Applications & Pathways
Role of Batteries and Fuel Cells in Achieving Net Zero- Session 1
Mar 2021
Publication
The House of Lords Science and Technology Committee will question experts on the role of batteries and fuel cells for decarbonisation and how much they can contribute to meeting the net-zero target.
Tuesday’s evidence session will be the first of the committee’s new decarbonisation inquiry which was launched on Wednesday 3 March and is currently accepting written evidence submissions.
The session will give an overview of battery and fuel cell technologies and their applications in transport and other sectors. The Committee will ask how battery manufacture can be scaled up to meet wide-scale deployment of electric vehicles and whether technical challenges can be overcome to allow batteries and fuel cells to be used in HGVs and trains. The Committee will also investigate the wider use of batteries and fuel cells in various sectors including integration into power grids and heating systems.
Inquiry Role of batteries and fuel cells in achieving Net Zero
Professor Nigel Brandon Dean of the Faculty of Engineering at Imperial College London
Professor Mauro Pasta Associate Professor of Materials at University of Oxford
Professor Pam Thomas CEO at Faraday Institution and Pro Vice Chancellor for Research at University of Warwick
Mr Amer Gaffar Director of Manchester Fuel Cell Innovation Centre at Manchester Metropolitan University
Possible questions
What contribution are battery and fuel cell technologies currently making towards decarbonization in the UK?
What advances do we expect to see in battery and fuel cell technologies and over what timeframes?
How quickly can UK battery and fuel cell manufacture be scaled up to meet electrification demands?
What are the challenges facing technological innovation and deployment in heavy transport?
Are there any sectors where battery and fuel cell technologies are not currently used but could contribute to decarbonisation?
What are the life cycle environmental impacts of batteries and fuel cells?
Parliament TV video of the meeting
This is part one of a three part enquiry.
Part two can be found here and part three can be found here.
Tuesday’s evidence session will be the first of the committee’s new decarbonisation inquiry which was launched on Wednesday 3 March and is currently accepting written evidence submissions.
The session will give an overview of battery and fuel cell technologies and their applications in transport and other sectors. The Committee will ask how battery manufacture can be scaled up to meet wide-scale deployment of electric vehicles and whether technical challenges can be overcome to allow batteries and fuel cells to be used in HGVs and trains. The Committee will also investigate the wider use of batteries and fuel cells in various sectors including integration into power grids and heating systems.
Inquiry Role of batteries and fuel cells in achieving Net Zero
Professor Nigel Brandon Dean of the Faculty of Engineering at Imperial College London
Professor Mauro Pasta Associate Professor of Materials at University of Oxford
Professor Pam Thomas CEO at Faraday Institution and Pro Vice Chancellor for Research at University of Warwick
Mr Amer Gaffar Director of Manchester Fuel Cell Innovation Centre at Manchester Metropolitan University
Possible questions
What contribution are battery and fuel cell technologies currently making towards decarbonization in the UK?
What advances do we expect to see in battery and fuel cell technologies and over what timeframes?
How quickly can UK battery and fuel cell manufacture be scaled up to meet electrification demands?
What are the challenges facing technological innovation and deployment in heavy transport?
Are there any sectors where battery and fuel cell technologies are not currently used but could contribute to decarbonisation?
What are the life cycle environmental impacts of batteries and fuel cells?
Parliament TV video of the meeting
This is part one of a three part enquiry.
Part two can be found here and part three can be found here.
Hybrid Hydrogen PEM Fuel Cell and Batteries Without DC–DC Converter
Sep 2013
Publication
Concerns about greenhouse gases as well as the price and security of oil supply have acted as a spur to sustainable automobile development. The hydrogen fuel cells electric vehicle (HFCEV) is generally recognised by leading automobile manufacturers and scientists as one of the optimum technologies for long-term future low carbon vehicle. In a typical HFCEV power train a DC–DC converter is required to balance the voltage difference between the fuel cells (FCs) stack and batteries. However research shows that a considerable amount of energy generated by the hydrogen FCs stack is deplete during this conversion process as heat. This experiment aims to improve the power train efficiency by eliminating the DC–DC converter by finding the best combination of FC stack and batteries matching the size and capacity of the electrical components.
Holistic Energy Efficiency and Environmental Friendliness Model for Short-Sea Vessels with Alternative Power Systems Considering Realistic Fuel Pathways and Workloads
Apr 2022
Publication
Energy requirements push the shipping industry towards more energy-efficient ships while environmental regulations influence the development of environmentally friendly ships by replacing fossil fuels with alternatives. Current mathematical models for ship energy efficiency which set the analysis boundaries at the level of the ship power system are not able to consider alternative fuels as a powering option. In this paper the energy efficiency and emissions index are formulated for ships with alternative power systems considering three different impacts on the environment (global warming acidification and eutrophication) and realistic fuel pathways and workloads. Besides diesel applications of alternative powering options such as electricity methanol liquefied natural gas hydrogen and ammonia are considered. By extending the analysis boundaries from the ship power system to the complete fuel cycle it is possible to compare different ships within the considered fleet or a whole shipping sector from the viewpoint of energy efficiency and environmental friendliness. The applicability of the model is illustrated on the Croatian ro-ro passenger fleet. A technical measure of implementation of alternative fuels in combination with an operational measure of speed reduction results in an even greater emissions reduction and an increase in energy efficiency. Analysis of the impact of voluntary speed reduction for ships with different power systems resulted in the identification of the optimal combination of alternative fuel and speed reduction by a specific percentage from the ship design speed.
Environmental Sustainability of Renewable Hydrogen in Comparison with Conventional Cooking Fuels
Jun 2018
Publication
Hydrogen could be used as a ‘cleaner’ cooking fuel particularly in communities that rely on biomass and fossil fuels to reduce local pollution and related health effects. However hydrogen must be produced using sustainable feedstocks and energy sources to ensure that local impacts are not reduced at the expense of other impacts generated elsewhere in the life cycle. To this end this paper evaluates life cycle environmental impacts of renewable hydrogen produced in a proton-exchange membrane electrolyser using solar energy. The aim of the study is to find out if hydrogen produced in this system and used as a cooking fuel is environmentally sustainable in comparison with conventional cooking fuels typically used in developing countries such as liquefied petroleum gas (LPG) charcoal and firewood. The results suggest that hydrogen would reduce the climate change impact by 2.5–14 times to 0.04 kg CO2 eq./MJ compared to firewood (0.10 kg CO2 eq./MJ) and LPG (0.57 kg CO2 eq./MJ). Some other impacts would also be lower by 6%–35 times including depletion of fossil fuels summer smog and health effects from emissions of particulates both locally and across the rest of the life cycle. However some other impacts would increase by 6%–6.7 times such as depletion of metals and freshwater and marine ecotoxicity. These are mainly due to the solar photovoltaic panels used to generate power for the electrolyser. In terms of the local impacts the study suggests that hydrogen would reduce local pollution and related health impacts by 8%–35 times. However LPG is still environmentally a better option than hydrogen for most of the impacts both at the point of use and on a life cycle basis.
The Role of Hydrogen in Achieving Net Zero: Parliamentary Inquiry
Mar 2021
Publication
A key component of the Government's recently announced ‘Ten Point Plan for a Green Industrial Revolution’ is 'Driving the Growth of Low Carbon Hydrogen'. The plan outlined a range of measures to support the development and adoption of hydrogen including a £240 million 'Net Zero Hydrogen Fund'. Noting this and the further £81 million allocated for hydrogen heating trials in the 2020 Spending Review the House of Commons Science and Technology Committee is today launching a new inquiry into the role of hydrogen in achieving Net Zero.
Following recommendations from the Committee on Climate Change that the Government develop a strategy for hydrogen use and should aim for largescale hydrogen trials to begin in the early 2020s the Committee seeks to ensure that the Government's intended plan will be suitable and effective. The Committee will also assess the infrastructure required for hydrogen as a Net Zero fuel and examine progress made so far internationally to determine the viability of hydrogen as a significant contributor to achieving Net Zero.
All documents are in the Supplements tab above.
Following recommendations from the Committee on Climate Change that the Government develop a strategy for hydrogen use and should aim for largescale hydrogen trials to begin in the early 2020s the Committee seeks to ensure that the Government's intended plan will be suitable and effective. The Committee will also assess the infrastructure required for hydrogen as a Net Zero fuel and examine progress made so far internationally to determine the viability of hydrogen as a significant contributor to achieving Net Zero.
All documents are in the Supplements tab above.
Hydrogen for Transport Prospective Australian Use Cases
Oct 2019
Publication
The Australian transport sector is under increasing pressure to reduce carbon emissions whilst also managing a fuel supply chain that relies heavily on foreign import partners.
Transport in Australia equates to a significant proportion (approximately 18%) of the country’s total greenhouse gas emissions. Due to ongoing population growth these emissions have been steadily rising with the increase of cars on our roads and freight trucks in transit. Coupled with this the transport fuel supply chain is highly reliant on overseas partners – Australia currently imports 90% of its liquid fuel. These two challenges present an interesting dichotomy for the industry incentivising research and development into new technologies that can address one or both of these issues.
