Applications & Pathways
Exploring the Gas Permeability of Type IV Hydrogen Storage Cylinder Liners: Research and Applications
Jul 2025
Publication
As hydrogen fuel cell vehicles gain momentum as crucial zero-emission transportation solutions the urgency to address hydrogen permeability through the polymer liner becomes paramount for ensuring the safety efficiency and longevity of Type IV hydrogen storage tanks. This paper synthesizes existing research findings analyzes the influence of different materials and structures on gas permeability elucidates the dissolution and diffusion mechanisms of hydrogen in plastic liners and discusses their engineering applications. We focus on measurement methods influencing factors and improvement strategies for liner gas permeability. Additionally we explore the prospects of Type IV hydrogen storage tanks in fields such as automotive aerospace and energy storage industries. Through this comprehensive review of liner gas permeability critical insights are provided to guide the development of efficient and safe hydrogen storage and transportation systems. These insights are vital for advancing the widespread application of hydrogen energy technology and fostering sustainable energy development significantly contributing to efforts aimed at enhancing the performance and safety of Type IV hydrogen storage tanks.
Injection Strategies in a Hydrogen SI Engine: Parameter Selection and Comparative Analysis
Oct 2025
Publication
Injection strategies play a crucial role in determining hydrogen engine performance. The diversity of these strategies and the limited number of comparative studies highlight the need for further investigation. This study focuses on the analysis parameter selection and comparison of single early and late direct injection single injection with ignition occurring during injection (the so-called jet-guided operation) and dual injection in a hydrogen spark-ignition engine. The applicability and effectiveness of these injection strategies are assessed using contour maps with ignition timing and start of injection as coordinates representing equal levels of key engine parameters. Based on this approach injection and ignition settings are selected for a range of engine operating modes. Simulations of engine performance under different load conditions are carried out using the selected parameters for each strategy. The results indicate that the highest indicated thermal efficiencies are achieved with single late injection while the lowest occur with dual injection. At the same time both dual injection and jet-guided operation provide advantages in terms of knock suppression peak pressure reduction and reduced nitrogen oxide emissions.
Multi-Objective Optimal Energy Management Strategy for Grid-Interactive Hydrogen Refueling Stations in Rural Areas
Mar 2025
Publication
The transportation sector is a significant contributor to global carbon emissions thus necessitating a transition toward renewable energy sources (RESs) and electric vehicles (EVs). Among EV technologies fuel-cell EVs (FCEVs) offer distinct advantages in terms of refueling time and operational efficiency thus rendering them a promising solution for sustainable transportation. Nevertheless the integration of FCEVs in rural areas poses challenges due to the limited availability of refueling infrastructure and constraints in energy access. In order to address these challenges this study proposes a multi-objective energy management model for a hydrogen refueling station (HRS) integrated with RESs a battery storage system an electrolyzer (EL) a fuel cell (FC) and a hydrogen tank serving diverse FCEVs in rural areas. The model formulated using mixed-integer linear programming (MILP) optimizes station operations to maximize both cost and load factor performance. Additionally bi-directional trading with the power grid and hydrogen network enhances energy flexibility and grid stability enabling a more resilient and self-sufficient energy system. To the best of the authors’ knowledge this study is the first in the literature to present a multi-objective optimal management approach for grid-interactive renewablesupported HRSs serving hydrogen-powered vehicles in rural areas. The simulation results demonstrate that RES integration improves economic feasibility by reducing costs and increasing financial gains while maximizing the load factor enhances efficiency cost-driven strategies that may impact stability. The impact of the EL on cost is more significant while RES capacity has a relatively smaller effect on cost. However its influence on the load factor is substantial. The optimization of RES-supported hydrogen production has been demonstrated to reduce external dependency thereby enabling surplus trading and increasing financial gains to the tune of USD 587.83. Furthermore the system enhances sustainability by eliminating gasoline consumption and significantly reducing carbon emissions thus supporting the transition to a cleaner and more efficient transportation ecosystem.
Net-Zero Backup Solutions for Green Ammonia Hubs Based on Hydrogen Power Generation
Jun 2025
Publication
This paper explores cleaner and techno-economically viable solutions to provide electricity heat and cooling using green hydrogen (H2) and green ammonia (NH3) across the entire decarbonized value chain. We propose integrating a 100% hydrogen-fueled internal combustion engine (e.g. Jenbacher JMS 420) as a stationary backup solution and comparing its performance with other backup technologies. While electrochemical storage systems or battery energy storage systems (BESSs) offer fast and reliable short-term energy buffering they lack flexibility in relocation and typically involve higher costs for extended backup durations. Through five case studies we highlight that renewable-based energy supply requires additional capacity to bridge longer periods of undersupply. Our results indicate that for cost reasons battery–electric solutions alone are not economically feasible for longterm backup. Instead a more effective system combines both battery and hydrogen storage where batteries address daily fluctuations and hydrogen engines handle seasonal surpluses. Despite lower overall efficiency gas engines offer favorable investment and operating costs in backup applications with low annual operating hours. Furthermore the inherent fuel flexibility of combustion engines eventually will allow green ammonia-based backup systems particularly as advancements in small-scale thermal cracking become commercially available. Future studies will address CO2 credit recognition carbon taxes and regulatory constraints in developing more effective dispatch and master-planning solutions.
Machine Learning-driven Stochastic Bidding for Hydrogen Refueling Station-integrated Virtual Power Plants in Energy Market
Aug 2025
Publication
Virtual power plants (VPPs) are gaining significance in the energy sector due to their capacity to aggregate distributed energy resources (DERs) and optimize energy trading. However their effectiveness largely depends on accurately modeling the uncertain parameters influencing optimal bidding strategies. This paper proposes a deep learning-based forecasting method to predict these uncertain parameters including solar irradiation temperature wind speed market prices and load demand. A stochastic programming approach is introduced to mitigate forecasting errors and enhance accuracy. Additionally this research assesses the flexibility of VPPs by mapping the flexible regions to determine their operational capabilities in response to market dynamics. The study also incorporates power-to‑hydrogen (P2H) and hydrogen-to-power (H2P) conversion processes to facilitate the integration of hydrogen fuel cell vehicles (HFCVs) into VPPs enhancing both technical and economic aspects. A network-aware VPP connected to generation resources storage facilities demand response programming (DRP) vehicle-to-grid technology (V2G) P2H and H2P is used to evaluate the proposed method. The problem is formulated as a convex model and solved using the GUROBI optimizer. Results indicate that a hydrogen refueling station can increase profits by approximately 49 % compared to the base case of directly selling surplus generation from renewable energy sources (RESs) to the market and profits can further increase to roughly 86 % when other DERs are incorporated alongside the hydrogen refueling station.
Double-Layer Optimal Configuration of Wind–Solar-Storage for Multi-Microgrid with Electricity–Hydrogen Coupling
Oct 2025
Publication
To address the collaborative optimization challenge in multi-microgrid systems with significant renewable energy integration this study presents a dual-layer optimization model incorporating power-hydrogen coupling. Firstly a hydrogen energy system coupling framework including photovoltaics storage batteries and electrolysis hydrogen production/fuel cells was constructed at the architecture level to realize the flexible conversion of multiple energy forms. From a modeling perspective the upper-layer optimization aims to minimize lifecycle costs by determining the optimal sizing of distributed PV systems battery storage hydrogen tanks fuel cells and electrolyzers within the microgrid. At the lower level a distributed optimization framework facilitates energy sharing (both electrical and hydrogen-based) across microgrids. This operational layer maximizes yearly system revenue while considering all energy transactions—both inter-microgrid and grid-to-microgrid exchanges. The resulting operational boundaries feed into the upper-layer capacity optimization with the optimal equipment configuration emerging from the iterative convergence of both layers. Finally the actual microgrid in a certain area is taken as an example to verify the effectiveness of the proposed method.
Influence of Engine Oils on Pre-Ignition Tendency in a Hydrogen–Kerosene Dual-Fuel Engine
Mar 2025
Publication
Reducing CO2 emissions is an increasingly important goal in general aviation. The dual-fuel hydrogen–kerosene combustion process has proven to be a suitable technology for use in small aircraft. This robust and reliable technology significantly reduces CO2 emissions due to the carbon-free combustion of hydrogen during operation while pure kerosene or sustainable aviation fuel (SAF) can be used in safety-critical situations or in the event of fuel supply issues. Previous studies have demonstrated the potential of this technology in terms of emissions performance and efficiency while also highlighting challenges related to abnormal combustion phenomena such as knocking and pre-ignition which limit the maximum achievable hydrogen energy share. However the causes of such phenomena—especially regarding the role of lubricating oils—have not yet been sufficiently investigated in hydrogen engines making this a crucial area for further development. In this paper investigations at the TU Wien Institute of Powertrain and Automotive Technology concerning the role of different engine oils in influencing pre-ignition tendencies in a hydrogen–kerosene dual-fuel engine are described. A specialized test procedure was developed to account for the unique combustion characteristics of the dual-fuel process along with a detailed purge procedure to minimize oil carryover. Multiple engine oils with varying compositions were tested to evaluate their influence on pre-ignition tendencies with a particular focus on additives containing calcium magnesium and molybdenum known for their roles in detergent and anti-wear properties. Additionally the study addressed the contribution of particles to pre-ignition occurrences. The results indicate that calcium and magnesium exhibit no notable impact on pre-ignition behavior; however the addition of molybdenum results in a pronounced reduction in pre-ignition events which could enable a higher hydrogen energy share and thus decrease CO2 emissions in the context of hydrogen dual-fuel aviation applications.
A Decision-support Flowchart for Including Parameter Uncertainty in Prospective Life Cycle Inventory Modeling: An Application to a PEM Fuel Cell-based APU System for a Hydrogen-powered Aircraft
Oct 2025
Publication
Emerging energy technologies offer significant opportunities for climate change mitigation. However the assessment of their potential environmental impact through prospective life cycle assessment (pLCA) is challeng‑ ing owing to parameter uncertainties arising from data gaps temporal variability and evolving technological contexts when modeling their prospective life cycle inventories (pLCI). Existing methodologies lack standardized approaches for systematically integrating parameter uncertainty within pLCI frameworks often initially overlooking it. In order to fill this gap this study proposes a structured and transparent approach for incorporating parameter uncertainty directly into the pLCI modeling process. The goal is to enhance the robustness transparency and reproducibility of pLCI models. A decision–support flowchart based on an adapted six-step framework was developed to help life cycle assessment (LCA) practitioners address parameter uncertainty during the “goal and scope definition” and“life cycle inventory” phases of pLCA. The flowchart guides users through the process of defining of the assessment’s goal scope as well as its temporal and geographical boundaries and the technology’s maturity level (Step 1). Step 2 entails gathering data to depict the technology’s development. Steps 3 and 4 involve identifying parameters that are likely to change in the future such as manufacturing processes materials equipment and component dimensions as well as their respective uncertainties. Step 5 includes the learning effects required for industrial-scale production once the technology has reached maturity. Finally step 6 identifies external developments impacting the technology as well as contributing uncertainties. A case study of a fuel cell-based propulsion system for a hydrogen-powered aircraft in 2040 illustrates the applicability of the framework. This study introduces a structured flowchart to support decision making in cases when parameter uncertainty should be integrated into pLCI modeling. By supporting the selection of appropriate prospective meth‑ ods as well as uncertainty identification and characterization strategies the proposed flowchart enhances the trans‑ parency consistency and representativeness of the pLCA results facilitating their broader application in emerging technology assessment methods.
Combined Effects of Copper Oxide Nanoparticles and Hydrogen Enrichment on the Performance and Emissions of Butanol Enriched Biodiesel in a Diesel Engine
Oct 2025
Publication
This study explores a multi-faceted approach to improving the combustion performance and emission characteristics of a single-cylinder four-stroke direct injection (DI) compression ignition engine through the combined effects of butanol enrichment green-synthesized copper oxide (CuO) nanoparticles and hydrogen supplementation. The baseline fuel was a B20 biodiesel blend further enriched with 10 % butanol to enhance oxygen availability and atomization. CuO nanoparticles were synthesized via an eco-friendly aloe vera extractmediated method and dispersed into the fuel to promote oxidation kinetics and stabilize combustion. Experimental results revealed that the B20+But10 %+CuO100 blend achieved the highest brake thermal efficiency (BTE) of 33.6 % at full load alongside notable reductions in carbon monoxide (CO) unburned hydrocarbons (HC) nitrogen oxides (NOx) and smoke opacity compared to neat B20. Reactivity controlled compression ignition (RCCI) trials further demonstrated that hydrogen enrichment at 5 LPM and 10 LPM improved flame propagation Brake thermal efficiency (33.89 % & 35.43 %) and reduced brake-specific fuel consumption of nearly 10 % (0.26 Kg/KWh) & 0.25 Kg/KWh). While excessive hydrogen supply (10 LPM) marginally increased HC emissions (110 PPM) at higher loads due to localized incomplete oxidation overall results confirm significant emission mitigation. The findings highlight that the synergistic integration of butanol oxygenation catalytically active CuO nanoparticles and optimized hydrogen enrichment offers a viable pathway toward cleaner combustion improved energy efficiency and reduced pollutant emissions in biodiesel-fueled CI engines.
Comprehensive Analysis of a Full-scale Solid Oxide Fuel Cell Stack Fueled by Ammonia
Oct 2025
Publication
Ammonia represents a promising alternative fuel and hydrogen carrier for power generation due to its advantages in storage and transportation compared to those of hydrogen. However challenges persist in the direct use of ammonia in solid oxide fuel cells (SOFCs) particularly with respect to performance degradation—an issue that necessitates comprehensive investigation at the full-stack scale. This study examines a ten-cell full-size SOFC stack under various operating conditions to evaluate the viability of ammonia as a direct fuel. Experiments were conducted using pure ammonia pure hydrogen fully reformed ammonia and 50 % pre-reformed ammonia at three operating temperatures (660◦C 710 ◦C and 760 ◦C). Performance was characterized through current–voltage curves electrochemical impedance spectroscopy and continuous monitoring of residual ammonia in the exhaust using Fourier-transform infrared spectroscopy. A 200-hour durability test was performed to assess long-term stability. The results demonstrated that at temperatures of ≥ 710 ◦C ammonia-fueled SOFCs performed comparably to hydrogen-fueled configurations within typical operating ranges (0.2–0.5 A/cm2 ). The stack achieved optimal performance at 55–80 % fuel utilization. The ammonia-fueled configurations exhibited different voltage behaviors at higher fuel utilizations compared with those of the hydrogen-fueled configurations. The residual ammonia concentration in the anode off-gas remained well below the safety thresholds. Long-term testing demonstrated an initial degradation that eventually stabilized at a more sustainable rate. These findings validate ammonia as a viable fuel for SOFC stacks when operated at appropriate temperatures (≥710 ◦C) and optimal fuel utilization offering a pathway toward sustainable carbon-free ammonia energy systems.
Life Cycle Assessment of Future Electricity and Hydrogen Systems: Implications for Low-carbon Transport
Oct 2025
Publication
This study develops and applies a life cycle assessment (LCA) framework combined with predictive market models to evaluate the environmental impacts of electricity and hydrogen for transport in the EU27+UK from 2020 to 2050. By linking evolving power sector scenarios with hydrogen supply models we assess the wellto-wheels (WTW) performance of battery electric vehicles (BEVs) and fuel cell electric vehicles (FCEVs) under consistent energy assumptions. Results show that electricity decarbonization can reduce GWP by up to 80% by 2050 but increases land use and mineral/metal demand due to renewable infrastructure expansion. The environmental impacts of hydrogen production are strongly influenced by the electricity mix especially in high electrolysis scenarios. WTW analysis indicates that while BEVs consistently achieve lower WTW GWP than FCEVs across all scenarios both drivetrains exhibit notable trade-offs in other impact categories. Scenarios dominated by blue hydrogen although not optimal in terms of GWP present a more balanced environmental profile making them a viable transitional pathway in contexts that prioritize minimizing other environmental impacts.
A Priori and a Posteriori Analyses of Differential and Preferential Diffusion in Large Eddy Simulations of Partially Premixed Hydrogen-air Flames
Oct 2025
Publication
Differential diffusion (DD) and non-unity Lewis number (Le) effects in the filtered equations of the mixture fraction progress variable their respective sub-grid scale (SGS) variances and enthalpy are investigated using a priori and a posteriori analyses of a lifted turbulent hydrogen jet flame. The a priori analyses show that the absolute magnitudes of the DD terms in the filtered mixture fraction equation and its SGS variance are significant individually but their net contribution is small. The DD effects are found to be small for the progress variable and its SGS variance. One non-unity Le term is of similar magnitude to the turbulent flux for the filtered enthalpy and is independent of turbulent transport. Therefore a simple model for this effect is constructed using flamelets. A priori validation of this model is performed using direct numerical simulation data of a lifted hydrogen flame and its a posteriori verification is undertaken through two large eddy simulations. This effect influences the enthalpy field and hence the temperature is affected because of the relative increase (decrease) in thermal diffusivity for lean (rich) mixtures. Hence higher peak temperatures are observed in the rich mixture when the non-unity Le effects are included. However its overall effects on the flame lift-off height and flame-brush structure are observed to be small when compared with measurements. Hence the DD and non-unity Le effects are negligible for LES of partially premixed combustion of hydrogen–air mixtures in high Reynolds number flows. Novelty and significance The relative importance of differential and preferential diffusion effects for large eddy simulations using the tabulated chemistry approach is systematically assessed. The consistency among the complete set of equations and their closure models of the controlling variables (filtered mixture fraction progress variable their subgrid scale variances and enthalpy) for partially premixed combustion is maintained on the physical and mathematical grounds for the first time. The novelty of this work lies in the development validation and verification of a computationally simple yet accurate and robust model for these diffusion effects and its a priori and a posteriori analyses. It is demonstrated that the influence of non-equidiffusion is small for turbulent partially premixed hydrogen–air flames and hence the standard unity Lewis number approach is shown to be sufficient for turbulent partially premixed flames with high turbulence levels which are typical in practical applications.
