United Kingdom

We demonstrate a new approach for producing highly dispersed supported metal phosphide powders with small particle size improved stability and increased electrocatalytic activity towards some useful reactions. The approach involves a one-step conversion of metal supported on high surface area carbon to the metal phosphide utilising a very simple and scalable synthetic process. We use this approach to produce PdP₂ and Pd₅P₂ particles dispersed on carbon with a particle size of 4.5–5.5 nm by converting a commercially available Pd/C powder. The metal phosphide catalysts were tested for the oxygen reduction hydrogen oxidation and evolution and formic acid oxidation reactions. Compared to the unconverted Pd/C material we find that alloying the P at different levels shifts oxide formation on the Pd to higher potentials leading to greater stability during cycling studies (20% more ECSA retained 5k cycles) and in thermal treatment under air. Hydrogen absorption within the PdP₂ and Pd₅P₂ particles is enhanced. The phosphides compare favourably to the most active catalysts reported to date for formic acid oxidation especially PdP₂ and there is a significant decrease in poisoning of the surface compared to Pd alone. The mechanistic changes in the reactions studied are rationalised in terms of increased water activation on the surface phosphorus atoms of the catalyst. One of the catalysts PdP₂/C is tested in a fuel cell as anode and cathode catalyst and shows good performance.

Numerical experiments are performed to understand different regimes of hydrogen non-premixed combustion in an enclosure with passive ventilation through one horizontal or vertical vent located at the top of a wall. The Reynolds averaged Navier–Stokes (RANS) computational fluid dynamics (CFD) model with a reduced chemical reaction mechanism is described in detail. The model is based on the renormalization group (RNG) k-ε turbulence model the eddy dissipation concept (EDC) model for simulation of combustion coupled with the 18-step reduced chemical mechanism (8 species) and the in-situ adaptive tabulation (ISAT) algorithm that accelerates the reacting flow calculations by two to three orders of magnitude. The analysis of temperature and species (hydroxyl hydrogen oxygen water) concentrations in time as well as the velocity through the vent shed a light on regimes and dynamics of indoor hydrogen fires. A well-ventilated fire is simulated in the enclosure at a lower release flow rate and complete combustion of hydrogen within the enclosure. Fire becomes under-ventilated at higher release flow rates with two different modes observed. The first mode is the external flame stabilised at the enclosure vent at moderate release rates and the second mode is the self-extinction of combustion inside and outside the enclosure at higher hydrogen release rates. The simulations demonstrated a complex reacting flow dynamics in the enclosure that leads to formation of the external flame or the self-extinction. The air intake into the enclosure at later stages of the process through the whole vent area is a characteristic feature of the self-extinction regime. This air intake is due to faster cooling of hot combustion products by sustained colder hydrogen leak compared to the generation of hot products by the ceasing chemical reactions inside the enclosure and hydrogen supply. In general an increase of hydrogen sustained release flow rate will change fire regime from the well-ventilated combustion within the enclosure through the external flame stabilised at the vent and finally to the self-extinction of combustion throughout the domain.

