Publications

Stationary fuel cells can play a beneficial role in Europe's changing energy landscape. The energy systems across Europe face significant challenges as they evolve against the backdrop of an ambitious climate agenda. As energy systems integrate more and more generation capacity from intermittent renewables numerous challenges arise. Amongst others Europe's energy systems of the future require new concepts for complementary supply such as efficient distributed power generation from natural gas. At the same time significant investments to modernise the electricity grid infrastructure are needed. Long-term storage solutions become a growing priority to ensure permanent power supply e.g. power-to-gas. Moreover Europe puts greater emphasis on energy efficiency in order to save primary energy reduce fuel imports and increase energy security.

Against this background distributed generation from stationary fuel cells promises significant benefits. This study outlines a pathway for commercialising stationary fuel cells in Europe The present study outlines a pathway for commercialising stationary fuel cells in Europe. It produces a comprehensive account of the current and future market potential for fuel cell distributed energy generation in Europe benchmarks stationary fuel cell technologies against competing conventional technologies in a variety of use cases and assesses potential business models for commercialisation. Considering the results of the technological and commercial analysis the study pinpoints focus areas for further R&D to sustain innovation and provides recommendations for supportive policy frameworks.

The study has been sponsored by the Fuel Cells and Hydrogen Joint Undertaking. Compiled by Roland Berger Strategy Consultants it builds on an interactive approach involving a coalition of more than 30 companies public institutions and associations from the stakeholder community of the European stationary fuel cell industry.

Hydrogen (H₂) is one of the best candidates to replace current petroleum energy resources due to its rich abundance and clean combustion. However the storage of H₂presents a major challenge. There are two methods for storing H₂ fuel chemical and physical both of which have some advantages and disadvantages. In physical storage highly porous organic polymers are of particular interest since they are low cost easy to scale up metal-free and environmentally friendly.

In this review highly porous polymers for H₂ fuel storage are examined from five perspectives:

(a) brief comparison of H₂ storage in highly porous polymers and other storage media;

(b) theoretical considerations of the physical storage of H₂ molecules in porous polymers;

(c) H₂ storage in different classes of highly porous organic polymers;

(d) characterization of microporosity in these polymers; and

(e) future developments for highly porous organic polymers for H₂ fuel storage. These topics will provide an introductory overview of highly porous organic polymers in H₂ fuel storage.

Power-to-gas technology plays a key role in the success of the energy transformation. This paper addresses issues related to the legal and technical regulations specifying the rules for adding hydrogen to the natural gas network. The main issue reviewed is the effects of the addition of hydrogen to natural gas on the durability of diaphragm gas meters. The possibility of adding hydrogen to the gas network requires confirmation of whether within the expected hydrogen concentrations long-term operation of gas meters will be ensured without compromising their metrological properties and operational safety. Methods for testing the durability of gas meters applied at test benches and sample results of durability tests of gas meters are presented. Based on these results a metrological and statistical analysis was carried out to establish whether the addition of hydrogen affects the durability of gas meters over time. The most important conclusion resulting from the conducted study indicates that for the tested gas meter specimens there was no significant metrological difference between the obtained changes of errors of indications after testing the durability of gas meters with varying hydrogen content (from 0% to 15%).

A solid-state hydrogen storage material comprising ammonia borane (AB) and polyethylene oxide (PEO) has been produced by freeze-drying from aqueous solutions from 0% to 100% AB by mass. The phase mixing behaviour of AB and PEO has been investigated using X-ray diffraction which shows that a new ‘intermediate’ crystalline phase exists different from both AB and PEO as observed in our previous work (Nathanson et al. 2015). It is suggested that hydrogen bonding interactions between the ethereal oxygen atom (–O–) in the PEO backbone and the protic hydrogen atoms attached to the nitrogen atom (N–H) of AB molecules promote the formation of a reaction intermediate leading to lowered hydrogen release temperatures in the composites compared to neat AB. PEO also acts to significantly reduce the foaming of AB during hydrogen release. A temperature-composition phase diagram has been produced for the AB-PEO system to show the relationship between phase mixing and hydrogen release.

