Applications & Pathways
Technology Transfer from Fuel Processing for Fuel Cells to Fuel Synthesis from Hydrogen and Carbon Dioxide
Aug 2023
Publication
Improving the energy efficiency of existing technologies such as the on-board power supply of trucks ships and aircraft is an important endeavor for reducing primary energy consumption. The approach consists of using fuel cell technology in conjunction with hydrogen production from liquid fuels. However the energy transition with the goal of complete climate-neutrality requires technological changes in the use of hydrogen produced from renewable energy via electrolysis. Synthetic fuels are an important building block for drive systems that will continue to require liquid energy carriers in the future due to their range. This study addresses the question of whether technical devices that were developed for the generation of hydrogen from liquid fuels for fuel cells to generate electricity are now suitable for the reverse process chain or can play an important role in it. The new process chain produces hydrogen from sustainable electricity combining it with carbon dioxide to create a synthetic liquid fuel.
Energy Consumption and Saved Emissions of a Hydrogen Power System for Ultralight Aviation: A Case Study
Jul 2024
Publication
The growing concern about climate change and the contemporary increase in mobility requirements call for faster cheaper safer and cleaner means of transportation. The retrofitting of fossil-fueled piston engine ultralight aerial vehicles to hydrogen power systems is an option recently proposed in this direction. The goal of this investigation is a comparative analysis of the environmental impact of conventional and hydrogen-based propulsive systems. As a case study a hybrid electric configuration consisting of a fuel cell with a nominal power of about 30 kW a 6 kWh LFP battery and a pressurized hydrogen vessel is proposed to replace a piston prop configuration for an ultralight aerial vehicle. Both power systems are modeled with a backward approach that allows the efficiency of the main components to be evaluated based on the load and altitude at every moment of the flight with a time step of 1 s. A typical 90 min flight mission is considered for the comparative analysis which is performed in terms of direct and indirect emissions of carbon dioxide water and pollutant substances. For the hydrogen-based configuration two possible strategies are adopted for the use of the battery: charge sustaining and charge depleting. Moreover the effect of the altitude on the parasitic power of the fuel cell compressor and consequently on the net efficiency of the fuel cell system is taken into account. The results showed that even if the use of hydrogen confines the direct environmental impact to the emission of water (in a similar quantity to the fossil fuel case) the indirect emissions associated with the production transportation and delivery of hydrogen and electricity compromise the desired achievement of pollutant-free propulsion in terms of equivalent emissions of CO2 and VOCs if hydrogen is obtained from natural gas reforming. However in the case of green hydrogen from electrolysis with wind energy the total (direct and indirect) emissions of CO2 can be reduced up to 1/5 of the fossil fuel case. The proposed configuration has the additional advantage of eliminating the problem of lead which is used as an additive in the AVGAS 100LL.
Design Investigation of Potential Long-Range Hydrogen Combustion Blended Wing Body Aircraft with Future Technologies
Jun 2023
Publication
Present work investigates the potential of a long-range commercial blended wing body configuration powered by hydrogen combustion engines with future airframe and propulsion technologies. Future technologies include advanced materials load alleviation techniques boundary layer ingestion and ultra-high bypass ratio engines. The hydrogen combustion configuration was compared to the configuration powered by kerosene with respect to geometric properties performance characteristics energy demand equivalent CO2 emissions and Direct Operating Costs. In addition technology sensitivity studies were performed to assess the potential influence of each technology on the configuration. A multi-fidelity sizing methodology using low- and mid-fidelity methods for rapid configuration sizing was created to assess the configuration and perform robust analyses and multi-disciplinary optimizations. To assess potential uncertainties of the fidelity of aerodynamic analysis tools high-fidelity aerodynamic analysis and optimization framework MACHAero was used for additional verification. Comparison of hydrogen and kerosene blended wing body aircraft showed a potential reduction of equivalent CO2 emission by 15% and 81% for blue and green hydrogen compared to the kerosene blended wing body and by 44% and 88% with respect to a conventional B777-300ER aircraft. Advancements in future technologies also significantly affect the geometric layout of aircraft. Boundary layer ingestion and ultra-high bypass ratio engines demonstrated the highest potential for fuel reduction although both technologies conflict with each other. However operating costs of hydrogen aircraft could establish a significant problem if pessimistic and base hydrogen price scenarios are achieved for blue and green hydrogen respectively. Finally configurational problems featured by classical blended wing body aircraft are magnified for the hydrogen case due to the significant volume requirements to store hydrogen fuel.
Operating Characteristics Analysis and Capacity Configuration Optimization of Wind-Solar-Hydrogen Hybrid Multi-energy Complementary System
Dec 2023
Publication
Wind and solar energy are the important renewable energy sources while their inherent natures of random and intermittent also exert negative effect on the electrical grid connection. As one of multiple energy complementary route by adopting the electrolysis technology the wind-solar-hydrogen hybrid system contributes to improving green power utilization and reducing its fluctuation. Therefore the moving average method and the hybrid energy storage module are proposed which can smooth the wind-solar power generation and enhance the system energy management. Moreover the optimization of system capacity configuration and the sensitive analysis are implemented by the MATLAB program platform. The results indicate that the 10-min grid-connected volatility is reduced by 38.7% based on the smoothing strategy and the internal investment return rate can reach 13.67% when the electricity price is 0.04 $/kWh. In addition the annual coordinated power and cycle proportion of the hybrid energy storage module are 80.5% and 90% respectively. The developed hybrid energy storage module can well meet the annual coordination requirements and has lower levelized cost of electricity. This method provides reasonable reference for designing and optimizing the wind-solar-hydrogen complementary system.
Split Injection Strategies for a High-pressure Hydrogen Direct Injection in a Small-bore Dual-fuel Diesel Engine
Jan 2024
Publication
Hydrogen-diesel dual direct-injection (H2DDI) engines present a promising pathway towards cleaner and more efficient transportation. In this study hydrogen split injection strategies were explored in an automotive-size single-cylinder compression ignition (CI) engine with a focus on varying the injection timings and energy fractions. The engine was operated at an intermediate load with fixed combustion phasing through adjustments of pilot diesel injection timing. An energy substitution principle guided the variation in energy fraction between the two hydrogen injections and then diesel injection while keeping the total energy input constant. The findings demonstrate that early first hydrogen injection timings lead to characteristics indicative of premixed combustion reflecting a high homogeneity of the hydrogen-air mixture. In contrast hydrogen stratification levels were predominantly influenced by later second injection timings with mixing-controlled combustion behaviour apparent for very late injections near top dead centre or when the second hydrogen injection held high energy fractions which led to decreased nitrogen oxides (NOx: NO and NO2) emissions. The carbon dioxide (CO2) emissions did not show high sensitivity to the hydrogen split injection strategies exhibiting about 77 % reduction compared to the diesel baseline due primarily to increased hydrogen energy fraction of up to 90 %
Green Hydrogen as a Clean Energy Resource and Its Applications as an Engine Fuel
Jan 2024
Publication
The world’s economy heavily depends on the energy resources used by various countries. India is one of the promising developing nations with very low crude reserves actively looking for new renewable energy resources to power its economy. Higher energy consumption and environmental pollution are two big global challenges for our sustainable development. The world is currently facing a dual problem of an energy crisis as well as environmental degradation. So there is a strong need to reduce our dependency on fossil fuels and greenhouse gas emissions. This can be achieved to a great extent by universally adopting clean fuels for all daily life uses like ethanol or liquified natural gas (LNG) as these burn very clean and do not emit many pollutants. Nowadays green hydrogen has emerged as a new clean energy source which is abundantly available and does not pollute much. This article explores the various benefits of green hydrogen with respect to fossil fuels various techniques of producing it and its possible use in different sectors such as industry transport and aviation as well as in day-to-day life. Finally it explores the use of green hydrogen as fuel in automobile engines its blending with CNG gas and its benefits in reducing emissions compared to fossil fuels. On combustion green hydrogen produces only water vapours and is thus a highly clean fuel. Thus it can potentially help humanity preserve the environment due to its ultra-low emissions and can be a consistent and reliable source of energy for generations to come thereby ending the clean energy security debate forever.
Recent Advances in Sustainable and Safe Marine Engine Operation with Alternative Fuels
Nov 2022
Publication
Pursuing net-zero emission operations in the shipping industry are quintessential for this sector to mitigate the environmental impact caused by hydrocarbon fuel combustion. Significant contributions to this are expected from the substitution of conventional marine fuels by alternative emission-free fuels with lower emission footprints. This study aims to conduct a comprehensive literature review for delineating the main characteristics of the considered alternative fuels specifically focusing on hydrogen methanol and ammonia which have recently attracted attention from both industry and academia. This study comparatively assesses the potential of using these fuels in marine engines and their subsequent performance characteristics as well as the associated environmental benefits. In addition the required storage conditions space as well as the associated costs are reviewed. Special attention is given to the safety characteristics and requirements for each alternative fuel. The results of this study demonstrate that the environmental benefits gained from alternative fuel use are pronounced only when renewable energy is considerably exploited for their production whereas the feasibility of each fuel depends on the vessel type used and pertinent storage constraints. Hydrogen ammonia and methanol are considered best-fit solutions for small scale shipping requiring minimal on-board storage. In addition the need for comparative assessments between diesel and alternative fuels is highlighted and sheds light on marine engines’ operational characteristics. Moreover using combinations of alternative and diesel fuels is identified as a direction towards decarbonisation of the maritime sector; intensifying the need for optimisation studies on marine engine design and operation. This study concludes with recommendations for future research directions thus contributing to fuel research concepts that can facilitate the shipboard use of alternative fuels.
A Multi-energy Multi-microgrid System Planning Model for Decarbonisation and Decontamination of Isolated Systems
May 2023
Publication
Decarbonising and decontaminating remote regions in the world presents several challenges. Many of these regions feature isolation dispersed demand in large areas and a lack of economic resources that impede the development of robust and sustainable networks. Furthermore isolated systems in the developing world are mostly based on diesel generation for electricity and firewood and liquefied petroleum gas for heating as these options do not require a significant infrastructure cost. In this context we present a stochastic multi-energy multi-microgrid system planning model that integrates electricity heat and hydrogen networks in isolated systems. The model is stochastic to capture uncertainty in renewable generation outputs particularly hydro and wind and thus design a multi-energy system proved secured against such uncertainty. The model also features two distinct constraints to limit the emissions of CO2 (for decarbonisation) and particulate matter (for decontamination) and incorporates firewood as a heating source. Moreover given that the focus is on low-voltage networks we introduce a fully linear AC power flow equations set allowing the planning model to remain tractable. The model is applied to a real-world case study to design a multi-energy multi-microgrid system in an isolated region in Chilean Patagonia. In a case with a zero limit over direct CO2 emissions the total system’s cost increases by 34% with respect to an unconstrained case. In a case with a zero limit over particulate matter emissions the total system’s cost increases by 189%. Finally although an absolute zero limit over both particulate matter and direct CO2 emissions leads to a total system’s cost increase of 650% important benefits in terms of decarbonisation and decontamination can be achieved at marginal cost increments.
An Energy Systems Model of a Large Commercial Liquid Hydrogen Aircraft in a Low-carbon Future
Apr 2023
Publication
Liquid hydrogen (LH2) aircraft have the potential to achieve carbon neutrality. However if the hydrogen is produced using electricity grids that utilise fossil fuel they have a non-zero carbon dioxide (CO2) emission associated with their well-to-wing pathway. To assess the potential of LH2 in aviation decarbonisation an energy systems comparison of large commercial LH2 liquified natural gas (LNG) conventional Jet-A and LH2 dual-fuel aircraft is presented. The performance of each aircraft is compared towards 2050 over which three system changes occur: (1) LH2 aircraft technology develops; (2) both world average and region-specific grid electricity which is used to produce the hydrogen decarbonises; and (3) the International Air Transportation Association (IATA) emissions targets which are used to restrict the passenger-range performance of each aircraft tighten. In 2050 the emissions of all aircraft are thus constrained to 0.063 kg-CO2/p-km relative to 0.110 kg-CO2/p-km for the unconstrained Jet A fuelled Boeing 787-8. It is estimated that in this year an LH2 aircraft powered by fuel cells and sourcing world average electricity can travel 6000 km 20% further than the conventional Jet A aircraft that is also constrained to meet the IATA targets but not as far as the LNG aircraft. At its maximum range the LH2 aircraft carries 84% of the Jet A passenger demand. Analysis using region-specific hydrogen indicates that LH2 aircraft can travel further than LNG aircraft in North America only accounting for 17% of the global demand. 1.59 times the current aviation energy consumption is required if all conventional aircraft are replaced with LH2 designs. Under stricter emissions constraints than those outlined by the IATA LH2 outperforms LNG in Europe and the Americas accounting for 41% of the global demand. Also in these regions the range energy consumption and passenger capacity of LH2 aircraft can be improved upon by combining the advantages of LH2 with LNG in dual-fuel aircraft concepts. The use of LH2 is therefore advantageous within several prominent niches of a future decarbonising aviation system.
Impact of Fuel Production Technologies on Energy Consumption and GHG Emissions from Diesel and Electric–Hydrogen Hybrid Buses in Rio de Janeiro, Brazil
Apr 2023
Publication
In view of the GHG reduction targets to be met Brazilian researchers are looking for cleaner alternatives to energy sources. These alternatives are primarily to be applied in the transport sector which presents high energy consumption as well as high CO2 emissions. In this sense this research developed an LCI study considering two bus alternatives for the city of Rio de Janeiro: diesel-powered internal combustion buses (ICEB) and a hydrogen-powered polymer fuel cell hybrid bus (FCHB). For the FCHB three hydrogen production methods were also included: water electrolysis (WE) ethanol steam reforming (ESR) and natural gas steam reforming (NGSR). The research was aimed at estimating energy consumption including the percentage of energy that is renewable as well as CO2 emissions. The results show diesel as the energy source with the highest emissions as well as the highest fossil energy consumption. Regarding the alternatives for hydrogen production water electrolysis stood out with the lowest emissions.
An Integrated Demand Response Dispatch Strategy for Low-carbon Energy Supply Park Considering Electricity-Hydrogen-Carbon Coordination
Apr 2023
Publication
Driven by the goal of ‘carbon peak carbon neutrality’ an integrated demand response strategy for integrated electricity– hydrogen energy systems is proposed for low-carbon energy supply parks considering the multi-level and multi-energy characteristics of campus-based microgrids. Firstly considering the spatial and temporal complementary nature of wind and photovoltaic generation and energy utilization the energy flow framework of the park is built based on the electricity and hydrogen energy carriers. Clean energy is employed as the main energy supply and power heat cooling and gas loads are considered energy consumption. Secondly the operation mechanism of coupled hydrogen storage hydrogen fuel cell and carbon capture equipment is analyzed in the two-stage power-to-gas conversion process. Thirdly considering the operating costs and environmental costs of the park an integrated demand response dispatch model is constructed for the coupled electricity– hydrogen–carbon system while satisfying the system equipment constraints network constraints and energy balance constraints of the park system. Finally Case study in an energy supply park system is implemented. The dispatch results of the integrated demand response with customer participation in the conventional electricity–hydrogen and electricity–hydrogen–carbon modes are compared to verify the effectiveness of the proposed strategy in renewable accommodation environmental protection and economic benefits.
Review of the Planning and Distribution Methodologies to Locate Hydrogen Infrastructure in the Territory
Jan 2024
Publication
The member countries of the European Union (EU) have prioritized the incorporation of hydrogen as a key component of their energy objectives. As the world moves towards reducing its dependence on fossil fuels alternative sources of energy have gained prominence. With the growing development of Fuel Cell Electric Vehicles (FCEVs) the establishment of an infrastructure for hydrogen production and the creation of a network of service stations have become essential. This article’s purpose is to conduct a methodical review of literature regarding the use of green hydrogen for transportation and the planning of imperative infrastructure in the territory of the EU specifically Hydrogen Refueling Stations (HRS). In order to increase the acceptance of fuel cell vehicles a comprehensive network of hydrogen refueling stations (HRS) must be built that enable drivers to refuel their vehicles quickly and easily similar to gasoline or diesel vehicles. The literature review on this topic was conducted using the Web of Science database (WOS) with a variety of search terms proposed to cover all the key components of green hydrogen production and refueling infrastructure. The implementation of HRS powered by renewable energy sources is an important step in the adoption of fuel cell vehicles and overcoming the obstacles that come with their implementation will require cooperation and innovation from governments private businesses and other stakeholders.
