Greece
A Simulated Roadmap of Hydrogen Technology Contribution to Climate Change Mitigation Based on Representative Concentration Pathways Considerations
Apr 2018
Publication
Hydrogen as fuel has been a promising technology toward climate change mitigation efforts. To this end in this paper we analyze the contribution of hydrogen technology to our future environmental goals. It is assumed that hydrogen is being produced in higher efficiency across time and this is simulated on Global Change Assessment Model (GCAM). The environmental restrictions applied are the expected emissions representative concentration pathways (RCP) 2.6 4.5 and 6.0. Our results have shown increasing hydrogen production as the environmental constraints become stricter and hydrogen more efficient in being produced. This increase has been quantified and provided on open access as Supporting Information to this manuscript.
The Interaction between Short- and Long-Term Energy Storage in an nZEB Office Building
Mar 2024
Publication
The establishment of near-autonomous micro-grids in commercial or public building complexes is gaining increasing popularity. Short-term storage capacity is provided by means of large battery installations or more often by the employees’ increasing use of electric vehicle batteries which are allowed to operate in bi-directional charging mode. In addition to the above short-term storage means a long-term storage medium is considered essential to the optimal operation of the building’s micro-grid. The most promising long-term energy storage carrier is hydrogen which is produced by standard electrolyzer units by exploiting the surplus electricity produced by photovoltaic installation due to the seasonal or weekly variation in a building’s electricity consumption. To this end a novel concept is studied in this paper. The details of the proposed concept are described in the context of a nearly Zero Energy Building (nZEB) and the associated micro-grid. The hydrogen produced is stored in a high-pressure tank to be used occasionally as fuel in an advanced technology hydrogen spark ignition engine which moves a synchronous generator. A size optimization study is carried out to determine the genset’s rating the electrolyzer units’ capacity and the tilt angle of the rooftop’s photovoltaic panels which minimize the building’s interaction with the external grid. The hydrogen-fueled genset engine is optimally sized to 40 kW (0.18 kW/kWp PV). The optimal tilt angle of the rooftop PV panels is 39◦ . The maximum capacity of the electrolyzer units is optimized to 72 kW (0.33 kWmax/kWp PV). The resulting system is tacitly assumed to integrate to an external hydrogen network to make up for the expected mismatches between hydrogen production and consumption. The significance of technology in addressing the current challenges in the field of energy storage and micro-grid optimization is discussed with an emphasis on its potential benefits. Moreover areas for further research are highlighted aiming to further advance sustainable energy solutions.
Energy-Economic Assessment of Islanded Microgrid with Wind Turbine, Photovoltaic Field, Wood Gasifier, Battery, and Hydrogen Energy Storage
Sep 2022
Publication
Island energy systems are becoming an important part of energy transformation due to the growing needs for the penetration of renewable energy. Among the possible systems a combination of different energy generation technologies is a viable option for local users as long as energy storage is implemented. The presented paper describes an energy-economic assessment of an island system with a photovoltaic field small wind turbine wood chip gasifier battery and hydrogen circuit with electrolyzer and fuel cell. The system is designed to satisfy the electrical energy demand of a tourist facility in two European localizations. The operation of the system is developed and dynamically simulated in the Transient System Simulation (TRNSYS) environment taking into account realistic user demand. The results show that in Gdansk Poland it is possible to satisfy 99% of user demand with renewable energy sources with excess energy equal to 31% while in Agkistro Greece a similar result is possible with 43% of excess energy. Despite the high initial costs it is possible to obtain Simple Pay Back periods of 12.5 and 22.5 years for Gdansk and Agkistro respectively. This result points out that under a high share of renewables in the energy demand of the user the profitability of the system is highly affected by the local cost of energy vectors. The achieved results show that the system is robust in providing energy to the users and that future development may lead to an operation based fully on renewables.
Techno-economic Evaluation of Medium Scale Power to Hydrogen to Combined Heat and Power Generation Systems
Jun 2022
Publication
The European Hydrogen Strategy and the new « Fit for 55 » package indicate the urgent need for the alignment of policy with the European Green Deal and European Union (EU) climate law for the decarbonization of the energy system and the use of hydrogen towards 2030 and 2050. The increasing carbon prices in EU Emission Trading System (ETS) as well as the lack of dispatchable thermal power generation as part of the Coal exit are expected to enhance the role of Combined Heat and Power (CHP) in the future energy system. In the present work the use of renewable hydrogen for the decarbonization of CHP plants is investigated for various fossil fuel substitution ratios and the impact of the overall efficiency the reduction of direct emissions and the carbon footprint of heat and power generation are reported. The analysis provides insights on efficient and decarbonized cogeneration linking the power with the heat sector via renewable hydrogen production and use. The levelized cost of hydrogen production as well as the levelized cost of electricity in the power to hydrogen to combined heat and power system are analyzed for various natural gas substitution scenarios as well as current and future projections of EU ETS carbon prices.
Techno-Economic Analysis of a Hydrogen-Based Power Supply Backup System for Tertiary Sector Buildings: A Case Study in Greece
May 2023
Publication
In view of the European Union’s strategy on hydrogen for decarbonization and buildings’ decarbonization targets the use of hydrogen in buildings is expected in the future. Backup power in buildings is usually provided with diesel generators (DGs). In this study the use of a hydrogen fuel cell (HFC) power supply backup system is studied. Its operation is compared to a DG and a techno-economic analysis of the latter’s replacement with an HFC is conducted by calculating relevant key performance indicators (KPIs). The developed approach is presented in a case study on a school building in Greece. Based on the school’s electricity loads which are calculated with a dynamic energy simulation and power shortages scenarios the backup system’s characteristics are defined and the relevant KPIs are calculated. It was found that the HFC system can reduce the annual CO2 emissions by up to 400 kg and has a lower annual operation cost than a DG. However due to its high investment cost its levelized cost of electricity is higher and the replacement of an existing DG is unviable in the current market situation. The techno-economic study reveals that subsidies of around 58–89% are required to foster the deployment of HFC backup systems in buildings.
A Priority-based Failure Mode and Effects Analysis (FMEA) Method for Risk Assessment of Hydrogen Applications Onboard Maritime Vessels
Sep 2023
Publication
The maritime industry is gaining momentum towards a more decarbonized and sustainable path. However most of the worldwide fleet still relies on fossil fuels for power producing harmful environmental emissions. Hydrogen as a clean fuel is a promising alternative but its unique properties pose significant safety challenges. For instance hydrogen has a wide flammability range inherently increasing the risk of ignition. Moreover its comparatively low volumetric energy density necessitates faster filling rates and larger volumes for bunkering and onboard storage leading to higher risk rates. Therefore the use of hydrogen for maritime applications requires the development of specialized riskbased approaches according to safety engineering principles and techniques. The key safety implications are discussed and reviewed with focus on onboard hydrogen storage handling and refueling while a priority-based Failure Mode and Effects Analysis (FMEA) method for risk assessment is proposed based on the revised guidelines of Automotive Industry Action Group (AIAG) and German Association of the Automotive Industry (VDA). The revised AIAG-VDA FMEA method replaces the conventional Risk Priority Number (RPN) with a new Action Priority (AP) rating enabling the prioritization of recommended actions for risk reduction. The paper aims to a more profound understanding of the safety risks associated with hydrogen as a maritime fuel and to provide an effective risk assessment method for hydrogen applications onboard maritime vessels.
Outlook and Challenges for Hydrogen Storage in Nanoporous Materials
Feb 2016
Publication
Darren P. Broom,
Colin Webb,
Katherine Hurst,
P. A. Parilla,
Thomas Gennett,
C. M. Brown,
Renju Zacharia,
E. Tylianakis,
E. Klontzas,
George E. Froudakis,
Th. A. Steriotis,
Pantelis N. Trikalitis,
Donald L. Anton,
B. Hardy,
David A. Tamburello,
Claudio Corgnale,
B. A. van Hassel,
D. Cossement,
Richard Chahine and
Michael Hirscher
Considerable progress has been made recently in the use of nanoporous materials for hydrogen storage. In this article the current status of the field and future challenges are discussed ranging from important open fundamental questions such as the density and volume of the adsorbed phase and its relationship to overall storage capacity to the development of new functional materials and complete storage system design. With regard to fundamentals the use of neutron scattering to study adsorbed H2 suitable adsorption isotherm equations and the accurate computational modelling and simulation of H2 adsorption are discussed. The new materials covered include flexible metal–organic frameworks core–shell materials and porous organic cage compounds. The article concludes with a discussion of the experimental investigation of real adsorptive hydrogen storage tanks the improvement in the thermal conductivity of storage beds and new storage system concepts and designs.