From an evaluation of the GB housing stock it is clear that a mosaic of low carbon heating technologies will be needed to reach net zero. While heat pumps are an important component of this mix our analysis shows that it is likely to be impractical to heat many GB homes with heat pumps only. A combination of lack of exterior space and/or the thermal properties of the building fabric mean that a heat pump is not capable of meeting the space heating requirement of 8 to 12m homes (or 37% to 54% of the 22.7m homes assessed in this report) or can do so only through the installation of highly disruptive and intrusive measures such as solid wall insulation. Hybrid heat pumps that are designed to optimise efficiency of the system do not have the same requirements of a heat pump and may be a suitable solution for some of these homes. This is likely to mean that decarbonised gas networks are therefore critical to delivery of net zero. 3 to 4m homes1 (or 14% to 18% of homes assessed in our analysis) could be made suitable for heat pump retrofit through energy efficiency measures such as cavity wall insulation. For 7 to 10m homes there are no limiting factors and they require minimal/no upgrade requirements to be made heat pump-ready. Nevertheless given firstly the levels of disruption to the floors and interiors of homes caused by the installation of heat pumps and secondly the cost and disruption associated with the requirement to significantly upgrade the electricity distribution networks to cope with large numbers of heat pumps operating at peak demand times - combined with the availability of a decarbonised gas network which requires a simple like-for-like boiler replacement - is likely to mean that many of these ‘swing’ properties will be better served through a gas based technology such as hydrogen (particularly when consumer choice is factored in) or a hybrid system. A recent trial run in winter 2018-19 by the Energy System Catapult revealed that all participants were reluctant to make expensive investments to improve the energy efficiency of their homes just to enhance the performance of their heat pump. They were more interested in less costly upgrades and tangible benefits such as lower bills or greater comfort. This means that renewable gases including hydrogen as heating fuels are a crucial component of the journey to net zero and the UK’s hydrogen ambitions should be reflective of this. The analysis presented in this paper focuses on the external fabric of the buildings further analysis should be undertaken to consider the internal system changes that would be required for heat pumps and hydrogen boilers for example BEIS Domestic Heat Distribution Systems: Gathering Report from February 2021 which considers the suitability of radiators for the low carbon transition.

The CCUS Advisory Group (CAG) established in March 2019 is an industry-led group considering the critical challenges facing the development of CCUS market frameworks and providing insight into potential solutions. The CAG brings together experts from across the CCUS industry finance and legal sectors.<br/>The CAG has examined a range of business models focusing on industrial CCUS power production CO? transport and storage and hydrogen production. It has considered how the proposed business models interact in order to minimise issues such as cross-chain risk and has considered issues such as delivery capability. The conclusions of the CAG can be found in this report.

Hydrogen presents an opportunity for Africa to not only decarbonise its own energy use and enable clean energy access for all but also to export renewable energy. This paper developed a framework for assessing renewable resources for hydrogen production and provides a new critical analysis as to how and what role hydrogen can play in the complex African energy landscape. The regional solar wind CSP and bio hydrogen potential ranges from 366 to 1311 Gt/year 162 to 1782 Gt/year 463 to 2738 Gt/year and 0.03 to 0.06 Gt/year respectively. The water availability and sensitivity results showed that the water shortages in some countries can be abated by importing water from regions with high renewable water resources. A techno-economic comparative analysis indicated that a high voltage direct current (HVDC) system presents the most cost-effective transportation system with overall costs per kg hydrogen of 0.038 $/kg followed by water pipeline with 0.084 $/kg seawater desalination 0.1 $/kg liquified hydrogen tank truck 0.12 $/kg compressed hydrogen pipeline 0.16 $/kg liquefied ammonia pipeline 0.38 $/kg liquefied ammonia tank truck 0.60 $/kg and compressed hydrogen tank truck with 0.77 $/kg. The results quantified the significance of economies of scale due to cost effectiveness of systems such as compressed hydrogen pipeline and liquefied hydrogen tank truck systems when hydrogen production is scaled up. Decentralization is favorable under some constraints e.g. compressed hydrogen and liquefied ammonia tank truck systems will be more cost effective below 800 km and 1400 km due to lower investment and operation costs.

Renewable energy is a key solution in maintaining global warming below 2 °C. However its intermittency necessitates the need for energy conversion technologies to meet demand when there are insufficient renewable energy resources. This study aims to tackle these challenges by thermo-electrochemical modelling and simulation of a reversible solid oxide fuel cell (RSOFC) and integration with the Haber Bosch process. The novelty of the proposed system is usage of nitrogen-rich fuel electrode exhaust gas for ammonia synthesis during fuel cell mode which is usually combusted to prevent release of highly flammable hydrogen into the environment. RSOFC round-trip efficiencies of 41–53% have been attained when producing excess ammonia (144 kg NH3/hr) for the market and in-house consumption respectively. The designed system has the lowest reported ammonia electricity consumption of 6.4–8.21 kWh/kg NH₃ power-to-hydrogen power-to-ammonia and power-generation efficiencies of 80% 55–71% and 64–66%.

