Publications
Site-Dependent Environmental Impacts of Industrial Hydrogen Production by Alkaline Water Electrolysis
Jun 2017
Publication
Industrial hydrogen production via alkaline water electrolysis (AEL) is a mature hydrogen production method. One argument in favor of AEL when supplied with renewable energy is its environmental superiority against conventional fossil-based hydrogen production. However today electricity from the national grid is widely utilized for industrial applications of AEL. Also the ban on asbestos membranes led to a change in performance patterns making a detailed assessment necessary. This study presents a comparative Life Cycle Assessment (LCA) using the GaBi software (version 6.115 thinkstep Leinfelden-Echterdingen Germany) revealing inventory data and environmental impacts for industrial hydrogen production by latest AELs (6 MW Zirfon membranes) in three different countries (Austria Germany and Spain) with corresponding grid mixes. The results confirm the dependence of most environmental effects from the operation phase and specifically the site-dependent electricity mix. Construction of system components and the replacement of cell stacks make a minor contribution. At present considering the three countries AEL can be operated in the most environmentally friendly fashion in Austria. Concerning the construction of AEL plants the materials nickel and polytetrafluoroethylene in particular used for cell manufacturing revealed significant contributions to the environmental burden.
Detecting Hydrogen Concentrations During Admixing Hydrogen in Natural Gas Grids
Aug 2021
Publication
The first applications of hydrogen in a natural gas grid will be the admixing of low concentrations in an existing distribution grid. For easy quality and process control it is essential to monitor the hydrogen concentration in real time preferably using cost effective monitoring solutions. In this paper we introduce the use of a platinum based hydrogen sensor that can accurately (at 0.1 vol%) and reversibly monitor the concentration of hydrogen in a carrier gas. This carrier gas that can be nitrogen methane or natural gas has no influence on the accuracy of the hydrogen detection. The hydrogen sensor consists of an interdigitated electrode on a chip coated with a platinum nanocomposite layer that interacts with the gas. This chip can be easily added to a gas sensor for natural gas and biogas that was already developed in previous research. Just by the addition of an extra chip we extended the applicability of the natural gas sensor to hydrogen admixing. The feasibility of the sensor was demonstrated in our own (TNO) laboratory and at a field test location of the HyDeploy program at Keele University in the U.K
Electronic Structure and d-Band Center Control Engineering over Ni-Doped CoP3 Nanowall Arrays for Boosting Hydrogen Production
Jun 2021
Publication
To address the challenge of highly efficient water splitting into H2 successful fabrication of novel porous three-dimensional Ni-doped CoP3 nanowall arrays on carbon cloth was realized resulting in an effective self-supported electrode for the electrocatalytic hydrogen-evolution reaction. The synthesized samples exhibit rough curly and porous structures which are beneficial for gaseous transfer and diffusion during the electrocatalytic process. As expected the obtained Ni-doped CoP3 nanowall arrays with a doping concentration of 7% exhibit the promoted electrocatalytic activity. The achieved overpotentials of 176 mV for the hydrogen-evolution reaction afford a current density of 100 mA cm−2 which indicates that electrocatalytic performance can be dramatically enhanced via Ni doping. The Ni-doped CoP3 electrocatalysts with increasing catalytic activity should have significant potential in the field of water splitting into H2. This study also opens an avenue for further enhancement of electrocatalytic performance through tuning of electronic structure and d-band center by doping.
Assessment of a Fuel Cell Based-hybrid Energy System to Generate and Store Electrical Energy
Jan 2022
Publication
Solid oxide fuel cells (SOFC) have significant applications and performance and their integration into coupled and cascading energy systems can improve the overall performance of the process. Furthermore due to the constant time performance of the fuel cell the problem of fuel starvation may arise by changing the amount of load which can adversely affect the overall performance of the process. In the present study the excess heat of the SOFC is converted into electrical energy in two stages using different heat generators. The coupled energy system in the present article has a new configuration in which the relationship of its components is different from the systems reported in the literature. Furthermore since the use of an energy storage system can improve the overall reliability the energy produced by the coupled energy cycle is stored by a storage technology for peak consumption times. The introduced system can generate approximately 580 W of electrical power with an efficiency of 80%. The highest and lowest share in power generation is related to fuel cell with 82% and thermoelectric generator with 5%. The rest of the system power (i.e. 13%) is produced by thermionic generator. In addition the system requires 0.025 kg per hour of hydrogen fuel. It was also found that to operate the system for 5 h a day requires a storage system with a size of 3.3 m3 . Moreover two key issues to enhance the storage system performance are: adjusting the initial pressure of the system to values close to the peak (optimal) value and using turbines and/or pumps with higher efficiencies. With the aim of supplying 5 kWh of electrical energy five different scenarios based on the design of various effective parameters have been presented.
Interface Instabilities of Growing Hydrides
Jul 2016
Publication
Formation of metal hydrides is a serious complication that occur when hydride forming metals such as zirconium niobium vanadium and magnesium are exposed to long term hydrogen environment. The main concern is that the hydride as being a brittle material has very poor fracture mechanical properties. Formation of hydride is associated with transportation of hydrogen along the gradients of increasing hydrostatic stress which leads to crack tips and other stress concentrators where it forms the hydride. In the present study the thermodynamics of the evolving hydrides is studied. The process is driven by the release of free strain chemical and gradient energies. A phase field model is used to capture the driving forces that the release of the free energy causes. The study gives the conditions that lead to hydride advancement versus retreat and under which conditions the metal-hydride interface becomes unstable and develops a waviness. The spatial frequency spectrum leading to instability is found to depend on the ratio of the elastic strain energy density and parameters related to the interface energy.
Large-scale Stationary Hydrogen Storage via Liquid Organic Hydrogen Carriers
Aug 2021
Publication
Large-scale stationary hydrogen storage is critical if hydrogen is to fulfill its promise as a global energy carrier. While densified storage via compressed gas and liquid hydrogen is currently the dominant approach liquid organic molecules have emerged as a favorable storage medium because of their desirable properties such as low cost and compatibility with existing fuel transport infrastructure. This perspective article analytically investigates hydrogenation systems' technical and economic prospects using liquid organic hydrogen carriers (LOHCs) to store hydrogen at a large scale compared to densified storage technologies and circular hydrogen carriers (mainly ammonia and methanol). Our analysis of major system components indicates that the capital cost for liquid hydrogen storage is more than two times that for the gaseous approach and four times that for the LOHC approach. Ammonia and methanol could be attractive options as hydrogen carriers at a large scale because of their compatibility with existing liquid fuel infrastructure. However their synthesis and decomposition are energy and capital intensive compared to LOHCs. Together with other properties such as safety these factors make LOHCs a possible option for large-scale stationary hydrogen storage. In addition hydrogen transportation via various approaches is briefly discussed. We end our discussions by identifying important directions for future research on LOHCs.
