Publications
Multi-Objective Optimization for Solar-Hydrogen-Battery-Integrated Electric Vehicle Charging Stations with Energy Exchange
Oct 2023
Publication
The importance of electric vehicle charging stations (EVCS) is increasing as electric vehicles (EV) become more widely used. EVCS with multiple low-carbon energy sources can promote sustainable energy development. This paper presents an optimization methodology for direct energy exchange between multi-geographic dispersed EVCSs in London UK. The charging stations (CSs) incorporate solar panels hydrogen battery energy storage systems and grids to support their operations. EVs are used to allow the energy exchange of charging stations. The objective function of the solar-hydrogen-battery storage electric vehicle charging station (SHS-EVCS) includes the minimization of both capital and operation and maintenance (O&M) costs as well as the reduction in greenhouse gas emissions. The system constraints encompass the power output limits of individual components and the need to maintain a power balance between the SHS-EVCSs and the EV charging demand. To evaluate and compare the proposed SHS-EVCSs two multi-objective optimization algorithms namely the Non-dominated Sorting Genetic Algorithm (NSGA-II) and the Multi-objective Evolutionary Algorithm Based on Decomposition (MOEA/D) are employed. The findings indicate that NSGA-II outperforms MOEA/D in terms of achieving higher-quality solutions. During the optimization process various factors are considered including the sizing of solar panels and hydrogen storage tanks the capacity of electric vehicle chargers and the volume of energy exchanged between the two stations. The application of the optimized SHS-EVCSs results in substantial cost savings thereby emphasizing the practical benefits of the proposed approach.
Underground Hydrogen Storage: Integrated Surface Facilities and Fluid Flow Modelling for Depleted Gas Reservoirs
Aug 2023
Publication
We report a new techno-economic model to assess performance and capital costs for large-scale underground hydrogen storage in depleted gas reservoirs. A simulation toolbox is developed to model surface facilities and to simulate the hydrogen flow in geological formations in an integrated fashion.<br/>Integrated modelling revealed the following key insights: 1) A buffer system is highly desirable to absorb inherent variability in upstream hydrogen production; 2) hydrogen mixing with existing gases in the reservoir together with gravity segregation and diffusion results in a decline in hydrogen purity at the wellhead over time and can require increased purification; 3) the capital cost is dominated by the cost of cushion gas (hydrogen) and the compression system where about 9% of the total energy content of the hydrogen is consumed for compression. The scenarios modelled in our study result in a levelized cost of storage in Australia ranging from 2.3 to 4.29 A$/(kg).
Critical and Strategic Materials for Electrolysers, Fuel Cells, Metal Hydrides and Hydrogen Seperation Technologies
May 2024
Publication
This paper provides an in-depth examination of critical and strategic raw materials (CRMs) and their crucial role in the development of electrolyzer and fuel cell technologies within the hydrogen economy. It methodically analyses a range of electrolyzer technologies including alkaline proton-exchange membrane solid-oxide anion-exchange membrane and proton-conducting ceramic systems. Each technology is examined for its specific CRM dependencies operational characteristics and the challenges associated with CRM availability and sustainability. The study further extends to hydrogen storage and separation technologies focusing on the materials employed in high-pressure cylinders metal hydrides and hydrogen separation processes and their CRM implications. A key aspect of this paper is its exploration of the supply and demand dynamics of CRMs offering a comprehensive view that encompasses both the present sttate and future projections. The aim is to uncover potential supply risks understand strategies and identify potential bottlenecks for materials involved in electrolyzer and fuel cell technologies addressing both current needs and future demands as well as supply. This approach is essential for the strategic planning and sustainable development of the hydrogen sector emphasizing the importance of CRMs in achieving expanded electrolyzer capacity leading up to 2050.
The Future European Hydrogen Market: Market Design and Policy Recommendations to Support Market Development and Commodity Trading
May 2024
Publication
A key building block of the European Green Deal is the development of a hydrogen commodity market which requires a suitable hydrogen market design and the timely introduction of related policy measures. Using exploratory interviews with five expert groups we contribute to this novel research field by outlining the core market design criteria and proposing suitable regulations for the future European hydrogen market. We identify detailed recommendations along three core market design focus areas: Market development policy measures infrastructure regulations as well as hydrogen and certificate trading. Our findings provide an across-industry view of current policy-related key challenges in the hydrogen commodity market development and mitigation approaches. We therefore support policymakers within the EU in the ongoing detailing of their regulatory hydrogen and green energy packages. Further we promote hydrogen market development by assisting current and future industry players in finding a common understanding of the future hydrogen market design.