Fuel Cell Air Compressor Concepts to Enhance the Efficiency of FCEV
Oct 2025
Publication
The thermal management system and the balance-of-plant (BoP) in fuel cell electric vehicles (FCEV) are characterized by a particularly high level of complexity and a number of interfaces. Optimizing the efficiency of the overall vehicle is of special importance to maximize the range and increase the attractiveness of this technology to customers. This paper focuses on the optimization potential of the air supply system in the BoP whereby the charging concepts of the electric supercharger (ESC) and the electrically assisted turbocharger (EAT) as well as the integration of water spray injection (WSI) at the compressor inlet are investigated in the framework of an FCEV complete vehicle co-simulation. As a benchmark for the integration of these optimization measures the complete vehicle co-simulation is designed for a fuel cell electric passenger car of the current generation. Here thermo-hydraulic fluid circuits in the thermal management software KULI are coupled with mathematical-physical models in MATLAB/Simulink. Applying advanced simulation methodologies for the components of fuel cell powertrain and vehicle cabin enables the mapping of the effects of realistic operating conditions on the FCEV characteristics. The EAT offers the advantage over the ESC that due to the arrangement of an exhaust gas turbine a part of the exhaust gas enthalpy flow downstream of the fuel cell stack can be recovered which reduces the electrical compressor drive power. Moreover an additional reduction of this power consumption can be achieved by WSI as the effect of evaporative cooling lowers the initial compression temperature. For analysis and comparison these concepts are again modeled with high degree of detail and integrated into the benchmark overall vehicle simulation. The results indicate considerable reductions in the electric compressor drive power of the EAT compared to the ESC with noteworthy potential for reducing the vehicle’s hydrogen consumption. At an operating point in Worldwide harmonized Light Duty Test Cycle (WLTC) under 35 ◦ C ambient temperature and 25 % relative humidity the electrical compressor drive power shows a reduction potential of −40 % which corresponds to a vehicle-level hydrogen consumption reduction of up to −3 %. In addition the results also highlight the effect of the WSI in both charging concepts whereby its potential to reduce the hydrogen consumption on the overall vehicle level is relatively small. In WLTC at 35 ◦C ambient temperature and 25 % relative humidity the compressor drive power reduction potential for ESC and EAT averages −5 % while the effect on hydrogen consumption is only around −0.25 %.
Catalytic Pathways Towards Sustainable Aviation Fuel Production from Waste Biomass: A Systematic Review
Oct 2025
Publication
Sustainable aviation fuel (SAF) derived from renewable resources presents a practical alternative to Jet-A fuel by mitigating the ecological impact of aviation’s reliance on fossil fuel. Among the available feedstocks waste biomass and waste oils present key advantages due to their abundance sustainability potential and waste valorization benefits. Despite continuous progress in SAF technologies comprehensive assessments of catalytic routes and their efficiency in transforming waste-based feedstocks into aviation-grade fuels remain limited. This review addresses this gap by systematically evaluating recent studies (2019–2024) that investigate catalytic conversion and upgrading of waste-derived biomass toward SAF production. Selection of thermochemical processes including pyrolysis gasification and hydrothermal liquefaction or biological pathways is driven by the physicochemical characteristics of the waste. These processes yield intermediates such as biocrude and bio-oils undergo catalytic upgrading to meet aviation fuel standards. Zeolitic acids sulfided NiMo or CoMo catalysts noble-metal/oxide systems and bifunctional or carbon-based catalysts drive hydroprocessing deoxygenation cracking and isomerisation reactions delivering high selectivity toward C8-C16fractions. Performance mechanisms and selectivity of these catalysts are critically assessed in relation to feedstock characteristics and operating conditions. Key factors such as metal-acid balance hierarchical porosity and tolerance to heteroatoms enhance catalytic efficiency. Persistent challenges including deactivation coking sintering and feedstock impurities continue to limit long-term performance and scalability in waste-to-SAF applications. Mitigation strategies including oxidative and resulfidation regeneration and support modification have demonstrated improved stability. Moreover waste-derived catalysts and circularity enhance process sustainability. Future work should align catalyst design with feedstock pretreatment and techno-economic assessments to scale sustainable and cost-effective waste-to-SAF pathways.
QDQN-ThermoNet: A Quantum-driven Dual Depp Q-network Framework for Intelligent Thermal Regulation in Solid-state and Hydrogen Fuel Cell Systems of Future Electric Vehicles
Oct 2025
Publication
This paper presents QDQN-ThermoNet a novel Quantum-Driven Dual Deep Q-Network framework for intelligent thermal regulation in next-generation electric vehicles with hybrid energy systems. Our approach introduces a dual-agent architecture where a classical DQN governs solid-state battery thermal management while a quantumenhanced DQN regulates proton exchange membrane fuel cell dynamics both sharing a unified quantumenhanced experience replay buffer to facilitate cross-system information transfer. Hardware-in-the-Loop validation across diverse operational scenarios demonstrates significant performance improvements compared to classical methods including enhanced thermal stability (95.1 % vs. 82.3 %) faster thermal response (2.1 s vs. 4.7 s) reduced overheating events (0.3 vs. 3.2) and superior energy efficiency (22.4 % energy savings). The quantum-enhanced components deliver 38.7 % greater sample efficiency and maintain robust performance under sparse data conditions (33.9 % improvement) while material-adaptive control strategies leveraging MXeneenhanced phase change materials achieve a 50.3 % reduction in peak temperature rise during transients. Component lifetime analysis reveals a 33.2 % extension in battery service life through optimized thermal management. These results establish QDQN-ThermoNet as a significant advancement in AI-driven thermal management for future electric vehicle platforms effectively addressing the complex challenges of coordinating thermal regulation across divergent energy sources with different optimal operating temperatures.
Fuel Cell and Electric Vehicles: Resource Use and Associated Environmental Impacts
Oct 2025
Publication
Achieving transport decarbonization depends on electric vehicle (EV) and fuel cell vehicle (FCV) deployment yet their material demands and impacts vary by vehicle type. This study explores how powertrain preferences in light-duty vehicles (LDVs) and heavy-duty vehicles (HDVs) shape future resource use and material-related environmental outcomes. Using dynamic material flow analysis and prospective life cycle assessment we assess three scenarios. In the S3 EV-dominant scenario 2050 lithium and cobalt demand rises by up to 11.9-fold and 1.8-fold relative to 2020 with higher global warming and human toxicity impacts. The S2 FCV-dominant scenario leads to a 21.7-fold increase in platinum-group metal demand driving up freshwater ecotoxicity and particulate emissions. A balanced S1 scenario EVs in LDVs and FCVs in HDVs yields moderate material demand and environmental burdens. These findings demonstrate that no single pathway can fully resolve material-related impacts while combining EVs and FCVs across LDVs and HDVs enables a more balanced and sustainable transition.
Numerical Investigation of Combustion, Performance, and Emission Attributes of Premixed Ammonia-hydrogen/air Flames within a Swirl Burners of a Gas Turbine
Oct 2025
Publication
This study investigates numerically combustion attributes and NOx formation of premixed ammonia-hydrogen/air flames within a swirl burner of a gas turbine considering various conditions of hydrogen fraction (HF: 0 % 5 % 30 % 40 % and 50 %) equivalence ratio (φ: 0.85 1.0 and 1.2) and mixture inlet temperature (Tin: 400–600 K). The results illustrate that flame temperature increases with hydrogen addition from 1958 K for pure ammonia to 2253 K at 50 % HF. Raising the inlet temperature from 400 K to 600 K markedly enhances combustion intensity resulting in an increase of the Damköhler number (Da) from 117 to 287. NOx levels rise from ∼1800 ppm (0 % HF) to ∼7500 ppm (50 % HF) and peak at 8243 ppm under lean conditions (φ = 0.85). Individual NO N2O and NO2 emissions also reach maxima at φ = 0.85 with values of 5870 ppm 2364 ppm and 10 ppm respectively decreasing significantly under richer conditions (2547 ppm 1245 ppm and 5 ppm at φ = 1.2). These results contribute to advancing low-carbon fuel technologies and highlight the viability of ammonia-hydrogen co-firing as a pathway toward sustainable gas turbine operation.
Verification of the reactingFoam Solver Through Simulating Hydrogen–Methane Turbulent Diffusion Flame, and an Overview of Flame Types and Flame Stabilization Techniques
Nov 2025
Publication
This study aims to qualitatively and quantitatively assess the ability of the flow solver “reactingFoam” of the open-source OpenFOAM software v.2506 for a control-volume-based computational fluid dynamics (CFD) solver in treating the reacting flow problem of a popular benchmarking bluff-body-stabilized turbulent diffusion (non-premixed) flame that is the HM1 flame. The HM1 flame has a fuel stream composed of 50% hydrogen (H2) and 50% methane (CH4) by mole. Thus the acronym “HM1” stands for “hydrogen– methane with level 1 of jet speed”. This fuel stream is surrounded by a coflow of oxidizing air jet. This flame was studied experimentally at the University of Sydney. A measurement dataset of flow and chemical fields was compiled and made available freely for validating relevant computational models. We simulate the HM1 flame using the reactingFoam solver and report here various comparisons between the simulation results and the experimental results to aid in judging the feasibility of this open-source CFD solver. The computational modeling was conducted using the specialized wedge geometry suitable for axisymmetric problems. The turbulence–chemistry interaction (TCI) was based on the Chalmers’ partially stirred reactor (CPaSR) model. The two-equation k-epsilon framework is used in modeling the small eddy scales. The four-step Jones-Lindstedt (JL) reaction mechanism is used to describe the chemical kinetics. Two meshes (coarse and fine) were attempted and a converged (mesh-independent) solution was nearly attained. Overall we notice good agreement with the experimental data in terms of resolved profiles of the axial velocity mass fractions and temperature. For either mesh resolution the overall deviation between the computational results and the experimental results is approximately 8% (mean absolute deviation) and 10% (root mean square deviation). These are favorably low. The current study and the presented details about the reactingFoam solver and its implementation can be viewed as a good case study in CFD modeling of reacting flows. In addition the information we provide about the measurement dataset the emphasized recirculation zone the entrainment phenomena and the irregularity in the radial velocity can help other researchers who may use the same HM1 data.
Assessing the Viability of Hydrogen-Based Wind Energy Conversion and Transmission Systems Versus the Existing Electrical-Based System—A Comprehensive Review
Nov 2025
Publication
This study presents a comprehensive review of the viability of hydrogen as an energy carrier for offshore wind energy compared to existing electricity carrier systems. To enable a state-of-the-art system comparison a review of wind-to-hydrogen energy conversion and transmission systems is conducted alongside wind-to-electricity systems. The review reveals that the wind-to-hydrogen energy conversion and transmission system becomes more cost-effective than the wind-to-electricity conversion and transmission system for offshore wind farms located far from the shore. Electrical transmission systems face increasing technical and economic challenges relative to the hydrogen transmission system when the systems move farther offshore. This study also explores the feasibility of using seawater for hydrogen production to conserve freshwater resources. It was found that while this approach conserves freshwater and can reduce transportation costs it increases overall system costs due to challenges such as membrane fouling in desalination units. Findings indicated that for this approach to be sustainable proper management of these challenges and responsible handling of saline waste are essential. For hydrogen energy transmission this paper further explores the potential of repurposing existing oil and gas pipeline infrastructure instead of constructing new pipelines. Findings indicated that with proper retrofitting the existing natural gas pipelines could provide a cost-effective and environmentally sustainable solution for hydrogen transport in the near future.
Outlook on the Decarbonization of Non-Electrified Passenger Railway Connections in Poland
Nov 2025
Publication
The decarbonization of regional passenger rail transport is one of the key challenges for the sustainable transformation of the transport sector in Poland. While railway transportation remains one of the least carbon-intensive modes of transport significant emission disparities persist between electrified and non-electrified lines where diesel traction is still prevalent. This article presents a comparative analysis of various propulsion technologies—diesel hybrid battery-electric and hydrogen fuel-cell—taking into account both local (TTW) and total (WTW) greenhouse gas emissions. The study incorporates Poland’s current energy mix and proposes a methodological framework to assess emissions at the line level. It highlights the risks of focusing exclusively on in situ zero-emission technologies and calls for a more flexible efficiency-based approach to fleet modernization. The analysis demonstrates that hybrid and optimized combustion-based systems can provide substantial emission reductions in the short term especially in rural and transitional regions. The paper also critically discusses transport funding policies pointing to discrepancies between incentives for private electric mobility and the lack of support for public transport solutions that could effectively counter mobility exclusion. The presented methodology and conclusions provide a basis for further research on transport decarbonization strategies tailored to national and regional contexts.
How Heat-Powered Heat Pumps Could Reduce the Need for Grid-Scale Energy Storage
Nov 2025
Publication
This paper explores how the deployment of “High-Performance Heat-Powered Heat Pumps” (HP3 s)—a novel heating technology—could help meet the domestic heating demand in the UK and reduce how much grid-scale energy storage is needed in comparison to a scenario where electrical heat pumps fully supply the heating demand. HP3 systems can produce electricity which can partially alleviate the stress caused by electrical heat pumps. A parametric analysis focusing on two variables the penetration of HP3 systems (H) and the amount of electricity exported (Ɛ) is presented. For every combination of H and Ɛ the electricity system is optimized to minimize the cost of electricity. Three parameters define the electricity system: the generation mix the energy storage mix and the amount of over-generation. The cost of electricity is at its highest when electrical heat pumps supply all demand. This reduces as the penetration of HP3 systems increases due to a reduction in the need for energy storage. When HP3 systems supply 100% of the heating demand the total cost of electricity and the storage capacity needed are 6% and 50% lower respectively compared to a scenario where electrical heat pumps are in 100% of residences.
Hybrid Wind–Solar–Fuel Cell–Battery Power System with PI Control for Low-Emission Marine Vessels in Saudi Arabia
Nov 2025
Publication
The maritime industry is under increasing pressure to reduce greenhouse gas emissions especially in countries such as Saudi Arabia that are actively working to transition to cleaner energy. In this paper a new hybrid shipboard power system which incorporates wind turbines solar photovoltaic (PV) panels proton-exchange membrane fuel cells (PEMFCs) and a battery energy storage system (BESS) together for propulsion and hotel load services is proposed. A multi-loop Energy Management System (EMS) based on proportional–integral control (PI) is developed to coordinate the interconnections of the power sources in real time. In contrast to the widely reported model predictive or artificial intelligence optimization schemes the PI-derived EMS achieves similar power stability and hydrogen utilization efficiency with significantly reduced computational overhead and full marine suitability. By taking advantage of the high solar irradiance and coastal wind resources in Saudi Arabia the proposed configuration provides continuous near-zeroemission operation. Simulation results show that the PEMFC accounts for about 90% of the total energy demand the BESS (±0.4 MW 2 MWh) accounts for about 3% and the stationary renewables account for about 7% which reduces the demand for hydro-gas to about 160 kg. The DC-bus voltage is kept within ±5% of its nominal value of 750 V and the battery state of charge (SOC) is kept within 20% to 80%. Sensitivity analyses show that by varying renewable input by ±20% diesel consumption is ±5%. These results demonstrate the system’s ability to meet International Maritime Organization (IMO) emission targets by delivering stable near-zero-emission operation while achieving high hydrogen efficiency and grid stability with minimal computational cost. Consequently the proposed system presents a realistic certifiable and regionally optimized roadmap for next-generation hybrid PEMFC–battery–renewable marine power systems in Saudi Arabian coastal operations.
A Deep Neural Network-Based Approach for Optimizing Ammonia–Hydrogen Combustion Mechanism
Nov 2025
Publication
Ammonia is a highly promising zero-carbon fuel for engines. However it exhibits high ignition energy slow flame propagation and severe pollutant emissions so it is usually burned in combination with highly reactive fuels such as hydrogen. An accurate understanding and modeling of ammonia–hydrogen combustion is of fundamental and practical significance to its application. Deep Neural Networks (DNNs) demonstrate significant potential in autonomously learning the interactions between high-dimensional inputs. This study proposed a deep neural network-based method for optimizing chemical reaction mechanism parameters producing an optimized mechanism file as the final output. The novelty lies in two aspects: first it systematically compares three DNN structures (Multilayer perceptron (MLP) Convolutional Neural Network and Residual Regression Neural Network (ResNet)) with other machine learning models (generalized linear regression (GLR) support vector machine (SVM) random forest (RF)) to identify the most effective structure for mapping combustion-related variables; second it develops a ResNet-based surrogate model for ammonia–hydrogen mechanism optimization. For the test set (20% of the total dataset) the ResNet outperformed all other ML models and empirical correlations achieving a coefficient of determination (R2 ) of 0.9923 and root mean square error (RMSE) of 135. The surrogate model uses the trained ResNet to optimize mechanism parameters based on a Stagni mechanism by mapping the initial conditions to experimental IDT. The results show that the optimized mechanism improves the prediction accuracy on laminar flame speed (LFS) by approximately 36.6% compared to the original mechanism. This method while initially applied to the optimization of an ammonia–hydrogen combustion mechanism can potentially be adapted to optimize mechanisms for other fuels.