Development of a Pneumatic Actuated Low-pressure Direct Injection Gas Injector for Hydrogen-fueled Internal Combustion Engines
Dec 2022
Publication
Mixture formation is one of the greatest challenges for the development of robust and efficient hydrogen-fueled internal combustion engines. In many reviews and research papers authors pointed out that direct injection (DI) has noteworthy advantages over a port fuel injection (PFI) such as higher power output higher efficiency the possibility of mixture stratification to control NOx-formation and reduce heat losses and above all to mitigate combustion abnormalities such as back-firing and pre-ignitions. When considering pressurized gas tanks for on-vehicle hydrogen storage a low-pressure (LP) injection system is advantageous since the tank capacity can be better exploited accordingly. The low gas density upstream of the injector requires cross-sectional areas far larger than any other injectors for direct injection in today's gasoline or diesel engines. The injector design proposed in this work consists of a flat valve seat to enable the achievement of lifetime requirements in heavy-duty applications. The gas supply pressure is used as the energy source for the actuation of the valve plate by means of a pneumatic actuator. This article describes the design and the performed tests carried out to prove the concept readiness of the new LP-DI-injector.
Advanced Hydrogen Storage of the Mg–Na–Al System: A Review
May 2021
Publication
A solid-state storage system is the most practical option for hydrogen because it is more convenient and safer. Metal hydrides especially MgH2 are the most promising materials that offer high gravimetric capacity and good reversibility. However the practical application of MgH2 is restricted by slow sorption kinetics and high stability of thermodynamic properties. Hydrogen storage performance of MgH2 was enhanced by introducing the Mg–Na–Al system that destabilises MgH2 with NaAlH4. The Mg–Na–Al system has superior performance compared to that of unary MgH2 and NaAlH4. To boost the performance of the Mg–Na–Al system the ball milling method and the addition of a catalyst were introduced. The Mg–Na–Al system resulted in a low onset decomposition temperature superior cyclability and enhanced kinetics performances. The Al12Mg17 and NaMgH3 that formed in situ during the dehydrogenation process modify the reaction pathway of the Mg–Na–Al system and alter the thermodynamic properties. In this paper the overview of the recent progress in hydrogen storage of the Mg–Na–Al system is detailed. The remaining challenges and future development of Mg–Na–Al system are also discussed. This paper is the first review report on hydrogen storage properties of the Mg–Na–Al system.
Optimal Scheduling of a Hydrogen-Based Energy Hub Considering a Stochastic Multi-Attribute Decision-Making Approach
Jan 2023
Publication
Nowadays the integration of multi-energy carriers is one of the most critical matters in smart energy systems with the aim of meeting sustainable energy development indicators. Hydrogen is referred to as one of the main energy carriers in the future energy industry but its integration into the energy system faces different open challenges which have not yet been comprehensively studied. In this paper a novel day-ahead scheduling is presented to reach the optimal operation of a hydrogen-based energy hub based on a stochastic multi-attribute decision-making approach. In this way the energy hub model is first developed by providing a detailed model of Power-to-Hydrogen (P2H) facilities. Then a new multi-objective problem is given by considering the prosumer’s role in the proposed energy hub model as well as the integrated demand response program (IDRP). The proposed model introduces a comprehensive approach from the analysis of the historical data to the final decision-making with the aim of minimizing the system operation cost and carbon emission. Moreover to deal with system uncertainty the scenario-based method is applied to model the renewable energy resources fluctuation. The proposed problem is defined as mixed-integer non-linear programming (MINLP) and to solve this problem a simple augmented e-constrained (SAUGMECON) method is employed. Finally the simulation of the proposed model is performed on a case study and the obtained results show the effectiveness and benefits of the proposed scheme.
Characterising Hydrogen Induced Cracking of Alloy 625+ Using Correlative SEM - EDX and NanoSIMS
Dec 2020
Publication
Hydrogen induced cracking behaviour of O&G nickel alloy 625+ (UNS N07716) was investigated. Deuterium was introduced electrochemically into samples by cathodic polarisation (3.5 wt.% NaCl.D2O) under different mechanical conditions. Subsequently deuterium distributions were mapped using NanoSIMS. Deuterium was used as an isotopic tracer instead of hydrogen to avoid the detection of hydrogen artefacts. Complimentary image analysis using scanning electron microscopy (SEM) and low voltage energy dispersive X-ray (EDX) allowed the identification of microstructural features corresponding to deuterium enrichments. The results provided experimental evidence of enrichments at dislocation slip bands (DSB) twin boundary and grain boundary features that include σ precipitates.
Alternative Fuels for Internal Combustion Engines
Aug 2020
Publication
The recent transport electrification trend is pushing governments to limit the future use of Internal Combustion Engines (ICEs). However the rationale for this strong limitation is frequently not sufficiently addressed or justified. The problem does not seem to lie within the engines nor with the combustion by themselves but seemingly rather with the rise in greenhouse gases (GHG) namely CO2 rejected to the atmosphere. However it is frequent that the distinction between fossil CO2 and renewable CO2 production is not made or even between CO2 emissions and pollutant emissions. The present revision paper discusses and introduces different alternative fuels that can be burned in IC Engines and would eliminate or substantially reduce the emission of fossil CO2 into the atmosphere. These may be non-carbon fuels such as hydrogen or ammonia or biofuels such as alcohols ethers or esters including synthetic fuels. There are also other types of fuels that may be used such as those based on turpentine or even glycerin which could maintain ICEs as a valuable option for transportation.
Magnesium-Based Materials for Hydrogen Storage—A Scope Review
Sep 2020
Publication
Magnesium hydride and selected magnesium-based ternary hydride (Mg2FeH6 Mg2NiH4 and Mg2CoH5) syntheses and modification methods as well as the properties of the obtained materials which are modified mostly by mechanical synthesis or milling are reviewed in this work. The roles of selected additives (oxides halides and intermetallics) nanostructurization polymorphic transformations and cyclic stability are described. Despite the many years of investigations related to these hydrides and the significant number of different additives used there are still many unknown factors that affect their hydrogen storage properties reaction yield and stability. The described compounds seem to be extremely interesting from a theoretical point of view. However their practical application still remains debatable.
Methanol Synthesis Using Captured CO2 as Raw Material: Techno-economic and Environmental Assessment
Aug 2015
Publication
The purpose of this paper is to assess via techno-economic and environmental metrics the production of methanol (MeOH) using H2 and captured CO2 as raw materials. It evaluates the potential of this type of carbon capture and utilisation (CCU) plant on (i) the net reduction of CO2 emissions and (ii) the cost of production in comparison with the conventional synthesis process of MeOH Europe. Process flow modelling is used to estimate the operational performance and the total purchased equipment cost; the flowsheet is implemented in CHEMCAD and the obtained mass and energy flows are utilised as input to calculate the selected key performance indicators (KPIs). CO2 -based metrics are used to assess the environmental impact. The evaluated MeOH plant produces 440 ktMeOH/yr and its configuration is the result of a heat integration process. Its specific capital cost is lower than for conventional plants. However raw materials prices i.e. H2 and captured CO2 do not allow such a project to be financially viable. In order to make the CCU plant financially attractive the price of MeOH should increase in a factor of almost 2 or H2 costs should decrease almost 2.5 times or CO2 should have a value of around 222 €/t under the assumptions of this work. The MeOH CCU-plant studied can utilise about 21.5% of the CO2 emissions of a pulverised coal (PC) power plant that produces 550MWnet of electricity. The net CO2 emissions savings represent 8% of the emissions of the PC plant (mainly due to the avoidance of consuming fossil fuels as in the conventional MeOH synthesis process). The results demonstrate that there is a net but small potential for CO2 emissions reduction; assuming that such CCU plants are constructed in Europe to meet the MeOH demand growth and the quantities that are currently imported the net CO2 emissions reduction could be of 2.71 MtCO2/yr.
