Publications
Hydrogen Jet Structure in Presence of Forced Co-, Counter- and Cross-flow Ventilation
Sep 2021
Publication
This paper presents results of experimental investigations on unignited horizontal hydrogen jets in air in presence of co- cross- and counter-flow. Hydrogen concentration distributions are obtained as functions of distance to the hydrogen release nozzle. The H2-jet variables are two nozzle diameters 1 mm and 4 mm and two H2-jet mass flow rates 1 g/s up to 5 g/s. A propeller fan is used to provide forced ventilation compared to the case with no ventilation three different airflow velocities up to 5 m/s were studied systematically. It was found that any forced ventilation in co- cross- and counter-flow direction reduces the size of the burnable mixture cloud of the H2-jet compared to a free jet in quiescent air.
The Role of κ-Carbides as Hydrogen Traps in High-Mn Steels
Jul 2017
Publication
Since the addition of Al to high-Mn steels is known to reduce their sensitivity to hydrogen-induced delayed fracture we investigate possible trapping effects connected to the presence of Al in the grain interior employing density-functional theory (DFT). The role of Al-based precipitates is also investigated to understand the relevance of short-range ordering effects. So-called E21-Fe3AlC κ-carbides are frequently observed in Fe-Mn-Al-C alloys. Since H tends to occupy the same positions as C in these precipitates the interaction and competition between both interstitials is also investigated via DFT-based simulations. While the individual H–H/C–H chemical interactions are generally repulsive the tendency of interstitials to increase the lattice parameter can yield a net increase of the trapping capability. An increased Mn content is shown to enhance H trapping due to attractive short-range interactions. Favorable short-range ordering is expected to occur at the interface between an Fe matrix and the E21-Fe3AlC κ-carbides which is identified as a particularly attractive trapping site for H. At the same time accumulation of H at sites of this type is observed to yield decohesion of this interface thereby promoting fracture formation. The interplay of these effects evident in the trapping energies at various locations and dependent on the H concentration can be expressed mathematically resulting in a term that describes the hydrogen embrittlement
Environmental Sustainability of Renewable Hydrogen in Comparison with Conventional Cooking Fuels
Jun 2018
Publication
Hydrogen could be used as a ‘cleaner’ cooking fuel particularly in communities that rely on biomass and fossil fuels to reduce local pollution and related health effects. However hydrogen must be produced using sustainable feedstocks and energy sources to ensure that local impacts are not reduced at the expense of other impacts generated elsewhere in the life cycle. To this end this paper evaluates life cycle environmental impacts of renewable hydrogen produced in a proton-exchange membrane electrolyser using solar energy. The aim of the study is to find out if hydrogen produced in this system and used as a cooking fuel is environmentally sustainable in comparison with conventional cooking fuels typically used in developing countries such as liquefied petroleum gas (LPG) charcoal and firewood. The results suggest that hydrogen would reduce the climate change impact by 2.5–14 times to 0.04 kg CO2 eq./MJ compared to firewood (0.10 kg CO2 eq./MJ) and LPG (0.57 kg CO2 eq./MJ). Some other impacts would also be lower by 6%–35 times including depletion of fossil fuels summer smog and health effects from emissions of particulates both locally and across the rest of the life cycle. However some other impacts would increase by 6%–6.7 times such as depletion of metals and freshwater and marine ecotoxicity. These are mainly due to the solar photovoltaic panels used to generate power for the electrolyser. In terms of the local impacts the study suggests that hydrogen would reduce local pollution and related health impacts by 8%–35 times. However LPG is still environmentally a better option than hydrogen for most of the impacts both at the point of use and on a life cycle basis.
The UK Carbon Capture, Usage and Storage (CCUS) Deployment Pathway: An Action Plan
Nov 2018
Publication
CCUS has economy-wide qualities which could be very valuable to delivering clean industrial growth. It could deliver tangible results in tackling some of the biggest challenges we face in decarbonising our economy contributing to industrial competitiveness and generating new economic opportunities – a key part of our modern Industrial Strategy.
Our vision is to become a global leader in CCUS unlocking the potential of the technology and securing the added value which it can bring to our industrial centres and businesses all across the UK.
Our ambition is that the UK should have the option to deploy CCUS at scale during the 2030s subject to the costs coming down sufficiently.
Our Industrial Strategy set out four Grand Challenges to put the UK at the forefront of the industries of the future. The Clean Growth Grand Challenge seeks to maximise the advantages for UK industry from the global shift to clean growth. CCUS can be an important part of achieving these objectives.
Our vision is to become a global leader in CCUS unlocking the potential of the technology and securing the added value which it can bring to our industrial centres and businesses all across the UK.
Our ambition is that the UK should have the option to deploy CCUS at scale during the 2030s subject to the costs coming down sufficiently.
Our Industrial Strategy set out four Grand Challenges to put the UK at the forefront of the industries of the future. The Clean Growth Grand Challenge seeks to maximise the advantages for UK industry from the global shift to clean growth. CCUS can be an important part of achieving these objectives.
Hydrogen Production by Steam Reforming of Ethanol on Rh-Pt Catalysts: Influence of CeO2, ZrO2, and La2O3 as Supports
Nov 2015
Publication
CeO2- ZrO2- and La2O3-supported Rh-Pt catalysts were tested to assess their ability to catalyze the steam reforming of ethanol (SRE) for H2 production. SRE activity tests were performed using EtOH:H2O:N2 (molar ratio 1:3:51) at a gaseous space velocity of 70600 h−1 between 400 and 700 °C at atmospheric pressure. The SRE stability of the catalysts was tested at 700 °C for 27 h time on stream under the same conditions. RhPt/CeO2 which showed the best performance in the stability test also produced the highest H2 yield above 600 °C followed by RhPt/La2O3 and RhPt/ZrO2. The fresh and aged catalysts were characterized by TEM XPS and TGA. The higher H2 selectivity of RhPt/CeO2 was ascribed to the formation of small (~5 nm) and stable particles probably consistent of Rh-Pt alloys with a Pt surface enrichment. Both metals were oxidized and acted as an almost constant active phase during the stability test owing to strong metal-support interactions as well as the superior oxygen mobility of the support. The TGA results confirmed the absence of carbonaceous residues in all the aged catalysts.
The Role of Hydrogen in Achieving Net Zero: Parliamentary Inquiry
Mar 2021
Publication
A key component of the Government's recently announced ‘Ten Point Plan for a Green Industrial Revolution’ is 'Driving the Growth of Low Carbon Hydrogen'. The plan outlined a range of measures to support the development and adoption of hydrogen including a £240 million 'Net Zero Hydrogen Fund'. Noting this and the further £81 million allocated for hydrogen heating trials in the 2020 Spending Review the House of Commons Science and Technology Committee is today launching a new inquiry into the role of hydrogen in achieving Net Zero.
Following recommendations from the Committee on Climate Change that the Government develop a strategy for hydrogen use and should aim for largescale hydrogen trials to begin in the early 2020s the Committee seeks to ensure that the Government's intended plan will be suitable and effective. The Committee will also assess the infrastructure required for hydrogen as a Net Zero fuel and examine progress made so far internationally to determine the viability of hydrogen as a significant contributor to achieving Net Zero.
All documents are in the Supplements tab above.
Following recommendations from the Committee on Climate Change that the Government develop a strategy for hydrogen use and should aim for largescale hydrogen trials to begin in the early 2020s the Committee seeks to ensure that the Government's intended plan will be suitable and effective. The Committee will also assess the infrastructure required for hydrogen as a Net Zero fuel and examine progress made so far internationally to determine the viability of hydrogen as a significant contributor to achieving Net Zero.
All documents are in the Supplements tab above.
Hydrogen Valleys. Insights Into the Emerging Hydrogen Economies Around the World
Jun 2021
Publication
Clean hydrogen is universally considered an important energy vector in the global efforts to limit greenhouse gas emissions to the "well below 2 °C scenario" as agreed by more than 190 states in the 2015 Paris Agreement. Hydrogen Valleys – regional ecosystems that link hydrogen production transportation and various end uses such as mobility or industrial feedstock – are important steps towards enabling the development of a new hydrogen economy.<br/><br/>This report has been issued during the setup of the "Mission Innovation Hydrogen Valley Platform" which was commissioned by the European Union and developed by the Fuel Cells and Hydrogen Joint Undertaking. The global information sharing platform to date already features 30+ global Hydrogen Valleys with a cumulative investment volume of more than EUR 30 billion. The projects provide a first-of-its kind look into the global Hydrogen Valley project landscape its success factors and remaining barriers. This report summarizes the findings and presents identified best practices for successful project development as well as recommendations for policymakers on how to provide a favourable policy environment that paves the way to reach the Hydrogen Valleys' full potential as enablers of the global hydrogen economy.
