Publications
A Portfolio of Powertrains for the UK: An Energy Systems Analysis
Jul 2014
Publication
There has recently been a concerted effort to commence a transition to fuel cell vehicles (FCVs) in Europe. A coalition of companies released an influential McKinsey-coordinated report in 2010 which concluded that FCVs are ready for commercial deployment. Public–private H2Mobility programmes have subsequently been established across Europe to develop business cases for the introduction of FCVs. In this paper we examine the conclusions of these studies from an energy systems perspective using the UK as a case study. Other UK energy system studies have identified only a minor role for FCVs after 2030 but we reconcile these views by showing that the differences are primarily driven by different data assumptions rather than methodological differences. Some energy system models do not start a transition to FCVs until around 2040 as they do not account for the time normally taken for the diffusion of new powertrains. We show that applying dynamic growth constraints to the UK MARKAL energy system model more realistically represents insights from innovation theory. We conclude that the optimum deployment of FCVs from an energy systems perspective is broadly in line with the roadmap developed by UK H2Mobility and that a transition needs to commence soon if FCVs are to become widespread by 2050.
Removing the Disrupting Wind Effect in Single Vented Enclosure Exposed to External Wind
Oct 2015
Publication
We are addressing hydrogen release into a single-vented facility with wind blowing onto the opposite side of the vent wall. Earlier work based on tests performed by HSL with wind (within the HyIndoor project) and comparative CFD simulations with and without wind ([1]within the H2FC project) has shown that the hydrogen concentrations inside the enclosure are increased compared to the case with no wind. This was attributed to the fact that wind is disrupting the passive ventilation. The present work is based on the GAMELAN tests (within the HyIndoor project) performed with one vent and no wind. For this enclosure simulations were performed with and without wind and reproduced the disrupting wind effect. In order to remove this effect and enhance the ventilation additional simulations were performed by considering different geometrical modifications near the vent. A simple geometrical layout around the vent is here proposed that leads to elimination of the disrupting wind effect. The analysis has been performed using the ADREA-HF code earlier validated both for the HSL and the GAMELAN tests. The current work was performed partly within HyIndoor project
Pressure Effects of an Ignited Release from Onboard Storage in a Garage with a Single Vent
Sep 2017
Publication
This work is driven by the need to understand the hazards resulting from the rapid ignited release of hydrogen from onboard storage tanks through a thermally activated pressure relief device (TPRD) inside a garage-like enclosure with low natural ventilation i.e. the consequences of a jet fire which has been immediately ignited. The resultant overpressure is of particular interest. Previous work [1] focused on an unignited release in a garage with minimum ventilation. This initial work demonstrated that high flow rates of unignited hydrogen through a thermally activated pressure relief device (TPRD) in ventilated enclosures with low air change per hour can generate overpressures above the limit of 10- 15 kPa which a typical civil structure like a garage could withstand. This is due to the pressure peaking phenomenon. Both numerical and phenomenological models were developed for an unignited release and this has been recently validated experimentally [2]. However it could be expected that the majority of unexpected releases through a TPRD may be ignited; leading to even greater overpressures and to date whilst there has been some work on fires in enclosures the pressure peaking phenomenon for an ignited release has yet to be studied or compared with that for an equivalent unignited release. A numerical model for ignited releases in enclosures has been developed and computational fluid dynamics has then been used to examine the pressure dynamics of an ignited hydrogen release in a real scale garage. The scenario considered involves a high mass flow rate release from an onboard hydrogen storage tank at 700 bar through a 3.34 mm diameter orifice representing the TPRD in a small garage with a single vent equivalent in area to small window. It is shown that whilst this vent size garage volume and TPRD configuration may be considered “safe” from overpressures in the event of an unignited release the overpressure resulting from an ignited release is two orders of magnitude greater and would destroy the structure. Whilst further investigation is needed the results clearly indicate the presence of a highly dangerous situation which should be accounted for in regulations codes and standards. The hazard relates to the volume of hydrogen released in a given timeframe thus the application of this work extends beyond TPRDs and is relevant where there is a rapid ignited release of hydrogen in an enclosure with limited ventilation.
Comparison of Two-layer Model for High Pressure Hydrogen Jets with Notional Nozzle Model Predictions and Experimental Data
Oct 2015
Publication
A two-layer reduced order model of high pressure hydrogen jets was developed which includes partitioning of the flow between the central core jet region leading to the Mach disk and the supersonic slip region around the core. The flow after the Mach disk is subsonic while the flow around the Mach disk is supersonic with a significant amount of entrained air. This flow structure significantly affects the hydrogen concentration profiles downstream. The predictions of this model are compared to previous experimental data for high pressure hydrogen jets up to 20 MPa and to notional nozzle models and CFD models for pressures up to 35 MPa using ideal gas properties. The results show that this reduced order model gives better predictions of the mole fraction distributions than previous models for highly underexpanded jets. The predicted locations of the 4% lower flammability limit also show that the two-layer model much more accurately predicts the measured locations than the notional nozzle models. The comparisons also show that the CFD model always underpredicts the measured mole fraction concentrations.
The Slow Burst Test as a Method for Probabilistic Quantification of Cylinder Degradation
Sep 2013
Publication
"The current practise of focusing the periodic retesting of composite cylinders primarily on the hydraulic pressure test has to be evaluated as critical - with regard to the damage of the specimen as well as in terms of their significance. This is justified by micro damages caused to the specimen by the test itself and by a lack of informative values. Thus BAM Federal Institute of Materials Research and Testing (Germany) uses a new approach of validation of composite for the determination of re-test periods. It enables the description of the state of a population of composite cylinders based on destructive tests parallel to operation.<br/>An essential aspect of this approach is the prediction of residual safe service life. In cases where it cannot be estimated by means of hydraulic load cycle tests as a replacement the creep or burst test remains. As a combination of these two test procedures BAM suggests the ""slow burst test SBT"". On this a variety of about 150 burst test results on three design types of cylinders with plastic liners are presented. For this purpose both the parameters of the test protocol as well as the nature and intensity of the pre-damage artificially aged test samples are analysed statistically. This leads first to an evaluation of the different types of artificial ageing but also to the clear recommendation that conventional burst tests be substituted totally if indented for assessment of composite pressure receptacles."
Feasibility of Renewable Hydrogen Based Energy Supply for a District
Sep 2017
Publication
Renewable generation technologies (e.g. photovoltaic panels (PV)) are often installed in buildings and districts with an aim to decrease their carbon emissions and consumption of non-renewable energy. However due to a mismatch between supply and demand at an hourly but also on a seasonal timescale; a large amount of electricity is exported to the grid rather than used to offset local demand. A solution to this is local storage of electricity for subsequent self-consumption. This could additionally provide districts with new business opportunities financial stability flexibility and reliability.<br/>In this paper the feasibility of hydrogen based electricity storage for a district is evaluated. The district energy system (DES) includes PV and hybrid photovoltaic panels (PVT). The proposed storage system consists of production of hydrogen using the renewable electricity generated within the district hydrogen storage and subsequent use in a fuel cell. Combination of battery storage along with hydrogen conversion and storage is also evaluated. A multi-energy optimization approach is used to model the DES. Results of the model are optimal battery capacity electrolyzer capacity hydrogen storage capacity fuel cell capacity and energy flows through the system. The model is also used to compare different system design configurations. The results of this analysis show that both battery capacity and conversion of electricity to hydrogen enable the district to decrease its carbon emissions by approximately 22% when compared to the reference case with no energy storage.
