt concentrations in the membrane (iv) heterogeneous enrichment of Ti on the cathode side likely originating from the cathode-side of the Ti bipolar plates (BPPs). These results are in good agreement with the electrochemical performance loss. Thus we were able to identify the degradation phenomena that dominate under high-current operation and their impact on performance.
A Framework for the Configuration and Operation of EV/FCEV Fast-Charging Stations Integrated with DERs Under Uncertainty
Oct 2025
Publication
The integration of electric vehicles (EVs) and fuel-cell electric vehicles (FCEVs) requires accessible and profitable facilities for fast charging. To promote fast-charging stations (FCSs) a systematic analysis that encompasses both planning and operation is required including the incorporation of multi-energy resources and uncertainty. This paper presents an optimization framework that addresses a joint strategy for the configuration and operation of an EV/FCEV fast-charging station (FCS) integrated with distributed energy resources (DERs) and hydrogen systems. The framework incorporates uncertainties related to solar photovoltaic (PV) generation and demand for EVs/FCEVs. The proposed joint strategy comprises a four-phase decision-making framework. Phase 1 involves modeling EV/FECE demand while Phase 2 focuses on determining an optimal long-term infrastructure configuration. Subsequently in Phase 3 the operator optimizes daily power scheduling to maximize profit. A real-time uncertainty update is then executed in Phase 4 upon the realization of uncertainty. The proposed optimization framework formulated as mixed-integer quadratic programming (MIQP) considers configuration investment operational maintenance and penalty costs for excessive grid power usage. A heuristic algorithm is proposed to solve this problem. It yields good results with significantly less computational complexity. A case study shows that under the most adverse conditions the proposed joint strategy increases the FCS owner’s profit by 3.32% compared with the deterministic benchmark.
Effect of Real Gas Equations on Calculation Accuracy of Thermodynamic State in Hydrogen Storage Tank
Oct 2025
Publication
The gas equation of state (EOS) serves as a critical tool for analyzing the thermal effects within the hydrogen storage tank during refueling processes. It quantifies the dynamic relationships among pressure temperature and volume playing a vital role in numerical simulations of hydrogen refueling the development of refueling protocols and ensuring refueling safety. This study first establishes a lumped-parameter thermodynamic model for the hydrogen refueling process which combines a zero-dimensional gas model with a one-dimensional tank wall model (0D1D). The model’s accuracy was validated against experimental data and will be used in combination with different EOSs to simulate hydrogen temperature and pressure. Subsequently parameter values are derived for the van der Waals EOS and its modified forms—Redlich–Kwong Soave and Peng–Robinson. The accuracy of the modified forms is evaluated using the Joule–Thomson inversion curve. A polynomial EOS is formulated and its parameters are numerically determined. Finally the hydrogen temperatures and pressures calculated using the van der Waals EOS Redlich– Kwong EOS polynomial EOS and the National Institute of Standards and Technology (NIST) database are compared. Within the initial and boundary conditions set in this study the results indicate that among the modified forms for van der Waals EOS the Redlich– Kwong EOS exhibits higher accuracy than the Soave and Peng–Robinson EOSs. Using the NIST-calculated hydrogen pressure as a benchmark the relative error is 0.30% for the polynomial EOS 1.83% for the Redlich–Kwong EOS and 17.90% for the van der Waals EOS. Thus the polynomial EOS exhibits higher accuracy followed by the Redlich–Kwong EOS while the van der Waals EOS demonstrates lower accuracy. This research provides a theoretical basis for selecting an appropriate EOS in numerical simulations of hydrogen refueling processes.
Optimizing Renewable Microgrid Performance Through Hydrogen Storage Integration
Oct 2025
Publication
The global transition to a low-carbon energy system requires innovative solutions that integrate renewable energy production with storage and utilization technologies. The growth in energy demand combined with the intermittency of these sources highlights the need for advanced management models capable of ensuring system stability and efficiency. This paper presents the development of an optimized energy management system integrating renewable sources with a focus on green hydrogen production via electrolysis storage and use through a fuel cell. The system aims to promote energy autonomy and support the transition to a low-carbon economy by reducing dependence on the conventional electricity grid. The proposed model enables flexible hourly energy flow optimization considering solar availability local consumption hydrogen storage capacity and grid interactions. Formulated as a Mixed-Integer Linear Programming (MILP) model it supports strategic decision-making regarding hydrogen production storage and utilization as well as energy trading with the grid. Simulations using production and consumption profiles assessed the effects of hydrogen storage capacity and electricity price variations. Results confirm the effectiveness of the model in optimizing system performance under different operational scenarios.
Response Surface Analysis of the Energy Performance and Emissions of a Dual-Fuel Engine Generator Using Biodiesel and Hydrogen-Enriched Biogas
Oct 2025
Publication
In this study we investigate the dual-fuel operation of compression ignition engines using biodiesel at varying concentrations in combination with biogas with and without hydrogen enrichment. A response surface methodology based on a central composite experimental design was employed to optimize energy efficiency and minimize pollutant emissions. The partial substitution of diesel with gaseous fuel substantially reduces the specific fuel consumption achieving a maximum decrease of 21% compared with conventional diesel operation. Enriching biogas with hydrogen accounting for 13.3% of the total flow rate increases the thermal efficiency by 0.8% compensating for the low calorific value and reduced volumetric efficiency of biogas. Variations in biodiesel concentration exhibits a nonlinear effect yielding an additional average efficiency gain of 0.4%. Regarding emissions the addition of hydrogen to biogas contributes to an average reduction of 5% in carbon monoxide emissions compared to the standard dual-fuel operation. However dual-fuel operation leads to higher unburned hydrocarbon emissions relative to neat diesel; hydrogen enrichment mitigates this drawback by reducing hydrocarbon emissions by 4.1%. Although NOx emissions increase by an average of 26.6% with hydrogen addition dual-fuel strategies achieve NOx reductions of 11.5% (hydrogen-enriched mode) and 33.3% (pure biogas mode) relative to diesel-only operation. Furthermore the application of response surface methodology is robust and reliable with experimental validation showing errors of 0.55–8.66% and an overall uncertainty of 4.84%.