Effects of Hot Stamping and Tempering on Hydrogen Embrittlement of a Low-Carbon Boron-Alloyed Steel
Dec 2018
Publication
The effects of hot stamping (HS) and tempering on the hydrogen embrittlement (HE) behavior of a low-carbon boron-alloyed steel were studied by using slow strain rate tensile (SSRT) tests on notched sheet specimens. It was found that an additional significant hydrogen desorption peak at round 65–80 °C appeared after hydrogen-charging the corresponding hydrogen concentration (CHr) of the HS specimen was higher than that of the directed quenched (DQ) specimen and subsequent low-temperature tempering gave rise to a decrease of CHr. The DQ specimen exhibited a comparatively high HE susceptibility while tempering treatment at 100 °C could notably alleviate it by a relative decrease of ~24% at no expanse of strength and ductility. The HS specimen demonstrated much lower HE susceptibility compared with the DQ specimen and tempering at 200 °C could further alleviate its HE susceptibility. SEM analysis of fractured SSRT surfaces revealed that the DQ specimen showed a mixed transgranular-intergranular fracture while the HS and low-temperature tempered specimens exhibited a predominant quasi-cleavage transgranular fracture. Based on the obtained results we propose that a modified HS process coupled with low-temperature tempering treatment is a promising and feasible approach to ensure a low HE susceptibility for high-strength automobile parts made of this type of steel.
Hydrogen for Transport Prospective Australian Use Cases
Oct 2019
Publication
The Australian transport sector is under increasing pressure to reduce carbon emissions whilst also managing a fuel supply chain that relies heavily on foreign import partners.
Transport in Australia equates to a significant proportion (approximately 18%) of the country’s total greenhouse gas emissions. Due to ongoing population growth these emissions have been steadily rising with the increase of cars on our roads and freight trucks in transit. Coupled with this the transport fuel supply chain is highly reliant on overseas partners – Australia currently imports 90% of its liquid fuel. These two challenges present an interesting dichotomy for the industry incentivising research and development into new technologies that can address one or both of these issues.
Hydrogen is one technology that has the potential to provide a reduction in greenhouse gas emissions as well as a more reliable domestic fuel supply. Hydrogen fuel cell electric vehicles (FCEVs) are an emerging zero-emission alternative for the transport sector which offer a variety of benefits.
You can read the full report on the Aurecon Australasia website at this link
Transport in Australia equates to a significant proportion (approximately 18%) of the country’s total greenhouse gas emissions. Due to ongoing population growth these emissions have been steadily rising with the increase of cars on our roads and freight trucks in transit. Coupled with this the transport fuel supply chain is highly reliant on overseas partners – Australia currently imports 90% of its liquid fuel. These two challenges present an interesting dichotomy for the industry incentivising research and development into new technologies that can address one or both of these issues.
Hydrogen is one technology that has the potential to provide a reduction in greenhouse gas emissions as well as a more reliable domestic fuel supply. Hydrogen fuel cell electric vehicles (FCEVs) are an emerging zero-emission alternative for the transport sector which offer a variety of benefits.
You can read the full report on the Aurecon Australasia website at this link
When and How to Regulate Hydrogen Networks?
Feb 2021
Publication
This European Green Deal Regulatory White Paper provides the views of Europe’s energy regulators represented by ACER and CEER on when and how to regulate the hydrogen networks in the future.
With the EU goal of becoming a carbon neutral continent by 2050 hydrogen is set to play a key role in decarbonising Europe's economy.
To realise the European Green Deal's ambitions for hydrogen the right regulatory framework must be created to facilitate a hydrogen economy in a cost-effective way.
European energy regulators (ACER and CEER) have published a set of recommendations on when and how to regulate pure hydrogen networks. The need and scope of hydrogen network regulation will depend on its structure and evolution.
This paper is the first in our new series of ACER-CEER European Green Deal Regulatory White Papers. This hydrogen paper examines:
The aim is to deepen understanding on the regulatory aspects of Green Deal issues and to assist the European Commission in assessing various options as part of the preparations for legislation on hydrogen and energy system integration. With the EU goal of becoming a carbon neutral continent by 2050 hydrogen is set to play a key role in decarbonising Europe's economy.
The Full report can be found on the ACER website
With the EU goal of becoming a carbon neutral continent by 2050 hydrogen is set to play a key role in decarbonising Europe's economy.
To realise the European Green Deal's ambitions for hydrogen the right regulatory framework must be created to facilitate a hydrogen economy in a cost-effective way.
European energy regulators (ACER and CEER) have published a set of recommendations on when and how to regulate pure hydrogen networks. The need and scope of hydrogen network regulation will depend on its structure and evolution.
This paper is the first in our new series of ACER-CEER European Green Deal Regulatory White Papers. This hydrogen paper examines:
- The circumstances under which regulating hydrogen networks is needed;
- How to treat existing hydrogen network infrastructure;
- How to address regulatory challenges related to the repurposing of gas infrastructure for dedicated hydrogen transport.
The aim is to deepen understanding on the regulatory aspects of Green Deal issues and to assist the European Commission in assessing various options as part of the preparations for legislation on hydrogen and energy system integration. With the EU goal of becoming a carbon neutral continent by 2050 hydrogen is set to play a key role in decarbonising Europe's economy.
The Full report can be found on the ACER website
Roadmap to Decarbonising European Shipping
Nov 2018
Publication
Shipping is one of the largest greenhouse gas (GHG) emitting sectors of the global economy responsible for around 1 Gt of CO2eq every year. If shipping were a country it would be the 6th biggest GHG emitter. EU related shipping is responsible for about 1/5 of global ship GHG emissions emitting on average 200 Mt/year. This report assesses potential technology pathways for decarbonising EU related shipping through a shift to zero carbon technologies and the impact such a move could have on renewable electricity demand in Europe. It also identifies key policy and sustainability issues that should be considered when analysing and supporting different technology options to decarbonise the maritime sector. The basis of the study is outbound journeys under the geographical scope of the EU ship MRV Regulation.
We have not tried to quantify the emissions reductions that specific regulatory measures to be introduced at the IMO or EU level might contribute towards decarbonisation by 2050 because there are too many uncertainties. We have taken a more limited first approach and investigated how zero carbon propulsion pathways that currently seem feasible to decarbonise shipping would likely affect the future EU renewable energy supply needs.
It is now generally accepted that ship design efficiency requirements while potentially having an important impact on future emissions growth will fall well short of what is needed. Further operational efficiency measures such as capping operational speed will be important to immediately peak energy consumption and emissions but will be insufficient to decarbonise the sector or reduce its growing energy needs. In this context this study assumes that with all the likely immediate measures adopted energy demand for EU related shipping will still grow by 50% by 2050 over 2010 levels. This is within the range of the 20 -1 20% global BAU maritime energy demand growth estimate.
The decarbonisation of shipping will require changes in on -board energy storage and use and the necessary accompanying bunkering infrastructure. This study identifies the technology options for zero emission propulsion that based on current know-how are likely to be adopted. It is not exhaustive nor prescriptive because the ultimate pathways will likely depend on both the requirements of the shipping industry in terms of cost efficiency and safety and on the future renewable electricity sources that the shipping sect or will need to compete for.
Literature is nascent on the different techno-economic options likely to be available to decarbonise shipping and individual ships 4 but almost completely lacking on the possible impacts of maritime decarbonisation on the broader energy system(s). Understanding these impacts is nevertheless essential because it will influence financial and economic decision making by the EU and member states including those related to investment in future renewable energy supplies and new ship bunkering infrastructure. With this in mind the report aims to provide a preliminary first answer to the following question: Under different zero emission technology pathways how much additional renewable electricity would be needed to cater for the needs of EU related shipping in 2050?
Link to Document Download on Transport & Environment website
We have not tried to quantify the emissions reductions that specific regulatory measures to be introduced at the IMO or EU level might contribute towards decarbonisation by 2050 because there are too many uncertainties. We have taken a more limited first approach and investigated how zero carbon propulsion pathways that currently seem feasible to decarbonise shipping would likely affect the future EU renewable energy supply needs.
It is now generally accepted that ship design efficiency requirements while potentially having an important impact on future emissions growth will fall well short of what is needed. Further operational efficiency measures such as capping operational speed will be important to immediately peak energy consumption and emissions but will be insufficient to decarbonise the sector or reduce its growing energy needs. In this context this study assumes that with all the likely immediate measures adopted energy demand for EU related shipping will still grow by 50% by 2050 over 2010 levels. This is within the range of the 20 -1 20% global BAU maritime energy demand growth estimate.
The decarbonisation of shipping will require changes in on -board energy storage and use and the necessary accompanying bunkering infrastructure. This study identifies the technology options for zero emission propulsion that based on current know-how are likely to be adopted. It is not exhaustive nor prescriptive because the ultimate pathways will likely depend on both the requirements of the shipping industry in terms of cost efficiency and safety and on the future renewable electricity sources that the shipping sect or will need to compete for.
