Publications

This paper presents a simulation tool for marine hybrid power-plants equipped with polymer exchange membrane fuel cells and batteries. The virtual model through the combination of operational data and dynamically modelled subsystems can simulate power-plants of different sizes and configurations in order to analyze the response of different energy management strategies. The model aims to replicate the realistic behavior of the components included in the vessel's grid to asses if the hardware selected by the user is capable of delivering the power set-point requested by the energy management system. The model can then be used to optimize key factors such as hydrogen consumption. The case study presented in the paper demonstrates how the model can be used for the evaluation of a retrofitting operation replacing a diesel electric power-plant with fuel cells and batteries. The vessel taken into consideration is a domestic ferry operating car and passenger transport in Denmark. The vessel is outfitted with a diesel electric plant and an alternative hybrid power-plant is proposed. The hybrid configuration is tested using the model in a discrete time-domain.

Palladium (Pd) membranes are a promising enabling technology for power generation and hydrogen production with CO2 capture. SINTEF has developed and patented a flexible technology to produce Pd-alloy membranes that significantly improves flux and thereby reduces material costs. Reinertsen AS and SINTEF aim to demonstrate the Pd membrane technology for H2 separation on a side stream of the Statoil Methanol Plant at Tjeldbergodden Norway. In the present article we present the upscaling of the membrane manufacturing process together with the membrane module and skid design and construction.

The cost of storing and transporting hydrogen have been one of the main challenges for the realization of the hydrogen economy. Liquid organic hydrogen carriers (LOHC) are a promising novel solution to tackle these challenges. In this paper we compare the LOHC concept to compressed gas truck delivery and on-site production of hydrogen via water electrolysis. As a case study we consider transportation of by-product hydrogen from chlor-alkali and chlorate plants to a single industrial customer which was considered to have the greatest potential for the LOHC technology to enter the markets. The results show that the LOHC delivery chain could significantly improve the economics of long distance road transport. For economic feasibility the most critical parameters identified are the heat supply method for releasing hydrogen at the end-user site and the investment costs for LOHC reactors.

Presently the fulfilment of world’s energy demand highly relies on the fossil fuel i.e. coal oil and natural gas. Fossil fuels pose threat to environment and biological systems on the earth. Usage of these fuels leads to an increase in the CO2 content in the atmosphere that causes global warming and undesirable climatic changes. Additionally these are limited sources of energy those will eventually dwindle. There is huge urge of identifying and utilizing the renewable energy resources to replace these fossil fuels in the near future as it is expected to have no impact on environment and thus would enable one to provide energy security. Hydrogen is one of the most desirable fuel capable of replacing vanishing hydrocarbons. In this review we present the status of energy demands recent advances in renewable energy and the prospects of hydrogen as a future fuel are highlighted. It gives a broad overview of different energy systems and mainly focuses on different technologies and their reliability for the production of hydrogen in present and future.

ISSUES MONITOR 2020: DECODING NEW SIGNALS OF CHANGE

The annual World Energy Issues Monitor provides unique insight into what energy policymakers CEOs and leading experts identify as Critical Uncertainties and Action Priorities. New this year the Issues Monitor also provides readers with the views of the individual customer detailing their perceptions of their role in the overall energy system. The Issues Monitor report includes a global issues map 58 country maps and six regional maps as well as perspectives from Future Energy Leaders (FEL) and energy innovators.

GLOBAL PERSPECTIVES

The 2020 global map incorporates all survey responses representing the views of over 3000 energy leaders from 104 countries. In this era of transition defined by decentralisation digitalisation and decarbonisation energy leaders must pay attention to many different signals of change and distinguish key issues from the noise. The Issues Monitor identifies shifting patterns of connected issues shaping energy transitions.

A NEW PULSE

The focus for the 2010s was about trying to automate and upgrade the energy system and set targets to move the energy transition forward. Digitalisation accelerated the transition of all sectors towards a more customer-centric environment. New policies and regulations were introduced to facilitate this transition and empower consumers. As a result the 2020s may very well be about realising those targets through a transition from activism to action.

TREND TRACKING: CCS

In comparing response from the Oil & Gas sector in 2015 with 2019 we found that almost half of respondents identified Carbon Capture & Storage (CCS) as a high impact issue in 2019 up from about a third in 2015. CCS is increasingly being viewed as an essential option for continued hydrocarbon use although governmental support is needed to enable scalability and cost effectiveness.