Advancing the Energy Transition in the Steel Industry: A Game-theoretic Bilevel Approach for Green Hydrogen Supply Chains
Sep 2025
Publication
Green hydrogen is essential for advancing the energy transition as it is regarded as a CO2-neutral flexible and storable energy carrier. Particularly in steel production which is known for its high energy intensity hydrogen has great potential to replace conventional energy sources. In a game-theoretic bi-level optimization model involving a power plant operator and a steel company we investigate in which situations the production and use of green hydrogen is advantageous from an economic and ecological point of view. Through an extensive case study based on a realworld scenario we can observe that hydrogen production can serve as a profitable and flexible secondary income opportunity for the power plant operator and help avoid curtailment and spot market losses. On the other hand the steel manufacturer can reduce CO2 emissions and associated costs while also meeting the growing customer demand for low-carbon products. However our findings also highlight important trade-offs and uncertainties. While lower electricity generation costs or improved electrolyzer efficiency enhance hydrogen’s competitiveness increases in coal and CO2 emission prices do not always result in greater hydrogen adoption. This is due to the persistent reliance on a non-replaceable share of coal in steel production which raises the overall cost of both low-carbon and carbon-intensive steel. The model further shows that consumer demand elasticity plays a critical role in determining hydrogen uptake. These insights underscore the importance of not only reducing hydrogen costs but also designing supportive policies that address market acceptance and the full cost structure of green industrial products.
Process Analysis and Techno-economic Comparison of Aviation Biofuel Production via Microbial Oil and Ethanol Upgrading
Oct 2025
Publication
The transport sector is the largest source of greenhouse gases in the EU after the energy supply one contributing approximately 27% of total emissions. Although decarbonization pathways for light-duty transport are relatively well established heavy-duty transport shipping and aviation emissions are difficult to eliminate through electrification. In particular the aviation sector is strongly dependent on liquid hydrocarbons making the development of sustainable aviation fuels (SAFs) a critical priority for achieving long-term climate targets. This study evaluates four biomass-to-liquid pathways for producing jet-like SAF from lignocellulosic biomass: (1) triacylglycerides (TAGs) production from syngas fermentation (2) TAGs production from sugar fermentation (3) ethanol production from syngas fermentation and (4) ethanol production from sugar fermentation. These pathways are simulated using Aspen Plus™ and the mass and heat balances obtained are used to assess their technical performance (e.g. carbon utilization energetic fuel efficiency) and techno-economic viability (e.g. production cost capital investment). Pathway (4) demonstrated the highest jet fuel selectivity (63%) and total carbon utilization (32.5%) but at higher power demands. Pathway (1) was self-sufficient in energy due to internal syngas utilization but exhibited lower carbon efficiencies. Cost analysis revealed that microbial oil-based pathways were restrained by higher hydrogen demands and lower product selectivity compared to ethanol-based routes. However with advancements in microbial oil production efficiency and reduced water usage these pathways could become competitive.
Towards Green and Smart Ports: A Review of Digital Twin and Hydrogen Applications in Maritime Management
Oct 2025
Publication
Modern ports are pivotal to global trade facing increasing pressures from operational demands resource optimization complexities and urgent decarbonization needs. This study highlights the critical importance of digital model adoption within the maritime industry particularly in the port sector while integrating sustainability principles. Despite a growing body of research on digital models industrial simulation and green transition a specific gap persists regarding the intersection of port management hydrogen energy integration and Digital Twin (DT) applications. Specifically a bibliometric analysis provides an overview of the current research landscape through a study of the most used keywords while the document analysis highlights three primary areas of advancement: optimization of hydrogen storage and integrated energy systems hydrogen use in propulsion and auxiliary engines and DT for management and validation in maritime operations. The main outcome of this research work is that while significant individual advancements have been made across critical domains such as optimizing hydrogen systems enhancing engine performance and developing robust DT applications for smart ports a major challenge persists due to the limited simultaneous and integrated exploration of them. This gap notably limits the realization of their full combined benefits for green ports. By mapping current research and proposing interdisciplinary directions this work contributes to the scientific debate on future port development underscoring the need for integrated approaches that simultaneously address technological environmental and operational dimensions.
Simulation of the Hydrogen Railway Engine Performance Under Different Load Conditions and Control Parameters
Oct 2025
Publication
The article examines the use of hydrogen fuel as an alternative to traditional diesel fuel for internal combustion engines (ICE) in railway applications. The main objective of the study is to analyze the operational consumption of hydrogen fuel based on the mathematical modeling of the working cycle of the EMD 12-645E3C engine installed on CIE 071 locomotives used in freight and passenger service. The article provides information on the design features of the EMD 12-645E3C engine its technical parameters and the results of bench tests. The indicator parameters of the engine at various controller positions are determined and analyzed and the results of mathematical modeling of its operation on hydrogen fuel are presented. Particular attention is paid to changes in indicator parameters including the maximum combustion pressure and the peak gas temperature in the cylinder as well as comparing the mass consumption of diesel and hydrogen fuel. The study results demonstrate that the use of hydrogen allows the engine to maintain effective power across all operational modes while simultaneously reducing energy costs up to 8%. In this case the pressure and temperature of the gases in the cylinder increased by 3–6% and 5–8%. Recommendations are also provided regarding technical challenges associated with transitioning to hydrogen fuel including the modernization of the combustion chamber fuel system and safety system.
Assessment of the Use of a Passive Pre-Chamber in a Marine Engine Fueled with Ammonia–Hydrogen Mixtures
Oct 2025
Publication
This study investigates the combustion process in a marine spark-ignition engine fueled with an ammonia–hydrogen blend (15% hydrogen by volume) using a passive pre-chamber. A 3D-CFD model supported by a 1D engine model was employed to analyze equivalence ratios between 0.7 and 0.9 and pre-chamber nozzle diameters from 7 to 3 mm. Results indicate that combustion is consistently initiated by turbulent jets but at an equivalence ratio of 0.7 the charge combustion is incomplete. For lean mixtures reducing nozzle size improves flame propagation although not sufficiently to ensure stable operation. At an equivalence ratio of 0.8 reducing the nozzle diameter from 7 to 5 mm advances CA50 by about 6 CAD while further reduction causes minor variations. At richer conditions nozzle diameter plays a negligible role. Optimal performance was achieved with a 7 mm nozzle at equivalence ratio 0.8 delivering about 43% efficiency and 1.17 MW per cylinder.
Development of DC-DC Converters for Fuel-Cell Hybrid Power Systems in a Lift-Cruise Unmanned Aerial Vehicle
Oct 2025
Publication
Lift–cruise-type unmanned aerial vehicles (UAVs) powered by hydrogen fuel cells often integrate secondary energy storage devices to improve responsiveness to load fluctuations during different flight phases which necessitates an efficient energy management strategy that optimizes power allocation among multiple power sources. This paper presents an innovative fuel cell DC–DC converter (FDC) design for the hybrid power system of a lift–cruise-type UAV comprising a multi-stack fuel cell system and a battery. The novelty of this work lies in the development of an FDC suitable for a multi-stack fuel cell system through a dual-input single-output converter structure and a control algorithm. To integrate inputs supplied from two hydrogen fuel cell stacks into a single output a controller with a single voltage controller–dual current controller structure was applied and its performance was verified through simulations and experiments. Load balancing was maintained even under input asymmetry and fault-tolerant performance was evaluated by analyzing the FDC output waveform under a simulated single-stack input failure. Furthermore under the assumed flight scenarios the results demonstrate that stable and efficient power supply is achieved through power-supply mode switching and application of a power distribution algorithm.
Application and Research Progress of Mechanical Hydrogen Compressors in Hydrogen Refueling Stations: Structure, Performance, and Challenges
Nov 2025
Publication
The hydrogen energy industry is rapidly developing positioning hydrogen refueling stations (HRSs) as critical infrastructure for hydrogen fuel cell vehicles. Within these stations hydrogen compressors serve as the core equipment whose performance and reliability directly determine the overall system’s economy and safety. This article systematically reviews the working principles structural features and application status of mechanical hydrogen compressors with a focus on three prominent types based on reciprocating motion principles: the diaphragm compressor the hydraulically driven piston compressor and the ionic liquid compressor. The study provides a detailed analysis of performance bottlenecks material challenges thermal management issues and volumetric efficiency loss mechanisms for each compressor type. Furthermore it summarizes recent technical optimizations and innovations. Finally the paper identifies current research gaps particularly in reliability hydrogen embrittlement and intelligent control under high-temperature and high-pressure conditions. It also proposes future technology development pathways and standardization recommendations aiming to serve as a reference for further R&D and the industrialization of hydrogen compression technology.
An Overview of Development and Challenges in the Use of Hydrogen as a Fuel for a Dual-Fuel Diesel Engine
Nov 2025
Publication
The gradual exhaustion of fossil fuel reserves along with the adverse effects of their consumption on global climate drives the need for research into alternative energy sources that can meet the growing demand in a sustainable and eco-friendly way. Among these hydrogen stands out as one of the most promising options for the automotive sector being the cleanest available fuel and capable of being produced from renewable resources. This paper reviews the existing literature on compression ignition engines operating in a dualfuel configuration where diesel serves as the ignition source and hydrogen is used to enhance the combustion process. The reviewed studies focus on engine systems with hydrogen injection into the intake manifold. The investigations analyzed the influence of hydrogen energy fraction on combustion characteristics engine performance combustion stability and exhaust emissions in diesel/hydrogen dual-fuel engines operating under full or near-full-load conditions. The paper identifies the main challenges hindering the widespread and commercial application of hydrogen in diesel/hydrogen dual-fuel engines and discusses potential methods to overcome the existing barriers in this area.
Life Cycle of Fuel Cells: From Raw Materials to End-of-Life Management
Nov 2025
Publication
Fuel cells are highly efficient electrochemical devices that convert the chemical energy of fuel directly into electrical energy while generating minimal pollutant emissions. In recent decades they have established themselves as a key technology for sustainable energy supply in the transport sector stationary systems and portable applications. In order to assess their real contribution to environmental protection and energy efficiency a comprehensive analysis of their life cycle Life Cycle Assessment (LCA) is necessary covering all stages from the extraction of raw materials and the production of components through operation and maintenance to decommissioning and recycling. Particular attention is paid to the environmental challenges associated with the extraction of platinum catalysts the production of membranes and waste management. Economic aspects such as capital costs the price of hydrogen and maintenance costs also have a significant impact on their widespread implementation. This manuscript presents detailed mathematical models that describe the electrochemical characteristics energy and mass balances degradation dynamics and cost structures over the life cycle of fuel cells. The models focus on proton exchange membrane fuel cells (PEMFCs) with possible extensions to other types. LCA is applied to quantify environmental impacts such as global warming potential (GWP) while the levelized cost of electricity (LCOE) is used to assess economic viability. Particular attention is paid to the sustainability challenges of platinum catalyst extraction membrane production and end-of-life material recovery. By integrating technical environmental and economic modeling the paper provides a systematic perspective for optimizing fuel cell deployment within a circular economy.
Optimal Dispatch Model for Hybrid Energy Storage in Low-Carbon Integrated Energy Systems
Nov 2025
Publication
Integrated Energy Systems (IESs) which leverage the synergistic coordination of electricity heat and gas networks serve as crucial enablers for a low-carbon transition. Current research predominantly treats energy storage as a subordinate resource in dispatch schemes failing to simultaneously optimise IES economic efficiency and storage operators’ profit maximisation thereby overlooking their potential value as independent market entities. To address these limitations this study establishes an operator-autonomous management framework incorporating electrical thermal and hydrogen storage in IESs. We propose a joint optimal dispatch model for hybrid energy storage systems in low-carbon IES operation. The upper-level model minimises total system operation costs for IES operators while the lower-level model maximises net profits for independent storage operators managing various storage assets. These two levels are interconnected through power price and carbon signals. The effectiveness of the proposed model is verified by setting up multiple scenarios for example analysis.
Hydrogen-Rich Gaseous Mixture for Enhanced Combustion in a Flex-Fuel Engine: An Experimental Analysis
Nov 2025
Publication
This experimental study examines the effect of adding a hydrogen-enriched synthetic gaseous mixture (HGM’) on the combustion and fuel conversion efficiency of a singlecylinder research engine (SCRE). The work assesses the viability of using this mixture as a supplemental fuel for flex-fuel engines operating under urban driving cycling conditions. An SCRE the AVL 5405 model was employed operating with ethanol and gasoline as primary fuels through direct injection (DI) and a volumetric compression ratio of 11.5:1. The HGM’ was added in the engine’s intake via fumigation (FS) with volumetric proportions ranging from 5% to 20%. The tests were executed at 1900 rpm and 2500 rpm engine speeds with indicated mean effective pressures (IMEPs) of 3 and 5 bar. When HGM’s 5% v/v was applied at 2500 rpm the mean indicated effective pressure of 3 bar was observed. A decrease of 21% and 16.5% in the ISFC was observed when using gasoline and ethanol as primary fuels respectively. The usage of an HGM’ combined with gasoline or ethanol proved to be a relevant and economically accessible strategy in the improvement of the conversion efficiency of combustion fuels once this gaseous mixture could be obtained through the vapor-catalytic reforming of ethanol giving up the use of turbochargers or lean and ultra-lean burn strategies. These results demonstrated the potential of using HGM’ as an effective alternative to increase the efficiency of flex-fuel engines.
Hydrogen Utilization for Decarbonizing the Dairy Industry: A Techno-economic Scenario Analysis
Nov 2025
Publication
This study investigates the integration of on-site green hydrogen as a substitute for methane in steam generation in the dairy industry specifically in the production of Parmigiano Reggiano cheese. This represents a novel application of green hydrogen in industrial dairy processing with the potential to reduce greenhouse gas emissions. Hydrogen is assumed to be generated via electrolysis powered by photovoltaic energy. A comprehensive techno-economic assessment was conducted with simulations covering key design variables such as hydrogen fraction in steam production photovoltaic panel orientation and storage pressure. A wide range of scenarios was defined in order to account for variability in system structures and performance and a comprehensive economic assessment was then carried out using a Monte Carlo simulation approach and a sensitivity analysis. Results indicate that in all scenarios the net present value over a 15-year period remains negative when benefits are limited to methane savings. Indeed the high capital expenditure associated with hydrogen systems presents a major barrier. The most favorable cases occur at low hydrogen shares with seasonal storage while full conversion to hydrogen maximizes CO2 abatement but is least economical. With public funding the emissions saved per euro of public support range from 1.58 to 2.14 kg CO2eq/€.
Decarbonization of Hard-to-abate Industries under Water Constraints via Renewable Hydrogen Infrastructure Planning
Nov 2025
Publication
Achieving global decarbonization is essential to mitigate climate change yet heat-intensive industries remain challenging to decarbonize through electrification alone. Green hydrogen offers a clean alternative to replace fossil fuels and fossil fuel–based hydrogen but its deployment requires careful planning and robust economic assessment. This study addresses the optimal design of a green hydrogen supply chain in a Mediterranean region where ceramics and cement dominate as energy-intensive industries while oil refining is the main consumer of fossil fuel–based hydrogen. The region also faces freshwater scarcity due to its climate and the high demand for water from tourism and agriculture. A Mixed-Integer Linear Programming (MILP) model is developed to minimize the total cost of supplying green hydrogen by determining the optimal size and location of renewable energy sources integrating desalinated seawater from existing desalination plants as feedstock and designing the infrastructure connecting production storage and demand centers. The cost-optimal configuration includes 3.4 GW of PEM electrolyzers requiring 41.1 m3 /h of desalinated seawater supplied by existing desalination plants along with 5.1 GW of wind and 12 GW of solar power as renewable energy sources for large-scale hydrogen production. Results show that supplying green hydrogen to these industries can avoid approximately 4.4 million tons of CO2 emissions annually achieving a levelized cost of hydrogen (LCOH) of $2.18/kg for the period 2030–2050. Beyond this case study the proposed framework provides a replicable methodology for planning hydrogen-based energy systems in regions facing similar water and decarbonization challenges.
Technical and Environmental Assessment of New Green Iron Production Strategies using Hydrogen
Nov 2025
Publication
In order to assess the decarbonization potential and overall environmental benefits of new reduction pathways in the ironmaking industry using hydrogen to produce Direct Reduced Iron (DRI) a coupled approach combining process simulation for rigorous technical and energy evaluation of iron ore conversion and Life Cycle Assessment (LCA) for environmental assessment was developed and extended to two alternative renewable heating strategies: (i) electric gas heating and (ii) solar reactor heating. The entire hydrogen-based ironmaking process including conversion in a shaft reactor gas and solid heating gas recycling and electrolysis was therefore simulated. The hydrogen-based reduction of iron ores in the shaft reactor was modeled using a rigorous reactor model describing the reduction of multi-layer iron ore pellets in countercurrent gas–solid moving beds with the particularity of representing the dual influence of particle size and temperature on conversion. The remainder of the process including gas recycling and hydrogen production was simulated using ProSim software. The hydrogen-based green ironmaking scenarios were then compared to MIDREX NG a leading natural gas-based reduction technology. Hydrogen-based scenarios powered by the French electricity mix reduce carbon footprints by 53 % for electric gas heating and 57 % for solar reactor heating potentially reaching 82 % (− 0.79 kgCO2-eq/kgDRI) with low-carbon electricity (hydro nuclear). Compared to MIDREX NG the energy requirements of both hydrogen-based scenarios are primarily determined by the use of electricity for hydrogen production illustrating the importance of hydrogen production for the assessment of future hydrogen-based green ironmaking.