Literature is nascent on the different techno-economic options likely to be available to decarbonise shipping and individual ships 4 but almost completely lacking on the possible impacts of maritime decarbonisation on the broader energy system(s). Understanding these impacts is nevertheless essential because it will influence financial and economic decision making by the EU and member states including those related to investment in future renewable energy supplies and new ship bunkering infrastructure. With this in mind the report aims to provide a preliminary first answer to the following question: Under different zero emission technology pathways how much additional renewable electricity would be needed to cater for the needs of EU related shipping in 2050?
Link to Document Download on Transport & Environment website
Resource Assessment for Hydrogen Production
Jul 2020
Publication
This analysis was conducted in support of the U.S. Department of Energy's H2@Scale initiative and this report examines the resources required to meet demand for an additional 10 million metric tonnes (MMT) of hydrogen in 2040. The technical potential of hydrogen production from fossil nuclear and renewable energy resources is presented. Updated maps describe the geographical distribution of hydrogen production potential from renewable energy resources. The results conclude that the technical resource availability of domestic energy resources is sufficient to meet an additional 10 MMT of hydrogen demand in 2040 without placing significant pressure on existing resources. While this level of hydrogen demand could result in a significant increase in renewable energy consumption in particular the technical potential of each resource is estimated to be sufficient to meet the demand. Future research to enable the large-scale integration of hydrogen in the U.S. energy and other sectors will include analyzing the geographic distribution of resources in relation to hydrogen demand for a variety of applications. Additional techno-economic analysis is also needed to understand the economic potential of hydrogen in other industries beyond transportation; such analysis is currently being undertaken by a multi-lab project initiated by DOE in 2016. Finally information from techno-economic analyses should be used to continually update and inform R&D targets for energy production hydrogen production and hydrogen utilization technologies.
Role of batteries and fuel cells in achieving Net Zero- Session 3
Mar 2021
Publication
The House of Lords Science and Technology Committee will hear from officials research funders and leading research consortia about the UK’s strategy for research and development of batteries and fuel cells to help meet the net-zero target.
The Committee will question officials from government departments and research councils about the UK’s increased support for battery development and how the initiatives and funding will evolve. The Committee will compare the support given to fuel cell research and ask how this technology will be developed for applications such as heavy transport. For both technologies it will ask how training will be delivered to provide a skilled workforce.
The Committee will also hear from leaders of research consortia asking them about support for their research sectors and how this compares with countries leading the development of the technologies. The Committee will explore coordination between research into batteries fuel cells and wider strategies such as for hydrogen and whether research for transport can be transferred to applications in other sectors such as power grids and heating.
At 10.00am: Oral evidence
Mr Tony Harper Industrial Strategy Challenge Director Faraday Battery Challenge at UK Research and Innovation (UKRI) at University of Central Lancashire
Dr Lucy Martin Deputy Director of Cross-Council Programmes and lead for Net Zero at University of Central Lancashire
Dr Bob Moran Deputy Director Head of Environment Strategy at University of Central Lancashire
Professor Paul Monks Chief Scientific Adviser at University of Central Lancashire
At 11.00am: Oral evidence
Professor Philip Taylor Director at EPSRC Supergen Energy Networks Hub and Pro-Vice Chancellor for Research and Enterprise at University of Bristol
Professor David Greenwood CEO High Value Manufacturing Catapult at University of Central Lancashire Director Industrial Engagement at University of Central Lancashire and Professor of Advanced Propulsion Systems at University of Warwick
Professor Paul Dodds Professor of Energy Systems at University of Central Lancashire
Possible questions
Parliament TV video of the meeting
This is part three of a three part enquiry.
Part one can be found here and part two can be found here.
The Committee will question officials from government departments and research councils about the UK’s increased support for battery development and how the initiatives and funding will evolve. The Committee will compare the support given to fuel cell research and ask how this technology will be developed for applications such as heavy transport. For both technologies it will ask how training will be delivered to provide a skilled workforce.
The Committee will also hear from leaders of research consortia asking them about support for their research sectors and how this compares with countries leading the development of the technologies. The Committee will explore coordination between research into batteries fuel cells and wider strategies such as for hydrogen and whether research for transport can be transferred to applications in other sectors such as power grids and heating.
At 10.00am: Oral evidence
Mr Tony Harper Industrial Strategy Challenge Director Faraday Battery Challenge at UK Research and Innovation (UKRI) at University of Central Lancashire
Dr Lucy Martin Deputy Director of Cross-Council Programmes and lead for Net Zero at University of Central Lancashire
Dr Bob Moran Deputy Director Head of Environment Strategy at University of Central Lancashire
Professor Paul Monks Chief Scientific Adviser at University of Central Lancashire
At 11.00am: Oral evidence
Professor Philip Taylor Director at EPSRC Supergen Energy Networks Hub and Pro-Vice Chancellor for Research and Enterprise at University of Bristol
Professor David Greenwood CEO High Value Manufacturing Catapult at University of Central Lancashire Director Industrial Engagement at University of Central Lancashire and Professor of Advanced Propulsion Systems at University of Warwick
Professor Paul Dodds Professor of Energy Systems at University of Central Lancashire
Possible questions
- On which aspects of battery and fuel cell research and development is the UK focusing and why?
- How successful have the UK’s new research initiatives been in advancing battery science and application?
- Does battery research receive greater public funding than fuel cell research? If so why?
- What technologies are seen as the most likely options for heavy transport i.e. HGVs buses and trains?
- What is the Government’s strategy for supporting the growth of skilled workers for battery and fuel cell research and development?
- To what extent is battery and fuel cell research and development coordinated in the UK? If so who is responsible for this coordination?
Parliament TV video of the meeting
This is part three of a three part enquiry.
Part one can be found here and part two can be found here.
Indicative Analysis of Blending Hydrogen in Gas Networks
May 2020
Publication
Frontier Economics has been engaged by the Commonwealth Department of the Environment and Energy (now Industry Science Energy and Resources) (the Department) to undertake an indicative analysis of the economics of blending hydrogen in Australian natural gas distribution networks. Our analysis is limited to a specific gas distribution network servicing urban areas of Melbourne.
We have investigated the economics of blending hydrogen in a natural gas distribution network by examining a number of energy supply options including options that involve blending hydrogen. While we consider that these cases we have examined are useful for understanding the economics of hydrogen blending at low rates in Victoria and for understanding the factors that are likely to drive the economics of blending at higher rates or in other regions it cannot be assumed that the results we find for the cases we investigate will necessarily apply in other regions or for blending at other rates. This report should be read as an assessment of the specific cases we have investigated and our findings cannot necessarily be extended to other cases (such as other locations or other rates of blending)"
The full report can be found via the website of the Australian government at this link
We have investigated the economics of blending hydrogen in a natural gas distribution network by examining a number of energy supply options including options that involve blending hydrogen. While we consider that these cases we have examined are useful for understanding the economics of hydrogen blending at low rates in Victoria and for understanding the factors that are likely to drive the economics of blending at higher rates or in other regions it cannot be assumed that the results we find for the cases we investigate will necessarily apply in other regions or for blending at other rates. This report should be read as an assessment of the specific cases we have investigated and our findings cannot necessarily be extended to other cases (such as other locations or other rates of blending)"
The full report can be found via the website of the Australian government at this link
Hydrogen Diffusion in Coal: Implications for Hydrogen Geo-storage
Oct 2021
Publication
Hypothesis: Hydrogen geo-storage is considered as an option for large scale hydrogen storage in a full-scale hydrogen economy. Among different types of subsurface formations coal seams look to be one of the best suitable options as coal’s micro/nano pore structure can adsorb a huge amount of gas (e.g. hydrogen) which can be withdrawn again once needed. However literature lacks fundamental data regarding H2 diffusion in coal. Experiments: In this study we measured H2 adsorption rate in an Australian anthracite coal sample at isothermal conditions for four different temperatures (20 C 30 C 45 C and 60 C) at equilibrium pressure 13 bar and calculated H2 diffusion coefficient (DH2 ) at each temperature. CO2 adsorption rates were measured for the same sample at similar temperatures and equilibrium pressure for comparison. Findings: Results show that H2 adsorption rate and consequently DH2 increases by temperature. DH2 values are one order of magnitude larger than the equivalent DCO2 values for the whole studied temperature range 20–60 C. DH2 / DCO2 also shows an increasing trend versus temperature. CO2 adsorption capacity at equilibrium pressure is about 5 times higher than that of H2 in all studied temperatures. Both H2 and CO2 adsorption capacities at equilibrium pressure slightly decrease as temperature rises.
Supporting Hydrogen Development in Australia Short Film
Jan 2021
Publication
This short film promotes Geoscience Australia's online and publicly accessible hydrogen data products. The film steps through the functionality of GA's Australian Hydrogen Opportunities Tool (AusH2) and describes the upcoming Hydrogen Economic Fairways Tool which has been created through a collaborative effort with Monash University.