The expansion of wind and solar power is creating a growing need for power system flexibility. Dispatchable power plants with CO₂ capture and storage (CCS) offer flexibility with low CO₂ emissions but these plants become uneconomical at the low running hours implied by renewables-based power systems. To address this challenge the novel gas switching reforming (GSR) plant was recently proposed. GSR can alternate between electricity and hydrogen production from natural gas offering flexibility to the power system without reducing the utilization rate of the capital stock embodied in CCS infrastructure. This study assesses the interplay between GSR and variable renewables using a power system model which optimizes investment and hourly dispatch of 13 different technologies. Results show that GSR brings substantial benefits relative to conventional CCS. At a CO₂ price of V100/ton inclusion of GSR increases the optimal wind and solar share by 50% lowers total system costs by 8% and reduces system emissions from 45 to 4 kgCO₂/MWh. In addition GSR produces clean hydrogen equivalent to about 90% of total electricity demand which can be used to decarbonize transport and industry. GSR could therefore become a key enabling technology for a decarbonization effort led by wind and solar power.

Compressed hydrogen storage is currently widely used in fuel cell vehicles due to its simplicity in tank structure and refuelling process. For safety reason the final gas temperature in the hydrogen tank during vehicle refuelling must be maintained under a certain limit e.g. 85 °C. Many experiments have been performed to find the relations between the final gas temperature in the hydrogen tank and refueling conditions. The analytical solution of the hydrogen temperature in the tank can be obtained from the simplified thermodynamic model of a compressed hydrogen storage tank and it serves as function formula to fit experimental temperatures. From the analytical solution the final hydrogen temperature can be expressed as a weighted average form of initial temperature inflow temperature and ambient temperature inspired by the rule of mixtures. The weighted factors are related to other refuelling parameters such as initial mass initial pressure refuelling time refuelling mass rate average pressure ramp rate (APRR) final mass final pressure etc. The function formula coming from the analytical solution of the thermodynamic model is more meaningful physically and more efficient mathematically in fitting experimental temperatures. The simple uniform formula inspired by the concept of the rule of mixture and its weighted factors obtained from the analytical solution of lumped parameter thermodynamics model is representatively used to fit the experimental and simulated results in publication. Estimation of final hydrogen temperature from refuelling parameters based on the rule of mixtures is simple and practical for controlling the maximum temperature and for ensuring hydrogen safety during fast filling process.

HyNet North West (NW) is an innovative integrated low carbon hydrogen production distribution and carbon capture utilisation and storage (CCUS) project. It provides hydrogen distribution and CCUS infrastructure across Liverpool Manchester and parts of Cheshire in support of the Government’s Clean Growth Strategy (CGS) and achievement of the UK’s emissions reduction targets.<br/>Hydrogen will be produced from natural gas and sent via a new pipeline to a range of industrial sites for injection as a blend into the existing natural gas network and for use as a transport fuel. Resulting carbon dioxide (CO2) will be captured and together with CO2 from local industry which is already available sent by pipeline for storage offshore in the nearby Liverpool Bay gas fields. Key data for the Project are presented in Table ES1.

Among the several typologies of storage technologies mainly on different physical principles (mechanical electrical and chemical) hydrogen produced by power to gas (P2G) from renewable energy sources complies with chemical storage principle and is based on the conversion of electrical energy into chemical energy by means of the electrolysis of water which does not produce any toxic or climate-relevant emission. This paper aims to pinpoint the potential uses of renewable hydrogen storage systems in Europe analysing current and potential locations regulatory framework governments’ outlooks economic issues and available renewable energy amounts. The expert opinion survey already used in many research articles on different topics including energy has been selected as an effective method to produce realistic results. The obtained results highlight strategies and actions to optimize the storage of hydrogen produced by renewables to face varying electricity demand and generation-driven fluctuations reducing the negative effects of the increasing share of renewables in the energy mix of European Countries.