Life-Cycle Greenhouse Gas Emissions Of Biomethane And Hydrogen Pathways In The European Union
Oct 2021
Publication
Gaseous fuels with low life-cycle emissions of greenhouse gases (GHG) play a prominent role in the European Union’s (EU) decarbonization plans. Renewable and low-GHG hydrogen are highlighted in the ambitious goals for a cross-sector hydrogen economy laid out in the European Commission’s Hydrogen Strategy. Renewable hydrogen and biomethane are given strong production incentives in the Commission’s proposed revision to the Renewable Energy Directive (REDII). The EU uses life-cycle analysis (LCA) to determine whether renewable gas pathways meet the GHG reduction thresholds for eligibility in the REDII. This study aims to support European policymakers with a better understanding of the uncertainties regarding gaseous fuels’ roles in meeting climate goals. Life-cycle GHG analysis is complex and differences in methodology as well as data inputs and assumptions can spell the difference between a renewable gas pathway qualifying or not for REDII eligibility at the 50% to 80% GHG reduction level. It is thus important for European policymakers to use robust LCA to ensure that policy only supports gas pathways consistent with a vision of deep decarbonization. For this purpose we conduct sensitivity analysis of the life-cycle GHG emissions of a number of low-GHG gas pathways including biomethane produced from four feedstocks: wastewater sludge manure landfill gas (LFG) and silage maize; and hydrogen produced from eight sources: natural gas combined with carbon capture and storage (CCS) coal with CCS biomass gasification renewable electricity 2030 EU grid electricity wastewater sludge biomethane manure biomethane and LFG biomethane. For each pathway we estimate the life-cycle GHG intensity using a default central case identify key parameters that strongly affect the fuel’s GHG intensity and conduct a sensitivity analysis by changing these key parameters according to the range of possible values collected from the literature. Figure ES1 summarizes the full range of possible GHG intensities for each gaseous pathway we analyzed in this study—biomethane is depicted in the top figure and hydrogen is shown in the bottom. The bars represent the GHG intensity of the central case and vertical error bars indicate the maximum and minimum GHG intensity of each pathway according to our sensitivity analysis. The dotted orange horizontal line illustrates the fossil comparator which is 94 grams of carbon dioxide equivalent per megajoule (gCO2e/MJ) for transport fuels in the REDII. The dotted yellow line represents the GHG intensity of a 65% GHG reduction goal for biomethane used in the transportation sector or 70% GHG reduction for hydrogen. Pathways are situated from left to right in increasing order of GHG intensity of the central case. Comparing the central cases of the four biomethane pathways the waste-based biomethane pathways generally have negative GHG intensity. However considering the uncertainty in these GHG intensities manure biomethane might have more limited carbon reduction potential in the 100-year timeframe if methane leakage from its production process is high. In contrast wastewater sludge biomethane and LFG biomethane even after accounting for uncertainties retain relatively low GHG emissions. On the other hand biomethane produced from silage maize can have much higher emissions; in the central case we find that silage maize biogas only reduces GHG emissions by 30% relative to the fossil comparator—the low carbon reduction potential is due to the significant emissions emerging from direct and indirect land use change involved in growing maize. Taking into account the variation in assumptions silage maize biomethane can be worse for the climate than fossil fuels.
Catalytic Hydrogen Production, Storage and Application
Jul 2021
Publication
Hydrogen is a clean fuel for transportation and energy storage. It has several attractive features including a higher energy content by weight use in fuel cells that produces only water as a by-product storage in small and large quantities by various methods and established transportation and infrastructures. A hydrogen economy consists of three steps i.e. hydrogen production storage and applications. All three steps involved in a hydrogen economy can be divided into catalytic and non-catalytic approaches. For catalytic processes the efficiency highly depends on the type and physico-chemical characteristics of the catalysts. Therefore for the improvement of these catalytic processes the development of highly efficient and stable catalysts is highly required.
Analysis of Hydrogen Production Potential from Waste Plastics by Pyrolysis and In Line Oxidative Steam Reforming
Oct 2021
Publication
A study was carried out on the valorization of different waste plastics (HDPE PP PS and PE) their mixtures and biomass/HDPE mixtures by means of pyrolysis and in line oxidative steam reforming. A thermodynamic equilibrium simulation was used for determining steam reforming data whereas previous experimental results were considered for setting the pyrolysis volatile stream composition. The adequacy of this simulation tool was validated using experimental results obtained in the pyrolysis and in line steam reforming of different plastics. The effect the most relevant process conditions i.e. temperature steam/plastic ratio and equivalence ratio have on H2 production and reaction enthalpy was evaluated. Moreover the most suitable conditions for the oxidative steam reforming of plastics of different nature and their mixtures were determined. The results obtained are evidence of the potential interest of this novel valorization route as H2 productions of up to 25 wt% were obtained operating under autothermal conditions.
Optimisation-based System Designs for Deep Offshore Wind Farms including Power to Gas Technologies
Feb 2022
Publication
A large deployment of energy storage solutions will be required by the stochastic and non-controllable nature of most renewable energy sources when planning for higher penetration of renewable electricity into the energy mix. Various solutions have been suggested for dealing with medium- and long-term energy storage. Hydrogen and ammonia are two of the most frequently discussed as they are both carbon-free fuels. In this paper the authors analyse the energy and cost efficiency of hydrogen and ammonia-based pathways for the storage transportation and final use of excess electricity from an offshore wind farm. The problem is solved as a linear programming problem simultaneously optimising the size of each problem unit and the respective time-dependent operational conditions. As a case study we consider an offshore wind farm of 1.5 GW size located in a reference location North of Scotland. The energy efficiency and cost of the whole chain are evaluated and compared with competitive alternatives namely batteries and liquid hydrogen storage. The results show that hydrogen and ammonia storage can be part of the optimal solution. Moreover their use for long-term energy storage can provide a significant cost-effective contribution to an extensive penetration of renewable energy sources in national energy systems.
Calibrating a Ductile Damage Model for Two Pipeline Steels: Method and Challenges
Dec 2020
Publication
This work is part of a project that aims to develop a micromechanics based damage law taking into account hydrogen assisted degradation. A 'vintage' API 5L X56N and a 'modern' API 5L X70M pipeline steel have been selected for this purpose. The paper focuses on an experimental calibration of ductile damage properties of the well known complete Gurson model for the two steels in absence of hydrogen. A basic microstructural characterization is provided showing a banded ferrite-pearlite microstructure for both steels. Charpy impact tests showed splits at the fracture surface for the X70 steel. Double-notched round bar tensile tests are performed aiming to provide the appropriate input for damage model calibration. The double-notched nature of the specimens allows to examine the material state at maximum load in the unfailed notch and the final material state in the failed notch. Different notch radii are used capturing a broad range of positive stress triaxialities. The notches are optically monitored for transverse necking in two perpendicular directions (transverse to rolling and through thickness) to reveal any anisotropy in plastic deformation and/or damage. It is explained how the occurrence of splits at the segregation zone and anisotropy complicate the calibration procedure. Calibration is done for each steel and acceptable results are obtained. However the occurrence of splits did not allow to evaluate the damage model for the highest levels of tested stress triaxiality.