Heat Transfer Enhancement in Regenerative Cooling Channels: Numerical Analysis of Single- and Double-row Cylindrical Ribs with Supercritical Hydrogen
Nov 2025
Publication
The thermal protection of rocket engine combustion chambers presents a critical challenge in supersonic flight applications. This study numerically investigates the enhancement of heat transfer and coolant flow characteristics in regenerative cooling channels through cylindrical rib integration employing ANSYS Fluent with SST k-ω turbulence modeling to evaluate single- and double-row configurations (0.75–1.25 mm diameter) under supercritical hydrogen conditions (3 MPa 300 K inlet). Results demonstrate that rib-induced turbulence disrupts thermal boundary layers with a 1.25 mm single-row design achieving a 13.67 % reduction in peak wall temperature compared to smooth channels while double-row arrangements show diminishing returns due to increased flow resistance. The thermal performance factor (η = (Nu/Nu₀)/(f/f₀) 1/3) reveals Case 3′s superiority (21.88 % improvement over the smooth channel configuration) in balancing heat transfer enhancement against pressure drop penalties (9.23–20.93 % for single-row 8.26–18.7 % for double-row). Notably density-driven flow acceleration near heated walls mitigates pressure losses through localized viscosity reduction. Furthermore cylindrical ribs reduce thermal stratification by up to 30 % in single-row configurations with double-row designs providing additional temperature homogenization at the cost of increased flow resistance. These findings offer critical insights for optimizing rib-enhanced cooling systems in high-performance rocket engines achieving simultaneous thermal efficiency and hydraulic performance improvements.
Flame Curvature in Heat-loss-affected Lean Hydrogen Flames: A One-dimensional Manifold Approach
Oct 2025
Publication
Curvature effects are incorporated into a one-dimensional composition-space formulation of a non-unity Lewis number lean premixed flame with strong heat loss. The results of this new canonical problem successfully compare with direct numerical simulations (DNS) of a lean hydrogen-air flame propagating in a narrow channel with heat conduction through the confining plates. The complex dynamics of the flame front consisting of isolated flame kernels are analyzed through the various terms arising from the projection of the fuel and energy equations onto a moving scalar reference frame attached to the reaction zone. Novelty and significance statement A novel one-dimensional flame model incorporating curvature and differential diffusion effects is introduced to address non-unity Lewis number lean premixed flames with strong heat loss. This canonical flame model arises from the projection of temperature and fuel gradient magnitude onto composition space. The framework is employed to analyze flame front dynamics and identify the reaction zones governing flame kernel propagation and heat release. The composition-space flame structure shows strong agreement between the canonical problem and direct numerical simulations (DNS) of a lean hydrogen-air flame propagating in a narrow channel with heat conduction.
Thermal Energy Integration and Optimization in a Biomass-fueled Multi-generation System for Power, Hydrogen, and Freshwater Production
Nov 2025
Publication
This work investigates a biomass-driven multi-generation system designed for simultaneous power freshwater and hydrogen production addressing the interlinked energy-waterenvironment nexus. The configuration integrates Brayton supercritical carbon dioxide (SCO2) organic Rankine cycle (ORC) and thermoelectric generator (TEG) subsystems to maximize utilization of biomass-derived syngas. The recovered energy drives a reverse osmosis (RO) desalination unit for freshwater production and an alkaline electrolyzer for hydrogen generation followed by two-stage compression for storage. Under baseline conditions the system generates 1.99 MW of electricity 9.38 kg/h of hydrogen and 88.6 m3 /h of freshwater with an overall exergetic efficiency of 20.25 % emissions intensity of 0.85 kg/kWh and a payback period of 5.87 years. The Brayton cycle accounts for 49.3 % of the total cost rate while the gasifier exhibits the highest exergy destruction at 46 %. Sensitivity analyses show that varying biomass moisture content (10–30 %) and operating temperatures (700–900 ◦C) significantly influence system performance. Using a data-driven optimization framework that combines artificial neural networks (ANN) and a genetic algorithm (GA) the system’s exergetic efficiency improves to 21.76 % freshwater output rises to 90.96 m3 /h and emissions intensity decreases to 0.877 kg/kWh. Additionally optimization reduces the total cost rate by 2.71 % leading to a payback period of 5.4 years and enhances the system’s overall performance by 12.64 %.
Optimal Possibilistic-robust Operation of Multi-energy Microgrids Considering Infrastructure Hydrogen Storage Capability
Nov 2025
Publication
In sustainable energy transitions the utilization of hydrogen is crucial providing flexibility in the operation of net-zero emission renewable-based energy systems. This paper presents a study on the optimal operation of netzero emission multi-energy future microgrids that utilize hydrogen as an alternative fuel instead of natural gas. The electrolyzers’ output is injected into the hydrogen grid to meet demand or converted back to electricity later using generating units owing to the storage capability of pipes called linepack. For this purpose a detailed mathematical model is developed to simulate the main characteristics of grids (e.g. voltage current hydrogen flow and pressure) as well as various components (e.g. renewable systems electrolyzers and hydrogen-fired units). To become more realistic a possibilistic-robust approach is developed to account for the uncertainty arising from the lack of real-world implementation. By representing a case study a test is performed to evaluate the possibility of employing a low-pressure gas grid to meet the demand for hydrogen. After that the effects of electrolyzers are analyzed in the presence and absence of the uncertainty consideration approach. The result indicates that despite hydrogen’s lower energy density compared to natural gas it is still feasible to satisfy the same energy demand level considering the technical characteristics of the grid. The integration of electrolyzers can reduce wind curtailment by 2 % and supplement hydrogen demand by 50 %. A higher level of conservatism in the possibilistic-robust approach leads to an increase in the mean value of the objective function and a reduction in the standard deviation under the realization of uncertain parameters which provides the decisionmakers with a more realistic insight.
Accelerated Numerical Simulations of Hydrogen Flames: Open-source Implementation of an Advanced Diffusion Model Library in OpenFOAM
Oct 2025
Publication
Here the OpenFOAM software with the dynamic load balancer library DLBFoam is investigated for computational fluid dynamics (CFD) simulations of different hydrogen (H2 ) flames. The benefits of DLBFoam for hydrogen have not been thoroughly investigated in the past. To explore this a new open-source diffusion model library FickianTransportFoam is implemented in this study. FickianTransportFoam includes species-specific constant Lewis number and mixture-averaged models with correction velocity to account for preferential diffusion. The model is first verified for one-dimensional (1D) premixed and non-premixed counterflow flames. Additionally four hydrogen/air flames are explored: (1) two-dimensional (2D) laminar freely propagating premixed flame (2) 2D axisymmetric laminar non-premixed jet flame (3) three-dimensional (3D) turbulent non-premixed swirling flame and (4) 3D turbulent premixed swirling flame. The main results and achievements regarding the implemented transport models are as follows. First the results from 2D freely propagating flame demonstrated thermodiffusively unstable flame formation using the mixture averaged model. The analytical and numerical dispersion relationships agree well for the linear instability growth phase. Second the model functionality is demonstrated for a laminar 2D jet case with conjugate heat transfer. Furthermore validation and grid sensitivity studies for the 3D turbulent flames are carried out. Third the computational benchmark for each configuration indicates a factor of ∼10-100 speed-up when utilizing DLBFoam. Finally the test cases and source codes for FickianTransportFoam are openly shared.
Optimal Sizing and Energy Management for Fuel Cell Electric Vehicles with 3D-ordered MEAs: A Pareto Frontier Study
Oct 2025
Publication
Fuel cell electric vehicles (FCEVs) are zero-emission but face cost and power density challenges. To mitigate these limitations a novel 3D-ordered nano-structured self-supporting membrane electrode assembly (MEA) has been developed. This paper investigates the optimal component sizing of the battery and fuel cell in FCEVs equipped with 3D-ordered MEAs integrating the energy management. To explore the trade-offs between component cost operational cost and fuel cell degradation the sizing and energy management problem is formulated into a multi-objective optimisation problem. A Pareto frontier (PF) study is conducted using the decomposed multi-objective evolutionary algorithm (MOEA/D) for a more diverse distribution of feasible solutions. The modular design of fuel cells is derived from a scaled and stressed experiment. After executing MOEA/D across the three aggressive driving cycles power source configurations are selected from the corresponding PFs based on objective trade-offs ensuring robustness of the overall system. The optimisation performance of the MOEA/D is compared with that of the multi-objective Particle Swarm Optimisation. In addition the selected powertrain configurations are evaluated and compared through standard and realworld driving cycles in a simulation environment. This paper also performs a sensitivity analysis to reveal the influence of diverse component unit costs and hydrogen price. The results indicate that the mediumsized configuration consisting of a 63.31 kW fuel cell stack and a 52.15 kWh battery pack delivers the best overall performance. It achieves a 26.71% reduction in component cost and up to 12.76% savings in hydrogen consumption across various driving conditions. These findings provide valuable insights into the design and optimisation of fuel cell systems for FCEVs.
Experimental Validation of DC-link Based Voltage Control Framework for Islanded Hydrogen DC Microgrids
Oct 2025
Publication
The integration of hydrogen technologies into islanded DC microgrids presents significant challenges in maintaining voltage stability and coordinating power flow under highly variable renewable energy conditions. This paper proposes a novel DC-link voltage control (DCVC) framework that incorporates adaptive droop control and autonomous operation algorithms to regulate fuel cells electrolysers and battery systems in a coordinated manner. Unlike conventional fixed-gain or priority-based methods the proposed adaptive control dynamically adjusts the droop coefficient in response to voltage deviations enhancing system stability and responsiveness. The control framework is validated on an industry-standard hydrogen DC microgrid platform developed at Griffith University featuring real-time implementation on a Raspberry Pi controller and comprehensive integration with solar wind wave and hydrogen energy sources. A small-signal stability analysis confirms that the proposed control ensures asymptotic voltage convergence under dynamic operating conditions. Experimental results across five case studies demonstrate that the proposed DCVC strategy ensures fast transient response minimises overshoot and maintains the DC-link voltage near the nominal 380 V under varying load and generation scenarios. The framework facilitates flexible energy sharing while ensuring safe hydrogen production and storage. It is also compatible with low-cost open-source hardware making it a scalable solution for remote and off-grid energy applications.
Techno-enviro-socio-economic Assessment and Sensitivity Analysis of an off-grid Tidal/Fuel Cell/Electrolyzer/Photovoltaic Hybrid System for Hydrogen and Electricity Production in Cameroon Coastal Areas
Oct 2025
Publication
Coastal regions in Cameroon including Douala Kribi Campo Dibamba and Limbe faced persistent electricity challenges driven by grid instability growing demand and dependence on fossil fuels. Solar resource availability was high but intermittent whereas tidal energy was predictable and energy-dense yet underused. This pilot delivers the first Cameroonian assessment of an off-grid tidal/PV/electrolyzer/hydrogen-storage/fuel-cell architecture explicitly co-optimizing electricity service and green hydrogen production and evaluating performance with a tri-metric economic lens (net present cost levelized cost of electricity and the levelized cost of hydrogen). The system was optimized to minimize net present cost (NPC) levelized cost of electricity (LCOE) levelized cost of hydrogen (LCOH) and three tidal-flow scenarios were analyzed to represent hydrokinetic variability. The design served households small businesses fishing activities schools and health facilities with a baseline demand of 389.50 kWh/day; surplus renewable power drove the electrolyzer to produce hydrogen for later reconversion in the fuel cell. Under the first scenario (1.25 m/s average speed) the optimal mix comprised 137 PV modules (600 W each) a 100 kW fuel cell six 40 kW tidal turbines six 10 kW electrolyzers a 19.5 kW converter and 41 hydrogen tanks (40 L each) yielding an NPC of US$ 2.16 million an LCOE of US$ 0.782/kWh and a LCOH of US$ 19.2/kg of hydrogen. The second scenario (1.47 m/s) required only 12 PV modules one electrolyzer and an 11.3 kW converter lowering costs to an NPC of US$ 1.52 million an LCOE of US$ 0.553/ kWh and a LCOH of US$ 15.4/kg of hydrogen. In the third scenario (1.61 m/s) the configuration shifted to 298 PV modules three tidal turbines eight electrolyzers and a 39.6 kW converter resulting in the highest NPC (US$ 2.47 million) and LCOE (US$ 0.901/kWh) with a LCOH of US$ 18.8/kg of hydrogen. The study also contributes a transparent component-wise employment indicator linking installed capacities/energies to jobs; deployment is expected to create about seven local jobs during installation and early operation tidal turbines (3) solar panels (1) electrolyzers (1) hydrogen tanks (1) and fuel cell (1) with additional minor operation and maintenance positions thereafter. Social analysis indicated improved energy access support for local livelihoods and job creation; environmental results confirmed clean operation with limited marine disturbance. A sensitivity study varying capital and replacement-cost multipliers showed robust performance across economic conditions. Taken together these contributions provide a decision-ready blueprint for coastal communities: a first-of-its-kind Cameroonian hybrid that quantifies both electricity and hydrogen costs (including feasible LCOH) and demonstrates socio-economic co-benefits offering a cost-effective pathway to strengthen energy security foster local development and reduce environmental impact.
Cutting-edge Advances in Hydrogen Applications for the Medical and Pharmaceutical Industries
Oct 2025
Publication
The adoption of clean hydrogen is expected to transform the global energy landscape reducing greenhouse gas emissions bridging gaps in renewable energy integration and driving innovation across multiple sectors. In the medical and pharmaceutical industries hydrogen offers unique opportunities for transformative progress. This review critically examines recent advances in three domains: hydrogen fuel cells as reliable scalable and sustainable energy solutions for hospitals; molecular hydrogen as a therapeutic and preventive medical gas particularly for brain disorders; and hydrogenation technologies for the efficient and sustainable pharmaceutical production. Despite encouraging advancements widespread adoption remains limited by economic constraints regulatory gaps and limited clinical evidence. Addressing these barriers through technological innovation largescale studies and life-cycle sustainability assessments is essential to translate hydrogen’s full potential into clinical and industrial practice. Responsible adoption of green hydrogen is poised to reshape the clinical approach to global health and enhance the quality of life for people worldwide.
Optical Investigation and combustion Analysis of Stratified Ammonia-hydrogen Pre-chamber Engine with Variable Injection Timing
Oct 2025
Publication
This study presents an experimental investigation of a direct injection ammonia-fuelled engine using hydrogen pre-chamber jet ignition. All tests have been conducted in an optically accessible combustion chamber that is installed in the head of a single-cylinder engine. The effect of ammonia injection timing on ignition and combustion characteristics was investigated with the timing varied from 165 CAD BTDC to 40 CAD BTDC. The experiments were conducted with a fixed spark timing of 14 CAD BTDC while ammonia injection duration was adjusted to maintain a main chamber global equivalence ratio of 0.6. Two pre-chamber nozzle configurations a single-hole and a multi-hole were tested. The results show that the later NH3 injection timing (40 CAD BTDC) significantly improved combustion with a peak in-cylinder pressure of 80 bar measured compared to a peak in-cylinder pressure of 50 bar with earlier injection (165 CAD BTDC). This study indicates the importance of optimising ammonia injection timing in order to enhance combustion stability and efficiency. The hydrogen pre-chamber jet ignition combined with a late ammonia injection is a promising approach for addressing the combustion challenges of ammonia as a zero-carbon fuel for maritime applications.
A Comparative Analysis of Conventional Thermal and Electrochemical Reforming Pathways for Hydrogen Production Towards Sustainable Aviation Fuels (SAF)
Oct 2025
Publication
H2 is increasingly recognized as a cornerstone of global decarbonization strategies including in hard-toabate sectors such as aviation. Its large-scale applicability remains limited owing to the limited diversity and maturity of low-carbon production pathways. Approximately 96% of global H2 production originates from non-renewable sources primarily through steam methane reforming (SMR) which remains the most commercially established route. Another critical barrier to the substitution of conventional aviation fuels lies in hydrogen storage as the current volumetric energy density and cryogenic storage requirements render onboard integration impractical for most aircraft configurations. To address these challenges this study developed a techno-economic and environmental benchmarking framework that compares conventional thermal reforming technologies (SMR autothermal and POX) with emerging electrochemical routes (water electrolysis and alcohol electro-oxidation) highlighting their potential roles in the transition toward sustainable aviation fuels (SAF). By normalizing efficiency energy intensity CO2 emissions and cost (USD kg 1 H2 and USD GJ 1 ) this study quantifies the trade-offs that define current and emerging pathways. SMR remains the industrial baseline (70%–85% thermal efficiency 1–2 USD kg−1 H2 9–12 kg CO2 kg−1 H2) whereas ethanol-based electrochemical reforming operates 0.3–0.9 V below conventional electrolysis achieving up to 40% lower electrical energy demand (∼2.4 kW h Nm−3 H2 with near-zero direct emissions. A sensitivity analysis demonstrates that a 60% reduction in catalyst cost or electricity prices below 0.03 USD (kW h)−1 could make electrochemical reforming cost-competitive with SMR. This study consolidates fragmented knowledge into a comprehensive roadmap that links catalyst performance and technology readiness for aviation decarbonization by integrating engineering metrics with policy and infrastructure perspectives to identify realistic transition pathways toward sustainable hydrogen and hybrid aviation fuels.