Hydrogenerally - Episode 9: Nuclear Hydrogen
Jan 2023
Publication
In this episode of the podcast Debra Jones Chemistry Knowledge Transfer Manager and Ray Chegwin Nuclear Knowledge Transfer Manager from Innovate UK KTN talk about nuclear uses for hydrogen with special guest Allan Simpson Technical Lead at the National Nuclear Laboratory.
The podcast can be found on their website.
The podcast can be found on their website.
Processes Supervision System for Green Hydrogen Production: Experimental Characterization and Data Acquisition of PEM Electrolyzer
May 2022
Publication
Green hydrogen is the term used to reflect the fact that hydrogen is generated from renewable energies. This process is commonly performed by means of water electrolysis decomposing water molecules into oxygen and hydrogen in a zero emissions process. Proton exchange membrane (PEM) electrolyzers are applied for such a purpose. These devices are complex systems with nonlinear behavior which impose the measurement and control of several magnitudes for an effective and safe operation. In this context the modern paradigm of Digital Twin (DT) is applied to represent and even predict the electrolyzer behavior under different operating conditions. To build this cyber replica a paramount previous stage consists of characterizing the device by means of the curves that relate current voltage and hydrogen flow. To this aim this paper presents a processes supervision system focused on the characterization of a experimental PEM electrolyzer. This device is integrated in a microgrid for production of green hydrogen using photovoltaic energy. Three main functions must be performed by the supervision system: measurement of the process magnitudes data acquisition and storage and real-time visualization. To accomplish these tasks firstly a set of sensors measure the process variables. In second place a programmable logic controller is responsible of acquiring the signals provided by the sensors. Finally LabVIEW implements the user interface as well as data storage functions. The process evolution is observed in real-time through the user interface composed by graphical charts and numeric indicators. The deployed process supervision system is reported together with experimental results to prove its suitability.
Optimal Design and Sizing of Hybrid Photovoltaic/Fuel Cell Electrical Power System
Aug 2023
Publication
Renewable energy solutions play a crucial role in addressing the growing energy demands while mitigating environmental concerns. This study examines the techno-economic viability and sensitivity of utilizing solar photovoltaic/polymer electrolyte membrane (PEM) fuel cells (FCs) to meet specific power demands in NEOM Saudi Arabia. The novelty of this study lies in its innovative approach to analyzing and optimizing PV/PEMFC systems aiming to highlight their economic feasibility and promote sustainable development in the region. The analysis focuses on determining the optimal size of the PV/PEMFC system based on two critical criteria: minimum cost of energy (COE) and minimum net present cost (NPC). The study considers PEMFCs with power ratings of 30 kW 40 kW and 50 kW along with four PV panel options: Jinko Solar Powerwave Tindo Karra and Trina Solar. The outcomes show that the 30 kW PEMFC and the 201 kW Trina Solar TSM-430NEG9R.28 are the most favorable choices for the case study. Under these optimal conditions the study reveals the lowest values for NPC at USD 703194 and COE at USD 0.498 per kilowatt-hour. The levelized cost of hydrogen falls within the range of USD 15.9 to 23.4 per kilogram. Furthermore replacing the 30 kW Trina solar panel with a 50 kW Tindo PV module results in a cost reduction of 32%. The findings emphasize the criticality of choosing optimal system configurations to attain favorable economic outcomes thereby facilitating the adoption and utilization of renewable energy sources in the region. In conclusion this study stands out for its pioneering and thorough analysis and optimization of PV/PEMFC systems providing valuable insights for sustainable energy planning in NEOM Saudi Arabia.