A DIFFERENCE IN OPINION: NUCLEAR

Opinions remain polarised but in many European countries nuclear power is increasingly recognised as a carbon-free energy source and potentially an integral part of the future energy mix. In December 2019 the European Commission set a target of net-zero carbon emissions by 2050. There is qualified support among energy leaders to include nuclear energy to help create a carbon neutral continent and enable a just energy transition.

In this paper a novel process is developed to cogenerate 4741 kg/h of methanol 297.7 kW of electricity and 35.73 ton/h of hot water including a hydrogen purification system an absorption– compression refrigeration cycle (ACRC) a regenerative Organic Rankine Cycle (ORC) and parabolic solar troughs. The heat produced in the methanol reactor is recovered in the ORC and ACRC. Parabolic solar troughs provide thermal power to the methanol distillation tower. Thermal efficiencies of the integrated structure and the liquid methanol production cycle are 78.14% and 60.91% respectively. The process’s total exergy efficiency and irreversibility are 89.45% and 16.89 MW. The solar thermal collectors take the largest share of exergy destruction (34%) followed by heat exchangers (30%) and mixers (19%). Based on the sensitivity analysis D17 (mixture of H2 and low-pressure fuel gas before separation) was the most influential stream affecting the performance of the process. With the temperature decline of stream D17 from −139 to −149 °C the methanol production rate and the total thermal efficiency rose to 4741.2 kg/h and 61.02% respectively. Moreover the growth in the hydrogen content from 55% to 80% molar of the feed gas the flow rate of liquid methanol and the total exergy efficiency declined to 4487 kg/h and 86.05%.

With the growth of aviation traffic and the demand for emission reduction alternative fuels like the so-called electrofuels could comprise a sustainable solution. Electrofuels are understood as those that use renewable energy for fuel synthesis and that are carbon-neutral with respect to greenhouse gas emission. In this study five potential electrofuels are discussed with respect to the potential application as aviation fuels being n-octane methanol methane hydrogen and ammonia and compared to conventional Jet A-1 fuel. Three important aspects are illuminated. Firstly the synthesis process of the electrofuel is described with its technological paths its energy efficiency and the maturity or research need of the production. Secondly the physico-chemical properties are compared with respect to specific energy energy density as well as those properties relevant to the combustion of the fuels i.e. autoignition delay time adiabatic flame temperature laminar flame speed and extinction strain rate. Results show that the physical and combustion properties significantly differ from jet fuel except for n-octane. The results describe how the different electrofuels perform with respect to important aspects such as fuel and air mass flow rates. In addition the results help determine mixture properties of the exhaust gas for each electrofuel. Thirdly a turbine configuration is investigated at a constant operating point to further analyze the drop-in potential of electrofuels in aircraft engines. It is found that electrofuels can generally substitute conventional kerosene-based fuels but have some downsides in the form of higher structural loads and potentially lower efficiencies. Finally a preliminary comparative evaluation matrix is developed. It contains specifically those fields for the different proposed electrofuels where special challenges and problematic points are seen that need more research for potential application. Synthetically-produced n-octane is seen as a potential candidate for a future electrofuel where even a drop-in capability is given. For the other fuels more issues need further research to allow the application as electrofuels in aviation. Specifically interesting could be the combination of hydrogen with ammonia in the far future; however the research is just at the beginning stage.

The presence of a conductive layers of hot-formed oxide on the surface of bars for pre or post-compressing structures can promote localized attacks as a function of pH. The aggressive local environment in the occluded cells inside localized attacks has as consequence the possibility of initiation of stress corrosion cracking. In this paper the stress corrosion cracking behavior of high strength steels proposed for tendons was studied by means of Constant Load (CL) tests and Slow Strain Rate (SSR) tests. Critical ranges of pH for cracking were verified. The promoting role of localized attack was confirmed. Further electrochemical tests were performed on bars in as received surface conditions in order to evaluate pitting initiation. The adverse effect of mill scale was recognized.

This paper describes a 1-D numerical model for the prediction of heat and mass transfer through an intumescent paint that is applied to an on-board high-pressure GH2 storage tank. The intumescent paint is treated as a composite system consisting of three general components decomposing in accordance with independent finite reaction rates. A moving mesh that is employed for a better prediction of the expansion process of the intumescent paint is based on the local changes of heat and mass. The numerical model is validated against experiments by Cagliostro et al. (1975). The overall model results are used to estimate effect of intumescent paint on fire resistance of carbon-fibre reinforced GH2 storage.