Photovoltaic and Hydrogen Plant Integrated with a Gas Heat Pump for Greenhouse Heating: A Mathematical Study
Feb 2018
Publication
Nowadays the traditional energy sources used for greenhouse heating are fossil fuels such as LPG diesel and natural gas. The global energy demand will continue to grow and alternative technologies need to be developed in order to improve the sustainability of crop production in protected environments. Innovative solutions are represented by renewable energy plants such as photovoltaic wind and geothermal integrated systems however these technologies need to be connected to the power grid in order to store the energy produced. On agricultural land power grids are not widespread and stand-alone renewable energy systems should be investigated especially for greenhouse applications. The aim of this research is to analyze by means of a mathematical model the energy efficiency of a photovoltaic (8.2 kW) hydrogen (2.5 kW) and ground source gas heat pump (2.2 kW) integrated in a stand-alone system used for heating an experimental greenhouse tunnel (48 m2 ) during the winter season. A yearlong energy performance analysis was conducted for three different types of greenhouse cover materials a single layer polyethylene film an air inflated-double layer polyethylene film and a double acrylic or polycarbonate. The results of one year showed that the integrated system had a total energy efficiency of 14.6%. Starting from the electric energy supplied by the photovoltaic array the total efficiency of the hydrogen and ground source gas heat pump system was 112% if the coefficient of the performance of the heat pump is equal to 5. The heating system increased the greenhouse air temperatures by 3–9 ◦C with respect to the external air temperatures depending on the greenhouse cover material used.
HyDeploy Report: Exemption
Oct 2018
Publication
Exemption is requested from the obligation set out in Regulation 8(1) of the Gas Safety (Management) Regulations 1996 (GSMR) to convey only natural gas that is compliant with the Interchangeability requirements of Part I of Schedule 3 of the GSMR within the G3 element of the Keele University gas distribution network (KU-GDN). The KU-GDN is owned and operated by Keele University. The proposed conveyance of non-compliant gas (hereafter called the “HyDeploy Field Trial”) will last for one year of injection and is part of a Network Innovation Competition Project “HyDeploy”. The project aims to demonstrate that natural gas containing hydrogen at a level above that normally permitted by Schedule 3 of the GSMR can be safely and efficiently conveyed and inform decisions on the feasibility and strategy for wider deployment of natural gas containing hydrogen in Great Britain’s (GB’s) gas transmission and gas distribution systems.<br/>Click the supplements tab for the other documents from this report.
The Effect of the Temperature and Moisture to the Permeation Properties of PEO-Based Membranes for Carbon-Dioxide Separation
Jun 2021
Publication
An increased demand for energy in recent decades has caused an increase in the emissions of combustion products among which carbon-dioxide is the most harmful. As carbon-dioxide induces negative environmental effects like global warming and the greenhouse effect a decrease of the carbon-dioxide emission has emerged as one of the most urgent tasks in engineering. In this work the possibility for the application of the polymer-based dense mixed matrix membranes for flue gas treatment was tested. The task was to test a potential decrease in the permeability and selectivity of a mixed-matrix membrane in the presence of moisture and at elevated temperature. Membranes are based on two different poly(ethylene oxide)-based polymers filled with two different zeolite powders (ITR and IWS). An additive of detergent type was added to improve the contact properties between the zeolite and polymer matrix. The measurements were performed at three different temperatures (30 60 and 90 °C) under wet conditions with partial pressure of the water equal to the vapor pressure of the water at the given temperature. The permeability of carbon-dioxide hydrogen nitrogen and oxygen was measured and the selectivity of the carbon-dioxide versus other gases was determined. Obtained results have shown that an increase of temperature and partial pressure of the vapor slightly increase both the selectivity and permeability of the synthesized membranes. It was also shown that the addition of the zeolite powder increases the permeability of carbon-dioxide while maintaining the selectivity compared to hydrogen oxygen and nitrogen.
CFD Analysis of Fast Filling Strategies for Hydrogen Tanks and their Effects on Key-parameters
Nov 2014
Publication
A major requirement for the filling of hydrogen tanks is the maximum gas temperature within the vessels during the process. Different filling strategies in terms of pressure and temperature of the gas injected into the cylinder and their effects on key parameters like maximum temperature state of charge and energy cooling demand are investigated. It is shown that pre-cooling of the gas is required but is not necessary for the whole duration of the filling. Relevant energy savings can be achieved with pre-cooling over a fraction of the time. The most convenient filling strategy from the cooling energy point of view is identified: with an almost linear pressure rise and pre-cooling in the second half of the process a 60% reduction of the cooling energy demand is achieved compared to the case of pre-cooling for the whole filling.
A Review of Fuel Cell Systems for Maritime Applications
Jul 2016
Publication
Progressing limits on pollutant emissions oblige ship owners to reduce the environmental impact of their operations. Fuel cells may provide a suitable solution since they are fuel efficient while they emit few hazardous compounds. Various choices can be made with regard to the type of fuel cell system and logistic fuel and it is unclear which have the best prospects for maritime application. An overview of fuel cell types and fuel processing equipment is presented and maritime fuel cell application is reviewed with regard to efficiency gravimetric and volumetric density dynamic behaviour environmental impact safety and economics. It is shown that low temperature fuel cells using liquefied hydrogen provide a compact solution for ships with a refuelling interval up to a tens of hours but may result in total system sizes up to five times larger than high temperature fuel cells and more energy dense fuels for vessels with longer mission requirements. The expanding infrastructure of liquefied natural gas and development state of natural gas-fuelled fuel cell systems can facilitate the introduction of gaseous fuels and fuel cells on ships. Fuel cell combined cycles hybridisation with auxiliary electricity storage systems and redundancy improvements are identified as topics for further study
Unconventional Pearlitic Pseudocolonies Affecting Macro-, Micro- and Nano-structural Integrity of Cold-drawn Pearlitic Steel Wires: Resembling van Gogh, Bernini, Mantegna and Picasso
Dec 2020
Publication
Prestressing steel wires are manufactured by cold drawing during which a preferential orientation is achieved in the matter of pearlitic colonies and lamellae. In addition to this general trend special (unconventional) pearlitic pseudocolonies evolve during the heavy-drawing manufacture process affecting the posterior macro- micro- and nano-structural integrity of the material. This paper discusses the important role of such a special microstructural unit (the pearlitic pseudocolony) in the fracture process in air (inert) environment in the presence of crack-like defects as well as in the case of environmentally assisted cracking (stress corrosion cracking by localized anodic dissolution) or hydrogen embrittlement. Results clearly demonstrate the key role of pearlitic pseudocolonies in promoting crack deflection (and thus mixed-mode propagation) after a global mode I cracking especially in the case of fracture in air and stress corrosion cracking.
Optimal Supply Chains and Power Sector Benefits of Green Hydrogen
Jul 2021
Publication
Green hydrogen can help to decarbonize parts of the transportation sector but its power sector interactions are not well understood so far. It may contribute to integrating variable renewable energy sources if production is sufficiently flexible in time. Using an open-source co-optimization model of the power sector and four options for supplying hydrogen at German filling stations we find a trade-of between energy efficiency and temporal flexibility. For lower shares of renewables and hydrogen more energy-efficient and less flexible small-scale on-site electrolysis is optimal. For higher shares of renewables and/or hydrogen more flexible but less energy-efficient large-scale hydrogen supply chains gain importance as they allow to temporally disentangle hydrogen production from demand via storage. Liquid hydrogen emerges as particularly beneficial followed by liquid organic hydrogen carriers and gaseous hydrogen. Large-scale hydrogen supply chains can deliver substantial power sector benefits mainly through reduced renewable curtailment. Energy modelers and system planners should consider the distinct flexibility characteristics of hydrogen supply chains in more detail when assessing the role of green hydrogen in future energy transition scenarios. We also propose two alternative cost and emission metrics which could be useful in future analyses.