Assessment of Full Life-cycle Air Emissions of Alternative Shipping Fuels
Oct 2017
Publication
There is a need for alternative fuels in the shipping sector for two main motivations: to deliver a reduction in local pollutants and comply with existing regulation; and to mitigate climate change and cut greenhouse gas emissions. However any alternative fuel must meet a range of criteria to become a viable option. Key among them is the requirement that it can deliver emissions reductions over its full life-cycle. For a set of fuels comprising both conventional and alternative fuels together with associated production pathways this paper presents a life-cycle assessment with respect to six emissions species: local pollutants sulphur oxides nitrogen oxides and particulate matter; and greenhouse gases carbon dioxide methane and nitrous oxide. While the analysis demonstrates that no widely available fuel exists currently to deliver on both motivations some alternative fuel options have the potential if key barriers can be overcome. Hydrogen or other synthetic fuels rely on decarbonisation of both energy input to production and other feedstock materials to deliver reductions in greenhouse gas emissions. Similarly bio-derived fuels can be an abatement option but only if it can be ensured that land-use change whilst growing biomass does not impact wider potential savings and the sector is able to compete sufficiently for their use. These examples show that crucial barriers are located upstream in the respective fuel life-cycle and that the way to overcome them may reside beyond the scope of the shipping sector alone.
Numerical Analysis of VPSA Technology Retrofitted to Steam Reforming Hydrogen Plants to Capture CO2 and Produce Blue H2
Feb 2022
Publication
The increasing demand for energy and commodities has led to escalating greenhouse gas emissions the chief of which is represented by carbon dioxide (CO2). Blue hydrogen (H2) a lowcarbon hydrogen produced from natural gas with carbon capture technologies applied has been suggested as a possible alternative to fossil fuels in processes with hard-to-abate emission sources including refining chemical petrochemical and transport sectors. Due to the recent international directives aimed to combat climate change even existing hydrogen plants should be retrofitted with carbon capture units. To optimize the process economics of such retrofit it has been proposed to remove CO2 from the pressure swing adsorption (PSA) tail gas to exploit the relatively high CO2 concentration. This study aimed to design and numerically investigate a vacuum pressure swing adsorption (VPSA) process capable of capturing CO2 from the PSA tail gas of an industrial steam methane reforming (SMR)-based hydrogen plant using NaX zeolite adsorbent. The effect of operating conditions such as purge-to-feed ratio and desorption pressure were evaluated in relation to CO2 purity CO2 recovery bed productivity and specific energy consumption. We found that conventional cycle configurations namely a 2-bed 4-step Skarstrom cycle and a 2-bed 6-step modified Skarstrom cycle with pressure equalization were able to concentrate CO2 to a purity greater than 95% with a CO2 recovery of around 77% and 90% respectively. Therefore the latter configuration could serve as an efficient process to decarbonize existing hydrogen plants and produce blue H2.
Room Temperature Metal Hydrides for Stationary and Heat Storage Applications: A Review
Apr 2021
Publication
Hydrogen has been long known to provide a solution toward clean energy systems. With this notion many efforts have been made to find new ways of storing hydrogen. As a result decades of studies has led to a wide range of hydrides that can store hydrogen in a solid form. Applications of these solid-state hydrides are well-suited to stationary applications. However the main challenge arises in making the selection of the Metal Hydrides (MH) that are best suited to meet application requirements. Herein we discuss the current state-of-art in controlling the properties of room temperature (RT) hydrides suitable for stationary application and their long term behavior in addition to initial activation their limitations and emerging trends to design better storage materials. The hydrogen storage properties and synthesis methods to alter the properties of these MH are discussed including the emerging approach of high-entropy alloys. In addition the integration of intermetallic hydrides in vessels their operation with fuel cells and their use as thermal storage is reviewed.
Role of batteries and fuel cells in achieving Net Zero: Session 2
Mar 2021
Publication
The House of Lords Science and Technology Committee will hear from leading researchers about anticipated developments in batteries and fuel cells over the next ten years that could contribute to meeting the net-zero target.
The Committee continues its inquiry into the Role of batteries and fuel cells in achieving Net Zero. It will ask a panel of experts about batteries hearing about the current state-of-the-art in technologies that are currently in deployment primarily lithium-ion batteries. It will also explore the potential of next generation technologies currently in development and the challenges in scaling them up to manufacture.
The Committee will then question a second panel about fuel cells hearing about the different types available and their applications. It will explore challenges that need to be overcome in the development of the technology and will consider the UK’s international standing in the sector.
Meeting details
At 10.00am: Oral evidence
Professor Serena Corr Chair in Functional Nanomaterials and Director of Research Department of Chemical and Biological Engineering at University of Sheffield
Professor Paul Shearing Professor in Chemical Engineering at University College London
Dr Jerry Barker Founder and Chief Technology Officer at Faradion Limited
Dr Melanie Loveridge Associate Professor Warwick Manufacturing Group at University of Warwick
At 11.00am: Oral evidence
Professor Andrea Russell Professor of Physical Electrochemistry at University of Southampton
Professor Anthony Kucernak Professor of Physical Chemistry Faculty of Natural Sciences at Imperial College London
Professor John Irvine Professor School of Chemistry at University of St Andrews
Possible questions
Parliament TV video of the meeting
This is part two of a three part enquiry.
Part one can be found here and part three can be found here.
The Committee continues its inquiry into the Role of batteries and fuel cells in achieving Net Zero. It will ask a panel of experts about batteries hearing about the current state-of-the-art in technologies that are currently in deployment primarily lithium-ion batteries. It will also explore the potential of next generation technologies currently in development and the challenges in scaling them up to manufacture.
The Committee will then question a second panel about fuel cells hearing about the different types available and their applications. It will explore challenges that need to be overcome in the development of the technology and will consider the UK’s international standing in the sector.
Meeting details
At 10.00am: Oral evidence
Professor Serena Corr Chair in Functional Nanomaterials and Director of Research Department of Chemical and Biological Engineering at University of Sheffield
Professor Paul Shearing Professor in Chemical Engineering at University College London
Dr Jerry Barker Founder and Chief Technology Officer at Faradion Limited
Dr Melanie Loveridge Associate Professor Warwick Manufacturing Group at University of Warwick
At 11.00am: Oral evidence
Professor Andrea Russell Professor of Physical Electrochemistry at University of Southampton
Professor Anthony Kucernak Professor of Physical Chemistry Faculty of Natural Sciences at Imperial College London
Professor John Irvine Professor School of Chemistry at University of St Andrews
Possible questions
- What contribution are battery and fuel cell technologies currently making towards decarbonization in the UK?
- What advances do we expect to see in battery and fuel cell technologies and over what timeframes?
- How quickly can UK battery and fuel cell manufacture be scaled up to meet electrification demands?
- What are the challenges facing technological innovation and deployment in heavy transport?
- Are there any sectors where battery and fuel cell technologies are not currently used but could contribute to decarbonisation?
- What are the life cycle environmental impacts of batteries and fuel cells?
Parliament TV video of the meeting
This is part two of a three part enquiry.
Part one can be found here and part three can be found here.
Analysis of Hydrogen-Induced Changes in the Cyclic Deformation Behaviour of AISI 300–Series Austenitic Stainless Steels Using Cyclic Indentation Testing
Jun 2021
Publication
The locally occurring mechanisms of hydrogen embrittlement significantly influence the fatigue behaviour of a material which was shown in previous research on two different AISI 300-series austenitic stainless steels with different austenite stabilities. In this preliminary work an enhanced fatigue crack growth as well as changes in crack initiation sites and morphology caused by hydrogen were observed. To further analyze the results obtained in this previous research in the present work the local cyclic deformation behaviour of the material volume was analyzed by using cyclic indentation testing. Moreover these results were correlated to the local dislocation structures obtained with transmission electron microscopy (TEM) in the vicinity of fatigue cracks. The cyclic indentation tests show a decreased cyclic hardening potential as well as an increased dislocation mobility for the conditions precharged with hydrogen which correlates to the TEM analysis revealing courser dislocation cells in the vicinity of the fatigue crack tip. Consequently the presented results indicate that the hydrogen enhanced localized plasticity (HELP) mechanism leads to accelerated crack growth and change in crack morphology for the materials investigated. In summary the cyclic indentation tests show a high potential for an analysis of the effects of hydrogen on the local cyclic deformation behaviour.
From Coal Ashes to Solid Sorbents for Hydrogen Storage
Jun 2020
Publication
The purpose of this work is the literature review in the field of hydrogen storage in solid sorbents. The best solid sorbents for hydrogen storage were selected with the possibility of synthesis them from coal fly ash. In addition the on-board hydrogen storage analysis was carried out. The review method consists of two parts. The first part based on research questions included types of the best sorbents for hydrogen storage the possibility to obtain them from coal fly ash and practical use in hydrogen storage system on-board. The second part was the selection of publications from The Web of Science and Elsevier Scopus databases and the analysis as well as available reports on the websites at this scope. After searching the relevant articles in the databases abstracts were analysed in terms of the questions asked. The links between references and research were checked. The search procedure was repeated several times. Finally articles with high Impact Factor index published by authors recognized on a global scale were selected for the presented review. The collected information proved that carbon materials are suited to hydrogen storage because of their high porosity large specific surface area and thermal stability. Besides solid sorbents such as zeolites metal-organic frameworks activated carbons or zeolite template carbons can be obtained from coal fly ash. Thanks to silicon aluminium and unburned carbon content fly ash is a good material for the synthesis of hydrogen sorbents. Under cryogenic conditions and high pressure it is possible to adsorb as much as 8.5 wt% of hydrogen. Although the Department of Energy (DOE) requirements for the hydrogen storage system on-board vehicles are not met the review of scientific publications shows that research in this area is developing and better parameters are being obtained.