Electrolysis is seen as a promising route for the production of hydrogen from water as part of a move to a wider “hydrogen economy”. The electro-oxidation of renewable feedstocks offers an alternative anode couple to the (high-overpotential) electrochemical oxygen evolution reaction for developing low-voltage electrolysers. Meanwhile the exploration of new membrane materials is also important in order to try and reduce the capital costs of electrolysers. In this work we synthesise and characterise a previously unreported anion-exchange membrane consisting of a fluorinated polymer backbone grafted with imidazole and trimethylammonium units as the ion-conducting moieties. We then investigate the use of this membrane in a lignin-oxidising electrolyser. The new membrane performs comparably to a commercially-available anion-exchange membrane (Fumapem) for this purpose over short timescales (delivering current densities of 4.4 mA cm⁻² for lignin oxidation at a cell potential of 1.2 V at 70 °C during linear sweep voltammetry) but membrane durability was found to be a significant issue over extended testing durations. This work therefore suggests that membranes of the sort described herein might be usefully employed for lignin electrolysis applications if their robustness can be improved.

Hydrogen jet fires from a thermally activated pressure relief device (TPRD) on onboard storage are considered for a vehicle in a naturally ventilated covered car park. Computational Fluid Dynamics was used to predict behaviour of ignited releases from a 70 MPa tank into a naturally ventilated covered car park. Releases through TPRD diameters 3.34 2 and 0.5 mm were studied to understand effect on hazard distances from the vehicle. A vertical release and downward releases at 0° 30° and 45° for TPRD diameters 2 and 0.5 mm were considered accounting for tank blowdown. direction of a downward release was found to significantly contribute to decrease of temperature in a hot cloud under the ceiling. Whilst the ceiling is reached by a jet exceeding 300 °C for a release through a TPRD of 2 mm for inclinations of either 0° 30° or 45° an ignited release through a TPRD of 0.5 mm and angle of 45° did not produce a cloud with a temperature above 300 °C at the ceiling during blowdown. The research findings specifically regarding the extent of the cloud of hot gasses have implications for the design of mechanical ventilation systems.

Natural gas based hydrogen production with carbon capture and storage is referred to as blue hydrogen. If substantial amounts of CO2 from natural gas reforming are captured and permanently stored such hydrogen could be a low-carbon energy carrier. However recent research raises questions about the effective climate impacts of blue hydrogen from a life cycle perspective. Our analysis sheds light on the relevant issues and provides a balanced perspective on the impacts on climate change associated with blue hydrogen. We show that such impacts may indeed vary over large ranges and depend on only a few key parameters: the methane emission rate of the natural gas supply chain the CO2 removal rate at the hydrogen production plant and the global warming metric applied. State-of-the-art reforming with high CO2 capture rates combined with natural gas supply featuring low methane emissions does indeed allow for substantial reduction of greenhouse gas emissions compared to both conventional natural gas reforming and direct combustion of natural gas. Under such conditions blue hydrogen is compatible with low-carbon economies and exhibits climate change impacts at the upper end of the range of those caused by hydrogen production from renewable-based electricity. However neither current blue nor green hydrogen production pathways render fully “net-zero” hydrogen without additional CO2 removal.

In response to the global climate emergency governments across the world are aiming to lower greenhouse gas emissions to slow the damaging effects of climate change.<br/>The Scottish Government has set a target of net zero emissions by 2045. Already a global leader in renewable energy and low-carbon technology deployment Scotland’s energy landscape is set to undergo more change as it moves toward becoming carbon-neutral. Key to that change will be the transition from natural gas to zero-carbon gases like hydrogen and biomethane.<br/>Scotland’s north-east and central belt are home to some of its largest industrial carbon emitters. The sector’s reliance on natural gas means that it emits 11.9Mt of CO2 emissions per year says NECCUS: the equivalent of 2.6 million cars or roughly all the cars in Scotland. Most homes and businesses across Scotland also use natural gas for heating.<br/>Our North-East Network and Industrial Cluster project is laying the foundations for the rapid decarbonisation of this high-emitting sector. We’ve published a report outlining the practical steps needed to rapidly decarbonise a significant part of Scotland’s homes and industry. It demonstrates how hydrogen can play a leading role in delivering the Scottish Government’s target of one million homes with low carbon heat by 2030.<br/>The research published with global consulting and engineering advisor Wood sets out a transformational and accelerated pathway to 100% hydrogen for Scotland’s gas networks which you can see on the map below. It also details the feasibility of a CO2 collection network to securely capture transport and store carbon dioxide emissions deep underground.