On the Design and Optimization of Distributed Energy Resources for Sustainable Grid-integrated Microgrid in Ethiopia
Apr 2023
Publication
This paper presents a study that focuses on alleviating the impacts of grid outages in Ethiopia. To deal with grid outages most industrial customers utilize backup diesel generators (DG) which are environmentally unfriendly and economically not viable. Grid integration of hybrid renewable energy systems (HRES) might be a possible solution to enhance grid reliability and reduce environmental and economic impacts of utilizing DG. In this study an optimization of grid integrated HRES is carried out for different dispatch and control strategies. The optimal power supply option is determined by performing comparative analysis of the different configurations of grid integrated HRES. The result of the study shows that grid integrated HRES consisting of photovoltaic and wind turbine as renewable energy sources and battery and hydrogen as hybrid energy storage systems is found to be the optimal system to supply the load demand. From the hydrogen produced on-site the FC generator and FCEVs consume 143 620 kg/yr of hydrogen which is equivalent to 394 955 kg/yr gasoline fuel consumption. This corresponds to saving 1 184 865 kg/yr of CO2 emissions and 605 703 $/yr revenue. Besides this system yields 547 035.4 $/yr revenue by injecting excess electricity to the grid. The study clearly shows the economic and environmental viability of this new technology for implementation.
Hydrogen Supply Chain and Refuelling Network Design: Assessment of Alternative Scenarios for the Long-haul Road Freight in the UK
Mar 2023
Publication
Shifting from fossil fuels to clean alternative fuel options such as hydrogen is an essential step in decarbonising the road freight transport sector and facilitating an efficient transition towards zero-emissions goods distribution of the future. Designing an economically viable and competitive Hydrogen Supply Chain (HSC) to support and accelerate the widespread adoption of hydrogen powered Heavy Goods Vehicles (H2-HGVs) is however significantly hindered by the lack of the infrastructure required for producing storing transporting and distributing the required hydrogen. This paper focuses on a bespoke design of a hydrogen supply chain and distribution network for the long-haul road freight transportation in the UK and develops an improved end-to-end and spatially-explicit optimisation tool to perform scenario analysis and provide important first-hand managerial and policy making insights. The proposed methodology improves over existing grid-based methodologies by incorporating spatially-explicit locations of Hydrogen Refuelling Stations (HRSs) and allowing further flexibility and accuracy. Another distinctive feature of the method and the analyses carried out in the paper pertains to the inclusion of bulk geographically agnostic as well as geological underground hydrogen storage options and reporting on significant cost saving opportunities. Finally the curve for H2-HGVs penetration levels safety stock period decisions and the transport mode capacity against hydrogen levelized cost at pump have been generated as important policy making tools to provide decision support and insights into cost resilience and reliability of the HSC.
Low-carbon Planning for Park-level Integrated Energy System Considering Optimal Construction Time Sequence and Hydrogen Energy Facility
Apr 2023
Publication
With the increasing concern about global energy crisis and environmental pollution the integrated renewable energy system has gradually become one of the most important ways to achieve energy transition. In the context of the rapid development of hydrogen energy industry the proportion of hydrogen energy in the energy system has gradually increased. The conversion between various energy sources has also become more complicated which poses challenges to the planning and construction of park-level integrated energy systems (PIES). To solve this problem we propose a bi-level planning model for an integrated energy system with hydrogen energy considering multi-stage investment and carbon trading mechanism. First the mathematical models of each energy source and energy storage in the park are established respectively and the independent operation of the equipment is analyzed. Second considering the operation state of multi-energy coordination a bi-level planning optimization model is established. The upper level is the capacity configuration model considering the variable installation time of energy facilities while the lower level is the operation optimization model considering several typical daily operations. Third considering the coupling relationship between upper and lower models the bi-level model is transformed into a solvable single-level mixed integer linear programming (MILP) model by using Karush–Kuhn–Tucker (KKT) condition and big-M method. Finally the proposed model and solution methods are verified by comprehensive case studies. Simulation results show that the proposed model can reduce the operational cost and carbon emission of PIES in the planning horizon and provide insights for the multi-stage investment of PIES.
Two-Layer Optimization Planning Model for Integrated Energy Systems in Hydrogen Refueling Original Station
May 2023
Publication
With the aggravation of global environmental pollution problems and the need for energy restructuring hydrogen energy as a highly clean resource has gradually become a hot spot for research in countries around the world. Facing the requirement of distributed hydrogen in refueling the original station for hydrogen transportation and other usage this paper proposes a comprehensive energy system planning model for hydrogen refueling stations to obtain the necessary devices construction the devices’ capacity decisions and the optimal operation behaviors of each device. Comparing to traditional single hydrogen producing technics in the traditional planning model the proposed model in this paper integrates both water-electrolysis-based and methanol-based manufacturing technics. A two-level optimization model is designed for this comprehensive system. The result of the numerical study shows that the proposed model can achieve a better optimal solution for distributed hydrogen production. Also it considers the single producing situation when price of one primary resource is sufficient higher than the other.
Influence of Natural Gas and Hydrogen Properties on Internal Combustion Engine Performance, Combustion, and Emissions: A Review
Jan 2024
Publication
This paper provides a comprehensive overview of the physical properties and applications of natural gas (NG) and hydrogen as fuels in internal combustion (IC) engines. The paper also meticulously examines the use of both NG and hydrogen as a fuel in vehicles their production physical characteristics and combustion properties. It reviews the current experimental studies in the literature and investigates the results of using both fuels. It further covers the challenges associated with injectors needle valves lubrication spark plugs and safety requirements for both fuels. Finally the challenges related to the storage production and safety of both fuels are also discussed. The literature review reveals that NG in spark ignition (SI) engines has a clear and direct positive impact on fuel economy and certain emissions notably reducing CO2 and non-methane hydrocarbons. However its effect on other emissions such as unburnt hydrocarbons (UHC) nitrogen oxides (NOx) and carbon monoxide (CO) is less clear. NG which is primarily methane has a lower carbon-to-hydrogen ratio than diesel fuel resulting in lower CO2 emissions per unit of energy released. In contrast hydrogen is particularly well-suited for use in gasoline engines due to its high self-ignition temperature. While increasing the hydrogen content of NG engines reduces torque and power output higher hydrogen input results in reduced fuel consumption and the mitigation of toxic exhaust emissions. Due to its high ignition temperature hydrogen is not inherently suitable for direct use in diesel engines necessitating the exploration of alternative methods for hydrogen introduction into the cylinder. The literature review suggests that hydrogen in diesel engines has shown a reduction in specific exhaust emissions and fuel consumption and an increase in NOx emissions. Overall the paper provides a valuable and informative overview of the challenges and opportunities associated with using hydrogen and NG as fuels in IC engines. It highlights the need for further research and development to address the remaining challenges such as the development of more efficient combustion chambers and the reduction of NOx emissions.
Towards Climate-neutral Aviation: Assessment of Maintenance Requirements for Airborne Hydrogen Storage and Distribution Systems
Apr 2023
Publication
Airlines are faced with the challenge of reducing their environmental footprint in an effort to push for climate-neutral initiatives that comply with international regulations. In the past the aviation industry has followed the approach of incremental improvement of fuel efficiency while simultaneously experiencing significant growth in annual air traffic. With the increase in air traffic negating any reduction in Greenhouse Gas (GHG) emissions more disruptive technologies such as hydrogen-based onboard power generation are required to reduce the environmental impact of airline operations. However despite initial euphoria and first conceptual studies for hydrogen-powered aircraft several decades ago there still has been no mass adoption to this day. Besides the challenges of a suitable ground infrastructure this can partly be attributed to uncertainties with the associated maintenance requirements and the expected operating costs to demonstrate the economic viability of this technology. With this study we address this knowledge gap by estimating changes towards scheduled maintenance activities for an airborne hydrogen storage and distribution system. In particular we develop a detailed system design for a hydrogen-powered fuel-cell-based auxiliary power generation and perform a comparative analysis with an Airbus A320 legacy system. That analysis allows us to (a) identify changes for the expected maintenance effort to enhance subsequent techno-economic assessments (b) identify implications of specific design assumptions with corresponding maintenance activities while ensuring regulatory compliance and (c) describe the impact on the resulting task execution. The thoroughly examined interactions between system design and subsequent maintenance requirements of this study can support practitioners in the development of prospective hydrogen-powered aircraft. In particular it allows the inclusion of maintenance implications in early design stages of corresponding system architectures. Furthermore since the presented methodology is transferable to different design solutions it provides a blueprint for alternative operating concepts such as the complete substitution of kerosene by hydrogen to power the main engines.
Impact of Climate and Geological Storage Potential on Feasibility of Hydrogen Fuels
Apr 2023
Publication
Electrofuels including hydrogen methane and ammonia have been suggested as one pathway in achieving net-zero greenhouse gas energy systems. They can play a role in providing an energy storage and fuel or feedstock to hard-to-abate sectors. In future energy systems their role is often studied in case studies adhering to specific region. In this study we study their role by defining multiple archetypal energy systems which represent approximations of real systems in different regions. Comparing the role of electrofuels across the cost-optimized systems relying only on renewable energy in power generation we found that hydrogen was a significant energy vector in all systems with its annual quantity approaching the classic electricity demand. The role of renewable methane was very limited. Electrofuel storages were needed in all systems and their capacity was the highest in the northern Hemiboreal system. Absence of cavern storage potential did not hamper the significance of electrofuels but increased the role of ammonia and led to average 5.5 % systemic cost increase. Systems where reservoir hydropower was scarce or level of electricity consumption was high needed more fuel storages. The findings of this study can help for better understanding of what kind of storage and generation technologies will be most useful in future carbon-neutral systems in different types of regions.
Hydrogen Consumption and Durability Assessment of Fuel Cell Vehicles in Realistic Driving
Jan 2024
Publication
This study proposes a predictive equivalent consumption minimization strategy (P-ECMS) that utilizes velocity prediction and considers various dynamic constraints to mitigate fuel cell degradation assessed using a dedicated sub-model. The objective is to reduce fuel consumption in real-world conditions without prior knowledge of the driving mission. The P-ECMS incorporates a velocity prediction layer into the Energy Management System. Comparative evaluations with a conventional adaptive-ECMS (A-ECMS) a standard ECMS with a well-tuned constant equivalence factor and a rule-based strategy (RBS) are conducted across two driving cycles and three fuel cell dynamic restrictions (|∕| ≤ 0.1 0.01 and 0.001 A∕cm2 ). The proposed strategy achieves H2 consumption reductions ranging from 1.4% to 3.0% compared to A-ECMS and fuel consumption reductions of up to 6.1% when compared to RBS. Increasing dynamic limitations lead to increased H2 consumption and durability by up to 200% for all tested strategies.
Analysis of CO2 Emissions Reduction on the Future Hydrogen Supply Chain Network for Dubai Buses
Apr 2023
Publication
There is an impetus to decarbonize transportation sector and mitigate climate change. This study examines the effect of adopting hydrogen (H2) as a fuel for Dubai Buses at different penetration scales on carbon dioxide (CO2) emissions reduction. A H2 supply-chain system dynamics model is developed to conduct life cycle cost and environmental analysis and evaluate the efficacy of different carbon prices and subsidies. Gray green and mixed H2 production scenarios were considered. The results show that gray hydrogen reduces 7.1 million tons of CO2 which is half of green hydrogen buses. Replacing diesel fleet at end of lifetime with mixed hydrogen bus fleet was the optimal approach to promote green hydrogen at pump reaching $4/kg in a decade. This gradual transition reduces 62% of the well-to-wheel CO2 emissions of the new bus fleet and creates mass for economies of scale as carbon prices and subsidies cannot promote green hydrogen alone.
Synthetic Fuels in the German Industry Sector Depending on Climate Protection Level
Aug 2021
Publication
Especially the electrification of the industry sector is highly complex and challenging mainly due to process-specific requirements. In this context there are several industrial processes where the direct and indirect use of electricity is subject to technical restrictions. In order to achieve the national climate goals the fossil energy consumption remaining after the implementation of efficiency and sufficiency measures as well as direct electrification has to be substituted through hydrogen and synthetic gaseous liquid and solid hydrocarbons. As the main research object the role of synthetic fuels in industrial transformation paths is investigated and analyzed by combining individual greenhouse gas abatement measures within the Sector Model Industry. Sector Model Industry is an energy consumption model that performs discrete deterministic energy and emission dynamic calculations with a time horizon up to 2050 at macroeconomic level. The results indicate that the use of synthetic fuels can be expected with a high level of climate protection. The industrial CO2 target in the model makes it necessary to replace CO2 -intensive fossil with renewable fuels. The model uses a total of 163 TWh of synthetic fuels in the climate protection scenario and thus achieves an 88% decrease in CO2 emissions in 2050 compared to 1990. This means that the GHG abatement achieved in industry is within the range of the targeted CO2 mitigation of the overall system in Germany of between 80 and 95% in 2050 compared to 1990. Due to technical restrictions the model mainly uses synthetic methane instead of hydrogen (134 TWh). The results show that despite high costs synthetic fuels are crucial for defossilization as a fall back option in the industrial scenario considering high climate ambition. The scenario does not include hydrogen technologies for heat supply. Accordingly the climate protection scenario uses hydrogen only in the steel industry for the direct reduction of iron (21 TWh). 8 TWh of synthetic oil substitute the same amount of fossil oil in the climate protection scenario. A further analysis conducted on the basis of the model results shows that transformation in the energy system and the use of smart ideas concepts and technologies are a basic prerequisite for enabling the holistic defossilisation of industry. The findings in the research can contribute to the cost-efficient use of synthetic fuels in industry and thus serve as a basis for political decision making. Moreover the results may have a practical relevance not only serving as a solid comparison base for the outcome of other studies but also as input data for further simulation of energy system transformation paths.
The Role of Hydrogen for the Defossilization of the German Chemical Industry
Apr 2023
Publication
Within the European Green Deal the European industry is summoned to transform towards a green and circular economy to reduce CO2-emissions and reach climate goals. Special focus is on the chemical industry to boost recycling processes for plastics exploit resource efficiency potentials and switch to a completely renewable feedstock (defossilization). Despite common understanding that drastic changes have to take place it is yet unknown how the industrial transformation should be accomplished. This work explains how a cost-optimal defossilization of the chemical industry in the context of national greenhouse gas (GHG) mitigation strategies look like. The central part of this investigation is based on a national energy system model to optimize the future energy system design of Germany as a case study for a highly industrialized country. A replacement of fossil-based feedstocks by renewable feedstocks leads to a significant increase in hydrogen demand by þ40% compared to a reference scenario. The resulting demand of hydrogen-based energy carriers including the demand for renewable raw materials must be produced domestically or imported. This leads to cumulative additional costs of the transformation that are 32% higher than those of a reference scenario without defossilization of the industry. Fischer-Tropsch synthesis and the methanol-to-olefins route can be identified as key technologies for the defossilization of the chemical industry.
Low Carbon Optimal Operation of Integrated Energy Systems Considering Air Pollution Emissions
Apr 2023
Publication
To reduce carbon sulfur dioxide (SO2) and nitrogen oxide (NOX) emissions from the integrated energy system (IES) a low carbon optimization strategy for the IES is proposed taking into account carbon SO2 and NOX emissions. Firstly hydrogen production storage and use equipment such as methane reactor electrolysis tank hydrogen fuel cell and hydrogen energy storage are added to the traditional IES to build a multi-energy complementary system of electricity gas cooling thermal and hydrogen. Then this paper introduces a stepped carbon trading mechanism and the model of the emissions of SO2 and NOX. Finally to further reduce its pollutant emissions the model of combined heat and power units and hydrogen fuel cells with adjustable thermoelectric ratio is built. To compare and account for the impact of air pollutant emissions on the optimal low-carbon operation of IES this paper construsted three scenarios with the lowest cost of carbon trading the lowest penalty cost for SO2 and NOX emissions and total operation cost as objective functions respectively The results show that the strategy is effective in reducing air pollutant emissions from integrated energy systems and the outputs of CHP and HFC with adjustable thermoelectric ratios are more flexible and can effectively achieve carbon reduction and pollutant emission reduction.