The Use of Hydrogen to Separate and Recycle Neodymium–iron–boron-type Magnets from Electronic Waste
May 2015
Publication
The rare earth metals have been identified by the European Union and the United States as being at greatest supply risk of all the materials for clean energy technologies. Of particular concern are neodymium and dysprosium both of which are employed in neodymium–iron–boron based magnets. Recycling of magnets based on these materials and contained within obsolete electronic equipment could provide an additional and secure supply. In the present work hydrogen has been employed as a processing agent to decrepitate sintered neodymium–iron–boron based magnets contained within hard disk drives into a demagnetised hydrogenated powder. This powder was then extracted mechanically from the devices with an extraction efficiency of 90 ± 5% and processed further using a combination of sieves and ball bearings to produce a powder containing <330 parts per million of nickel contamination. It is then possible for the extracted powder to be re-processed in a number of ways namely directly by blending and re-sintering to form fully dense magnets by Hydrogenation Disproportionation Desorption Recombination processing to produce an anisotropic coercive powder suitable for bonded magnets by re-melting; or by chemical extraction of the rare earth elements from the alloy. For example it was shown that by the re-sintering route it was possible to recover >90% of the magnetic properties of the starting material with significantly less energy than that employed in primary magnet production. The particular route used will depend upon the magnetic properties required the level of contamination of the extracted material and the compositional variation of the feedstock. The various possibilities have been summarised in a flow diagram.
Controller Design for Polymer Electrolyte Membrane Fuel Cell Systems for Automotive Applications
May 2021
Publication
Continuous developments in Proton Exchange Membrane Fuel Cells (PEMFC) make them a promising technology to achieve zero emissions in multiple applications including mobility. Incremental advancements in fuel cells materials and manufacture processes make them now suitable for commercialization. However the complex operation of fuel cell systems in automotive applications has some open issues yet. This work develops and compares three different controllers for PEMFC systems in automotive applications. All the controllers have a cascade control structure where a generator of setpoints sends references to the subsystems controllers with the objective to maximize operational efficiency. To develop the setpoints generators two techniques are evaluated: off-line optimization and Model Predictive Control (MPC). With the first technique the optimal setpoints are given by a map obtained off-line of the optimal steady state conditions and corresponding setpoints. With the second technique the setpoints time profiles that maximize the efficiency in an incoming time horizon are continuously computed. The proposed MPC architecture divides the fast and slow dynamics in order to reduce the computational cost. Two different MPC solutions have been implemented to deal with this fast/slow dynamics separation. After the integration of the setpoints generators with the subsystems controllers the different control systems are tested and compared using a dynamic detailed model of the automotive system in the INN-BALANCE project running under the New European Driving Cycle.
Hydrogen Embrittlement Susceptibility of R4 and R5 High-Strength Mooring Steels in Cold and Warm Seawater
Sep 2018
Publication
Hydrogen embrittlement susceptibility ratios calculated from slow strain rate tensile tests have been employed to study the response of three high-strength mooring steels in cold and warm synthetic seawater. The selected nominal testing temperatures have been 3 °C and 23 °C in order to resemble sea sites of offshore platform installation interest such as the North Sea and the Gulf of Mexico respectively. Three scenarios have been studied for each temperature: free corrosion cathodic protection and overprotection. An improvement on the hydrogen embrittlement tendency of the steels has been observed when working in cold conditions. This provides a new insight on the relevance of the seawater temperature as a characteristic to be taken into account for mooring line design in terms of hydrogen embrittlement assessment.
Microbial Fuel Cells: Technologically Advanced Devices and Approach for Sustainable/renewable Energy Development
Dec 2021
Publication
There is a huge quantity of energy needs/demands for multiple developmental and domestic activities in the modern era. And in this context consumption of more non-renewable energy is reported and created many problems or issues (availability of fossil fuel stocks in the future period causes a huge quantity of toxic gases or particles or climatic change effects) at the global level. And only sustainable or renewable fuel development can provide alternate fuel and we report from various biological agents processes including microbial biofuel cell applications for future energy needs only. These will not cause any interference in natural resources or services. Microbial biofuel cells utilize the living cell to produce bioelectricity via bioelectrochemical system. It can drive electricity or other energy generation currents via lived cell interaction. Microbial fuel cells (MFCs) and enzymatic biofuel cells with their advancement in design can improve sustainable bio-energy production by proving an efficient conversion system compared to chemical fuels into electric power. Different types of MFCs operation are reported in wastewater treatment with biogas biohydrogen and other biofuel/energy generation. Later biogas can convert into electric power. Hybrid microbial biofuel cell utility with photochemical reaction is found for electricity generation. Recent research and development in microbial biofuel design and its application will emphasize bioenergy for the future.
Numerical Simulation of Solid Oxide Fuel Cells Comparing Different Electrochemical Kinetics
Mar 2021
Publication
Solid oxide fuel cells (SOFCs) produce electricity with high electrical efficiency and fuel flexibility without pollution for example CO2 NOx SOx and particles. Still numerous issues hindered the large‐scale commercialization of fuel cell at a large scale such as fuel storage mechanical failure catalytic degradation electrode poisoning from fuel and air for example lifetime in relation to cost. Computational fluid dynamics (CFD) couples various physical fields which is vital to reduce the redundant workload required for SOFC development. Modeling of SOFCs includes the coupling of charge transfer electrochemical reactions fluid flow energy transport and species transport. The Butler‐Volmer equation is frequently used to describe the coupling of electrochemical reactions with current density. The most frequently used is the activation‐ and diffusion‐controlled Butler‐Volmer equation. Three different electrode reaction models are examined in the study which is named case 1 case 2 and case 3 respectively. Case 1 is activation controlled while cases 2 and 3 are diffusion‐controlled which take the concentration of redox species into account. It is shown that case 1 gives the highest reaction rate followed by case 2 and case 3. Case 3 gives the lowest reaction rate and thus has a much lower current density and temperature. The change of activation overpotential does not follow the change of current density and temperature at the interface of the anode and electrolyte and interface of cathode and electrolyte which demonstrates the non‐linearity of the model. This study provides a reference to build electrochemical models of SOFCs and gives a deep understanding of the involved electrochemistry.
Mechanical Properties of Gas Main Steels after Long-Term Operation and Peculiarities of Their Fracture Surface Morphology
Feb 2019
Publication
Regularities of steel structure degradation of the “Novopskov-Aksay-Mozdok” gas main pipelines (Nevinnomysskaya CS) as well as the “Gorky-Center” pipelines (Gavrilovskaya CS) were studied. The revealed peculiarities of their degradation after long-term operation are suggested to be treated as a particular case of the damage accumulation classification (scheme) proposed by prof. H.M. Nykyforchyn. It is shown that the fracture surface consists of sections of ductile separation and localized zones of micro-spalling. The presence of the latter testifies to the hydrogen-induced embrittlement effect. However the steels under investigation possess sufficiently high levels of the mechanical properties required for their further safe exploitation both in terms of durability and cracking resistance.
Hydrogen from Natural Gas – The Key to Deep Decarbonisation
Jul 2019
Publication
This Discussion Paper was commissioned by Zukunft ERDGAS to contribute to the debate concerning the deep decarbonisation of the European energy sector required to meet the Paris Agreement targets. Previous discussion papers have put forward decarbonisation pathways that rely heavily on ‘All-Electric’ solutions. These depend predominantly on renewable electricity to deliver decarbonisation of all sectors. This paper offers an alternative to an ‘All-Electric’ solution by building an alternative pathway that allows the inclusion of gas based technologies alongside the ‘All-Electric’ pathway technologies. The new pathway demonstrates that hydrogen from natural gas can be an essential complement to renewable electricity. The pathway also considers the benefits of utilising methane pyrolysis technology in Europe to produce zero carbon hydrogen.
Read the full report at this link
Read the full report at this link
Analysis of the Hydrogen Induced Cracking by Means of the Small Punch Test: Effect of the Specimen Geometry and the Hydrogen Pre-Charge Mode
Nov 2018
Publication
This paper presents a simplified procedure to analyse the Hydrogen Induced Cracking (HIC) of structural steels by means of the Small Punch Test (SPT). Two types of notched specimens were used: one with through-thickness lateral notch and another with surface longitudinal notch. The results for conventional specimens were compared with those for hydrogen pre-charged specimens. For this purpose two different methods to introduce hydrogen in the specimens were used: cathodic/electrochemical pre-charging and pressurized gaseous hydrogen pre-charging. The results obtained with both methods are also discussed.