Hydrogen is one technology that has the potential to provide a reduction in greenhouse gas emissions as well as a more reliable domestic fuel supply. Hydrogen fuel cell electric vehicles (FCEVs) are an emerging zero-emission alternative for the transport sector which offer a variety of benefits.
You can read the full report on the Aurecon Australasia website at this link
Transport in Australia equates to a significant proportion (approximately 18%) of the country’s total greenhouse gas emissions. Due to ongoing population growth these emissions have been steadily rising with the increase of cars on our roads and freight trucks in transit. Coupled with this the transport fuel supply chain is highly reliant on overseas partners – Australia currently imports 90% of its liquid fuel. These two challenges present an interesting dichotomy for the industry incentivising research and development into new technologies that can address one or both of these issues.
Hydrogen is one technology that has the potential to provide a reduction in greenhouse gas emissions as well as a more reliable domestic fuel supply. Hydrogen fuel cell electric vehicles (FCEVs) are an emerging zero-emission alternative for the transport sector which offer a variety of benefits.
You can read the full report on the Aurecon Australasia website at this link
Roadmap to Decarbonising European Shipping
Nov 2018
Publication
Shipping is one of the largest greenhouse gas (GHG) emitting sectors of the global economy responsible for around 1 Gt of CO2eq every year. If shipping were a country it would be the 6th biggest GHG emitter. EU related shipping is responsible for about 1/5 of global ship GHG emissions emitting on average 200 Mt/year. This report assesses potential technology pathways for decarbonising EU related shipping through a shift to zero carbon technologies and the impact such a move could have on renewable electricity demand in Europe. It also identifies key policy and sustainability issues that should be considered when analysing and supporting different technology options to decarbonise the maritime sector. The basis of the study is outbound journeys under the geographical scope of the EU ship MRV Regulation.
We have not tried to quantify the emissions reductions that specific regulatory measures to be introduced at the IMO or EU level might contribute towards decarbonisation by 2050 because there are too many uncertainties. We have taken a more limited first approach and investigated how zero carbon propulsion pathways that currently seem feasible to decarbonise shipping would likely affect the future EU renewable energy supply needs.
It is now generally accepted that ship design efficiency requirements while potentially having an important impact on future emissions growth will fall well short of what is needed. Further operational efficiency measures such as capping operational speed will be important to immediately peak energy consumption and emissions but will be insufficient to decarbonise the sector or reduce its growing energy needs. In this context this study assumes that with all the likely immediate measures adopted energy demand for EU related shipping will still grow by 50% by 2050 over 2010 levels. This is within the range of the 20 -1 20% global BAU maritime energy demand growth estimate.
The decarbonisation of shipping will require changes in on -board energy storage and use and the necessary accompanying bunkering infrastructure. This study identifies the technology options for zero emission propulsion that based on current know-how are likely to be adopted. It is not exhaustive nor prescriptive because the ultimate pathways will likely depend on both the requirements of the shipping industry in terms of cost efficiency and safety and on the future renewable electricity sources that the shipping sect or will need to compete for.
Literature is nascent on the different techno-economic options likely to be available to decarbonise shipping and individual ships 4 but almost completely lacking on the possible impacts of maritime decarbonisation on the broader energy system(s). Understanding these impacts is nevertheless essential because it will influence financial and economic decision making by the EU and member states including those related to investment in future renewable energy supplies and new ship bunkering infrastructure. With this in mind the report aims to provide a preliminary first answer to the following question: Under different zero emission technology pathways how much additional renewable electricity would be needed to cater for the needs of EU related shipping in 2050?
Link to Document Download on Transport & Environment website
We have not tried to quantify the emissions reductions that specific regulatory measures to be introduced at the IMO or EU level might contribute towards decarbonisation by 2050 because there are too many uncertainties. We have taken a more limited first approach and investigated how zero carbon propulsion pathways that currently seem feasible to decarbonise shipping would likely affect the future EU renewable energy supply needs.
It is now generally accepted that ship design efficiency requirements while potentially having an important impact on future emissions growth will fall well short of what is needed. Further operational efficiency measures such as capping operational speed will be important to immediately peak energy consumption and emissions but will be insufficient to decarbonise the sector or reduce its growing energy needs. In this context this study assumes that with all the likely immediate measures adopted energy demand for EU related shipping will still grow by 50% by 2050 over 2010 levels. This is within the range of the 20 -1 20% global BAU maritime energy demand growth estimate.
The decarbonisation of shipping will require changes in on -board energy storage and use and the necessary accompanying bunkering infrastructure. This study identifies the technology options for zero emission propulsion that based on current know-how are likely to be adopted. It is not exhaustive nor prescriptive because the ultimate pathways will likely depend on both the requirements of the shipping industry in terms of cost efficiency and safety and on the future renewable electricity sources that the shipping sect or will need to compete for.
Literature is nascent on the different techno-economic options likely to be available to decarbonise shipping and individual ships 4 but almost completely lacking on the possible impacts of maritime decarbonisation on the broader energy system(s). Understanding these impacts is nevertheless essential because it will influence financial and economic decision making by the EU and member states including those related to investment in future renewable energy supplies and new ship bunkering infrastructure. With this in mind the report aims to provide a preliminary first answer to the following question: Under different zero emission technology pathways how much additional renewable electricity would be needed to cater for the needs of EU related shipping in 2050?
Link to Document Download on Transport & Environment website
Role of batteries and fuel cells in achieving Net Zero- Session 3
Mar 2021
Publication
The House of Lords Science and Technology Committee will hear from officials research funders and leading research consortia about the UK’s strategy for research and development of batteries and fuel cells to help meet the net-zero target.
The Committee will question officials from government departments and research councils about the UK’s increased support for battery development and how the initiatives and funding will evolve. The Committee will compare the support given to fuel cell research and ask how this technology will be developed for applications such as heavy transport. For both technologies it will ask how training will be delivered to provide a skilled workforce.
The Committee will also hear from leaders of research consortia asking them about support for their research sectors and how this compares with countries leading the development of the technologies. The Committee will explore coordination between research into batteries fuel cells and wider strategies such as for hydrogen and whether research for transport can be transferred to applications in other sectors such as power grids and heating.
At 10.00am: Oral evidence
Mr Tony Harper Industrial Strategy Challenge Director Faraday Battery Challenge at UK Research and Innovation (UKRI) at University of Central Lancashire
Dr Lucy Martin Deputy Director of Cross-Council Programmes and lead for Net Zero at University of Central Lancashire
Dr Bob Moran Deputy Director Head of Environment Strategy at University of Central Lancashire
Professor Paul Monks Chief Scientific Adviser at University of Central Lancashire
At 11.00am: Oral evidence
Professor Philip Taylor Director at EPSRC Supergen Energy Networks Hub and Pro-Vice Chancellor for Research and Enterprise at University of Bristol
Professor David Greenwood CEO High Value Manufacturing Catapult at University of Central Lancashire Director Industrial Engagement at University of Central Lancashire and Professor of Advanced Propulsion Systems at University of Warwick
Professor Paul Dodds Professor of Energy Systems at University of Central Lancashire
Possible questions
Parliament TV video of the meeting
This is part three of a three part enquiry.
Part one can be found here and part two can be found here.
The Committee will question officials from government departments and research councils about the UK’s increased support for battery development and how the initiatives and funding will evolve. The Committee will compare the support given to fuel cell research and ask how this technology will be developed for applications such as heavy transport. For both technologies it will ask how training will be delivered to provide a skilled workforce.
The Committee will also hear from leaders of research consortia asking them about support for their research sectors and how this compares with countries leading the development of the technologies. The Committee will explore coordination between research into batteries fuel cells and wider strategies such as for hydrogen and whether research for transport can be transferred to applications in other sectors such as power grids and heating.
At 10.00am: Oral evidence
Mr Tony Harper Industrial Strategy Challenge Director Faraday Battery Challenge at UK Research and Innovation (UKRI) at University of Central Lancashire
Dr Lucy Martin Deputy Director of Cross-Council Programmes and lead for Net Zero at University of Central Lancashire
Dr Bob Moran Deputy Director Head of Environment Strategy at University of Central Lancashire
Professor Paul Monks Chief Scientific Adviser at University of Central Lancashire
At 11.00am: Oral evidence
Professor Philip Taylor Director at EPSRC Supergen Energy Networks Hub and Pro-Vice Chancellor for Research and Enterprise at University of Bristol
Professor David Greenwood CEO High Value Manufacturing Catapult at University of Central Lancashire Director Industrial Engagement at University of Central Lancashire and Professor of Advanced Propulsion Systems at University of Warwick
Professor Paul Dodds Professor of Energy Systems at University of Central Lancashire
Possible questions
- On which aspects of battery and fuel cell research and development is the UK focusing and why?
- How successful have the UK’s new research initiatives been in advancing battery science and application?
- Does battery research receive greater public funding than fuel cell research? If so why?
- What technologies are seen as the most likely options for heavy transport i.e. HGVs buses and trains?
- What is the Government’s strategy for supporting the growth of skilled workers for battery and fuel cell research and development?
- To what extent is battery and fuel cell research and development coordinated in the UK? If so who is responsible for this coordination?
Parliament TV video of the meeting
This is part three of a three part enquiry.