A Two-Layer HiMPC Planning Framework for High-Renewable Grids: Zero-Exchange Test on Germany 2045
Oct 2025
Publication
High-renewables grids are planned in min but judged in milliseconds; credible studies must therefore resolve both horizons within a single model. Current adequacy tools bypass fast frequency dynamics while detailed simulators lack multi-hour optimization leaving investors without a unified basis for sizing storage shifting demand or upgrading transfers. We present a two-layer Hierarchical Model Predictive Control framework that links 15-min scheduling with 1-s corrective action and apply it to Germany’s four TSO zones under a stringent zero-exchange stress test derived from the NEP 2045 baseline. Batteries vehicleto-grid pumped hydro and power-to-gas technologies are captured through aggregators; a decentralized optimizer pre-positions them while a fast layer refines setpoints as forecasts drift; all are subject to inter-zonal transfer limits. Year-long simulations hold frequency within ±2 mHz for 99.9% of hours and below ±10 mHz during the worst multi-day renewable lull. Batteries absorb sub-second transients electrolyzers smooth surpluses and hydrogen turbines bridge week-long deficits—none of which violate transfer constraints. Because the algebraic core is modular analysts can insert new asset classes or policy rules with minimal code change enabling policy-relevant scenario studies from storage mandates to capacity-upgrade plans. The work elevates predictive control from plantscale demonstrations to system-level planning practice. It unifies adequacy sizing and dynamic-performance evaluation in a single optimization loop delivering an open scalable blueprint for high-renewables assessments. The framework is readily portable to other interconnected grids supporting analyses of storage obligations hydrogen roll-outs and islanding strategies.
Solar-powered Electric Vehicles - Batter EV & Fuel Cell EV: A Review
Sep 2025
Publication
The transport sector is a major contributor to greenhouse gas emissions largely due to its dependence on fossil fuels. Electrifying transport through Battery Electric Vehicles (BEVs) and Hydrogen Fuel Cell Electric Vehicles (FCEVs) is widely recognized as a key pathway to reducing emissions. While both BEVs and FCEVs are zero-emission during operation they still require electricity to function. Sourcing this electricity from solar energy presents a promising opportunity for sustainable operation. The novelty of this work lies in exploring how solar energy can be effectively integrated into both BEV and FCEV systems. The paper examines the potential scope and infrastructure requirements of these vehicle types as well as innovative charging and refuelling strategies. For BEVs charging options include fixed charging stations battery swapping stations and wireless charging. In the context of solar integration photovoltaic (PV) systems can be mounted directly on the vehicle body or used to power charging stations. While current PV efficiency and reliability are insufficient to meet the full energy demand of BEVs they can provide valuable auxiliary power. For FCEVs solar energy can be utilized for hydrogen production enabling the concept of solar-powered FCEVs. Refuelling options include onsite and offsite hydrogen production facilities as well as mobile refuelling units. In both cases land requirements for PV installations are significant. Alternatives to ground-mounted PV such as floating PV or agrivoltaics (agriPV) should be considered to optimize land use. While solar-powered charging or refuelling stations are technically feasible complete reliance on solar power alone is not yet practical. A hybrid approach with grid connections energy storage or backup generation remains necessary to ensure consistent energy availability. For BEVs the cost of charging particularly for long-distance travel where rapid charging is required remains a barrier. For FCEVs challenges include the high cost of hydrogen production and the limited availability of refuelling infrastructure despite their advantage of fast refuelling times. Government policies and incentives are playing a critical role in overcoming these barriers fostering investment in infrastructure and accelerating the transition toward a cleaner transport sector. In summary integrating solar energy into BEV and FCEV infrastructure can advance sustainable mobility by reducing lifecycle emissions. While current PV efficiency storage and hydrogen production limitations require hybrid energy solutions ongoing technological improvements and supportive policies can enable broader adoption. A balanced renewable energy mix with solar as a key component will be essential for realizing truly sustainable zero-emission transport.
Experimental and Numerical Analysis of Hydrogen-Induced Effects in ASTM A131 and A36 Steels for Naval Fuel Systems
Oct 2025
Publication
Hydrogen embrittlement (HE) can degrade the mechanical integrity of steel pipes increasing failure risks in naval fuel systems. This study assesses HE effects on ASTM A131 and A36 steels through tensile testing and numerical modeling. Tests conducted with varying exposure times to hydrogen revealed that A131 outperformed A36 in terms of mechanical strength. However both materials experienced property degradation after six hours. After nine hours a transient increase in strength occurred due to temporary microstructural hardening though the overall trend remained a decline. The maximum reductions in ultimate tensile strength and toughness were 19% and 47% for A131 and 39% and 61% for A36 respectively. Additionally microstructural analysis revealed the presence of inclusions intergranular decohesion and micro-crack in specimens exposed for longer periods. Finally a combined GTN-PLNIH numerical model was implemented demonstrating its effectiveness in predicting the mechanical behavior of structures exposed to hydrogen.