HyUnder – Hydrogen Underground Storage at Large Scale: Case Study Spain
Aug 2015
Publication
Hydrogen as an energy carrier is understood as a system capable of storing energy for a later use in a controlled manner. Surplus electricity from renewable energy serves for green hydrogen generation via electrolysis. Once produced the hydrogen is stored for later consumption. This paper describes the Spanish Case Study of the HyUnder project which aims to evaluate the potential of underground hydrogen storage for large-scale energy storage along Europe analysing besides the Spanish Case France Germany the Netherlands Romania and the United Kingdom. This case study has considered for the assessment the competitiveness of hydrogen storage against other large scale energy storage concepts the geological potential for hydrogen storage in the region how to embed the hydrogen energy storage in the energy market and the possible business cases in four different applications: transport Power to Gas re-electrification and industry taking into account all the economic aspects such us the electrolyser OPEX and CAPEX or the cavern electricity and water costs. It is shown that the Spanish geology can provide four technical options for hydrogen underground storage. Results have shown the interest of the technology in short – medium term especially linked to certain conditions of high intermittent renewable energy penetration in the Spanish power grid that result in surplus or residual electricity. Hydrogen storage is interesting because it can integrate renewable energy systems in other sectors which do not have overcapacity and a high use of fossil fuels as the natural gas sector and the transport sector. Moreover all the economic issues have been analysed for two different horizons 2025 and 2050; concluding that the average price of electricity is the main cost. From the financial results transport application represents a business case which although in order has enough values of hydrogen demand to be stored combination of different applications must be needed in order to make sense to the development of the cavern.
A Comprehensive Review of Microbial Electrolysis Cells (MEC) Reactor Designs and Configurations for Sustainable Hydrogen Gas Production
Nov 2015
Publication
Hydrogen gas has tremendous potential as an environmentally acceptable energy carrier for vehicles. A cutting edge technology called a microbial electrolysis cell (MEC) can achieve sustainable and clean hydrogen production from a wide range of renewable biomass and wastewaters. Enhancing the hydrogen production rate and lowering the energy input are the main challenges of MEC technology. MEC reactor design is one of the crucial factors which directly influence on hydrogen and current production rate in MECs. The rector design is also a key factor to upscaling. Traditional MEC designs incorporated membranes but it was recently shown that membrane-free designs can lead to both high hydrogen recoveries and production rates. Since then multiple studies have developed reactors that operate without membranes. This review provides a brief overview of recent advances in research on scalable MEC reactor design and configurations.
Investigation of the Influence of Pre-Charged Hydrogen on Fracture Toughness of As-Received 2.25Cr1Mo0.25V Steel and Weld
Jun 2018
Publication
Fracture failure caused by hydrogen embrittlement (HE) is a major concern for the system reliability and safety of hydrogen storage vessels which are generally made of 2.25Cr1Mo0.25V steel. Thus study of the influence of pre-charged hydrogen on fracture toughness of as-received 2.25Cr1Mo0.25V steel and weld is of significant importance. In the current work the influence of hydrogen on fracture toughness of as-received 2.25Cr1Mo0.25V steel and weld was systematically studied. Base metal (BM) and weld metal (WM) specimens under both hydrogen-free and hydrogen-charged conditions were tested using three-point bending tests. Hydrogen was pre-charged inside specimens by the immersion charging method. The J-integral values were calculated for quantitatively evaluating the fracture toughness. In order to investigate the HE mechanisms optical microscopy (OM) and scanning electron microscopy (SEM) were used to characterize the microstructure of BM and WM specimens. The results revealed that the presence of pre-charged hydrogen caused a significant decrease of the fracture toughness for both BM and WM specimens. Moreover the pre-charged hydrogen led to a remarkable transition of fracture mode from ductile to brittle pattern in 2.25Cr1Mo0.25V steel.
Assessing Uncertainties of Well-To-Tank Greenhouse Gas Emissions from Hydrogen Supply Chains
Jun 2017
Publication
Hydrogen is a promising energy carrier in the clean energy systems currently being developed. However its effectiveness in mitigating greenhouse gas (GHG) emissions requires conducting a lifecycle analysis of the process by which hydrogen is produced and supplied. This study focuses on the hydrogen for the transport sector in particular renewable hydrogen that is produced from wind- or solar PV-powered electrolysis. A life cycle inventory analysis is conducted to evaluate the Well-to-Tank (WtT) GHG emissions from various renewable hydrogen supply chains. The stages of the supply chains include hydrogen being produced overseas converted into a transportable hydrogen carrier (liquid hydrogen or methylcyclohexane) imported to Japan by sea distributed to hydrogen filling stations restored from the hydrogen carrier to hydrogen and filled into fuel cell vehicles. For comparison an analysis is also carried out with hydrogen produced by steam reforming of natural gas. Foreground data related to the hydrogen supply chains are collected by literature surveys and the Japanese life cycle inventory database is used as the background data. The analysis results indicate that some of renewable hydrogen supply chains using liquid hydrogen exhibited significantly lower WtT GHG emissions than those of a supply chain of hydrogen produced by reforming of natural gas. A significant piece of the work is to consider the impacts of variations in the energy and material inputs by performing a probabilistic uncertainty analysis. This suggests that the production of renewable hydrogen its liquefaction the dehydrogenation of methylcyclohexane and the compression of hydrogen at the filling station are the GHG-intensive stages in the target supply chains.
Effect of Vanadium-alloying on Hydrogen Embrittlement of Austenitic High-nitrogen Steels
Dec 2018
Publication
The effect of hydrogen on tensile behavior and fracture mechanisms of V-alloying and V-free high-nitrogen austenitic steels was evaluated. Two steels with the chemical compositions of Fe-23Cr–17Mn–0.1C–0.6N (0V-HNS) and Fe-19Cr–22Mn–1.5V–0.3C–0.9N (1.5V-HNS) were electrochemically hydrogen-charged in NaCl water-solution for 100 hours. According to X-ray diffraction analysis and TEM researches V-alloying promotes particle strengthening of the 1.5V-HNS. Despite differences in chemical compositions namely carbon and nitrogen concentrations a solid solution hardening is similar for both steels because of precipitate-assisted depletion of austenite by interstitial atoms (carbon and nitrogen) in 1.5V-HNS. For hydrogen-free state the values of the yield stress and the tensile strength are higher for particle-strengthened 1.5V-HNS as compared to 0V-HNS. Hydrogen-charging increases both the yield stress and the tensile strength of the steels but hydrogen-assisted fracture micromechanisms are different for 0V-HNS and 1.5V-HNS. Hydrogen-charging drastically reduces a total elongation in 0V-HNS but provides insufficient embrittlement in 1.5V-HNS. Hydrogen-assisted brittle layers form on lateral surfaces of the specimens and the widths and fracture micromechanisms in them are different for two steels. For 0V-HNS surface layers of 84 μm in width possess transgranular brittle fracture mechanism (quasi-cleavage mode). For 1.5V-HNS the brittle surface layers (31 μm width) destroy in intergranular brittle fracture mode. The central parts of steel specimens show dimple fracture similar to hydrogen-free steels. The possible reasons for different hydrogen-induced effects in 0V-HNS and 1.5V-HNS are discussed.
Health-Conscious Optimization of Long-Term Operation for Hybrid PEMFC Ship Propulsion Systems
Jun 2021
Publication
The need to decarbonize the shipping sector is leading to a growing interest in fuel cell-based propulsion systems. While Polymer Electrolyte Membrane Fuel Cells (PEMFC) represent one of the most promising and mature technologies for onboard implementation they are still prone to remarkable degradation. The same problem is also affecting Lithium-ion batteries (LIB) which are usually coupled with PEMFC in hybrid powertrains. By including the combined degradation effects in an optimization strategy the best compromise between costs and PEMFC/LIB lifetime could be determined. However this is still a challenging yet crucial aspect rarely addressed in the literature and rarely yet explored. To fill this gap a health-conscious optimization is here proposed for the long-term minimization of costs and PEMFC/LIB degradation. Results show that a holistic multi-objective optimization allows a 185% increase of PEMFC/LIB lifetime with respect to a fuel-consumption-minimization-only approach. With the progressive ageing of PEMFC/LIB the hybrid propulsion system modifies the energy management strategy to limit the increase of the daily operation cost. Comparing the optimization results at the beginning and the end of the plant lifetime daily operation costs are increased by 73% and hydrogen consumption by 29%. The proposed methodology is believed to be a useful tool able to give insights into the effective costs involved in the long-term operation of this new type of propulsion system.