Hydrogen Production Using Solar Energy - Technical Analysis
Mar 2019
Publication
This paper presents a case study concerning a plant for hydrogen production and storage having a daily capacity of 100kg. The plant is located in Cluj-Napoca Romania. It produces hydrogen by means of water electrolysis while the energy is provided using solar energy. We performed the calculations for four different technical solutions used for the hydrogen production and storage plant and also we considered three scenarios regarding the sub-systems of the hydrogen production and storage plant efficiency. The conclusion of this study is that one can maximize the conversion of solar radiation into chemical energy in the form of hydrogen by hybridizing the solar hydrogen production system namely using both electrical energy as well as thermal energy in the form of steam.
Safe Storage of Compressed Hydrogen at Ambient and Cryogenic Temperatures in Flexible Glass Capillaries
Sep 2013
Publication
We have demonstrated that the strength of produced flexible quartz capillaries can be high enough to withstand the internal hydrogen pressure up to 233 MPa at normal and cryogenic temperature. According to the experimental results the cryo-compressed storage of hydrogen in the capillaries at moderate pressure can enable one to reach DOE 2015 aims for the gravimetric and volumetric capacities of vessels for the safe mobile hydrogen storage. Furthermore flexible capillaries in a bundle can probably serve as a high-pressure pipes for the transportation of gases over long distances. The developed technology of hydrogen storage can be applied to methane and hythane (H₂ - CH₄ mixture) which bridge the gap between conventional fossil fuels and the clean future of a hydrogen economy. It can be also applied to other gases i.e. air oxygen and helium-oxygen mixtures widely used in autonomic breathing devices.
Detonation Wave Propagation in Semi-confined Layers of Hydrogen-air and Hydrogen-oxygen Mixtures
Oct 2015
Publication
This paper presents results of an experimental investigation on detonation wave propagation in semi-confined geometries. Large scale experiments were performed in layers up to 0.6 m filled with uniform and non-uniform hydrogen–air mixtures in a rectangular channel (width 3 m; length 9 m) which is open from below. A semi confined driver section is used to accelerate hydrogen flames from weak ignition to detonation. The detonation propagation was observed in a 7 m long unobstructed part of the channel. Pressure measurements ionization probes soot-records and high speed imaging were used to observe the detonation propagation. Critical conditions for detonation propagation in different layer thicknesses are presented for uniform H2/air-mixtures as well as experiments with uniform H2/O2 mixtures in a down scaled transparent channel. Finally detail investigations on the detonation wave propagation in H2/air-mixtures with concentration gradients are shown.
Very Low-cost Visual and Wireless Sensors for Effective Hydrogen Gas Leak Detection
Sep 2013
Publication
Element One Inc. Boulder CO is developing novel hydrogen gas leak indicators to improve the safety and maintenance operations of hydrogen production and chemical processing facilities and hydrogen fueling stations. These technologies can be used to make visual gas leak indicators such as paints decals and conformal plastic films as well as RF sensors for wireless networks. The primary advantage of the Element One hydrogen gas indicators is their low cost and easy deployment which allows them to be used ubiquitously at each and every potential hydrogen leak site. They have the potential to convert safety problems into routine maintenance problems thereby improving overall safety and decreasing operational costs.
Radiation from Hydrogen Jet Fires Investigated by Time-resolved Spectroscopy
Sep 2013
Publication
Jet fires develop on release of hydrogen from pressurized storage depending on orifice pressures and volumes. Risks arise from flame contact dispersion of hot gases and heat radiation. The latter varies strongly in time at short scales down to milliseconds caused by turbulent air entrainment and fluctuations. These jets emit bands of OH in the UV and water in the NIR and IR spectral range. These spectra enable the temperature measurement and the estimation of the air number of the measuring spot which can be used to estimate the total radiation at least from the bright combustion zones. Compared to video and IR camera frames the radiation enables to estimate species and temperatures distributions and total emissions. Impurities generate continuum radiation and the emission of CO2 in the IR indicates air entrainment which can be compared to CHEMKIN II calculation of the reaction with air.
Experimental Study of the Thermal Behaviour of Hydrogen Tanks During Hydrogen Cycling
Sep 2013
Publication
The thermal behaviour of several commercial hydrogen tanks has been studied during high pressure (70-84 MPa) hydrogen cycling. The temperature of the gas at different points inside the tank the temperature at the bosses and the tank outer wall temperature have been measured under different filling and emptying conditions. From the experimental results the effect of the filling rate (1.5-4 g/s) and the influence of the liner material in the thermal behaviour of the hydrogen tanks have been evaluated. Bosses thermal response under the different cycling conditions has also been investigated.
Energy Storage as Part of a Secure Energy Supply
Mar 2017
Publication
Florian Ausfelder,
Christian Beilmann,
Martin Bertau,
Sigmar Bräuninger,
Angelika Heinzel,
Renate Hoer,
Wolfram Koch,
Falko Mahlendorf,
Anja Metzelthin,
Marcell Peuckert,
Ludolf Plass,
Konstantin Räuchle,
Martin Reuter,
Georg Schaub,
Sebastian Schiebahn,
Ekkehard Schwab,
Ferdi Schüth,
Detlef Stolten,
Gisa Teßmer,
Kurt Wagemann and
Karl-Friedrich Ziegahn
The current energy system is subject to a fundamental transformation: A system that is oriented towards a constant energy supply by means of fossil fuels is now expected to integrate increasing amounts of renewable energy to achieve overall a more sustainable energy supply. The challenges arising from this paradigm shift are currently most obvious in the area of electric power supply. However it affects all areas of the energy system albeit with different results. Within the energy system various independent grids fulfill the function of transporting and spatially distributing energy or energy carriers and the demand-oriented supply ensures that energy demands are met at all times. However renewable energy sources generally supply their energy independently from any specific energy demand. Their contribution to the overall energy system is expected to increase significantly.<br/>Energy storage technologies are one option for temporal matching of energy supply and demand. Energy storage systems have the ability to take up a certain amount of energy store it in a storage medium for a suitable period of time and release it in a controlled manner after a certain time delay. Energy storage systems can also be constructed as process chains by combining unit operations each of which cover different aspects of these functions. Large-scale mechanical storage of electric power is currently almost exclusively achieved by pumped-storage hydroelectric power stations.<br/>These systems may be supplemented in the future by compressed-air energy storage and possibly air separation plants. In the area of electrochemical storage various technologies are currently in various stages of research development and demonstration of their suitability for large-scale electrical energy storage. Thermal energy storage technologies are based on the storage of sensible heat exploitation of phase transitions adsorption/desorption processes and chemical reactions. The latter offer the possibility of permanent and loss-free storage of heat. The storage of energy in chemical bonds involves compounds that can act as energy carriers or as chemical feedstocks. Thus they are in direct economic competition with established (fossil fuel) supply routes. The key technology here – now and for the foreseeable future – is the electrolysis of water to produce hydrogen and oxygen.<br/>Hydrogen can be transformed by various processes into other energy carriers which can be exploited in different sectors of the energy system and/or as raw materials for energy-intensive industrial processes. Some functions of energy storage systems can be taken over by industrial processes. Within the overall energy system chemical energy storage technologies open up opportunities to link and interweave the various energy streams and sectors. Chemical energy storage not only offers means for greater integration of renewable energy outside the electric power sector it also creates new opportunities for increased flexibility novel synergies and additional optimization.<br/>Several examples of specific energy utilization are discussed and evaluated with respect to energy storage applications. The article describes various technologies for energy storage and their potential applications in the context of Germany’s Energiewende i.e. the transition towards a more sustainable energy system. Therefore the existing legal framework defines some of the discussions and findings within the article specifically the compensation for renewable electricity providers defined by the German Renewable Energy Sources Act which is under constant reformation. While the article is written from a German perspective the authors hope this article will be of general interest for anyone working in the areas of energy systems or energy technology.