The Role of Hydrogen-based Local Energy Communities in the Development of Hydrogen Cities: A Systematic Review
Nov 2025
Publication
Hydrogen-based Local Energy Communities (LECs) play a pivotal role in modern energy systems and form the fundamental building blocks of hydrogen cities. This review provides a comprehensive assessment of how hydrogen-based LECs advance the hydrogen city concept by examining the technological economic environmental regulatory and social dimensions that shape the integration of green hydrogen into local energy networks. The paper explores the structure of hydrogen cities focusing on the role of multiple LECs in alignment with the European Union’s Clean Energy Package (CEP). Furthermore a case study and mathematical model are presented where the hydrogen city is modelled and the impact of Electric Parking Lot (EPL) and Hydrogen Parking Lot (HPL) management on the hydrogen city’s operation cost is evaluated. The results show that optimised EPL and HPL management can reduce overall operational costs by 5.53 % demonstrating the economic advantages of intelligent scheduling strategies in hydrogen cities.
Design of Hydrogen-Powered Mobile Emergency Power Vehicle with Soft Open Point and Appropriate Energy Management Strategy
Oct 2025
Publication
Zhigang Liu,
Wen Chen,
Shi Liu,
Yu Cao and
Yitao Li
Mobile emergency power supply vehicles (MEPSVs) powered by diesel engines or lithiumion batteries (LIBs) have become a viable tool for emergency power supply. However diesel-powered MEPSVs generate noise and environmental pollution while LIB-powered vehicles suffer from limited power supply duration. To overcome these limitations a hydrogen-powered MEPSV incorporating a soft open point (SOP) was developed in this study. We analyzed widely used operating scenarios for the SOP-equipped MEPSV and determined important parameters including vehicle body structure load capacity driving speed and power generation capability for the driving motor hydrogen fuel cell (FC) module auxiliary LIB module and SOP equipment. Subsequently we constructed an energy management strategy for the model for MEPSV which uses multiple energy sources of hydrogen fuel cells and lithium-ion batteries. Through simulations an optimal hydrogen consumption rate in various control strategies was validated using a predefined load curve to optimize the energy consumption minimization strategy and achieve the highest efficiency.
Enhancing Power-to-Hydrogen Flexibility Through Optimal Bidding in Nordic Energy Activation Market with Wind Integration
Oct 2025
Publication
The recent updates to the Single Day-Ahead Coupling (SDAC) framework in the European energy market along with new rules for providing manual frequency restoration reserve (mFRR) products in the Nordic Energy Activation Market (EAM) have introduced a finer Market Time Unit (MTU) resolution. These developments underscore the growing importance of flexible assets such as power-to-hydrogen (PtH) facilities in delivering system flexibility. However to successfully participate in such markets well-designed and accurate bidding strategies are essential. To fulfill this aim this paper proposes a Mixed Integer Linear Programming (MILP) model to determine the optimal bidding strategies for a typical PtH facility accounting for both the technical characteristics of the involved technologies and the specific participation requirements of the mFRR EAM. The study also explores the economic viability of sourcing electricity from nearby wind turbines (WTs) under a Power Purchase Agreement (PPA). The simulation is conducted using a case study of a planned PtH facility at the Port of Hirtshals Denmark. Results demonstrate that participation in the mFRR EAM particularly through the provision of downward regulation can yield significant economic benefits. Moreover involvement in the mFRR market reduces power intake from the nearby WTs as capacity must be reserved for downward services. Finally the findings highlight the necessity of clearly defined business models for such facilities considering both technical and economic aspects.
Toward Zero-emission Ferries: Integrating Systematic Review and Bibliometric Analysis Insights on Alternative Fuels and Policies
Nov 2025
Publication
The shipping industry aims to achieve full decarbonization at the European Union (EU) level by mid-century. Over the past decade various alternative fuels have been explored to address this goal. However challenges such as insufficient bunkering infrastructure technological immaturity and high costs have made shipowners hesitant to invest in“clean” propulsion systems. This study conducts a bibliometric analysis supported by a systematic literature review to map and critically synthesize current knowledge on alternative fuels for ferry decarbonization and their alignment with emissions reduction policies. Using the Greek ferry fleet as a representative case study the paper evaluates the regulatory framework and technical characteristics of various fuel options and examines their compatibility with different vessel categories. A qualitative comparative framework is introduced to link policy types with alternative fuel pathways offering original insights into policy—fuel alignment. The findings highlight methanol and green electricity (battery-electric systems) as highly promising solutions especially if battery technologies further advance in the coming years. Hydrogen also presents significant potential but is currently limited by high production costs and infrastructure requirements. Rather than presenting a quantitative decision-making model this review establishes the conceptual basis for such a framework in future research. This paper also offers innovative proposals to accelerate the adoption of zero-emission fuels addresses key gaps in existing research and provides insights for advancing ferry decarbonization.
A Two-Stage Optimal Dispatch Strategy for Electric-ThermalHydrogen Integrated Energy System Based on IGDT and Fuzzy Chance-Constrained Programming
Nov 2025
Publication
Na Sun,
Hongxu He and
Haiying Dong
To address the economic and reliability challenges of high-penetration renewable energy integration in electricity-heat-hydrogen integrated energy systems and support the dualcarbon strategy this paper proposes an optimal dispatch method integrating Information Gap Decision Theory (IGDT) and Fuzzy Chance-Constrained Programming (FCCP). An IES model coupling multiple energy components was constructed to exploit multi-energy complementarity. A stepped carbon trading mechanism was introduced to quantify emission costs. For interval uncertainties in renewable generation IGDT-based robust and opportunistic dispatch models were established; for fuzzy load uncertainties FCCP transformed them into deterministic equivalents forming a dual-layer “IGDT-FCCP” uncertainty handling framework. Simulation using CPLEX demonstrated that the proposed model dynamically adjusts uncertainty tolerance and confidence levels effectively balancing economy robustness and low-carbon performance under complex uncertainties: reducing total costs by 12.7% cutting carbon emissions by 28.1% and lowering renewable curtailment to 1.8%. This study provides an advanced decision-making paradigm for low-carbon resilient IES.
Effects of Hydrogen-rich Gas Injection on Combustion Characteristics in Blast Furnace Raceway and Thermal Load of Tuyere: A Numerical Simulation Study
Nov 2025
Publication
Hydrogen-rich gas (HRG) injection is a promising low-carbon solution for blast furnace ironmaking. This study conducted numerical simulations in the lower part of a blast furnace to analyze the combustion behavior of coinjected coke oven gas (COG) and pulverized coal (PC) within the raceway and the associated thermal load on the tuyere. A three-dimensional computational fluid dynamics model incorporating fluid–thermal–solid coupling and the GRI-Mech 3.0 chemical kinetic mechanism (validated for 300–2500 K) was established to simulate the lance–blowpipe–tuyere–raceway region. The simulation results revealed that moderate COG injection accelerated volatile release from PC and enlarged the high-temperature zone (>2000 K). However excessive COG injection intensified oxygen competition and shortened the residence time of PC ultimately decreasing the burnout rate. Notably although COG has high reactivity its injection did not cause an increase in tuyere temperature. By contrast the presence of an unburned gas layer near the upper wall of the tuyere and the existence of a strong convective cooling effect contributed to a reduction in tuyere temperature. An optimized cooling water channel was designed to enhance flow distribution and effectively suppress localized overheating. The findings of this study offer valuable technical insights for ensuring safe COG injection and advancing low-carbon steelmaking practices.
Joint Optimization Scheduling of Electric Vehicles and Electro–Olefin–Hydrogen Electromagnetic Energy Supply Device for Wind–Solar Integration
Nov 2025
Publication
In northern China the long winter heating period is accompanied by severe wind curtailment. To address this issue a joint optimization scheduling strategy of electric vehicles (EVs) and electro–olefin–hydrogen electromagnetic energy supply device (EHED) is proposed to promote deep wind–solar integration. Firstly the feasibility analysis of EVs participating in scheduling is conducted and the operation models of dispatchable EVs and thermal energy storage EHEDs within the scheduling period are established. Secondly a control strategy for the joint optimization scheduling of wind–solar farms EVs EHEDs and power grid is constructed. Then an economic dispatch model for joint optimization of EVs and EHEDs is established to minimize the system operation cost within the scheduling period and the deep wind–solar integration of the joint optimization model is studied by considering EVs under different demand responses. Finally the proposed model is solved by CPLEX solver. The simulation results show that the established joint optimization economic dispatch model of EV-EHEDs can improve the enthusiasm of dispatchable EVs to participate in deep wind–solar integration reduce wind curtailment power and decrease the overall system operation cost.
An Explainable Fault Diagnosis Algorithm for Proton Exchange Membrane Fuel Cells Integrating Gramian Angular Fields and Gradient-Weighted Class Activation Mapping
Nov 2025
Publication
Reliable operation of proton exchange membrane fuel cells (PEMFCs) is crucial for their widespread commercialization and accurate fault diagnosis is the key to ensuring their long-term stable operation. However traditional fault diagnosis methods not only lack sufficient interpretability making it difficult for users to trust their diagnostic decisions but also one-dimensional (1D) feature extraction methods highly rely on manual experience to design and extract features which are easily affected by noise. This paper proposes a new interpretable fault diagnosis algorithm that integrates Gramian angular field (GAF) transform convolutional neural network (CNN) and gradient-weighted class activation mapping (Grad-CAM) for enhanced fault diagnosis and analysis of proton exchange membrane fuel cells. The algorithm is systematically validated using experimental data to classify three critical health states: normal operation membrane drying and hydrogen leakage. The method first converts the 1D sensor signal into a two-dimensional GAF image to capture the temporal dependency and converts the diagnostic problem into an image recognition task. Then the customized CNN architecture extracts hierarchical spatiotemporal features for fault classification while Grad-CAM provides visual explanations by highlighting the most influential regions in the input signal. The results show that the diagnostic accuracy of the proposed model reaches 99.8% which is 4.18% 9.43% and 2.46% higher than other baseline models (SVM LSTM and CNN) respectively. Furthermore the explainability analysis using Grad-CAM effectively mitigates the “black box” problem by generating visual heatmaps that pinpoint the key feature regions the model relies on to distinguish different health states. This validates the model’s decision-making rationality and significantly enhances the transparency and trustworthiness of the diagnostic process.
Evaluation of Heat Transfer Technologies for High Temperature Polymer Electrolyte Membrane Fuel Cells as Primary Power Source in a Regional Aircraft
Oct 2025
Publication
High-temperature proton exchange membrane fuel cells (HT-PEM FCs) represent a promising avenue for generating carbon dioxide-free electricity through the utilization of hydrogen fuel. These systems present numerous advantages and challenges for mobile applications positioning them as pivotal technologies for the realization of emission-free regional aircraft. Efficient thermal management of such fuel cell-powered systems is crucial for ensuring the safe and durable operation of the aircraft while concurrently optimizing system volume mass and minimizing parasitic energy consumption. This paper presents four distinct heat transfer principles tailored for the FC-system of a conceptual hydrogen-electric regional aircraft exemplified by DLR’s H2ELECTRA. The outlined approaches encompass conductive cooling air cooling liquid cooling phase change cooling and also included is the utilization of liquid hydrogen as a heat sink. Approaches are introduced with schematic cooling architectures followed by a comprehensive evaluation of their feasibility within the proposed drivetrain. Essential criteria pertinent to airborne applications are evaluated to ascertain the efficacy of each thermal management strategy. The following criteria are selected for evaluation: safety ease of integration reliability and life-cycle costs technology readiness and development as well as performance which is comprised of heat transfer weight volume and parasitic power consumption. Of the presented cooling methods two emerged to be functionally suitable for the application in MW-scale aircraft applications at their current state of the art: liquid cooling utilizing water under high pressure or other thermal carrier liquids and phase-change cooling. Air cooling and conductive cooling have a high potential due to their reduced system complexity and mass but additional studies investigating effects at architecture level in large-scale fuel cell stacks are needed to increase performance levels. These potentially suitable heat transfer technologies warrant further investigation to assess their potential for complexity and weight reduction in the aircraft drivetrain.
Marine Hydrogen Pressure Reducing Valves: A Review on Multi-Physics Coupling, Flow Dynamics, and Structural Optimization for Ship-Borne Storage Systems
Oct 2025
Publication
As a zero-carbon energy carrier hydrogen is playing an increasingly vital role in the decarbonization of maritime transportation. The hydrogen pressure reducing valve (PRV) is a core component of ship-borne hydrogen storage systems directly influencing the safety efficiency and reliability of hydrogen-powered vessels. However the marine environment— characterized by persistent vibrations salt spray corrosion and temperature fluctuations— poses significant challenges to PRV performance including material degradation flow instability and reduced operational lifespan. This review comprehensively summarizes and analyzes recent advances in the study of high-pressure hydrogen PRVs for marine applications with a focus on transient flow dynamics turbulence and compressible flow characteristics multi-stage throttling strategies and valve core geometric optimization. Through a systematic review of theoretical modeling numerical simulations and experimental studies we identify key bottlenecks such as multi-physics coupling effects under extreme conditions and the lack of marine-adapted validation frameworks. Finally we conducted a preliminary discussion on future research directions covering aspects such as the construction of coupled multi-physics field models the development of marine environment simulation experimental platforms the research on new materials resistant to vibration and corrosion and the establishment of a standardized testing system. This review aims to provide fundamental references and technical development ideas for the research and development of high-performance marine hydrogen pressure reducing valves with the expectation of facilitating the safe and efficient application and promotion of hydrogen-powered shipping technology worldwide.
Evaluating the Role of Hybrid Renewable Energy Systems in Supporting South Africa’s Energy Transition
Oct 2025
Publication
This report evaluates the role of Hybrid Renewable Energy Systems (HRESs) in supporting South Africa’s energy transition amidst persistent power shortages coal dependency and growing decarbonisation imperatives. Drawing on national policy frameworks including the Integrated Resource Plan (IRP 2019) the Just Energy Transition (JET) strategy and Net Zero 2050 targets this study analyses five major HRES configurations: PV–Battery PV–Diesel–Battery PV–Wind–Battery PV–Hydrogen and Multi-Source EMS. Through technical modelling lifecycle cost estimation and trade-off analysis the report demonstrates how hybrid systems can decentralise energy supply improve grid resilience and align with socio-economic development goals. Geographic application cost-performance metrics and policy alignment are assessed to inform region-specific deployment strategies. Despite enabling technologies and proven field performance the scale-up of HRESs is constrained by financial regulatory and institutional barriers. The report concludes with targeted policy recommendations to support inclusive and regionally adaptive HRES investment in South Africa.
Co-Optimization of Capacity and Operation for Battery-Hydrogen Hybrid Energy Storage Systems Based on Deep Reinforcement Learning and Mixed Integer Programming
Oct 2025
Publication
The hybrid energy storage system (HESS) that combines battery with hydrogen storage exploits complementary power/energy characteristics but most studies optimize capacity and operation separately leading to suboptimal overall performance. To address this issue this paper proposes a bi-level co-optimization framework that integrates deep reinforcement learning (DRL) and mixed integer programming (MIP). The outer layer employs the TD3 algorithm for capacity configuration while the inner layer uses the Gurobi solver for optimal operation under constraints. On a standalone PV–wind–load-HESS system the method attains near-optimal quality at dramatically lower runtime. Relative to GA + Gurobi and PSO + Gurobi the cost is lower by 4.67% and 1.31% while requiring only 0.52% and 0.58% of their runtime; compared with a direct Gurobi solve the cost remains comparable while runtime decreases to 0.07%. Sensitivity analysis further validates the model’s robustness under various cost parameters and renewable energy penetration levels. These results indicate that the proposed DRL–MIP cooperation achieves near-optimal solutions with orders of magnitude speedups. This study provides a new DRL–MIP paradigm for efficiently solving strongly coupled bi-level optimization problems in energy systems.
Hydrogen Vehicle Adoption: Perceptions, Barriers, and Global Strategies
Oct 2025
Publication
This paper analyzes the potential of hydrogen technologies in transport placing it within the context of global environmental and energy challenges. Its primary purpose is to eval‑ uate the prospects for the implementation of these technologies at international and na‑ tional levels including Poland. This study utilizes a literature review and an analysis of the results of a highly limited exploratory pilot survey measuring public perception of hydrogen technology in transport. It is critical to note that the survey was conducted on a small non‑representative sample and exhibited a strong geographical bias primarily collecting responses from Europe (50 people) and North America (30 people). This study also details hydrogen vehicle types (FCEV HICE) and the essential infrastructure required (HRS). Despite solid technological foundations the development of hydrogen technology heavily relies on non‑technical factors such as infrastructure development support pol‑ icy and social acceptance. Globally the number of vehicles and stations is growing but remains limited with the pace of development correlating with the involvement of coun‑ tries. The pilot survey revealed a generally positive perception of the technology (mainly due to environmental benefits) but highlighted three key barriers: limited availability of refueling infrastructure—51.5% of respondents strongly agreed on this obstacle high pur‑ chase and maintenance costs and insufficient public awareness. Infrastructure subsidies and tax breaks were identified as effective incentives. Hydrogen technology offers a poten‑ tially competitive and sustainable transport solution but it demands significant systemic support intensive investment in large‑scale infrastructure expansion and comprehensive educational activities. Further governmental engagement is crucial. The severe limitations resulting from the pilot nature of the survey should be rigorously taken into account dur‑ ing interpretation.