The Fuel Flexibility of Gas Turbines: A Review and Retrospective Outlook
May 2023
Publication
Land-based gas turbines (GTs) are continuous-flow engines that run with permanent flames once started and at stationary pressure temperature and flows at stabilized load. Combustors operate without any moving parts and their substantial air excess enables complete combustion. These features provide significant space for designing efficient and versatile combustion systems. In particular as heavy-duty gas turbines have moderate compression ratios and ample stall margins they can burn not only high- and medium-BTU fuels but also low-BTU ones. As a result these machines have gained remarkable fuel flexibility. Dry Low Emissions combustors which were initially confined to burning standard natural gas have been gradually adapted to an increasing number of alternative gaseous fuels. The paper first delivers essential technical considerations that underlie this important fuel portfolio. It then reviews the spectrum of alternative GT fuels which currently extends from lean gases (coal bed coke oven blast furnace gases . . . ) to rich refinery streams (LPG olefins) and from volatile liquids (naphtha) to heavy hydrocarbons. This “fuel diet” also includes biogenic products (biogas biodiesel and ethanol) and especially blended and pure hydrogen the fuel of the future. The paper also outlines how historically land-based GTs have gradually gained new fuel territories thanks to continuous engineering work lab testing experience extrapolation and validation on the field.
Navigating Turbulence: Hydrogen's Role in the Decarbonization of the Aviation Sector
Jan 2024
Publication
This paper offers a comprehensive analysis of the historical evolution and the current state of the aviation industry with a particular emphasis on the critical need for this sector to decarbonize. It delves into emerging propulsion technologies such as battery electric and hydrogen-based systems assessing their potential impact on sustainability within the aviation sector. Special attention is devoted to the global regulatory framework notably carbon offsetting and emission reduction scheme for international aviation which encapsulates initiatives such as lower carbon aviation fuels and sustainable aviation fuels. Examining the environmental challenges facing aviation the paper underscores the necessity for a balanced and comprehensive strategy that integrates various approaches to achieve sustainable solutions. By addressing both the historical context and contemporary advances the paper aims to provide a nuanced understanding of the complexities surrounding aviation's decarbonization journey acknowledging the industry's strides while recognizing the ongoing challenges in the pursuit of sustainability.
Prediction of Freezing Time During Hydrogen Fueling Using Machine Learning
Nov 2024
Publication
This study presents a method for predicting nozzle surface temperature and the timing of frost formation during hydrogen refueling using machine learning. A continuous refueling system was implemented based on a simulation model that was developed and validated in previous research. Data were collected under various boundary conditions and eight regression models were trained and evaluated for their predictive performance. Hyperparameter optimization was performed using random search to enhance model performance. The final models were validated by applying boundary conditions not used during model development and comparing the predicted values with simulation results. The comparison revealed that the maximum error rate occurred after the second refueling with a value of approximately 4.79%. Currently nitrogen and heating air are used for defrosting and frost reduction which can be costly. The developed machine learning models are expected to enable prediction of both frost formation and defrosting timings potentially allowing for more cost-effective management of defrosting and frost reduction strategies.
Conversion of a Small-Size Passenger Car to Hydrogen Fueling: 0D/1D Simulation of EGR and Related Flow Limitations
Jan 2024
Publication
Hydrogen is seen as a prime choice for complete replacement of gasoline so as to achieve zero-emissions energy and mobility. Combining the use of this alternative fuel with a circular economy approach for giving new life to the existing fleet of passenger cars ensures further benefits in terms of cost competitiveness. Transforming spark ignition (SI) engines to H2 power requires relatively minor changes and limited added components. Within this framework the conversion of a small-size passenger car to hydrogen fueling was evaluated based on 0D/1D simulation. One of the methods to improve efficiency is to apply exhaust gas recirculation (EGR) which also lowers NOx emissions. Therefore the previous version of the quasi-dimensional model was modified to include EGR and its effects on combustion. A dedicated laminar flame speed model was implemented for the specific properties of hydrogen and a purpose-built sub-routine was implemented to correctly model the effects of residual gas at the start of combustion. Simulations were performed in several operating points representative of urban and highway driving. One of the main conclusions was that highpressure recirculation was severely limited by the minimum flow requirements of the compressor. Low-pressure EGR ensured wider applicability and significant improvement of efficiency especially during partial-load operation specific to urban use. Another benefit of recirculation was that pressure rise rates were predicted to be more contained and closer to the values expected for gasoline fueling. This was possible due to the high tolerance of H2 to the presence of residual gas.
Effects of Hydrogen, Methane, and Their Blends on Rapid-Filling Process of High-Pressure Composite Tank
Feb 2024
Publication
Alternative fuels such as hydrogen compressed natural gas and liquefied natural gas are considered as feasible energy carriers. Selected positive factors from the EU climate and energy policy on achieving climate neutrality by 2050 highlighted the need for the gradual expansion of the infrastructure for alternative fuel. In this research continuity equations and the first and second laws of thermodynamics were used to develop a theoretical model to explore the impact of hydrogen and natural gas on both the filling process and the ultimate in-cylinder conditions of a type IV composite cylinder (20 MPa for CNG 35 MPa and 70 MPa for hydrogen). A composite tank was considered an adiabatic system. Within this study based on the GERG-2008 equation of state a thermodynamic model was developed to compare and determine the influence of (i) hydrogen and (ii) natural gas on the selected thermodynamic parameters during the fast-filling process. The obtained results show that the cylinder-filling time depending on the cylinder capacity is approximately 36–37% shorter for pure hydrogen compared to pure methane and the maximum energy stored in the storage tank for pure hydrogen is approximately 28% lower compared to methane whereas the total entropy generation for pure hydrogen is approximately 52% higher compared to pure methane.
The ATHENA Framework: Analysis and Design of a Strategic Hydrogen Refuelling Infrastructure
Apr 2023
Publication
With the pressured timescale in determining effective and viable net zero solutions within the transport sector it is important to understand the extent of implementing a new refuelling infrastructure for alternative fuel such as hydrogen. The proposed ATHENA framework entails three components which encapsulates the demand data analysis an optimisation model in determining the minimal cost hydrogen refuelling infrastructure design and an agent-based model simulating the operational system. As a case study the ATHENA framework is applied to Northern England focusing on the design of a hydrogen refuelling infrastructure for heavy goods vehicles. Analysis is performed in calibrating parameters and investigating different scenarios within the optimisation and agent-based simulation models. For this case study the system optimality is limited by the feasible number of tube trailer deliveries per day which suggests an opportunity for alternative delivery methods.
Low-carbon Economy Dispatching of Integrated Energy System with P2G-HGT Coupling Wind Power Absorption Based on Stepped Carbon Emission Trading
Aug 2023
Publication
To improve the renewable energy consumption capacity of integrated energy system (IES) and reduce the carbon emission level of the system a low-carbon economic dispatch model of IES with coupled power-to-gas (P2G) and hydrogen-doped gas units (HGT) under the stepped carbon trading mechanism is proposed. On the premise of wind power output uncertainty the operating characteristics of the coupled electricity-to-gas equipment in the system are used to improve the wind abandonment problem of IES and increase its renewable energy consumption capacity; HGT is introduced to replace the traditional combustion engine for energy supply and on the basis of refined P2G a part of the volume fraction of hydrogen obtained from the production is extracted and mixed with methane to form a gas mixture for HGT combustion so as to improve the low-carbon economy of the system. The ladder type carbon trading mechanism is introduced into IES to guide the system to control carbon emission behavior and reduce the carbon emission level of IES. Based on this an optimal dispatching strategy is constructed with the economic goal of minimizing the sum of system operation cost wind abandonment cost carbon trading cost and energy purchase cost. After linearization of the established model and comparison analysis by setting different scenarios the wind power utilization rate of the proposed model is increased by 24.5% and the wind abandonment cost and CO2 emission are reduced by 86.3% and 10.5% respectively compared with the traditional IES system which achieves the improvement of renewable energy consumption level and low carbon economy.
A Comparative Environmental Life Cycle Assessment Study of Hydrogen Fuel Electricity and Diesel Fuel for Public Buses
Aug 2023
Publication
Hydrogen fuel and electricity are energy carriers viewed as promising alternatives for the modernization and decarbonization of public bus transportation fleets. In order to choose development pathways that will lead transportation systems toward a sustainable future the authors developed an environmental model based on the Life Cycle Assessment approach. The model tested the impact of energy carrier consumption during driving as well as the electricity origin employed to power electric buses and produce hydrogen. Energy sources such as wind solar waste and grid electricity were investigated. The scope of the study included the life cycles of the energy carrier and the necessary infrastructure. The results were presented from two perspectives: the total environmental impact and global warming potential. In order to create a roadmap an original method for choosing sustainable development pathways was prepared. It was shown that the modernization of conventional bus fleets using hydrogen and electrical pathways can provide significant environmental benefits from both perspectives but especially in terms of global warming potential. It was emphasized that attention should be paid to the use of low- and zero-emission energy sources because their impact often strongly influenced the final environmental judgment. The energy carrier consumption also had a strong impact on the results obtained and that is why efforts should be made to reduce it. In addition it was confirmed that hydrogen and electricity production systems based on electricity generated by a waste-to-energy plant could be an environmentally reasonable dual solution for both sustainable waste management and meeting transport needs.
Enhancing the Risk-oriented Participation of Wind Power Plants in Day-ahead Balancing, and Hydrogen Markets with Shared Multi-energy Storage Systems
Dec 2024
Publication
The increasing demand for renewable energy sources (RES) to address environmental concerns and reduce fossil fuel dependency highlights the need for efficient energy storage and balancing mechanisms to manage RES output uncertainty. However providing dedicated storage units to RES owners is often infeasible. Additionally the growing interest in hydrogen utilization complicates optimal decision-making for multi-energy systems. To tackle these challenges this paper presents a novel bidding strategy enabling wind farms to participate in dayahead balancing and hydrogen markets through shared multi-energy storage (SMES) systems. These SMES which include both battery and hydrogen storage offer a cost-effective solution by allowing RES owners to rent storage capacity. By optimizing SMES utilization and wind farm management we propose an integrated strategy for day-ahead electrical and real-time balancing markets and also hydrogen markets. The approach incorporates with uncertainties of wind generation bidding by using conditional value at risk (CVaR) to account for different risk-aversion levels. The Dantzig–Wolfe Decomposition (DWD) method is applied to decentralize the problem reduce the calculation burden and enhance the data privacy. The framework is modeled as a mixed-integer linear program (MILP) and solved using CPLEX solver via GAMS software. The results demonstrate the effectiveness of this strategy offering insights into the risk-oriented market participation of wind power plants with the aid of SMES system supporting a more sustainable and resilient energy system. The numerical results show that by utilizing a SMES with only batteries the revenue can be increased by 17.3% and equipping the SMES with hydrogen storage and participating in both markets leads to 36.9% increment in the revenue of the wind power plant.
Operation Optimization of Regional Integrated Energy Systems with Hydrogen by Considering Demand Response and Green Certificate–Carbon Emission Trading Mechanisms
Jun 2024
Publication
Amidst the growing imperative to address carbon emissions aiming to improve energy utilization efficiency optimize equipment operation flexibility and further reduce costs and carbon emissions of regional integrated energy systems (RIESs) this paper proposes a low-carbon economic operation strategy for RIESs. Firstly on the energy supply side energy conversion devices are utilized to enhance multi-energy complementary capabilities. Then an integrated demand response model is established on the demand side to smooth the load curve. Finally consideration is given to the RIES’s participation in the green certificate–carbon trading market to reduce system carbon emissions. With the objective of minimizing the sum of system operating costs and green certificate–carbon trading costs an integrated energy system optimization model that considers electricity gas heat and cold coupling is established and the CPLEX solver toolbox is used for model solving. The results show that the coordinated optimization of supply and demand sides of regional integrated energy systems while considering multi-energy coupling and complementarity effectively reduces carbon emissions while further enhancing the economic efficiency of system operations.
Robust Control for Techno-economic Efficiency Energy Management of Fuel Cell Hybrid Electric Vehicles
Apr 2022
Publication
The design of an efficient techno-economic autonomous fuel cell hybrid electric vehicle(FCHEV) is a crucial challenge. This paper investigates the design of a near optimal PI controller for an automated FCHEV where autonomy is expressed as efficient and robust tracking of a given reference speed trajectory without driver’s intervention. An impartial comparison is introduced to illustrate the effectiveness of the proposed metaheuristic-based optimal controllers in enhancing the system dynamic performance. The comprehensive optimization performance indicator is considered as a function of the vehicle dynamic characteristics while determining the optimal controller gains. In this paper the proposed effective up-to-date metaheuristic techniques are the grey wolf optimization (GWO) as well as the artificial bee colony (ABC). Using MATLAB TM /Simulink numerical simulations clearly illustrate the efficiency of near-optimal gains in the optimized tuning methodologies and the fixed manual one in realizing adequate velocity tracking. The simulation results demonstrate the superiority of both ABC and GWO rather than the manual controller for driving cycles of high acceleration and deceleration levels. In absence of these latter the manual defined gain controller is considered sufficient. Through a comprehensive sensitivity analysis the robustness of both metaheuristic-based controllers is verified under diverse driving cycles of different operation features and nature. Despite GWO results in better dynamic characteristics the ABC provides more economical feature with about 1.5% compared to manual system in extra urban driving cycle. However manual-controller has the minimum fuel cost under the United States driving cycle developed by the environmental protection agency as a New York city cycle(US EPA NYCC) and urban driving cycle (ECE). Ecologically electric vehicles have an environmentally friendly effect especially when driven with green hydrogen. Autonomous vehicles involving velocity control systems would raise car share and provide more comfort.
Modelling Methodologies to Design and Control Renewables and Hydrogen-Based Telecom Towers Power Supply Systems
Aug 2023
Publication
Proton exchange membrane fuel cell (PEMFCS) and electrolyser (PEMELS) systems together with a hydrogen storage tank (HST) are suitable to be integrated with renewable microgrids to cover intermittency and fully exploit the excess of electrical energy. Such an integration perfectly fits telecom tower power supply needs both in off-grid and grid-connected sites. In this framework a model-based tool enabling both optimal sizing and proper year-through energy management of both the above applications is proposed. Respectively the islanded optimisation is performed considering two economic indices i.e. simple payback (SPB) and levelised cost of energy (LCOE) together with two strategies of hydrogen tank management charge sustaining and depleting and also accounting for the impact of grid extension distance. On the other hand the grid connection is addressed through the dynamic programming method while downsizing PEMELS and HST sizes to improve techno-economic effectiveness thanks to grid contribution towards renewables curtailment issues mitigation. For both the above introduced HST management strategies a reduction of more than 70% of the nominal PEMELS power and 90% of the HST size which will in turn lead to SPB and LCOE being reduced by 80% and 60% in comparison to the islanded case respectively is achieved. Furthermore the charge depleting strategy relying on possible hydrogen purchase interestingly provides an SPB and LCOE of 9% and 7% lower than the charge sustaining one.
Knock Mitigation and Power Enhancement of Hydrogen Spark-Ignition Engine through Ammonia Blending
Jun 2023
Publication
Hydrogen and ammonia are primary carbon-free fuels that have massive production potential. In regard to their flame properties these two fuels largely represent the two extremes among all fuels. The extremely fast flame speed of hydrogen can lead to an easy deflagration-to-detonation transition and cause detonation-type engine knock that limits the global equivalence ratio and consequently the engine power. The very low flame speed and reactivity of ammonia can lead to a low heat release rate and cause difficulty in ignition and ammonia slip. Adding ammonia into hydrogen can effectively modulate flame speed and hence the heat release rate which in turn mitigates engine knock and retains the zero-carbon nature of the system. However a key issue that remains unclear is the blending ratio of NH3 that provides the desired heat release rate emission level and engine power. In the present work a 3D computational combustion study is conducted to search for the optimal hydrogen/ammonia mixture that is knock-free and meanwhile allows sufficient power in a typical spark-ignition engine configuration. Parametric studies with varying global equivalence ratios and hydrogen/ammonia blends are conducted. The results show that with added ammonia engine knock can be avoided even under stoichiometric operating conditions. Due to the increased global equivalence ratio and added ammonia the energy content of trapped charge as well as work output per cycle is increased. About 90% of the work output of a pure gasoline engine under the same conditions can be reached by hydrogen/ammonia blends. The work shows great potential of blended fuel or hydrogen/ammonia dual fuel in high-speed SI engines.