Part one can be found here and part two can be found here.
Supporting Hydrogen Development in Australia Short Film
Jan 2021
Publication
This short film promotes Geoscience Australia's online and publicly accessible hydrogen data products. The film steps through the functionality of GA's Australian Hydrogen Opportunities Tool (AusH2) and describes the upcoming Hydrogen Economic Fairways Tool which has been created through a collaborative effort with Monash University.
Assessment of Full Life-cycle Air Emissions of Alternative Shipping Fuels
Oct 2017
Publication
There is a need for alternative fuels in the shipping sector for two main motivations: to deliver a reduction in local pollutants and comply with existing regulation; and to mitigate climate change and cut greenhouse gas emissions. However any alternative fuel must meet a range of criteria to become a viable option. Key among them is the requirement that it can deliver emissions reductions over its full life-cycle. For a set of fuels comprising both conventional and alternative fuels together with associated production pathways this paper presents a life-cycle assessment with respect to six emissions species: local pollutants sulphur oxides nitrogen oxides and particulate matter; and greenhouse gases carbon dioxide methane and nitrous oxide. While the analysis demonstrates that no widely available fuel exists currently to deliver on both motivations some alternative fuel options have the potential if key barriers can be overcome. Hydrogen or other synthetic fuels rely on decarbonisation of both energy input to production and other feedstock materials to deliver reductions in greenhouse gas emissions. Similarly bio-derived fuels can be an abatement option but only if it can be ensured that land-use change whilst growing biomass does not impact wider potential savings and the sector is able to compete sufficiently for their use. These examples show that crucial barriers are located upstream in the respective fuel life-cycle and that the way to overcome them may reside beyond the scope of the shipping sector alone.
Role of batteries and fuel cells in achieving Net Zero: Session 2
Mar 2021
Publication
The House of Lords Science and Technology Committee will hear from leading researchers about anticipated developments in batteries and fuel cells over the next ten years that could contribute to meeting the net-zero target.
The Committee continues its inquiry into the Role of batteries and fuel cells in achieving Net Zero. It will ask a panel of experts about batteries hearing about the current state-of-the-art in technologies that are currently in deployment primarily lithium-ion batteries. It will also explore the potential of next generation technologies currently in development and the challenges in scaling them up to manufacture.
The Committee will then question a second panel about fuel cells hearing about the different types available and their applications. It will explore challenges that need to be overcome in the development of the technology and will consider the UK’s international standing in the sector.
Meeting details
At 10.00am: Oral evidence
Professor Serena Corr Chair in Functional Nanomaterials and Director of Research Department of Chemical and Biological Engineering at University of Sheffield
Professor Paul Shearing Professor in Chemical Engineering at University College London
Dr Jerry Barker Founder and Chief Technology Officer at Faradion Limited
Dr Melanie Loveridge Associate Professor Warwick Manufacturing Group at University of Warwick
At 11.00am: Oral evidence
Professor Andrea Russell Professor of Physical Electrochemistry at University of Southampton
Professor Anthony Kucernak Professor of Physical Chemistry Faculty of Natural Sciences at Imperial College London
Professor John Irvine Professor School of Chemistry at University of St Andrews
Possible questions
Parliament TV video of the meeting
This is part two of a three part enquiry.
Part one can be found here and part three can be found here.
The Committee continues its inquiry into the Role of batteries and fuel cells in achieving Net Zero. It will ask a panel of experts about batteries hearing about the current state-of-the-art in technologies that are currently in deployment primarily lithium-ion batteries. It will also explore the potential of next generation technologies currently in development and the challenges in scaling them up to manufacture.
The Committee will then question a second panel about fuel cells hearing about the different types available and their applications. It will explore challenges that need to be overcome in the development of the technology and will consider the UK’s international standing in the sector.
Meeting details
At 10.00am: Oral evidence
Professor Serena Corr Chair in Functional Nanomaterials and Director of Research Department of Chemical and Biological Engineering at University of Sheffield
Professor Paul Shearing Professor in Chemical Engineering at University College London
Dr Jerry Barker Founder and Chief Technology Officer at Faradion Limited
Dr Melanie Loveridge Associate Professor Warwick Manufacturing Group at University of Warwick
At 11.00am: Oral evidence
Professor Andrea Russell Professor of Physical Electrochemistry at University of Southampton
Professor Anthony Kucernak Professor of Physical Chemistry Faculty of Natural Sciences at Imperial College London
Professor John Irvine Professor School of Chemistry at University of St Andrews
Possible questions
- What contribution are battery and fuel cell technologies currently making towards decarbonization in the UK?
- What advances do we expect to see in battery and fuel cell technologies and over what timeframes?
- How quickly can UK battery and fuel cell manufacture be scaled up to meet electrification demands?
- What are the challenges facing technological innovation and deployment in heavy transport?
- Are there any sectors where battery and fuel cell technologies are not currently used but could contribute to decarbonisation?
- What are the life cycle environmental impacts of batteries and fuel cells?
Parliament TV video of the meeting
This is part two of a three part enquiry.
Part one can be found here and part three can be found here.
The Use of Hydrogen to Separate and Recycle Neodymium–iron–boron-type Magnets from Electronic Waste
May 2015
Publication
The rare earth metals have been identified by the European Union and the United States as being at greatest supply risk of all the materials for clean energy technologies. Of particular concern are neodymium and dysprosium both of which are employed in neodymium–iron–boron based magnets. Recycling of magnets based on these materials and contained within obsolete electronic equipment could provide an additional and secure supply. In the present work hydrogen has been employed as a processing agent to decrepitate sintered neodymium–iron–boron based magnets contained within hard disk drives into a demagnetised hydrogenated powder. This powder was then extracted mechanically from the devices with an extraction efficiency of 90 ± 5% and processed further using a combination of sieves and ball bearings to produce a powder containing <330 parts per million of nickel contamination. It is then possible for the extracted powder to be re-processed in a number of ways namely directly by blending and re-sintering to form fully dense magnets by Hydrogenation Disproportionation Desorption Recombination processing to produce an anisotropic coercive powder suitable for bonded magnets by re-melting; or by chemical extraction of the rare earth elements from the alloy. For example it was shown that by the re-sintering route it was possible to recover >90% of the magnetic properties of the starting material with significantly less energy than that employed in primary magnet production. The particular route used will depend upon the magnetic properties required the level of contamination of the extracted material and the compositional variation of the feedstock. The various possibilities have been summarised in a flow diagram.
Controller Design for Polymer Electrolyte Membrane Fuel Cell Systems for Automotive Applications
May 2021
Publication
Continuous developments in Proton Exchange Membrane Fuel Cells (PEMFC) make them a promising technology to achieve zero emissions in multiple applications including mobility. Incremental advancements in fuel cells materials and manufacture processes make them now suitable for commercialization. However the complex operation of fuel cell systems in automotive applications has some open issues yet. This work develops and compares three different controllers for PEMFC systems in automotive applications. All the controllers have a cascade control structure where a generator of setpoints sends references to the subsystems controllers with the objective to maximize operational efficiency. To develop the setpoints generators two techniques are evaluated: off-line optimization and Model Predictive Control (MPC). With the first technique the optimal setpoints are given by a map obtained off-line of the optimal steady state conditions and corresponding setpoints. With the second technique the setpoints time profiles that maximize the efficiency in an incoming time horizon are continuously computed. The proposed MPC architecture divides the fast and slow dynamics in order to reduce the computational cost. Two different MPC solutions have been implemented to deal with this fast/slow dynamics separation. After the integration of the setpoints generators with the subsystems controllers the different control systems are tested and compared using a dynamic detailed model of the automotive system in the INN-BALANCE project running under the New European Driving Cycle.
Microbial Fuel Cells: Technologically Advanced Devices and Approach for Sustainable/renewable Energy Development
Dec 2021
Publication
There is a huge quantity of energy needs/demands for multiple developmental and domestic activities in the modern era. And in this context consumption of more non-renewable energy is reported and created many problems or issues (availability of fossil fuel stocks in the future period causes a huge quantity of toxic gases or particles or climatic change effects) at the global level. And only sustainable or renewable fuel development can provide alternate fuel and we report from various biological agents processes including microbial biofuel cell applications for future energy needs only. These will not cause any interference in natural resources or services. Microbial biofuel cells utilize the living cell to produce bioelectricity via bioelectrochemical system. It can drive electricity or other energy generation currents via lived cell interaction. Microbial fuel cells (MFCs) and enzymatic biofuel cells with their advancement in design can improve sustainable bio-energy production by proving an efficient conversion system compared to chemical fuels into electric power. Different types of MFCs operation are reported in wastewater treatment with biogas biohydrogen and other biofuel/energy generation. Later biogas can convert into electric power. Hybrid microbial biofuel cell utility with photochemical reaction is found for electricity generation. Recent research and development in microbial biofuel design and its application will emphasize bioenergy for the future.