Techno-economic Analysis of Large-scale Green Hydrogen Production and Storage
Jun 2023
Publication
Producing clean energy and minimising energy waste are essential to achieve the United Nations sustainable development goals such as Sustainable Development Goal 7 and 13. This research analyses the techno-economic potential of waste heat recovery from multi-MW scale green hydrogen production. A 10 MW proton exchange membrane electrolysis process is modelled with a heat recovery system coupled with an organic Rankine cycle (ORC) to drive the mechanical compression of hydrogen. The technical results demonstrate that when implementing waste heat recovery coupled with an ORC the first-law efficiency of electrolyser increases from 71.4% to 98%. The ORC can generate sufficient power to drive the hydrogen's compression from the outlet pressure at the electrolyser 30 bar up to 200 bar. An economic analysis is conducted to calculate the levelised cost of hydrogen (LCOH) of system and assess the feasibility of implementing waste heat recovery coupled with ORC. The results reveal that electricity prices dominate the LCOH. When electricity prices are low (e.g. dedicated offshore wind electricity) the LCOH is higher when implementing heat recovery. The additional capital expenditure and operating expenditure associated with the ORC increases the LCOH and these additional costs outweigh the savings generated by not purchasing electricity for compression. On the other hand heat recovery and ORC become attractive and feasible when grid electricity prices are higher.
Industrial Development Status and Prospects of the Marine Fuel Cell: A Review
Jan 2023
Publication
In the context of the increasingly strict pollutant emission regulations and carbon emission reduction targets proposed by the International Maritime Organization the shipping industry is seeking new types of marine power plants with the advantages of high efficiency and low emissions. Among the possible alternatives the fuel cell is considered to be the most practical technology as it provides an efficient means to generate electricity with low pollutant emissions and carbon emissions. Very few comprehensive reviews focus on the maritime applications of the fuel cell. Thus news reports and literature on the maritime applications of the fuel cell in the past sixty years were collected and the industrial development status and prospects of the marine fuel cell were summarized as follows. Some countries in Europe North America and Asia have invested heavily in researching and developing the marine fuel cell and a series of research projects have achieved concrete results such as the industrialized marine fuel cell system or practical demonstration applications. At present the worldwide research of the marine fuel cell focuses more on the proton exchange membrane fuel cell (PEMFC). However the power demand of the marine fuel cell in the future will show steady growth and thus the solid oxide fuel cell (SOFC) with the advantages of higher power and fuel diversity will be the mainstream in the next research stage. Although some challenges exist the SOFC can certainly lead the upgrading and updating of the marine power system with the cooperative efforts of the whole world.
Refuelling Tests of a Hydrogen Tank for Heavy-duty Applications
Sep 2023
Publication
A transition towards zero-emission fuels is required in the mobility sector in order to reach the climate goals. Here (green) renewable hydrogen for use in fuel cells will play an important role especially for heavy duty applications such as trucks. However there are still challenges to overcome regarding efficient storage infrastructure integration and optimization of the refuelling process. A key aspect is to reduce the refuelling duration as much as possible while staying below the maximum allowed temperature of 85 C. Experimental tests for the refuelling of a 320 l type III tank were conducted at different operating conditions and the tank gas temperature measured at the front and back ends. The results indicate a strongly inhomogeneous temperature field where measuring and verifying the actual maximum temperatures proves difficult. Furthermore a simulation approach is provided to calculate the average tank gas temperature at the end of the refuelling process.
Low-carbon Development for the Iron and Steel Industry in China and the World: Status Quo, Future Vision, and Key Actions
Nov 2021
Publication
The low-carbon development of China’s iron and steel industry (ISI) is important but challenging work for the attainment of China’s carbon neutrality by 2060. However most previous studies related to the low-carbon development of China’s ISI are fragmented from different views such as production-side mitigation demand-side mitigation or mitigation technologies. Additionally there is still a lack of a comprehensive overview of the long-term pathway to the low-carbon development of China’s ISI. To respond to this gap and to contribute to better guide policymaking in China this paper conducted a timely and comprehensive review following the technology roadmap framework covering the status quo future vision and key actions of the low-carbon development of the world and China’s ISI. First this paper provides an overview of the technology roadmap of low-carbon development around the main steel production countries in the world. Second the potential for key decarbonization actions available for China’s ISI are evaluated in detail. Third policy and research recommendations are put forward for the future low-carbon development of China’s ISI. Through this comprehensive review four key actions can be applied to the low-carbon development of China’s ISI: improving energy efficiency shifting to Scrap/EAF route promoting material efficiency strategy and deploying radical innovation technologies.