A Rigorous Optimization Method for Long-term Multi-stage Investment Planning: Integration of Hydrogen into a Decentralized Multi-energy System
Dec 2024
Publication
Thoroughly assessing future energy systems requires examining both their end states and the paths leading to them. Employing dynamic investment or multi-stage optimization models is crucial for this analysis. However solving these optimization problems becomes increasingly challenging due to their long time horizons – often spanning several decades – and their dynamic nature. While simplifications like aggregations are often used to expedite solving procedures they introduce higher uncertainty into the results and might lead to suboptimal solutions compared to non-simplified models. Against this background this paper presents a rigorous optimization method tailored for multi-stage optimization problems in long-term energy system planning. By dividing the solution algorithm into a design and operational optimization step the proposed method efficiently finds feasible solutions for the non-simplified optimization problem with simultaneous quality proof. Applied to a real-life energy system of a waste treatment plant in Germany the method significantly outperforms a benchmark solver by reducing the computational time to find the first feasible solution from more than two weeks to less than one hour. Furthermore it exhibits greater robustness compared to a conventional long-term optimization approach and yields solutions closer to the optimum. Overall this method offers decision-makers computationally efficient and reliable information for planning investment decisions in energy systems.
Evaluation of Hydrogen Addition on Combustion and Emission Characteristics of Dual-Fuel Diesel Engines with Different Compression Ratios
Sep 2023
Publication
In this paper a computational fluid dynamics (CFD) model was established and verified on the basis of experimental results and then the effect of hydrogenation addition on combustion and emission characteristics of a diesel–hydrogen dual-fuel engine fueled with hydrogenation addition (0% 5% and 10%) under different hydrogenation energy shares (HESs) and compression ratios (CRs) were investigated using CONVERGE3.0 software. And this work assumed that the hydrogen and air were premixed uniformly. The correctness of the simulation model was verified by experimental data. The values of HES are in the range of 0% 5% 10% and 15%. And the values of CR are in the range of 14 16 18 and 20. The results of this study showed that the addition of hydrogen to diesel fuel has a significant effect on the combustion characteristics and the emission characteristics of diesel engines. When the HES was 15% the in-cylinder pressure increased by 10.54%. The in-cylinder temperature increased by 15.11%. When the CR was 20 the in-cylinder pressure and the in-cylinder temperature increased by 66.10% and 13.09% respectively. In all cases HC CO CO2 and soot emissions decreased as the HES increased. But NOx emission increased.
Carbon Footprint Enhancement of an Agricultural Telehandler through the Application of a Fuel Cell Powertrain
Mar 2024
Publication
The growing awareness about climate change and environmental pollution is pushing the industrial and academic world to investigate more sustainable solutions to reduce the impact of anthropic activities. As a consequence a process of electrification is involving all kind of vehicles with a view to gradually substitute traditional powertrains that emit several pollutants in the exhaust due to the combustion process. In this context fuel cell powertrains are a more promising strategy with respect to battery electric alternatives where productivity and endurance are crucial. It is important to replace internal combustion engines in those vehicles such as the those in the sector of NonRoad Mobile Machinery. In the present paper a preliminary analysis of a fuel cell powertrain for a telehandler is proposed. The analysis focused on performance fuel economy durability applicability and environmental impact of the vehicle. Numerical models were built in MATLAB/Simulink and a simple power follower strategy was developed with the aim of reducing components degradation and to guarantee a charge sustaining operation. Simulations were carried out regarding both peak power conditions and a typical real work scenario. The simulations’ results showed that the fuel cell powertrain was able to achieve almost the same performances without excessive stress on its components. Indeed a degradation analysis was conducted showing that the fuel cell system can achieve satisfactory durability. Moreover a Well-to-Wheel approach was adopted to evaluate the benefits in terms of greenhouse gases of adopting the fuel cell system. The results of the analysis demonstrated that even if considering grey hydrogen to feed the fuel cell system the proposed powertrain can reduce the equivalent CO2 emissions of 69%. This reduction can be further enhanced using hydrogen from cleaner production processes. The proposed preliminary analysis demonstrated that fuel cell powertrains can be a feasible solution to substitute traditional systems on off-road vehicles even if a higher investment cost might be required.
The Transition to a Renewable Energy Electric Grid in the Caribbean Island Nation of Antigua and Barbuda
Aug 2023
Publication
The present study describes the development and application of a model of the national electricity system for the Caribbean dual-island nation of Antigua and Barbuda to investigate the cost optimal mix of solar photovoltaics (PVs) wind and in the most novel contribution concentrating solar power (CSP). These technologies together with battery and hydrogen energy storage can enable the aim of achieving 100% renewable electricity and zero carbon emissions. The motivation for this study was that while most nations in the Caribbean rely largely on diesel fuel or heavy fuel oil for grid electricity generation many countries have renewable resources beyond wind and solar energy. Antigua and Barbuda generates 93% of its electricity from diesel-fueled generators and has set the target of becoming a net-zero nation by 2040 as well as having 86% renewable energy generation in the electricity sector by 2030 but the nation has no hydroelectric or geothermal resources. Thus this study aims to demonstrate that CSP is a renewable energy technology that can help assist Antigua and Barbuda in its transition to a renewable energy electric grid while also decreasing electricity generation costs. The modeled optimal mix of renewable energy technologies presented here was found for Antigua and Barbuda by assessing the levelized cost of electricity (LCOE) for systems comprising various combinations of energy technologies and storage. Other factors were also considered such as land use and job creation. It was found that 100% renewable electricity systems are viable and significantly less costly than current power systems and that there is no single defined pathway towards a 100% renewable energy grid but several options are available.
Predictive Maintenance and Reinspection Strategies for Hydrogen Refueling Station Pressure Vessels: A Case Study in South Korea
Jul 2024
Publication
Hydrogen refueling stations rely on pressure vessels capable of withstanding pressures up to 90 MPa while mitigating concerns related to hydrogen embrittlement. However a gap exists in understanding the long-term fatigue behavior of these vessels under real operational conditions. This study focuses on evaluating the safety of SA372 pressure vessels using operational data from a hydrogen refueling station in Pyeongtaek South Korea. A predictive reinspection methodology is proposed based on this evaluation. Parameters including hydrogen-induced stress intensity factor (KIH) initial crack size (a0 c0) and pressure vessel specifications are considered to assess critical crack depth (ac) critical usage cycles (Nc) and allowable usage cycles (Nallowed). Leveraging operational data collected between August and November 2023 fatigue analysis and Rainflow counting inform reinspection schedules. Results indicate a need for mid-bank vessel reinspection within the second year high-bank vessel reinspection every 20 years and low-bank vessel reinspection every 143 years in accordance with safety regulations. Additionally a revised refueling logic is proposed to optimize vehicle charging methods and pressure ranges enhancing operational safety. This study serves as a preliminary investigation highlighting the need for broader data collection and analysis to generalize findings across multiple stations.
Current Status and Economic Analysis of Green Hydrogen Energy Industry Chain
Feb 2024
Publication
Under the background of the power system profoundly reforming hydrogen energy from renewable energy as an important carrier for constructing a clean low-carbon safe and efficient energy system is a necessary way to realize the objectives of carbon peaking and carbon neutrality. As a strategic energy source hydrogen plays a significant role in accelerating the clean energy transition and promoting renewable energy. However the cost and technology are the two main constraints to green hydrogen energy development. Herein the technological development status and economy of the whole industrial chain for green hydrogen energy “production-storage-transportation-use” are discussed and reviewed. After analysis the electricity price and equipment cost are key factors to limiting the development of alkaline and proton exchange membrane hydrogen production technology; the quantity scale and distance of transportation are key to controlling the costs of hydrogen storage and transportation. The application of hydrogen energy is mainly concentrated in the traditional industries. With the gradual upgrading and progress of the top-level design and technology the application of hydrogen energy mainly including traffic transportation industrial engineering energy storage power to gas and microgrid will show a diversified development trend. And the bottleneck problems and development trends of the hydrogen energy industry chain are also summarized and viewed.
Low-carbon Economic Operation of IES Based on Life Cycle Method and Hydrogen Energy Utilization
Aug 2023
Publication
The Integrated Energy System (IES) that coordinates multiple energy sources can effectively improve energy utilization and is of great significance to achieving energy conservation and emission reduction goals. In this context a low-carbon and economic dispatch model for IES is proposed. Firstly a hydrogen energy-based IES (H2-IES) is constructed to refine the utilization process of hydrogen energy. Secondly the carbon emissions of different energy chains throughout their life cycle are analyzed using the life cycle assessment method (LCA) and the carbon emissions of the entire energy supply and demand chain are considered. Finally a staged carbon trading mechanism is adopted to promote energy conservation and emission reduction. Based on this an IES low-carbon and economic dispatch model is constructed with the optimization goal of minimizing the sum of carbon trading costs energy procurement costs and hydrogen sales revenue while considering network constraints and constraints on key equipment. By analyzing the model under different scenarios the introduction of life cycle assessment staged carbon trading and hydrogen energy utilization is shown to promote low-carbon and economic development of the comprehensive energy system.
The Role of Hydrogen-based Power Systems in the Energy Transition of the Residential Sector
Sep 2021
Publication
The unsustainable and continuous growth of anthropogenic emissions of greenhouse gases (GHG) has pushed governments private companies and stakeholders to adopt measures and policies to fight against climate change. Within this framework increasing the contribution of renewable energy sources (RES) to final consumed energy plays a key role in the planned energy transition. Regarding the residential sector in Europe 92% of GHG emissions comes from 75% of the building stock that is over 25 years old and highly inefficient. Thus this sector must raise RES penetration from the current 36% to 77% by 2050 to comply with emissions targets. In this regard the hybridization of hydrogen-based technologies and RES represents a reliable and versatile solution to facilitate decarbonization of the residential sector. This study provides an overview and analysis of standalone renewable hydrogen-based systems (RHS) focusing on the residential and buildings sector as well as critical infrastructures like telecom stations data servers etc. For detailed evaluation of RHS several pilot plants and real demonstration plants implemented worldwide are reviewed. To this end a techno-economic assessment of relevant parameters like self-sufficiency ratio levelized cost of energy and hydrogen roundtrip efficiency is provided. Moreover the performance of the different configurations is evaluated by comparing the installed power of each component and their energy contribution to cover the load over a defined period of time. Challenges ahead are identified for the wider deployment of RHS in the residential and buildings sector.
Sustainable Fuel Production Using In-situ Hydrogen Supply via Aqueous Phase Reforming: A Techno-economic and Life-cycle Greenhouse Gas Emissions Assessment
Jul 2023
Publication
Sustainable aviation fuel (SAF) production is one of the strategies to guarantee an environmental-friendly development of the aviation sector. This work evaluates the technical economic and environmental feasibility of obtaining SAFs by hydrogenation of vegetable oils thanks to in-situ hydrogen production via aqueous phase reforming (APR) of glycerol by-product. The novel implementation of APR would avoid the environmental burden of conventional fossil-derived hydrogen production as well as intermittency and storage issues related to the use of RES-based (renewable energy sources) electrolysers. The conceptual design of a conventional and advanced (APR-aided) biorefinery was performed considering a standard plant capacity equal to 180 ktonne/y of palm oil. For the advanced scenario the feed underwent hydrolysis into glycerol and fatty acids; hence the former was subjected to APR to provide hydrogen which was further used in the hydrotreatment reactor where the fatty acids were deoxygenated. The techno-economic results showed that APR implementation led to a slight increase of the fixed capital investment by 6.6% compared to the conventional one while direct manufacturing costs decreased by 22%. In order to get a 10% internal rate of return the minimum fuel selling price was found equal to 1.84 $/kg which is 17% lower than the one derived from conventional configurations (2.20 $/kg). The life-cycle GHG emission assessment showed that the carbon footprint of the advanced scenario was equal to ca. 12 g CO2/MJSAF i.e. 54% lower than the conventional one (considering an energy-based allocation). The sensitivity analysis pointed out that the cost of the feedstock SAF yield and the chosen plant size are keys parameters for the marketability of this biorefinery while the energy price has a negligible impact; moreover the source of hydrogen has significant consequences on the environmental footprint of the plant. Finally possible uncertainties for both scenarios were undertaken via Monte Carlo simulations.
Climate Change Mitigation Potentials of on Grid-connected Power-to-X Fuels and Advanced Biofuels for the European Maritime Transport
Jul 2023
Publication
This study proposes a country-based life-cycle assessment (LCA) of several conversion pathways related 10 to both on grid-connected Power-to-X (PtX) fuels and advanced biofuel production for maritime transport 11 in Europe. We estimate the biomass resource availability (both agricultural and forest residues and 12 second-generation energy crops from abandoned cropland) electricity mix and a future-oriented 13 prospective LCA to assess how future climate change mitigation policies influence the results. Our results 14 indicate that the potential of PtX fuels to achieve well-to-wake greenhouse gas intensities lower than 15 those of fossil fuels is limited to countries with a carbon intensity of the electricity mix below 100 gCO2eq kWh-1 16 . The more ambitious FuelEU Maritime goal could be achieved with PtX only if connected to electricity sources below ca. 17 gCO2eq kWh-1 17 which can become possible for most of the national 18 electricity mix in Europe by 2050 if renewable energy sources will become deployed at large scales. For 19 drop-in and hydrogen-based biofuels biomass residues have a higher potential to reduce emissions than 20 dedicated energy crops. In Europe the potentials of energy supply from all renewable and low-carbon 21 fuels (RLFs) range from 32-149% of the current annual fuel consumption in European maritime transport. 22 The full deployment of RLFs with carbon capture and storage technologies could mitigate up to 184% of 23 the current well-to-wake shipping emissions in Europe. Overall our study highlights how the strategic use 24 of both hydrogen-based biofuels and PtX fuels can contribute to the climate mitigation targetsfor present 25 and future scenarios of European maritime transport.
Investigations on Pressure Dependence of Coriolis Mass Flow Meters Used at Hydrogen Refueling Stations
Sep 2020
Publication
In the framework of the ongoing EMPIR JRP 16ENG01 ‘‘Metrology for Hydrogen Vehicles’’ a main task is to investigate the influence of pressure on the measurement accuracy of Coriolis Mass Flow Meters (CFM) used at Hydrogen Refueling Stations (HRS). At a HRS hydrogen is transferred at very high and changing pressures with simultaneously varying flow rates and temperatures. It is clearly very difficult for CFMs to achieve the current legal requirements with respect to mass flow measurement accuracy at these measurement conditions. As a result of the very dynamic filling process it was observed that the accuracy of mass flow measurement at different pressure ranges is not sufficient. At higher pressures it was found that particularly short refueling times cause significant measurement deviations. On this background it may be concluded that pressure has a great impact on the accuracy of mass flow measurement. To gain a deeper understanding of this matter RISE has built a unique high-pressure test facility. With the aid of this newly developed test rig it is possible to calibrate CFMs over a wide pressure and flow range with water or base oils as test medium. The test rig allows calibration measurements under the conditions prevailing at a 70 MPa HRS regarding mass flows (up to 3.6 kg min−1) and pressures (up to 87.5 MPa).