Fast response and high durability hydrogen sensor is required in the safety management of hydrogen station and fuel cell vehicle. We had developed the catalytic combustion type hydrogen sensor in the shape of the miniature beads. It is using the optimized Pd-Pt/Al2O3 catalyst and the Pt micro-heater coil. Both warm-up time and response time of this sensor achieved less than 1 second by downsizing the element to 200μm diameter. Furthermore we improved the resistance of sensor poisoning to silicone vapor and confirmed long term stability within +/-10% of output error up to 8 years. Therefore we assume that our sensor technology contribute to hydrogen safety.

There is significant interest in Australia both federally and at the state level to develop a hydrogen production industry. Australia’s Chief Scientist Alan Finkel recently prepared a briefing paper for the COAG Energy Council outlining a road map for hydrogen. It identifies hydrogen has the potential to be a significant source of export revenue for Australia in future years assist with decarbonising Australia’s economy and could establish Australia as a leader in low emission fuel production.

As part of the ongoing investigations into the hydrogen production potential of Australia Geoscience Australia has been commissioned by the Department of Industry Innovation and Science to develop heat maps that show areas with high potential for future hydrogen production. The study is technology agnostic in that it considers hydrogen production via electrolysis using renewable energy sources and also fossil fuel hydrogen coupled with carbon capture and storage (CCS). The heat maps presented in this work are synthesized from the key individual national-scale datasets that are relevant for hydrogen production. In the case of hydrogen from electrolysis renewable energy potential and the availability of water are the most important factors with various infrastructural considerations playing a secondary role. In the case of fossil fuel hydrogen proximity to gas and coal resources water and availability of carbon storage sites are the important parameters that control the heat maps. In this report we present 5 different heat map scenarios reflecting different assumptions in the geospatial analysis and also reflecting to some degree the different projected timeframes for hydrogen production. The first three scenarios pertain to renewable energy and hydrogen There is significant interest in Australia both federally and at the state level to develop a hydrogen production industry. In August 2018 Australia’s Chief Scientist Dr Alan Finkel prepared a briefing paper for the COAG Energy Council outlining a road map for hydrogen. It identifies hydrogen has the potential to be a significant source of export revenue for Australia in future years assist with decarbonising Australia’s economy and could establish Australia as a leader in low emission fuel production.

As part of ongoing investigations into the hydrogen production potential of Australia Geoscience Australia has been engaged by the Department of Industry Innovation and Science to develop maps that show areas with high potential for future hydrogen production. The study is technology agnostic but considers only low carbon production processes. It includes hydrogen production via electrolysis using renewable energy sources (referred to as renewable hydrogen) as well as fossil fuel-derived hydrogen coupled with carbon capture and storage (CCS) (referred to as CCS hydrogen). The maps presented in this work are synthesized from the key individual national-scale datasets that are relevant for hydrogen production. In the case of hydrogen from electrolysis renewable energy potential (from wind solar and hydro resources) and the availability of water are the most important factors while various infrastructure considerations also play a role. In the case of CCS hydrogen proximity to gas and coal resources water and availability of carbon storage sites are the important parameters that control the spatial distribution of potential hydrogen production. In this report we present five different scenarios that reflect key differences in technologies for hydrogen production and the requirements of those technologies. Using geospatial analysis each scenario is translated into a heat map that shows regional trends in potential for hydrogen production based on access to underpinning resources and existing infrastructure.

Three scenarios explore the future potential for renewable hydrogen produced by electrolysis. These demonstrate a high potential for hydrogen production in the future near many Australian coastal areas which is even larger if infrastructure is available to transport renewable power generated from inland areas to the coast. Results also show significant future potential for hydrogen production in inland areas where water is available. The final two scenarios focus on the future potential for CCS hydrogen: a 2030 scenario and a 2050 scenario. A key factor in future CCS hydrogen potential is related to the timeframes for the availability of geological storage resources for CO_2.