The Study on the Internal Temperature Change of Type 3 and Type 4 Composite Cylinder During Filling
Sep 2013
Publication
The number of eco friendly vehicle which is using green energy such as natural gas(NG) and hydrogen(H2) is rapidly increasing in the world. Almost all of the car manufacturers are adopting the pressurizing fuel method to storage gas. The fuel storage system which can pressurize the fuel as high as possible is necessary to maximize the mileage of the vehicle. In Korea the most important issue is that makes sure of safety of the fuel storage system and several tests are performed to verify safety of the composite cylinder especially for Type 3 and Type 4. In this research an empirical study on the internal temperature change of Type 3 and Type 4 composite cylinder during filling is performed by gas cycling test equipment. In order to measure the temperature totally twelve sensors(every four sensors on the top middle and bottom) are installed in each cylinder. As a consequence large amount of compression heat is generated during rapid filling and the result temperature change in Type 4 is greater than Type 3 is confirmed depending on property of the liner material such as thermal conduction and thickness of carbon composite.
Communicating Leakage Risk in the Hydrogen Economy: Lessons Already Learned from Geoenergy Industries
Sep 2019
Publication
Hydrogen may play a crucial part in delivering a net zero emissions future. Currently hydrogen production storage transport and utilisation are being explored to scope opportunities and to reduce barriers to market activation. One such barrier could be negative public response to hydrogen technologies. Previous research around socio-technical risks finds that public acceptance issues are particularly challenging for emerging remote technical sensitive uncertain or unfamiliar technologies - such as hydrogen. Thus while the hydrogen value chain could offer a range of potential environmental economic and social benefits each will have perceived risks that could challenge the introduction and subsequent roll-out of hydrogen. These potential issues must be identified and managed so that the hydrogen sector can develop adapt or respond appropriately. Geological storage of hydrogen could present challenges in terms of perceived safety. Valuable lessons can be learned from international research and practice of CO2 and natural gas storage in geological formations (for carbon capture and storage CCS and for power respectively). Here we explore these learnings. We consider the similarities and differences between these technologies and how these may affect perceived risks. We also reflect on lessons for effective communication and community engagement. We draw on this to present potential risks to the perceived safety of - and public acceptability of – the geological storage of hydrogen. One of the key lessons learned from CCS and natural gas storage is that progress is most effective when risk communication and public acceptability is considered from the early stages of technology development.
Sample Scale Testing Method to Prevent Collapse of Plastic Liners in Composite Pressure Vessels
Sep 2017
Publication
Type IV pressure vessels are commonly used for hydrogen on-board stationary or bulk storages. When pressurised hydrogen permeates through the materials and solves into them. Emptying then leads to a difference of pressure at the interface between composite and liner possibly leading to a permanent deformation of the plastic liner called “collapse” or “buckling”. This phenomenon has been studied through French funded project Colline allowing to better understand its initiation and long-term effects. This paper presents the methodology followed using permeation tests hydrogen decompression tests on samples and gas diffusion calculation in order to determine safe operating conditions such as maximum flow rate or residual pressure level.
Boundary Layer Effects on the Critical Nozzle of Hydrogen Sonic Jet
Oct 2015
Publication
When hydrogen flows through a small finite length constant exit area nozzle the viscous effects create a fluid throat which acts as a converging-diverging nozzle and lead to Mach number greater than one at the exit if the jet is under-expanded. This phenomenon influences the mass flow rate and the dispersion cloud size. In this study the boundary layer effect on the unsteady hydrogen sonic jet flow through a 1 mm diameter pipe from a high pressure reservoir (up to 70 MPa) is studied using computational fluid dynamics with a large eddy simulation turbulence model. This viscous flow simulation is compared with a non-viscous simulation to demonstrate that the velocity is supersonic at the exit of a small exit nozzle and that the mass flow is reduced.
Vented Hydrogen Deflagrations in Containers: Effect of Congestion for Homogeneous Mixtures
Sep 2017
Publication
This paper presents results from an experimental study of vented hydrogen deflagrations in 20-foot ISO containers. The scenarios investigated include 14 tests with explosion venting through the doors of the containers and 20 tests with venting through openings in the roof. The parameters investigated include hydrogen concentration vent area type of venting device and the level of congestion inside the containers. All tests involved homogeneous and initially quiescent hydrogen-air mixtures. The results demonstrate the strong effect of congestion on the maximum reduced explosion pressures which typically is not accounted for in current standards and guidelines for explosion protection. The work is a deliverable from work package 2 (WP2) in the project “Improving hydrogen safety for energy applications through pre-normative research on vented deflagrations” or HySEA which receives funding from the Fuel Cells and Hydrogen Joint Undertaking (FCH JU) under grant agreement no. 671461.
Early Community Engagement with Hydrogen in Australia
Sep 2019
Publication
Community support and acceptance is part of the licence to operate for any industry. The hydrogen industry is no different and we will need to have strong support from the broad community to establish a viable hydrogen economy in Australia.<br/>As Woodside progresses our plans for bulk hydrogen export and associated domestic opportunities stakeholder engagement throughout will be critical to success. This talk will share Woodside’s approach to community engagement and local opportunities and how we plan to draw on more than 30 years’ experience operating liquefied natural gas plants in Western Australia’s Pilbara region.<br/>At this early stage of our hydrogen work we are beginning with the end in mind: engaging the customer. We’ve worked with local Australian businesses to help raise public awareness and interest in hydrogen by producing prototype consumer products. We will share experiences from this work that underscore the value of early engagement with all stakeholders: government regulators industrial and community neighbours and end consumers to enable the hydrogen economy vision for Australia. This paper will present information on community engagement and acceptance of hydrogen in Australia.<br/>This information has come from Woodside Energy Ltd by engaging with small businesses government regulators and the community at large. As we establish community acceptance for hydrogen as an energy carrier in Australia Woodside has been working in parallel to have standards and regulations established for hydrogen in Australia. Through our work with Hydrogen Mobility Australia we are advocating the adoption of ISO standards unless there is a specific geographic or health safety and environment reason not to.