The Role of Power-to-hydrogen in Carbon Neutral Energy and Industrial Systems: Case Finland
Aug 2023
Publication
To combat climate change decarbonization measures are undertaken across the whole energy sector. Industry and transportation sectors are seen as difficult sectors to decarbonize with green hydrogen being proposed as a solution to achieve decarbonization in these sectors. While many methods of introducing hydrogen to these sectors are present in literature few systemlevel works study the specific impacts of large-scale introduction has on power and heat sectors in an energy system. This contribution examines the effects of introducing hydrogen into a Finnish energy system in 2040 by conducting scenario simulations in EnergyPLAN – software. Primary energy consumption and CO2 emissions of the base scenario and hydrogen scenarios are compared. Additionally the differences between a constant and flexible hydrogen production profile are studied. Introducing hydrogen increases electricity consumption by 31.9 % but reduces CO2 emissions by 71.5 % and fossil energy consumption by 72.6%. The flexible hydrogen profile lowers renewable curtailment and improves energy efficiency but requires economically unfeasible hydrogen storage. Biomass consumption remains high and is not impacted significantly by the introduction of hydrogen. Additional measures in other sectors are needed to ensure carbon neutrality.
Low Platinum Fuel Cell as Enabler for the Hydrogen Fuel Cell Vehicle
Feb 2024
Publication
In this work the design and modeling of a fuel cell vehicle using low-loading platinum catalysts were investigated. Data from single fuel cells with low Pt-loading cathode catalysts were scaled up to fuel cell stacks and systems implemented in a vehicle and then compared to a commercial fuel cell vehicle. The low-loading Pt systems have shown lower efficiency at high loads compared to the commercial systems suggesting less stable materials. However the analysis showed that the vehicle comprising low-loading Pt catalysts achieves similar or higher efficiency compared to the commercial fuel cell vehicle when being scaled up for the same number of cells. When the systems were scaled up for the same maximum power as the commercial fuel cell vehicle all the low-loading Pt fuel cell systems showed higher efficiencies. In this case more cells are needed but still the amount of Pt is significantly reduced compared to the commercial one. The high-efficiency results can be associated with the vehicle’s power range operation that meets the region where the low-loading Pt fuel cells have high performance. The results suggested a positive direction towards the reduction of Pt in commercial fuel cell vehicles supporting a cost-competitive clean energy transition based on hydrogen.
Investigating the Future of Freight Transport Low Carbon Technologies Market Acceptance across Different Regions
Oct 2024
Publication
Fighting climate change has become a major task worldwide. One of the key energy sectors to emit greenhouse gases is transportation. Therefore long term strategies all over the world have been set up to reduce on-road combustion emissions. In this context the road freight sector faces significant challenges in decarbonization driven by its limited availability of low-emission fuels and commercialized zero-emission vehicles compared with its high energy demand. In this work we develop the Mobility and Energy Transportation Analysis (META) Model a python-based optimization model to quantify the impact of transportation projected policies on freight transport by projecting conventional and alternative fuel technologies market acceptance as well as greenhouse gas (GHG) emissions. Along with introducing e-fuels as an alternative refueling option for conventional vehicles META investigates the market opportunities of Mobile Carbon Capture (MCC) until 2050. To accurately assess this technology a techno-economic analysis is essential to compare MCC abatement cost to alternative decarbonization technologies such as electric trucks. The novelty of this work comes from the detailed cost categories taken into consideration in the analysis including intangible costs associated with heavy-duty technologies such as recharging/refueling time cargo capacity limitations and consumer acceptance towards emerging technologies across different regions. Based on the study results the competitive total cost of ownership (TCO) and marginal abatement cost (MAC) values of MCC make it an economically promising alternative option to decarbonize the freight transport sector. Both in the KSA and EU MCC options could reach greater than 50% market shares of all ICE vehicle sales equivalent to a combined 35% of all new sales shares by 2035.
Economic Prospects of Taxis Powered by Hydrogen Fuel Cells in Palestine
Feb 2024
Publication
Recently major problems related to fuel consumption and greenhouse gas (GHG) emissions have arisen in the transportation sector. Therefore developing transportation modes powered by alternative fuels has become one of the main targets for car manufacturers and governments around the world. This study aimed to investigate the economic prospects of using hydrogen fuel cell technology in taxi fleets in Westbank. For this purpose a model that could predict the number of taxis was developed and the expected economic implications of using hydrogen fuel cell technology in taxi fleets were determined based on the expected future fuel consumption and future fuel cost. After analysis of the results it was concluded that a slight annual increase in the number of taxis in Palestine is expected in the future due to the government restrictions on issuing new taxi permits in order to get this sector organized. Furthermore using hydrogen fuel cells in taxi fleets is expected to become more and more feasible over time due to the expected future increase in oil price and the expected significant reduction in hydrogen cost as a result of the new technologies that are expected to be used in the production and handling of hydrogen.
Subcooled Liquid Hydrogen Technology for Heavy-Duty Trucks
Jan 2024
Publication
Subcooled liquid hydrogen (sLH2) is an onboard storage as well as a hydrogen refueling technology that is currently being developed by Daimler Truck and Linde to boost the mileage of heavy-duty trucks while also improving performance and reducing the complexity of hydrogen refueling stations. In this article the key technical aspects advantages challenges and future developments of sLH2 at vehicle and infrastructure levels will be explored and highlighted.
Decarbonizing Combustion with Hydrogen Blended Fuels: An Exploratory Study of Impact of Hydrogen on Hydrocarbon Autoignition
Jan 2024
Publication
Blending hydrogen to existing fuel mix represents a major opportunity for decarbonisation. One important consideration for this application is the chemical interaction between hydrogen and hydrocarbon fuels arising from their different combustion chemistries and varying considerably with combustion processes. This paper conducted an exploratory study of hydrogen’s impact on autoignition in several combustion processes where hydrogen is used as a blending component or the main fuel. Case studies are presented for spark ignition engines (H2/natural gas) compression ignition engines (H2/diesel) moderate or intense low-oxygen dilution (MILD) combustors (H2/natural gas) and rotational detonation engines (H2/natural gas). Autoignition reactivity as a function of the hydrogen blending level is investigated numerically using the ignition delay iso-contours and state-of-the-art kinetic models at time scales representative of each application. The results revealed drastically different impact of hydrogen blending on autoignition due to different reaction temperature pressure and time scale involved in these applications leaving hydrocarbon interacting with hydrogen at different ignition branches where the negative pressure/temperature dependency of oxidation kinetics could take place. The resulted non-linear and at times non-monotonic behaviours indicate a rich topic for combustion chemistry and also demonstrates ignition delay iso-contour as a useful tool to scope autoignition reactivity for a wide range of applications.
Towards Energy Freedom: Exploring Sustainable Solutions for Energy Independence and Self-sufficiency using Integrated Renewable Energy-driven Hydrogen System
Jan 2024
Publication
n the pursuit of sustainable energy solutions the integration of renewable energy sources and hydrogen technologies has emerged as a promising avenue. This paper introduces the Integrated Renewable Energy-Driven Hydrogen System as a holistic approach to achieve energy independence and self-sufficiency. Seamlessly integrating renewable energy sources hydrogen production storage and utilization this system enables diverse applications across various sectors. By harnessing solar and/or wind energy the Integrated Renewable EnergyDriven Hydrogen System optimizes energy generation distribution and storage. Employing a systematic methodology the paper thoroughly examines the advantages of this integrated system over other alternatives emphasizing its zero greenhouse gas emissions versatility energy resilience and potential for large-scale hydrogen production. Thus the proposed system sets our study apart offering a distinct and efficient alternative compared to conventional approaches. Recent advancements and challenges in hydrogen energy are also discussed highlighting increasing public awareness and technological progress. Findings reveal a payback period ranging from 2.8 to 6.7 years depending on the renewable energy configuration emphasizing the economic attractiveness and potential return on investment. This research significantly contributes to the ongoing discourse on renewable energy integration and underscores the viability of the Integrated Renewable EnergyDriven Hydrogen System as a transformative solution for achieving energy independence. The employed model is innovative and transferable to other contexts.
Techno-economic Feasibility of Distributed Waste-to-hydrogen Systems to Support Green Transport in Glasgow
Mar 2022
Publication
Distributed waste-to-hydrogen (WtH) systems are a potential solution to tackle the dual challenges of sustainable waste management and zero emission transport. Here we propose a concept of distributed WtH systems based on gasification and fermentation to support hydrogen fuel cell buses in Glasgow. A variety of WtH scenarios were configured based on biomass waste feedstock hydrogen production reactors and upstream and downstream system components. A cost-benefit analysis (CBA) was conducted to compare the economic feasibility of the different WtH systems with that of the conventional steam methane reforming-based method. This required the curation of a database that included inter alia direct cost data on construction maintenance operations infrastructure and storage along with indirect cost data comprising environmental impacts and externalities cost of pollution carbon taxes and subsidies. The levelized cost of hydrogen (LCoH) was calculated to be 2.22 GB P/kg for municipal solid waste gasification and 2.02 GB P/kg for waste wood gasification. The LCoHs for dark fermentation and combined dark and photo fermentation systems were calculated to be 2.15 GB P/kg and 2.29 GB P/kg. Sensitivity analysis was conducted to identify the most significant influential factors of distributed WtH systems. It was indicated that hydrogen production rates and CAPEX had the largest impact for the biochemical and thermochemical technologies respectively. Limitations including high capital expenditure will require cost reduction through technical advancements and carbon tax on conventional hydrogen production methods to improve the outlook for WtH development.
Industrial and Academic Collaboration Strategies on Hydrogen Fuel Cell Technology Development in Malaysia
Nov 2013
Publication
Hydrogen fuel cells are electrochemical power generators of high conversion efficiency and incredibly clean operation. Throughout the world the growth of fuel cell research and application has been very rapid in the last ten years where successful pilot projects on many areas have been implemented. In Malaysia approximately RM40 million has been granted to academic research institutions for fuel cell study and development. Recently Malaysia saw the emergence of its first hydrogen fuel cell developer signaling the readiness of the industrial sector to be involved in marketing the potential of fuel cells. Focusing mainly on Polymer Electrolyte Membrane fuel cell technology this paper demonstrates the efforts by Malaysian institutions both industrial and academic to promote hydrogen fuel cell education training application R&D as well as technology transfer. Emphasis is given to the existing collaboration between G-Energy Technologies and UniversitiTeknologi MARA that culminates with the successful application of a locally developed fuel cell system for a single-seated vehicle. Briefs on the potential of realizing a large-scale utilization of this clean technology into Malaysia’s mainstream power industry domestic consumers and energy consuming industries is also discussed. Key challenges are also identified where pilot projects government policy and infrastructural development is central to strengthen the prospect of hydrogen fuel cell implementation in Malaysia.
Dual Fuel-based Multi-Energy System for Australian Renewable Energy Zones at Country Scale
Jul 2025
Publication
This paper aims to optimize dual-fuel facilitated off-/on-grid multi-energy systems (MESs) for different renewable energy zones (REZs) in Australia. The main objective is to develop a novel MES with the main feature of green hydrogen production and blended natural gas utilization for remote households. The proposed optimal system produces green hydrogen of 5343 kg/yr via proton exchange membrane (PEM) electrolyzer and blends it with natural gas. It involves 20 % hydrogen and 80 % natural gas in the overall volume of the blending process. This study contributes by performing optimal sizing of the components economic-energy-environmental and performance analyses to examine the most feasible solution for each REZ. The results indicate that the optimal system in North Queensland REZ has the lowest levelized cost of energy (LCE) of 1.28 A$/kWh and 0.1003 A $/kWh and the net present cost (NPC) of A$0.311 million and A$0.219 million for off-grid and on-grid configurations. The optimal on-grid system has 95.27 % less carbon emissions than the natural gas-fueled combustion energy system.
A Review of Liquid Hydrogen Aircraft and Propulsion Technologies
Jan 2024
Publication
Sustainable aviation is a key part of achieving Net Zero by 2050 and is arguably one of the most challenging sectors to decarbonise. Hydrogen has gained unprecedented attention as a future fuel for aviation for use within fuel cell or hydrogen gas turbine propulsion systems. This paper presents a survey of the literature and industrial projects on hydrogen aircraft and associated enabling technologies. The current and predicted technology capabilities are analysed to identify important trends and to assess the feasibility of hydrogen propulsion. Several key enabling technologies are discussed in detail and gaps in knowledge are identified. It is evident that hydrogen propelled aircraft are technologically viable by 2050. However convergence of a number of critical factors is required namely: the extent of industrial collaboration the understanding of environmental science and contrails green hydrogen production and its availability at the point of use and the safety and certification of the aircraft and supporting infrastructure.
Lab-Scale Investigation of the Integrated Backup/Storage System for Wind Turbines Using Alkaline Electrolyzer
Apr 2023
Publication
The depletion of fossil fuel sources has encouraged the authorities to use renewable resources such as wind energy to generate electricity. A backup/storage system can improve the performance of wind turbines due to fluctuations in power demand. The novelty of this study is to utilize a hybrid system for a wind farm using the excess electricity generated by the wind turbines to produce hydrogen in an alkaline electrolyzer (AEL). The hydrogen storage tank stores the produced hydrogen and provides hydrogen to the proton-exchange membrane fuel cell (PEMFC) to generate electricity once the power demand is higher than the electricity generated by the wind turbines. The goal of this study is to use the wind profile of a region in Iran namely the Cohen region to analyze the performance of the suggested integrated system on a micro scale. The output results of this study can be used as a case study for construction in the future based on the exact specification of NTK300 wind turbines. The results indicate that with the minimum power supply of 30 kW from the wind turbines on a lab scale the generated power by the PEMFC will be 1008 W while the maximum generated hydrogen will be 304 mL/h.
Explaining Varying Speeds of Low-carbon Reorientation in the United Kingdom's Steel, Petrochemical, and Oil Refining Industries: A Multi-dimensional Comparative Analysis and Outlook
Feb 2024
Publication
Accelerated decarbonisation of steelmaking oil refining and petrochemical industries is essential for climate change mitigation. Drawing on three longitudinal case studies of these industries in the UK this synthesis article makes a comparative analysis of their varying low-carbon reorientation speeds. The paper uses the triple embeddedness framework to analyse five factors (policy support international competition financial health technical feasibility corporate strategy and mindset) that explain why UK oil refineries have in recent years been comparatively the fastest in their low-carbon reorientation and UK steelmakers the slowest. We find that policy support has been more beneficial for refining and petrochemicals than for steel although recent government deals with steelmakers addressed this imbalance. International competition has been high for steel and petrochemicals and comparatively lower for refining (meaning that decarbonisation costs are less detrimental for international competitiveness). Financial performance has comparatively been worst for steel and best for oil refining which shapes the economic feasibility of low-carbon options. Hydrogen and carbon-capture-and-storage are technologically feasible for refining and petrochemicals while Electric Arc Furnaces are technically feasible for steelmakers but face wider feasibility problems (with scrap steel supply electricity grids and electricity prices) which is why we question the recent government deals. Corporate strategy and perceptions changed in oil refining with firms seeing economic opportunities in decarbonisation while steelmakers and petrochemical firms still mostly see decarbonisation as a burden and threat. The paper ends with comparative conclusions a discussion of political considerations and future outlooks for the three UK industries policy and research.
Prospects of Hydrogen Application as a Fuel for Large-Scale Compressed-Air Energy Storages
Jan 2024
Publication
A promising method of energy storage is the combination of hydrogen and compressed-air energy storage (CAES) systems. CAES systems are divided into diabatic adiabatic and isothermal cycles. In the diabatic cycle thermal energy after air compression is discharged into the environment and the scheme implies the use of organic fuel. Taking into account the prospects of the decarbonization of the energy industry it is advisable to replace natural gas in the diabatic CAES scheme with hydrogen obtained by electrolysis using power-to-gas technology. In this article the SENECA-1A project is considered as a high-power hybrid unit using hydrogen instead of natural gas. The results show that while keeping the 214 MW turbines powered the transition to hydrogen reduces carbon dioxide emissions from 8.8 to 0.0 kg/s while the formation of water vapor will increase from 17.6 to 27.4 kg/s. It is shown that the adiabatic CAES SENECA-1A mode compared to the diabatic has 0.0 carbon dioxide and water vapor emission with relatively higher efficiency (71.5 vs. 62.1%). At the same time the main advantage of the diabatic CAES is the possibility to produce more power in the turbine block (214 vs. 131.6 MW) having fewer capital costs. Thus choosing the technology is a subject of complex technical economic and ecological study.