Hydrogen Propulsion Technologies for Aviation: A Review of Fuel Cell and Direct Combustion Systems Towards Decarbonising Medium-Haul Aircraft
Oct 2025
Publication
Hydrogen propulsion technologies are emerging as a key enabler for decarbonizing the aviation sector especially for regional commercial aircraft. The evolution of aircraft propulsion technologies in recent years raises the question of the feasibility of a hydrogen propulsion system for beyond regional aircraft. This paper presents a comprehensive review of hydrogen propulsion technologies highlighting key advancements in component-level performance metrics. It further explores the technological transitions necessary to enable hydrogen-powered aircraft beyond the regional category. The feasibility assessment is based on key performance parameters including power density efficiency emissions and integration challenges aligned with the targets set for 2035 and 2050. The adoption of hydrogen-electric powertrains for the efficient transition from KW to MW powertrains depends on transitions in fuel cell type thermal management systems (TMS) lightweight electric machines and power electronics and integrated cryogenic cooling architectures. While hydrogen combustion can leverage existing gas turbine architectures with relatively fewer integration challenges it presents its technical hurdles especially related to combustion dynamics NOx emissions and contrail formation. Advanced combustor designs such as micromix staged and lean premixed systems are being explored to mitigate these challenges. Finally the integration of waste heat recovery technologies in the hydrogen propulsion system is discussed demonstrating the potential to improve specific fuel consumption by up to 13%.
Energy Management in an Insular Region with Renewable Energy Sources and Hydrogen: The Case of Graciosa, Azores
Sep 2025
Publication
Insular regions face unique energy management challenges due to physical isolation. Graciosa (Azores) has high renewable energy sources (RES) potential theoretically enabling a 100% green system. However RES intermittency combined with the lack of energy storage solutions reduces renewable penetration and raises curtailment. This article studies the technical and economic feasibility of producing green hydrogen from curtailment energy in Graciosa through two distinct case studies. Case Study 1 targets maximum renewable penetration with green hydrogen serving as chemical storage converted back to electricity via fuel cells during RES shortages. Case Study 2 focuses on maximum profitability where produced gases are sold to monetize curtailment without additional electricity production. Levelized Cost of Hydrogen (LCOH) values of €3.06/kgH2 and €2.68/kgH2 respectively and Internal Rate of Return (IRR) values of 3.7% and 17.1% were obtained for Case Studies 1 and 2 with payback periods of 15.2 and 6.1 years. Hence only Case Study 2 is economically viable but it does not allow increasing the renewable share in the energy mix. Sensitivity analysis for Case Study 1 shows that overall efficiency and CAPEX are the main factors affecting viability highlighting the need for technological advances and economies of scale as well as the importance of public funding to promote projects like this.
Modeling Gas Producibility and Hydrogen Potential—An Eastern Mediterranean Case Study
Oct 2025
Publication
The transition to low-carbon energy systems demands robust strategies that leverage existing fossil resources while integrating renewable technologies. In this work a single-cycle Gaussian-based producibility model is developed to forecast natural gas production profiles domestic consumption export potential hydrogen production and revenues adaptive for untapped natural gas discoveries. Annual natural gas production is represented by a bell curve defined by peak year and maximum capacity allowing flexible adaptation to different reserve sizes. The model integrates renewable energy adoption and steam–methane reforming to produce hydrogen while tracking revenue streams from domestic sales exports and hydrogen markets alongside carbon taxation. Applicability is demonstrated through a case study of Eastern Mediterranean gas discoveries where combined reserves of 2399 bcm generate a production peak of 100 bcm/year in 2035 and deliver 40.71 billion kg of hydrogen by 2050 leaving 411.87 bcm of reserves. A focused Cyprus scenario with 411 bcm of reserves peaks at 10 bcm/year produces 4.07 billion kg of hydrogen and retains 212.29 bcm of reserves. Cumulative revenues span from USD 84.37 billion under low hydrogen pricing to USD 247.29 billion regionally while the Cyprus-focused case yields USD 1.79 billion to USD 18.08 billion. These results validate the model’s versatility for energy transition planning enabling strategic insights into infrastructure deployment market dynamics and resource management in gas-rich regions.
Carbon Emission Reduction Capability Analysis of Electricity–Hydrogen Integrated Energy Storage Systems
Oct 2025
Publication
Against the dual backdrop of intensifying carbon emission constraints and the large-scale integration of renewable energy integrated electricity–hydrogen energy systems (EH-ESs) have emerged as a crucial technological pathway for decarbonising energy systems owing to their multi-energy complementarity and cross-scale regulation capabilities. This paper proposes an operational optimisation and carbon reduction capability assessment framework for EH-ESs focusing on revealing their operational response mechanisms and emission reduction potential under multi-disturbance conditions. A comprehensive model encompassing an electrolyser (EL) a fuel cell (FC) hydrogen storage tanks and battery energy storage was constructed. Three optimisation objectives—cost minimisation carbon emission minimisation and energy loss minimisation—were introduced to systematically characterise the trade-offs between economic viability environmental performance and energy efficiency. Case study validation demonstrates the proposed model’s strong adaptability and robustness across varying output and load conditions. EL and FC efficiencies and costs emerge as critical bottlenecks influencing system carbon emissions and overall expenditure. Further analysis reveals that direct hydrogen utilisation outperforms the ‘electricity–hydrogen–electricity’ cycle in carbon reduction providing data support and methodological foundations for low-carbon optimisation and widespread adoption of electricity–hydrogen systems.