A Comparative Review of Alternative Fuels for the Maritime Sector: Economic, Technology, and Policy Challenges for Clean Energy Implementation
Oct 2021
Publication
Global maritime transportation is responsible for around 3% of total anthropogenic green‐ house gas emissions and significant proportions of SOx NOx and PM emissions. Considering the predicted growth in shipping volumes to 2050 greenhouse gas emissions from ships must be cut by 75–85% per ton‐mile to meet Paris Agreement goals. This study reviews the potential of a range of alternative fuels for decarbonisation in maritime. A systematic literature review and information synthesis method was applied to evaluate fuel characteristics production pathways utilization technologies energy efficiency lifecycle environmental performance economic viability and cur‐ rent applicable policies. Alternative fuels are essential to decarbonisation in international shipping. However findings suggest there is no single route to deliver the required greenhouse gas emissions reductions. Emissions reductions vary widely depending on the production pathways of the fuel. Alternative fuels utilising a carbon‐intensive production pathway will not provide decarbonisation instead shifting emissions elsewhere in the supply chain. Ultimately a system‐wide perspective to creating an effective policy framework is required in order to promote the adoption of alternative propulsion technologies.
Degradation Mechanisms in the Operation of Pressured Pipelines
Aug 2019
Publication
Many non-standard situations like subsoil slipping vibrations ... as well as degradation mechanisms of pipeline materials can occur in the operation of pressured pipelines. The article deals with the mechanisms of the degradation processes and their formation like corrosion brittleness and steel ageing that may occur in operation of pipeline systems. Material ageing of steels is documented on specimens created from pipeline materials and obtained by experimental measurements on these specimens after the multi-annual operation.
Numerical Evaluation of the Effect of Fuel Blending with CO2 and H2 on the Very Early Corona‐Discharge Behavior in Spark Ignited Engines
Feb 2022
Publication
Reducing green‐house gases emission from light‐duty vehicles is compulsory in order to slow down the climate change. The application of High Frequency Ignition systems based on the Corona discharge effect has shown the potential to extend the dilution limit of engine operating conditions promoting lower temperatures and faster combustion events thus higher thermal and indicating efficiency. Furthermore predicting the behavior of Corona ignition devices against new sustainable fuel blends including renewable hydrogen and biogas is crucial in order to deal with the short‐intermediate term fleet electric transition. The numerical evaluation of Corona‐induced discharge radius and radical species under those conditions can be helpful in order to capture local effects that could be reached only with complex and expensive optical investigations. Using an ex‐ tended version of the Corona one‐dimensional code previously published by the present authors the simulation of pure methane and different methane–hydrogen blends and biogas–hydrogen blends mixed with air was performed. Each mixture was simulated both for 10% recirculated exhaust gas dilution and for its corresponding dilute upper limit which was estimated by means of chemical kinetics simulations integrated with a custom misfire detection criterion.
HyDeploy Report: Quantitative Risk Assessment of the Field Trial of Hydrogen Injection into the Keele University Gas Distribution System
Oct 2018
Publication
A consortium comprising Cadent Northern Gas Networks Keele University Health and Safety Laboratory ITM Power and Progressive Energy is undertaking the research project HyDeploy. The project funded under the UK Network Innovation Competition scheme aims to demonstrate that natural gas containing levels of hydrogen beyond the upper limit set out in Schedule 3 of in the Gas Safety (Management) Regulations (GSMR) can be distributed and utilised safely and efficiently in a section of the UK distribution network. It will conclude with a field trial in which hydrogen will be injected into part of a private gas distribution system owned and operated by Keele University. Dave Lander Consulting Limited and Kiwa Ltd are providing technical support to the HyDeploy project and this report presents the results of Quantified Risk Assessment (QRA) for the proposed field trial. The QRA is intended to support an application by Keele University for exemption from the legal requirement to only convey gas that is compliant with the requirements of Schedule 3 of the GSMR. The QRA is aimed at demonstrating that the field trial will not result in a material increase in risk to persons within Keele University affected by the proposed field trial.<br/>Check the supplements tab for the other documents from this report
Road Map to a US Hydrogen Energy: Reducing Emissions and Driving Growth Across the Nation
Oct 2020
Publication
This US Hydrogen Road Map was created through the collaboration of executives and technical industry experts in hydrogen across a broad range of applications and sectors who are committed to improving the understanding of hydrogen and how to increase its adoption across many sectors of the economy. For the first time this coalition of industry leaders has convened to develop a targeted holistic approach for expanding the use of hydrogen as an energy carrier. Due to great variation among national and state policies infrastructure needs and community interests each state and region of the US will likely have its own specific policies and road maps for implementing hydrogen infrastructure. The West Coast for example has traditionally had progressive policies on reducing transportation emissions so it is likely that hydrogen will scale sooner for vehicles in this region especially California. Experts also acknowledge the role that hydrogen in combination with renewables can play in supplying microgrid-type power to communities with the highest risk of shut-offs during seasonal weather-related issues such as high temperatures or wildfire-related power interruptions. Some states have emphasized the need to decarbonize the gas grid so blending hydrogen in natural gas networks and using hydrogen as feedstock may advance more quickly in these regions. Other states are interested in hydrogen as a means to address power grid issues enable the deployment of renewables and support competitive nuclear power. The launch of hydrogen technologies in some states or regions will help to scale hydrogen in various applications across the country laying the foundation for energy security grid resiliency economic growth and the reduction of both greenhouse gas (GHG) emissions and air pollutants. This report outlines the benefits and impact of fuel cell technologies and hydrogen as a viable solution to the energy challenges facing the US through 2030 and beyond. As such it can serve as the latest comprehensive industry-driven national road map to accelerate and scale up hydrogen in the economy across North America
Toward a Non-destructive Diagnostic Analysis Tool of Exercises Pipelines: Models and Experiences
Dec 2018
Publication
Strategic networks of hydrocarbon pipelines in long time service are adversely affected by the action of aggressive chemicals transported with the fluids and dissolved in the environment. Material degradation phenomena are amplified in the presence of hydrogen and water elements that increase the material brittleness and reduce the safety margins. The risk of failure during operation of these infrastructures can be reduced if not prevented by the continuous monitoring of the integrity of the pipe surfaces and by the tracking of the relevant bulk properties. A fast and potentially non-destructive diagnostic tool of material degradation which may be exploited in this context is based on the instrumented indentation tests that can be performed on metals at different scales. Preliminary validation studies of the significance of this methodology for the assessment of pipeline integrity have been carried out with the aid of interpretation models of the experiments. The main results of this ongoing activity are illustrated in this contribution.