Hydrogen-Powered Vehicles: Comparing the Powertrain Efficiency and Sustainability of Fuel Cell versus Internal Combustion Engine Cars
Feb 2024
Publication
Due to the large quantities of carbon emissions generated by the transportation sector cleaner automotive technologies are needed aiming at a green energy transition. In this scenario hydrogen is pointed out as a promising fuel that can be employed as the fuel of either a fuel cell or an internal combustion engine vehicle. Therefore in this work we propose the design and modeling of a fuel cell versus an internal combustion engine passenger car for a driving cycle. The simulation was carried out using the quasistatic simulation toolbox tool in Simulink considering the main powertrain components for each vehicle. Furthermore a brief analysis of the carbon emissions associated with the hydrogen production method is addressed to assess the clean potential of hydrogen-powered vehicles compared to conventional fossil fuel-fueled cars. The resulting analysis has shown that the hydrogen fuel cell vehicle is almost twice as efficient compared to internal combustion engines resulting in a lower fuel consumption of 1.05 kg-H2/100 km in the WLTP driving cycle for the fuel cell vehicle while the combustion vehicle consumed about 1.79 kg-H2/100 km. Regarding using different hydrogen colors to fuel the vehicle hydrogen-powered vehicles fueled with blue and grey hydrogen presented higher carbon emissions compared to petrol-powered vehicles reaching up to 2–3 times higher in the case of grey hydrogen. Thus green hydrogen is needed as fuel to keep carbon emissions lower than conventional petrol-powered vehicles.
Operational Optimization of Regional Integrated Energy Systems with Heat Pumps and Hydrogen Renewable Energy under Integrated Demand Response
Jan 2024
Publication
A regional integrated energy system (RIES) synergizing multiple energy forms is pivotal for enhancing renewable energy use and mitigating the greenhouse effect. Considering that the equipment of the current regional comprehensive energy system is relatively simple there is a coupling relationship linking power generation refrigeration and heating in the cogeneration system which is complex and cannot directly meet various load demands. This article proposes a RIES optimization model for bottom-source heat pumps and hydrogen storage systems in the context of comprehensive demand response. First P2G electric hydrogen production technology was introduced into RIES to give full play to the high efficiency advantages of hydrogen energy storage system and the adjustable thermoelectric ratio of the HFC was considered. The HFC could adjust its own thermoelectric ratio according to the system load and unit output. Second through the groundsource heat pump’s cleaning efficiency function further separation and cooling could be achieved. The heat and electrical output of RIES improved the operating efficiency of the system. Thirdly a comprehensive demand response model for heating cooling and electricity was established to enable users to reasonably adjust their own energy use strategies to promote the rational distribution of energy in the system. The model integrates power-to-gas (P2G) technology leveraging the tunable thermoelectric ratio of a hydrogen fuel cell (HFC) to optimize the generation of electricity and heat while maximizing the efficiency of the hydrogen storage system. Empirical analysis substantiated the proposed RIES model’s effectiveness and economic benefits when integrating ground-source HP and electric hydrogen production with IDR. Compared with the original model the daily operating cost of the proposed model was reduced by RMB 1884.16.
A Comprehensive Review on Condition Monitoring and Fault Diagnosis in Fuel Cell Systems: Challenges and Issues
Jan 2024
Publication
The complexity of Fuel Cell (FC) systems demands a profound and sustained understanding of the various phenomena occurring inside of it. Thus far FCs especially Proton Exchange Membrane Fuel Cells (PEMFCs) have been recognized as being among the most promising technologies for reducing Green House Gas (GHG) emissions because they can convert the chemical energy bonded to hydrogen and oxygen into electricity and heat. However their efficiency remains limited. To enhance their efficiency two distinct factors are suggested. First the quality of materials plays a significant role in the development of more robust and efficient FCs. Second the ability to identify mitigate and reduce the occurrence of faults through the use of robust control algorithms is crucial. Therefore more focused on the second point this paper compiles distinguishes and analyzes several publications from the past 25 years related to faults and their diagnostic techniques in FCs. Furthermore the paper presents various schemes outlining different symptoms their causes and corresponding fault algorithms.
Experimental Study of a Homogeneous Charge Compression Ignition Engine Using Hydrogen at High-Altitude Conditions
Feb 2024
Publication
One of the key factors of the current energy transition is the use of hydrogen (H2 ) as fuel in energy transformation technologies. This fuel has the advantage of being produced from the most primary forms of energy and has the potential to reduce carbon dioxide (CO2 ) emissions. In recent years hydrogen or hydrogen-rich mixtures in internal combustion engines (ICEs) have gained popularity with numerous reports documenting their use in spark ignition (SI) and compression ignition (CI) engines. Homogeneous charge compression ignition (HCCI) engines have the potential for substantial reductions in nitrogen oxides (NOx) and particulate matter (PM) emissions and the use of hydrogen along with this kind of combustion could substantially reduce CO2 emissions. However there have been few reports using hydrogen in HCCI engines with most studies limited to evaluating technical feasibility combustion characteristics engine performance and emissions in laboratory settings at sea level. This paper presents a study of HCCI combustion using hydrogen in a stationary air-cooled Lombardini 25 LD 425-2 modified diesel engine located at 1495 m above sea level. An experimental phase was conducted to determine the intake temperature requirements and equivalence ratios for stable HCCI combustion. These results were compared with previous research carried out at sea level. To the best knowledge of the authors this is the first report on the combustion and operational limits for an HCCI engine fueled with hydrogen under the mentioned specific conditions. Equivalence ratios between 0.21 and 0.28 and intake temperatures between 188 ◦C and 235 ◦C effectively achieved the HCCI combustion. These temperature values were on average 100 ◦C higher than those reported in previous studies. The maximum value for the indicated mean effective pressure (IMEPn) was 1.75 bar and the maximum thermal efficiency (ITEn) was 34.5%. The achieved results are important for the design and implementation of HCCI engines running solely on hydrogen in developing countries located at high altitudes above sea level.
Life Cycle Assessment of an Autonomous Underwater Vehicle that Employs Hydrogen Fuel Cell
Aug 2023
Publication
In recent years there has been a significant increase in the adoption of autonomous vehicles for marine and submarine missions. The advancement of emerging imaging navigation and communication technologies has greatly expanded the range of operational capabilities and opportunities available. The ENDURUNS project is a European research endeavor focused on identifying strategies for achieving minimal environmental impact. To measure these facts this article evaluates the product impacts employing the Life Cycle Assessment methodology for the first time following the ISO 14040 standard. In this analysis the quantitative values of Damage and Environmental Impact using the Eco-Indicator 99 methodology in SimaPro software are presented. The results report that the main contributors in environmental impact terms have been placed during the manufacturing phase. Thus one of the challenges is accomplished avoiding the use phase emissions that are the focus to reduce nowadays in the marine industry.
Optimized Scheduling of Integrated Energy Systems Accounting for Hydrogen Energy Multi-Utilization Models
Jan 2024
Publication
To cope with the growing penetration rate of renewable energy and to enhance the absorption capacity of wind power this paper investigates the applications of an Integrated Energy System (IES) Hydrogen Compressed Natural Gas (HCNG) and power-to-hydrogen (P2H) devices within the IES. It employs power-to-gas and gas blending with hydrogen to construct an efficient electricity–gas–electricity energy flow loop establishing a Natural Gas–Electricity Coupling System (NGECS) model. On this basis a coordinated scheduling method for gas–electric coupling systems using gas blended with hydrogen is proposed. A carbon trading mechanism is introduced to constrain carbon emissions further reducing the system’s carbon footprint. Multiple scenarios are set up for a comparative analysis in order to validate the effectiveness of the proposed model. This study also analyzes the impact of different hydrogen blending ratios and methods on the low-carbon and economic performance of IES.
Decarbonizing the Spanish Transportation Sector by 2050: Design and Techno-economic Assessment of the Hydrogen Generation and Supply Chain
May 2023
Publication
The transport sector is difficult to decarbonize due to its high reliance on fossil fuels accounting for 37% of global end-use sectors emissions in 2021. Therefore this work proposes an energy model to replace the Spanish vehicle fleet by hydrogen-fueled vehicles by 2050. Thus six regions are defined according to their proximity to regasification plants where hydrogen generation hubs are implemented. Likewise renewables deployment is subject to their land availability. Hydrogen is transported through an overhauled primary natural gas transport network while two distribution methods are compared for levelized cost of hydrogen minimization: gaseous pipeline vs liquid hydrogen supply in trucks. Hence a capacity of 443.1 GW of renewables 214 GW of electrolyzers and 3.45 TWh of hydrogen storage is required nationwide. Additionally gaseous hydrogen distribution is on average 17% cheaper than liquid hydrogen delivery. Finally all the regions present lower prices per km traveled than gasoline or diesel.
Numerical Analysis of the Hydrogen-air Mixture Formation Process in a Direct-injection Engine for Off-road Applications
Jun 2024
Publication
Among the different hydrogen premixed combustion concepts direct injection (DI) is one of the most promising for internal combustion engine (ICE) applications. However to fully exploit the benefits of this solution the optimization of the mixture preparation process is a crucial factor. In the present work a study of the hydrogenair mixture formation process in a DI H2-ICE for off-road applications was performed through 3D-CFD simulations. First a sensitivity analysis on the injection timing was carried out to select the optimal injection operating window capable of maximizing mixture homogeneity without a significant volumetric efficiency reduction. Then different spray injector guiding caps were tested to assess their effect on in-cylinder dynamics and mixture characteristics consequently. Finally the impact of swirl intensity on hydrogen distribution has been assessed. The optimization of the combustion chamber geometry has allowed the achievement of significant improvements in terms of mixture homogeneity.
Hydrogen Fuel Cell as an Electric Generator: A Case Study for a General Cargo Ship
Feb 2024
Publication
In this study real voyage data and ship specifications of a general cargo ship are employed and it is assumed that diesel generators are replaced with hydrogen proton exchange membrane fuel cells. The effect of the replacement on CO2 NOX SOX and PM emissions and the CII value is calculated. Emission calculations show that there is a significant reduction in emissions when hydrogen fuel cells are used instead of diesel generators on the case ship. By using hydrogen fuel cells there is a 37.4% reduction in CO2 emissions 32.5% in NOX emissions 37.3% in SOX emissions and 37.4% in PM emissions. If hydrogen fuel cells are not used instead of diesel generators the ship will receive an A rating between 2023 and 2026 a B rating in 2027 a C rating in 2028–2029 and an E rating in 2030. On the other hand if hydrogen fuel cells are used the ship will always remain at an A rating between 2023 and 2030. The capital expenditure (CAPEX) and operational expenditure (OPEX) of the fuel cell system are USD 1305720 and USD 2470320 respectively for a 15-year lifetime and the hydrogen fuel expenses are competitive at USD 260981 while marine diesel oil (MDO) fuel expenses are USD 206435.
Thermodynamic Modelling and Optimisation of a Green Hydrogen-blended Syngas-fueled Integrated PV-SOFC System
Sep 2023
Publication
Developing an effective energy transition roadmap is crucial in the face of global commitments to achieve net zero emissions. While renewable power generation systems are expanding challenges such as curtailments and grid constraints can lead to energy loss. To address this surplus electricity can be converted into green hydrogen serving as a key component in the energy transition. This research explores the use of renewable solar energy for powering a proton exchange membrane electrolyser to produce green hydrogen while a downdraft gasifier fed by municipal solid waste generates hydrogen-enriched syngas. The blended fuel is then used to feed a Solid Oxide Fuel Cell (SOFC) system. The study investigates the impact of hydrogen content on the performance of the fuel cell-based power plant from thermodynamics and exergoeconomic perspectives. Multiobjective optimisation using a genetic algorithm identifies optimal operating conditions for the system. Results show that blending hydrogen with syngas increases combined heat and power efficiency by up to 3% but also raises remarkably the unit product cost and reduces carbon dioxide emissions. Therefore the optimal values for hydrogen content current density temperatures and other parameters are determined. These findings contribute to the design and operation of an efficient and sustainable energy generation system.
Numerical Modeling for Analysis and Improvement of Hydrogen Refueling Process for Heavy-duty Vehicles
Dec 2024
Publication
This paper presents the development validation and application of a numerical model to simulate the process of refueling hydrogen-powerd heavy-duty vehicles with a cascade hydrohen refueling station design. The model is implemented and validated using experimental data from SAE J2601. The link between the average pressure ramp (APRR) and flow rate which is responsible for the dynamic evolution of the refueling process was analyzed. Various simulations were conducted with a vehicle tank of 230 L and nominal pressure of 35 MPa typical of tanks adopted in heavy-duty vehicles varying the ambient temperature between 0 and 40 °C the cooling temperature of the hydrogen by the system cooling between −40 and 0 °C and the APRR between 2 and 14 MPa/min. The study found that if the ambient temperature does not exceed 30 °C rapid refueling can be carried out with not very low pre-cooling temperatures e.g. -20 °C or − 10 °C guaranteeing greater savings in station management. Cooling system thermal power has been investigated through the analyses in several scenarios with values as high as 38.2 kW under the most challenging conditions. For those conditions it was shown that energy savings could reach as much as 90 %. Furthermore the refueling process was analyzed taking into account SAE J2061/2 limitations and an update was proposed. An alternative strategy was proposed such that the settings allow a higher flow rate to be associated with a given standard pressure ramp. This approach was designed to ensure that the maximum allowable pressure downstream of the pressure control valve as specified by the refueling protocol is reached exactly at the end of the refueling process. It has been observed that the adoption of this strategy has significant advantages. In the case of refueling with higher APPR refueling is about 20 s faster with a single tank with limited increases in temperature and pressure within it.
Evaluation of Significant Greenhouse Gas Emissions Reduction Using Hydrogen Fuel in a LFG/Diesel RCCI Engine
Jan 2024
Publication
The production of solid waste in human societies and the related environmental and global warming concerns are increasing. Extensive use of existing conventional diesel and dual-fuel engines also causes the production of high levels of greenhouse gases and aggravating the aforementioned concerns. Therefore the aim of this study is to reduce the greenhouse emissions in existing natural gas/diesel dual-fuel heavy-duty diesel engine. For this purpose changing the type of combustion to reactivity-controlled compression-ignition combustion and using landfill gas instead of natural gas in a dual-fuel engine were simultaneously implemented. Moreover a traditional method was used to evaluate the effect of variations in three important parameters on the engine's performance in order to determine the appropriate engine operating ranges. The simulation results indicate that although the consumption of 102000 cubic meters per year of natural gas in each cylinder is reduced only by replacing landfill gas the level of engine greenhouse gas emissions is too high compared to the relevant levels of emissions standards. Hence by keeping the total energy content of the fuels constant landfill gas enrichment with hydrogen was considered to reduce the engine emissions. The simulation results show that by increasing the hydrogen energy share up to 37% the engine load has the potential to be improved up to 7% without any exposure to diesel knock. However the downfall is the reduction in the gross indicated efficiency up to 3%. Meanwhile not only the fifth level of the European emission standard for nitrogen oxides and the sixth level of this standard for carbon monoxide can be achieved but it is also possible to overcome the high level of unburned methane as a drastic greenhouse gas and formaldehyde as a related carcinogenic species.
Renewable Hydrogen and Synthetic Fuels Versus Fossil Fuels for Trucking, Shipping and Aviation: A Holistic Cost Model
Aug 2023
Publication
Potential carbon neutrality of the global trucking shipping and aviation sectors by 2050 could be achieved by substituting fossil fuels with renewable hydrogen and synthetic fuels. To investigate the economic impact of fuel substitution over time a holistic cost model is developed and applied to three case studies in Norway an early adopter of carbon-neutral freight transport. The model covers the value chains from local electricity and fuel production (hydrogen ammonia Fischer–Tropsch e-fuel) to fuel consumption for long-haul trucking short-sea shipping and mid-haul aviation. The estimates are internally consistent and allow cross-mode and cross-fuel comparisons that set this work apart from previous studies more narrowly focused on a given transport mode or fuel. The model contains 150 techno-economic parameters to identify which components along the value chains drive levelized costs. This paper finds a cost reduction potential for renewable fuels of 41% to 68% until 2050 but carbon-neutral transport will suffer asymmetric cost disadvantages. Fuel substitution is most expensive in short-sea shipping followed by mid-haul aviation and long-haul trucking. Cost developments of electricity direct air capture of carbon vehicle expenses and fuel-related payload losses are significant drivers.