Numerical Simulation of Solid Oxide Fuel Cells Comparing Different Electrochemical Kinetics
Mar 2021
Publication
Solid oxide fuel cells (SOFCs) produce electricity with high electrical efficiency and fuel flexibility without pollution for example CO2 NOx SOx and particles. Still numerous issues hindered the large‐scale commercialization of fuel cell at a large scale such as fuel storage mechanical failure catalytic degradation electrode poisoning from fuel and air for example lifetime in relation to cost. Computational fluid dynamics (CFD) couples various physical fields which is vital to reduce the redundant workload required for SOFC development. Modeling of SOFCs includes the coupling of charge transfer electrochemical reactions fluid flow energy transport and species transport. The Butler‐Volmer equation is frequently used to describe the coupling of electrochemical reactions with current density. The most frequently used is the activation‐ and diffusion‐controlled Butler‐Volmer equation. Three different electrode reaction models are examined in the study which is named case 1 case 2 and case 3 respectively. Case 1 is activation controlled while cases 2 and 3 are diffusion‐controlled which take the concentration of redox species into account. It is shown that case 1 gives the highest reaction rate followed by case 2 and case 3. Case 3 gives the lowest reaction rate and thus has a much lower current density and temperature. The change of activation overpotential does not follow the change of current density and temperature at the interface of the anode and electrolyte and interface of cathode and electrolyte which demonstrates the non‐linearity of the model. This study provides a reference to build electrochemical models of SOFCs and gives a deep understanding of the involved electrochemistry.
Hydrogen from Natural Gas – The Key to Deep Decarbonisation
Jul 2019
Publication
This Discussion Paper was commissioned by Zukunft ERDGAS to contribute to the debate concerning the deep decarbonisation of the European energy sector required to meet the Paris Agreement targets. Previous discussion papers have put forward decarbonisation pathways that rely heavily on ‘All-Electric’ solutions. These depend predominantly on renewable electricity to deliver decarbonisation of all sectors. This paper offers an alternative to an ‘All-Electric’ solution by building an alternative pathway that allows the inclusion of gas based technologies alongside the ‘All-Electric’ pathway technologies. The new pathway demonstrates that hydrogen from natural gas can be an essential complement to renewable electricity. The pathway also considers the benefits of utilising methane pyrolysis technology in Europe to produce zero carbon hydrogen.
Read the full report at this link
Read the full report at this link
Assessing Uncertainties of Well-To-Tank Greenhouse Gas Emissions from Hydrogen Supply Chains
Jun 2017
Publication
Hydrogen is a promising energy carrier in the clean energy systems currently being developed. However its effectiveness in mitigating greenhouse gas (GHG) emissions requires conducting a lifecycle analysis of the process by which hydrogen is produced and supplied. This study focuses on the hydrogen for the transport sector in particular renewable hydrogen that is produced from wind- or solar PV-powered electrolysis. A life cycle inventory analysis is conducted to evaluate the Well-to-Tank (WtT) GHG emissions from various renewable hydrogen supply chains. The stages of the supply chains include hydrogen being produced overseas converted into a transportable hydrogen carrier (liquid hydrogen or methylcyclohexane) imported to Japan by sea distributed to hydrogen filling stations restored from the hydrogen carrier to hydrogen and filled into fuel cell vehicles. For comparison an analysis is also carried out with hydrogen produced by steam reforming of natural gas. Foreground data related to the hydrogen supply chains are collected by literature surveys and the Japanese life cycle inventory database is used as the background data. The analysis results indicate that some of renewable hydrogen supply chains using liquid hydrogen exhibited significantly lower WtT GHG emissions than those of a supply chain of hydrogen produced by reforming of natural gas. A significant piece of the work is to consider the impacts of variations in the energy and material inputs by performing a probabilistic uncertainty analysis. This suggests that the production of renewable hydrogen its liquefaction the dehydrogenation of methylcyclohexane and the compression of hydrogen at the filling station are the GHG-intensive stages in the target supply chains.
Health-Conscious Optimization of Long-Term Operation for Hybrid PEMFC Ship Propulsion Systems
Jun 2021
Publication
The need to decarbonize the shipping sector is leading to a growing interest in fuel cell-based propulsion systems. While Polymer Electrolyte Membrane Fuel Cells (PEMFC) represent one of the most promising and mature technologies for onboard implementation they are still prone to remarkable degradation. The same problem is also affecting Lithium-ion batteries (LIB) which are usually coupled with PEMFC in hybrid powertrains. By including the combined degradation effects in an optimization strategy the best compromise between costs and PEMFC/LIB lifetime could be determined. However this is still a challenging yet crucial aspect rarely addressed in the literature and rarely yet explored. To fill this gap a health-conscious optimization is here proposed for the long-term minimization of costs and PEMFC/LIB degradation. Results show that a holistic multi-objective optimization allows a 185% increase of PEMFC/LIB lifetime with respect to a fuel-consumption-minimization-only approach. With the progressive ageing of PEMFC/LIB the hybrid propulsion system modifies the energy management strategy to limit the increase of the daily operation cost. Comparing the optimization results at the beginning and the end of the plant lifetime daily operation costs are increased by 73% and hydrogen consumption by 29%. The proposed methodology is believed to be a useful tool able to give insights into the effective costs involved in the long-term operation of this new type of propulsion system.
Process of Transformation to Net Zero Steelmaking: Decarbonisation Scenarios Based on the Analysis of the Polish Steel Industry
Apr 2023
Publication
The European steel industry is experiencing new challenges related to the market situation and climate policy. Experience from the period of pandemic restrictions and the effects of Russia’s armed invasion of Ukraine has given many countries a basis for including steel along with raw materials (coke iron ore electricity) in economic security products (CRMA). Steel is needed for economic infrastructure and construction development as well as a material for other industries (without steel factories will not produce cars machinery ships washing machines etc.). In 2022 steelmakers faced a deepening energy crisis and economic slowdown. The market situation prompted steelmakers to impose restrictions on production volumes (worldwide production fell by 4% compared to the previous year). Despite the difficult economic situation of the steel industry (production in EU countries fell by 11% in 2022 compared to the previous year) the EU is strengthening its industrial decarbonisation policy (“Fit for 55”). The decarbonisation of steel production is set to accelerate by 2050. To sharply reduce carbon emissions steel mills need new steelmaking technologies. The largest global steelmakers are already investing in new technologies that will use green hydrogen (produced from renewable energy sources). Reducing iron ore with hydrogen plasma will drastically reduce CO2 emissions (steel production using hydrogen could emit up to 95% less CO2 than the current BF + BOF blast furnace + basic oxygen furnace integrated method). Investments in new technologies must be tailored to the steel industry. A net zero strategy (deep decarbonisation goal) may have different scenarios in different EU countries. The purpose of this paper was to introduce the conditions for investing in low-carbon steelmaking technologies in the Polish steel market and to develop (based on expert opinion) scenarios for the decarbonisation of the Polish steel industry.
Solar Hydrogen for High Capacity, Dispatchable, Long-distance Energy transmission – A Case Study for Injection in the Greenstream Natural Gas Pipeline
Nov 2022
Publication
This paper presents the results of techno-economic modelling for hydrogen production from a photovoltaic battery electrolyser system (PBES) for injection into a natural gas transmission line. Mellitah in Libya connected to Gela in Italy by the Greenstream subsea gas transmission line is selected as the location for a case study. The PBES includes photovoltaic (PV) arrays battery electrolyser hydrogen compressor and large-scale hydrogen storage to maintain constant hydrogen volume fraction in the pipeline. Two PBES configurations with different large-scale storage methods are evaluated: PBESC with compressed hydrogen stored in buried pipes and PBESL with liquefied hydrogen stored in spherical tanks. Simulated hourly PV electricity generation is used to calculate the specific hourly capacity factor of a hypothetical PV array in Mellitah. This capacity factor is then used with different PV sizes for sizing the PBES. The levelised cost of delivered hydrogen (LCOHD) is used as the key techno-economic parameter to optimise the size of the PBES by equipment sizing. The costs of all equipment except the PV array and batteries are made to be a function of electrolyser size. The equipment sizes are deemed optimal if PBES meets hydrogen demand at the minimum LCOHD. The techno-economic performance of the PBES is evaluated for four scenarios of fixed and constant hydrogen volume fraction targets in the pipeline: 5% 10% 15% and 20%. The PBES can produce up to 106 kilotonnes of hydrogen per year to meet the 20% target at an LCOHD of 3.69 €/kg for compressed hydrogen storage (PBESC) and 2.81 €/kg for liquid hydrogen storage (PBESL). Storing liquid hydrogen at large-scale is significantly cheaper than gaseous hydrogen even with the inclusion of a significantly larger PV array that is required to supply additional electrcitiy for liquefaction.
Implementation of Fuel Cells in Aviation from a Maintenance, Repair and Overhaul Perspective
Dec 2022
Publication
Hydrogen is one of the most promising power sources for meeting the aviation sector’s long-term decarbonization goals. Although on-board hydrogen systems namely fuel cells are extensively researched the maintenance repair and overhaul (MRO) perspective remains mostly unaddressed. This paper analyzes fuel cells from an MRO standpoint based on a literature review and comparison with the automotive sector. It also examines how well the business models and key resources of MRO providers are currently suited to provide future MRO services. It is shown that fuel cells require extensive MRO activities and that these are needed to meet the aviation sector’s requirements for price safety and especially durability. To some extent experience from the automotive sector can be built upon particularly with respect to facility requirements and qualification of personnel. Yet MRO providers’ existing resources only partially allow them to provide these services. MRO providers’ underlying business models must adapt to the implementation of fuel cells in the aviation sector. MRO providers and services should therefore be considered and act as enablers for the introduction of fuel cells in the aviation industry.