Electrochemical Fracture Analysis of In-service Natural Gas Pipeline Steels
Dec 2018
Publication
Long-term operation of natural gas transit pipelines implies aging hydrogen-induced and stress corrosion cracking and it causes hydrogen embrittlement of steels degradation of mechanical properties associated to a safe serviceability of pipelines and failure risk increase. The implementation of effective diagnostic measures of pipelines steels degradation would allow planning actions in order to reduce a risk of fracture. In this paper a new scientific and methodical approach based on the electrochemical analysis of fracture surface for evaluation of in-service degradation of operated pipeline steels was developed. It was suggested that carbon diffusion to grain boundaries and to defects inside grains intensified by hydrogen under long-term operation led to formation of nanoparticles of carbides which resulted in intergranular cracking of operated pipeline steels under service and their transgranular cracking under impact toughness testing. Therefore fracture surface was enriched by carbon compounds and electrochemical characteristics were sensitive to this. In-service degradation of ferrite-pearlite pipeline steels was accompanied by a sharp shift in open-circuit potential of the fracture surface (brittle fracture) of specimens after impact toughness tests compared with that of polished steel surfaces. A significant difference between potentials of the fracture surface and the polished steel surface (over 60 mV in 0.3% NaCl solution) of specimens made of ferrite-pearlite pipeline steels observed after their long-term operation was evidently due to the increased content of carbon compounds on the fracture surface. Mechanism of ferrite-pearlite pipeline steels embrittlement under operation consisted in carbides enrichment not only grain boundaries but also intragranular defects has been revealed as it is indicated by an increase of carbon content on transgranular fracture surfaces determined electrochemically.
Proposal and Verification of Novel Fatigue Crack Propagation Simulation Method by Finite Element Method.
Dec 2018
Publication
In this paper we propose and verify a novel method to simulate crack propagation without propagating a crack by finite element method. We propose this method for elastoplastic analysis coupled with convection-diffusion. In the previous study we succeeded in performing elastoplastic analysis coupled with convection-diffusion of hydrogen for a material with a crack under tensile loading. This research extends the successful method to fatigue crack propagation. In convection-diffusion analysis in order to simulate the invasion and release of elements through the free surface the crack tip is expressed by using a notch with a sufficiently small radius. Therefore the node release method conventionally used to simulate crack propagation cannot be applied. Hence instead of crack propagation based on an analytical model we propose a novel method that can reproduce the influence of the vicinity of the crack tip on a crack. We moved the stress field near the crack tip in the direction opposite to that of crack propagation by an amount corresponding to the crack propagation length. When we extend the previous method to fatigue crack propagation simulation we must consider the difference in strain due to loading and unloading. This problem was solved by considering the strain due to loading as a displacement. Instead of moving the strain due to loading we moved the displacement. First we performed a simple tensile load analysis on the model and output the displacement of all the nodes of the model at maximum load. Then the displacement was moved in the direction opposite to that of crack propagation. Finally the stress field was reproduced by forcibly moving all the nodes by the displacement amount. The strain due to unloading was reproduced by removing the displacement. Furthermore we verified the equivalence of the crack propagation simulation and the proposed method.
The Role of Green and Blue Hydrogen in the Energy Transition—A Technological and Geopolitical Perspective
Dec 2020
Publication
Hydrogen is currently enjoying a renewed and widespread momentum in many national and international climate strategies. This review paper is focused on analysing the challenges and opportunities that are related to green and blue hydrogen which are at the basis of different perspectives of a potential hydrogen society. While many governments and private companies are putting significant resources on the development of hydrogen technologies there still remains a high number of unsolved issues including technical challenges economic and geopolitical implications. The hydrogen supply chain includes a large number of steps resulting in additional energy losses and while much focus is put on hydrogen generation costs its transport and storage should not be neglected. A low-carbon hydrogen economy offers promising opportunities not only to fight climate change but also to enhance energy security and develop local industries in many countries. However to face the huge challenges of a transition towards a zero-carbon energy system all available technologies should be allowed to contribute based on measurable indicators which require a strong international consensus based on transparent standards and targets.
A Holistic Consideration of Megawatt Electrolysis as a Key Component of Sector Coupling
May 2022
Publication
In the future hydrogen (H2) will play a significant role in the sustainable supply of energy and raw materials to various sectors. Therefore the electrolysis of water required for industrial‐ scale H2 production represents a key component in the generation of renewable electricity. Within the scope of fundamental research work on cell components for polymer electrolyte membrane (PEM) electrolyzers and application‐oriented living labs an MW electrolysis system was used to further improve industrial‐scale electrolysis technology in terms of its basic structure and systems‐ related integration. The planning of this work as well as the analytical and technical approaches taken along with the essential results of research and development are presented herein. The focus of this study is the test facility for a megawatt PEM electrolysis stack with the presentation of the design processing and assembly of the main components of the facility and stack.
Techno-economic Analysis of Hydrogen Electrolysis from Off-Grid Stand-Alone Photovoltaics Incorporating Uncertainty Analysis
Oct 2020
Publication
Solar-driven electrolysis of water to generate hydrogen is emerging as a viable strategy to decarbonize the global energy economy. However this direction is more expensive than traditional fossil fuel generation of hydrogen and effective pathways to lower this cost need to be identified. Here we report a Monte Carlo approach to explore a wide range of input assumptions to identify key cost drivers targets and localized conditions necessary for competitive stand-alone dedicated PV powered hydrogen electrolysis. We determine the levelized cost of hydrogen (LCOH) considering historical weather data for specific locations to model our PV system and optimize its size compared to the electrolyzer. This analysis and its methods show the potential for green hydrogen production using off-grid PV shows the merits of remote systems in areas of high solar resource and provides cost and performance targets for electrolyzer technologies.
Solid-State Hydrogen Storage Systems and the Relevance of a Gender Perspective
Sep 2021
Publication
This paper aims at addressing the exploitation of solid-state carriers for hydrogen storage with attention paid both to the technical aspects through a wide review of the available integrated systems and to the social aspects through a preliminary overview of the connected impacts from a gender perspective. As for the technical perspective carriers to be used for solid-state hydrogen storage for various applications can be classified into two classes: metal and complex hydrides. Related crystal structures and corresponding hydrogen sorption properties are reviewed and discussed. Fundamentals of thermodynamics of hydrogen sorption evidence the key role of the enthalpy of reaction which determines the operating conditions (i.e. temperatures and pressures). In addition it rules the heat to be removed from the tank during hydrogen absorption and to be delivered to the tank during hydrogen desorption. Suitable values for the enthalpy of hydrogen sorption reaction for operating conditions close to ambient (i.e. room temperature and 1–10 bar of hydrogen) are close to 30 kJ·molH2 −1 . The kinetics of the hydrogen sorption reaction is strongly related to the microstructure and to the morphology (i.e. loose powder or pellets) of the carriers. Usually the kinetics of the hydrogen sorption reaction is rather fast and the thermal management of the tank is the rate-determining step of the processes. As for the social perspective the paper arguments that as it occurs with the exploitation of other renewable innovative technologies a wide consideration of the social factors connected to these processes is needed to reach a twofold objective: To assess the extent to which a specific innovation might produce positive or negative impacts in the recipient socioeconomic system and from a sociotechnical perspective to explore the potential role of the social components and dynamics in fostering the diffusion of the innovation itself. Within the social domain attention has been paid to address the underexplored relationship between the gender perspective and the enhancement of hydrogen-related energy storage systems. This relationship is taken into account both in terms of the role of women in triggering the exploitation of hydrogen-based storage playing as experimenter and promoter and in terms of the intertwined impact of this innovation in their current conditions at work and in daily life.