Research of Energy Efficiency and Environmental Performance of Vehicle Power Plant Converted to Work on Alternative Fuels
Apr 2024
Publication
The use of alternative fuels remains an important factor in solving the problem of reducing harmful substances caused by vehicles and decarbonising transport. It is also important to ensure the energy efficiency of vehicle power plants when using different fuels at a sufficient level. The article presents the results of theoretical and experimental studies of the conversion of diesel engine to alternative fuels with hydrogen admixtures. Methanol is considered as an alternative fuel which is a cheaper alternative to commercial diesel fuel. The chemical essence of improving the calorific value of alternative methanol fuel was investigated. Studies showed that the energy effect of burning an alternative mixture with hydrogen additives exceeds the effect of burning the same amount of methanol fuel. The increase in combustion energy and engine power is achieved as a result of heat from efficient use of the engine exhaust gases and chemical conversion of methanol. An experimental installation was created to study the work of a converted diesel engine on hydrogen–methanol mixtures and thermochemical regeneration processes. Experimental studies of the energy and environmental parameters of diesel engine converted to work on an alternative fuel with hydrogen admixtures have shown that engine power increases by 10–14% and emissions of harmful substances decrease.
An Optimization-Based Power-Following Energy Management Strategy for Hydrogen Fuel Cell Vehicles
Dec 2024
Publication
This paper presents an energy management algorithm based on an extended proportional integral derivative (PID) controller. To validate the proposed algorithm comprehensive simulation models were developed including a longitudinal dynamics-based vehicle model an ampere–hour integration-based power battery model a fuel cell model based on the Nernst equation and a hydrogen consumption model. An economic assessment was conducted through integrated simulation across all subsystems. The extended PID power regulation method was compared with the conventional power regulation method and the on–off power regulation method in a simulation environment using the China heavy-duty commercial vehicle test cycleB (CHTC-B) criterion. Additionally the power consumption of the lithium battery was converted into equivalent hydrogen consumption combining it with the hydrogen consumption of the fuel cell. The results showed that the extended PID strategy achieves an equivalent hydrogen consumption of 19.64 kg per 100 km compared to 20.41 kg for the traditional power–following strategy and 21.54 kg for the on–off strategy. Therefore the extended PID power–following strategy reduces equivalent hydrogen consumption by 8.8% compared to the on–off strategy and by 3.7% compared to the traditional power–following strategy.
Modelling of Fast Fueling of Pressurized Hydrogen Tanks for Maritime Applications
Apr 2023
Publication
This paper studies fast fueling of gaseous hydrogen into large hydrogen (H2) tanks suitable for maritime applications. Three modeling methods have been developed and evaluated: (1) Two-dimensional computational fluid dynamic (CFD) modeling (2) One-dimensional wall discretized modeling and (3) Zero-dimensional modeling. A detailed 2D CFD simulation of a small H2-tank was performed and validated with data from literature and then used to simulate a large H2-tank. Results from the 2D-model show non-uniform temperature distribution inside the large tank but not in the small H2-tank. The 1D-model can predict the mean temperature in small H2-tanks but not the inhomogeneous temperature field in large H2-tanks. The 0D-model is suitable as a screening tool to obtain rough estimates. Results from the modeling of the large H2-tank show that the heat transfer to the wall during fast filling is inhibited by heat conduction in the wall which leads to an unacceptably high mean hydrogen temperature.
Concept Design and Energy Balance Optimization of a Hydrogen Fuel Cell Helicoptor for Unmanned Aerial Vehicle and Aerotaxi Applications
May 2023
Publication
In the new scenario where the transportation sector must be decarbonized to limit global warming fuel cellpowered aerial vehicles have been selected as a strategic target application to compose part of the urban fleet to minimize road transport congestion and make goods and personal transportation fast and efficient. To address the necessity of clean and efficient urban air transport this work consists of the conceptual development of a lightweight rotary-winged transport vehicle using a hydrogen-based fuel cell propulsion system and the optimization of its energy balance. For that purpose the methods for integrating the coupled aerodynamic and propulsion system sizing and optimization was developed with the aim of designing concepts capable of carrying 0 (unmanned aerial vehicle — Design 1) and 1 (Aerotaxi — Design 2) passengers for a distance of 300 km at a cruise altitude of 500 m with a minimum climbing rate capability of 6 m s−1 at 1000 m. The results show how these designs with the desired performance specifications can be obtained with a vehicle mass ranging from 416 to 648 kg depending on the application and with specific range and endurance respectively within 46.2–47.8 km/kg and 20.4–21.3 min/kg for design 1 and 33.3–33.8 km/kg and 12.5–13.9 min/kg for design 2.
A Novel Scheme to Allocate the Green Energy Transportation Costs—Application to Carbon Captured and Hydrogen
Mar 2023
Publication
Carbon dioxide (CO2 ) and hydrogen (H2 ) are essential energy vectors in the green energy transition. H2 is a fuel produced by electrolysis and is applied in heavy transportation where electrification is not feasible yet. The pollutant substance CO2 is starting to be captured and stored in different European locations. In Denmark the energy vision aims to use this CO2 to be reacted with H2 producing green methanol. Typically the production units are not co-located with consumers and thus the required transportation infrastructure is essential for meeting supply and demand. This work presents a novel scheme to allocate the transportation costs of CO2 and H2 in pipeline networks which can be applied to any network topology and with any allocation method. During the tariff formation process coordinated adjustments are made by the novel scheme on the original tariffs produced by the allocation method employed considering the location of each customer connected to pipeline network. Locational tariffs are provided as result and the total revenue recovery is guaranteed to the network owner. Considering active customers the novel scheme will lead to a decrease of distant pipeline flows thereby contributing to the prevention of bottlenecks in the transportation network. Thus structural reinforcements can be avoided reducing the total transportation cost paid by all customers in the long-term.
Mathematical Model for the Placement of Hydrogen Refueling Stations to Support Future Fuel Cell Trucks
Nov 2021
Publication
Fuel cell- and electric-powered trucks are promising technologies for zero-emission heavyduty transportation. Recently Fuel Cell Trucks (FCT) have gained wider acceptance as the technology of choice for long-distance trips due to their lighter weight and shorter fueling time than electric-powered trucks. Broader adoption of Fuel Cell Trucks (FCT) requires planning strategies for locating future hydrogen refueling stations (HRS) especially for fleets that transport freight along intercity and inter-country highways. Existing mathematical models of HRS placement often focus on inner-city layouts which make them inadequate when studying the intercity and intercountry FCT operation scale of FCT. Furthermore the same models rarely consider decentralized hydrogen production from renewable energy sources essential for decarbonizing the transportation sector. This paper proposes a mathematical model to guide the planning of the hydrogen infrastructure to support future long-haul FCTs. First the model uses Geographic Information System (GIS) data to determine the HRS’s optimal number and location placement. Then the model categorizes and compares potential hydrogen production sources including off-site delivery and on-site solar-to-hydrogen production. The proposed model is illustrated through a case study of the west coastal area of the United States (from Baja California Mexico to British Columbia Canada). Different geospatial scenarios were tested ranging from the current operational distance of FCEV (250km) and future releases of hydrogen FCT (up to 1500km). Results highlight the capabilities of the model in identifying the number and location of the HRS based on operation distances in addition to determining the optimal hydrogen production technology for each HRS. The findings also confirm the viability of green hydrogen production through solar energy which could play a critical role in a low-carbon transportation future.
Improving Ecological Efficiency of Gas Turbine Power System by Combusting Hydrogen and Hydrogen-Natural Gas Mixtures
Apr 2023
Publication
Currently the issue of creating decarbonized energy systems in various spheres of life is acute. Therefore for gas turbine power systems including hybrid power plants with fuel cells it is relevant to transfer the existing engines to pure hydrogen or mixtures of hydrogen with natural gas. However significant problems arise associated with the possibility of the appearance of flashback zones and acoustic instability of combustion an increase in the temperature of the walls of the flame tubes and an increase in the emission of nitrogen oxides in some cases. This work is devoted to improving the efficiency of gas turbine power systems by combusting pure hydrogen and mixtures of natural gas with hydrogen. The organization of working processes in the premixed combustion chamber and the combustion chamber with a sequential injection of ecological and energy steam for the “Aquarius” type power plant is considered. The conducted studies of the basic aerodynamic and energy parameters of a gas turbine combustor working on hydrogen-containing gases are based on solving the equations of conservation and transfer in a multicomponent reacting system. A four-stage chemical scheme for the burning of a mixture of natural gas and hydrogen was used which allows for the rational parameters of environmentally friendly fuel burning devices to be calculated. The premixed combustion chamber can only be recommended for operations on mixtures of natural gas with hydrogen with a hydrogen content not exceeding 20% (by volume). An increase in the content of hydrogen leads to the appearance of flashback zones and fuel combustion inside the channels of the swirlers. For the combustion chamber of the combined-cycle power plant “Vodoley” when operating on pure hydrogen the formation of flame flashback zones does not occur.
An Approach for Sizing a PV-battery-electrolyzer-fuel cell Energy System: A Cast Study at a Field Lab
May 2023
Publication
Hydrogen is becoming increasingly popular as a clean secure and affordable energy source for the future. This study develops an approach for designing a PV–battery–electrolyzer–fuel cell energy system that utilizes hydrogen as a long-term storage medium and battery as a short-term storage medium. The system is designed to supply load demand primarily through direct electricity generation in the summer and indirect electricity generation through hydrogen in the winter. The sizing of system components is based on the direct electricity and indirect hydrogen demand with a key input parameter being the load sizing factor which determines the extent to which hydrogen is used to meet seasonal imbalance. Technical and financial indicators are used to assess the performance of the designed system. Simulation results indicate that the energy system can effectively balance the seasonal variation of renewable generation and load demand with the use of hydrogen. Additionally guidelines for achieving self-sufficiency and system sustainability for providing enough power in the following years are provided to determine the appropriate component size. The sensitivity analysis indicates that the energy system can achieve self-sufficiency and system sustainability with a proper load sizing factor from a technical perspective. From an economic perspective the levelized cost of energy is relatively high because of the high costs of hydrogen-related components at this moment. However it has great economic potential for future self-sufficient energy systems with the maturity of hydrogen technologies.
Simulating Offshore Hydrogen Production via PEM Electrolysis using Real Power Production Data from a 2.3 MW Floating Offshore Wind Turbine
Mar 2023
Publication
This work presents simulation results from a system where offshore wind power is used to produce hydrogen via electrolysis. Real-world data from a 2.3 MW floating offshore wind turbine and electricity price data from Nord Pool were used as input to a novel electrolyzer model. Data from five 31-day periods were combined with six system designs and hydrogen production system efficiency and production cost were estimated. A comparison of the overall system performance shows that the hydrogen production and cost can vary by up to a factor of three between the cases. This illustrates the uncertainty related to the hydrogen production and profitability of these systems. The highest hydrogen production achieved in a 31-day period was 17 242 kg using a 1.852 MW electrolyzer (i.e. utilization factor of approximately 68%) the lowest hydrogen production cost was 4.53 $/kg H2 and the system efficiency was in the range 56.1e56.9% in all cases.
The Status of On-Board Hydrogen Storage in Fuel Cell Electric Vehicles
Aug 2023
Publication
Hydrogen as an energy carrier could help decarbonize industrial building and transportation sectors and be used in fuel cells to generate electricity power or heat. One of the numerous ways to solve the climate crisis is to make the vehicles on our roads as clean as possible. Fuel cell electric vehicles (FCEVs) have demonstrated a high potential in storing and converting chemical energy into electricity with zero carbon dioxide emissions. This review paper comprehensively assesses hydrogen’s potential as an innovative alternative for reducing greenhouse gas (GHG) emissions in transportation particularly for on-board applications. To evaluate the industry’s current status and future challenges the work analyses the technology behind FCEVs and hydrogen storage approaches for on-board applications followed by a market review. It has been found that to achieve long-range autonomy (over 500 km) FCEVs must be capable of storing 5–10 kg of hydrogen in compressed vessels at 700 bar with Type IV vessels being the primary option in use. Carbon fiber is the most expensive component in vessel manufacturing contributing to over 50% of the total cost. However the cost of FCEV storage systems has considerably decreased with current estimates around 15.7 $/kWh and is predicted to drop to 8 $/kWh by 2030. In 2021 Toyota Hyundai Mercedes-Benz and Honda were the major car brands offering FCEV technology globally. Although physical and chemical storage technologies are expected to be valuable to the hydrogen economy compressed hydrogen storage remains the most advanced technology for on-board applications.
Integration of Air-cooled Multi-stack Polymer Electrolyte Fuel Cell Systems into Renewable Microgrids
May 2022
Publication
Currently there is a growing interest in increasing the power range of air-cooled fuel cells (ACFCs) as they are cheaper easier to use and maintain than water-cooled fuel cells (WCFCs). However air-cooled stacks are only available up to medium power (<10 kW). Therefore a good solution may be the development of ACFCs consisting of several stacks until the required power output is reached. This is the concept of air-cooled multi-stack fuel cell (AC-MSFC). The objective of this work is to develop a turnkey solution for the integration of AC-MSFCs in renewable microgrids specifically those with high-voltage DC (HVDC) bus. This is challenging because the AC-MSFCs must operate in the microgrid as a single ACFC with adjustable power depending on the number of stacks in operation. To achieve this the necessary power converter (ACFCs operate at low voltages so high conversion rates are required) and control loops must be developed. Unlike most designs in the literature the proposed solution is compact forming a system (AC-MSFCS) with a single input (hydrogen) and a single output (high voltage regulated power or voltage) that can be easily integrated into any microgrid and easily scalable depending on the power required. The developed AC-MSFCS integrates stacks balance of plant data acquisition and instrumentation power converters and local controllers. In addition a virtual instrument (VI)has been developed which connected to the energy management system (EMS) of the microgrid allows monitoring of the entire AC-MSFCS (operating temperature purging cell voltage monitoring for degradation evaluation stacks operating point control and alarm and event management) as well as serving as a user interface. This allows the EMS to know the degradation of each stack and to carry out energy distribution strategies or specific maintenance actions which improves efficiency lifespan and of course saves costs. The experimental results have been excellent in terms of the correct operation of the developed AC-MSFCS. Likewise the accumulated degradation of the stacks was quantified showing cells with a degradation of >80%. The excellent electrical and thermal performance of the developed power converter was also validated which allowed the correct and efficient supply of regulated power (average efficiency above 90%) to the HVDC bus according to the power setpoint defined by the EMS of the microgrid.
A Review of Port Decarbonisation Options: Identified Opportunities for Deploying Hydrogen Technologies
Apr 2024
Publication
The utilisation of hydrogen is being explored as a viable solution for reducing carbon emissions in port operations with potential applications in cargo handling transportation and shipping vessel operations. To comprehensively list the decarbonisation options in ports this study conducted a Systematic Literature Review to identify and then survey twelve highly cited review papers. Initially a typology approach was used to categorise the decarbonisation options by activities and technologies. Subsequently the study introduced a novel Port Energy Map to reveal the energy system pathways and their interconnections. Each pathway was then converted into a simpler linear sequence of activities shown as a Port Energy System Taxonomy which outlines the energy supply and energy-using activities. By utilising this taxonomy and map the study identified opportunities and research gaps for integrating hydrogen technologies into port energy systems which serves as a valuable tool for assessing port decarbonisation options.
Work Efficiency and Economic Efficiency of Actual Driving Test of Proton Exchange Membrane Fuel Cell Forklift
Aug 2023
Publication
A 3.5 tonne forklift containing proton exchange membrane fuel cells (PEMFCs) and lithium-ion batteries was manufactured and tested in a real factory. The work efficiency and economic applicability of the PEMFC forklift were compared with that of a lithium-ion battery-powered forklift. The results showed that the back-pressure of air was closely related to the power density of the stack whose stability could be improved by a reasonable control strategy and membrane electrode assemblies (MEAs) with high consistency. The PEMFC powered forklift displayed 40.6% higher work efficiency than the lithium-ion battery-powered forklift. Its lower use-cost compared to internal engine-powered forklifts is beneficial to the commercialization of this product.