In this study a green hydrogen system was studied to provide electricity for an office building in the Sharjah emirate in the United Arab Emirates. Using a solar PV a fuel cell a diesel generator and battery energy storage; a hybrid green hydrogen energy system was compared to a standard hybrid system (Solar PV a diesel generator and battery energy storage). The results show that both systems adequately provided the power needed for the load of the office building. The cost of the energy for both the basic and green hydrogen energy systems was 0.305 USD/kWh and 0.313 USD/kWh respectively. The cost of the energy for both systems is very similar even though the capital cost of the green hydrogen energy system was the highest value; however the replacement and operational costs of the basic system were higher in comparison to the green hydrogen energy system. Moreover the impact of the basic system in terms of the carbon footprint was more significant when compared with the green hydrogen system. The reduction in carbon dioxide was a 4.6 ratio when compared with the basic system.

To achieve the UK’s net zero target vehicles including heavy-duty vehicles (HDVs) will need to be entirely decarbonised. The UK government has announced that it plans to phase out the sale of all new cars and vans with engines between 2030 and 2035. It has also announced its intention to consult on a similar phase-out for diesel-powered heavy-goods vehicles (HGVs). This study analyses policies and technologies which can contribute to the decarbonisation of the UK's inland freight sector.



It comprises an emissions modelling exercise and a cost analysis for total cost of ownership (TCO) of long-haul trucks. The study shows that for urban and regional deliveries battery electric trucks offer the best option to decarbonise. It also shows that battery electric trucks and those using an overhead catenary infrastructure are likely to be the most cost-effective pathway to decarbonise long-haul trucks by 2050 but that renewable hydrogen could also be an option.



​Link to Document Download on Transport & Environment website​​​

Future energy systems could rely on hydrogen (H2) to achieve decarbonisation and net-zero goals. In a similar energy landscape to natural gas H2 emissions occur along the supply chain. It has been studied how current gas infrastructure can support H2 but there is little known about how H2 emissions affect global warming as an indirect greenhouse gas. In this work we have estimated for the first time the potential emission profiles (g CO2eq/MJ H2HHV) of H2 supply chains and found that the emission rates of H2 from H2 supply chains and methane from natural gas supply are comparable but the impact on global warming is much lower based on current estimates. This study also demonstrates the critical importance of establishing mobile H2 emission monitoring and reducing the uncertainty of short-lived H2 climate forcing so as to clearly address H2 emissions for net-zero strategies.

A global transition to hydrogen fuel offers major opportunities to decarbonise a range of different energyintensive sectors from large-scale electricity generation through to heating in homes. Hydrogen can be deployed as an energy source in two distinct ways in electrochemical fuel cells and via combustion. Combustion seems likely to be a major pathway given that it requires only incremental technological change. The use of hydrogen is not however without side-effects and the widely claimed benefit that only water is released as a by-product is only accurate when it is used in fuel cells. The burning of hydrogen can lead to the thermal formation of nitrogen oxides (NOx – the sum of NO + NO2) via a mechanism that also applies to the combustion of fossil fuels. NO2 is a key air pollutant that is harmful in its own right and is a precursor to other pollutants of concern such as fine particulate matter and ozone. Minimising NOx as a by-product from hydrogen boilers and engines is possible through control of combustion conditions but this can lead to reduced power output and performance. After-treatment and removal of NOx is possible but this increases cost and complexity in appliances. Combustion applications therefore require optimisation and potentially lower hydrogen-specific emissions standards if the greatest air quality benefits are to derive from a growth in hydrogen use