Biomass-based gasification is an attractive and promising pathway for hydrogen production. In this work a biomass-based hydrogen production system integrated with organic Rankine cycle was designed and investigated to predict the performance of hydrogen production yield and electricity generation under various operating conditions. The modified equilibrium model presented desirable results for the produced syngas compositions compared with the experimental data. Hydrogen yields from four types of biomass (wood chips daily manure sorghum and grapevine pruning wastes) were compared under the same operating condition with wood chips exhibiting the maximum hydrogen yield of 11.59 mol/kg. The effects of gasification temperature equivalence ratio and steam-to-biomass ratio on the hydrogen yield and electricity generation were investigated by using the response surface method. Furthermore the system was optimized using a genetic algorithm based on the response surface model. A preferred optimal solution with a hydrogen yield of 39.31 mol/kg and an output power of 3558.08 kW (0.99 kW h/kg) was selected by the linear programming technique for multidimensional analysis of the preference method.

In this paper a gas-to-power (GtoP) system for power outages is digitally modeled and experimentally developed. The design includes a solid-state hydrogen storage system composed of TiFeMn as a hydride forming alloy (6.7 kg of alloy in five tanks) and an air-cooled fuel cell (maximum power: 1.6 kW). The hydrogen storage system is charged under room temperature and 40 bar of hydrogen pressure reaching about 110 g of hydrogen capacity. In an emergency use case of the system hydrogen is supplied to the fuel cell and the waste heat coming from the exhaust air of the fuel cell is used for the endothermic dehydrogenation reaction of the metal hydride. This GtoP system demonstrates fast stable and reliable responses providing from 149 W to 596 W under different constant as well as dynamic conditions. A comprehensive and novel simulation approach based on a network model is also applied. The developed model is validated under static and dynamic power load scenarios demonstrating excellent agreement with the experimental results.

With the gradual popularization of hydrogen fuel cell vehicles (HFCVs) the construction and planning of hydrogen refueling stations (HRSs) are increasingly important. Taking operational HRSs in China’s coastal and major cities as examples we consider the main factors affecting the site selection of HRSs in China from the three aspects of economy technology and society to establish a site selection evaluation system for hydrogen refueling stations and determine the weight of each index through the analytic hierarchy process (AHP). Then combined with fuzzy comprehensive evaluation (FCE) method and artificial neural network model (ANN) FCE method is used to evaluate HRS in operation in China's coastal areas and major cities and we used the resulting data obtained from the comprehensive evaluation as the training data to train the neural network. So an intelligent site selection model for HRSs based on fuzzy comprehensive evaluation and artificial neural network model (FCE-ANN) is proposed. The planned HRSs in Shanghai are evaluated and an optimal site selection of the HRS is obtained. The results show that the optimal HRSs site selected by the FCE-ANN model is consistent with the site selection obtained by the FCE method and the accuracy of the FCE-ANN model is verified. The findings of this study may provide some guidelines for policy makers in planning the hydrogen refueling stations

In super duplex stainless steels (SDSSs) both austenite and ferrite are susceptible to hydrogen embrittlement however there is a lack of understanding into the effect of hydrogen in each phase. In this study in neutron diffraction was applied on hydrogen-charged (H-charged) samples to investigate the hydrogen embrittlement behaviour in super duplex stainless steels. The result reveals that austenite maintains good plasticity during tensile testing whilst a loss of it is realised in ferrite. Fractography analysis reveals the diffusion of hydrogen induced a brittle-to-ductile transition from the sample surface towards the centre; hydrogen embrittlement vanishes as the specimen’s centre is approached while it is demonstrated to disappear first in austenite but not in ferrite. This transition can be predicted by applying a physics-based hydrogen embrittlement model which incorporates the effects of hydrogen concentration hydrogen diffusivity residual stress loading state and temperature. The present work demonstrates the dissimilar susceptibility of austenite and ferrite to hydrogen embrittlement providing a tool to describe it.

With the rapid development of hydrogen vehicle technology and large scale fuel cell vehicle (FCV) demonstration project worldwide more hydrogen refueling stations need to be built. Safety distances of hydrogen refueling stations have always been a public concern and have become a critical issue to further implementation of hydrogen station. In this paper safety distances for 35MPa and 70MPa gaseous hydrogen refueling station are evaluated on the basis of the maximum consequences likely to occur. Four typical consequences of hydrogen release are considered in modeling: physical explosion jet fire flash fire and confined vapor cloud explosion. Results show that physical explosion and the worst case of confined vapor cloud explosion produce the longest harm effect distances for instantaneous and continuous release respectively indicating that they may be considered as leading consequences for the determination of safety distances. For both 35MPa station and 70MPa station safety measures must be implemented because the calculated safety distances of most hydrogen facilities can not meet the criteria in national code if without sufficient mitigation measures. In order to reduce the safety distances to meet the national code some mitigation measures are investigated including elevation of hydrogen facilities using smaller vessel and pipe work and setting enclosure around compressors. Results show that these measures are effective to improve safety but each has different effectiveness on safety distance reduction. The combination of these safety measures may effectively eliminate the hazard of 35MPa station however may be not enough for 70MPa station. Further improvements need to be studied for compressors inside 70MPa station.