Hybrid Hydrogen–PV–e-Mobility Industrial Energy Community Concept—A Technology Feasibility Study
Sep 2021
Publication
As renewable energy sources are spreading the problems of energy usage transport and storage arise more frequently. In order that the performance of energy producing units from renewable sources which have a relatively low efficiency should not be decreased further and to promote sustainable energy consumption solutions a living lab conception was elaborated in this project. At the pilot site the produced energy (by PV panels gas turbines/engines) is stored in numerous ways including hydrogen production. The following uses of hydrogen are explored: (i) feeding it into the national natural gas network; (ii) selling it at a H-CNG (compressed natural gas) filling station; (iii) using it in fuel cells to produce electricity. This article introduces the overall implementation plan which can serve as a model for the hybrid energy communities to be established in the future.
Dynamic Simulation and Thermoeconomic Analysis of a Hybrid Renewable System Based on PV and Fuel Cell Coupled with Hydrogen Storage
Nov 2021
Publication
The production of “green hydrogen” is currently one of the hottest topics in the field of renewable energy systems research. Hydrogen storage is also becoming more and more attractive as a flexible solution to mitigate the power fluctuations of solar energy systems. The most promising technology for electricity-to-hydrogen conversion and vice versa is the reversible solid-oxide cell (SOC). This device is still very expensive but it exhibits excellent performance under dynamic operating conditions compared to the competing devices. This work presents the dynamic simulation of a prototypal renewable plant combining a 50 kW photovoltaic (PV) field with a 50 kW solid-oxide electrolyzer cell (SOEC) and a compressed hydrogen tank. The electricity is used to meet the energy demand of a dwelling located in the area of Campi Flegrei (Naples). The SOC efficiency is simulated by developing a mathematical model in MATLAB®. The model also calculates the cell operating temperature as a function of the input current. Once the optimal values of the operating parameters of the SOC are calculated the model is integrated in the transient system simulation tool (TRNSYS) for dynamic analysis. Furthermore this work presents a parametric analysis of the hydrogen storage system (HSS). The results of the energy and environmental analyses show that the proposed system can reach a primary energy saving by 70% and an amount of saved CO2 of 28 tons/year. Some possible future market scenarios are considered for the economic analysis. In the most realistic case the optimal configuration shows a simple pay back lower than 10 years and a profit index of 46%.
A Review of Energy Systems Models in the UK: Prevalent Usage and Categorisation
Feb 2016
Publication
In this paper a systematic review of academic literature and policy papers since 2008 is undertaken with an aim of identifying the prevalent energy systems models and tools in the UK. A list of all referenced models is presented and the literature is analysed with regards sectoral coverage and technological inclusion as well as mathematical structure of models. The paper compares available models using an appropriate classification schema the introduction of which is aimed at making the model landscape more accessible and perspicuous thereby enhancing the diversity of models within use. The distinct classification presented in this paper comprises three sections which specify the model purpose and structure technological detail and mathematical approach. The schema is not designed to be comprehensive but rather to be a broad classification with pertinent level of information required to differentiate between models. As an example the UK model landscape is considered and 22 models are classified in three tables as per the proposed schema.
The Future of Clean Hydrogen in the United States: Views from Industry, Market Innovators, and Investors
Sep 2021
Publication
This report The Future of Clean Hydrogen in the United States: Views from Industry Market Innovators and Investors sheds light on the rapidly evolving hydrogen market based on 72 exploratory interviews with organizations across the current and emerging hydrogen value chain. This report is part of a series From Kilograms to Gigatons: Pathways for Hydrogen Market Formation in the United States which will build on this study to evaluate policy opportunities for further hydrogen development in the United States. The goal of the interviews was to provide a snapshot of the clean hydrogen investment environment and better understand organizations’ market outlook investment rationale and areas of interest. This interview approach was supported by traditional research methods to contextualize and enrich the qualitative findings. This report should be understood as input to a more extensive EFI analysis of hydrogen market formation in the United States; the directions that companies are pursuing in hydrogen production transport and storage and end use at this early stage of value chain development will inform subsequent analysis in important ways.
Influence of Cs Promoter on Ethanol Steam-Reforming Selectivity of Pt/m-ZrO2 Catalysts at Low Temperature
Sep 2021
Publication
The decarboxylation pathway in ethanol steam reforming ultimately favors higher selectivity to hydrogen over the decarbonylation mechanism. The addition of an optimized amount of Cs to Pt/m-ZrO2 catalysts increases the basicity and promotes the decarboxylation route converting ethanol to mainly H2 CO2 and CH4 at low temperature with virtually no decarbonylation being detected. This offers the potential to feed the product stream into a conventional methane steam reformer for the production of hydrogen with higher selectivity. DRIFTS and the temperature-programmed reaction of ethanol steam reforming as well as fixed bed catalyst testing revealed that the addition of just 2.9% Cs was able to stave off decarbonylation almost completely by attenuating the metallic function. This occurs with a decrease in ethanol conversion of just 16% relative to the undoped catalyst. In comparison with our previous work with Na this amount is—on an equivalent atomic basis—just 28% of the amount of Na that is required to achieve the same effect. Thus Cs is a much more efficient promoter than Na in facilitating decarboxylation.
Research and Development Investment and Collaboration Framework for the Hydrogen Economy in South Korea
Sep 2021
Publication
South Korea developed its hydrogen strategies to achieve carbon neutrality and dominate the hydrogen economy amidst and with the impetus of the coronavirus disease 2019 (COVID-19) pandemic. The government strives toward the goal via continuous investment in green hydrogen technologies as well as strategic collaborations. To facilitate the transition into the hydrogen economy this study presents a research and development (R&D) investment and collaboration framework as a national strategy. The framework offers abundant information to elucidate the technology R&D spectrum and regional dimensions of the strategy. Furthermore the proposed framework was applied to the Korean hydrogen economy comprising 955 nationally funded projects worth USD 565.7 million. The statuses and trends of the government’s investment in nationally funded research projects are illustrated with regard to the value chains of the hydrogen economies of 16 regions as well as nine technology clusters relating to the hydrogen economy thereby determining the research organizations that played crucial roles in each cluster of the 16 regions between 2015 and 2020. The results indicate that the research organizations in Daejeon acquired the highest government R&D funding in many hydrogen-economy-related research fields and that an R&D spectrum-based research/strategic collaboration is required to accomplish specialized complexes in the regions.
Hydrogen Infrastructure Project Risks in The Netherlands
Sep 2021
Publication
This study aims to assess the potential risks of setting up a hydrogen infrastructure in the Netherlands. An integrated risk assessment framework capable of analyzing projects identifying risks and comparing projects is used to identify and analyze the main risks in the upcoming Dutch hydrogen infrastructure project. A time multiplier is added to the framework to develop parameters. The impact of the different risk categories provided by the integrated framework is calculated using the discounted cash flow (DCF) model. Despite resource risks having the highest impact scope risks are shown to be the most prominent in the hydrogen infrastructure project. To present the DCF model results a risk assessment matrix is constructed. Compared to the conventional Risk Assessment Matrix (RAM) used to present project risks this matrix presents additional information in terms of the internal rate of return and risk specifics.