Safety Concept of Nuclear Cogeneration of Hydrogen and Electricity
Oct 2015
Publication
There is a significant potential for nuclear combined heat and power (CHP) in quite a number of industries. The reactor concepts of the next generation would be capable to open up in particular the high temperature heat market where nuclear energy is applicable to the production processes of hydrogen (or liquid fuels) by steam reforming or water splitting. Due to the need to locate a nuclear facility near the hydrogen plant an overall safety concept has to deal with the question of safety of the combined nuclear/industrial system by taking into account a qualitatively new class of events characterized by interacting influences. Specific requirements will be determined by such factors as the reactor type the nature of the industrial process the separation distances of the industrial facility and population centers from the nuclear plant and prevailing public attitudes. Based on the Japanese concept of the GTHTR300C nuclear reactor for electricity and hydrogen cogeneration theoretical studies were conducted on the release dispersive transport and explosion of a hydrogen cloud in the atmosphere for the sake of assessing the required minimum separation distance to avoid any risk to the nuclear plant's safety systems. In the case of sulfur-iodine water splitting the accidental release of process intermediates including large amounts of sulfur dioxide sulfur trioxide and sulfuric acid need to be investigated as well to estimate the potential risk to nuclear installations like the operators' room and estimate appropriate separation distances against toxic gas propagation. Results of respective simulation studies will be presented.
HIAD 2.0 – Hydrogen Incident and Accident Database
Sep 2019
Publication
Hydrogen technologies are expected to play a key role in implementing the transition from a fossil fuel- based to a more sustainable lower-carbon energy system. To facilitate their widespread deployment the safe operation and hydrogen systems needs to be ensured together with the evaluation of the associated risk.<br/>HIAD has been designed to be a collaborative and communicative web-based information platform holding high quality information of accidents and incidents related to hydrogen technologies. The main goal of HIAD was to become not only a standard industrial accident database but also an open communication platform suitable for safety lessons learned and risk communication as well as a potential data source for risk assessment; it has been set up to improve the understanding of hydrogen unintended events to identify measures and strategies to avoid incidents/accidents and to reduce the consequence if an accident occurs.<br/>In order to achieve that goal the data collection is characterized by a significant degree of detail and information about recorded events (e.g. causes physical consequences lesson learned). Data are related not only to real incident and accidents but also to hazardous situations.<br/>The concept of a hydrogen accident database was generated in the frame of the project HySafe an EC co-funded NoE of the 6th Frame Work Programme. HIAD was built by EC-JRC and populated by many HySafe partners. After the end of the project the database has been maintained and populated by JRC with publicly available events. The original idea was to provide a tool also for quantitative risk assessment able to conduct simple analyses of the events; unfortunately that goal could not be reached because of a lack of required statistics: it was not possible to establish a link with potential event providers coming from private sector not willing to share information considered confidential. Starting from June 2016 JRC has been developing a new version of the database (i.e. HIAD 2.0); the structure of the database and the web-interface have been redefined and simplified resulting in a streamlined user interface compared to the previous version of HIAD. The new version is mainly focused to facilitate the sharing of lessons learned and other relevant information related to hydrogen technology; the database will be public and the events will be anonymized. The database will contribute to improve the safety awareness fostering the users to benefit from the experiences of others as well as to share information from their own experiences.
Formation and Dissociation Behaviour Studies of Hydrogen Hydrate in the Presence of Tetrahydrofuran by using High Pressure DSC
Mar 2019
Publication
Significant challenges still remain in the development of suitable materials for storing hydrogen for practical applications. Clathrate hydrates as a special inclusion compounds could be tailored by changing the storage pressure and temperature to adapt ambient conditions. In this work the hydrates were adopted to encage hydrogen in tetrahydrofuran (THF) aqueous solution with concentration of 3.0 mol%. The formation and dissociation behaviours were investigated by a high pressure micro-differential scanning calorimeter at the operating pressure of 18 MPa 25 MPa and 34 MPa. Experimental results show that the memory water only affects the hydrate formation behaviour instead of the hydrate dissociation behaviour. The dissociation temperature of the THF-H2 hydrate increases with the increase of the operating pressure and its dissociation equilibrium data can be obtained. The dissociation temperatures of the THF-H2 hydrate are 9.26 ℃ 10.94 ℃ and 12.67 ℃ at the operating pressure of 18 MPa 25 MPa and 34 MPa respectively. It is fundamental for performing the kinetics and microscopic experiments.
Flame Propagation Near the Limiting Conditions in a Thin Layer Geometry
Sep 2019
Publication
A series of experiments on hydrogen flame propagation in a thin layer geometry is presented. Premixed hydrogen-air compositions in the range from 6 to 15%(vol.) H2 are tested. Semi-open vertical combustion chamber consists of two transparent Plexiglas side walls with main dimensions of 90x20 cm with a gap from 1 to 10 mm in between. Test mixtures are ignited at the open end of the chamber so that the flame propagates towards the closed end. Ignition position changes from top to bottom in order to take into account an effect of gravity on flame propagation regimes. High-speed shadow imaging is used to visualize and record the combustion process. Thermal-diffusion and Darrieus-Landau instabilities are governing the general flame behaviour. Heat losses to side walls and viscous friction in a thin layer may fully suppress the flame propagation with local or global extinction. The sensitivity to heat losses can be characterized using a Peclet number as a ratio of layer thickness to laminar flame thickness. Approaching to critical Peclet number Pec = 42 the planar or wrinkled flame surface degradants to one-or two-heads "finger" flame propagating straight (for two-heads flame) or chaotic (for one-head "finger" flame). Such a "fingering" of the flame is found for the first time for gaseous systems and very similar to that reported for smouldering or filtering combustion of solid materials and also under micro-gravity conditions. The distance between "fingers" may depend on deficit of limiting component. The processes investigated can be very important from academic and practical points of view with respect to safety of hydrogen fuel cells.
Hydrogen for Renewable Energy Export: Broadening the Concept of Hydrogen Safety
Sep 2019
Publication
Recently we have seen hydrogen (re)emerge as an important component of widespread decarbonisation of energy sectors. From an Australian perspective this brings with it an opportunity to store transport and export renewable energy—either as liquefied hydrogen or in a carrier such as ammonia. The growth of the hydrogen industry to now include the power and transport sectors as well as the notion of hydrogen export has broadened the range of safety considerations required and seen them extend into the realm of the consumer for the first time.<br/>Hydrogen as well as ammonia and other carriers such as methanol are existing industrial chemicals which have established protocols for their handling and use in the chemicals sector. As their use in energy and transport increases especially in the context of widespread domestic use their handling and use by inexperienced people in less-controlled environments expands shifting the risk profiles and management systems required. There is also the potential for novel hydrogen carriers such as methylcyclohexane/toluene to reach commercial viability at industrial scale.<br/>This paper will discuss some of these emerging applications of hydrogen and its carriers and discuss some of the technological innovations under development that may accompany a new energy industry— with some consideration given to their potential risks and the required safety considerations. In addition we will also provide an overview of global activity in this area and how new standards and regulations would need to be developed for the adaption of these technologies in an Australian context.