An Inter-laboratory Comparison between 13 International Laboratories for Eight Components Relevant for Hydrogen Fuel Quality Assessment
Mar 2024
Publication
The quality of the hydrogen delivered by refuelling stations is critical for end-users and society. The purity of the hydrogen dispensed at hydrogen refuelling points should comply with the technical specifications included in the ISO 14687:2019 and EN 17124:2022 standards. Once laboratories have set up methods they need to verify their performances for example through participation in interlaboratory comparisons. Due to the challenge associated with the production of stable reference materials and transport of these which are produced in hydrogen at high pressure (>10 bar) interlaboratory comparisons have been organized in different steps with increasing extent. This study describes an inter-laboratory comparison exercise for hydrogen fuel involving a large number of participants (13 laboratories) completed in less than a year and included eight key contaminants of hydrogen fuel at level close to the ISO14687 threshold. These compounds were selected based on their high probability of occurrence or because they have been found in hydrogen fuel samples. For the results of the intercomparison it appeared that fully complying with ISO 21087:2019 is still challenging for many participants and highlighted the importance of organising these types of exercises. Many laboratories performed corrective actions based on their results which in turn significantly improved their performances.
Research on the Adaptability of Proton Exchange Membrane Electrolysis in Green Hydrogen-Electric Coupling System Under Multi-operating Conditions
Mar 2023
Publication
The green hydrogen–electric coupling system can consume locally generated renewable energy thereby improving energy utilization and enabling zero-carbon power supply within a certain range. This study focuses on a green hydrogen–electric coupling system that integrates photovoltaic energy storage and proton exchange membrane electrolysis (PEME). Firstly the impact of operating temperature power quality and grid auxiliary services on the characteristics of the electrolysis cell is analyzed and a voltage model and energy model for the cell are established. Secondly a multi-operating conditions adaptability experiment for PEME grid-connected operation is designed. A test platform consisting of a grid simulator simulated photovoltaic power generation system lithium battery energy storage system PEME and measurement and acquisition device is then built. Finally experiments are conducted to simulate multi-operating conditions such as temperature changes voltage fluctuations frequency offsets harmonic pollution and current adjustment speed. The energy efficiency and consumption is calculated based on the recorded data and the results are helpful to guide the operation of the system.
Increasing Technical Efficiency of Renewable Energy Sources in Power Systems
Mar 2023
Publication
This paper presents a method for refining the forecast schedule of renewable energy sources (RES) generation by its intraday adjustment and investigates the measures for reserving RES with unstable generation in electric power systems (EPSs). Owing to the dependence of electricity generation by solar and wind power plants (PV and WPPs respectively) on natural conditions problems arise with their contribution to the process of balancing the power system. Therefore the EPS is obliged to keep a power reserve to compensate for deviations in RES from the planned generation amount. A system-wide reserve (mainly the shunting capacity of thermal and hydroelectric power plants) is used first followed by other means of power reserve: electrochemical hydrogen or biogas plants. To analyze the technical and economic efficiency of certain backup means mathematical models based on the theory of similarity and the criterion method were developed. This method is preferred because it provides the ability to compare different methods of backing up RES generation with each other assess their proportionality and determine the sensitivity of costs to the capacity of backup methods with minimal available initial information. Criterion models have been formed that allow us to build dependencies of the costs of backup means for unstable RES generation on the capacity of the backup means. It is shown that according to the results of the analysis of various methods and means of RES backup hydrogen technologies are relatively the most effective. The results of the analysis in relative units can be clarified if the current and near-term price indicators are known.
Low Carbon Optimal Operation of Integrated Energy System Based on Concentrating Solar Power Plant and Power to Hydrogen
Mar 2023
Publication
A new integrated energy system (IES) framework is created in order to encourage the consumption of renewable energy which is represented by wind and solar energy and lower carbon emissions. The connection between the units in the composite system is examined in this research. In-depth analysis is done on how energy is transferred between electricity heat gas and hydrogen. The system model and constraints are used to build an objective function with the lowest total operating cost. The calculation of carbon trading includes the ladder carbon trading method. And set up 6 cases for analysis which verifies the effectiveness of the participation of the concentrated solar power plant (CSPP) in the heat supply and power to hydrogen system (P2HS) in reducing the total operating cost of the system reducing wind curtailment and light curtailment and reducing carbon emissions. Under the model considered in this paper reduces the total operating cost reduces by 27.04% when the concentrated solar power plant is involved in the supply of thermal load. And the carbon emission is reduced by 14.529%. Compared with the traditional power to gas considers the power to hydrogen system in this paper which reduces the total operating cost by 4.79%.
Green Hydrogen Value Chain: Modelling of a PV Power Plant Integrated with H2 Production for Industry Application
Mar 2024
Publication
Based on the Sustainable Development Goals outlined in the 2030 agenda of the United Nations affordable and clean energy is one of the most relevant goals to achieve the decarbonization targets and break down the global climate change effects. The use of renewable energy sources namely solar energy is gaining attention and market share due to reductions in investment costs. Nevertheless it is important to overcome the energy storage problems mostly in industrial applications. The integration of photovoltaic power plants with hydrogen production and its storage for further conversion to usable electricity are an interesting option from both the technical and economic points of view. The main objective of this study is to analyse the potential for green hydrogen production and storage through PV production based on technical data and operational considerations. We also present a conceptual model and the configuration of a PV power plant integrated with hydrogen production for industry supply. The proposed power plant configuration identifies different pathways to improve energy use: supply an industrial facility supply the hydrogen production and storage unit sell the energy surplus to the electrical grid and provide energy to a backup battery. One of the greatest challenges for the proposed model is the component sizing and water electrolysis process for hydrogen production due to the operational requirements and the technology costs.
Refuelling Infrastructure Requirements for Renewable Hydrogen Road Fuel through the Energy Transition
Nov 2022
Publication
Current commercially available options for decarbonisation of road transport are battery electric vehicles or hydrogen fuel cell electric vehicles. BEVs are increasingly deployed while hydrogen is in its infancy. We examine the infrastructure necessary to support hydrogen fuelling to various degrees of market penetration. Scotland makes a good exemplar of transport transition with a world leading Net-Zero ambition and proven pathways for generating ample renewable energy. We identified essential elements of the new transport systems and the associated capital expenditure. We developed nine scenarios based on the pace of change and the ultimate market share of hydrogen and constructed a model to analyse their infrastructure requirements. This is a multi-period model incorporating Monte Carlo and Markov Chain elements. A “no-regrets” initial action is rapid deployment of enough hydrogen infrastructure to facilitate the early years of a scenario where diesel fuel becomes replaced with hydrogen. Even in a lower demand scenario of only large and heavy goods vehicles using hydrogen the same infrastructure would be required within a further two years. Subsequent investment in infrastructure could be considered in the light of this initial development.
Comprehensive Analysis of the Operation of an Internal Combustion Engine Fueled by Hydrogen-containing Mixtures
Mar 2023
Publication
At present hydrogen is considered as one of the most promising motor fuels capable of replacing traditional hydrocarbons. This article presents the results of a comprehensive experimental study of the effect of hydrogen additives on the main parameters of a gasoline spark-ignition ICE. The thermophysical parameters of the processes of ignition and combustion inside the cylinder with the addition of hydrogen in the amount of 0%–20% of the air volume as well as the fuel and energy characteristics of the engine and its impact on the environment were studied. It has been established that hydrogen leads to significant changes in the engine operation. It increases some parameters and reduces others improving or worsening them compared to running on pure gasoline. So with a 20% H2 addition at an average engine load the following parameters increase: the maximum pressure in the cylinder by almost 20%; the rate of pressure increase in the combustion chamber by 2.8 times; the highest combustion temperature by 140 K. At the same time the following parameters decrease: average indicator pressure by 18%; ignition timing by 82% (6◦ to TDC versus 34◦ for gasoline); crank angle corresponding to the maximum pressure by 32% (9.4◦ versus 13.9◦ for gasoline); crank angle corresponding to maximum temperature by 54% (17.7◦ after TDC versus 38.3◦ for clean gasoline); ignition delay time (τind = 0.32 ms) and visible combustion time (τvis = 1.58 ms) by 4 and 2.3 times respectively.
Towards a Prioritization of Alternative Energy Sources for Sustainable Shipping
Apr 2023
Publication
Studies on the prospects of the use of alternative fuels in the maritime industry have rarely been assessed in the context of developing countries. This study assesses seven energy sources for shipping in the context of Bangladesh with a view to ranking their prospects based on sustainability as well as identifying the energy transition criteria. Data were collected from maritime industry experts including seafarers shipping company executives government representatives and academics. The Bayesian Best-Worst Method (BWM) was used for ranking nine criteria related to the suitability and viability of the considered alternative energy sources. Next the PROMETHEE-GAIA method is applied for priority analysis of the seven energy alternatives. The findings reveal that capital cost alternative energy price and safety are the most important factors for alternative energy transition in Bangladesh. Apart from the benchmark HFO Liquified Natural Gas (LNG) HFO-Wind and LNG-Wind hybrids are considered the most viable alternatives. The findings of the study can guide policymakers in Bangladesh in terms of promoting viable energy sources for sustainable shipping.