Ammonia as Effective Hydrogen Storage: A Review on Production, Storage and Utilization
Jun 2020
Publication
Ammonia is considered to be a potential medium for hydrogen storage facilitating CO2-free energy systems in the future. Its high volumetric hydrogen density low storage pressure and stability for long-term storage are among the beneficial characteristics of ammonia for hydrogen storage. Furthermore ammonia is also considered safe due to its high auto ignition temperature low condensation pressure and lower gas density than air. Ammonia can be produced from many different types of primary energy sources including renewables fossil fuels and surplus energy (especially surplus electricity from the grid). In the utilization site the energy from ammonia can be harvested directly as fuel or initially decomposed to hydrogen for many options of hydrogen utilization. This review describes several potential technologies in current conditions and in the future for ammonia production storage and utilization. Ammonia production includes the currently adopted Haber–Bosch electrochemical and thermochemical cycle processes. Furthermore in this study the utilization of ammonia is focused mainly on the possible direct utilization of ammonia due to its higher total energy efficiency covering the internal combustion engine combustion for gas turbines and the direct ammonia fuel cell. Ammonia decomposition is also described in order to give a glance at its progress and problems. Finally challenges and recommendations are also given toward the further development of the utilization of ammonia for hydrogen storage.
Optimization of Component Sizing for a Fuel Cell-Powered Truck to Minimize Ownership Cost
Mar 2019
Publication
In this study we consider fuel cell-powered electric trucks (FCETs) as an alternative to conventional medium- and heavy-duty vehicles. FCETs use a battery combined with onboard hydrogen storage for energy storage. The additional battery provides regenerative braking and better fuel economy but it will also increase the initial cost of the vehicle. Heavier reliance on stored hydrogen might be cheaper initially but operational costs will be higher because hydrogen is more expensive than electricity. Achieving the right tradeoff between these power and energy choices is necessary to reduce the ownership cost of the vehicle. This paper develops an optimum component sizing algorithm for FCETs. The truck vehicle model was developed in Autonomie a platform for modelling vehicle energy consumption and performance. The algorithm optimizes component sizes to minimize overall ownership cost while ensuring that the FCET matches or exceeds the performance and cargo capacity of a conventional vehicle. Class 4 delivery truck and class 8 linehaul trucks are shown as examples. We estimate the ownership cost for various hydrogen costs powertrain components ownership periods and annual vehicle miles travelled.
Decarbonizing China’s Energy System – Modeling the Transformation of the Electricity, Transportation, Heat, and Industrial Sectors
Nov 2019
Publication
Growing prosperity among its population and an inherent increasing demand for energy complicate China’s target of combating climate change while maintaining its economic growth. This paper therefore describes three potential decarbonization pathways to analyze different effects for the electricity transport heating and industrial sectors until 2050. Using an enhanced version of the multi-sectoral open-source Global Energy System Model enables us to assess the impact of different CO2 budgets on the upcoming energy system transformation. A detailed provincial resolution allows for the implementation of regional characteristics and disparities within China. Conclusively we complement the model-based analysis with a quantitative assessment of current barriers for the needed transformation. Results indicate that overall energy system CO2 emissions and in particular coal usage have to be reduced drastically to meet (inter-) national climate targets. Specifically coal consumption has to decrease by around 60% in 2050 compared to 2015. The current Nationally Determined Contributions proposed by the Chinese government of peaking emissions in 2030 are therefore not sufficient to comply with a global CO2 budget in line with the Paris Agreement. Renewable energies in particular photovoltaics and onshore wind profit from decreasing costs and can provide a more sustainable and cheaper energy source. Furthermore increased stakeholder interactions and incentives are needed to mitigate the resistance of local actors against a low-carbon transformation.
Material-based Hydrogen Storage Projection
Sep 2021
Publication
Massive consumption of fossil fuel leads to shortage problems as well as various global environmental issues. Due to the global climatic problem in the world techniques to supply energy demand change from conventional methods that use fossil fuel as the energy source to clean and renewable sources such as solar and wind. However these renewable energy sources are not permanent. Energy storage methods can ensure to supply the energy demand in need if the energy is stored when the renewable source is available. Hydrogen is considered a promising alternative feedstock owing to has unique properties such as clean energy high energy density absence of toxic materials and carbon-free nature. Hydrogen is used main fuel source in fuel cells and hydrogen can be produced with various methods such as wind or electrolysis of water systems that supply electricity from renewable sources. However the safe effective and economical storage of hydrogen is still a challenge that limits the spread of the usage of hydrogen energy. High pressed hydrogen gas and cryogenic hydrogen liquid are two applied storage pathways although they do not meet the above-mentioned requirement. To overcome these drawbacks materials-based hydrogen storage materials have been mostly investigated research field recently. The aim of the study is that exhibiting various material-based hydrogen storage systems and development of these techniques worldwide. Additionally past and current status of the technology are explained and future perspective is discussed.
Liquid Hydrogen as Prospective Energy Carrier: A Brief Review and Discussion of Underlying Assumptions Applied in Value Chain Analysis
Nov 2021
Publication
In the literature different energy carriers are proposed in future long-distance hydrogen value chains. Hydrogen can be stored and transported in different forms e.g. as compressed dense-phase hydrogen liquefied hydrogen and in chemically bound forms as different chemical hydrides. Recently different high-level value chain studies have made extrapolative investigations and compared such options with respect to energy efficiency and cost. Three recent journal papers overlap as the liquid hydrogen option has been considered in all three studies. The studies are not fully aligned in terms of underlying assumptions and battery limits. A comparison reveals partly vast differences in results for chain energy efficiency for long-distance liquid hydrogen transport which are attributable to distinct differences in the set of assumptions. Our comparison pinpoints the boiloff ratio i.e. evaporation losses due to heat ingress in liquid hydrogen storage tanks as the main cause of the differences and this assumption is further discussed. A review of spherical tank size and attributed boiloff ratios is presented for existing tanks of different vintage as well as for recently proposed designs. Furthermore the prospect for further extension of tanks size and reduction of boiloff ratio is discussed with a complementary discussion about the use of economic assumptions in extrapolative and predictive studies. Finally we discuss the impact of battery limits in hydrogen value chain studies and pinpoint knowledge needs and the need for a detailed bottom-up approach as a prerequisite for improving the understanding for pros and cons of the different hydrogen energy carriers.
A Novel Framework for Development and Optimisation of Future Electricity Scenarios with High Penetration of Renewables and Storage
May 2019
Publication
Although electricity supply is still dominated by fossil fuels it is expected that renewable sources will have a much larger contribution in the future due to the need to mitigate climate change. Therefore this paper presents a new framework for developing Future Electricity Scenarios (FuturES) with high penetration of renewables. A multi-period linear programming model has been created for power-system expansion planning. This has been coupled with an economic dispatch model PowerGAMA to evaluate the technical and economic feasibility of the developed scenarios while matching supply and demand. Application of FuturES is demonstrated through the case of Chile which has ambitious plans to supply electricity using only renewable sources. Four cost-optimal scenarios have been developed for the year 2050 using FuturES: two Business as usual (BAU) and two Renewable electricity (RE) scenarios. The BAU scenarios are unconstrained in terms of the technology type and can include all 11 options considered. The RE scenarios aim to have only renewables in the mix including storage. The results show that both BAU scenarios have a levelised cost of electricity (LCOE) lower than or equal to today’s costs ($72.7–77.3 vs $77.6/MWh) and include 81–90% of renewables. The RE scenarios are slightly more expensive than today’s costs ($81–87/MWh). The cumulative investment for the BAU scenarios is $123-$145 bn compared to $147-$157 bn for the RE. The annual investment across the scenarios is estimated at $4.0 ± 0.4 bn. Both RE scenarios show sufficient flexibility in matching supply and demand despite solar photovoltaics and wind power contributing around half of the total supply. Therefore the FuturES framework is a powerful tool for aiding the design of cost-efficient power systems with high penetration of renewables.
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