Is Greece Ready for a Hydrogen Energy Transition?—Quantifying Relative Costs in Hard to Abate Industries
Apr 2024
Publication
During the past few years hydrogen use has come to be considered as an alternative energy carrier in a future decarbonized world. Many developed nations are undergoing a shift towards low-carbon energy sources driven by the excessive reliance on fossil fuels and the detrimental effects of climate change. This study aims to investigate the potential for hydrogen deployment in the Greek energy market during the next few decades. In this context green hydrogen’s potential application in the Greek market is being assessed employing an integrated techno-economic model grounded in worldwide trends and localized expenses. The forthcoming years will see an analysis of both the challenges and opportunities surrounding the integration and implementation of hydrogen in new and existing processes within Greece. Many alternative ways to produce hydrogen in Greece are investigated contemplating different production paths. We evaluate how fluctuations in hydrogen oil and carbon prices affect the economics of green hydrogen adoption in oil refining as is detailed in the draft of the European Union delegated act published in May 2022. The Levelized Cost of Hydrogen (LCOH) for different scenarios is calculated for the time frame up until 2050. A sensitivity analysis reveals that investment costs electricity prices electrolyzer efficiency and carbon taxes significantly influence the LCOH ultimately impacting the economic competitiveness of hydrogen production. These findings underscore the importance of aligning public–private partnership agendas in hydrogen production to create optimal conditions for investment attraction and development.
Integration of Different Storage Technologies towards Sustainable Development—A Case Study in a Greek Island
Mar 2024
Publication
The necessity for transitioning to renewable energy sources and the intermittent nature of the natural variables lead to the integration of storage units into these projects. In this research paper wind turbines and solar modules are combined with pumped hydro storage batteries and green hydrogen. Energy management strategies are described for five different scenarios of hybrid renewable energy systems based on single or hybrid storage technologies. The motivation is driven by grid stability issues and the limited access to fresh water in the Greek islands. A RES-based desalination unit is introduced into the hybrid system for access to low-cost fresh water. The comparison of single and hybrid storage methods the exploitation of seawater for the simultaneous fulfillment of water for domestic and agricultural purposes and the evaluation of different energy economic and environmental indices are the innovative aspects of this research work. The results show that pumped hydro storage systems can cover the energy and water demand at the minimum possible price 0.215 EUR/kWh and 1.257 EUR/m3 while hybrid storage technologies provide better results in the loss of load probability payback period and CO2 emissions. For the pumped hydro– hydrogen hybrid storage system these values are 21.40% 10.87 years and 2297 tn/year respectively.
Establishment of Austria’s First Regional Green Hydrogen Economy: WIVA P&G HyWest
Apr 2023
Publication
The regional parliament of Tyrol in Austria adopted the climate energy and resources strategy “Tyrol 2050 energy autonomous” in 2014 with the aim to become climate neutral and energy autonomous. “Use of own resources before others do or have to do” is the main principle within this long-term strategic approach in which the “power on demand” process is a main building block and the “power-to-hydrogen” process covers the intrinsic lack of a long-term large-scale storage of electricity. Within this long-term strategy the national research and development (R&D) flagship project WIVA P&G HyWest (ongoing since 2018) aims at the establishment of the first sustainable business-case-driven regional green hydrogen economy in central Europe. This project is mainly based on the logistic principle and is a result of synergies between three ongoing complementary implementation projects. Among these three projects to date the industrial research within “MPREIS Hydrogen” resulted in the first green hydrogen economy. One hydrogen truck is operational as of January 2023 in the region of Tyrol for food distribution and related monitoring studies have been initiated. To fulfil the logistic principle as the main outcome another two complementary projects are currently being further implemented.
The Role of Hydrogen and H2 Mobility on the Green Transition of Islands: The Case of Anafi (Greece)
Apr 2023
Publication
The holistic green energy transition of non-interconnected islands faces several challenges if all the energy sectors are included i.e. electricity heating/cooling and mobility. On the one hand the penetration of renewable energy systems (RES) is limited due to design restrictions with respect to the peak demand. On the other hand energy-intensive heating and mobility sectors pose significant challenges and may be difficult to electrify. The focus of this study is on implementing a hybrid Wind–PV system on the non-interconnected island of Anafi (Greece) that utilizes surplus renewable energy production for both building heating through heat pumps and hydrogen generation. This comprehensive study aims to achieve a holistic green transition by addressing all three main sectors—electricity heating and transportation. The produced hydrogen is utilized to address the energy needs of the mobility sector (H2 mobility) focusing primarily on public transportation vehicles (buses) and secondarily on private vehicles. The overall RES production was modeled to be 91724 MWh with a RES penetration of 84.68%. More than 40% of the produced electricity from RES was in the form of excess electricity that could be utilized for hydrogen generation. The modeled generated hydrogen was simulated to be more than 40 kg H2/day which could cover all four bus routes of the island and approximately 200 cars for moderate use i.e. traveled distances of less than 25 km/day for each vehicle.
Decarbonization of Former Lignite Regions with Renewable Hydrogen: The Western Macedonia Case
Oct 2023
Publication
For lignite intense regions such as the case of Western Macedonia (WM) the production and utilization of green hydrogen is one of the most viable ways to achieve near zero emissions in sectors like transport chemicals heat and energy production synthetic fuels etc. However the implementation of each technology that is available to a respective sector differs significantly in terms of readiness and the current installation scale of each technology. The goal of this study is the provision of a transition roadmap for a decarbonized future for the WM region through utilizing green hydrogen. The technologies which can take part in this transition are presented along with the implementation purpose of each technology and the reasonable extension that each technology could be adopted in the present context. The WM region’s limited capacity for green hydrogen production leads to certain integration scenarios with regards to the required hydrogen electrolyzer capacities and required power whereas an environmental assessment is also presented for each scenario.
Computational Analysis of Liquid Hydrogen Storage Tanks for Aircraft Applications
Mar 2023
Publication
During the last two decades the use of hydrogen (H2 ) as fuel for aircraft applications has been drawing attention; more specifically its storage in liquid state (LH2 ) which is performed in extreme cryogenic temperatures (−253 ◦C) is a matter of research. The motivation for this effort is enhanced by the predicted growth of the aviation sector; however it is estimated that this growth could be sustainable only if the strategies and objectives set by global organizations for the elimination of greenhouse gas emissions during the next decades such as the European Green Deal are taken into consideration and consequently technologies such as hydrogen fuel are promoted. Regarding LH2 in aircraft substantial effort is required to design analyze and manufacture suitable tanks for efficient storage. Important tools in this process are computational methods provided by advanced engineering software (CAD/CAE). In the present work a computational study with the finite element method is performed in order to parametrically analyze proper tanks examining the effect of the LH2 level stored as well as the tank geometric configuration. In the process the need for powerful numerical models is demonstrated owing to the highly non-linear dependence on temperature of the involved materials. The present numerical models’ efficiency could be further enhanced by integrating them as part of a total aircraft configuration design loop.
Sustainable Power Generation Expansion in Island Systems with Extensive RES and Energy Storage
Oct 2023
Publication
Insular networks constitute ideal fields for investment in renewables and storage due to their excellent wind and solar potential as well the high generation cost of thermal generators in such networks. Nevertheless in order to ensure the stability of insular networks network operators impose strict restrictions on the expansion of renewables. Storage systems render ideal solutions for overcoming the aforementioned restrictions unlocking additional renewable capacity. Among storage technologies hybrid battery-hydrogen demonstrates beneficial characteristics thanks to the complementary features that battery and hydrogen exhibit regarding efficiency self-discharge cost etc. This paper investigates the economic feasibility of a private investment in renewables and hybrid hydrogen-battery storage realized on the interconnected island of Crete Greece. Specifically an optimization formulation is proposed to optimize the capacity of renewables and hybrid batteryhydrogen storage in order to maximize the profit of investment while simultaneously reaching a minimum renewable penetration of 80% in accordance with Greek decarbonization goals. The numerical results presented in this study demonstrate that hybrid hydrogen-battery storage can significantly reduce electricity production costs in Crete potentially reaching as low as 64 EUR/MWh. From an investor’s perspective even with moderate compensation tariffs the energy transition remains profitable due to Crete’s abundant wind and solar resources. For instance with a 40% subsidy and an 80 EUR/MWh compensation tariff the net present value can reach EUR 400 million. Furthermore the projected cost reductions for electrolyzers and fuel cells by 2030 are expected to enhance the profitability of hybrid renewable-battery-hydrogen projects. In summary this research underscores the sustainable and economically favorable prospects of hybrid hydrogen-battery storage systems in facilitating Crete’s energy transition with promising implications for investors and the wider renewable energy sector.
Hydrogen Role in the Valorization of Integrated Steelworks Process Off-gases through Methane and Methanol Syntheses
Jun 2021
Publication
The valorization of integrated steelworks process off-gases as feedstock for synthesizing methane and methanol is in line with European Green Deal challenges. However this target can be generally achieved only through process off-gases enrichment with hydrogen and use of cutting-edge syntheses reactors coupled to advanced control systems. These aspects are addressed in the RFCS project i3 upgrade and the central role of hydrogen was evident from the first stages of the project. First stationary scenario analyses showed that the required hydrogen amount is significant and existing renewable hydrogen production technologies are not ready to satisfy the demand in an economic perspective. The poor availability of low-cost green hydrogen as one of the main barriers for producing methane and methanol from process off-gases is further highlighted in the application of an ad-hoc developed dispatch controller for managing hydrogen intensified syntheses in integrated steelworks. The dispatch controller considers both economic and environmental impacts in the cost function and although significant environmental benefits are obtainable by exploiting process off-gases in the syntheses the current hydrogen costs highly affect the dispatch controller decisions. This underlines the need for big scale green hydrogen production processes and dedicated green markets for hydrogen-intensive industries which would ensure easy access to this fundamental gas paving the way for a C-lean and more sustainable steel production.