Liquid hydrogen vent stacks often release hydrogen for example due to pressure relief from an underutilized tank boiling off hydrogen or after hydrogen delivery and transfer (trucks often depressurize through the tank vent stack to meet pressure regulations for on-road transport).<br/>A rapid release of cryogenic hydrogen through a vent stack will condense moisture from the entrained air forming a visible cloud. It is often assumed that the extent of the cold hydrogen is concurrent with the cloud. In this work a laser-based Raman scattering diagnostic was used to map out the hydrogen location during a series of vent stack release experiments. A description of the diagnostic instrument is given followed by a comparison of hydrogen signals to the visible cloud for releases through a liquid hydrogen vent stack. A liquid hydrogen pump was used to vary the flowrate of hydrogen through the vent stack and tests were performed under low and high wind conditions as well as low and high humidity conditions. The hydrogen was observed only where the condensed moisture was located regardless of the humidity level or wind. These measurements are being used to validate models such as those included in Sanda’s HyRAM toolkit and inform safety codes and standards.

Exposing and stabilizing undercoordinated platinum (Pt) sites and therefore optimizing their adsorption to reactive intermediates offers a desirable strategy to develop highly efficient Pt-based electrocatalysts. However preparation of atomically controllable Pt-based model catalysts to understand the correlation between electronic structure adsorption energy and catalytic properties of atomic Pt sites is still challenging. Herein we report the atomically thin two-dimensional PtTe₂ nanosheets with well-dispersed single atomic Te vacancies (Te-SAVs) and atomically well-defined undercoordinated Pt sites as a model electrocatalyst. A controlled thermal treatment drives the migration of the Te-SAVs to form thermodynamically stabilized ordered Te-SAV clusters which decreases both the density of states of undercoordinated Pt sites around the Fermi level and the interacting orbital volume of Pt sites. As a result the binding strength of atomically defined Pt active sites to H intermediates is effectively reduced which renders PtTe₂ nanosheets highly active and stable in hydrogen evolution reaction.

Blending hydrogen (H2) produced from PEM electrolysis coupled to Renewable Energy Sources (RES) in the existing Natural Gas (NG) network is a promising option for the deep decarbonization of the gas sector. However blending H2 with NG significantly affects the thermophysical properties of the gas mixture changing the gas supply requirements to meet the demand. In this work different scenarios of green hydrogen blending (Blend Ratio BR equal to 5/10/15/20%vol) are analyzed at the national level with different temporal constraints (hour/day/week/month/year) based on real gas demand data in Italy addressing both design requirements (RES and PEM electrolyzer capacity) via Linear Programming (LP) and carrying out dynamic simulations of different operational strategies (constant or variable blend). Although H2/NG blending provides a huge opportunity in terms of deployed H2 volume higher BRs show rapidly increasing design requirements (1.3-1.5 GWe/%vol and 2.5-3 GWe/%vol for PEM electrolyzers and RES capacity respectively) and a significative increase of the total gas mixture volume (0.83 %/%vol) which hinders the CO2 reduction potential (0.37 %/%vol). A variable blend operation strategy (allowing a variation of BR within the analyzed period) allows to balance a variable H2 production from RES. Wider temporal constraints imply several beneficial effects such as relaxing design constraints and avoiding the implementation of an external storage. The Levelized Cost Of Hydrogen (LCOH) is preliminarily estimated at around 7.3 $/kg for yearly scenarios (best-case) although shorter temporal constraints entail significant excess hydrogen which would increase the LCOH if not deployed for other applications.

In this paper different techniques to test notched Small Punch (SPT) samples in fracture conditions in aggressive environments are studied based on the comparison of the micromechanisms at different rates. Pre-embrittled samples subsequently tested in air at rates conventionally employed (0.01 and 0.002 mm/s) are compared to embrittled ones tested in environment at the same rates (0.01 and 0.002 mm/s) and at a very slow rate (5E-5 mm/s). A set of samples tested in environment under a set of constant loads that produce very slow rates completes the experimental results. As a conclusion it is recommended to test SPT notched specimens in environment at very slow rates of around E-6 mm/s when characterizing in Hydrogen Embrittlement (HE) scenarios in order to allow the interaction material-environment to govern the process.

