Publications

Hydrogen’s wide availability and versatile production methods establish it as a primary green energy source driving substantial interest among the public industry and governments due to its future fuel potential. Notable investment is directed toward hydrogen research and material innovation for transmission storage fuel cells and sensors. Ensuring safe and dependable hydrogen facilities is paramount given the challenges in accident control. Addressing material compatibility issues within hydrogen systems remains a critical focus. Challenges roadmaps and scenarios steer long-term planning and technology outlooks. Strategic visions align actions and policies encompassing societal and ecological dimensions. The confluence of hydrogen’s promise with material progress holds the prospect of reshaping our energy landscape sustainably. Forming collective future perspectives to foresee this emerging technology’s potential benefits is valuable. Our review article comprehensively explores the forthcoming challenges in hydrogen technology. We extensively examine the challenges and opportunities associated with hydrogen production incorporating CO2 capture technology. Furthermore the interaction of materials and composites with hydrogen particularly in the context of hydrogen transmission pipeline and infrastructure are discussed to understand the interplay between materials and hydrogen dynamics. Additionally the exploration extends to the embrittlement phenomena during storage and transmission coupled with a comprehensive examination of the advancements and hurdles intrinsic to hydrogen fuel cells. Finally our exploration encompasses addressing hydrogen safety from an industrial perspective. By illuminating these dimensions our article provides a panoramic view of the evolving hydrogen landscape.

The intermittency of renewable energy sources necessitates energy storage to meet the full demand and balancing requirements of the grid. Green hydrogen (H2) is a chemical energy carrier that can be used in a flexible manner and store large amounts of energy for long periods of time. This techno-economic analysis investigates H2 production from wind using commercially available desalination and electrolysis units. Proton exchange membrane and alkaline electrolyser units are utilised and compared. The intermittency of wind is examined with comparison against grid-bought electricity. A model is developed to determine the selling price required to ensure profitability over a 10-year period. Firstly where H2 is produced using energy from the grid with electricity purchased when below a specified price point or between specified hours. In the second scenario a wind turbine is owned by the user and the electricity price is not considered while the turbine capital expenditure is. The price of H2 production from wind is found to be comparable with natural gas derived H2 at a larger scale with a minimum selling price calculated to be 4.85 £/kg at a setpoint of 500 kg of H2/hr. At a setpoint of 50 kg of H2/hr this is significantly higher at 12.10 £/kg. In both cases the alkaline electrolyser produced cheaper H2. This study demonstrates an economy of scale with H2 prices decreasing with increased scale. H2 prices are also closely linked to the capital expenditure with the equipment size space and safety identified as limiting factors.

In a future energy generation market the storage of energy is going to become increasingly important. Besides classic ways of storage like pumped storage hydro power stations etc the production of hydrogen will play an important role as an energy storage system. Hydrogen may be stored as a liquefied gas (LH2) on a long term base as well as for short term supply of fuel stations to ensure a so called “green” mobility. The handling with LH2 has been subject to several recent safety studies. In this context reliable simulation tools are necessary to predict the spill and spreading of LH2 during an accidental release. This paper deals with the different boiling regimes: film boiling transition boiling and nucleation boiling after a release and their modeling by means of an inhouse-code for wall evaporation which is implemented in the commercial CFD code ANSYS CFX. The paper will describe the model its implementation and validation against experimental data such as the HSL LH2 spill experiments.

Recent targets have increased pressure for the maritime sector to accelerate the uptake of clean fuels. A potential future fuel for shipping is hydrogen however there is a common perception that the volume requirements for this fuel are too large for deep sea shipping. This study has developed a range of techniques to accurately simulate the fuel requirements of hydrogen for a case study vessel. Hydrogen can use fuel cells which achieve higher efficiencies than combustion methods but may require a battery hybrid system to meet changes in demand. A series of novel models for different fuel cell types and other technologies have been developed. The models have been used to run dynamic simulations for different energy system setups. Simulations tested against power profiles from real-world shipping data to establish the minimum viable setup capable of meeting all the power demand for the case study vessel to a higher degree of accuracy than previously achieved. Results showed that the minimum viable setup for hydrogen was with liquid storage a 105.6 MW PEM fuel cell stack and 6.9 MWh of batteries resulting in a total system size of 8934 m3 . Volume requirement results could then be compared to other concepts such as systems using ammonia and methanol 8970 m3 and 6033 m3 respectively.