Investment in Wind-based Hydrogen Production under Economic and Physical Uncertainties
Feb 2023
Publication
This paper evaluates the economic viability of a combined wind-based green-hydrogen facility from an investor’s viewpoint. The paper introduces a theoretical model and demonstrates it by example. The valuation model assumes that both the spot price of electricity and wind capacity factor evolve stochastically over time; these state variables can in principle be correlated. Besides it explicitly considers the possibility to use curtailed wind energy for producing hydrogen. The model derives the investment project’s net present value (NPV) as a function of hydrogen price and conversion capacity. Thus the NPV is computed for a given price and a range of capacities. The one that leads to the maximum NPV is the ‘optimal’ capacity (for the given price). Next the authors estimate the parameters underlying the two stochastic processes from Spanish hourly data. These numerical estimates allow simulate hourly paths of both variables over the facility’s expected useful lifetime (30 years). According to the results green hydrogen production starts becoming economically viable above 3 €/kg. Besides it takes a hydrogen price of 4.7 €/kg to reach an optimal conversion capacity half the capacity of the wind park. The authors develop sensitivity analyses with respect to wind capacity factor curtailment rate and discount rate.
The Influence of the First Filling Period Length and Reservoir Level Depth on the Operation of Underground Hydrogen Storage in a Deep Aquifer
Sep 2022
Publication
Underground storage is a method of storing large amounts of renewable energy that can be converted into hydrogen. One of the fundamental problems associated with this process concerns determining the timing and amount of injected gas in the first filling period for the operation of an underground storage facility. Ascertaining the hydrogen flow rate is essential to ensure that the capillary and fracturing pressures are not exceeded. The value of the flow rate was assessed by modelling the injection of hydrogen into a deep aquifer. The best initial H2 injection period was found to be five months. The volume of the cushion gas and the total storage capacity expanded with the extension of the first filling period length. The working capacity grew as the depth increased reaching maximum values at depths of approximately 1200e1400 m. This depth was considered optimal for storing hydrogen in the analysed structure.
Global Hydrogen and Synfuel Exchanges in an Emission-Free Energy System
Apr 2023
Publication
This study investigates the global allocation of hydrogen and synfuels in order to achieve the well below 2 ◦C preferably 1.5 ◦C target set in the Paris Agreement. For this purpose TIMES Integrated Assessment Model (TIAM) a global energy system model is used. In order to investigate global hydrogen and synfuel flows cost potential curves are aggregated and implemented into TIAM as well as demand technologies for the end use sectors. Furthermore hydrogen and synfuel trades are established using liquid hydrogen transport (LH2 ) and both new and existing technologies for synfuels are implemented. To represent a wide range of possible future events four different scenarios are considered with different characteristics of climate and security of supply policies. The results show that in the case of climate policy the renewable energies need tremendous expansion. The final energy consumption is shifting towards the direct use of electricity while certain demand technologies (e.g. aviation and international shipping) require hydrogen and synfuels for full decarbonization. Due to different security of supply policies the global allocation of hydrogen and synfuel production and exports is shifting while the 1.5 ◦C target remains feasible in the different climate policy scenarios. Considering climate policy Middle East Asia is the preferred region for hydrogen export. For synfuel production several regions are competitive including Middle East Asia Mexico Africa South America and Australia. In the case of security of supply policies Middle East Asia is sharing the export volume with Africa while only minor changes can be seen in the synfuel supply.
Investigation of Hydrogen-Blended Natural Gas Pipelines in Utility Tunnel Leakage and Development of an Accident Ventilation Strategy for the Worst Leakage Conditions
Mar 2024
Publication
The development of hydrogen-blended natural gas (HBNG) increases the risk of gas transportation and presents challenges for pipeline security in utility tunnels. The objective of this study is to investigate the diffusion properties of HBNG in utility tunnels and evaluate the effectiveness of various ventilation mechanisms. The numerical simulation software Fluent 2023 R1 is applied to simulate and analyze the leakage of small holes in a HBNG pipeline in the natural gas compartment. By examining the leaking behavior of HBNG through small holes in different circumstances we aimed to identify the most unfavorable operational situation for leakage. Subsequently we analyzed the ventilation strategy for sub-high-pressure pipes at various pressure levels in this unfavorable condition. This study’s findings demonstrate that blending hydrogen improves the gas diffusion capacity and increases the likelihood of explosion. The primary factors that influence the pattern of leakage are the size of the leaking holes and the pressure of the pipeline. The gas compartment experiences the most unfavorable working conditions for natural gas pipeline leaks when there are higher pressures wider leak openings higher hydrogen blending ratios (HBRs) and leaks in close proximity to an air inlet. When the HBR is 20% the minimum accident ventilation rates for pressures of 0.4 MPa and 0.8 MPa are 15 air changes per hour and 21 air changes per hour respectively. The maximum allowable wind speed for accident ventilation is 5 m/s as regulated by China’s national standard GB 50838-2015. This regulation makes it difficult to minimize the risk of leakage in a 1.6 MPa gas pipeline. It is recommended to install a safety interlock device to quickly shut off the pipeline in the event of a leak in order to facilitate the dispersion of the substance.
A Study on the Prediction of the Temperature and Mass of Hydrogen Gas inside a Tank during Fast Filling Process
Dec 2020
Publication
The hydrogen compression cycle system recycles hydrogen compressed by a compressor at high pressure and stores it in a high-pressure container. Thermal stress is generated due to increase in the pressure and temperature of hydrogen in the hydrogen storage tank during the fast filing process. For the sake of safety it is of great practical significance to predict and control the temperature change in the tank. The hydrogen charging process in the storage tank of the hydrogen charging station was studied by experimentation and simulation. In this paper a Computational Fluid Dynamics (CFD) model for non-adiabatic real filling of a 50 MPa hydrogen cylinder was presented. In addition a shear stress transport (k-ω) model and real gas model were used in order to account for thermo-fluid dynamics during the filling of hydrogen storage tanks (50 MPa 343 L). Compared to the simulation results with the experimental data carried out under the same conditions the temperatures calculated from the simulated non-adiabatic condition results were lower (by 5.3%) than those from the theoretical adiabatic condition calculation. The theoretical calculation was based on the experimentally measured pressure value. The calculated simulation mass was 8.23% higher than the theoretical result. The results of this study will be very useful in future hydrogen energy research and hydrogen charging station developments.
Techno-economic Analysis of Hydrogen Production from PV Plants
Jan 2022
Publication
Hydrogen production through electrolysis from renewable sources is expected to play an important role to achieve the reduction targets of carbon dioxide emissions set for the next decades. Electrolysers can use the renewable energy surplus to produce green hydrogen and contribute to making the electrical grid more stable. Hydrogen can be used as medium-long term energy storage converted into other fuels or used as feedstock in industry thus contributing to decarbonise hard-to-abate-sectors. However due to the intermittent and variable nature of solar and wind power the direct coupling of electrolysers with renewables may lead to high production fluctuations and frequent shutdowns. As a consequence accelerated electrolyser degradation and safety issues related to low load operation may arise. In this study simulations of hydrogen production with an electrolyser fed by a PV system are performed in Matlab for a reference year. The effect of PV power fluctuations on the electrolyser operation and production is investigated. The impact of the electrolyser size for a fixed nominal power of the PV plant is also analysed from both energetic and economic points of view.
Process of Transformation to Net Zero Steelmaking: Decarbonisation Scenarios Based on the Analysis of the Polish Steel Industry
Apr 2023
Publication
The European steel industry is experiencing new challenges related to the market situation and climate policy. Experience from the period of pandemic restrictions and the effects of Russia’s armed invasion of Ukraine has given many countries a basis for including steel along with raw materials (coke iron ore electricity) in economic security products (CRMA). Steel is needed for economic infrastructure and construction development as well as a material for other industries (without steel factories will not produce cars machinery ships washing machines etc.). In 2022 steelmakers faced a deepening energy crisis and economic slowdown. The market situation prompted steelmakers to impose restrictions on production volumes (worldwide production fell by 4% compared to the previous year). Despite the difficult economic situation of the steel industry (production in EU countries fell by 11% in 2022 compared to the previous year) the EU is strengthening its industrial decarbonisation policy (“Fit for 55”). The decarbonisation of steel production is set to accelerate by 2050. To sharply reduce carbon emissions steel mills need new steelmaking technologies. The largest global steelmakers are already investing in new technologies that will use green hydrogen (produced from renewable energy sources). Reducing iron ore with hydrogen plasma will drastically reduce CO2 emissions (steel production using hydrogen could emit up to 95% less CO2 than the current BF + BOF blast furnace + basic oxygen furnace integrated method). Investments in new technologies must be tailored to the steel industry. A net zero strategy (deep decarbonisation goal) may have different scenarios in different EU countries. The purpose of this paper was to introduce the conditions for investing in low-carbon steelmaking technologies in the Polish steel market and to develop (based on expert opinion) scenarios for the decarbonisation of the Polish steel industry.