The study analyses the role of hydrogen in the National Energy and Climate Plans (NECPs) and identifies and highlights opportunities for hydrogen technologies to contribute to effective and efficient achievement of the 2030 climate and energy targets of the EU and its Member States.<br/>The study focuses on the potential and opportunities of renewable hydrogen produced by electrolysers using renewable electricity and of low-carbon hydrogen produced by steam methane reforming combined with CCS. The opportunities for and impacts of hydrogen deployment are assessed and summarised in individual fiches per Member State.<br/>The study analyses to what extent policy measures and industrial initiatives are already being taken to facilitate large-scale implementation of hydrogen in the current and the next decades. The study concludes by determining the CO2 reduction potential beyond what is foreseen in the NECPs through hydrogen energy technologies estimating the reduction of fossil fuel imports and reliance the prospective cost and the value added and jobs created. National teams working on decarbonisation roadmaps and updates of the NECPs are welcome to consider the opportunities and benefits of hydrogen deployment identified in this study.

Hydrogen as a future energy carrier is receiving a significant amount of attention in Japan. From the viewpoint of safety risk evaluation is required in order to increase the number of hydrogen refuelling stations (HRSs) implemented in Japan. Collecting data about accidents in the past will provide a hint to understand the trend in the possibility of accidents occurrence by identifying its operation time However in new technology; accident rate estimation can have a high degree of uncertainty due to absence of major accident direct data in the late operational period. The uncertainty in the estimation is proportional to the data unavailability which increases over long operation period due to decrease in number of stations. In this paper a suitable time correlation model is adopted in the estimation to reflect lack (due to the limited operation period of HRS) or abundance of accident data which is not well supported by conventional approaches. The model adopted in this paper shows that the uncertainty in the estimation increases when the operation time is long owing to the decreasing data.

Plasmonic Ni nanoparticles were incorporated into LaFeO₃ photocathode (LFO-Ni) to excite the surface plasmon resonances (SPR) for enhanced light harvesting for enhancing the photoelectrochemical (PEC) hydrogen evolution reaction. The nanostructured LFO photocathode was prepared by spray pyrolysis method and Ni nanoparticles were incorporated on to the photocathode by spin coating technique. The LFO-Ni photocathode demonstrated strong optical absorption and higher current density where the untreated LFO film exhibited a maximum photocurrent of 0.036 mA/cm² at 0.6 V vs RHE and when incorporating 2.84 mmol Ni nanoparticles the photocurrent density reached a maximum of 0.066 mA/cm² at 0.6 V vs RHE due to the SPR effect. This subsequently led to enhanced hydrogen production where more than double (2.64 times) the amount of hydrogen was generated compared to the untreated LFO photocathode. Ni nanoparticles were modelled using Finite Difference Time Domain (FDTD) analysis and the results showed optimal particle size in the range of 70–100 nm for Surface Plasmon Resonance (SPR) enhancement.

Hydrogen evolution reaction (HER) plays a key role in generating clean and renewable energy. As the most effective HER electrocatalysts Pt group catalysts suffer from severe problems such as high price and scarcity. It is highly desirable to design and synthesize sustainable HER electrocatalysts to replace the Pt group catalysts. Due to their low cost high abundance and high activities cobalt-incorporated N-doped nanocarbon hybrids are promising candidate electrocatalysts for HER. In this report we demonstrated a robust and eco-friendly host-guest approach to fabricate metallic cobalt nanoparticles embedded in N-doped carbon fibers derived from natural silk fibers. Benefiting from the one-dimensional nanostructure the well-dispersed metallic cobalt nanoparticles and the N-doped thin graphitized carbon layer coating the best Co-based electrocatalyst manifests low overpotential (61 mV@10 mA/cm2) HER activity that is comparable with commercial 20% Pt/C and good stability in acid. Our findings provide a novel and unique route to explore high-performance noble-metal-free HER electrocatalysts.

This report summarises key themes emerging from the Energy Technologies Institute’s (ETI) project ‘Enabling efficient networks for low carbon futures’. The project aimed to explore the options for reforming the governance and regulatory arrangements to enable major changes to and investment in the UK’s energy network infrastructures. ETI commissioned four expert perspectives on the challenges and options facing the UK.