This paper aims to provide a holistic analysis of the role of hydrogen for achieving greenhouse gas neutrality in Germany. For that purpose we apply an integrated energy system model which includes all demand sectors of the German energy system and optimizes the transformation pathway from today's energy system to a future cost-optimal energy system. We show that 412 TWh of hydrogen are needed in the year 2045 mostly in the industry and transport sector. Particularly the use of about 267 TWh of hydrogen in industry is essential as there are no cost-effective alternatives for the required emission reduction in the chemical industry or in steel production. Furthermore we illustrate that the German hydrogen supply in the year 2045 requires both an expansion of domestic electrolyzer capacity to 71 GWH2 and hydrogen imports from other European countries and Northern Africa of about 196 TWh. Moreover flexible operation of electrolyzers is cost-optimal and crucial for balancing the intermittent nature of volatile renewable energy sources. Additionally a conducted sensitivity analysis shows that full domestic hydrogen supply in Germany is possible but requires an electrolyzer capacity of 111 GWH2.

The HyDeploy project seeks to address a key issue for UK customers and UK energy policy makers: how to reduce the carbon emitted from heating homes. The UK has a world class gas distribution grid delivering heat conveniently and safely to over 83% of homes. Emissions can be reduced by lowering the carbon content of gas through blending with hydrogen. This delivers carbon savings without customers requiring disruptive and expensive changes in their homes. It also provides the platform for deeper carbon savings by enabling wider adoption of hydrogen across the energy system. HyDeploy has previously delivered a successful trial demonstrations of repurposing existing UK distribution gas networks (Keele University) to operate on a blend of natural gas and hydrogen (up to 20% mol/mol) showing that carbon savings can be made through the gas networks today whilst continuing to meet the needs of gas consumers without introducing any disruptions.<br/>The ultimate objective of the HyDeploy programme is to see the roll-out of hydrogen blends across the GB gas distribution network unlocking 35 TWh pa of low carbon heat - the equivalent of removing 2.5 million fossil-fuelled cars off the roads. To achieve this the next phase of the programme is to address the remaining evidence gaps that had not been covered by the trial demonstration programmes.<br/>The demonstrations have focussed on the low and medium pressure tiers of the gas distribution network (i.e. injecting into a 2 bar gauge pressure network and distributing the blended gas down to the low pressure network and into people’s homes and commercial buildings and businesses) and predominantly serving domestic appliances.<br/>The remainder of the HyDeploy2 programme will generate an evidence base for GB’s gas distribution network which includes demonstrating the suitability of using hydrogen blended gas in the fields of industrial and commercial users and the performance of materials assets and procedures on the higher pressure tiers (i.e. 7 bar gauge operation and above).<br/>This report captures the details of the Winlaton trial and provides a future look to how the UK can transition from successful hydrogen blending trials to roll-out.

The article reviews gas turbine combustion technologies focusing on their current ability to operate with hydrogen enriched natural gas up to 100% H2. The aim is to provide a picture of the most promising fuel-flexible and clean combustion technologies the object of current research and development. The use of hydrogen in the gas turbine power generation sector is initially motivated highlighting both its decarbonisation and electric grid stability objectives; moreover the state-of-the-art of hydrogen-blend gas turbines and their 2024 and 2030 targets are reported in terms of some key performance indicators. Then the changes in combustion characteristics due to the hydrogen enrichment of natural gas blends are briefly described from their enhanced reactivity to their pollutant emissions. Finally gas turbine combustion strategies both already commercially available (mostly based on aerodynamic flame stabilisation self-ignition and staging) or still under development (like the micro-mixing and the exhaust gas recirculation concepts) are described.