Hydrogen Direct Reduced Iron Melting in an Electric Arc Furnace: Benefits of In Situ Monitoring
Oct 2025
Publication
The transition toward environmentally friendly steelmaking using hydrogen direct reduced iron as feed material in electric arc furnaces will eventually require process adjustments due to changes in the pellet properties when compared to e.g. blast furnace pellets. To this end the melting of hydrogen direct reduced iron pellets with 68 and 100% reduction degrees and Fe content of 67.24% was investigated in a laboratory-scale electric arc furnace. The presence of iron oxide-rich slag had a significant effect on the arc movement on the melt and an inhibiting effect on iron evaporation. The melting was monitored with video recording and optical emission spectroscopy. The videos were used to monitor the melting behavior whereas optical emissions revealed iron gangue elements and hydrogen from the pellets radiating in the plasma. Furthermore the flow of the melt is well seen in the videos as well as the movement of slag droplets on the melt surface. After the experiments the metal had silica-rich inclusions whereas slag had mostly penetrated into the crucible. The most notable differences in melting behavior can be attributed to the iron oxide-rich slag its interaction with the arc and penetration into the crucible and how it affects the arc movement and heat transfer.
Sensitivity Analysis of Geological Parameters to Evaluate Uncertainty in Underground Hydrogen Storage Performance for a Saline Aquifer at Ketzin (Germany)
May 2025
Publication
A numerical sensitivity analysis of a hydrogen pore storage system is carried out on a reservoir-scale geological model of the Ketzin site (Germany) to analyze the influence of uncertainty in geological parameters and fluid properties on storage performance. Therefore the following physical geological parameters and fluid properties were investigated: Porosity and permeability of the reservoir rock the brine salinity relative permeability and capillary pressure and mechanical dispersion. The range of the applied parameters is based on experimental and field data of the chosen location obtained during the former CO2 storage projects at the Ketzin site from 2008 to 2013. Using the open-source reservoir software MUFITS for the numerical simulations strong differences between the results can be observed. The results were evaluated based on measures to quantify performance such as the ratio of produced hydrogen mass to produced cushion gas (nitrogen) productivity index and sustainability index. The strongest impact on the performance parameters was observed with variations in the capillary pressure and the relative permeability curves followed by the absolute permeabilities while the least impact was seen with changes in the porosity and salinity of the brine. This work is not only crucial as a pre-feasibility study for the Ketzin storage site for hydrogen storage but also as a basis for decision-making for other potential storage sites in sedimentary basins.
Mapping Hydrogen Demand for Heavy-duty Vehicles: A Spatial Disaggregation Approach
Jul 2025
Publication
Hydrogen is the key to decarbonising heavy-duty transport. Understanding the distribution of hydrogen demand is crucial for effective planning and development of infrastructure. However current data on future hydrogen demand is often coarse and aggregated limiting its utility for detailed analysis and decision-making. This study developed a spatial disaggregation approach to estimating hydrogen demand for heavy-duty trucks and mapping the spatial distribution of hydrogen demand across multiple scales in Australia. By integrating spatial datasets with economic factors market penetration rates and technical specifications of hydrogen fuel cell vehicles the approach disaggregates the projected demand into specific demand centres allowing for the mapping of regional hydrogen demand patterns and the identification of key centres of hydrogen demand based on heavy-duty truck traffic flow projections under different scenarios. This approach was applied to Australia and the findings offered valuable insights that can help policymakers and stakeholders plan and develop hydrogen infrastructure such as optimising hydrogen refuelling station locations and support the transition to a low-carbon heavy-duty transport sector.
Techno-Economic Assessment of Carbon-Neutral Ammonia Fuel for Ships from Renewable Wind Energy
Oct 2025
Publication
Climate change is fuelled by the continued growth of global carbon emissions with the widespread use of fossil fuels being the main driver. To achieve a decarbonisation transition of the energy mix the development of clean and renewable fuels has become crucial. Ammonia is seen as an important option for decarbonisation in the transport and energy sectors due to its zero-carbon emission potential and renewable energy compatibility. However the high energy consumption and carbon emissions of the conventional Haber– Bosch method limit its sustainability. A green ammonia synthesis system was designed using ECLIPSE and Excel simulations in the study. Results show that at a recirculation ratio of 70% the system’s annual total energy consumption is 426.22 GWh with annual ammonia production reaching 8342.78 t. The optimal system configuration comprises seven 12 MW offshore wind turbines integrated with a 460 MWh lithium battery and 240 t of hydrogen storage capacity. At this configuration the LCOE is approximately £5956.58/t. It shows that incorporating renewable energy can significantly reduce greenhouse gas emissions but further optimisation of energy storage configurations and reaction conditions is needed to lower costs. This research provides a reference for the industrial application of green ammonia in the transportation sector.
Comparative Techno-Economic and Life Cycle Assessment of Stationary Energy Storage Systems: Lithium-Ion, Lead-Acid, and Hydrogen
Oct 2025
Publication
This study presents a comparative techno-economic and environmental assessment of three leading stationary energy storage technologies: lithium-ion batteries lead-acid batteries and hydrogen systems (electrolyzer–tank–fuel cell). The analysis integrates Life Cycle Assessment (LCA) and Levelized Cost of Storage (LCOS) to provide a holistic evaluation. The LCA covers the full cradle-to-grave stages while LCOS accounts for capital and operational expenditures efficiency and cycling frequency. The results indicate that lithium-ion batteries achieve the lowest LCOS (120–180 EUR/MWh) and high round-trip efficiency (90–95%) making them optimal for short- and medium-duration storage. Lead-acid batteries though characterized by low capital expenditures (CAPEX) and high recyclability (>95%) show limited cycle life and lower efficiency (75–80%). Hydrogen systems remain costly (>250 EUR/MWh) and less efficient (30–40%) yet they demonstrate clear advantages for long-term and seasonal storage particularly under scenarios with “green” hydrogen production and reduced CAPEX. These findings provide practical guidance for policymakers investors and industry stakeholders in selecting appropriate storage solutions aligned with decarbonization and sustainability goals.