Operation Strategy for an Integrated Energy System Considering the Slow Dynamic Response Characteristics of Power-to-Gas Conversion
Jun 2024
Publication
Power-to-gas technology provides an emerging pathway for promoting green and lowcarbon transformation of energy systems. Through the processes of electrolyzing water and the methanation reaction it converts surplus renewable energy into hydrogen and natural gas offering an effective approach for large-scale integration of renewable energy sources. However the optimization of existing integrated energy systems has yet to finely model the operational characteristics of power-to-gas technology severely limiting the energy conversion efficiency of systems. To address this issue this paper proposes an integrated energy system operation strategy considering the slow dynamic response characteristics of power-to-gas. Firstly based on the technical features of power-to-gas an operational model for electrolyzing water to produce hydrogen is constructed considering the transition relationships among cold start-up hot start-up and production states of a methanation reaction thereby building a power-to-gas operation model considering slow dynamic response characteristics. This model finely reflects the impact of power-to-gas operational states on methanation facilitating accurate representation of the operational states of methanation. Then considering the energy conversion constraints and power balance of various coupled devices within integrated energy systems an optimization model for the operation of the integrated energy system is constructed with the total daily operation cost of the system as the optimization objective. Finally simulation comparisons are conducted to demonstrate the necessity of considering the slow dynamic response characteristics of power-to-gas technology for integrated energy system operation. The case study results indicate that the proposed power-to-gas operation model can accurately simulate the methanation process facilitating the rational conversion of surplus renewable energy into natural gas energy and avoiding misjudgments in system operation costs and energy utilization efficiency.
A Review of Hydrogen-based Hybrid Renewable Energy Systems: Simulation and Optimization with Artificial Intelligence
Nov 2021
Publication
With the massive use of traditional fossil fuels greenhouse gas emissions are increasing and environmental pollution is becoming an increasingly serious problem which led to an imminent energy transition. Therefore the development and application of renewable energy are particularly important. This paper reviews a wide range of issues associated with hybrid renewable energy systems (HRESs). The issues concerning system configurations energy storage options simulation and optimization with artificial intelligence are discussed in detail. Storage technology options are introduced for stand-alone (off-grid) and grid-connected (on-grid) HRESs. Different optimization methodologies including classical techniques intelligent techniques hybrid techniques and software tools for sizing system components are presented. Besides the artificial intelligence methods for optimizing the solar/wind HRESs are discussed in detail.
Multi-Objective Optimization for Solar-Hydrogen-Battery-Integrated Electric Vehicle Charging Stations with Energy Exchange
Oct 2023
Publication
The importance of electric vehicle charging stations (EVCS) is increasing as electric vehicles (EV) become more widely used. EVCS with multiple low-carbon energy sources can promote sustainable energy development. This paper presents an optimization methodology for direct energy exchange between multi-geographic dispersed EVCSs in London UK. The charging stations (CSs) incorporate solar panels hydrogen battery energy storage systems and grids to support their operations. EVs are used to allow the energy exchange of charging stations. The objective function of the solar-hydrogen-battery storage electric vehicle charging station (SHS-EVCS) includes the minimization of both capital and operation and maintenance (O&M) costs as well as the reduction in greenhouse gas emissions. The system constraints encompass the power output limits of individual components and the need to maintain a power balance between the SHS-EVCSs and the EV charging demand. To evaluate and compare the proposed SHS-EVCSs two multi-objective optimization algorithms namely the Non-dominated Sorting Genetic Algorithm (NSGA-II) and the Multi-objective Evolutionary Algorithm Based on Decomposition (MOEA/D) are employed. The findings indicate that NSGA-II outperforms MOEA/D in terms of achieving higher-quality solutions. During the optimization process various factors are considered including the sizing of solar panels and hydrogen storage tanks the capacity of electric vehicle chargers and the volume of energy exchanged between the two stations. The application of the optimized SHS-EVCSs results in substantial cost savings thereby emphasizing the practical benefits of the proposed approach.
Optimal Design and Sizing of Hybrid Photovoltaic/Fuel Cell Electrical Power System
Aug 2023
Publication
Renewable energy solutions play a crucial role in addressing the growing energy demands while mitigating environmental concerns. This study examines the techno-economic viability and sensitivity of utilizing solar photovoltaic/polymer electrolyte membrane (PEM) fuel cells (FCs) to meet specific power demands in NEOM Saudi Arabia. The novelty of this study lies in its innovative approach to analyzing and optimizing PV/PEMFC systems aiming to highlight their economic feasibility and promote sustainable development in the region. The analysis focuses on determining the optimal size of the PV/PEMFC system based on two critical criteria: minimum cost of energy (COE) and minimum net present cost (NPC). The study considers PEMFCs with power ratings of 30 kW 40 kW and 50 kW along with four PV panel options: Jinko Solar Powerwave Tindo Karra and Trina Solar. The outcomes show that the 30 kW PEMFC and the 201 kW Trina Solar TSM-430NEG9R.28 are the most favorable choices for the case study. Under these optimal conditions the study reveals the lowest values for NPC at USD 703194 and COE at USD 0.498 per kilowatt-hour. The levelized cost of hydrogen falls within the range of USD 15.9 to 23.4 per kilogram. Furthermore replacing the 30 kW Trina solar panel with a 50 kW Tindo PV module results in a cost reduction of 32%. The findings emphasize the criticality of choosing optimal system configurations to attain favorable economic outcomes thereby facilitating the adoption and utilization of renewable energy sources in the region. In conclusion this study stands out for its pioneering and thorough analysis and optimization of PV/PEMFC systems providing valuable insights for sustainable energy planning in NEOM Saudi Arabia.
Industrial Development Status and Prospects of the Marine Fuel Cell: A Review
Jan 2023
Publication
In the context of the increasingly strict pollutant emission regulations and carbon emission reduction targets proposed by the International Maritime Organization the shipping industry is seeking new types of marine power plants with the advantages of high efficiency and low emissions. Among the possible alternatives the fuel cell is considered to be the most practical technology as it provides an efficient means to generate electricity with low pollutant emissions and carbon emissions. Very few comprehensive reviews focus on the maritime applications of the fuel cell. Thus news reports and literature on the maritime applications of the fuel cell in the past sixty years were collected and the industrial development status and prospects of the marine fuel cell were summarized as follows. Some countries in Europe North America and Asia have invested heavily in researching and developing the marine fuel cell and a series of research projects have achieved concrete results such as the industrialized marine fuel cell system or practical demonstration applications. At present the worldwide research of the marine fuel cell focuses more on the proton exchange membrane fuel cell (PEMFC). However the power demand of the marine fuel cell in the future will show steady growth and thus the solid oxide fuel cell (SOFC) with the advantages of higher power and fuel diversity will be the mainstream in the next research stage. Although some challenges exist the SOFC can certainly lead the upgrading and updating of the marine power system with the cooperative efforts of the whole world.
Refuelling Tests of a Hydrogen Tank for Heavy-duty Applications
Sep 2023
Publication
A transition towards zero-emission fuels is required in the mobility sector in order to reach the climate goals. Here (green) renewable hydrogen for use in fuel cells will play an important role especially for heavy duty applications such as trucks. However there are still challenges to overcome regarding efficient storage infrastructure integration and optimization of the refuelling process. A key aspect is to reduce the refuelling duration as much as possible while staying below the maximum allowed temperature of 85 C. Experimental tests for the refuelling of a 320 l type III tank were conducted at different operating conditions and the tank gas temperature measured at the front and back ends. The results indicate a strongly inhomogeneous temperature field where measuring and verifying the actual maximum temperatures proves difficult. Furthermore a simulation approach is provided to calculate the average tank gas temperature at the end of the refuelling process.
Low-carbon Development for the Iron and Steel Industry in China and the World: Status Quo, Future Vision, and Key Actions
Nov 2021
Publication
The low-carbon development of China’s iron and steel industry (ISI) is important but challenging work for the attainment of China’s carbon neutrality by 2060. However most previous studies related to the low-carbon development of China’s ISI are fragmented from different views such as production-side mitigation demand-side mitigation or mitigation technologies. Additionally there is still a lack of a comprehensive overview of the long-term pathway to the low-carbon development of China’s ISI. To respond to this gap and to contribute to better guide policymaking in China this paper conducted a timely and comprehensive review following the technology roadmap framework covering the status quo future vision and key actions of the low-carbon development of the world and China’s ISI. First this paper provides an overview of the technology roadmap of low-carbon development around the main steel production countries in the world. Second the potential for key decarbonization actions available for China’s ISI are evaluated in detail. Third policy and research recommendations are put forward for the future low-carbon development of China’s ISI. Through this comprehensive review four key actions can be applied to the low-carbon development of China’s ISI: improving energy efficiency shifting to Scrap/EAF route promoting material efficiency strategy and deploying radical innovation technologies.
Techno-economic Investigation of Hybrid Peaker Plant and Hydrogen Refuelling Station
Sep 2023
Publication
The power and transport sectors are responsible for significant emissions of greenhouse gases. Therefore it is imperative that substantial efforts are directed towards the decarbonisation of these industries. This study establishes a combined-solar-wind system's economic and technical practicality for producing hydrogen for an onsite hydrogen refuelling station (HRS) and electricity to meet peak demand. To minimise the levelised cost of electricity and maximise the system's reliability at different commercial locations in South Africa the dual-objective optimisation sizing is carried out using Mixed Integer Quadratic Constrained Programming (MICQP) model and was executed with an Advanced Multi-dimensional Modelling System (AIMMS) [61] [62]. The levelised costs of electricity and hydrogen at Johannesburg Pretoria and Cape Town for 2 MW grid export benchmark are 74.2 $/MWh/5.85 $/kg 76.3 $/MWh/5.97 $/kg and 50 $/MWh/4.45 $/kg respectively. The CO₂ equivalent emissions (tonnes) are 54000 55800 59000 and the corresponding carbon taxes ($) avoided for the locations are 432100 446200 and 472000 for Johannesburg Pretoria and Cape Town respectively. The results of the framework show that it can be adopted as a viable and fossil-free replacement for conventional peaking generators.
Design of a Hydrogen Aircraft for Zero Persistent Contrails
Jul 2023
Publication
Contrails are responsible for a significant proportion of aviation’s climate impact. This paper uses data from the European Centre for Medium-Range Weather Forecasts to identify the altitudes and latitudes where formed contrails will not persist. This reveals that long-lived contrails may be prevented by flying lower in equatorial regions and higher in non-equatorial regions. Subsequently it is found that the lighter fuel and reduced seating capacity of hydrogen-powered aircraft lead to a reduced aircraft weight which increases the optimal operating altitude by about 2 km. In non-equatorial regions this would lift the aircraft’s cruise point into the region where long-lived contrails do not persist unlocking hydrogen-powered low-contrails operation. The baseline aircraft considered is an A320 retrofitted with in-fuselage hydrogen tanks. The impacts of the higher-altitude cruise on fuel burn and the benefits unlocked by optimizing the wing geometry for this altitude are estimated using a drag model based on theory proposed by Cavcar Lock and Mason and verified against existing aircraft. The weight penalty associated with optimizing wing geometry for this altitude is estimated using Torenbeek’s correlation. It is found that thinner wings with higher aspect ratios are particularly suited to this high-altitude operation and are enabled by the relaxation of the requirement to store fuel in the wings. An example aircraft design for the non-equatorial region is provided which cruises at a 14 km altitude at Mach 0.75 with a less than 1% average probability of generating long-lived contrails when operating at latitudes more than 35◦ from the equator. Compared to the A320 this concept design is estimated to have a 20% greater cruise lift–drag ratio due to the 33% thinner wings with a 50% larger aspect ratio enabling just 5% more energy use per passenger-km despite fitting 40% fewer seats.
Modelling Large-scale Hydrogen Uptake in the Mexican Refinery and Power Sectors
Sep 2023
Publication
Due to the emissions reduction commitments that Mexico compromised in the Paris Agreement several clean fuel and renewable energy technologies need to penetrate the market to accomplish the environmental goals. Therefore there is a need to develop achievable and realistic policies for such technologies to ease the decision-making on national energy strategies. Several countries are starting to develop large-scale green hydrogen production projects to reduce the carbon footprint of the multiple sectors within the country. The conversion sectors namely power and refinery are fundamental sectors to decarbonise due to their energy supply role. Nowadays the highest energy consumables of the country are hydrocarbons (more than 90%) causing a particular challenge for deep decarbonisation. The purpose of this study is to use a multi-regional energy system model of Mexico to analyse a decarbonisation scenario in line with the latest National Energy System Development Program. Results show that if the country wants to succeed in reducing 22% of its GHG emissions and 51% of its short-lived climate pollutants emissions green hydrogen could play a role in power generation in regions with higher energy demand growth rates. These results show regarding the power sector that H2 could represent 13.8 GW or 5.1% of the total installed capacity by 2050 while for the refinery sector H2 could reach a capacity of 157 PJ/y which is around 31.8% of the total share and it is mainly driven by the increasing demands of the transport industry and power sectors. Nevertheless as oil would still represent the largest energy commodity CCS technologies would have to be deployed for new and retrofitted refinery facilities.
Numerical Modelling of a Heavy-duty Diesel-hydrogen Dual-fuel Engine with Late High Pressure Hydrogen Direct Injection and Diesel Pilot
Sep 2023
Publication
Direct gaseous fuel injection in internal combustion engines is a potential strategy for improving in-cylinder combustion processes and performance while reducing emissions and increasing hydrogen energy share (HES). Through use of numerical modelling the current study explores combustion in a compression ignition engine utilising a late compression/early power stroke direct gaseous hydrogen injection ignited by a diesel pilot at up to 99% HES. The combustion process of hydrogen in this type of engine is mapped out and compared to that of the same engine using methane direct injection. Four distinct phases of combustion are found which differ from that of pure diesel operation. Interaction of the injected gas jet with the chamber walls is found to have a considerable impact on performance and emission characteristics and is a factor which needs to be explored in greater detail in future studies. Considerable performance increase and carbon-based emission reductions are identified at up to 99% HES at high load but low load performance greatly deteriorated when 95% HES was exceeded due to a much reduced diesel pilot struggling to ignite the main hydrogen injection.
Investigation of Hybrid Power-to-hydrogen/Nautral Gas and Hydrogen-to-X System in Cameroon
May 2024
Publication
In Sub-Saharan Africa (SSA) the capacity to generate energy faces significant hurdles. Despite efforts to integrate renewable energy sources and natural gas power plants into the energy portfolio the desired reduction in environmental impact and alleviation of energy poverty remain elusive. Hence exploring a spectrum of hybrid technologies encompassing storage and hydrogen-based solutions is imperative to optimize energy production while mitigating harmful emissions. To exemplify this necessity the 216 MW Kribi gas power plant in Cameroon is the case study. The primary aim is to investigate cutting-edge emissions and energy schemes within the SSA. This paper assessed the minimum complaint load technique and four power-to-fuel options from technical financial and environmental perspectives to assess the viability of a natural gas fuel system powered with hydrogen in a hybrid mode. The system generates hydrogen by using water electrolysis with photovoltaic electricity and gas power plant. This research also assesses process efficiency storage capacity annual costs carbon avoided costs and production prices for various fuels. Results showed that the LCOE from a photovoltaic solar plant is 0.19$/kWh with the Power-to-Hydrogen process (76.2% efficiency) being the most efficient followed by the ammonia and urea processes. The study gives a detailed examination of the hybrid hydrogen natural gas fuel system. According to the annual cost breakdown the primary costs are associated with the acquisition of electrical energy and electrolyser CAPEX and OPEX which account for 95% of total costs. Urea is the cheapest mass fuel. However it costs more in terms of energy. Hydrogen is the most cost-effective source of energy. In terms of energy storage and energy density by volume the methane resulted as the most suitable solution while the ammonia resulted as the best H2 storage medium in terms of kg of H2 per m3 of storage (108 kgH2/m3 ). By substituting the fuel system with 15% H2 the environmental effects are reduced by 1622 tons per year while carbon capture technology gathered 16664 tons of CO2 for methanation and urea operations yielding a total carbon averted cost of 21 $/ton.
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