Assessment of Regional Hydrogen Refueling Station Layout Planning and Carbon Reduction Benefits Based on Multi-Dimensional Factors of Population, Land, and Demand
Oct 2025
Publication
The urgent global transition toward low-carbon energy systems has highlighted the need for systematic planning of hydrogen refueling stations (HRS) to facilitate clean energy adoption. This study develops an integrated framework for regional HRS layout optimization and carbon emission assessment considering population distribution land area and hydrogen demand. Using Hainan Province as a case study the model estimates regional hydrogen demand determines optimal HRS deployment evaluates spatial coverage and refueling distances and quantifies potential carbon emission reductions under various renewable energy scenarios. Model validation with Haikou demonstrates its reliability and applicability at the regional scale. Results indicate pronounced spatial disparities in hydrogen demand and infrastructure requirements emphasizing that prioritizing station deployment in densely populated urban areas can enhance accessibility and maximize emission reduction. The framework offers a practical data-efficient tool for policymakers and planners to guide early-stage hydrogen infrastructure development and supports strategies for regional decarbonization and sustainable energy transitions.
Methodology for Evaluating and Comparing Different Sustainable Energy Generation and Storage Systems for Residential Buildings—Application to the Case of Spain
Nov 2025
Publication
This paper focuses on assessing different sustainable energy generation and storage systems for residential buildings in Spain identifying the best-performing system according to the end-user requirements. As outlined by the consulted literature the authors have selected two types of hybrid configurations—a Photovoltaic System with Battery Backup (PSBB) and a Photovoltaic System with Hydrogen Hybrid Storage Backup (PSHB)—and a Grid-Based System with Renewable Hydrogen Contribution (GSHC) is proposed. A Fuzzy Analytical Hierarchy Process methodology (FAHP) is employed for evaluating the hybrid power systems from a multi-criteria approach: acquisition operational and environmental. The main requirements for selecting the optimal system are organized under these criteria and evaluated using key performance indicators. This methodology allows the selection of the best option considering objective and subjective system performance indicators. Beyond establishing the ranking a sensitivity analysis was conducted to provide insights into how individual criteria influence the ranking of the hybrid power systems alternatives. The results demonstrate that the selection of hybrid power systems for a residential building is highly dependent on consumer preferences but the PSBB system scores highly in operation and acquisition criteria while the GSHC has good performance in all the criteria.
Deployment of Modular Renewable Energy Sources and Energy Storage Schemes in a Renewable Energy Valley
Nov 2025
Publication
While community energy initiatives and pilot projects have demonstrated technical feasibility and economic benefits their site-specific nature limits transferability to systematic scalable investment models. This study addresses this gap by proposing a modular framework for Renewable Energy Valleys (REVs) developed from real-world Community Energy Lab (CEL) demonstrations in Crete Greece which is an island with pronounced seasonal demand fluctuation strong renewable potential and ongoing hydrogen valley initiatives. Four modular business schemes are defined each representing different sectoral contexts by combining a baseline of 50 residential units with one representative large consumer (hotel rural households with thermal loads municipal swimming pool or hydrogen bus). For each scheme a mixed-integer linear programming model is applied to optimally size and operate integrated solar PV wind battery (BAT) energy storage and hydrogen systems across three renewable energy penetration (REP) targets: 90% 95% and 99.9%. The framework incorporates stochastic demand modeling sector coupling and hierarchical dispatch schemes. Results highlight optimal technology configurations that minimize dependency on external sources and curtailment while enhancing reliability and sustainability under Mediterranean conditions. Results demonstrate significant variation in optimal configurations across sectors and targets with PV capacity ranging from 217 kW to 2840 kW battery storage from 624 kWh to 2822 kWh and hydrogen systems scaling from 65.2 kg to 192 kg storage capacity. The modular design of the framework enables replication beyond the specific context of Crete supporting the scalable development of Renewable Energy Valleys that can adapt to diverse sectoral mixes and regional conditions.
Feasibility and Sensitivity Analysis of an Off-Grid PV/Wind Hybrid Energy System Integrated with Green Hydrogen Production: A Case Study of Algeria
Nov 2025
Publication
Algeria’s transition toward sustainable energy requires the exploitation of its abundant solar and wind resources for green hydrogen production. This study assesses the technoeconomic feasibility of an off-grid PV/wind hybrid system integrated with a hydrogen subsystem (electrolyzer fuel cell and hydrogen storage) to supply both electricity and hydrogen to decentralized sites in Algeria. Using HOMER Pro five representative Algerian regions were analyzed accounting for variations in solar irradiation wind speed and groundwater availability. A deferrable water-extraction and treatment load was incorporated to model the water requirements of the electrolyzer. In addition a comprehensive sensitivity analysis was conducted on solar irradiation wind speed and the capital costs of PV panels and wind turbines to capture the effects of renewable resource and investment cost fluctuations. The results indicate significant regional variation with the levelized cost of energy (LCOE) ranging from 0.514 to 0.868 $/kWh the levelized cost of hydrogen (LCOH) between 8.31 and 12.4 $/kg and the net present cost (NPC) between 10.28 M$ and 17.7 M$ demonstrating that all cost metrics are highly sensitive to these variations.
Benefit Allocation Strategies for Electric–Hydrogen Coupled Virtual Power Plants with Risk–Reward Tradeoffs
Nov 2025
Publication
Driven by carbon neutrality goals electric–hydrogen coupled virtual power plants (EHCVPPs) integrate renewable hydrogen production with power system flexibility resources emerging as a critical technology for large-scale renewable integration. As distributed energy resources (DERs) within EHCVPPs diversify heterogeneous resources generate diversified market values. However inadequate benefit allocation mechanisms risk reducing participation incentives destabilizing cooperation and impairing operational efficiency. To address this benefit allocation must balance fairness and efficiency by incorporating DERs’ regulatory capabilities risk tolerance and revenue contributions. This study proposes a multi-stage benefit allocation framework incorporating risk–reward tradeoffs and an enhanced optimization model to ensure sustainable EHCVPP operations and scalability. The framework elucidates bidirectional risk–reward relationships between DERs and EHCVPPs. An individualized risk-adjusted allocation method and correction mechanism are introduced to address economic-centric inequities while a hierarchical scheme reduces computational complexity from diverse DERs. The results demonstrate that the optimized scheme moderately reduces high-risk participants’ shares increasing operator revenue by 0.69% demand-side gains by 3.56% and reducing generation-side losses by 1.32%. Environmental factors show measurable yet statistically insignificant impacts. The framework meets stakeholders’ satisfaction and minimizes deviation from reference allocations.
A Review on Electric Vehicle Charging Station Planning: Infrastructure Placement, Sizing, Upgrades, and Uncertainties
Nov 2025
Publication
Electric Vehicles (EVs) are rapidly expanding resulting in increased demand on power systems and transportation networks. This study reviews recent advancements in planning EV Charging Stations (EVCSs) focusing on siting sizing grid upgrades and managing uncertainty. Analysis suggests that while many studies optimize either the location or the size of these stations few consider their combined effects resulting in missed opportunities for synergy. A lack of attention to cross-sector integration with hydrogen inadequate treatment of grid reinforcement and fragmented approaches to modeling uncertainties such as EV behavior renewable energy variability and market dynamics is also observed. To address these gaps a synthesis of the interdependencies between siting and sizing is provided along with a review of multi-energy integration opportunities an evaluation of Vehicle-to-Grid technology and smart charging including technical benefits and challenges strategies that link the deployment of EVCS to grid upgrades and a taxonomy of uncertainty sources along with advanced stochastic and data-driven solutions. This review emphasizes the importance of integrated data-informed planning in the development of EV charging infrastructure.
Coordinated Operation Mechanism of Electric-hydrogen-traffic Coupling System that Considers Carbon Emissions and Uncertainties
Nov 2025
Publication
During the critical period of energy transition the collaborative optimization of the electricity-hydrogentransportation coupling system is of vital importance for achieving efficient energy utilization and sustainable development.This paper proposes a collaborative operation mechanism of Distributed Robust Optimization (DRO) considering carbon emissions. Firstly a Stackelberg game dynamic pricing strategy is constructed for the integrated energy station (IES) and the electricity-hydrogen hybrid charging station (HRS) where the upper-level IES optimizes the electricity price setting strategy and the lower-level HRS dynamically adjusts the electricity purchase-hydrogen production plan. Secondly the Wasserstein distance is used to describe the uncertainties of hydrogen vehicle loads and wind-solar power generation and a bisection algorithm-column constraint generation (BA-C&CG) hybrid algorithm is designed to solve the model. Finally the numerical example verification shows that the daily operation cost of HRS under the proposed mechanism is as low as 1108.53 EUR which is 10.58 % and 7.38 % lower than that of the commonly used stochastic optimization (SO) and robust optimization (RO) respectively. The variance analysis (F = 536.05P < 0.001) confirms that the cost advantage is statistically significant. In terms of carbon emission reduction effect the DRO-Stackelberg game model has the lowest daily carbon cost (6.98EUR). This mechanism effectively balances the economic and robustness of the system and the single dispatch calculation time is only 112.09 s meeting the real-time operation requirements of engineering. It provides technical support for the low-carbon collaborative operation of the electricity-hydrogen-transportation coupling system.
Inverse Design and Porous Metal Printing of GDL-integrated Flow Field Plates for High-temperature Hydrogen Fuel Cells
Nov 2025
Publication
High-temperature (HT) proton exchange membrane (PEM) fuel cells (FC) offer key advantages for sustainable transportation especially in heavy-duty applications due to their improved thermal efficiency and water management. This study introduces an inverse design framework to develop flow field plates integrated with a gas diffusion layer (GDL) enabling scalable electrochemical performance from the unit cell to the plate level. A reduced-order homogenization-based multiphysics model is developed to evaluate designs with approximately 1000× faster computation. Flow channel orientation is optimized using a tensor field method and dehomogenized into manufacturable geometries. Optimized designs validated through high-fidelity 3D simulations show up to 12% higher average current density and 88% lower pressure drop compared to conventional parallel and mesh configurations. To address fabrication challenges solid-to-porous metal additive manufacturing is employed producing monolithic structures that integrate flow channels with a porous metal GDL. Both numerical and physical tests confirm high permeability and improved power output compared to carbon-based GDLs. These findings highlight the effectiveness of combining advanced computational modeling with metal 3D printing to enhance the performance and manufacturability of high-temperature PEMFC supporting their broader adoption in sustainable energy applications.
Reliability and Risk Assessment of Hydrogen-Powered Marine Propulsion Systems Based on the Integrated FAHP-FMECA Framework
Nov 2025
Publication
With the IMO’s 2050 decarbonization target hydrogen is a key zero-carbon fuel for shipping but the lack of systematic risk assessment methods for hydrogen-powered marine propulsion systems (under harsh marine conditions) hinders its large-scale application. To address this gap this study proposes an integrated risk evaluation framework by fusing Failure Mode Effects and Criticality Analysis (FMECA) with the Fuzzy Analytic Hierarchy Process (FAHP)—resolving the limitation of traditional single evaluation tools and adapting to the dynamic complexity of marine environments. Scientific findings from this framework confirm that hydrogen leakage high-pressure storage tank valve leakage and inverter overload are the three most critical failure modes with hydrogen leakage being the primary risk source due to its high severity and detection difficulty. Further hazard matrix analysis reveals two key risk mechanisms: one type of failure (e.g. insufficient hydrogen concentration) features “high severity but low detectability” requiring real-time monitoring; the other (e.g. distribution board tripping) shows “high frequency but controllable impact” calling for optimized operations. This classification provides a theoretical basis for precise risk prevention. Targeted improvement measures (e.g. dual-sealed valves redundant cooling circuits AI-based regulation) are proposed and quantitatively validated reducing the system’s overall risk value from 4.8 (moderate risk) to 1.8 (low risk). This study’s core contribution lies in developing a universally applicable scientific framework for marine hydrogen propulsion system risk assessment. It not only fills the methodological gap in traditional evaluations but also provides a theoretical basis for the safe promotion of hydrogen shipping supporting the scientific realization of the IMO’s decarbonization goal.
Techno-economic Feasibility of Centralized and Decentralized Ammonia Production in the United States
Nov 2025
Publication
Ammonia is a cornerstone of modern agriculture supplying the nitrogen essential for crops that nourish nearly half the global population. Yet its production is responsible for ~2 % of global greenhouse gas emissions. To meet climate and food security goals sustainable low-carbon and resilient ammonia production systems are needed. Here we develop a spatially explicit techno-economic model to compare centralized and decentralized ammonia production pathways across the U.S. a major global ammonia producer and consumer spanning the full supply chain from hydrogen production to fertilizer delivery. We integrate high-resolution supply and demand data and apply linear optimization to estimate delivered ammonia costs accounting for geographic mismatches and transportation. Our results show that decentralized ammonia production whether powered by grid electricity or solar energy is substantially more expensive than centralized production from natural gas or coal. Centralized natural gas-based ammonia has a median production cost of 326 USD/tonne NH3 compared to 499 USD/tonne for coal. Decentralized grid-powered systems range from 659 to 1634 USD/tonne and solar-powered systems from 1077 to 2266 USD/tonne. Transportation costs for centralized production range from 7 to 85 USD/tonne with a median of 40 USD/tonne resulting in a delivered cost of 343 USD/tonne. Median delivered costs for decentralized grid- and solar-powered systems are 1069 and 1494 USD/tonne respectively. Decentralized systems require electricity prices below 19 USD/MWh (grid) and 17 USD/MWh (solar) to achieve cost parity well below 2024 U S. averages of 117 USD/MWh. These results highlight the economic challenges facing decentralized ammonia production and the importance of electricity cost reductions tax credits carbon pricing or further technological breakthroughs for broader viability.
Simulation of the Refuelling Process for an LH2-powered Commercial Aircraft Part 1 - Modelling and Validation
Nov 2025
Publication
Liquid hydrogen (LH2) is a promising candidate for zero emission aviation but its cryogenic properties make the refuelling process fundamentally different from that of conventional jet fuels. Although previous studies have addressed LH2 storage and system integration detailed modelling of the refuelling process remains limited. This paper presents the first part of a two-part study focused on simulation of the refuelling process for an LH2-powered commercial aircraft. An existing tank model is substantially modified to more accurately capture relevant physical phenomena including heat transfer and droplet dynamics during top-fill spray injection. Newly available experimental data on LH2 no-vent filling enables direct validation of the model under conditions that match the experimental setup. A sensitivity analysis identifies the most influential parameters that affect model precision including loss coefficient droplet diameter radiative heat ingress and vent-closing pressure. The validated model forms the basis for Part 2 of this study in which it is applied to a representative LH2-powered commercial aircraft to simulate refuelling times quantify venting losses and assess the impact of key operational settings. These results support the design of efficient LH2 refuelling systems for future aircraft and airport infrastructure.
Techno-economic Assessment of Hythane-fueled Industrial SOFC Systems
Nov 2025
Publication
Solid oxide fuel cell (SOFC) systems offer high-efficiency conversion of the chemical energy of fuel gases into electrical energy. To meet market and policy targets such systems must be able of operating on an industrial scale and be compatible with environmentally friendly fuels. This study models the scale-up of a 750 W naturalgas-fueled SOFC to a 240 kW system with various gas-path configurations evaluating the impact of blending up to 30 vol% of hydrogen (H2) into the methane feed. Aspen Plus simulations coupled with pressure-loss and carbon-deposition models were used to optimize recirculation ratio and reactant utilization for maximum efficiency. The parallel configuration achieved the highest electrical efficiency of 64.0 % while series-connected and intermediate systems suffered from increased pressure losses. H2 admixture simulations confirm that operation is feasible without loss of efficiency in the small- and large-scale systems due to reduced carbondeposition potential. A techno-economic analysis indicates a 91.7 % cost reduction through scale-up and a 1.6 % cost increase for adjusting the system to H2 admixtures. The economic viability of the large-scale system was evaluated for all tested fuel compositions (0.201–0.204 €/kWh) with payback times under 20 years at market-relevant electricity prices. These results demonstrate the technical and economic feasibility of large-scale H2-adapted SOFC systems for industrial decarbonization.
Direct Injection Hydrogen Combustion under Leaner Conditions in an Optical Engine using Optical/Laser Diagnostics
Nov 2025
Publication
Hydrogen’s increasing potential as an alternative fuel for heavy-duty transport has led to the conversion of conventional diesel compression-ignition engines to spark-ignition hydrogen operation. Hydrogen’s broad flammability range enables leaner operation achieving both higher engine efficiency and near-zero emissions. In particular direct injection hydrogen combustion improves volumetric efficiency and reduces problems including pre-ignition and knock related to hydrogen port-fuel injection. In the present work we performed an optical investigation of direct injection (DI) hydrogen combustion under leaner mixture conditions. The study was conducted using a heavy-duty optical diesel engine modified for spark-ignition operation. Bottom-view natural flame luminosity and OH-PLIF imaging were conducted along with in-cylinder pressure measurements. Experiments were conducted at three air-excess ratios (3 3.4 and 3.8) with spark timings (ST) varied from − 15 ◦CA aTDC to − 30 ◦CA aTDC. Hydrogen injection ended at − 30 ◦CA aTDC with the start of injection adjusted accordingly to achieve the desired lambda conditions. The maximum IMEPg corresponded to the lowest COV of the IMEPg indicating optimal spark timing for lean DI hydrogen combustion. The optimized spark timing for λ = 3 λ = 3.4 and λ = 3.8 were occurred at − 25 ◦CA aTDC − 25 ◦CA aTDC and − 30 ◦CA aTDC respectively. The corresponding COV of IMEPg values were below 5 % indicating stable combustion. The flame kernel first initiates at the spark plug and then propagates toward the piston’s outer boundary however the flame propagation does not remain as a continuous front unlike port-fuel injected hydrogen combustion. The effect of fuel stratification is evident in combustion luminosity and OH-PLIF images showing pockets of varying intensity within the combustion chamber. Natural flame luminosity images reveal incomplete flame coverage and asymmetric combustion emphasizing the need for metal engine experiments to further quantify the unburned hydrogen and associated combustion losses.