Low-emission Hydrogen: Global Value Chain Opportunities for Latecomers and Industrial Policy Challenges
Jul 2025
Publication
To meet decarbonization targets demand for low-emission hydrogen is increasing. A considerable share of supply will come from latecomer countries. We study how latecomer countries and firms participate in the emerging global low-emission hydrogen economy and how industrial policies can help maximize societal benefits. This requires a specific conceptualization of industrial policy: First the latecomer condition calls for specific policy mixes as latecomers typically cannot build on established innovation systems and network externalities and rather need to combine FDI attraction with measures strengthening absorptive capacity and ensuring knowledge transfer from FDI to domestic firms; second low-emission hydrogen is a policy-induced alternative that requires creating entirely new firm ecosystems while competing with lower-cost emission-intensive incumbent technologies. Hence industrial policies need to account for enhanced coordination failure and internalization of environmental costs. We analyze the published national hydrogen strategies of 20 latecomer economies and derive a novel typology differentiating four hydrogen-specific industrial development pathways. For each pathway we assess entry barriers and risks identify the policies suggested in the country strategies and discuss how likely those are to be successful. The novel pathway typology and comparison of associated policy mixes may help policymakers maximize the gains of hydrogen investments.
Mechanical Testing Methods for Assessing Hydrogen Embrittlement in Pipeline Steels: A Review
Oct 2025
Publication
As the transport of gaseous hydrogen and its use as a low carbon-footprint energy vector become increasingly likely scenarios both the scientific literature and technical standards addressing the compatibility of pipeline steels with high-pressure hydrogen environments are rapidly expanding. This work presents a detailed review of the most relevant hydrogen embrittlement testing methodologies proposed in standards and the academic literature. The focus is placed on testing approaches that support design-oriented assessments rather than simple alloy qualification for hydrogen service. Particular attention is given to tensile tests (conducted on smooth and notched specimens) as well as to J-integral and fatigue tests performed following the fracture mechanics’ approach. The influences of hydrogen partial pressure and deformation rate are critically examined as these parameters are essential for ensuring meaningful comparisons across different studies.
Hydrogen UK - Supply Chain Strategic Assessment: Phase I
Mar 2025
Publication
The UK Hydrogen Supply Chain Strategic Assessment – Phase II report is developed as an appendix to the UK Hydrogen Supply Chain Strategic Assessment – Phase I report published in September 2024. Whereas the Phase I report prioritised the supply side elements of the hydrogen supply chain i.e. power industry storage electrolytic production CCUS enabled production and networks the Phase II focuses on demand side elements in the hydrogen supply chain i.e. fuel cell systems (including cars vans heavy goods vehicles & non road mobile machinery rail marine) and hydrogen refuelling systems. The Phase II adopts the same approach as carried out in Phase I by utilising analysis based on feedback from survey questionnaires interviews with key industrial stakeholders and internal research.
The paper can be found on their website.
The paper can be found on their website.
Simulation of a Solar-based Small-scale Green Hydrogen Production Unit in Iran: A Techno-economic-feasibility Analysis
Aug 2025
Publication
Based on the global efforts to reduce fossil fuel dependence and its environmental concerns green hydrogen has been considered a promising pathway towards sustainable energy transition. Iran is considered a promising location for green hydrogen production due to its considerable solar energy potential. While global interest in green hydrogen continues to grow studies that explore the techno-economic feasibility of small-scale solar-based green hydrogen systems tailored to Iran’s diverse climatic conditions are still relatively limited. This study aims to assess the technical and economic feasibility of small-scale green hydrogen production based on solar energy (photovoltaics) in six cities of Iran including Isfahan Kerman Kermanshah Shiraz Tehran and Zahedan by examining whether such systems can be financially viable despite their relatively high unit costs. The study employs TRNSYS for dynamic simulation of the hydrogen production system and RETScreen for economic analysis. The results indicate that the system has an annual energy production capacity ranging from 831.52 to 1062.22 MWh across the studied locations. The system's hydrogen production rate was between 16800 and 21114 kg/year. Based on the results the lowest levelized cost of hydrogen (LCOH) was recorded in Shiraz at $6.43/kg H₂ while Tehran experienced the highest value ($8.81/kg H₂). Among the evaluated cities Shiraz demonstrated the most favorable financial performance with an internal rate of return (IRR) of 18.5% and a payback period of 8 years. These findings can be useful for policymakers in Iran and the MENA region in investment planning related to the clean energy transition.
The European Hydrogen Market Landscape - November 2024
Nov 2024
Publication
This report aims to summarise the status of the European hydrogen market landscape. It is based on the information available at the European Hydrogen Observatory (EHO) initiative the leading source of data on hydrogen in Europe exploring the basic concepts latest trends and role of hydrogen in the energy transition. The data presented in this report is based on research conducted until the end of September 2024. This report contains information on current hydrogen production and trade distribution and storage end-use cost and technology manufacturing as of the end of 2023 except if stated otherwise in Europe. A substantial portion of the data gathering was carried out within the framework of Hydrogen Europe's efforts for the European Hydrogen Observatory. Downloadable spreadsheets of the data can be accessed on the website: https://observatory.clean-hydrogen.europa.eu/. The production and trade section provides insights into hydrogen production capacity and production output by technology in Europe and into international hydrogen trade (export and import) to and between European countries. The section referring to distribution and storage presents the location and main attributes of operational dedicated hydrogen pipelines and storage facilities as well as publicly accessible and operational hydrogen refuelling stations in Europe. The end-use section provides information on annual hydrogen consumption per end-use in Europe the deployment of hydrogen fuel cell electric vehicles in Europe the current and future hydrogen Valleys in Europe and the leading scenarios for future hydrogen demand in Europe in 2030 2040 and 2050 by sector. The cost chapter offers a comprehensive examination of the levelised cost of hydrogen production by technology and country. This chapter also gives estimations of renewable hydrogen break-even prices for different end-use applications in addition to electrolyser cost components by technology. Finally a chapter on technologies manufacturing explores data on the European electrolyser manufacturing capacity and sales and the fuel cell market.