Integration of Renewable Hydrogen Production in Steelworks Off-Gases for the Synthesis of Methanol and Methane
May 2021
Publication
The steel industry is among the highest carbon-emitting industrial sectors. Since the steel production process is already exhaustively optimized alternative routes are sought in order to increase carbon efficiency and reduce these emissions. During steel production three main carbon-containing off-gases are generated: blast furnace gas coke oven gas and basic oxygen furnace gas. In the present work the addition of renewable hydrogen by electrolysis to those steelworks off-gases is studied for the production of methane and methanol. Different case scenarios are investigated using AspenPlusTM flowsheet simulations which differ on the end-product the feedstock flowrates and on the production of power. Each case study is evaluated in terms of hydrogen and electrolysis requirements carbon conversion hydrogen consumption and product yields. The findings of this study showed that the electrolysis requirements surpass the energy content of the steelwork’s feedstock. However for the methanol synthesis cases substantial improvements can be achieved if recycling a significant amount of the residual hydrogen.
A Multicriteria Modeling Approach for Evaluating Power Generation Scenarios Under Uncertainty: The Case of Green Hydrogen in Greece
Oct 2023
Publication
Clean energy technological innovations are widely acknowledged as a prerequisite to achieving ambitious longterm energy and climate targets. However the optimal speed of their adoption has been parsimoniously studied in the literature. This study seeks to identify the optimal intensity of moving to a green hydrogen electricity sector in Greece using the OSeMOSYS energy modeling framework. Green hydrogen policies are evaluated first on the basis of their robustness against uncertainty and afterwards against conflicting performance criteria and for different decision-making profiles towards risk by applying the VIKOR and TOPSIS multi-criteria decision aid methods. Although our analysis focuses exclusively on the power sector and compares different rates of hydrogen penetration compared to a business-as-usual case without considering other game-changing innovations (such as other types of storage or carbon capture and storage) we find that a national transition to a green hydrogen economy can support Greece in potentially cutting at least 16 MtCO2 while stimulating investments of EUR 10–13 bn. over 2030–2050.
Literature Review of Hydrogen Energy Systems and Renewable Energy Sources
Nov 2023
Publication
The role of hydrogen as a clean energy source is a promising but also a contentious issue. The global energy production is currently characterized by an unprecedented shift to renewable energy sources (RES) and their technologies. However the local and environmental benefits of such RES-based technologies show a wide variety of technological maturity with a common mismatch to local RES stocks and actual utilization levels of RES exploitation. In this literature review the collected documents taken from the Scopus database using relevant keywords have been organized in homogeneous clusters and are accompanied by the registration of the relevant studies in the form of one figure and one table. In the second part of this review selected representations of typical hydrogen energy system (HES) installations in realistic in-field applications have been developed. Finally the main concerns challenges and future prospects of HES against a multi-parametric level of contributing determinants have been critically approached and creatively discussed. In addition key aspects and considerations of the HES-RES convergence are concluded.
Recent Advances in Sustainable Hydrogen Production from Microalgae: Mechanisms, Challenges, and Future Perspectives
Jan 2024
Publication
The depletion of fossil fuel reserves has resulted from their application in the industrial and energy sectors. As a result substantial efforts have been dedicated to fostering the shift from fossil fuels to renewable energy sources via technological advancements in industrial processes. Microalgae can be used to produce biofuels such as biodiesel hydrogen and bioethanol. Microalgae are particularly suitable for hydrogen production due to their rapid growth rate ability to thrive in diverse habitats ability to resolve conflicts between fuel and food pro duction and capacity to capture and utilize atmospheric carbon dioxide. Therefore microalgae-based bio hydrogen production has attracted significant attention as a clean and sustainable fuel to achieve carbon neutrality and sustainability in nature. To this end the review paper emphasizes recent information related to microalgae-based biohydrogen production mechanisms of sustainable hydrogen production factors affecting biohydrogen production by microalgae bioreactor design and hydrogen production advanced strategies to improve efficiency of biohydrogen production by microalgae along with bottlenecks and perspectives to over come the challenges. This review aims to collate advances and new knowledge emerged in recent years for microalgae-based biohydrogen production and promote the adoption of biohydrogen as an alternative to con ventional hydrocarbon biofuels thereby expediting the carbon neutrality target that is most advantageous to the environment.
Hydrogen Production from Wave Power Farms to Refuel Hydrogen-Powered Ships in the Mediterranean Sea
Aug 2024
Publication
The maritime industry is a major source of greenhouse gas (GHG) emissions largely due to ships running on fossil fuels. Transitioning to hydrogen-powered marine transportation in the Mediterranean Sea requires the development of a network of hydrogen refueling stations across the region to ensure a steady supply of green hydrogen. This paper explores the technoeconomic viability of harnessing wave energy from the Mediterranean Sea to produce green hydrogen for hydrogenpowered ships. Four promising island locations—near Sardegna Galite Western Crete and Eastern Crete—were selected based on their favorable wave potential for green hydrogen production. A thorough analysis of the costs associated with wave power facilities and hydrogen production was conducted to accurately model economic viability. The techno-economic results suggest that with anticipated cost reductions in wave energy converters the levelized cost of hydrogen could decrease to as low as 3.6 €/kg 4.3 €/kg 5.5 €/kg and 3.9 €/kg for Sardegna Galite Western Crete and Eastern Crete respectively. Furthermore the study estimates that in order for the hydrogen-fueled ships to compete effectively with their oil-fueled counterparts the levelized cost of hydrogen must drop below 3.5 €/kg. Thus despite the competitive costs further measures are necessary to make hydrogen-fueled ships a viable alternative to conventional diesel-fueled ships.
The UAE Net-Zero Strategy—Aspirations, Achievements and Lessons for the MENA Region
Aug 2025
Publication
The Middle East and North Africa region has not played a major role in climate action so far and several countries depend economically on fossil fuel exports. However this is a region with vast solar energy resources which can be exploited affordably for power generation and hydrogen production at scale to eventually reach carbon neutrality. In this paper we elaborate on the case of the United Arab Emirates and explore the aspirations and feasibility of its net-zero by 2050 target. While we affirm the concept per se we also highlight the technological complexity and economic dimensions that accompany such transformation. We expect the UAE’s electricity demand to triple between today and 2050 and the annual green hydrogen production is expected to reach 3.5 Mt accounting for over 40% of the electricity consumption. Green hydrogen will provide power-to-fuel solutions for aviation maritime transport and hard-to-abate industries. At the same time electrification will intensify—most importantly in road transport and low-temperature heat demands. The UAE can meet its future electricity demands primarily with solar power followed by natural gas power plants with carbon capture utilization and storage while the role of nuclear power in the long term is unclear at this stage.
Towards Sustainable Energy Independence: A Case Study of Green Hydrogen as Seasonal Storage Integration in a Small Island
Mar 2025
Publication
Tilos a Greek island in the Mediterranean Sea hosts a pioneering hybrid energy system combining an 800-kW wind turbine and a 160-kWp photovoltaic (PV) field. The predominance of wind power makes the energy production of the island almost constant during the year while the consumption peaks in summer in correspondence with the tourist season. If the island wants to achieve complete selfsufficiency seasonal storage becomes compulsory. This study makes use of measured production data over 1 year to understand the best combination of renewable energy generation and storage to match energy production with consumption. A stochastic optimization based on a differential evolution algorithm is carried out to showcase the configuration that minimizes the levelized cost of required energy (LCORE) in different scenarios. System performance is simulated by progressively increasing the size of the storage devices including a combination of Lithium-ion batteries and power-to-gas-topower (P2G2P) technologies and the PV field. An in-depth market review of current and forecasted prices for RES and ESS components supports the economic analysis including three time horizons (current and projections to 2030 and 2050) to account for the expected drop in component prices. Currently the hybrid storage system combining BESS and P2G2P is more cost-effective (264 €/MWh) than a BESS-only system (320 €/MWh). In the mid-term (2030) the expected price drop in batteries will shift the optimal solution towards this technology but the LCORE reached by the hybrid storage (174 €/MWh) will still be more economical than BESS-only (200 €/MWh). In the long term (2050) the expected price drop in hydrogen technologies will push again the economic convenience of P2G2P and further reduce the LCORE (132.4 €/MWh).