OH* Chemiluminescence in Non-premixed Industrial Natural Gas/hydrogen Flames under Air-fuel and Oxy-fuel Conditions: Kinetic Modeling and Experimental Validation
Oct 2025
Publication
The application of OH* chemiluminescence diagnostics is becoming increasingly prevalent in the combustion characterization of hydrogen. As the current literature is lacking a systematic study of OH* chemiluminescence in non-premixed turbulent natural gas (NG) and hydrogen (H2 ) flames the present work was designed to address this research gap. Therefore extensive experiments were performed on a semi-industrial burner operating at 50–100 kW in NG/H2–Air/O2 combustion modes which were complemented by comprehensive numerical simulations including 1D laminar counterflow diffusion flamelet calculations and full 3D CFD simulations of the semi-industrial furnace setup. In this way an OH* chemistry model is presented that accurately predicts the global reaction zone characteristics and their difference between CH4 and H2 in air-fired and oxygen-fired flames. The comprehensive numerical approach in conjunction with the subsequent study of different operating conditions yielded novel insights into both combustion modeling and the underlying thermochemical phenomena providing an essential contribution to the transition of the thermal energy sector towards hydrogen as an alternative carbon-free fuel.
Towards the Decarbonization of the Maritime Industry: Design of a Novel Methodology for the Sustainable Strategy Assessment
Oct 2025
Publication
The growing concern about the increase in European Union (EU)’s total CO2 emissions due to maritime activities and the ambitious goal of net zero emissions they are asked to fulfil by 2050 are leading the way to the adoption of new sustainable strategies. In this article a novel methodology for the classification of the sustainable actions is proposed. Moreover new indicators have been designed to compare the level of sustainable development of each port. Among them a new coefficient for the assessment of the Ports’ Potential Sustainability (PPS) have been designed. Main results showed that 56% of the actions were in the improvement and environmentally sustainable group while 19% were shift-economic actions related to the installation of technologies. As a matter of the fact all European ports under analysis have adopted cold ironing system which can reduce up to 4% of the global shipping emissions. Similarly 50% of them have already integrated renewables energies and prioritize equipment electrification in their processes. Finally the most relevant projects to optimize the energy consumption of daily operations and the main challenges that still need to be addressed have been analyzed showing the current trends maritime sector is undertaking to advance towards the sustainable development.
Life Cycle and Economic Viability Assessment of Clean Hydrogen as a Fuel in Corn Drying
Oct 2025
Publication
This study presents a comparative life cycle and economic assessment of using clean hydrogen as a sustainable alternative to natural gas and propane for corn grain drying. The study compares the environmental performance limited to GWP100 and cost-effectiveness of hydrogen from various renewable sources (hydro wind solar) and plasma pyrolysis of natural gas against conventional fossil fuels under two delivery scenarios: pipeline and trucking. A life cycle assessment is conducted using Open LCA to quantify the carbon intensity of each fuel from cradle to combustion at multiple energy requirements based on four burner efficiencies across each scenario. In parallel economic analysis is conducted by calculating the fuel cost required per ton of dried corn grains at each efficiency across both scenarios. The results indicate that green hydrogen consistently outperforms current fuels in terms of emissions but it is generally more expensive at lower burner efficiencies and in trucking scenarios. However the cost competitiveness of green hydrogen improves significantly at higher efficiency and with pipeline infrastructure development it can become more economical when compared to propane. Hydrogen produced via plasma pyrolysis offers high environmental and economic costs due to its electricity and natural gas requirements. Sensitivity analysis further explores the impact of a 50% reduction in hydrogen production and transportation costs revealing that hydrogen could become a viable option for grain drying in both pipeline and trucking scenarios. This study highlights the long-term potential of hydrogen in reducing carbon emissions and offers insights into the economic feasibility of hydrogen adoption in agricultural drying processes. The findings suggest that strategic investments in hydrogen infrastructure could significantly enhance the sustainability of agricultural practices paving the way for a greener future in food production.
Hydrogen Strategies Under Uncertainty: Risk-Averse Choices for Green Hydrogen Pathways
Oct 2025
Publication
The last decade has been characterized by a growing environmental awareness and the rise of climate change concerns. Continuous advancement of renewable energy technologies in this context has taken a central stage on the global agenda leading to a diverse array of innovations ranging from cutting-edge green energy production technologies to advanced energy storage solutions. In this evolving context ensuring the sustainability of energy systems—through the reduction of carbon emissions enhancement of energy resilience and responsible resource integration—has become a primary objective of modern energy planning. The integration of hydrogen technologies for power-to-gas (P2G) and power-topower (P2P) and energy storage systems is one of the areas where the most remarkable progress is being made. However real case implementations are lagging behind expectations due to large-scale investments needed which under high energy price uncertainty act as a barrier to widespread adoption. This study proposes a risk-averse approach for sizing an Integrated Hybrid Energy System considering the uncertainty of electricity and gas prices. The problem is formulated as a mixed-integer program and tested on a real-world case study. The analysis sheds light on the value of synergies and innovative solutions that hold the promise of a cleaner more sustainable future for generations to come.
Modeling Hydrogen-Assisted Combustion of Liquid Fuels in Compression-Ignition Engines Using a Double-Wiebe Function
Oct 2025
Publication
This article discusses the potential of using the double-Wiebe function to model combustion in a compression-ignition engine fueled by diesel fuel or its substitutes such as hydrotreated vegetable oil (HVO) and rapeseed methyl ester (RME) and hydrogen injected into the engine intake manifold. The hydrogen amount ranged from 0 to 35% of the total energy content of the fuels burned. It was found that co-combustion of liquid fuel with hydrogen is characterized by two distinct combustion phases: premixed and diffusion combustion. The premixed phase occurring just after ignition is characterized by a rapid combustion rate which increases with an increase in hydrogen injected. The novelty in this work is the modified formula for a double-Wiebe function and the proposed parameters of this function depending on the amount of hydrogen added for co-combustion with liquid fuel. To model this combustion process the modified double-Wiebe function was proposed which can model two phases with different combustion rates. For this purpose a normalized HRR was calculated and based on this curve coefficients for the double-Wiebe function were proposed. Satisfactory consistency with the experiment was achieved at a level determined by the coefficient of determination (R-squared) of above 0.98. It was concluded that the presented double-Wiebe function can be used to model combustion in 0-D and 1-D models for fuels: RME and HVO with hydrogen addition.
Insights from Swirl Number and Ambient Pressure Variations with a Hydrogen/Ammonia Swirl Stabilized Diffusion Flame
Oct 2025
Publication
Contemporary research into decarbonized fuels such as H2/NH3 has highlighted complex challenges with applied combustion with marked changes in thermochemical properties leading to significant issues such as limited operational range flashback and instability particularly when attempts are made to optimize emissions production in conventional lean-premixed systems. Non-premixed configurations may address some of these issues but often lead to elevated NOx production particularly when ammonia is retained in the fuel mixture. Optimized fuel injection and blending strategies are essential to mitigate these challenges. This study investigates the application of a 75 %/25 %mol H2/NH3 blend in a swirl-stabilized combustor operated at elevated conditions of inlet temperature (500 K) and ambient pressure (0.11–0.6 MPa). A complex nonmonotonic relationship between swirl number and increasing ambient combustor pressure is demonstrated highlighting the intricate interplay between swirling flow structures and reaction kinetics which remains poorly understood. At medium swirl (SN = 0.8) an increase in pressure initially reduces NO emissions diminishing past ~0.3 MPa with an opposing trend evident for high swirl (SN = 2.0) as NO emissions fall rapidly when combustor pressure approaches 0.6 MPa. High-fidelity numerical modeling is presented to elucidate these interactions in detail. Numerical data generated using Detached Eddy Simulations (DES) were validated against experimental results to demonstrate a change in flame anchoring on the axial shear layer and marked change in recirculated flow structure successfully capturing the features of higher swirl number flows. Favorable comparisons are made with optical data and a reduction in NO emissions with increasing pressure is demonstrated to replicate changes to the swirling flame chemical kinetics. Findings provide valuable insights into the combustion behavior of hydrogen-rich ammonia flames contributing to the development of cleaner combustion technologies.
Hybrid Renewable Energy Systems for Off-Grid Electrification: A Comprehensive Review of Storage Technologies, Metaheuristic Optimization Approaches and Key Challenges
Nov 2025
Publication
Hybrid Renewable Energy Systems (HRESs) are a practical solution for providing reliable low-carbon electricity to off-grid and remote communities. This review examines the role of energy storage within HRESs by systematically comparing electrochemical mechanical thermal and hydrogen-based technologies in terms of technical performance lifecycle cost operational constraints and environmental impact. We synthesize findings from implemented off-grid projects across multiple countries to evaluate real-world performance metrics including renewable fraction expected energy not supplied (EENS) lifecycle cost and operation & maintenance burdens. Special attention is given to the emerging role of hydrogen as a long-term and cross-sector energy carrier addressing its technical regulatory and financial barriers to widespread deployment. In addition the paper reviews real-world implementations of off-grid HRES in various countries summarizing practical outcomes and lessons for system design and policy. The discussion also includes recent advances in metaheuristic optimization algorithms which have improved planning efficiency system reliability and cost-effectiveness. By combining technological operational and policy perspectives this review identifies current challenges and future directions for developing sustainable resilient and economically viable HRES that can accelerate equitable electrification in remote areas. Finally the review outlines key limitations and future directions calling for more systematic quantitative studies long-term field validation of emerging technologies and the development of intelligent Artificial Intelligence (AI)-driven energy management systems within broader socio-techno-economic frameworks. Overall this work offers concise insights to guide researchers and policymakers in advancing the practical deployment of sustainable and resilient HRES.
Hydrogen Blending as a Transitional Solution for Decarbonizing the Jordanian Electricity Generation Sector
Nov 2025
Publication
While renewable energy deployment has accelerated in recent years fossil fuels continue to play a dominant role in electricity generation worldwide. This necessitates the development of transitional strategies to mitigate greenhouse gas emissions from this sector while gradually reducing reliance on fossil fuels. This study investigates the potential of blending green hydrogen with natural gas as a transitional solution to decarbonize Jordan’s electricity sector. The research presents a comprehensive techno-economic and environmental assessment evaluating the compatibility of the Arab Gas Pipeline and major power plants with hydrogen–natural gas mixtures considering blending limits energy needs environmental impacts and economic feasibility under Jordan’s 2030 energy scenario. The findings reveal that hydrogen blending between 5 and 20 percent can be technically achieved without major infrastructure modifications. The total hydrogen demand is estimated at 24.75 million kilograms per year with a reduction of 152.7 thousand tons of carbon dioxide per annum. This requires 296980 cubic meters of water per year equivalent to only 0.1 percent of the National Water Carrier’s capacity indicating a negligible impact on national water resources. Although technically and environmentally feasible the project remains economically constrained requiring a carbon price of $1835.8 per ton of carbon dioxide for economic neutrality.
Green Hydrogen as a Decarbonization Pathway for Steel Industry in Pakistan
Nov 2025
Publication
The global steel industry emits 1.92 tons of CO2 per ton of output and faces urgent pressure to decarbonize. In Pakistan the sector accounts for 0.29 tons of CO2 per ton of output with limited mitigation frameworks in place. Green hydrogen (GH2)-based steelmaking offers a strategic pathway toward decarbonization. However realizing its potential depends on access to renewable energy. Despite Pakistan’s substantial technical wind potential of 340 GW grid limitations currently restrict wind power to only 4% of national electricity generation. This study explores GH2 production through sector coupling and power wheeling repurposing curtailed wind energy from Sindh to supply Karachi’s steel industry and proposing a phased roadmap for GH enabling fossil fuel substitution industrial resilience and alignment with global carbon-border regulations.
An Effective Integrated Optimal Day-ahead and Real-time Power Scheduling Approach for Hydrogen-based Microgrid
Oct 2025
Publication
The increasing penetration of renewable energy sources in power systems poses significant challenges for maintaining grid reliability mainly due to the variability and uncertainty of solar and demand profiles. Microgrids equipped with diverse storage technologies have emerged as a promising solution to address these issues.This paper proposes an integrated day-ahead and real-time power scheduling approach for grid-connected microgrids equipped with both conventional and hydrogen-based ESSs. While existing strategies often address day-ahead and real-time scheduling separately or rely on a single storage technology this work introduces a unified framework that exploits the complementary characteristics of batteries and hydrogen systems. The proposed approach is based on a novel two-stage stochastic optimization model embedded within a hierarchical optimization framework to address these two intertwined problems efficiently. For the day-ahead scheduling a two-stage stochastic programming energy management model is solved to optimize the microgrid schedule based on forecasted load demand and PV production profiles. Building upon the day-ahead schedule another optimization model is solved which addresses real-time power imbalances caused by deviations in actual PV production and load demand power profiles with respect to the forecasted ones with the aim of minimizing operational disruptions. Simulation results demonstrate the validity of the proposed approach achieving both cost reductions and minimal power imbalances. By dynamically adjusting energy flows and using both conventional batteries and hydrogen systems the proposed approach ensures improved reliability reduced operational costs and enhanced integration of RES in microgrids. These findings highlight the potential of the proposed hierarchical framework to support the large-scale deployment of RES while ensuring resilient and cost-effective microgrid operations.
Blockchain-based Traceability and Certifications of Hydrogen Refueling Station Components
Oct 2025
Publication
As hydrogen gains prominence in energy systems its adoption as an energy source for fuel cell electric vehicles (FCEVs) necessitates the establishment of hydrogen refueling stations (HRS). These stations contain critical compo-nents including nozzles storage tanks heat exchangers and compressors which must be certified by regulatory agen-cies to ensure safety and public trust. Current certification processes are fragmented and manually intensive creating inefficiencies and limiting transparency across the infrastructure lifecycle. In this paper we propose a blockchain-based solution that creates a secure and auditable network for certifying key HRS components. The system integrates an EVM-compatible blockchain decentralized storage and a modular suite of smart contracts (SCs) that formalize registration bidding accreditation certification and governance. Each contract encodes a distinct actor-driven work-flow enabling traceable and role-specific operations. A Decentralized Application (DApp) interface supports real-time and role-based interaction across the ecosystem. We present and evaluate the SCs and their underlying algorithms us-ing gas usage analysis load testing and security auditing. Load testing across the certification lifecycle shows stable transaction throughput and predictable cost profiles under increasing actor activity. A static security analysis con-firms resilience against common vulnerabilities. Our cost analysis indicates that while the framework is technically deployable on public blockchains the execution costs of certain functions make it more cost-effective for private blockchains or Layer 2 networks. We also compare our framework with existing systems to highlight its novelty and technical advantages. Our SCs DApp interface and load testing scripts are publicly available on GitHub.
Uncertainty Ahead: Should Stand-alone Energy Systems Bet on Hydrogen Backup?
Oct 2025
Publication
Achieving net zero by 2050 will require decarbonising stand-alone energy applications. Hydrogen is increasingly viewed as a promising energy carrier but its economic viability remains uncertain due to the lack of consensus on future demand and limited deployment of key components such as fuel cells in stationary stand-alone applications. This study investigates whether hybridising batteries with hydrogen can deliver meaningful cost benefits under future cost trajectories. Using a Monte Carlo framework we simulate 8000 scenarios across constant and seasonal load profiles varying the capital costs of batteries fuel cells electrolysers and hydrogen tanks based on 2025 estimates and 2050 projections. Our results show that hydrogen integration only becomes economically attractive when multiple component costs decline simultaneously. The fuel cell-to-battery power capital cost ratio emerges as the dominant driver of levelised cost of energy (LCOE) improvements. For constant loads median LCOE savings remain below 12 % with more than 5 % savings only achieved when the fuel cell cost is less than 7 times that of the battery. Seasonal nighttime loads offer a wider theoretical LCOE savings range (0–156 %) but substantial gains occur only under unrealistic cost mixes where battery costs remain high and fuel cell costs fall sharply. These findings highlight the sensitivity of hydrogen viability to load profile characteristics and cost interdependencies. They underscore the need for targeted cost reduction strategies particularly for fuel cells to justify added system complexity. These findings are important considerations for future investment and policy decisions.
Life Cycle Assessment of Hydrogen-based Fuels Use in Internal Combustion Engines of Container Ships until 2050
Oct 2025
Publication
Hydrogen-based fuels are potential candidates to help international shipping achieve net-zero greenhouse gas (GHG) emissions by around 2050. This paper quantifies the environmental impacts of liquid hydrogen liquid ammonia and methanol used in a Post-Panamax container ship from 2020 to 2050. It considers cargo capacity changes electricity decarbonization and hydrogen production transitions under two International Energy Agency scenarios: the Stated Policies Scenario (STEPS) and the Net Zero Emissions by 2050 Scenario (NZE). Results show that compared to the existing HFO ship hydrogen-based propulsion systems can decrease cargo weight capacity by 0.3 % to 25 %. In the NZE scenario hydrogen-based fuels can reduce GHG emissions per tonne-nautical mile by 48 %–65 % compared to heavy fuel oil by 2050. Even with fully renewable hydrogenbased fuels 18 %–31 % of GHG emissions would still remain. Using hydrogen-based fuels in internal combustion engines requires attention to minimize environmental trade-offs.