Synergistic Effects of Air Pollution and Carbon Reduction Policies in China’s Iron and Steel Industry
Oct 2025
Publication
As an energy-intensive sector China’s iron and steel industry is crucial for achieving “Dual Carbon” goals. This study fills the research gap in systematically comparing the synergistic effects of multiple policies by evaluating five key measures (2020–2023) in ultra-low-emission retrofits and clean energy alternatives. Using public macro-data at the national level this study quantified cumulative reductions in air pollutants (SO2 NOx PM VOCs) and CO2. A synergistic control effect coordinate system and a normalized synergistic emission reduction equivalent (APeq) model were employed. The results reveal significant differences: Sintering machine desulfurization and denitrification (SDD) showed the highest APeq but increased CO2 emissions in 2023. Dust removal equipment upgrades (DRE) and unorganized emission control (UEC) demonstrated stable co-reduction effects. While electric furnace short-process steelmaking (ES) and hydrogen metallurgy (HM) showed limited current benefits they represent crucial deep decarbonization pathways. The framework provides multi-dimensional policy insights beyond simple ranking suggesting balancing short-term pollution control with long-term transition by prioritizing clean alternatives.
Renewable Energy Storage in a Poly-Generative System Fuel Cell/Electrolyzer, Supporting Green Mobility in a Residential Building
Oct 2025
Publication
The European Commission through the REPowerEU plan and the “Fit for 55” package aims to reduce fossil fuel dependence and greenhouse gas emissions by promoting electric and fuel cell hybrid electric vehicles (EV-FCHEVs). The transition to this mobility model requires energy systems that are able to provide both electricity and hydrogen while reducing the reliance of residential buildings on the national grid. This study analyses a poly-generative (PG) system composed of a Solid Oxide Fuel Cell (SOFC) fed by biomethane a Photovoltaic (PV) system and a Proton Exchange Membrane Electrolyser (PEME) with electric vehicles used as dynamic storage units. The assessment is based on simulation tools developed for the main components and applied to four representative seasonal days in Rende (Italy) considering different daily travel ranges of a 30-vehicle fleet. Results show that the PG system provides about 27 kW of electricity 14.6 kW of heat and 3.11 kg of hydrogen in winter spring and autumn and about 26 kW 14 kW and 3.11 kg in summer; it fully covers the building’s electrical demand in summer and hot water demand in all seasons. The integration of EV batteries reduces grid dependence improves renewable self-consumption and allows for the continuous and efficient operation of both the SOFC and PEME demonstrating the potential of the proposed system to support the green transition.
Review and Evaluation of Hydrogen and Air Heat Exchangers for Fuel Cell-Powered Electric Aircraft Propulsion
Mar 2025
Publication
Hydrogen fuel cell systems are a viable option for electrified aero engines due to their efficiency and environmental benefits. However integrating these systems presents challenges notably in terms of overall system weight and thermal management. Heat exchangers are crucial for the effective thermal management system of electric propulsion systems in commercial electrified aviation. This paper provides a comprehensive review of various heat exchanger types and evaluates their potential applications within these systems. Selection criteria are established based on the specific requirements for air and hydrogen heat exchangers in electrified aircraft. The study highlights the differences in weighting criteria for these two types of heat exchangers and applies a weighted point rating system to assess their performance. Results indicate that extended surface microchannel and printed circuit heat exchangers exhibit significant promise for aviation applications. The paper also identifies key design challenges and research needs particularly in enhancing net heat dissipation increasing compactness improving reliability and ensuring effective integration with aircraft systems.
Evaluating the Role of Hydrogen as an Energy Carrier: Perspectives on Low-Emission Applications
Oct 2025
Publication
Application of low-emission hydrogen production methods in the decarbonization process remains a highly relevant topic particularly in the context of sustainable hydrogen value chains. This study evaluates hydrogen applications beyond industry focusing on its role as an energy carrier and applying multi-criteria decision analysis (MCDA) to assess economics environmental impact efficiency and technological readiness. The analysis confirmed that hydrogen use for heating was the most competitive non-industrial application (ranking first in 66%) with favorable efficiency and costs. Power generation placed among the top two alternatives in 75% of cases. Transport end-use was less suitable due to compression requirements raising emissions to 272–371 g CO2/kg H2 and levelizing the cost of hydrogen (LCOH) to 13–17 EUR/kg. When H2 transport was included new pipelines and compressed H2 clearly outperformed other methods for short- and long-distances adding only 3.2–3.9% to overall LCOH. Sensitivity analysis confirmed that electricity price variations had a stronger influence on LCOH than capital expenditures. Comparing electrolysis technologies yielded that proton-exchange membrane and solid oxide reduced costs by 12–20% and CO2 emissions by 15–25% compared to alkaline. The study highlights heating end-use and compressed hydrogen and pipeline transport proving MCDA to be useful for selecting scalable pathways.
Levelised Cost of Hydrogen (LCOH) Calculator Manual - Update of the May 2024 Manual
May 2025
Publication
The LCOH calculator manual explains the methodology behind the calculator in detail and demonstrates how the calculator can be used.<br/>In this second version the default prices are updated based on the latest data available in the calculator and a new use case is introduced on changing the economic lifetime and cost of capital of an electrolysis installation.