Public Acceptance of a Proposed Sub-Regional, Hydrogen–Electric, Aviation Service: Empirical Evidence from HEART in the United Kingdom
Apr 2025
Publication
This paper addresses public acceptance of a proposed sub-regional hydrogen– electric aviation service reporting initial empirical evidence from the UK HEART project. The objective was to assess public acceptance of a wide range of service features including hydrogen power electric motors and pilot assistance automation in the context of an ongoing realisable commercial plan. Both qualitative and quantitative data collection instruments were leveraged including focus groups and stakeholder interviews as well as the questionnaire-based Scottish National survey coupled with the advanced discretechoice modelling of the data. The results from each method are presented compared and contrasted focusing on the strength reliability and validity of the data to generate insights into public acceptance. The findings suggest that public concerns were tempered by an incomplete understanding of the technology but were interpretable in terms of key service elements. Respondents’ concerns and opinions centred around hydrogen as a fuel singlepilot automation safety and security disability and inclusion environmental impact and the perceived usefulness of novel service features such as terminal design automation and sustainability. The latter findings were interpreted under a joint framework of technology acceptance theory and the diffusion of innovation. From this we drew key insights which were presented alongside a discussion of the results.
Socio-Economic Impact Assessment of Hydrogen Injection in the Natural Gas Network
Feb 2025
Publication
This study explores the feasibility parameters of a potential investment plan for injecting “green” hydrogen into the existing natural gas supply network in Greece. To this end a preliminary profitability optimization analysis was conducted through key performance indicators such as the cost of hydrogen and the socio-environmental benefit of carbon savings followed by break-even and sensitivity analyses. The identification of the major impact drivers of the assessment was based on the examination of a set of operational scenarios of varying hydrogen and natural gas flow rates. The results show that high natural gas capacities with a 5% hydrogen content by volume are the optimal case in terms of socio-economic viability but the overall profitability is too sensitive to hydrogen pricing rendering it unfeasible without additional motives measures and pricing strategies. The results feed into the main challenge of implementing commercial “green” hydrogen infrastructures in the market in a sustainable and feasible manner.
The Extractive Industry’s Decarbonization Potential Using Electrification and Hydrogen Technologies
Mar 2025
Publication
The challenge of achieving net-zero CO2 emissions will require a significant scaling up of the production of several raw materials that are critical for decarbonizing the global economy. In contrast metal extraction processes utilize carbon as a reducing agent which is oxidized to CO2 resulting in considerable emissions and having a negative impact on climate change. In order to abate their emissions extractive industries will have to go through a profound transformation including switching to alternative climateneutral energy and feedstock sources. This paper presents the authors’ perspectives for consideration in relation to the H2 potential for direct reduction of oxide and sulfide ores. For each case scenario the reduction of CO2 emissions is analyzed and a breakthrough route for H2S decomposition is presented which is a by-product of the direct reduction of sulfide ores with H2. Electrified indirect-fired metallurgical kiln advantages are also presented a solution that can substitute fossil fuel-based heating technologies which is one of the main backbones of industrial processes currently applied to the extractive industries.
Sustainable Fuel Supply for Very Small Island Transportation: The Potential of Hybrid Renewable Energy and Green Hydrogen
Mar 2025
Publication
The transition to a low-carbon future necessitates innovative approaches to renewable energy deployment particularly in the marine environment where abundant resources remain underutilized. This paper explores the potential of hybrid renewable energy systems and green hydrogen production to address the energy challenges faced by Very Small Islands (VSIs). These islands heavily rely on imported fossil fuels making them vulnerable to global price fluctuations and contributing to economic instability and environmental degradation. Offshore floating platforms present a transformative opportunity by harnessing marine renewable resources integrating wind solar and wave energy to maximize energy production while minimizing land use conflicts. Green hydrogen produced through the electrolysis of seawater powered by these renewable sources offers a sustainable alternative for decarbonizing transportation particularly in the maritime sector. The study aims to assess the feasibility of converting small conventional passenger vessels to hydrogen propulsion and evaluate the technical economic and environmental impacts of deploying offshore platforms for hydrogen production. By examining these aspects this research contributes to the broader discourse on sustainable energy solutions for island communities and provides actionable insights into implementing renewable hydrogen-based maritime transport.
Comparison of Hydro-pumped and Green Hydrogen as Energy Storage Process: A Case Study on Kefalonia Island, Greece
Sep 2025
Publication
The present research work investigates the performance of two large-scale energy storage technologies: hydro-pumped storage (HPS) and green hydrogen production within a hybrid renewable energy system (HRES) developed for Kefalonia Island Greece. Given the island’s seasonal water and electricity shortages driven by summer demand and limited infrastructure the goal is to identify which storage option better supports local autonomy. Two scenarios differing only in storage method were simulated using identical wind input and desalination setup. Performance was evaluated based on climate and demand data focusing on water and electricity needs. Both scenarios achieved 99.9 % potable water coverage. The HPS system exhibited notably higher energy efficiency (67 %) compared to hydrogen (33 %) and produced slightly more desalinated water reaching 18157791 m3 versus 17986544 m3 respectively. Electricity demand coverage reached 77.8 % with HPS and 76.0 % with hydrogen while irrigation demand was met by 80.2 % and 79.4 % respectively. Seasonal storage analysis revealed pronounced summer depletion in both cases due to high demand and low wind availability with HPS recovering faster and maintaining higher storage levels owing to lower energy losses. The comparison underscores the need for storage strategies adapted to island-specific water and energy dynamics. HPS is more efficient for short-to-medium-term needs while green hydrogen offers potential for long-duration storage and deeper decarbonization.
Multi-Physics Digital Model of an Aluminum 2219 Liquid Hydrogen Aircraft Tank
Feb 2024
Publication
Future liquid hydrogen-powered aircraft requires the design and optimization of a large number of systems and subsystems with cryogenic tanks being one of the largest and most critical. Considering previous space applications these tanks are usually stiffened by internal members such as stringers frames and stiffeners resulting in a complex geometry that leads to an eventual reduction in weight. Cryogenic tanks experience a variety of mechanical and thermal loading conditions and are usually constructed out of several different materials. The complexity of the geometry and the loads highlights the necessity for a computational tool in order to conduct analysis. In this direction the present work describes the development of a multi-physics finite element digital simulation conducting heat transfer and structural analysis in a fully parametric manner in order to be able to support the investigation of different design concepts materials geometries etc. The capabilities of the developed model are demonstrated by the design process of an independent-type aluminum 2219 cryogenic tank for commuter aircraft applications. The designed tank indicates a potential maximum take-off weight reduction of about 8% for the commuter category and demonstrates that aluminum alloys are serious candidate materials for future aircraft.
A Comprehensive Overview of Technologies Applied in Hydrogen Valleys
Dec 2024
Publication
Hydrogen valleys are encompassed within a defined geographical region with various technologies across the entire hydrogen value chain. The scope of this study is to analyze and assess the different hydrogen technologies for their application within the hydrogen valley context. Emphasizing on the coupling of renewable energy sources with electrolyzers to produce green hydrogen this study is focused on the most prominent electrolysis technologies including alkaline proton exchange membrane and solid oxide electrolysis. Moreover challenges related to hydrogen storage are explored alongside discussions on physical and chemical storage methods such as gaseous or liquid storage methanol ammonia and liquid organic hydrogen carriers. This article also addresses the distribution of hydrogen within valley operations especially regarding the current status on pipeline and truck transportation methods. Furthermore the diverse applications of hydrogen in the mobility industrial and energy sectors are presented showcasing its potential to integrate renewable energy into hard-to-abate sectors.
Post-mortem Analysis as a Method to Identify Degradation of PEM Fuel Cells Affecting their Durability in Maritime Applications
Sep 2025
Publication
Proton exchange membrane fuel cells (PEMFCs) present great potential for the decarbonization of the maritime sector but their durability in harsh marine environments remains a critical challenge. This review focuses on post-mortem analysis techniques as a tool to understand the degradation mechanisms of PEMFCs under stressors relevant to marine applications. In further detail the application of various imaging (SEM TEM) structural (XRD) electrochemical (CV) and elemental analysis (EDS) methods to characterize the effects of key stressors such as salt spray mechanical vibration and operational cycling was examined. By analyzing degraded PEMFC components post-mortem analysis reveals critical insights into catalyst layer degradation membrane damage and the impact of impurities enabling the identification of failure modes and the development of effective mitigation strategies for the establishment of PEMFCs in the maritime sector.