Modeling Electrochemical Impedance Spectroscopy of Hydrogen Complexes During Hydrogen Evolution on Single-stom Electrocatalysts
Nov 2025
Publication
Single Atom Catalysts (SACs) are an emerging frontier in heterogeneous electrocatalysis. They are made of metal atoms atomically dispersed on a matrix. A lot of attention has been dedicated to the study of Hydrogen Evolution Reaction (HER) mechanism due to its relevance in energy conversion technologies both with computational and experimental methods. The classical HER mechanism can be described by a Volmer–Heyrovsky–Tafel mechanism where the two desorption steps are competitive. The Volmer-Heyrovsky mechanism is conventionally proposed for single-atom catalysts. It has been computationally demonstrated that hydrogen complexes can form on SACs due to their analogy with homogeneous catalysts. Unfortunately it is hard to “visualize” these species experimentally. Electrochemical Impedance Spectroscopy (EIS) could be the most promising approach to study electrocatalytic mechanisms. In this work we present microkinetic and Electrochemical Impedance Spectroscopy models for HER on SACs describing Volmer-Heyrovsky and a mechanism mediated by the formation of hydrogen complexes. Our simulated data applied to a case study based on Pd@TiN show that Tafel plots will not suffice in the visualization of hydrogen complexes formation and will need the support of electrochemical impedance spectra in order to clarify the correct mechanism.
The Development of an Analysis Framework for the Integration of Low-carbon Hydrogen into Multi-regional Natural Gas Energy Systems
Nov 2025
Publication
In 2023 global carbon dioxide emissions reached 40 billion tonnes 60 % more than in 1990 intensifying climate concerns. This study explores hydrogen-natural gas blending as a transitional strategy for decarbonization across several regions and energy sectors – residential commercial industrial and agricultural. A multi-regional analysis framework evaluates integration of 20 % by volume low-carbon hydrogen blending into natural gas systems by identifying hydrogen producers importers and exporters based on production and import costs. Applied to Canada 528 scenarios (2026–2050) assess inter-regional hydrogen trade within Canadian provinces. The lowest-cost scenario involves Alberta exporting hydrogen produced through autothermal reforming with 91 % carbon capture and storage and British Columbia producing its own. The grid electrolysis scenario achieves the highest GHG reductions with a 4.5 % GHG mitigation in Canada with full energy system representation. These findings provide insights for policymakers and stakeholders in advancing hydrogen infrastructure and decarbonization strategies.
Techno-economic Analysis of Technologies for Decarbonizing Low- and Medium-Temperature Industrial Heat
Dec 2025
Publication
Decarbonizing industrial heat is critical for achieving climate targets. This study evaluates the economic viability of technologies for decarbonizing industrial heat in Europe through a techno-economic analysis. High-temperature heat pumps (HTHPs) and electric hydrogen and biomass boilers are compared in terms of levelized cost of heat (LCOH) under various scenarios including the impact of thermal storage leveraging dynamic electricity prices. In scenarios for the year 2030 we show that HTHPs leveraging free excess heat achieve LCOH values at least 30% to 60% lower than hydrogen boilers and up to 37% lower than biomass boilers. Integrating daily thermal storage reduces LCOH by up to 15% for heat pumps and 27% for electric boilers. By 2050 anticipated cost and efficiency improvements further enhance the competitiveness of heat pumps. These results highlight the economic advantage of HTHPs particularly when integrating excess heat and thermal storage.
Hydrogen Reduction of Combusted Iron Powder: Role of the Fluidization Regime on the Conversion
Nov 2025
Publication
Fluidized bed systems play a crucial role in industrial processes such as combustion and gasification. In the Iron Power Cycle fluidized bed systems are essential for enabling the reduction of combusted iron back to iron making them a critical component in the regeneration step of the cycle. This study investigates the impact of operating gas velocity on conversion by performing reduction experiments at three distinct fluidization numbers (us/umf): 16 (bubbling regime) 55 (transition region) and 100 (fully turbulent regime). Experiments were conducted to determine the appropriate velocities for each regime ensuring optimal fluidization conditions across reduction temperatures ranging from 500 to 700 ⚬C. The results reveal that conversion rates increase significantly with gas velocities. At 500 ⚬C operating at approximately six times higher velocity leads to a sixfold improvement in conversion when using iron-oxide particles with a Sauter mean diameter of 61 µm. However while enhanced velocities improve reaction efficiency challenges remain at elevated temperatures (T ≥ 500 ⚬C) where iron undergoes defluidization when exposed to hydrogen. Once defluidization occurs refluidization proves impossible with either hydrogen or nitrogen raising concerns about process stability. These insights highlight the potential for optimizing fluidized bed reduction through velocity control while also underscoring the need for additional measures to mitigate unstable fluidization during high-temperature iron oxide reduction.
Techno-economic Assessment of Retrofitted Combined-cycles for Power-to-hydrogen-to-power Systems in European Electricity Markets
Oct 2025
Publication
This paper investigates the performance and economic viability of Combined Cycle Gas Turbines (CCGT) operating on natural gas (NG) and hydrogen within the context of evolving electricity markets. The study is structured into several sections beginning with a benchmark analysis to establish baseline performance metrics including break-even prices and price margins for CCGTs running on NG. The research then explores various base cases and sensitivity analyses focusing on different CCGT capacity factors and the uncertainties surrounding key parameters. The study also compares the performance of CCGTs across different European countries highlighting the impact of increased price fluctuations in forecasted electricity markets. Additionally the paper examines Power-to-X-to-Power (P2X2P) configurations assessing the economic feasibility of hydrogen production and its integration into CCGT operations. The analysis considers scenarios where hydrogen is sourced externally or produced on-site using renewable energy or grid electricity during off-peak hours. The results provide insights into the competitiveness and adaptability of CCGTs in a transitioning energy landscape emphasizing the potential role of hydrogen as a flexible and sustainable energy carrier.
Applied Simulation Study of a Metal Hydride Refrigeration System for Fuel Cell Trucks
Oct 2025
Publication
Refrigeration units in semi-trucks or rigged-body trucks have an energy demand of 8.2–12.4 MWh/y and emit 524.26 kt CO2e/y in Germany. Electrification with fuel cell systems reduces the CO2 emission but an increase of efficiency is necessary because of rapidly increasing hydrogen costs. A metal hydride refrigeration system can increase the efficiency. Even though it was already demonstrated in lab scale with 900 W this power is not sufficient to support a truck refrigeration system and the power output of the lab system was not controllable. Here we show the design and validation of a MATLAB© Simulink model of this metal hydride refrigeration system and its suitability for high power applications with a scaled-up reactor. It was scaled up to rated power of 5 kW and efficiency improvements with an advanced valve switching as well as a controlled cooling pump were implemented. Two application-relevant use cases with hydrogen mass flows from hydrogen fuel cell truck systems were analyzed. The simulation results of these use cases provide an average cooling power of 4.2 and 6.1 kW. Additionally the control of the coolant mass flow at different temperature levels a controlled hydrogen mass flow with a bypass system and an advanced valve switching mechanism increased the system efficiency of the total refrigeration system by 30 % overall.
Energy Management of Hybrid Energy System Considering a Demand-Side Management Strategy and Hydrogen Storage System
Oct 2025
Publication
Nadia Gouda and
Hamed Aly
A hybrid energy system (HES) integrates various energy resources to attain synchronized energy output. However HES faces significant challenges due to rising energy consumption the expenses of using multiple sources increased emissions due to non-renewable energy resources etc. This study aims to develop an energy management strategy for distribution grids (DGs) by incorporating a hydrogen storage system (HSS) and demand-side management strategy (DSM) through the design of a multi-objective optimization technique. The primary focus is on optimizing operational costs and reducing pollution. These are approached as minimization problems while also addressing the challenge of achieving a high penetration of renewable energy resources framed as a maximization problem. The third objective function is introduced through the implementation of the demand-side management strategy aiming to minimize the energy gap between initial demand and consumption. This DSM strategy is designed around consumers with three types of loads: sheddable loads non-sheddable loads and shiftable loads. To establish a bidirectional communication link between the grid and consumers by utilizing a distribution grid operator (DGO). Additionally the uncertain behavior of wind solar and demand is modeled using probability distribution functions: Weibull for wind PDF beta for solar and Gaussian PDF for demand. To tackle this tri-objective optimization problem this work proposes a hybrid approach that combines well-known techniques namely the non-dominated sorting genetic algorithm II and multi-objective particle swarm optimization (Hybrid-NSGA-II-MOPSO). Simulation results demonstrate the effectiveness of the proposed model in optimizing the tri-objective problem while considering various constraints.
Decarbonising Sustainable Aviation Fuel (SAF) Pathways: Emerging Perspectives on Hydrogen Integration
Oct 2025
Publication
The growing demand for air connectivity coupled with the forecasted increase in passengers by 2040 implies an exigency in the aviation sector to adopt sustainable approaches for net zero emission by 2050. Sustainable Aviation Fuel (SAF) is currently the most promising short-term solution; however ensuring its overall sustainability depends on reducing the life cycle carbon footprints. A key challenge prevails in hydrogen usage as a reactant for the approved ASTM routes of SAF. The processing conversion and refinement of feed entailing hydrodeoxygenation (HDO) decarboxylation hydrogenation isomerisation and hydrocracking requires substantial hydrogen input. This hydrogen is sourced either in situ or ex situ with the supply chain encompassing renewables or non-renewables origins. Addressing this hydrogen usage and recognising the emission implications thereof has therefore become a novel research priority. Aside from the preferred adoption of renewable water electrolysis to generate hydrogen other promising pathways encompass hydrothermal gasification biomass gasification (with or without carbon capture) and biomethane with steam methane reforming (with or without carbon capture) owing to the lower greenhouse emissions the convincing status of the technology readiness level and the lower acidification potential. Equally imperative are measures for reducing hydrogen demand in SAF pathways. Strategies involve identifying the appropriate catalyst (monometallic and bimetallic sulphide catalyst) increasing the catalyst life in the deoxygenation process deploying low-cost iso-propanol (hydrogen donor) developing the aerobic fermentation of sugar to 14 dimethyl cyclooctane with the intermediate formation of isoprene and advancing aqueous phase reforming or single-stage hydro processing. Other supportive alternatives include implementing the catalytic and co-pyrolysis of waste oil with solid feedstocks and selecting highly saturated feedstock. Thus future progress demands coordinated innovation and research endeavours to bolster the seamless integration of the cutting-edge hydrogen production processes with the SAF infrastructure. Rigorous technoeconomic and life cycle assessments alongside technological breakthroughs and biomass characterisation are indispensable for ensuring scalability and sustainability
Coordinated Control Strategy for Island Power Generation System with Photovoltaic, Hydrogen-Fueled Gas Turbine and Hybrid Energy Storage
Oct 2025
Publication
Marine and island power systems usually incorporate various forms of energy supply which poses challenges to the coordinated control of the system under diverse irregular and complex load operation modes. To improve the stability and self-sufficiency of island-isolated microgrids with high penetration of renewable energy this study proposes a coordinated control strategy for an island microgrid with PV HGT and HESS combining primary power allocation via low-pass filtering with a fuzzy logic-based secondary correction. The fuzzy controller dynamically adjusts power distribution based on the states of charge of the battery and supercapacitor following a set of predefined rules. A comprehensive system model is developed in Matlab R2023b integrating PV generation an electrolyzer HGT and a battery–supercapacitor HESS. Simulation results across four operational cases demonstrate that the proposed strategy reduces DC bus voltage fluctuations to a maximum of 4.71% (compared to 5.63% without correction) with stability improvements between 0.96% and 1.55%. The HESS avoids overcharging and over-discharging by initiating priority charging at low SOC levels thereby extending service life. This work provides a scalable control framework for enhancing the resilience of marine and island microgrids with high renewable energy penetration.
Analysis of Fuel Cell Electric Vehicle Performance Under Standard Electric Vehicle Driving Protocol
Nov 2025
Publication
The paper studies and analyzes electric vehicle engines powered by hydrogen under the WLTP standard driving protocol. The driving range extension is estimated using a specific protocol developed for FCEV compared with the standard value for battery electric vehicles. The driving range is extended by 10 km averaging over the four protocols with a maximum of 11.6 km for the FTP-75 and a minimum of 7.7 km for the WLTP. This driving range extension represents a 1.8% driving range improvement on average. Applying the FCEV current weight the driving range is extended to 18.9 km and 20.4 km on average when using power source energy capacity standards for BEVs and FCEVs.
Rooftop Agrivoltaic Powered Onsite Hydrogen Production for Insulated Gasochromic Smart Glazing and Hydrogen Vehicles: A Holistic Approach to Sustainable Residential Building
Nov 2025
Publication
The study focused on designing a sustainable building involving rooftop agrivoltaics advanced glazing technologies and onsite hydrogen production for a residential property in Birmingham UK where green hydrogen produced by harnessing electricity generated by agrivoltaics system on rooftop of the building is employed to change the transparency of vacuum gasochromic glazing and refuel hydrogen-powered fuel cell vehicle using storage hydrogen for a sustainable building approach. The change in the transparency of the glazing reduces the energy requirement of the building according to the occupant’s requirement and weather conditions. This research investigates the performance of various rooftop agrivoltaic systems including vertical optimal 30◦ tilt and dome setups for both monofacial and bifacial agrivoltaic consisting of tomato farming. Promising results were observed for agrivoltaic systems with consistent tomato production of 0.31 kg/m2 with varying shading experienced due to the different photovoltaic setups. Maximum electricity is produced by bifacial 30◦ with 7919 kWh though the lowest LCOE can be observed by monofacial 30◦ with £0.061/kWh. It also compares the efficiency of vacuum gasochromic windows against double glazing vacuum double glazing electrochromic and gasochromic options which can play an essential role in energy saving and reduced carbon emission. Vacuum gasochromic demonstrated the lowest U-value of 1.32 Wm2 K though it has the highest thickness with 24.6 mm. Additionally the study examines the feasibility of small-scale green hydrogen production from the electricity generated by agrivoltaics to fuel hydrogen vehicles and glazing considering the economic viability. The results suggested that the hydrogen required by the glazing accounts for 52.56 g annually and the maximum distance that can be covered theoretically is by bifacial 30◦ which is approximately 64.23 km per day. The interdisciplinary approach aims to optimise land use enhance energy efficiency and promote sustainable urban agriculture to contribute to the UK’s goal of increasing solar energy capacity and achieving net-zero emissions while addressing food security concerns. The findings of this study have potential implications for urban planning renewable energy integration especially solar and sustainable residential design.
Interleaved Parallel VDCM Improves Stability Control of Wind Power-hydrogen Coupled Integrated System
Nov 2025
Publication
Aiming at the problems of poor transient characteristics of converter output DC voltage and large DC current ripple caused by alkaline electrolyzer (AEL) switching operation in the wind power-hydrogen coupled integrated system this paper proposes an interleaved parallel VDCM control method to improve the stable operation of the system. Firstly a refined mathematical-physical model of the wind power-hydrogen coupled integrated system including HD-PMSG interleaved parallel buck and AEL is constructed. Then the VDCM control strategy is introduced into the interleaved parallel buck converter which provides reliable inertia and damping support for the output voltage of the hydrogen production system by simulating the DC motor power regulation characteristics and effectively improving the current ripple of the output current. Meanwhile the influence of rotational inertia and the damping coefficient on the dynamic stability of the system in the control strategy is analyzed based on the small signal method. Finally the proposed method is validated through MATLAB/SIMULINK simulation experiments and RCP + HIL hardware-in-the-loop experiments. The results show that the proposed method can improve the dynamic stability of the wind power-hydrogen coupled integrated system effectively.
A Pathway to Decarbonizing Cement Manufacturing via Solar-driven Green Hydrogen Systems
Nov 2025
Publication
The cement industry a foundation of infrastructure development is responsible for nearly 7 % of global CO2 emissions highlighting an urgent need for scalable decarbonization strategies. This study investigates the technoeconomic feasibility of integrating on-site solar-powered green hydrogen production into cement manufacturing processes. A mixed-integer linear programming (MILP) model optimizes the design and operation of solar photovoltaics (PV) proton exchange membrane (PEM) electrolyzer and hydrogen storage for a representative cement plant in Texas. Five hydrogen substitution scenarios (10–30 % of thermal demand) were evaluated based on net present cost (NPC) levelized cost of hydrogen (LCOH) cost of CO2 avoided and greenhouse gas (GHG) emissions reduction. Hydrogen integration up to 30 % is technically viable but economically constrained with LCOH rising non-linearly from $58.7 to $95.3 GJ− 1 due to escalating component costs. Environmentally a 30 % hydrogen share could reduce total U.S. cement sector emissions by 22 %. While significant this confirms at present the solar-driven hydrogen serves as a partial solution rather than a standalone pathway to deep decarbonization suggesting it must complement other strategies like carbon capture electrification and other complementary technologies. The economic viability of this approach is entirely contingent on financial incentives as the investment tax credits of 80 % or higher are essential to enable cost parity with fossil fuels. This work provides a comprehensive techno-economic and environmental framework concluding immense economic barriers and that aggressive policy support is indispensable for enabling the transition to low-carbon cement manufacturing.
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