Techno-economic Investigation of Hybrid Peaker Plant and Hydrogen Refuelling Station
Sep 2023
Publication
The power and transport sectors are responsible for significant emissions of greenhouse gases. Therefore it is imperative that substantial efforts are directed towards the decarbonisation of these industries. This study establishes a combined-solar-wind system's economic and technical practicality for producing hydrogen for an onsite hydrogen refuelling station (HRS) and electricity to meet peak demand. To minimise the levelised cost of electricity and maximise the system's reliability at different commercial locations in South Africa the dual-objective optimisation sizing is carried out using Mixed Integer Quadratic Constrained Programming (MICQP) model and was executed with an Advanced Multi-dimensional Modelling System (AIMMS) [61] [62]. The levelised costs of electricity and hydrogen at Johannesburg Pretoria and Cape Town for 2 MW grid export benchmark are 74.2 $/MWh/5.85 $/kg 76.3 $/MWh/5.97 $/kg and 50 $/MWh/4.45 $/kg respectively. The CO₂ equivalent emissions (tonnes) are 54000 55800 59000 and the corresponding carbon taxes ($) avoided for the locations are 432100 446200 and 472000 for Johannesburg Pretoria and Cape Town respectively. The results of the framework show that it can be adopted as a viable and fossil-free replacement for conventional peaking generators.
Design of Hydrogen Production Systems Powered by Solar and Wind Energy: An Insight into the Optimal Size Ratios
Jun 2024
Publication
Green hydrogen is expected to play a crucial role in the future energy landscape particularly in the pursuit of deep decarbonisation strategies within hard-to-abate sectors such as the chemical and steel industries and heavy-duty transport. However competitive production costs are vital to unlock the full potential of green hydrogen. In the case of green hydrogen produced via water electrolysis powered by fluctuating renewable energy sources the design of the plant plays a pivotal role in achieving market-competitive production costs. The present work investigates the optimal design of power-to-hydrogen systems powered by renewable sources (solar and wind energy). A detailed model of a power-to-hydrogen system is developed: an energy simulation framework coupled with an economic assessment provides the hydrogen production cost as a function of the component sizes. By spanning a wide range of size ratios namely the ratio between the size of the renewable generator and the size of the electrolyser the cost-optimal design point (minimum hydrogen production cost) is identified. This investigation is carried out for three plant configurations: solar-only wind-only and hybrid. The objective is to extend beyond the analysis of a specific case study and provide broadly applicable considerations for the optimal design of green hydrogen production systems. In particular the rationale behind the cost-optimal size ratio is unveiled and discussed through energy (utilisation factors) and economic (hydrogen production cost) indicators. A sensitivity analysis on investment costs for the power-to-hydrogen technologies is also conducted to explore various technological learning paths from today to 2050. The optimal size ratio is found to be a trade-off between the utilisation factors of the electrolyser and the renewable generator which exhibit opposite trends. Moreover the costs of the power-to-hydrogen technologies are a key factor in determining the optimal size ratio: depending on these costs the optimal solution tends to improve one of the two utilization factors at the expense of the other. Finally the optimal size ratio is foreseen to decrease in the upcoming years primarily due to the reduction in the investment cost of the electrolyser.