RES-electrolyser Coupling witin TRIERES Hydrogen Valley - A Flexible Technoeconomic Assessment Tool
Jan 2025
Publication
The escalating urgency to address climate change has sparked unprecedented interest in green hydrogen as a clean energy carrier. The intermittent nature of Renewable Energy Sources (RES) like wind and solar can introduce unpredictability into the energy supply potentially causing mismatches in the power grid. To this end green hydrogen production can provide a solution by enhancing system flexibility thereby accommodating the fluctuations and stochastic characteristics of RES. Furthermore green hydrogen could play a pivotal role in decarbonizing hard-to-abate sectors and promoting sector coupling. This research article endeavors to delve into this subject by developing a dynamic techno-economic analysis tool capable of flexibly assessing the optimal setup of Alkaline (AEL) electrolysis coupled with RES in a specific region or hub. The focus lies on achieving costeffectiveness efficiency and sustainable production of green hydrogen. The tool leverages a comprehensive dataset covering a full year of hourly data on both renewable electricity production from intermittent RES and wholesale electricity market prices alongside customizable inputs from users. It can be applied across various scenarios including direct coupling with dedicated RES plants and hybrid configurations utilizing the electricity grid as a backup source. The model optimizes RES electrolyser and hydrogen storage capacities to minimize the Levelized Cost of Hydrogen (LCOH) and/or the operational Carbon Intensity (CI) of hydrogen produced. The tool is applied within a real-world application study in the framework of the TRIERES Hydrogen Valley Project which is taking shape in Peloponnese Greece. For the various configurations analysed the LCOH ranges from 7.75 to 12.68 €/kgH2. The cost-optimal system configuration featuring a hybrid RES power supply of 12 MW solar and 19 MW wind energy alongside with 3.5 tonnes of hydrogen storage leads to a minimum LCOH of 7.75 €/kgH2. Subsidies on electrolyser stack and balance of plant CAPEX can reduce LCOH by up to 0.6 €/kgH2.
Methanol, a Plugin Marine Fuel for Green House Gas Reduction—A Review
Jan 2024
Publication
The escalating global demand for goods transport via shipping has heightened energy consumption impacting worldwide health and the environment. To mitigate this international organizations aim to achieve complete fuel desulphurization and decarbonization by 50% by 2050. Investigating eco-friendly fuels is crucial particularly those with a reduced carbon and zero sulfur content. Methanol derived mainly from renewable sources and produced by carbon dioxide’s hydrogenation method stands out as an effective solution for GHG reduction. Leveraging its favorable properties global scalability and compatibility with the existing infrastructure especially LNGs methanol proves to be a cost-efficient and minimally disruptive alternative. This review explores methanol’s role as a hybrid maritime fuel emphasizing its ecological production methods advantages and challenges in the shipping industry’s green transition. It discusses the environmental impacts of methanol use and analyzes economic factors positioning methanol not only as an ecofriendly option but also as a financially prudent choice for global shipping. Methanol is efficient and cost-effective and excels over MGO especially in new ships. It is economically advantageous with decreasing investment costs compared to LNG while providing flexibility without specialized pressure tanks. Global marine fuel trends prioritize fuel traits accessibility and environmental considerations incorporating factors like policies emissions bunkering and engine adaptability during transitions.
Environmental Assessment of Replacing Fossil Fuels with Hydrogen for Motorised Equipment in the Mining Sector
Nov 2023
Publication
To achieve the European milestone of climate neutrality by 2050 the decarbonisation of energy-intensive industries is essential. In 2022 global energy-related CO2 emissions increased by 0.9% or 321 Mt reaching a peak of over 36.8 Gt. A large amount of these emissions is the result of fossil fuel usage in the motorised equipment used in mining. Heavy diesel vehicles like excavators wheel loaders and dozers are responsible for an estimated annual CO2 emissions of 400 Mt of CO2 accounting for approximately 1.1% of global CO2 emissions. In addition exhaust gases of CO2 and NOx endanger the personnel’s health in all mining operations especially in underground environments. To tackle these environmental concerns and enhance environmental health extractive industries are focusing on replacing fossil fuels with alternative fuels of low or zero CO2 emissions. In mining the International Council on Mining and Metals has committed to achieving net zero emissions by 2050 or earlier. Of the various alternative fuels hydrogen (H2 ) has seen a considerable rise in popularity in recent years as H2 combustion accounts for zero CO2 emissions due to the lack of carbon in the burning process. When combusted with pure oxygen it also accounts for zero NOx formation and near-zero emissions overall. To this end this study aims to examine the overall environmental performance of H2 -powered motorised equipment compared to conventional fossil fuel-powered equipment through Life Cycle Assessment. The assessment was conducted using the commercial software Sphera LCA for Experts following the conventionally used framework established by ISO 14040:2006 and 14044:2006/A1:2018 and the International Life Cycle Data Handbook consisting of (1) the goal and scope definition (2) the Life Cycle Inventory (LCI) preparation (3) the Life Cycle Impact Assessment (LCIA) and (4) the interpretation of the results. The results will offer an overview to support decision-makers in the sector.
A New Path towards Sustainable Energy Transition: Techno-Economic Feasibility of a Complete Hybrid Small Modular Reactor/Hydrogen (SMR/H2) Energy System
Oct 2023
Publication
Small modular reactors (SMRs) are nuclear reactors with a smaller capacity than traditional large-scale nuclear reactors offering advantages such as increased safety flexibility and cost-effectiveness. By producing zero carbon emissions SMRs represent an interesting alternative for the decarbonization of power grids. Additionally they present a promising solution for the production of hydrogen by providing large amounts of energy for the electrolysis of water (pink hydrogen). The above hint at the attractiveness of coupling SMRs with hydrogen production and consumption centers in order to form clusters of applications which use hydrogen as a fuel. This work showcases the techno-economic feasibility of the potential installation of an SMR system coupled with hydrogen production the case study being the island of Crete. The overall aim of this approach is the determination of the optimal technical characteristics of such a system as well as the estimation of the potential environmental benefits in terms of reduction of CO2 emissions. The aforementioned system which is also connected to the grid is designed to serve a portion of the electric load of the island while producing enough hydrogen to satisfy the needs of the nearby industries and hotels. The results of this work could provide an alternative sustainable approach on how a hydrogen economy which would interconnect and decarbonize several industrial sectors could be established on the island of Crete. The proposed systems achieve an LCOE between EUR 0.046/kWh and EUR 0.052/kWh while reducing carbon emissions by more than 5 million tons per year in certain cases.
Hydrogen Revolution in Europe: Bibliometric Review of Industrial Hydrogen Applications for a Sustainable Future
Jul 2024
Publication
Industrial applications of hydrogen are key to the transition towards a sustainable lowcarbon economy. Hydrogen has the potential to decarbonize industrial sectors that currently rely heavily on fossil fuels. Hydrogen with its unique and versatile properties has several in-industrial applications that are fundamental for sustainability and energy efficiency such as the following: (i) chemical industry; (ii) metallurgical sector; (iii) transport; (iv) energy sector; and (v) agrifood sector. The development of a bibliometric analysis of industrial hydrogen applications in Europe is crucial to understand and guide developments in this emerging field. Such an analysis can identify research trends collaborations between institutions and countries and the areas of greatest impact and growth. By examining the scientific literature and comparing it with final hydrogen consumption in different regions of Europe the main actors and technologies that are driving innovation in industrial hydrogen use on the continent can be identified. The results obtained allow for an assessment of the knowledge gaps and technological challenges that need to be addressed to accelerate the uptake of hydrogen in various industrial sectors. This is essential to guide future investments and public policies towards strategic areas that maximize the economic and environmental impact of industrial hydrogen applications in Europe.
Techno-Economic Feasibility of Fuel Cell Vehicle-to-Grid Fast Frequency Control in Non-Interconnected Islands
Dec 2024
Publication
This paper presents an innovative approach to fast frequency control in electric grids by leveraging parked fuel cell electric vehicles (FCEVs) especially heavy-duty vehicles such as trucks. Equipped with hydrogen storage tanks and fuel cells these vehicles can be repurposed as dynamic grid-support assets while parked in designated areas. Using an external cable and inverter system FCEVs inject power into the grid by converting DC from fuel cells into AC to be compatible with grid requirements. This functionality addresses sudden power imbalances providing a rapid and efficient solution for frequency stabilization. The system’s external inverter serves as a central control hub monitoring real-time grid frequency and directing FCEVs to supply virtual inertia and primary reserves through droop control as required. Simulation results validate that FCEVs could effectively complement thermal generators preventing unacceptable frequency drops load shedding and network blackouts. A techno-economic analysis demonstrates the economic feasibility of the concept concluding that each FCEV consumes approximately 0.3 kg of hydrogen per day incurring a daily cost of around EUR 1.5. For an island grid with a nominal power of 100 MW maintaining frequency stability requires a fleet of 100 FCEVs resulting in a total daily cost of EUR 150. Compared to a grid-scale battery system offering equivalent frequency response services the proposed solution is up to three times more cost-effective highlighting its economic and technical potential for grid stabilization in renewable-rich non-interconnected power systems.
Cost Projection of Global Green Hydrogen Production Scenarios
Nov 2023
Publication
A sustainable future hydrogen economy hinges on the development of green hydrogen and the shift away from grey hydrogen but this is highly reliant on reducing production costs which are currently too high for green hydrogen to be competitive. This study predicts the cost trajectory of alkaline and proton exchange membrane (PEM) electrolyzers based on ongoing research and development (R&D) scale effects and experiential learning consequently influencing the levelized cost of hydrogen (LCOH) projections. Electrolyzer capital costs are estimated to drop to 88 USD/kW for alkaline and 60 USD/kW for PEM under an optimistic scenario by 2050 or 388 USD/kW and 286 USD/kW respectively under a pessimistic scenario with PEM potentially dominating the market. Through a combination of declining electrolyzer costs and a levelized cost of electricity (LCOE) the global LCOH of green hydrogen is projected to fall below 5 USD/kgH2 for solar onshore and offshore wind energy sources under both scenarios by 2030. To facilitate a quicker transition the implementation of financial strategies such as additional revenue streams a hydrogen/carbon credit system and an oxygen one (a minimum retail price of 2 USD/kgO2 ) and regulations such as a carbon tax (minimum 100 USD/tonCO2 for 40 USD/MWh electricity) and a contract-for-difference scheme could be pivotal. These initiatives would act as financial catalysts accelerating the transition to a greener hydrogen economy.