Hydrogen infrastructures are important for the commercialization of fuel cell vehicles. Hydrogen storage and transportation are significant topics because it is difficult to safely and effectively treat large amounts of hydrogen because of hydrogen hazards. An organic chemical hydride method keeps and provides hydrogen using hydrogenation and dehydrogenation chemical reactions with aromatic compounds. This method has advantages in that the conventional petrochemical products are used as a hydrogen carrier and petrochemicals are more easily treated than hydrogen because of low hazards. Hydrogen fueling stations are also crucial infrastructures for hydrogen supply. In Japan hybrid gasoline-hydrogen fuelling stations are needed for effective space utilization in urban areas. It is essential to address the safety issues of hybrid fueling stations for inherently safer station construction. We focused on a hybrid gasoline-hydrogen fuelling station with an on-site hydrogen production system using methylcyclohexane as an organic chemical hydride. The purpose of this study is to reveal unique hybrid risks in the station with a hazard identification study (HAZID study). As a result of the HAZID study we identified 314 accident scenarios involving gasoline and organic chemical hydride systems. In addition we suggested improvement safety measures for uniquely worst-case accident scenarios to prevent and mitigate the scenarios.

Governments around the world are leveraging unprecedented amounts of capital to respond to the pandemic and bailing out struggling industries. Trends in energy-related spending indicate that despite the green push the world’s largest economies have still favoured fossil energy over clean energy.<br/><br/>We evaluate energy-related spending in Canada in 2020 (since the onset of COVID-19) using data from the Energy Policy Tracker. Trends in Canada are then compared to flagship policies in key jurisdictions with recent progressive climate policy announcements including France Germany and the United Kingdom. The brief ends with broad recommendations on how Canada can better align its recovery funding with climate action and fossil fuel subsidy reform.<br/><br/>This brief is one of three International Institute for Sustainable Development (IISD) policy briefs in its Recovery Through Reform series which assesses how efforts to achieve a green recovery from COVID-19 in Canada rely on—and can contribute to—fossil fuel subsidy reform.

A key challenge for future clean power or hydrogen projects via gasification is the need to reduce the overall cost while achieving significant levels of CO2 capture. The current state of the art technology for capturing CO2 from sour syngas uses a physical solvent absorption process (acid gas removal–AGR) such as Selexol™ or Rectisol® to selectively separate H2S and CO2 from the H2. These two processes are expensive and require significant utility consumption during operation which only escalates with increasing levels of CO2 capture. Importantly Air Products has developed an alternative option that can achieve a higher level of CO2 capture than the conventional technologies at significantly lower capital and operating costs. Overall the system is expected to reduce the cost of CO2 capture by over 25%.<br/>Air Products developed this novel technology by leveraging years of experience in the design and operation of H2 pressure swing adsorption (PSA) systems in its numerous steam methane reformers. Commercial PSAs typically operate on clean syngas and thus need an upstream AGR unit to operate in a gasification process. Air Products recognized that a H2 PSA technology adapted to handle sour feedgas (Sour PSA) would enable a new and enhanced improvement to a gasification system. The complete Air Products CO2 Capture technology (CCT) for sour syngas consists of a Sour PSA unit followed by a low-BTU sour oxycombustion unit and finally a CO2 purification / compression system.

Sustainable secure and competitive energy supply and transport services are at the heart of the EU2020 strategy towards a low carbon and inclusive economy geared towards a reduction of 80% of CO2 emissions by 2050. This objective has been endorsed by the European Institutions and Member States. It is widely recognised that a technological shift and the deployment of new clean technologies are critical for a successful transition to such a new sustainable economy. Furthermore in addition to bringing a healthier environment and securing energy supply innovation will provide huge opportunities for the European economy.  However this paradigm shift will not be purely driven by the market. A strong and determined commitment of public institutions and the private sector together are necessary to support the European political ambition. The period 2014-2020 will be critical to ensure that the necessary investments are realized to support the EU2020 vision. In terms of hydrogen and fuel cell technologies significant investments are required for (a) transportation for scaling up the car fleet and building up of refuelling infrastructure needs (b) hydrogen production technologies to integrate renewable intermittent power sources to the electrical grid (wind and solar) (c) stationary fuel cell applications with large demonstration projects in several European cities and (d) identified early markets (material handling vehicles back-up power systems) to allow for volume developments and decrease of system-costs.<br/>This Report summarizes the sector’s financial ambition to reach Europe’s objectives in 2020.