One of the most challenging sectors to meet “Net Zero emissions” target by 2050 in the UK is the domestic heating sector. This paper provides a comprehensive literature review of the main challenges of heating systems transition to low carbon technologies in which three distinct categories of challenges are discussed. The first challenge is of decarbonizing heat at the supply side considering specifically the difficulties in integrating hydrogen as a low-carbon heating substitute to the dominant natural gas. The next challenge is of decarbonizing heat at the demand side and research into the difficulties of retrofitting the existing UK housing stock of digitalizing heating energy systems as well as ensuring both retrofits and digitalization do not disproportionately affect vulnerable groups in society. The need for demonstrating innovative solutions to these challenges leads to the final focus which is the challenge of modeling and demonstrating future energy systems heating scenarios. This work concludes with recommendations for the energy research community and policy makers to tackle urgent challenges facing the decarbonization of the UK heating sector.

The clean hydrogen in the prioritized value chain platform could provide energy incentives and reduce environmental impacts. In the current study strengths weaknesses opportunities and threats (SWOT) analysis has been successfully applied to the clean hydrogen value chain in different sectors to determine Japan’s clean hydrogen value chain’s strengths weaknesses opportunities and threats as a case study. Japan was chosen as a case study since we believe that it is the only pioneer country in that chain with a national strategy investments and current projects which make it unique in this way. The analyses include evaluations of clean energy development power supply chains regional energy planning and renewable energy development including the internal and external elements that may influence the growth of the hydrogen economy in Japan. The ability of Japan to produce and use large quantities of clean hydrogen at a price that is competitive with fossil fuels is critical to the country’s future success. The implementation of an efficient carbon tax and carbon pricing is also necessary for cost parity. There will be an increasing demand for global policy coordination and inter-industry cooperation. The results obtained from this research will be a suitable model for other countries to be aware of the strengths weaknesses opportunities and threats in this field in order to make proper decisions according to their infrastructures potentials economies and socio-political states in that field.

Previously suggested options to achieve carbon neutrality involve the use of fossil fuels with carbon capture or exploiting biomass as sources of energy. Industrial high-temperature heating could possibly exploit electrical heating or combustion using hydrogen. However it is difficult to replace all the current coal or natural gas furnaces with these options for chemical industry. In this work a method that integrates solid oxide electrolysis cells (SOEC) and H2–O2 combustion is proposed and the related parameters are modelled to analyze their impacts. There is no waste heat and waste emissions in the proposed option and all substances are recycled. Unlike previous research the heat required for SOEC operation is generated from H2 combustion. The best working condition is under thermoneutral voltage and the highest electricity-to-thermal efficiency that can be achieved is 86.88% under a current density of 12000 A/m2 and operating temperature of 750 ◦C. Ohmic overpotential has the greatest effect on electricity consumption and the anode activation overpotential is the second most important option. Increasing combustion product temperature cannot significantly improve thermal efficiency but can raise the available maximum thermal energy.

Since the UK’s Net Zero greenhouse gas emissions target was set in 2019 organisations across the energy systems community have released pathways on how we might get there – which end-use technologies are deployed across each sector of demand how our fossil fuel-based energy supply would be transferred to low carbon vectors and to what extent society must change the way it demands energy services. This paper presents a comparative analysis between seven published Net Zero pathways for the UK energy system collected from Energy Systems Catapult National Grid ESO Centre for Alternative Technology and the Climate Change Committee. The key findings reported are that (i) pathways that rely on less stringent behavioural changes require more ambitious technology development (and vice versa); (ii) electricity generation will increase by 51-160% to facilitate large-scale fuel-switching in heating and transport the vast majority of which is likely to be generated from variable renewable sources; (iii) hydrogen is an important energy vector in meeting Net Zero for all pathways providing 100-591 TWh annually by 2050 though the growth in demand is heavily dependent on the extent to which it is used in supplying heating and transport demand. This paper also presents a re-visited analysis of the potential renewable electricity generation resource in the UK. It was found that the resource for renewable electricity generation outstrips the UK’s projected 2050 electricity demand by a factor 12-20 depending on the pathway. As made clear in all seven pathways large-scale deployment of flexibility and storage is required to match this abundant resource to our energy demand.