Economic Evaluation of a Power-to-hydrogen System Providing Frequency Regulation Reserves: A Case Study of Denmark
Mar 2023
Publication
Operating costs are dominant in the hydrogen production of a power-to-hydrogen system. An optimal operational strategy or bidding framework is effective in reducing these costs. However it is still found that the production cost of hydrogen is high. As the electrolysis unit is characterized by high flexibility providing ancillary service to the grid becomes a potential pathway for revenue stacking. Recent research has demonstrated the feasibility of providing such a service but the related economics have not been well evaluated. In this work we propose a comprehensive operation model to enable participation in the day-head balancing and reserve markets. Three types of reserves are considered by using different operational constraints. Based on the proposed operation framework we assess the economic performance of a power-to-hydrogen system in Denmark using plentiful actual market data. The results reveal that providing frequency containment reserve and automatic frequency restoration reserve efficiently raises the operational contribution margins. In parallel by investing in the cash flows net present value and break-even hydrogen prices we conclude that providing reserves makes the power-to-hydrogen project more profitable in the studied period and region.
Reduction of Iron Oxides with Hydrogen - A Review
Aug 2019
Publication
This review focuses on the reduction of iron oxides using hydrogen as a reducing agent. Due to increasing requirements from environmental issues a change of process concepts in the iron and steel industry is necessary within the next few years. Currently crude steel production is mainly based on fossil fuels and emitting of the climate-relevant gas carbon dioxide is integral. One opportunity to avoid or reduce greenhouse gas emissions is substituting hydrogen for carbon as an energy source and reducing agent. Hydrogen produced via renewable energies allows carbon-free reduction and avoids forming harmful greenhouse gases during the reduction process. The thermodynamic and kinetic behaviors of reduction with hydrogen are summarized and discussed in this review. The effects of influencing parameters such as temperature type of iron oxide grain size etc. are shown and compared with the reduction behavior of iron oxides with carbon monoxide. Different methods to describe the kinetics of the reduction progress and the role of the apparent activation energy are shown and proofed regarding their plausibility.
Power Scheduling Optimization Method of Wind-Hydrogen Integrated Energy System Based on the Improved AUKF Algorithm test2
Nov 2022
Publication
With the proposal of China’s green energy strategy the research and development technologies of green energy such as wind energy and hydrogen energy are becoming more and more mature. However the phenomenon of wind abandonment and anti-peak shaving characteristics of wind turbines have a great impact on the utilization of wind energy. Therefore this study firstly builds a distributed wind-hydrogen hybrid energy system model then proposes the power dispatching optimization technology of a wind-hydrogen integrated energy system. On this basis a power allocation method based on the AUKF (adaptive unscented Kalman filter) algorithm is proposed. The experiment shows that the power allocation strategy based on the AUKF algorithm can effectively reduce the incidence of battery overcharge and overdischarge. Moreover it can effectively deal with rapid changes in wind speed. The wind hydrogen integrated energy system proposed in this study is one of the important topics of renewable clean energy technology innovation. Its grid-connected power is stable with good controllability and the DC bus is more secure and stable. Compared with previous studies the system developed in this study has effectively reduced the ratio of abandoned air and its performance is significantly better than the system with separate grid connected fans and single hydrogen energy storage. It is hoped that this research can provide some solutions for the research work on power dispatching optimization of energy systems.
Renewable Electricity for Decarbonisation of Road Transport: Batteries or E-Fuels?
Feb 2023
Publication
Road transport is one of the most energy-consuming and greenhouse gas (GHG) emitting sectors. Progressive decarbonisation of electricity generation could support the ambitious target of road vehicle climate neutrality in two different ways: direct electrification with onboard electro-chemical storage or a change of energy vector with e-fuels. The most promising state-of-the-art electrochemical storages for road transport have been analysed considering current and future technologies (the most promising ones) whose use is assumed to occur within the next 10–15 years. Different e-fuels (e-hydrogen e-methanol e-diesel e-ammonia E-DME and e-methane) and their production pathways have been reviewed and compared in terms of energy density synthesis efficiency and technology readiness level. A final energetic comparison between electrochemical storages and e-fuels has been carried out considering different powertrain architectures highlighting the huge difference in efficiency for these competing solutions. E-fuels require 3–5 times more input energy and cause 3–5 times higher equivalent vehicle CO2 emissions if the electricity is not entirely decarbonised.
Fuel Cells for Shipping: To Meet On-board Auxiliary Demand and Reduce Emissions
Feb 2021
Publication
The reduction of harmful emissions from the international shipping sector is necessary. On-board energy demand can be categorised as either: propulsion or auxiliary services. Auxiliary services contribute a significant proportion of energy demand with major loads including: compressors pumps and HVAC (heating ventilation and air-conditioning). Typically this demand is met using the same fuel source as the main propulsion (i.e. fossil fuels). This study has analysed whether emissions from large scale ships could feasibly be reduced by meeting auxiliary demand by installing a hydrogen fuel cell using data from an LNG tanker to develop a case study. Simulations have shown that for a capacity of 10 x 40ft containers of compressed hydrogen the optimal fuel cell size would be 3 MW and this could save 10600 MWh of fossil fuel use equivalent to 2343 t of CO2. Hence this could potentially decarbonise a significant proportion of shipping energy demand. Although there are some notable technical and commercial considerations such as fuel cell lifetime and capital expenditure requirements. Results imply that if auxiliary loads could be managed to avoid peaks in demand this could further increase the effectiveness of this concept.
Assessing the Performance of Fuel Cell Electric Vehicles Using Synthetic Hydrogen Fuel
Mar 2024
Publication
The deployment of hydrogen fuel cell electric vehicles (FCEVs) is critical to achieve zero emissions. A key parameter influencing FCEV performance and durability is hydrogen fuel quality. The real impact of contaminants on FCEV performance is not well understood and requires reliable measurements from real-life events (e.g. hydrogen fuel in poor-performing FCEVs) and controlled studies on the impact of synthetic hydrogen fuel on FCEV performance. This paper presents a novel methodology to flow traceable hydrogen synthetic fuel directly into the FCEV tank. Four different synthetic fuels containing N2 (90–200 µmol/mol) CO (0.14–5 µmol/mol) and H2S (4–11 nmol/mol) were supplied to an FCEV and subsequently sampled and analyzed. The synthetic fuels containing known contaminants powered the FCEV and provided real-life performance testing of the fuel cell system. The results showed for the first time that synthetic hydrogen fuel can be used in FCEVs without the requirement of a large infrastructure. In addition this study carried out a traceable H2 contamination impact study with an FCEV. The impact of CO and H2S at ISO 14687:2019 threshold levels on FCEV performance showed that small exceedances of the threshold levels had a significant impact even for short exposures. The methodology proposed can be deployed to evaluate the composition of any hydrogen fuel.
Drop-in and Hydrogen-based Biofuels for Maritime Transport: Country-based Assessment of Climate Change Impacts in Europe up to 2050
Nov 2022
Publication
Alternative fuels are crucial to decarbonize the European maritime transport but their net climate benefits vary with the type of fuel and production country. In this study we assess the energy potential and climate change mitigation benefits of using agricultural and forest residues in different European countries for drop-in (Fast Pyrolysis Hydrothermal Liquefaction and Gasification to Fischer-Tropsch fuels or Bio-Synthetic Natural Gas) and hydrogen-based biofuels (hydrogen ammonia and methanol) with or without carbon capture and storage (CCS). Our results show the combinations of countries and biofuel options that successfully achieve the decarbonization targets set by the FuelEU Maritime initiative for the next years including a prospective analysis that include technological changes projected for the biofuel supply chains until 2050. With the current technologies the largest greenhouse gas (GHG) mitigation potential per year at a European scale is obtained with bio-synthetic natural gas and hydrothermal liquefaction. Among carbon-free biofuels ammonia currently has higher mitigation but hydrogen can achieve a lower GHG intensity per unit of energy with the projected decarbonization of the electricity mixes until 2050. The full deployment of CCS can further accelerate the decarbonization of the maritime sector. Choosing the most suitable renewable fuels requires a regional perspective and a transition roadmap where countries coordinate actions to meet ambitious climate targets.