CFD Analysis of Delayed Ignition Hydrogen Releases from a Train Inside a Tunnel
Sep 2023
Publication
In the present work we present the results of numerical simulations involving the dispersion and combustion of a hydrogen cloud released in an empty tunnel. The simulations were conducted with the use of ADREA-HF CFD code and the results are compared with measurements from experiments conducted by HSE in a tunnel with the exact same geometry. The length of the tunnel is equal to 70 m and the maximum height from the floor is equal to 3.25 m. Hydrogen release is considered to occur from a train containing pressurized hydrogen stored at 580 bars. The release diameter is equal to 4.7 mm and the release direction is upwards. Initially dispersion simulation was performed in order to define the initial conditions for the deflagration simulations. The effect of the initial wind speed and the effect of the ignition delay time were investigated. An extensive grid sensitivity study was conducted in order to achieve grid independent results. The CFD model takes into account the flame instabilities that are developed as the flame propagates inside the tunnel and turbulence that exists in front of the flame front. Pressure predictions are compared against experimental measurements revealing a very good performance of the CFD model.
CFD Modelling of Large Scale Liquid Hydrogen Experiments Indoors and Outdoors
Sep 2023
Publication
The use of liquid hydrogen in maritime applications is expected to grow in the coming years in order to meet the decarbonisation goals that EU countries and countries worldwide have set for 2050. In this context The Norwegian Public Roads Administration commissioned large-scale LH2 dispersion and explosion experiments both indoors and outdoors which were conducted by DNG GL in 2019 to better understand safety aspects of LH2 in the maritime sector. In this work the DNV unignited outdoor and indoor tests have been simulated and compared with the experiments with the aim to validate the ADREA-HF Computational Fluid Dynamics (CFD) code in maritime applications. Three tests two outdoors and one indoors were chosen for the validation. The outdoor tests (test 5 and 6) involved liquid hydrogen release vertically downwards and horizontal to simulate an accidental leakage during bunkering. The indoor test (test 9) involved liquid hydrogen release inside a closed room to simulate an accident inside a tank connection space (TCS) connected to a ventilation mast.
Numerical Investigation of Hydrogen Jet Dispersion Below and Around a Car in a Tunnel
Sep 2023
Publication
Accidental release from a hydrogen car tank in a confined space like a tunnel poses safety concerns. This Computational Fluid Dynamics (CFD) study focuses on the first seconds of such a release which are the most critical. Hydrogen leaks through a Thermal Pressure Relief Device (TPRD) forms a high-speed jet that impinges on the street spreads horizontally recirculates under the chassis and fills the area below it in about one second. The “fresh-air entrainment effect” at the back of the car changes the concentrations under the chassis and results in the creation of two “tongues” of hydrogen at the rear corners of the car. Two other tongues are formed near the front sides of the vehicle. In general after a few seconds hydrogen starts moving upwards around the car mainly in the form of buoyant blister-like structures. The average hydrogen volume concentrations below the car have a maximum of 71% which occurs at 2 s. The largest “equivalent stoichiometric flammable gas cloud size Q9” is 20.2 m3 at 2.7 s. Smaller TPRDs result in smaller hydrogen flow rates and smaller buoyant structures that are closer to the car. The investigation of the hydrogen dispersion during the initial stages of the leak and the identification of the physical phenomena that occur can be useful for the design of experiments for the determination of the TPRD characteristics for potential safety measures and for understanding the further distribution of the hydrogen cloud in the tunnel.
The Potential Role of Africa in Green Hydrogen Production: A Short-Term Roadmap to Protect the World’s Future from Climate Crisis
Feb 2025
Publication
The global need for energy has risen sharply recently. A global shift to clean energy is urgently needed to avoid catastrophic climate impacts. Hydrogen (H2) has emerged as a potential alternative energy source with near-net-zero emissions. In the African continent for sustainable access to clean energy and the transition away from fossil fuels this paper presents a new approach through which waste energy can produce green hydrogen from biomass. Bio-based hydrogen employing organic waste and biomass is recommended using biological (anaerobic digestion and fermentation) processes for scalable cheaper and low-carbon hydrogen. By reviewing all methods for producing green hydrogen dark fermentation can be applied in developed and developing countries without putting pressure on natural resources such as freshwater and rare metals the primary feedstocks used in producing green hydrogen by electrolysis. It can be expanded to produce medium- and long-term green hydrogen without relying heavily on energy sources or building expensive infrastructure. Implementing the dark fermentation process can support poor communities in producing green hydrogen as an energy source regardless of political and tribal conflicts unlike other methods that require political stability. In addition this approach does not require the approval of new legislation. Such processes can ensure the minimization of waste and greenhouse gases. To achieve cost reduction in hydrogen production by 2030 governments should develop a strategy to expand the use of dark fermentation reactors and utilize hot water from various industrial processes (waste energy recovery from hot wastewater).
Fuzzy Logic-Based Energy Management Strategy for Hybrid Fuel Cell Electric Ship Power and Propulsion System
Oct 2024
Publication
The growing use of proton-exchange membrane fuel cells (PEMFCs) in hybrid propulsion systems is aimed at replacing traditional internal combustion engines and reducing greenhouse gas emissions. Effective power distribution between the fuel cell and the energy storage system (ESS) is crucial and has led to a growing emphasis on developing energy management systems (EMSs) to efficiently implement this integration. To address this goal this study examines the performance of a fuzzy logic rule-based strategy for a hybrid fuel cell propulsion system in a small hydrogenpowered passenger vessel. The primary objective is to optimize fuel efficiency with particular attention on reducing hydrogen consumption. The analysis is carried out under typical operating conditions encountered during a river trip. Comparisons between the proposed strategy with other approaches—control based optimization based and deterministic rule based—are conducted to verify the effectiveness of the proposed strategy. Simulation results indicated that the EMS based on fuzzy logic mechanisms was the most successful in reducing fuel consumption. The superior performance of this method stems from its ability to adaptively manage power distribution between the fuel cell and energy storage systems.
Energy Management in a Super-Tanker Powered by Solar, Wind, Hydrogen and Boil-Off Gas for Saving CO2 Emissions
Apr 2024
Publication
In terms of energy generation and consumption ships are autonomous isolated systems with power demands varying according to the type of ship: passenger or commercial. The power supply in modern ships is based on thermal engines-generators which use fossil fuels marine diesel oil (MDO) and liquefied natural gas (LNG). The continuous operation of thermal engines on ships during cruises results in increased emissions of polluting gases mainly CO/CO2 . The combination of renewable energy sources (REs) and triple-fuel diesel engines (TFDEs) can reduce CO/CO2 emissions resulting in a “greener” interaction between ships and the ecosystem. This work presents a new control method for balancing the power generation and the load demands of a ship equipped with TFDEs fuel cells (FCs) and REs based on a real and accurate model of a super-tanker and simulation of its operation in real cruise conditions. The new TFDE technology engines are capable of using different fuels (marine diesel oil heavy fuel oil and liquified natural gas) producing the power required for ship operation as well as using compositions of other fuels based on diesel aiming to reduce the polluting gases produced. The energy management system (EMS) of a ship is designed and implemented in the structure of a finite state machine (FSM) using the logical design of transitions from state to state. The results demonstrate that further reductions in fossil fuel consumption as well as CO2 emissions are possible if ship power generation is combined with FC units that consume hydrogen as fuel. The hydrogen is produced locally on the ship through electrolysis using the electric power generated by the on-board renewable energy sources (REs) using photovoltaic systems (PVs) and wind energy conversion turbines (WECs).
A Technology Review of Decarbonization: Efficient Techniques for Producing Hydrogen as Fuel
Aug 2023
Publication
Climate change is obvious in many ways. The weather changes rapidly from day to day reaching high temperatures such as 28 ◦C one day and heavy rain the next with temperatures below 18 ◦C. There are also very strong storms caused by this phenomenon. The way the environment acts is different than the current epoch would predict indicating a long-term shift in weather and temperature patterns. The mean temperature of earth is rising due to the greenhouse effect that is caused by human activity and mostly by the burning of fossil fuel emitting CO2 and other pollutant gasses. Nowadays every country is trying to lower CO2 emissions from everyday human activities a movement called “decarbonization”. Since the 18th century there has been a great deal of research carried out on possible alternatives to fossil fuels. Some of the work was just to discover ways to power heaters or automotive vehicle but there is a great deal of work remaining to complete regarding this issue after discovering the greenhouse effect and its impact on the planet’s climate in order to eliminate it by using fuel whose combustion emissions are more environmentally friendly. In the present work many discoveries will be presented that use hydrogen (H2 ) or hydroxy (H-OH) as fuel. The main reason for this is the emission of pure water after combustion but the most interesting part is the approach every scientist uses to create the fuel gas from water.