Europe’s low-carbon energy policy favors a greater use of fuel cells and technologies based on hydrogen used as a fuel. Hydrogen delivered at the hydrogen refueling station must be compliant with requirements stated in different standards. Currently the quality control process is performed by offline analysis of the hydrogen fuel. It is however beneficial to continuously monitor at least some of the contaminants onsite using chemical sensors. For hydrogen quality control with regard to contaminants high sensitivity integration parameters and low cost are the most important requirements. In this study we have reviewed the existing sensor technologies to detect contaminants in hydrogen then discussed the implementation of sensors at a hydrogen refueling stations described the state-of-art in protocols to perform assessment of these sensor technologies and finally identified the gaps and needs in these areas. It was clear that sensors are not yet commercially available for all gaseous contaminants mentioned in ISO14687:2019. The development of standardized testing protocols is required to go hand in hand with the development of chemical sensors for this application following a similar approach to the one undertaken for air sensors.

Liquid hydrogen (LH2) has the potential to form part of the UK energy strategy in the future and therefore could see widespread use due to the relatively high energy density when compared to other renewable energy sources. To study the feasibility of this the European Fuel Cells and Hydrogen Joint Undertaking (FCH JU) funded project PRESLHY undertook pre-normative research for the safe use of cryogenic LH2 in non-industrial settings. Several key scenarios were identified as knowledge gaps and both theoretical and experimental studies were conducted to provide insight into these scenarios. This included experiments studying the effect of congestion on an ignited hydrogen plume that develops from a release of LH2; this paper describes the objectives experimental setup and a summary of the results from these activities. Characterisation of the LH2 release hydrogen concentration and temperatures measurements within the resulting gas cloud was undertaken along with pressure measurements both within the cloud and further afield. Various release conditions and congestion levels were studied. Results showed that at high levels of congestion increased overpressures occurred with the higher flow rates studied including one high order event. Data generated from these experiments is being taken forward to generate and validate theoretical models ultimately to contribute to the development of regulations codes and standards (RCS) for LH2."

By considering the weight penalty of batteries on payload and total vehicle weight this paper shows that almost all forms of land-based transport may be served by battery electric vehicles (BEV) with acceptable cost and driving range. Only long-distance road freight is unsuitable for battery electrification. The paper models the future Indian electricity grid supplied entirely by low-carbon forms of generation to quantify the additional solar PV power required to supply energy for transport. Hydrogen produced by water electrolysis for use as a fuel for road freight provides an inter-seasonal energy store that accommodates variations in renewable energy supply. The advantages and disadvantages are considered of midday electric vehicle charging vs. overnight charging considering the temporal variations in supply of renewable energy and demand for transport services. There appears to be little to choose between these two options in terms of total system costs. The result is an energy scenario for decarbonized surface transport in India based on renewable energy that is possible realistically achievable and affordable in a time frame of year 2050.

The turbine-combined free-piston engine generator (TCFPEG) is a hybrid machine generating both mechanical work from the gas turbine and electricity from the linear electric generator for battery charging. In the present study the system performance of the designed TCFPEG system is predicted using a validated numerical model. A parametric analysis is undertaken based on the influence of the engine load valve timing the number of linear generators adopted and different fuels on the system performance. It is found that when linear electric generators are connected with the free-piston gas turbine the bottom dead centre the peak piston velocity and engine operation frequency are all reduced. Very minimal difference on the in-cylinder pressure and the compressor pressure is observed while the peak pressure in the bounce chamber is reduced. When coupled with a linear electric generator the system efficiency can be improved to nearly 50% by optimising engine load and the number of the linear generators adopted in the TCFPEG system. The system is able to be operated with different fuels as the piston is not limited by a mechanical system; the output power and system efficiency are highest when hydrogen is used as the fuel.