Cruel Utopia of the Seas? Multiple Risks Challenge the Singular Hydrogen Hype in Finnish Maritime Logistics
Oct 2025
Publication
To address the global climate crisis maritime logistics are undergoing a transition away from fossil-based energy sources. The transition is envisaged to be both green (involving renewables) and digital (involving various kinds of digitalization). Much of the hope rests on the new hydrogen economy involving the build-up of infrastructure for hydrogen-derived alternative fuels such as methanol and ammonia. Indeed the new hydrogen economy is often portrayed as set to revolutionize maritime transport. The hope behind the hype reflects a belief in the performativity of hypes: some technological phenomenon will eventually materialise in innovation and business practices. In this paper we critically analyse the current hydrogen hype in the field of Finnish maritime logistics as a paradigmatic case of performative techno-optimism. Based on causal network analysis and thematic analysis of expert interviews and workshop data we argue that the phenomenon of performative techno-optimism is more nuanced than hitherto presented in the related literature. We showcase a variety of stances along a spectrum ranging from radical optimism to radical pessimism. Furthermore our causal network analysis indicates that the current green and digital transition of maritime transport is caught in a systemic catch-22: transitioning to alternative fuels in maritime logistics faces a lock-in of between overly cautious demand for alternative fuels leading to overly cautious investment in supply which only secures the modest demand. Finally our thematic analysis of techno-optimist stances suggests the following two major ways out of the systemic dilemma: large-scale technological innovations and global regulatory solutions.
Sorption-enhanced Steam Reforming Technology for Promoting Hydrogen Production with In-situ CO2 Capture: Recent Advances and Prospects
Aug 2025
Publication
Sorption-enhanced steam reforming (SorESR) is an advanced thermochemical process integrating in-situ CO2 capture via solid sorbents to significantly enhance hydrogen production and purity. By coupling CO2 adsorption with steam reforming SorESR shifts the reaction equilibrium toward increased H₂ yield surpassing the limitations of conventional steam reforming (SR). The efficacy of SorESR critically depends on the physicochemical properties of the solid CO2 sorbents employed. This review critically evaluates widely studied sorbents including Ca-based Mg-based hydrotalcite-like and alkali ceramic sorbents focusing on their CO2 capture capacity reaction kinetics thermal stability and cyclic durability under SR conditions. Furthermore recent progress in multifunctional sorbent-catalysts that synergistically facilitate catalytic steam reforming alongside CO2 sorption is critically discussed. Moreover the review summarises recent performance achievements and proposes strategies to improve sorbent capacity and reaction kinetics thereby making the SorESR process more appealing for commercial applications. Large-scale SorESR implementation is expected to substantially increase hydrogen production efficiency while concurrently reducing CO2 emissions and advancing sustainable energy technologies. This review offers novel insights into the development of advanced sorbent-catalyst systems and provides new strategies for enhancing SorESR efficiency and scalability for commercial H2 Production.
System Efficiency Analysis of Direct Coupled PV-PEM Electrolyzer Systems
Oct 2025
Publication
Green hydrogen is an important technology in the energy transition with potential to decarbonize industrial processes increase renewable energy use and reduce reliance on fossil fuels yet it currently accounts for less than 1% of global hydrogen demand. One promising approach to expand production is the direct coupling of photovoltaic–electrolyzer systems. In this study overall and sub-system efficiencies were analyzed for different system setups coupling points and operating conditions such as temperature and irradiance. The highest overall system efficiencies were found to be more than 18%. The effect of varying irradiances on the coupled efficiency was not more than 5.7%. Different system designs optimized for different irradiances led to effects such as an increase in current density at the electrolyzer and thus an increase in the overvoltage which resulted in an overall efficiency loss of more than 3%. A key finding was that aligning the PV maximum power point with the electrolyzer polarization curve enables consistently high system efficiencies across the investigated irradiances. The findings were validated with two real life systems reproducing the coupling efficiencies of the model with 12%–14% including loss factors and approximately 18% for a direct coupled system respectively
Vehicle Peak Power Management System: Design, Development, and Testing of a Fuel Cell and Supercapacitor Hybrid
Oct 2025
Publication
The passive combination of fuel cells and supercapacitors possesses promising applications in the automotive industry due to its ability to decrease stack size maintain peak power capacity improve system productivity and go away with the need for additional control all without Direct current to Direct Current (DC/DC) converters. This research describes the steps to create and evaluate a fuel cell (FC) and supercapacitor (SC) passive hybrid electrical system for a 60-V lightweight vehicle. Also study offers a thorough design approach and model and experimentally to validate every passive hybrid testing station component. When both concepts are stable the voltage errors are about 2 % and 3 % respectively for fuel cells and supercapacitors. The results of the experiments provide more evidence that the passive design is effective under step loads and driving cycles. The results of the measurements match the models used to simulate the passive hybrid system if a step load voltage is used. A smaller FC stack is possible since the fuel cell controls the steady-state current. Alternatively the supercapacitors provide varying currents because of their reduced resistance. This study use a driving cycle to show that the FC stack can lower its output to 25 % of the peak power required by the load.
Bipolar Electrolysis Cells with Hydride Ion-proton Conductor Heterejunctions
Oct 2025
Publication
Protonic solid oxide electrolysis cells are pivotal for environmentally sustainable hydrogen production via water splitting but suffer from efficiency losses due to partial hole conductivity. Here we introduce a device architecture based on a hydride-ion (H− )/proton (H+ ) bipolar electrolyte which exploits electrochemical rectification at a heteroionic interface to overcome this limitation. The perovskite-type BaZr0.5In0.5O2.75 electrolyte undergoes an in situ transformation under electrolysis conditions forming an H+ -conducting hydrate layer adjacent to the anode and an H− -conducting oxyhydride layer near the cathode governed by competitive thermodynamic equilibria of hydration and hydrogenation. This bipolar configuration enables high Faradaic currents through the superior H− ion conductivity of the oxyhydride phase stabilized by cathodic potentials while facilitating continuous H+ /H− interconversion at the interface. Furthermore electrochemical hydrogenation generates an electron-depleted interfacial layer that effectively suppresses hole conduction. Consequently the cells achieve efficiencies of ∼95% at 1.0 A cm− 2 surpassing conventional H+ unipolar designs.