Quantifying the Potential Consequences of a Detonation in a Hydrogen Jet Release
Sep 2019
Publication
The unconfined release of high-pressure hydrogen can create a large flammable jet with the potential to generate significant damage. To properly understand the separation distances necessary to protect the immediate surroundings it is important to accurately assess the potential consequences. In these events the possibility for a detonation cannot be excluded and would generally result in the worst case scenario from the standpoint of damaging overpressure. The strong concentration gradients created by a jet release however raises the question of what portion of the flammable cloud should be considered. Often all of the fuel within the limits of fast-flame acceleration or even all of the fuel within the flammability range is considered which typically comprises the majority of the flammable cloud. In this work prior detonation studies are reviewed to illustrate the inherently unstable nature of detonations with a focus on the critical dimensions and concentration gradients that can support a propagating detonation wave. These criteria are then applied to the flammable cloud concentration distributions generated by an unconfined jet release of hydrogen. By evaluating these limits it is found that the portion of the flammable cloud that is likely to participate is significantly reduced. These results are compared with existing experimental data on the ignition of unconfined hydrogen releases and the peak pressures that were measured are consistent with a detonation of a mass of fuel that is equivalent to the model prediction for the mass of fuel within the detonable limits. This work demonstrates how the critical conditions for detonation propagation can be used to estimate the portion of a hydrogen release that could participates in a detonation and how these criteria can be readily incorporated into existing dispersion modelling approaches.
Cautiously Optimistic: Understanding the Australian Public’s Response to the Hydrogen Opportunity
Sep 2019
Publication
The increased activity across the technical world for developing hydrogen has not gone unnoticed at the political level. However there remains a gap in understanding of how the general public will respond to the development of such an emergent industry. Recognising this gap we undertook ten focus groups (N=92) and a nationally representative online survey (N=2785) with the Australian public to better understand their response to hydrogen and the opportunities it presents for export and domestic use. In both focus groups and the national survey when Australians first heard the word hydrogen they were most likely to respond with a neutral response. For example in the survey 81% responded with words such as gas energy water; with only 13% giving negative associations (e.g. bomb explosion Hindenburg); and 3% positive (e.g. clean future). Males were more likely to be supportive of hydrogen than females. Those who answered more knowledge questions correctly were also more supportive. The main benefits associated with the use of hydrogen technologies centred around the environment - reduced greenhouse gas emissions and climate change mitigation potential were key benefits. With safety cost and environmental impacts - particularly concerns around pollution emissions and water use - being the most frequently cited concerns about the production and use of hydrogen. This presentation focuses on Australian attitudes to the developing hydrogen export opportunity and also for domestic use. Implications for industry and policy makers will be discussed in light of these Australians responses.
Application of Natural Ventilation Engineering Models to Hydrogen Build Up in Confined Zones
Sep 2013
Publication
Correlative engineering models (Linden 1994) are compared to recent published (Cariteau et al. (2009) Pitts et al. (2009) Barley and Gawlick (2009) Swain et al. (1999) Merilo et al. (2010)) and unpublished (CEA experiments in a 1 m3 with two openings) experimental hydrogen or helium distribution in enclosures (with one and two openings). The modelling-experiments comparison is carried out in transient and in steady state conditions. On this basis recommendations and limits of use of these models are proposed.
Kinetic Model of Incipient Hydride Formation in Zr Clad under Dynamic Oxide Growth Conditions
Feb 2020
Publication
The formation of elongated zirconium hydride platelets during corrosion of nuclear fuel clad is linked to its premature failure due to embrittlement and delayed hydride cracking. Despite their importance however most existing models of hydride nucleation and growth in Zr alloys are phenomenological and lack sufficient physical detail to become predictive under the variety of conditions found in nuclear reactors during operation. Moreover most models ignore the dynamic nature of clad oxidation which requires that hydrogen transport and precipitation be considered in a scenario where the oxide layer is continuously growing at the expense of the metal substrate. In this paper we perform simulations of hydride formation in Zr clads with a moving oxide/metal boundary using a stochastic kinetic diffusion/reaction model parameterized with state-of-the-art defect and solute energetics. Our model uses the solutions of the hydrogen diffusion problem across an increasingly-coarse oxide layer to define boundary conditions for the kinetic simulations of hydrogen penetration precipitation and dissolution in the metal clad. Our method captures the spatial dependence of the problem by discretizing all spatial derivatives using a stochastic finite difference scheme. Our results include hydride number densities and size distributions along the radial coordinate of the clad for the first 1.6 h of evolution providing a quantitative picture of hydride incipient nucleation and growth under clad service conditions.
Hydrogen-powered Vehicles in Urban Transport Systems – Current State and Development
Mar 2020
Publication
The work is dedicated to the possibility of using hydrogen-powered vehicles in urban transport systems. Due to the need to look for alternative solutions for vehicles with conventional drive in cities hydrogen-powered cars are one of the practical possibilities of realizing the sustainable transport assumptions and independence from oil imports - which is one of the main priorities of the European Union. This paper presents a literature analysis the analysis of the current state and development of use hydrogen-powered vehicles in the world.<br/>The article refers to the possibilities of use hydrogen-vehicles in different ways of mobility: individual vehicles taxis and shared mobility. In addition the author focused on showing the advantages and disadvantages of using hydrogen-powered vehicles in urban transport systems.
Changing the Fate of Fuel Cell Vehicles: Can lessons be Learnt from Tesla Motors?
Dec 2014
Publication
Fuel Cell Vehicles (FCVs) are a disruptive innovation and are currently looking towards niche market entry. However commercialisation has been unsuccessful thus far and there is a limited amount of literature that can guide their market entry. In this paper a historical case study is undertaken which looks at Tesla Motors high-end encroachment market entry strategy. FCVs have been compared to Tesla vehicles due to their similarities; both are disruptive innovations both are high cost and both are zero emission vehicles. Therefore this paper looks at what can be learned form Tesla Motors successful market entry strategy and proposes a market entry strategy for FCVs. It was found that FCVs need to enact a paradigm shift from their current market entry strategy to one of high-end encroachment. When this has been achieved FCVs will have greater potential for market penetration.
European Hydrogen Safety Panel (EHSP)
Sep 2019
Publication
Inaki Azkarate,
Marco Carcassi,
Francesco Dolci,
Alberto Garcia-Hombrados,
Stuart J. Hawksworth,
Thomas Jordan,
Georg W. Mair,
Daniele Melideo,
Vladimir V. Molkov,
Pietro Moretto,
Ernst Arndt Reinecke,
Pratap Sathiah,
Ulrich Schmidtchen,
Trygve Skjold,
Etienne Studer,
Tom Van Esbroeck,
Elena Vyazmina,
Jennifer Xiaoling Wen,
Jianjun Xiao and
Joachim Grüne
The FCH 2 JU launched the European Hydrogen Safety Panel (EHSP) initiative in 2017. The mission of the EHSP is to assist the FCH 2 JU both at programme and at project level in assuring that hydrogen safety is adequately managed and to promote and disseminate H2 safety culture within and outside of the FCH 2 JU programme. The EHSP is composed of a multidisciplinary pool of safety experts grouped in ad-hoc working groups (task forces) according to the tasks to be performed and to expertise. The scope and activities of the EHSP are structured around four main areas:
TF.1. Support at project level The EHSP task under this category includes the development of measures to avoid any accident by integrating safety learnings expertise and planning into FCH 2 JU funded projects and by ensuring that all projects address and incorporate the state-of-the-art in hydrogen safety appropriately. To this end a Safety guidance document for hydrogen and fuel cell projects will be produced.