Hydrogen or Hydrogen-derived Methanol for Dual-fuel Compression-ignition Combustion: An Engine Perspective
Oct 2022
Publication
Synthetic fuels or e-fuels produced from captured CO2 and renewable hydrogen are envisaged as a feasible path towards a climate-neutral transportation in medium/heavy-duty and maritime sectors. EU is presently debating energy targets by 2030 for these fuels. As their production involves chemical processing of hydrogen it must be evaluated if the extra cost is worthy at least in applications where hydrogen use is possible. This manuscript focuses on the performance and environmental impact when hydrogen and methanol are fed to a heavy-duty compression-ignition engine working under dual-fuel combustion. The trade-off thermal efficiency-NOx emissions is primary considered in the assessment by combining both variables in an own defined function. During the work engine operating settings were adjusted to exploit the potential of methanol and hydrogen. Compared to conventional combustion methanol required centering the combustion towards TDC and doubling the EGR rate resulting in a low temperature highly premixed combustion almost soot-free and with extremely low NOx emissions. The best settings for hydrogen were in the middle of those for methanol and conventional combustion. Results showed great dependance with the engine load but methanol proved superior to hydrogen for all conditions. At high load 20–60 % methanol even improved the efficiency and reduced the NOx emissions obtained by conventional combustion. However at low load hydrogen could substitute 90 % of the diesel fuel while methanol failed at substitutions higher than 55 %.
Pre-cooling Systems for Hydrogen Fueling Stations: Techno-economic Analysis for Scaled Enactment
Mar 2023
Publication
Hydrogen fueling standards stipulates a sustainable cooling system technically and economically. Accordingly the interior surface temperature of the on-board H2 storage tank in fuel cell electric vehicles must not exceed the maximum specified limit (358.15 K) and the fueling rate must be ≤ 42.86 sec / kg-H2 with T40 dispenser at 70 MPa. In this context H2 refueling stations often employ double-tube and block heat exchangers for heat transfer. This study examines the H2 pre-cooling system for various loads and provides a comparative techno-economic analysis of double tube heat exchangers (DTHE) and microchannel heat exchangers (MCHE) under stipulated technical operational and outlet gas standards. For this purpose thermal and hydraulic performances were simulated using ANSYS-CFX. Technical and cost models utilize manufacturer specifications and literature-based technical and economic characteristics to derive the minimum sustainable price defined as the price to sustain the product. The results showed that the MCHE outperformed the DTHE for setups in mass manufacturing improved effective heat transfer area and predicted long term unit cost. The annual quantitative output affects manufacturing expenses and profit margins substantially. With high production rates it is expected that the unit cost of the MCHE will decrease by up to 74%. In switching from DTHE to MCHE general material requirements decreased by ~60% with scrap waste savings of ~45% reflecting an appreciable footprint reduction.
Assessment of the Co-combustion Process of Ammonia with Hydrogen in a Research VCR Piston Engine
Oct 2022
Publication
The presented work concerns experimental research of a spark-ignition engine with variable compression ratio (VCR) adapted to dual-fuel operation in which co-combustion of ammonia with hydrogen was conducted and the energy share of hydrogen varied from 0% to 70%. The research was aimed at assessing the impact of the energy share of hydrogen co-combusted with ammonia on the performance stability and emissions of an engine operating at a compression ratio of 8 (CR 8) and 10 (CR 10). The operation of the engine powered by ammonia alone for both CR 8 and CR 10 is associated with either a complete lack of ignition in a significant number of cycles or with significantly delayed ignition and the related low value of the maximum pressure pmax. Increasing the energy share of hydrogen in the fuel to 12% allows to completely eliminate the instability of the ignition process in the combustible mixture which is confirmed by a decrease in the IMEP uniqueness and a much lower pmax dispersion. For 12% of the energy share of hydrogen co-combusted with ammonia the most favorable course of the combustion process was obtained the highest engine efficiency and the highest IMEP value were recorded. The conducted research shows that increasing the H2 share causes an increase in NO emissions for both analyzed compression ratios
Green Hydrogen Based Power Generation Prospect for Sustainable Development of Bangladesh using PEMFC and Hydrogen Gas Turbine
Feb 2023
Publication
Bangladesh focuses on green energy sources to be a lesser dependent on imported fossil fuels and to reduce the GHG emission to decarbonize the energy sector. The integration of renewable energy technologies for green hydrogen production is promising for Bangladesh. Hybrid renewable plants at the coastline along the Bay of Bengal Kuakata Sandwip St. Martin Cox’sbazer and Chattogram for green hydrogen production is very promising to solve the power demand scarcity of Bangladesh. Hydrogen gas turbine and hydrogen fuel cell configured power plant performances are studied to observe the feasibility/prospect to the green energy transition. The Plant’s performances investigated based on specification of the plant’s units and verified by MATLAB SIMULINK software. Fuels blending (different percent of hydrogen with fossil fuel/NG) technique makes the hydrogen more feasible as turbine fuel. The net efficiency of the fuel cell-based combined cycle configuration (74%) is higher than that of the hydrogen gas turbine-based configuration (51.9%). Moreover analyses show that the increment of combined cycle gas turbine efficiency (+18.5%) is more than the combined cycle PEMFC configuration (+14%). Long-term storage of renewable energy in the salt cavern as green hydrogen can be a source of energy for emergency. A significant share of power can be generated by a numbers of green power plants at specified places in Bangladesh.
Overview of the Method and State of Hydrogenization of Road Transport in the World and the Resulting Development Prospects in Poland
Jan 2021
Publication
National Implementation Plans (NIP) in regard hydrogenation motor transport are in place in European Union (EU) countries e.g.Germany France or Belgium Denmark Netherlands. Motor transport hydrogenization plans exist in the Japan and USA. In Poland the methodology deployment Hydrogen Refuelling Stations (HRS) developed in Motor Transport Institute is of multi-stage character are as follows: Stage I: Method allowing to identify regions in which HRS should be located. Stage II: Method allowing to identify urban centres in which should be located the said stations. Stage III: Method for determining the area of the station location. The presentation of the aforesaid NIPS and based on that and the mentioned methodology the conditions for hydrogenization of motor transport in Poland is the purpose of this article which constitutes its novelty. The scope of the article concerns the hydrogenization of motor transport in the abovementioned countries. With the above criteria the order the construction in Poland of a HRS in the order of their creation along the TEN-T corridors is as follows: 1 - Poznan 2 - Warsaw 3 - Bialystok 4 - Szczecin 5 - the Lodz region 6 - the Tri-City region 7 - Wrocław 8 - the Katowice region 9 – Krakow. The concluding discussion sets out the status of deployment HRS and FCEVs in the analysed countries.
Study on the Use of Fuel Cells in Shipping
Jan 2017
Publication
Fuel Cells are a promising technology in the context of clean power sustainability and alternative fuels for shipping. Different specific developments on Fuel Cells are available today with research and pilot projects under evaluation that have revealed strong potential for further scaled up implementation. The EMSA Study on the use of Fuel Cells in Shipping has been the result of this Agency’s initiative under the agreement of the Commission and in support of EU Member States an important instrument developed in close partnership with DNV-GL.
Notwithstanding the close dependency of Fuel Cell technology and the development of hydrogen fuel solutions different solutions are today in place making use of LNG methanol and other low flashpoint fuels. EMSA participates in support of the Commission in the 2nd phase development of the IGF Code where provisions for Fuel Cells are to be included as a new part of the text.
The EMSA Study on the use of Fuel Cells in Shipping includes a technology and regulatory review identifying gaps to be further explored the selection of the most promising Fuel Cell technologies for shipping and finally a generic Safety Assessment where the selected technologies are evaluated according to Risk & Safety aspects in generic ship design applications.
Notwithstanding the close dependency of Fuel Cell technology and the development of hydrogen fuel solutions different solutions are today in place making use of LNG methanol and other low flashpoint fuels. EMSA participates in support of the Commission in the 2nd phase development of the IGF Code where provisions for Fuel Cells are to be included as a new part of the text.
The EMSA Study on the use of Fuel Cells in Shipping includes a technology and regulatory review identifying gaps to be further explored the selection of the most promising Fuel Cell technologies for shipping and finally a generic Safety Assessment where the selected technologies are evaluated according to Risk & Safety aspects in generic ship design applications.
Comparing e-Fuels and Electrification for Decarbonization of Heavy-Duty Transports
Oct 2022
Publication
The freight sector is expected to keep or even increase its fundamental role for the major modern economies and therefore actions to limit the growing pressure on the environment are urgent. The use of electricity is a major option for the decarbonization of transports; in the heavy-duty segment it can be implemented in different ways: besides full electric-battery powertrains electricity can be used to supply catenary roads or can be chemically stored in liquid or gaseous fuels (e-fuels). While the current EU legislation adopts a tailpipe Tank-To-Wheels approach which results in zero emissions for all direct uses of electricity a Well-To-Wheels (WTW) method would allow accounting for the potential benefits of using sustainable fuels such as e-fuels. In this article we have performed a WTW-based comparison and modelling of the options for using electricity to supply heavy-duty vehicles: e-fuels eLNG eDiesel and liquid Hydrogen. Results showed that the direct use of electricity can provide high Greenhouse Gas (GHG) savings and also in the case of the e-fuels when low-carbonintensity electricity is used for their production. While most studies exclusively focus on absolute GHG savings potential considerations of the need for new infrastructures and the technological maturity of some options are fundamental to compare the different technologies. In this paper an assessment of such technological and non-technological barriers has been conducted in order to compare alternative pathways for the heavy-duty sector. Among the available options the flexibility of using drop-in energy-dense liquid fuels represents a clear and substantial immediate advantage for decarbonization. Additionally the novel approach adopted in this paper allows us to quantify the potential benefits of using e-fuels as chemical storage able to accumulate electricity from the production peaks of variable renewable energies which would otherwise be wasted due to grid limitations.