Ultrasonic Time-of-flight Measurement of Hydrogen Blending Ratios for Industrial Combustion Applications
Oct 2025
Publication
Hydrogen blending offers significant potential for decarbonizing natural gas-based thermal processes particularly in the steel and cement sectors. Due to its distinct combustion properties compared to natural gas – such as lower minimum air requirements and altered flame speeds – the hydrogen fraction of the fuel must be monitored for combustion control. In this study we present an ultrasonic time-of-flight measurement system for hydrogen concentrations of 0–40% in natural gas. The system is verified with test gas mixtures at laboratory scale and validated in a technical-scale setup using a real blower burner (< 60 kW). We evaluate uncertainty of the hydrogen fraction measurement and analyze the influence of varying natural gas compositions. We show that standard uncertainties below 4% can be achieved without knowledge of the specific natural gas composition. Our results provide insights for measurement system design and support the safe application of hydrogen in thermal systems for industrial processes.
Hydrogen Valleys to Foster Local Decarbonisation Targets: A Multiobjective Optimisation Approach for Energy Planning
Oct 2025
Publication
Hydrogen Valley represents localised ecosystems that enable the integrated production storage distribution and utilisation of hydrogen to support the decarbonisation of the energy system. However planning such integrated systems necessitates a detailed evaluation of their interconnections with variable renewable generation sector coupling and system flexibility. The novelty of this work lies in addressing a critical gap in system-level modelling for Hydrogen Valleys by introducing an optimization-based framework to determine their optimal configuration. This study focuses on the scenario-based multiobjective design of local hydrogen energy systems considering renewable integration infrastructure deployment and sector coupling. We developed and simulated three scenarios based on varying hydrogen pathways and penetration levels using the EnergyPLAN model implemented through a custom MATLAB Toolbox. Several decision variables such as renewable energy capacity electrolyser size and hydrogen storage were optimised to minimise CO₂ emissions total annual system cost and critical excess electricity production simultaneously. The findings show that Hydrogen Valley deployment can reduce CO₂ emissions by up to 30 % triple renewable penetration in the primary energy supply and lower the levelized cost of hydrogen from 7.6 €/kg to 5.6 €/kg despite a moderate increase in the total cost of the system. The approach highlights the potential of sector coupling and Power-to-X technologies in enhancing system flexibility and supporting green hydrogen integration. The outcome of our research offers valuable insights for policymakers and planners seeking to align local hydrogen strategies with broader decarbonisation targets and regulatory frameworks.
Proposal for an Energy Efficiency Index for Green Hydrogen Production—An Integrated Approach
Jun 2025
Publication
In the context of mounting concerns over carbon emissions and the need to accelerate the energy transition green hydrogen has emerged as a strategic solution for decarbonizing hard-to-abate sectors. This paper introduces a methodological innovation by proposing the Green Hydrogen Efficiency Index (GHEI) a unified and quantitative framework that integrates multiple stages of the hydrogen value chain into a single comparative metric. The index encompasses six core criteria: electricity source water treatment electrolysis efficiency compression end-use conversion and associated greenhouse gas emissions. Each are normalized and weighted to reflect different performance priorities. Two weighting profiles are adopted: a first profile which assigns equal importance to all criteria referred to as the balanced profile and a second profile derived using the analytic hierarchy process (AHP) based on structured expert judgment named the AHP profile. The methodology was developed through a systematic literature review and was applied to four representative case studies sourced from the academic literature covering diverse configurations and geographies. The results demonstrate the GHEI’s capacity to distinguish the energy performance of different green hydrogen routes and support strategic decisions related to technology selection site planning and logistics optimization. The results highlight the potential of the index to contribute to more sustainable hydrogen value chains and advance decarbonization goals by identifying pathways that minimize energy losses and maximize system efficiency
Prioritization of the Critical Factors of Hydrogen Transportation in Canada Using the Intuitionistic Fuzzy AHP Method
Jun 2025
Publication
Hydrogen is a potential source of imminent clean energy in the future with its transportation playing a crucial role in allowing large-scale deployment. The challenge lies in selecting an effective sustainable and scalable transportation alternative. This study develops a multi-criteria decision-making (MCDM) framework based on the intuitionistic fuzzy analytic hierarchy process (IF-AHP) to evaluate land-based hydrogen transportation alternatives across Canada. The framework includes uncertainty and decision-maker hesitation through the application of triangular intuitionistic fuzzy numbers (TIFNs). Seven factors their subsequent thirty-three subfactors and three alternatives to hydrogen transportation were identified through a literature review. Pairwise comparison was aggregated among factors subfactors and alternatives from three decision makers using an intuitionistic fuzzy weighted average and priority weights were computed using entropy-based weight. The results show that safety and economic efficiency emerged as the most influential factors in the evaluation of hydrogen transportation alternatives followed by environmental impact security and social impact and public health in ascending order. Among the alternatives tube truck transport obtained the highest overall weight (0.3551) followed by pipelines (0.3272) and rail lines (0.3251). The findings suggest that the tube ruck is currently the most feasible transport option for land-based hydrogen distribution that aims to provide a transition of Canada’s energy mix.
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