IGEM/SR/23 (“Venting of natural gas”) provides recommendations for the conceptual design operation and safety aspects of permanent temporary and emergency venting of natural gas. The document was originally developed many years ago and the current edition dates to 1995. The document is due to be reviewed and updated for application to natural gas but the aim of this study is not to review the applicability of the document for natural gas but to assess the possible impact of 100% hydrogen on specific aspects of the existing guidance.<br/>A key element of the guidance concerns the safe dispersion distances for natural gas as vents are intended to provide a means of safely dispersing gas in the atmosphere without ignition. Guidance on safe dispersion distances for venting are provided in Section 6.6 accompanied by graphs showing the relationship between the mass flow rate through the vent and the safe (horizontal) dispersion distance. Details of the model used to predict the dispersion distances are given in Appendix 1. However for dispersion the guidance in IGEM/SR/23 has been superseded by similar guidance on hazard distances for unignited releases in IGEM/SR/25 (“Hazardous area classification of natural gas installations”) [2]. A comprehensive review of the applicability of IGEM/SR/25 to hydrogen is already underway for the LTS Futures project and is not duplicated here.<br/>However IGEM/SR/23 contains guidance on other important aspects relevant to the safe design and operation of vents which are not addressed elsewhere in the IGEM suite of standards; in particular guidance on hazard ranges for thermal radiation (in the event of an unplanned ignition of the venting gas) and noise.<br/>The main aim of this report is to assess the potential impact of replacing natural gas with 100% hydrogen on the guidance in IGEM/SR/23 concerned with thermal hazards with a secondary objective of assessing the available information to comment on the possible influence of hydrogen on noise.

The H21 National Innovation Competition project is examining the feasibility of repurposing the existing GB natural gas distribution network for transporting 100% hydrogen. It aims to undertake an experimental testing programme that will provide the necessary data to quantify the comparative risk between a 100% hydrogen network and the natural gas network. The first phase of the project focuses on leakage testing of a strategic set of assets that have been removed from service which provide a representative sample of assets across the network. This paper presents the work undertaken for Phase 1A (background testing) where HSE and industry partners have tested a range of natural gas pipework assets of varying size material age and pressure-rating in a new bespoke open-air testing facility at the HSE Science and Research Centre Buxton. The assets have been pressurised with hydrogen and then methane and the leakage rate from the assets measured in both cases. The main finding of this work is that the assets tested which leak hydrogen also leak methane. None of the assets were found to leak hydrogen but not methane. In addition repair techniques that were effective at stopping methane leaks were also effective at stopping hydrogen leaks. The data from the experiments have been interpreted to obtain a range of leakage ratios between the two gases for releases under different conditions. This has been compared to the predicted ratio of hydrogen to methane volumetric leak rates for laminar (1.2:1) and turbulent (2.9:1) releases and good agreement was observed.

Current standard practice at wastewater treatment plants (WWTPs) involves the recycling of digestate liquor produced from the anaerobic digestion of sludge back into the treatment process. However a significant amount of energy is required to enable biological breakdown of ammonia present in the liquor. This biological processing also results in the emission of damaging quantities of greenhouse gases making diversion of liquor and recovery of ammonia a noteworthy option for improving the sustainability of wastewater treatment. This study presents a novel process which combines ammonia recovery from diverted digestate liquor for use (alongside biomethane) in a solid oxide fuel cell (SOFC) system for implementation at WWTPs. Aspen Plus V.8.8 and numerical steady state models have been developed using data from a WWTP in West Yorkshire (UK) as a reference facility (750000p.e.). Aspen Plus simulations demonstrate an ability to recover 82% of ammoniacal nitrogen present in digestate liquor produced at the WWTP. The recovery process uses a series of stripping absorption and flash separation units where water is recovered alongside ammonia. This facilitates effective internal steam methane as a case of study has the potential to make significant impacts energetically and environmentally; findings suggest the treatment facility could transform from a net consumer of electricity to a net producer. The SOFC has been demonstrated to run at an electrical efficiency of 48% with NH3 contributing 4.6% of its power output. It has also been demonstrated that 3.5 kg CO2e per person served by the WWTP could be mitigated a year due to a combination of emissions savings by diversion of ammonia from biological processing and lifecycle emissions associated with the lack of reliance on grid electricity.