Kinetic rate data for steam methane reforming (SMR) coupled with water gas shift (WGS) over an 18 wt. % NiO/α-Al₂O₃ catalyst are presented in the temperature range of 300–700 °C at 1 bar. The experiments were performed in a plug flow reactor under the conditions of diffusion limitations and away from the equilibrium conditions. The kinetic model was implemented in a one-dimensional heterogeneous mathematical model of catalytic packed bed reactor developed on gPROMS model builder 4.1.0®. The mathematical model of SMR process was simulated and the model was validated by comparing the results with the experimental values. The simulation results were in excellent agreement with the experimental results. The effect of various operating parameters such as temperature pressure and steam to carbon ratio on fuel and water conversion (%) H2 yield (wt. % of CH4) and H2 purity was modelled and compared with the equilibrium values.

On the occasion of its 10th Stakeholder forum the FCH JU published a unique and exclusive book. This book sets out the story behind both the FCH JU and fuel cell and hydrogen technology in Europe. It reviews the events leading to its creation and examines the achievements that have allowed Europe to take a leading role in fuel cell and hydrogen excellence. It also looks at what this investment in fuel cell technology will mean for the EU in the coming years

Fossil fuels have to be substituted by climate neutral fuels to contribute to CO₂ reduction in the future energy system. Pyrolysis of natural gas is a well-known technical process applied for production of e. g. carbon black.

In the future it might contribute to carbon dioxide-free hydrogen production. Production of hydrogen from natural gas pyrolysis has thus gained interest in research and energy technology in the near past. If the carbon by-product of this process can be used for material production or can be sequestrated the produced hydrogen has a low carbon footprint.

This article reviews literature on the state of the art of methane/ natural gas pyrolysis process developments and at-tempts to assess the technology readiness level (TRL).

Power-to-gas is a promising option for storing interment renewables nuclear baseload power and distributed energy and it is a novel concept for the transition to increased renewable content of current fuels with an ultimate goal of transition to a sustainable low-carbon future energy system that interconnects power transportation sectors and thermal energy demand all together. The aim of this paper is to introduce different Power-to-gas “pathways” including Power to Hydrogen Power to Natural Gas End-users Power to Renewable Content in Petroleum Fuel Power to Power Seasonal Energy Storage to Electricity Power to Zero Emission Transportation Power to Seasonal Storage for Transportation Power to Micro grid Power to Renewable Natural Gas (RNG) to Pipeline (“Methanation”) and Power to Renewable Natural Gas (RNG) to Seasonal Storage. In order to compare the different pathways the review of key technologies of Power-to-gas systems are studied and the qualitative efficiency and benefits of each pathway is investigated from the technical points of view. Moreover different Power-to-gas pathways are discussed as an energy policy option that can be implemented to transition towards a lower carbon economy for Ontario’s energy systems

The 2019 Programme Review Report presents the findings of a review into activities supported by the FCH 2 JU under the EU’s Seventh Framework Programme and Horizon 2020 by the European Commission’s Joint Research Centre (JRC ). It pays particular attention to the added value effectiveness and techno-economic efficiency of FCH 2 JU projects assigned to six review panels under two main pillars:<br/>Transport and Energy (TRANSPORT: a.trials and deployment of fuel cell applications and b.the next generation of products) (ENERGY: a.trials and deployment of fuel cell applications b.next generation of products and c.hydrogen for sectoral integration)<br/>Support for market uptake (cross-cutting activities such as standards and consumer awareness)<br/>This report covers all 81 projects that were ongoing for any time between April and October 2018 and assesses the strengths and accomplishments of each panel and areas that would benefit from further attention.