TF.2. Support at programme level Activities under this category include answering questions related to hydrogen safety in an independent coordinated and consolidated way via hotline-support or if necessary via physical presence of safety representative at the FCH 2 JU. It could also include a short introduction to hydrogen safety and the provision of specific guidelines for the handling storage and use of hydrogen in the public domain. As a start a clear strategy on this should be developed and therefore related M ulti-annual work plan 2018-2020.
TF.3. Data collection and assessment The EHSP tasks include the analysis of existing events already introduced in the European Hydrogen Safety Reference Database (HIAD) and of new information from relevant mishaps incidents or accidents. The EHSP should therefore derive lessons learned and provide together with the involved parties further general recommendations to all stakeholders based on these data. For 2018 the following deliverables should be produced: methodology to collect inputs from projects and to provide lessons learned and guidelines assessment and lessons learned from HIAD and a report on research progress in the field of hydrogen safety.
TF.4. Public outreach Framed within the context of the intended broad information exchange the EHSP tasks under this category include the development of a regularly updated webpage hosted on the FCH 2 JU website.
Heat Transfer Analysis for Fast Filling of On-board Hydrogen Tank
Mar 2019
Publication
The heat transfer analysis in the filling process of compressed on-board hydrogen storage tank has been the focus of hydrogen storage research. The initial conditions mass flow rate and heat transfer coefficient have certain influence on the hydrogen filling performance. In this paper the effects of mass flow rate and heat transfer coefficient on hydrogen filling performance are mainly studied. A thermodynamic model of the compressed hydrogen storage tank was established by Matlab/Simulink. This 0D model is utilized to predict the hydrogen temperature hydrogen pressure tank wall temperature and SOC (State of Charge) during filling process. Comparing the simulated results with the experimental data the practicability of the model can be verified. The simulated results have certain meaning for improving the hydrogenation parameters in real filling process. And the model has a great significance to the study of hydrogen filling and purification.
The Pressure Peaking Phenomenon: Validation for Unignited Releases in Laboratory-scale Enclosure
Oct 2015
Publication
This study is aimed at the validation of the pressure peaking phenomenon against laboratory-scale experiments. The phenomenon was discovered recently as a result of analytical and numerical studies performed at Ulster University. The phenomenon is characterized by the existence of a peak on the overpressure transient in an enclosure with vent(s) at some conditions. The peak overpressure can significantly exceed the steady-state pressure and jeopardise a civil structure integrity causing serious life safety and property protection problems. However the experimental validation of the phenomenon was absent until recently. The validation experiments were performed at Karlsruhe Institute of Technology within the framework of the HyIndoor project. Tests were carried out with release of three different gases (air helium and hydrogen) within a laboratory-scale enclosure of about 1 m3 volume with a vent of comparatively small size. The model of pressure peaking phenomenon reproduced closely the experimental pressure dynamics within the enclosure for all three used gases. The prediction of pressure peaking phenomenon consists of two steps which are explained in detail. Examples of calculation for typical hydrogen applications are presented.
Experimental Study on Hydrogen/Air Premixed Flame Propagation in Closed Rectangular Channels
Sep 2019
Publication
An experimental study of hydrogen/air premixed flame propagation in a closed rectangular channel with the inhibitions (N2 or CO2) was conducted to investigate the inhibiting effect of N2 and CO2 on the flame properties during its propagation. Both Schlieren system and the pressure sensor were used to capture the evolution of flame shape and pressure changes in the channel. It was found that both N2 and CO2 have considerable inhibiting effect on hydrogen/air premixed flames. Compared with N2 CO2 has more prominent inhibition which has been interpreted from thermal and kinetic standpoints. In all the flames the classic tulip shape was observed. With different inhibitor concentration the flame demonstrated three types of deformation after the classic tulip inversion. A simple theoretical analysis has also been conducted to indicate that the pressure wave generated upon the first flame-wall contact can affect the flame deformation depending on its meeting moment with the flame front. Most importantly the meeting moment is always behind the start of tulip inversion which suggests the non-dominant role of pressure wave on this featured phenomenon.
The Future of the UK Gas Network
Jun 2013
Publication
The UK has an extensive natural gas pipeline network supplying 84% of homes. Previous studies of decarbonisation pathways using the UK MARKAL energy system model have concluded that the low pressure gas networks should be mostly abandoned by 2050. yet most of the iron pipes near buildings are currently being replaced early for safety reasons. Our study suggests that this programme will not lock-in the use of gas in the long-term. We examine potential future uses of the gas network in the UK energy system using an improved version of UK MARKAL that introduces a number of decarbonisation options for the gas network including bio-methane hydrogen injection to the natural gas and conversion of the network to deliver hydrogen.<br/>We conclude that hydrogen conversion is the only gas decarbonisation option that might enable the gas networks to continue supplying energy to most buildings in the long-term from a cost-optimal perspective. There is an opportunity for the government to adopt a longt erm strategy for the gas distribution networks that either curtails the iron mains replacement programme or alters it to prepare the network for hydrogen conversion; both options could substantially reduce the long-term cost of supplying heat to UK buildings.
An Inter-comparison Exercise on Engineering Models Capabilities to Simulate Hydrogen Vented Explosions
Sep 2013
Publication
A benchmark exercise on vented explosion engineering model was carried out against the maximum overpressures (one or two peaks) of published experiments. The models evaluated are Bauwens et al. (2012-1 and 2012-2) [4 7] models Molkov Vent Sizing Technology 1999 2001 and 2008 models [12 13 6]. The experiments in consideration are Pasman et al. experiments (1974) (30% H2 - 1m3) [1] Bauwens et al. (2012) experiments (64m3) [4] Daubech et al. (2011) experiments (10 to 30% H2 - 1 and 10 m3) [2] and Daubech et al. (2013) [5] experiments (4 m3 – H2 10 to 30%). On this basis recommendations and limits of use of these models are proposed.
Self-acceleration of a Spherically Expanding Hydrogen-air Flame at Elevated Pressure
Sep 2019
Publication
Self-acceleration of a spherically expanding hydrogen-air flame was experimentally investigated in a closed dual-chamber apparatus with the quartz windows enabled to a flame diameter with up to 240 mm. The flame radius and flame speed in lean hydrogen-air mixtures at elevated pressure were evaluated using a high speed Schlieren photography. The experimental results from hydrogen-air explosion at elevated pressure validated the prediction model for self-similar propagation. The flame radius and its speed calculated by the prediction models agree well with the experimental results of hydrogen-air explosions at elevated pressure. Furthermore the acceleration exponent α is evaluated by plotting the flame radius with time. The results show the α value increase with the dimensionless flame radius r/rcl. It is indicated that the self-acceleration and the transition regime to self-similar propagation exist in the spherically expanding hydrogen-air flame.