Charting the Course: Navigating Decarbonisation Pathways in Greece, Germany, The Netherlands, and Spain’s Industrial Sectors
Jul 2024
Publication
In the quest for a sustainable future energy-intensive industries (EIIs) stand at the forefront of Europe’s decarbonisation mission. Despite their significant emissions footprint the path to comprehensive decarbonisation remains elusive at EU and national levels. This study scrutinises key sectors such as non-ferrous metals steel cement lime chemicals fertilisers ceramics and glass. It maps out their current environmental impact and potential for mitigation through innovative strategies. The analysis spans across Spain Greece Germany and the Netherlands highlighting sector-specific ecosystems and the technological breakthroughs shaping them. It addresses the urgency for the industry-wide adoption of electrification the utilisation of green hydrogen biomass bio-based or synthetic fuels and the deployment of carbon capture utilisation and storage to ensure a smooth transition. Investment decisions in EIIs will depend on predictable economic and regulatory landscapes. This analysis discusses the risks associated with continued investment in high-emission technologies which may lead to premature decommissioning and significant economic repercussions. It presents a dichotomy: invest in climate-neutral technologies now or face the closure and offshoring of operations later with consequences for employment. This open discussion concludes that while the technology for near-complete climate neutrality in EIIs exists and is rapidly advancing the higher costs compared to conventional methods pose a significant barrier. Without the ability to pass these costs to consumers the adoption of such technologies is stifled. Therefore it calls for decisive political commitment to support the industry’s transition ensuring a greener more resilient future for Europe’s industrial backbone.
Towards the Design of a Hydrogen-powered Ferry for Cleaner Passenger Transport
Aug 2024
Publication
The maritime transportation sector is a large and growing contributor of greenhouse gas and other emissions. Therefore stringent measures have been taken by the International Maritime Organization to mitigate the environmental impact of the international shipping. These lead to the adoption of new technical solutions involving clean fuels such as hydrogen and high efficiency propulsion technologies that is fuel cells. In this framework this paper proposes a methodological approach aimed at supporting the retrofit design process of a car-passenger ferry operating in the Greece’s western maritime zone whose conventional powertrain is replaced with a fuel cell hybrid system. To this aim first the energy/power requirements and the expected hydrogen consumption of the vessel are determined basing on a typical operational profile retrieved from data provided by the shipping company. Three hybrid powertrain configurations are then proposed where fuel cell and batteries are balanced out according to different design criteria. Hence a new vessel layout is defined for each of the considered options by taking into account on-board weight and space constraints to allocate the components of the new hydrogen-based propulsion systems. Finally the developed vessel configurations are simulated in a virtual towing tank environment in order to assess their hydrodynamic response and compare them with the original one thus providing crucial insights for the design process of new hydrogen-fueled vessel solutions. Findings from this study reveal that the hydrogen-based configurations of the vessel are all characterized by a slight reduction of the payload mainly due to the space required to allocate the hydrogen storage system; instead the hydrodynamic behavior of the H2 powered vessels is found to be similar to the one of the original Diesel configuration; also from a hydrodynamic point of view the results show that mid load operating conditions get relevance for the design process of the hybrid vessels.
Management of Hybrid Wind and Photovoltaic System Electrolyzer for Green Hydrogen Production and Storage in the Presence of a Small Fleet of Hydrogen Vehicles— An Economic Assessment
Dec 2023
Publication
Nowadays with the need for clean and sustainable energy at its historical peak new equipment strategies and methods have to be developed to reduce environmental pollution. Drastic steps and measures have already been taken on a global scale. Renewable energy sources (RESs) are being installed with a growing rhythm in the power grids. Such installations and operations in power systems must also be economically viable over time to attract more investors thus creating a cycle where green energy e.g. green hydrogen production will be both environmentally friendly and economically beneficial. This work presents a management method for assessing wind–solar– hydrogen (H2 ) energy systems. To optimize component sizing and calculate the cost of the produced H2 the basic procedure of the whole management method includes chronological simulations and economic calculations. The proposed system consists of a wind turbine (WT) a photovoltaic (PV) unit an electrolyzer a compressor a storage tank a fuel cell (FC) and various power converters. The paper presents a case study of green hydrogen production on Sifnos Island in Greece through RES together with a scenario where hydrogen vehicle consumption and RES production are higher during the summer months. Hydrogen stations represent H2 demand. The proposed system is connected to the main power grid of the island to cover the load demand if the RES cannot do this. This study also includes a cost analysis due to the high investment costs. The levelized cost of energy (LCOE) and the cost of the produced H2 are calculated and some future simulations correlated with the main costs of the components of the proposed system are pointed out. The MATLAB language is used for all simulations.
Waste to Sustainable Biohydrogen Production Via Photo-Fermentation and Biophotolysis - A Systematic Review
Oct 2021
Publication
Considering the environmental challenges humanity faces in the 21st century it is obvious that there is an enormous need for change of the global energy map. Under these circumstances new energy sources and intermediates must be considered as options to limit the greenhouse gases emissions and mitigate climate crisis. Biohydrogen production is one of the most appealing options due to hydrogen’s multiple applications and zero emissions as a fuel to empower a future hydrogen circular economy. In this review article we focus on two methods that are not widely used at industrial scale but have many future possibilities and growth margins: (a) photo-fermentation and (b) bio photolysis. Both methods are light dependent and need photobioreactors to function and produce significant amounts of biohydrogen. Based on an extensive literature search and systemic analysis of the findings presentation of the different reactants operating conditions and biohydrogen productions key factors and effecting parameters were discussed. Temperature pH light intensity and photobioreactor operation and design are some of the most significant factors that define the biohydrogen production rates and yields. Innovative solutions and approaches are presented including biotechnological and genetic engineering modifications to microorganisms as well as combinations of some hybrid biohydrogen producing methods especially dark and photo fermentation. For implementing a biohydrogen circular-economy different wastes were explored as potential feedstocks and overcoming of major bottlenecks that biophotolysis and photo-fermentation face in the transition to a sustainable biohydrogen economy were discussed.
An Overview of Hydrogen Valleys: Current Status, Challenges and their Role in Increased Renewable Energy Penetration
Sep 2024
Publication
Renewable hydrogen is a flexible and versatile energy vector that can facilitate the decarbonization of several sectors and simultaneously ease the stress on the electricity grids that are currently being saturated with intermittent renewable power. But hydrogen technologies are currently facing limitations related to existing infrastructure limitations available markets as well as production storage and distribution costs. These challenges will be gradually addressed through the establishment operation and scaling-up of hydrogen valleys. Hydrogen valleys are an important stepping stone towards the full-scale implementation of the hydrogen economy with the target to foster sustainability lower carbon emissions and derisk the associated hydrogen technologies. These hydrogen ecosystems integrate renewable energy sources efficient hydrogen production storage transportation technologies as well as diverse end-users within a defined geographical region. This study offers an overview of the hydrogen valleys concept analyzing the critical aspects of their design and the key segments that constitute the framework of a hydrogen valley. А holistic overview of the key characteristics of a hydrogen valley is provided whereas an overview of key on-going hydrogen valley projects is presented. This work underscores the importance of addressing challenges related to the integration of renewable energy sources into electricity grids as well as scale-up challenges associated with economic and market conditions society awareness and political decision-making.
On the Identification of Regulatory Gaps for Hydrogen as Maritime Fuel
Feb 2025
Publication
C. Georgopoulou,
C. Di Maria,
G. Di Ilio,
Viviana Cigolotti,
Mariagiovanna Minutillo,
Mosè Rossi,
B.P. Sullivan,
A. Bionda,
Markus Rautanen,
R. Ponzini,
F. Salvadore,
M. Alvarez-Cardozo,
P. Douska,
L. Koukoulopoulos,
G. Psaraftis,
G. Dimopoulos,
T. Wannemacher,
N. Baumann,
K. Mahosl,
M. Tome,
O. Noguero Torres,
F. Oikonomou,
A. Hamalainen,
F. Chillé,
Y. Papagiannopoulos and
N. Sakellaridis
The decarbonization of the maritime sector represents a priority in the energy policy agendas of the majority of Countries worldwide and the International Maritime Organization (IMO) has recently revised its strategy aiming for an ambitious zero-emissions scenario by 2050. In these regards there is a broad consensus on hydrogen as one of the most promising clean energy vectors for maritime transport and a key towards that goal. However to date an international regulatory framework for the use of hydrogen on-board of ships is absent this posing a severe limitation to the adoption of hydrogen technologies in this sector. To cope with this issue this paper presents a preliminary gap assessment analysis for the International Code of Safety for Ship Using Gases or other Low-flashpoint Fuels (IGF Code) with relation to hydrogen as a fuel. The analysis is structured according to the IGF Code chapters and a bottom-up approach is followed to review the code content and assess its relevance to hydrogen. The risks related to hydrogen are accounted for in assessing the gaps and providing a first level set of recommendations for IGF Code updates. By this means this work settles the basis for further research over the identified gaps towards the identification of a final set of recommendations for the IGF Code update.