Britain stands on the cusp of a world-leading hydrogen revolution and one which we are almost uniquely positioned to take advantage of. With an extensive world-leading gas grid huge amounts of offshore wind resource and liquid energy markets there are few other places as well positioned as the UK to lead the international race to build a hydrogen economy. Published as part of Energy Networks Association’s Gas Goes Green programme Britain’s Hydrogen Network Plan will play a vital role in delivering the UK’s ambitions for hydrogen as set out in the Prime Minister’s Ten Point Plan For A Green Industrial Revolution.<br/>This Plan sets out how Britain’s gas network companies will enable 100% hydrogen to be transported for use in different sectors of the UK economy. It also identifies the wider actions needed to provide hydrogen production and storage showing how transitioning the gas networks to hydrogen will allow hydrogen to play a full role in achieving net zero in the hard to decarbonise sectors such as industry heavy transport and domestic heating saving an estimated 40 million tonnes of CO2 emissions every year. All five of Britain’s gas network companies responsible for owning and operating £24bn of critical national energy infrastructure are committing through this Plan to delivering this work. It forms a key part of their ambition to building the world’s first zero carbon gas grid here in the UK.<br/>Britain’s Hydrogen Network Plan is founded on four tenets that will underpin the role of Britain’s gas network infrastructure in a hydrogen economy. These tenets reflect the breadth and scale of the impact that the transformation of our gas networks will have. They will guide how gas network companies ensure people’s safety in a fast moving and changing energy system. They reflect how the companies will maintain security of supply to our homes and businesses as we move away from the natural gas that has been the bedrock of our energy system for half a century. They will support the public’s ability to choose the right technology so households and businesses can choose the low carbon technologies that are best suited to their needs. And they will deliver jobs and investment so the transition of our gas networks has a lasting and enduring economic impact in communities across the country.<br/>As we look to the future the exciting role that hydrogen has to play in delivering a net zero economy is becoming increasingly clear. We look forward to working closely with the customers we serve the Government and the wider energy industry to turn that ambition into reality.

Biomimetic sulfur-deficient indium sulfide (In_2.77S₄) was synthesized by a template-assisted hydrothermal method using leaves of Mimosa pudica as a template for the first time. The effect of this template in modifying the morphology of the semiconductor particles was determined by physicochemical characterization revealing an increase in surface area decrease in microsphere size and pore size and an increase in pore volume density in samples synthesized with the template. X-ray photoelectron spectroscopy (XPS) analysis showed the presence of organic sulfur (Ssingle bondO/Ssingle bondC/Ssingle bondH) and sulfur oxide species (single bondSO₂ SO₃²− SO₄²−) at the surface of the indium sulfide in samples synthesized with the template. Biomimetic indium sulfide also showed significant amounts of Fe introduced as a contaminant present on the Mimosa pudica leaves. The presence of these sulfur and iron species favors the photocatalytic activity for hydrogen production by their acting as a sacrificial reagent and promoting water oxidation on the surface of the templated particles respectively. The photocatalytic hydrogen production rates over optimally-prepared biomimetic indium sulfide and indium sulfide synthesized without the organic template were 73 and 22 μmol g⁻¹ respectively indicating an improvement by a factor of three in the templated sample.

Metal hydride (MH) thermal sorption compression is an efficient and reliable method allowing a conversion of energy from heat into a compressed hydrogen gas. The most important component of such a thermal engine – the metal hydride material itself – should possess several material features in order to achieve an efficient performance in the hydrogen compression. Apart from the hydrogen storage characteristics important for every solid H storage material (e.g. gravimetric and volumetric efficiency of H storage hydrogen sorption kinetics and effective thermal conductivity) the thermodynamics of the metal–hydrogen systems is of primary importance resulting in a temperature dependence of the absorption/desorption pressures). Several specific features should be optimised to govern the performance of the MH-compressors including synchronisation of the pressure plateaus for multi-stage compressors reduction of slope of the isotherms and hysteresis increase of cycling stability and life time together with challenges in system design associated with volume expansion of the metal matrix during the hydrogenation.<br/>The present review summarises numerous papers and patent literature dealing with MH hydrogen compression technology. The review considers (a) fundamental aspects of materials development with a focus on structure and phase equilibria in the metal–hydrogen systems suitable for the hydrogen compression; and (b) applied aspects including their consideration from the applied thermodynamic viewpoint system design features and performances of the metal hydride compressors and major applications.