Integrating IT-SOFC and Gasification Combined Cycle with Methanation Reactor and Hydrogen Firing for Near Zero-emission Power Generation from Coal
Apr 2011
Publication
Application of Solid Oxide Fuel Cells (SOFC) in gasification-based power plants would represent a turning point in the power generation sector allowing to considerably increase the electric efficiency of coal-fired power stations while reducing CO2 and other pollutant emissions. The aim of this paper is the thermodynamic assessment of a SOFC-based IGFC plant with methanation reactor hydrogen post-firing and CO2 capture by physical absorption. The configuration proposed allows to obtain a very high net efficiency (51.6%) overcoming the main limits of configurations assessed in previous works.
Detonation Dynamics in a Curved Chamber for an Argon Diluted Hydrogen-oxygen Mixture
Sep 2019
Publication
The dynamics of detonation transmission from a straight channel into a curved chamber was investigated as a function of initial pressure using a combined experimental and numerical study. Hi-speed Schlieren and *OH chemiluminescense were used for flow visualization; numerical simulations considered the two-dimensional reactive Euler equations with detailed chemistry. Results show the highly transient sequence of events (i.e. detonation diffraction re-initiation attempts and wave reflections) that precede the formation of a steadily rotating Mach detonation along the outer wall of the chamber. An increase in pressure from 15 kPa to 26 kPa expectedly resulted in detonations that are less sensitive to diffraction. Local quenching of the initial detonation occurred for all pressures considered. The location where this decoupling occurred along the inner wall determined the location where transition from regular reflection to a rather complex wave structure occurred along the outer wall. This complex wave structure includes a steadily rotating Mach detonation (stem) an incident decoupled shock-reaction zone region and a transverse detonation that propagates in pre-shocked mixture.
H-Mat Hydrogen Compatibility of Polymers and Elastomers
Sep 2019
Publication
The H2@Scale program of the U.S. Department of Energy (DOE) Fuel Cell Technologies Office is supporting work on the hydrogen compatibility of polymers to improve the durability and reliability of materials for hydrogen infrastructure. The hydrogen compatibility program (H-Mat) seeks “to address the challenges of hydrogen degradation by elucidating the mechanisms of hydrogen-materials interactions with the goal of providing science-based strategies to design materials (micro)structures and morphology with improved resistance to hydrogen degradation.” This research has found hydrogen and pressure interactions with model rubber-material compounds demonstrating volume change and compression-set differences in the materials. The research leverages state-of-the-art capabilities of the DOE national labs. The materials were investigated using helium-ion microscopy which revealed significant morphological changes in the plasticizer incorporating compounds after exposure as evidenced by time-of-flight secondary ion mass spectrometry. Additional studies using transmission electron microscopy and nuclear magnetic resonance revealed that nanosized inclusions developed after gas decompression in rubber- and plasticizer-only materials; this is an indication of void formation at the nanometer level.
Framing Policy on Low Emissions Vehicles in Terms of Economic Gains: Might the Most Straightforward Gain be Delivered by Supply Chain Activity to Support Refuelling?
May 2018
Publication
A core theme of the UK Government's new Industrial Strategy is exploiting opportunities for domestic supply chain development. This extends to a special ‘Automotive Sector Deal’ that focuses on the shift to low emissions vehicles (LEVs). Here attention is on electric vehicle and battery production and innovation. In this paper we argue that a more straightforward gain in terms of framing policy around potential economic benefits may be made through supply chain activity to support refuelling of battery/hydrogen vehicles. We set this in the context of LEV refuelling supply chains potentially replicating the strength of domestic upstream linkages observed in the UK electricity and/or gas industries. We use input-output multiplier analysis to deconstruct and assess the structure of these supply chains relative to that of more import-intensive petrol and diesel supply. A crucial multiplier result is that for every £1million of spending on electricity (or gas) 8 full-time equivalent jobs are supported throughout the UK. This compares to less than 3 in the case of petrol/diesel supply. Moreover the importance of service industries becomes apparent with 67% of indirect and induced supply chain employment to support electricity generation being located in services industries. The comparable figure for GDP is 42%.
HyP SA – Our safety story
Sep 2019
Publication
Australian Gas Infrastructure Group’s (AGIG’s) vision is to be the leading gas infrastructure business in Australia this means delivering for our customers being a good employer and being sustainably cost efficient. Establishing and developing a hydrogen industry is a key pathway for us to achieve our vision.
In South Australia AGIG is pioneering the introduction of hydrogen into its existing gas distribution networks through the Hydrogen Park South Australia (HyP SA) project. With safety our top priority we would like to give an overview of the safety considerations of our site our network methodology and the development of new safety procedures and culture regarding the production handling and reticulation of a 5% hydrogen blend.
We will cover three themes each having a safety story that is specific to the Australian context and to the project’s success:
The Production Plant and Site
Project site safety known hazards and risk mitigation electrical protection safety procedures lighting and security. Hydrogen storage filling and transportation.
The Network
Securing the network for an isolated safe demonstration footprint. Gas network and hydrogen safety considerations why 5%? Emergency procedures and crew training. New safety regulations blended networks. How does hydrogen perform in a blended gas with respect to leaks? How safe is the existing network and what sensors and controls are we using.
The Home
Introducing blended gas to existing homes. Appliance safety and failure mode analysis. Community engagement and education on a 5% renewable hydrogen gas blend and use in the home
.
We aim to give a comprehensive overview of delivering a safe demonstration network for the HyP SA project in terms of the three main ecosystems that the hydrogen will be present our learnings so far and the development of the safety methodologies that will be applied in the industry in the future.
In South Australia AGIG is pioneering the introduction of hydrogen into its existing gas distribution networks through the Hydrogen Park South Australia (HyP SA) project. With safety our top priority we would like to give an overview of the safety considerations of our site our network methodology and the development of new safety procedures and culture regarding the production handling and reticulation of a 5% hydrogen blend.
We will cover three themes each having a safety story that is specific to the Australian context and to the project’s success:
The Production Plant and Site
Project site safety known hazards and risk mitigation electrical protection safety procedures lighting and security. Hydrogen storage filling and transportation.
The Network
Securing the network for an isolated safe demonstration footprint. Gas network and hydrogen safety considerations why 5%? Emergency procedures and crew training. New safety regulations blended networks. How does hydrogen perform in a blended gas with respect to leaks? How safe is the existing network and what sensors and controls are we using.
The Home
Introducing blended gas to existing homes. Appliance safety and failure mode analysis. Community engagement and education on a 5% renewable hydrogen gas blend and use in the home
.
We aim to give a comprehensive overview of delivering a safe demonstration network for the HyP SA project in terms of the three main ecosystems that the hydrogen will be present our learnings so far and the development of the safety methodologies that will be applied in the industry in the future.