Exploring Hydrogen-Enriched Fuels and the Promise of HCNG in Industrial Dual-Fuel Engines
Mar 2024
Publication
This paper presents a theoretical analysis of the selected properties of HCNG fuel calculations and a literature review of the other fuels that allow the storage of ecologically produced hydrogen. Hydrogen has the most significant CO2 reduction potential of all known fuels. However its transmission in pure form is still problematic and its use as a component of fuels modified by it has now become an issue of interest for researchers. Many types of hydrogen-enriched fuels have been invented. However this article will describe the reasons why HCNG may be the hydrogen-enriched fuel of the future and why internal combustion (IC) piston engines working on two types of fuel could be the future method of using it. CO2 emissions are currently a serious problem in protecting the Earth’s natural climate. However secondarily power grid stabilization with a large share of electricity production from renewable energy sources must be stabilized with very flexible sources—as flexible as multi-fuel IC engines. Their use is becoming an essential element of the electricity power systems of Western countries and there is a chance to use fuels with zero or close to zero CO2 emissions like e-fuels and HCNG. Dual-fuel engines have become an effective way of using these types of fuels efficiently; therefore in this article the parameters of hydrogen-enriched fuel selected in terms of relevance to the use of IC engines are considered. Inaccuracies found in the literature analysis are discussed and the essential properties of HCNG and its advantages over other hydrogen-rich fuels are summarized in terms of its use in dual-fuel (DF) IC engines.
Power Balance Control and Dimensioning of a Hybrid Off-grid Energy system for a Nordic Climate Townhouse
Mar 2023
Publication
This paper investigates conversion of a Nordic oil-heated townhouse into carbon-neutral by different energy efficiency (EE) improvements and an off-grid system including solar photovoltaics (PV) wind power and battery and hydrogen energy storage systems (BESS and HESS). A heat-pump-based heating system including waste heat recovery (WHR) from the HESS and an off-grid electrical system are dimensioned for the building by applying models developed in MATLAB and Microsoft Excel to study the life cycle costs (LCC). The work uses a measured electrical load profile and the heat generation of the new heating system and the power generation are simulated by commercial software. It is shown that the EE improvements and WHR from the HESS have a positive effect on the dimensioning of the off-grid system and the LCC can be reduced by up to €2 million. With the EE improvements and WHR the component dimensioning can be reduced by 22%–41% and 13%–51% on average respectively. WHR can cover up to 57% of the building's annual heat demand and full-power dimensioning of the heat pump is not reasonable when WHR is applied. Wind power was found to be very relevant in the Nordic conditions reducing the LCC by 32%.
On the Technology of Solid Oxide Fuel Cell (SOFC) Energy Systems for Stationary Power Generation: A Review
Nov 2022
Publication
This paper presents a comprehensive overview on the current status of solid oxide fuel cell (SOFC) energy systems technology with a deep insight into the techno-energy performance. In recent years SOFCs have received growing attention in the scientific landscape of high efficiency energy technologies. They are fuel flexible highly efficient and environmentally sustainable. The high working temperature makes it possible to work in cogeneration and drive downstream bottomed cycles such as Brayton and Hirn/Rankine ones thus configuring the hybrid system of a SOFC/turbine with very high electric efficiency. Fuel flexibility makes SOFCs independent from pure hydrogen feeding since hydrocarbons can be fed directly to the SOFC and then converted to a hydrogen rich stream by the internal thermochemical processes. SOFC is also able to convert carbon monoxide electrochemically thus contributing to energy production together with hydrogen. SOFCs are much considered for being supplied with biofuels especially biogas and syngas so that biomass gasifiers/SOFC integrated systems contribute to the “waste to energy” chain with a significant reduction in pollution. The paper also deals with the analysis of techno-energy performance by means of ad hoc developed numerical modeling in relation to the main operating parameters. Ample prominence is given to the aspect of fueling emphasizing fuel processing with a deep discussion on the impurities and undesired phenomena that SOFCs suffer. Constituent materials geometry and design methods for the balance of plant were studied. A wide analysis was dedicated to the hybrid system of the SOFC/turbine and to the integrated system of the biomass gasifier/SOFC. Finally an overview of SOFC system manufacturing companies on SOFC research and development worldwide and on the European roadmap was made to reflect the interest in this technology which is an important signal of how communities are sensitive toward clean low carbon and efficient technologies and therefore to provide a decisive and firm impulse to the now outlined energy transition.
Characterization of the Hydrogen Combustion Process in a Scramjet Engine
May 2024
Publication
In this paper by using a large eddy simulation we study the combustion process in the HyShot II scramjet combustor. By conducting a detailed analysis of the mass-fraction distributions of the main species such as H2 H2O and the radicals OH and HO2 of the mass source terms of these main species and of the chemical source term of the energy equation we detect the regions where chemical reactions occur through a diffusion process and the regions where auto-ignition and premixed combustion may develop. The analysis indicates that the combustion process is mainly of diffusive type along a thin shear layer enveloping the hydrogen plume whereas there could be some auto-ignition and/or premixed combustion cores inside the plume.
Research on Energy Management Method of Fuel Cell/Supercapacitor Hybrid Trams Based on Optimal Hydrogen Consumption
Jul 2023
Publication
In this paper based on the operating states and characteristics of fuel cell/supercapacitor hybrid trams an optimal hydrogen energy management method is proposed. This method divides the operating states into two parts: traction state and non-traction state. In the traction state the real-time loss function of the hybrid power system which is used to obtain the fuel cell optimal output power under the different demand powers and supercapacitor voltage is established. In the non-traction state the constant-power charging method which is obtained by solving the power-voltage charging model is used to ensure the supercapacitor voltage of the beginning-state and the end-state in an entire operation cycle are the same. The RT-LAB simulation platform is used to verify that the proposed method has the ability to control the hybrid real-time system. Using the comparative experiment between the proposed method and power-follow method the results show that the proposed method offers a significant improvement in both fuel cell output stability and hydrogen consumption in a full operation cycle.
Precise Dynamic Modelling of Real-World Hybrid Solar-Hydrogen Energy Systems for Grid-Connected Buildings
Jul 2023
Publication
Hybrid renewable hydrogen energy systems could play a key role in delivering sustainable solutions for enabling the Net Zero ambition; however the lack of exact computational modelling tools for sizing the integrated system components and simulating their real-world dynamic behaviour remains a key technical challenge against their widespread adoption. This paper addresses this challenge by developing a precise dynamic model that allows sizing the rated capacity of the hybrid system components and accurately simulating their real-world dynamic behaviour while considering effective energy management between the grid-integrated system components to ensure that the maximum possible proportion of energy demand is supplied from clean sources rather than the grid. The proposed hybrid system components involve a solar PV system electrolyser pressurised hydrogen storage tank and fuel cell. The developed hybrid system model incorporates a set of mathematical models for the individual system components. The developed precise dynamic model allows identifying the electrolyser’s real-world hydrogen production levels in response to the input intermittent solar energy production while also simulating the electrochemical behaviour of the fuel cell and precisely quantifying its real-world output power and hydrogen consumption in response to load demand variations. Using a university campus case study building in Scotland the effectiveness of the developed model has been assessed by benchmarking comparison between its results versus those obtained from a generic model in which the electrochemical characteristics of the electrolyser and fuel cell systems were not taken into consideration. Results from this comparison have demonstrated the potential of the developed model in simulating the real-world dynamic operation of hybrid solar hydrogen energy systems for grid-connected buildings while sizing the exact capacity of system components avoiding oversizing associated with underutilisation costs and inaccurate simulation.
Analyzing the Future Potential of Defossilizing Industrial Specialty Glass Production with Hydrogen by LCA
Mar 2022
Publication
The glass industry is part of the energy-intensive industry with most of the energy needed to melt the raw materials. To produce glass temperatures between 1000 and 1600 °C are necessary. Presently mostly fossil natural gas is the dominant energy source. As direct electrification is not always possible in this paper a Life Cycle Assessment (LCA) for specialty glass production is conducted where the conventional fossil-based reference process is compared to a hydrogen-fired furnace. This hydrogen can be produced on-site in an water electrolyzer using not only the hydrogen for the combustion but also the produced oxygen. Hydrogen can be produced alternatively off-site in a large scale electrolyzer to facilitate economy of scale. For the transport and distribution of this hydrogen different options are available. A rather new option are liquid organic hydrogen carriers (LOHC) which bind the hydrogen in a chemical substance. However temperatures around 300 °C are necessary to separate the hydrogen from the LOHC after transport. At the glass trough waste heat is available at the required temperature level to facilitate the dehydrogenation. The comparison is completed by the production of off-site hydrogen transported to the glass trough as conventional liquefied hydrogen in cooling tanks by truck or in hydrogen pipelines. In this assessment to power the electrolyzers the national grid mix of Germany is used. A time frame from 2020 till 2050 and its changing energy system towards defossilisation is analyzed. Regarding climate change on-site hydrogen production causes the least impact for specialty glass production in 2050. However negative trade-offs for other environmental impact categories e.g. Metal depletion are recorded.
No more items...