Solar Hydrogen for High Capacity, Dispatchable, Long-distance Energy transmission – A Case Study for Injection in the Greenstream Natural Gas Pipeline
Nov 2022
Publication
This paper presents the results of techno-economic modelling for hydrogen production from a photovoltaic battery electrolyser system (PBES) for injection into a natural gas transmission line. Mellitah in Libya connected to Gela in Italy by the Greenstream subsea gas transmission line is selected as the location for a case study. The PBES includes photovoltaic (PV) arrays battery electrolyser hydrogen compressor and large-scale hydrogen storage to maintain constant hydrogen volume fraction in the pipeline. Two PBES configurations with different large-scale storage methods are evaluated: PBESC with compressed hydrogen stored in buried pipes and PBESL with liquefied hydrogen stored in spherical tanks. Simulated hourly PV electricity generation is used to calculate the specific hourly capacity factor of a hypothetical PV array in Mellitah. This capacity factor is then used with different PV sizes for sizing the PBES. The levelised cost of delivered hydrogen (LCOHD) is used as the key techno-economic parameter to optimise the size of the PBES by equipment sizing. The costs of all equipment except the PV array and batteries are made to be a function of electrolyser size. The equipment sizes are deemed optimal if PBES meets hydrogen demand at the minimum LCOHD. The techno-economic performance of the PBES is evaluated for four scenarios of fixed and constant hydrogen volume fraction targets in the pipeline: 5% 10% 15% and 20%. The PBES can produce up to 106 kilotonnes of hydrogen per year to meet the 20% target at an LCOHD of 3.69 €/kg for compressed hydrogen storage (PBESC) and 2.81 €/kg for liquid hydrogen storage (PBESL). Storing liquid hydrogen at large-scale is significantly cheaper than gaseous hydrogen even with the inclusion of a significantly larger PV array that is required to supply additional electrcitiy for liquefaction.
OIES Podcast – PolyGrid 2050: Integrating Hydrogen into the European Energy Transfer Infrastructure Landscape
Feb 2023
Publication
In this podcast David Ledesma talks with Rahmat Poudineh and Martin Palovic about their paper on integrating hydrogen into the European energy transfer infrastructure landscape. As hydrogen is expected to play an important role in European plans towards climate neutrality adequate hydrogen transport (and storage) infrastructure needs to be established. However hydrogen transport infrastructures are costly and have a long lead time. Furthermore hydrogen can be transported via a variety of means: it can be transported as a gas via pipelines or liquid via road rail and sea or even converted to derivatives such as ammonia or methanol for long distance transportation. It is also possible to transfer electrical energy instead of hydrogen and produce hydrogen in a decentralized way. From a system perspective all these infrastructures represent elements of a grand hydrogen ‘polygrid’ that will be the backbone of the future decarbonized energy system. This raises the fundamental question of how to prevent inefficiency and infrastructure redundancy across different modes of hydrogen transport. The task is made more challenging by technological uncertainty the unpredictability of future supply and demand for hydrogen network externality effects and investment irreversibility of grid-based infrastructures. In this podcast we discuss three possible coordination approaches to optimise future cross-sectoral investment into hydrogen transport infrastructure and highlight their strengths and shortcomings.
The podcast can be found on their website.
The podcast can be found on their website.
Chilean National Green Hydrogen Strategy
Nov 2020
Publication
Like hydrogen Chile is small by nature and accordingly contributes just 0.3% to global greenhouse gas emissions. However we too have an outsized role to play in turning the tide on rising emissions and pursuing a low carbon path to growth and development.<br/>What we lack in size we more than make up for in potential. In the desert in the North with the highest solar irradiance on the planet and in the Patagonia in the South with strong and consistent winds we have the renewable energy potential to install 70 times the electricity generation capacity we have today. This abundant renewable energy will enable us to become the cheapest producer of green hydrogen on Earth. Our National Green Hydrogen Strategy is aimed at turning this promise into reality.<br/>The Strategy is the result of collaborative work between industry academia civil society and the public sector and is an essential piece of our carbon neutrality plan and commitment to sustainable development. It will allow us to produce and export products that are created using zero carbon fuels distinguishing our exports as clean products for end users. It will also enable us to export our renewable energy to the world in the form of green liquid hydrogen green ammonia and clean synthetic fuels.<br/>Traditionally Chile lacked fossil fuels and was forced to import the energy it required. Now the coming of age of the tiniest atom will allow us to drive deep decarbonization in our own country and throughout the world. This Strategy is the first step for Chile in embracing this promise and fulfilling its new potential.
Implementation of Fuel Cells in Aviation from a Maintenance, Repair and Overhaul Perspective
Dec 2022
Publication
Hydrogen is one of the most promising power sources for meeting the aviation sector’s long-term decarbonization goals. Although on-board hydrogen systems namely fuel cells are extensively researched the maintenance repair and overhaul (MRO) perspective remains mostly unaddressed. This paper analyzes fuel cells from an MRO standpoint based on a literature review and comparison with the automotive sector. It also examines how well the business models and key resources of MRO providers are currently suited to provide future MRO services. It is shown that fuel cells require extensive MRO activities and that these are needed to meet the aviation sector’s requirements for price safety and especially durability. To some extent experience from the automotive sector can be built upon particularly with respect to facility requirements and qualification of personnel. Yet MRO providers’ existing resources only partially allow them to provide these services. MRO providers’ underlying business models must adapt to the implementation of fuel cells in the aviation sector. MRO providers and services should therefore be considered and act as enablers for the introduction of fuel cells in the aviation industry.
An Inter-laboratory Comparison between 13 International Laboratories for Eight Components Relevant for Hydrogen Fuel Quality Assessment
Mar 2024
Publication
The quality of the hydrogen delivered by refuelling stations is critical for end-users and society. The purity of the hydrogen dispensed at hydrogen refuelling points should comply with the technical specifications included in the ISO 14687:2019 and EN 17124:2022 standards. Once laboratories have set up methods they need to verify their performances for example through participation in interlaboratory comparisons. Due to the challenge associated with the production of stable reference materials and transport of these which are produced in hydrogen at high pressure (>10 bar) interlaboratory comparisons have been organized in different steps with increasing extent. This study describes an inter-laboratory comparison exercise for hydrogen fuel involving a large number of participants (13 laboratories) completed in less than a year and included eight key contaminants of hydrogen fuel at level close to the ISO14687 threshold. These compounds were selected based on their high probability of occurrence or because they have been found in hydrogen fuel samples. For the results of the intercomparison it appeared that fully complying with ISO 21087:2019 is still challenging for many participants and highlighted the importance of organising these types of exercises. Many laboratories performed corrective actions based on their results which in turn significantly improved their performances.
Research on the Adaptability of Proton Exchange Membrane Electrolysis in Green Hydrogen-Electric Coupling System Under Multi-operating Conditions
Mar 2023
Publication
The green hydrogen–electric coupling system can consume locally generated renewable energy thereby improving energy utilization and enabling zero-carbon power supply within a certain range. This study focuses on a green hydrogen–electric coupling system that integrates photovoltaic energy storage and proton exchange membrane electrolysis (PEME). Firstly the impact of operating temperature power quality and grid auxiliary services on the characteristics of the electrolysis cell is analyzed and a voltage model and energy model for the cell are established. Secondly a multi-operating conditions adaptability experiment for PEME grid-connected operation is designed. A test platform consisting of a grid simulator simulated photovoltaic power generation system lithium battery energy storage system PEME and measurement and acquisition device is then built. Finally experiments are conducted to simulate multi-operating conditions such as temperature changes voltage fluctuations frequency offsets harmonic pollution and current adjustment speed. The energy efficiency and consumption is calculated based on the recorded data and the results are helpful to guide the operation of the system.
Techno-economic Assessment of Long-distance Supply Chains of Energy Carriers: Comparing Hydrogen and Iron for Carbon-free Electricity Generation
Mar 2023
Publication
The effective usage of renewable energy sources requires ways of storage and delivery to balance energy demand and availability divergences. Carbon-free chemical energy carriers are proposed solutions converting clean electricity into stable media for storage long-distance energy trade and on-demand electricity generation. Among them hydrogen (H2) is noteworthy being the subject of significant investment and research. Metal fuels such as iron (Fe) represent another promising solution for a clean energy supply but establishing an interconnected ecosystem still requires considerable research and development. This work proposes a model to assess the supply chain characteristics of hydrogen and iron as clean carbon-free energy carriers and then examines case studies of possible trade routes between the potential energy exporters Morocco Saudi Arabia and Australia and the energy importers Germany and Japan. The work comprises the assessment of economic (levelized cost of electricity - LCOE) energetic (thermodynamic efficiency) and environmental (CO2 emissions) aspects which are quantified by the comprehensive model accounting for the most critical processes in the supply chain. The assessment is complemented by sensitivity and uncertainty analyses to identify the main drivers for energy costs. Iron is shown to be lower-cost and more efficient to transport in longer routes and for long-term storage but potentially more expensive and less efficient than H2 to produce and convert. Uncertainties related to the supply chain specifications and the sensitivity to the used variables indicate that the path to viable energy carriers fundamentally depends on efficient synthesis conversion storage and transport. A break-even analysis demonstrated that clean energy carriers could be competitive with conventional energy carriers at low renewable energy prices while carbon taxes might be needed to level the playing field. Thereby green iron shows potential to become an important energy carrier for long-distance trade in a globalized clean energy market.
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