Simulation of Hydrogen Dispersion under Cryogenic Release Conditions
Sep 2013
Publication
The use of hydrogen as fuel should always be accompanied by a safety assessment in case of an accidental release. To evaluate the potential hazards in a spill accident both experiments and simulations are performed. In the present work the CFD code ADREA-HF is used to simulate the liquefied hydrogen (LH2) spill experiments (test 5 6 7) conducted by the Health and Safety Laboratory (HSL). In these tests LH2 was spilled at a fixed rate of 60lt/min in several directions and for several durations. The factors that influence the vapor dispersion under cryogenic release conditions that were examined in this study are: the air humidity the wind direction and the slip effect of droplets formed by both the cryogenic liquid and the condensation of air humidity. The numerical results were compared with the experimental measurements and the effect of each abovementioned factors in the vapor dispersion is being discussed.
Safe Hydrogen Fuel Handling and Use for Efficient Implementation – SH2IFT
Sep 2019
Publication
The SH2IFT project combines social and technical scientific methods to address knowledge gaps regarding safe handling and use of gaseous and liquid hydrogen. Theoretical approaches will be complemented by fire and explosion experiments with emphasis on topics of strategic importance to Norway such as tunnel safety maritime applications etc. Experiments include Rapid Phase Transition Boiling Liquid Expanding Vapour Explosion and jet fires. This paper gives an overview of the project and preliminary results.
Membrane Based Purification of Hydrogen System (MEMPHYS)
Feb 2019
Publication
A hydrogen purification system based on the technology of the electrochemical hydrogen compression and purification is introduced. This system is developed within the scope of the project MEMPHYS. Therefore the project its targets and the different work stages are presented. The technology of the electrochemical purification and the state of the art of hydrogen purification are described. Early measurements in the project have been carried out and the results are shown and discussed. The ability of the technology to recover hydrogen from a gas mixture can be recognized and an outlook into further optimizations shows the future potential. A big advantage is the simultaneous compression of the purified hydrogen up to 200 bar therefore facilitating the transportation and storage.
Chitosan Flocculation Associated with Biofilms of C. Saccharolyticus and C. Owensensis Enhances Biomass Retention in a CSTR
Jun 2021
Publication
Cell immobilization and co-culture techniques have gained attention due to its potential to obtain high volumetric hydrogen productivities (QH2). Chitosan retained biomass in the fermentation of co-cultures of Caldicellulosiruptor saccharolyticus and C. owensensis efficiently up to a maximum dilution rate (D) of 0.9 h−1. Without chitosan wash out of the co-culture occurred earlier accompanied with approximately 50% drop in QH2 (D > 0.4 h−1). However butyl rubber did not show as much potential as carrier material; it did neither improve QH2 nor biomass retention in continuous culture. The population dynamics revealed that C. owensensis was the dominant species (95%) in the presence of chitosan whereas C. saccharolyticus was the predominant (99%) during cultivation without chitosan. In contrast the co-culture with rubber as carrier maintained the relative population ratios around 1:1. This study highlighted chitosan as an effective potential carrier for immobilization thereby paving the way for cost – effective hydrogen production.
Delivering a Safe, Viable Hydrogen Economy in Australia
Sep 2019
Publication
At Woodside Energy Ltd (Woodside) safety is built into everything we do and progressing hydrogen opportunities is no exception. This paper will present information from the macro level of process safety for hydrogen at a plant level through to the consumer experience. Examples of the benefits of an integrated process safety approach will be used from Woodside’s experience pioneering the liquefied natural gas industry in Australia.<br/>This paper will underscore the reasons why Australia needs to adopt robust safety standards for hydrogen as quickly as possible in order to advance the hydrogen economy across all sectors. Focus areas requiring attention during development of standards and potential mechanisms to close will be proposed. Establishing a hydrogen economy in Australia could lower carbon emissions stabilise power grids increase renewable energy penetration and create jobs. Developing Australian standards that are fully aligned with international standards will facilitate Australia taking a leading role in the global hydrogen economy.
Homogeneous and Inhomogeneous Hydrogen Deflagrations in 25 m3 Enclosure
Sep 2019
Publication
Explosion venting is a frequently used measure to mitigate the consequence of gas deflagrations in closed environments. Despite the effort to predict the vent area needed to achieved the protection through engineering formulas and CFD tools work has still to be done to reliably predict the outcome of a vented gas explosion. Most of available data derived from experimental campaigns performed in the past involved homogeneous conditions while especially in the case of a very buoyant gas such as hydrogen the most probable scenario that can follow and unintended release in a closed environment foresee the ignition of a stratified inhomogeneous mixture. University of Pisa performed experimental tests in a 25 m3 facility in homogeneous and inhomogeneous conditions. The present paper is aimed to share the results of hydrogen dispersion and deflagration tests and discuss the comparison of maximum peak overpressure generated in the two scenarios. Description of the experimental set-up includes all the details deemed necessary to reproduce the phenomenon with a CFD tool.
Dependency of Equivalence Ratio on Hydrogen Cylindrical Detonation Induced by Direct Initiation
Sep 2011
Publication
A hydrogen fuel is expected to expand its demand in the future. However hydrogen has to be treated with enough caution because of wide combustible conditions and easiness to ignite. Detonation accidents are caused in hydrogen gas such as the explosion accident in Fukushima first nuclear plant (2011). Therefore it is necessary to comprehend initiation conditions of detonation to prevent its detonation explosion. In the present study cylindrical detonation induced by direct initiation is simulated to understand the dependency of equivalence ratios in hydrogen-oxygen mixture. The several detailed kinetic models are compared to select the most appropriate model for detonation in a wide range of equivalence ratios. The Petersen-Hanson model is used in the present study due to the best agreement among the other models. In the numerical results of cylindrical detonation induced by direct initiation a cellular structure which is similar to the experimental smoked foil record is observed. The local pressure is up to 12 MPa under the condition at the standard state. The ignition process of cylindrical detonation has two stages. At the first stage the normalized cell width /L1/2 at each equivalence ratio increases linearly. At the second stage cell bifurcations appear due to a generation of new transverse waves. It is observed that a transverse wave transforms to a transverse detonation at the end of the first stage and after that some disturbance is developed to be a new transverse wave at the beginning of the second stage.
Experimental Results on The Dispersion of Buoyant Gas in a Full Scale Garage from a Complex Source
Sep 2009
Publication
The lack of experimental data on hydrogen dispersion led to the experimental project DRIVE (Experimental Data for Hydrogen Automotive Risks Assessment for the validation of numerical tools and for the Edition of guidelines) that involves the CEA (French Atomic Energy Commission) the National Institute of Industrial Environment and Risks (INERIS) the French car manufacturer PSA PEUGEOT CITROËN and the Research Institute on Out of Equilibrium Phenomena (IRPHE). The CEA has developed an experimental setup named GARAGE in order to analyze the condition of formation of an explosive atmosphere in an enclosure. This is a full scale facility in which a real car can be parked. Hydrogen releases were simulated with helium which volume fraction was measured with mini-katharometers. These thermal conductivity probes allow spatial and time volume fraction variations measurements. We present experimental results on the dispersion of helium in the enclosure due to releases in a typical car. The tested parameters are the location of the source (engine bottom of the car storage) and the flow rate. Emphasis is put on the influence of these parameters on the time evolution of the volume fraction in the enclosure as well as on the vertical distribution of helium.
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