Overview of advances in the technology of solid state hydrogen storage methods applying different kinds of novel materials is provided. Metallic and intermetallic hydrides complex chemical hydride nanostructured carbon materials metal-doped carbon nanotubes metal-organic frameworks (MOFs) metal-doped metal organic frameworks covalent organic frameworks (COFs) and clathrates solid state hydrogen storage techniques are discussed. The studies on their hydrogen storage properties are in progress towards positive direction. Nevertheless it is believed that these novel materials will offer far-reaching solutions to the onboard hydrogen storage problems in near future. The review begins with the deficiencies of current energy economy and discusses the various aspects of implementation of hydrogen energy based economy.

Hydrogen has become a strong candidate to be a future energy storage medium but there are technological challenges both in its production and storage. For storage a search for lightweight abundant and non-toxic materials is on the way. An abundant natural material such as wood cellulose would make an ideal storage medium from a sustainability perspective. Here using a combination of static DFT calculations and ab initio molecular dynamics simulations at different temperatures it is shown that wood cellulose has the ability to uptake H2 via a physisorption mechanism based on dispersion interactions of the van der Waals type involving the O-atoms of the d-glucose rings. The absorption causes little to no disturbances on the cellulose structure and H2 is highly mobile in the material. At an external pressure of H2(g) of 0.09 atm and T = 25 °C cellulose has a theoretical gravimetric density of hydrogen storage of ≈1%.

This White Paper has been commissioned by the UK Hydrogen and Fuel Cell (H2FC) SUPERGEN Hub to examine the roles and potential benefits of hydrogen and fuel cell technologies for heat provision in future low-carbon energy systems. The H2FC SUPERGEN Hub is an inclusive network encompassing the entire UK hydrogen and fuel cells research community with around 100 UK-based academics supported by key stakeholders from industry and government. It is funded by the UK EPSRC research council as part of the RCUK Energy Programme. This paper is the first of four that will be published over the lifetime of the Hub with the others examining: (i) low-carbon energy systems (including balancing renewable intermittency); (ii) low-carbon transport systems; and (iii) the provision of secure and affordable energy supplies for the future

• Hydrogen and fuel cells are part of the cost-optimal heating technology portfolio in long-term UK energy system scenarios.
• Fuel cell CHP is already being deployed commercially around the world.
• Hydrogen can be a zero-carbon alternative to natural gas. Most technologies that use natural gas can be adapted to use hydrogen and still provide the same level of service.
• Hydrogen and fuel cell technologies avoid some of the disadvantages of other low-carbon heating technologies.

The highly combustible nature of hydrogen poses a great hazard creating a number of problems with its safety and handling. As a part of safety studies related to the use of hydrogen in a confined environment it is extremely important to have a good knowledge of the dispersion mechanism.<br/>The present work investigates the concentration field and flammability envelope from a small scale leak. The hydrogen is released into a 0.47 m × 0.33 m x 0.20 m enclosure designed as a 1/15 – scale model of a room in a nuclear facility. The performed tests evaluates the influence of the initial conditions at the leakage source on the dispersion and mixing characteristics in a confined environment. The role of the leak location and the presence of obstacles are also analyzed. Throughout the test during the release and the subsequent dispersion phase temporal profiles of hydrogen concentration are measured using thermal conductivity gauges within the enclosure. In addition the BOS (Background Oriented Schlieren) technique is used to visualise the cloud evolution inside the enclosure. These instruments allow the observation and quantification of the stratification effects.

Mechanical alloying is widely used for the synthesis of hydrogen storage materials. However amorphization and contamination triggered by long-time milling are serious drawbacks for obtaining efficient hydrogen storage. In this work short-time ball milling synthesis is explored for a representative hydride forming compound: TiNi. Through structural morphological and chemical characterizations we evidence that formation of TiNi is complete in only 20 min with minor Fe contamination (0.2 wt%). Cross-sectional analysis of powder stuck on milling balls reveals that alloy formation occurs through the interdiffusion between thin layers of co-laminated pure elements. Hydrogenation thermodynamics and kinetics of short-time mechanically alloyed TiNi are similar to those of coarse-grained compounds obtained by classical high-temperature melting. Mechanical alloying is a suitable method for fast and energy-efficient synthesis of intermetallic compounds such as TiNi.