Design of a Hydrogen Aircraft for Zero Persistent Contrails
Jul 2023
Publication
Contrails are responsible for a significant proportion of aviation’s climate impact. This paper uses data from the European Centre for Medium-Range Weather Forecasts to identify the altitudes and latitudes where formed contrails will not persist. This reveals that long-lived contrails may be prevented by flying lower in equatorial regions and higher in non-equatorial regions. Subsequently it is found that the lighter fuel and reduced seating capacity of hydrogen-powered aircraft lead to a reduced aircraft weight which increases the optimal operating altitude by about 2 km. In non-equatorial regions this would lift the aircraft’s cruise point into the region where long-lived contrails do not persist unlocking hydrogen-powered low-contrails operation. The baseline aircraft considered is an A320 retrofitted with in-fuselage hydrogen tanks. The impacts of the higher-altitude cruise on fuel burn and the benefits unlocked by optimizing the wing geometry for this altitude are estimated using a drag model based on theory proposed by Cavcar Lock and Mason and verified against existing aircraft. The weight penalty associated with optimizing wing geometry for this altitude is estimated using Torenbeek’s correlation. It is found that thinner wings with higher aspect ratios are particularly suited to this high-altitude operation and are enabled by the relaxation of the requirement to store fuel in the wings. An example aircraft design for the non-equatorial region is provided which cruises at a 14 km altitude at Mach 0.75 with a less than 1% average probability of generating long-lived contrails when operating at latitudes more than 35◦ from the equator. Compared to the A320 this concept design is estimated to have a 20% greater cruise lift–drag ratio due to the 33% thinner wings with a 50% larger aspect ratio enabling just 5% more energy use per passenger-km despite fitting 40% fewer seats.
UK HSE Hydrogen for Heating Evidence Review Process
Sep 2023
Publication
As part of the UK Government’s Net Zero targets to tackle Climate Change the Health and Safety Executive (HSE) aims to reach an authoritative view on the safety of using 100% hydrogen for heating across the UK to feed into Government policy decisions by the mid-2020s. This paper describes the background and process of a programme of work led by HSE in support of the Department for Energy Security and Net Zero (formerly BEIS) that will inform strategic policy decisions by 2026. The strategic framework of HSE’s programme of work was defined between BEIS and HSE. HSE’s programme of work follows on from a previous project which engaged with HSE policy regulatory and scientific colleagues working with industry stakeholders identifying knowledge gaps for the safe distribution storage and use of hydrogen gas in domestic industrial and commercial premises. These knowledge gaps were subsequently used in discussions with stakeholders to prioritise research projects and evidence gathering exercises. To review this scientific evidence HSE developed a review framework and convened Evidence Review Groups (ERGs) to cover all evidence areas encompassing topics such as quantified risk assessment material compatibility and operational procedures. These ERGs include representation from relevant divisions across HSE (policy regulation and science). The paper explains the structure of HSE’s input into the hydrogen for heating programme the ERG process and timelines along with the proposed outputs. Additional activities have been undertaken by HSE within the programme to highlight specific issues in support of the review process which will also be discussed.
Exploring Hydrogen Embrittlement: Mechanisms, Consequences, and Advances in Metal Science
Jun 2024
Publication
Hydrogen embrittlement (HE) remains a pressing issue in materials science and engineering given its significant impact on the structural integrity of metals and alloys. This exhaustive review aims to thoroughly examine HE covering a range of aspects that collectively enhance our understanding of this intricate phenomenon. It proceeds to investigate the varied effects of hydrogen on metals illustrating its ability to profoundly alter mechanical properties thereby increasing vulnerability to fractures and failures. A crucial section of the review delves into how different metals and their alloys exhibit unique responses to hydrogen exposure shedding light on their distinct behaviors. This knowledge is essential for customizing materials to specific applications and ensuring structural dependability. Additionally the paper explores a diverse array of models and classifications of HE offering a structured framework for comprehending its complexities. These models play a crucial role in forecasting preventing and mitigating HE across various domains ranging from industrial settings to critical infrastructure.
Hydrogen–Natural Gas Mix—A Viable Perspective for Environment and Society
Aug 2023
Publication
The increase in demand and thus the need to lower its price has kept C-based fuels as the main source. In this context the use of oil and gas has led to increased climate change resulting in greenhouse gases. The high percentage of emissions over 40% is due to the production of electricity heat or/and energy transport. This is the main reason for global warming and the extreme and increasingly common climate change occurrences with all of nature being affected. Due to this reason in more and more countries there is an increased interest in renewable energies from sustainable sources with a particular emphasis on decarbonisation. One of the energies analysed for decarbonisation that will play a role in future energy systems is hydrogen. The development of hydrogen–natural gas mixtures is a major challenge in the field of energy and fuel technology. This article aims to highlight the major challenges associated with researching hydrogen–natural gas blends. Meeting this challenge requires a comprehensive research and development effort including exploring appropriate blending techniques optimising performance addressing infrastructure requirements and considering regulatory considerations. Overcoming this challenge will enable the full potential of hydrogen–natural gas blends to be realised as a clean and sustainable energy source. This will contribute to the global transition to a greener and more sustainable future. Several international European and Romanian studies projects and legislative problems are being analysed. The mix between H2 and natural gas decreases fugitive emissions. In contrast using hydrogen increases the risk of fire more than using natural gas because hydrogen is a light gas that easily escapes and ignites at almost any concentration in the air.