The integration of an increasing share of Renewable Energy Sources (RES) requires the availability of suitable energy storage systems to improve the grid flexibility and Compressed Air Energy Storage (CAES) systems could be a promising option. In this study a CO2 -free Diabatic CAES system is proposed and analyzed. The plant configuration is derived from a down-scaled version of the McIntosh Diabatic CAES plant where the natural gas is replaced with green hydrogen produced on site by a Proton Exchange Membrane electrolyzer powered by a photovoltaic power plant. In this study the components of the hydrogen production system are sized to maximize the self-consumption share of PV energy generation and the effect of the design parameters on the H2 -CAES plant performance are analyzed on a yearly basis. Moreover a comparison between the use of natural gas and hydrogen in terms of energy consumption and CO2 emissions is discussed. The results show that the proposed hydrogen fueled CAES can effectively match the generation profile and the yearly production of the natural gas fueled plant by using all the PV energy production while producing zero CO2 emissions.

Hydrogen is gaining prominence as a sustainable energy source in the UK aligning with the country’s commitment to advancing sustainable development across diverse sectors. However a rigorous examination of the interplay between the hydrogen economy and the Sustainable Development Goals (SDGs) is imperative. This study addresses this imperative by comprehensively assessing the risks associated with hydrogen production storage transportation and utilization. The overarching aim is to establish a robust framework that ensures the secure deployment and operation of hydrogen-based technologies within the UK’s sustainable development trajectory. Considering the unique characteristics of the UK’s energy landscape infrastructure and policy framework this paper presents practical and viable recommendations to facilitate the safe and effective integration of hydrogen energy into the UK’s SDGs. To facilitate sophisticated decision making it proposes using an advanced Decision-Making Trial and Evaluation Laboratory (DEMATEL) tool incorporating regret theory and a 2-tuple spherical linguistic environment. This tool enables a nuanced decision-making process yielding actionable insights. The analysis reveals that Incident Reporting and Learning Robust Regulatory Framework Safety Standards and Codes are pivotal safety factors. At the same time Clean Energy Access Climate Action and Industry Innovation and Infrastructure are identified as the most influential SDGs. This information provides valuable guidance for policymakers industry stakeholders and regulators. It empowers them to make well-informed strategic decisions and prioritize actions that bolster safety and sustainable development as the UK transitions towards a hydrogen-based energy system. Moreover the findings underscore the varying degrees of prominence among different SDGs. Notably SDG 13 (Climate Action) exhibits relatively lower overall distinction at 0.0066 and a Relation value of 0.0512 albeit with a substantial impact. In contrast SDG 7 (Clean Energy Access) and SDG 9 (Industry Innovation and Infrastructure) demonstrate moderate prominence levels (0.0559 and 0.0498 respectively) each with its unique influence emphasizing their critical roles in the UK’s pursuit of a sustainable hydrogen-based energy future.

Renewable hydrogen production has an opportunity to reduce carbon emissions in the transportation and industrial sectors. This method generates hydrogen utilizing renewable energy sources such as the sun wind and hydropower lowering the number of greenhouse gases released into the environment. In recent years considerable progress has been made in the production of sustainable hydrogen particularly in the disciplines of electrolysis biomass gasification and photoelectrochemical water splitting. This review article figures out the capacity efficiency and cost-effectiveness of hydrogen production from renewable sources effectively comparing the conventionally used technologies with the latest techniques which are getting better day by day with the implementation of the technological advancements. Governments investors and industry players are increasingly interested in manufacturing renewable hydrogen and the global need for clean energy is expanding. It is projected that facilities for manufacturing renewable hydrogen as well as infrastructure to support this development would expand hastening the transition to an environment-friendly and low-carbon economy