Integrating Sustainability in Aircraft Component Design: Towards a Transition from Eco-Driven to Sustainability-Driven Design
Feb 2025
Publication
Eco-design is an innovative design methodology that focuses on minimizing the environmental footprint of industries including aviation right from the conceptual and development stages. However rising industrial demand calls for a more comprehensive strategy wherein beyond environmental considerations competitiveness becomes a critical factor supported by additional pillars of sustainability such as economic viability circularity and social impact. By incorporating sustainability as a primary design driver at the initial design stages this study suggests a shift from eco-driven to sustainability-driven design approaches for aircraft components. This expanded strategy considers performance and safety goals environmental impact costs social factors and circular economy considerations. To provide the most sustainable design that balances all objectives these aspects are rigorously quantified and optimized during the design process. To efficiently prioritize different variables methods such as multi-criteria decision-making (MCDM) are employed and a sustainability index is developed in this framework to assess the overall sustainability of each design alternative. The most sustainable design configurations are then identified through an optimization process. A typical aircraft component namely a hat-stiffened panel is selected to demonstrate the proposed approach. The study highlights how effectively sustainability considerations can be integrated from the early stages of the design process by exploring diverse material combinations and geometric configurations. The findings indicate that the type of fuel used and the importance given to the sustainability pillars—which are ultimately determined by the particular requirements and goals of the user—have a significant impact on the sustainability outcome. When equal prioritization is given across the diverse dimensions of sustainability the most sustainable option appears to be the full thermoplastic component when kerosene is used. Conversely when hydrogen is considered the full aluminum component emerges as the most sustainable choice. This trend also holds when environmental impact is prioritized over the other aspects of sustainability. However when costs are prioritized the full thermoplastic component is the most sustainable option whether hydrogen or kerosene is used as the fuel in the use phase. This innovative approach enhances the overall sustainability of aircraft components emphasizing the importance and benefits of incorporating a broader range of sustainability factors at the conceptual and initial design phases.
Sustainability Assessment of Alternative Energy Fuels for Aircrafts—A Life Cycle Analysis Approach
Nov 2024
Publication
Aviation is of crucial importance for the transportation sector and fundamental for the economy as it facilitates trade and private travel. Nonetheless this sector is responsible for a great amount of global carbon dioxide emissions exceeding 920 million tonnes annually. Alternative energy fuels (AEFs) can be considered as a promising solution to tackle this issue with the potential to lower greenhouse gas emissions and reduce reliance on fossil fuels in the aviation industry. A life cycle analysis is performed considering an aircraft running on conventional jet fuel and various alternative fuels (biojet methanol and DME) including hydrogen and ammonia. The comparative assessment investigates different fuel production pathways including the following: JETA-1 and biojet fuels via hydrotreated esters and fatty acids (HEFAs) as well as hydrogen and ammonia employing water electrolysis using wind and solar photovoltaic collectors. The outputs of the assessment are quantified in terms of carbon dioxide equivalent emissions acidification eutrophication eco-toxicity human toxicity and carcinogens. The life cycle phases included the following: (i) the construction maintenance and disposal of airports; (ii) the operation and maintenance of aircrafts; and (iii) the production transportation and utilisation of aviation fuel in aircrafts. The results suggest that hydrogen is a more environmentally benign alternative compared to JETA-1 biojet fuel methanol DME and ammonia.
Design, Analysis, and Testing of a Type V Composite Pressure Vessel for Hydrogen Storage
Dec 2024
Publication
Hydrogen as a zero-emission fuel produces only water when used in fuel cells making it a vital contributor to reducing greenhouse gas emissions across industries like transportation energy and manufacturing. Efficient hydrogen storage requires lightweight high-strength vessels capable of withstanding high pressures to ensure the safe and reliable delivery of clean energy for various applications. Type V composite pressure vessels (CPVs) have emerged as a preferred solution due to their superior properties thus this study aims to predict the performance of a Type V CPV by developing its numerical model and calculating numerical burst pressure (NBP). For the validation of the numerical model a Hydraulic Burst Pressure test is conducted to determine the experimental burst pressure (EBP). The comparative study between NBP and EBP shows that the numerical model provides an accurate prediction of the vessel’s performance under pressure including the identification of failure locations. These findings highlight the potential of the numerical model to streamline the development process reduce costs and accelerate the production of CPVs that are manufactured by prepreg hand layup process (PHLP) using carbon fiber/epoxy resin prepreg material.
Production and Storage of Hydrogen from Biomass and Other Sources: Technologies and Policies
Jan 2025
Publication
Hydrogen has emerged as a critical energy carrier for achieving global decarbonization and supporting a sustainable energy future. This review explores key advancements in hydrogen production technologies including electrolysis biomass gasification and thermochemical processes alongside innovations in storage methods like metal hydrides and liquid organic hydrogen carriers (LOHCs). Despite its promise challenges such as high production costs scalability issues and safety concerns persist. Biomass gasification stands out for its dual benefits of waste management and carbon neutrality yet hurdles like feedstock variability and energy efficiency need further attention. This review also identifies opportunities for improvement such as developing cost-effective catalysts and hybrid storage systems while emphasizing future research on improving storage efficiency and tackling production bottlenecks. By addressing these challenges hydrogen can play a central role in the global transition to cleaner energy systems.
Numerical Estimation of the Structural Integrity in an Existing Pipeline Network for the Transportation of Hydrogen Mixture in the Future
Jan 2025
Publication
Hydrogen is gaining attention due to its potential to address key challenges in the sectors of energy transportation and industry since it is a much cleaner energy source when compared to fossil fuels. The transportation of hydrogen from the point of its production to the point of use can be performed by road rail sea pipeline networks or a combination of the abovementioned. Being in the preliminary stage of hydrogen use the utilization of the already existing natural gas pipeline networks for hydrogen mixtures transportation has been suggested as an efficient means of expanding hydrogen infrastructure. Yet exploring this alternative major challenges such as the pre-existence of cracks in the pipelines and the effect of hydrogen embrittlement on the material of the pipelines exist. In this paper the macroscopic numerical modeling of pipeline segments with the use of the finite element method is performed. In more details the structural integrity of intact and damaged pipeline segments of different geometry and mechanical properties was estimated. The effect of the pipeline geometry and material has been investigated in terms of stress contours with and without the influence of hydrogen. The results suggest that the structural integrity of the pipeline segments is more compromised by pre-existing longitudinal cracks which might lead to an increase in the maximum value of equivalent Von Mises stress by up to four times depending on their length-tothickness ratio. This effect becomes more pronounced with the existence of hydrogen in the pipeline network.
A Review of Caprock Integrity in Underground Hydrogen Storage Sites: Implication of Wettability, Interfacial Tension, and Diffusion
Oct 2025
Publication
As industry moves from fossil fuels to green energy substituting hydrocarbons with hydrogen as an energy carrier seems promising. Hydrogen can be stored in salt caverns depleted hydrocarbon fields and saline aquifers. Among other criteria these storage solutions must ensure storage safety and prevent leakage. The ability of a caprock to prevent fluid from flowing out of the reservoir is thus of utmost importance. In this review the main factors influencing fluid flow are examined. These are the wettability of the caprock formation the interfacial tension (IFT) between the rock and the gas or liquid phases and the ability of gases to diffuse through it. To achieve effective sealing the caprock formation should possess low porosity a disconnected or highly complicated pore system low permeability and remain strongly water-wet regardless of pressure and temperature conditions. In addition it must exhibit low rock–liquid IFT while presenting high rock–gas and liquid–gas IFT. Finally the effective diffusion coefficient should be the lowest possible. Among all of the currently reviewed formations and minerals the evaporites low-organic-content shales mudstones muscovite clays and anhydrite have been identified as highly effective caprocks offering excellent sealing capabilities and preventing hydrogen leakages.
TwinP2G: A Software Application for Optimal Power-to Gas Planning
Sep 2025
Publication
This paper presents TwinP2G a software application for optimal planning of investments in power-to-gas (PtG) systems. TwinP2G provides simulation and optimization services for the techno-economic analysis of user-customized energy networks. The core of TwinP2G is based on power flow simulation; however it supports energy sector coupling including electricity green hydrogen natural gas and synthetic methane. The framework provides a user-friendly user interface (UI) suitable for various user roles including data scientists and energy experts using visualizations and metrics on the assessed investments. An identity and access management mechanism also serves the security and authorization needs of the framework. Finally TwinP2G revolutionizes the concept of data availability and data sharing by granting its users access to distributed energy datasets available in the EnerShare Data Space. These data are available to TwinP2G users for conducting their experiments and extracting useful insights on optimal PtG investments for the energy grid.
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