Modelling Large-scale Hydrogen Uptake in the Mexican Refinery and Power Sectors
Sep 2023
Publication
Due to the emissions reduction commitments that Mexico compromised in the Paris Agreement several clean fuel and renewable energy technologies need to penetrate the market to accomplish the environmental goals. Therefore there is a need to develop achievable and realistic policies for such technologies to ease the decision-making on national energy strategies. Several countries are starting to develop large-scale green hydrogen production projects to reduce the carbon footprint of the multiple sectors within the country. The conversion sectors namely power and refinery are fundamental sectors to decarbonise due to their energy supply role. Nowadays the highest energy consumables of the country are hydrocarbons (more than 90%) causing a particular challenge for deep decarbonisation. The purpose of this study is to use a multi-regional energy system model of Mexico to analyse a decarbonisation scenario in line with the latest National Energy System Development Program. Results show that if the country wants to succeed in reducing 22% of its GHG emissions and 51% of its short-lived climate pollutants emissions green hydrogen could play a role in power generation in regions with higher energy demand growth rates. These results show regarding the power sector that H2 could represent 13.8 GW or 5.1% of the total installed capacity by 2050 while for the refinery sector H2 could reach a capacity of 157 PJ/y which is around 31.8% of the total share and it is mainly driven by the increasing demands of the transport industry and power sectors. Nevertheless as oil would still represent the largest energy commodity CCS technologies would have to be deployed for new and retrofitted refinery facilities.
The Hydrogen Economy can Reduce Costs of Climate Change Mitigation by up to 22%
May 2024
Publication
In response to the urgent need to mitigate climate change via net-zero targets many nations are renewing their interest in clean hydrogen as a net-zero energy carrier. Although clean hydrogen can be directly used in various sectors for deep decarbonization the relatively low energy density and high production costs have raised doubts as to whether clean hydrogen development is worthwhile. Here we improve on the GCAM model by including a more comprehensive and detailed representation of clean hydrogen production distribution and demand in all sectors of the global economy and simulate 25 scenarios to explore the costeffectiveness of integrating clean hydrogen into the global energy system. We show that due to costly technical obstacles clean hydrogen can only provide 3%–9% of the 2050 global final energy use. Nevertheless clean hydrogen deployment can reduce overall energy decarbonization costs by 15%–22% mainly via powering ‘‘hard-to-electrify’’ sectors that would otherwise face high decarbonization expenditures. Our work provides practical references for cost-effective clean hydrogen planning.
Sonochemical and Sonoelectrochemical Production of Hydrogen
Aug 2018
Publication
Reserves of fossil fuels such as coal oil and natural gas on earth are finite. The continuous use and burning of these fossil fuel resources in the industrial domestic and transport sectors has resulted in the extremely high emission of greenhouse gases GHGs (e.g. CO2) and solid particulates into the atmosphere. Therefore it is necessary to explore pollution free and more efficient energy sources in order to replace depleting fossil fuels. The use of hydrogen (H2) as an alternative fuel source is particularly attractive due to its very high specific energy compared to other conventional fuels and its zero GHG emission when used in a fuel cell. Hydrogen can be produced through various process technologies such as thermal electrolytic photolytic and biological processes. Thermal processes include gas reforming renewable liquid and biooil processing biomass and coal gasification; however these processes release a huge amount of greenhouse gases. Production of electrolytic hydrogen from water is an attractive method to produce clean hydrogen. It could even be a more promising technology when combining water electrolysis with power ultrasound to produce hydrogen efficiently where sonication enhances the electrolytic process in several ways such as enhanced mass transfer removal of hydrogen and oxygen (O2) gas bubbles and activation of the electrode surface. In this review production of hydrogen through sonochemical and sonoelectrochemical methods along with a brief description of current hydrogen production methods and power ultrasound are discussed.
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