United Kingdom

The combination of offshore wind and green hydrogen provides major opportunities for job creation economic growth and regional regeneration as well as attracting inward investment alongside delivering the emission reductions needed to achieve climate neutrality. In order to get to Net Zero emissions in 2050 the UK is likely to need a minimum of 75GW of offshore wind (OSW) and modelling of the energy system indicates that hydrogen will play a major role in integrating the high levels of OSW on the electricity grid.<br/><br/>Some of the key findings from report are listed below:<br/><br/>The UK has vast resources of offshore wind with the potential for over 600GW in UK waters and potentially up to 1000GW. This is well above the he figure of 75-100GW likely to be needed for UK electricity generation by 2050.<br/>The universities in the UK provide the underpinning science and engineering for electrolysers fuel cells and hydrogen and are home to world-leading capability in these areas.<br/>In order to achieve cost reduction and growing a significant manufacturing and export industry it will be crucial to develop green hydrogen in the next 5 years<br/>By 2050 green hydrogen can be cheaper than blue hydrogen. With accelerated deployment green hydrogen costs can be competitive with blue hydrogen by the eary 2030s.<br/>The combination of additional OSW deployment and electrolyser manufacture alone could generate over 120000 new jobs. These are are expected to be based mainly in manufacturing OSW-related activity shipping and mobility<br/>By 2050 it is estimated that the cumulative gross value added (GVA) from supply of electrolysers and additional OSW farm could be up to £320bn where the majority will come from exports of electrolysers to overseas markets.<br/>The report also calls for immediate government intervention and a new national strategy to support the creation of supply and demand in the new industry.<br/><br/>This study was jointly supported by the Offshore Wind Industry Council (OWIC) and ORE Catapult.

Determination of the behaviour of hydrogen when leaking from pipework on gas distribution assets is essential in assessing the comparative risk associated with using pure hydrogen in place of natural gas in existing assets. Experimental work considering the behaviour of gaseous hydrogen when released in large volumes from gas distribution pipework at pressures of up to 7 barg through holes of up to 200mm in diameter in both buried and unburied scenarios is currently underway. The present paper presents and briefly discusses the results from a set of ignited 20mm diameter releases of hydrogen at pressures up to 7 barg vertically upwards from a pipe in an open excavation. Gaseous releases which find a direct route to atmosphere have the potential to create significant volumes of flammable gas and subsequently significant fires in the case of ignition. It is important to understand both the dispersion distances and thermal hazard field to be able to understand the comparative risk posed when compared to natural gas releases in similar situations. Results of current work completed to date are presented alongside comparisons with known properties of natural gas releases and the potential implications to the comparative risk of hydrogen network operation. The work has been conducted at the DNV GL Spadeadam Testing and Research Centre UK as part of the UK Gas Distribution Networks and Ofgem National Innovation Competition funded H21 project.

ISSUES MONITOR 2020: DECODING NEW SIGNALS OF CHANGE

The annual World Energy Issues Monitor provides unique insight into what energy policymakers CEOs and leading experts identify as Critical Uncertainties and Action Priorities. New this year the Issues Monitor also provides readers with the views of the individual customer detailing their perceptions of their role in the overall energy system. The Issues Monitor report includes a global issues map 58 country maps and six regional maps as well as perspectives from Future Energy Leaders (FEL) and energy innovators.

GLOBAL PERSPECTIVES

The 2020 global map incorporates all survey responses representing the views of over 3000 energy leaders from 104 countries. In this era of transition defined by decentralisation digitalisation and decarbonisation energy leaders must pay attention to many different signals of change and distinguish key issues from the noise. The Issues Monitor identifies shifting patterns of connected issues shaping energy transitions.

A NEW PULSE

The focus for the 2010s was about trying to automate and upgrade the energy system and set targets to move the energy transition forward. Digitalisation accelerated the transition of all sectors towards a more customer-centric environment. New policies and regulations were introduced to facilitate this transition and empower consumers. As a result the 2020s may very well be about realising those targets through a transition from activism to action.

TREND TRACKING: CCS

In comparing response from the Oil & Gas sector in 2015 with 2019 we found that almost half of respondents identified Carbon Capture & Storage (CCS) as a high impact issue in 2019 up from about a third in 2015. CCS is increasingly being viewed as an essential option for continued hydrocarbon use although governmental support is needed to enable scalability and cost effectiveness.

A DIFFERENCE IN OPINION: NUCLEAR

Opinions remain polarised but in many European countries nuclear power is increasingly recognised as a carbon-free energy source and potentially an integral part of the future energy mix. In December 2019 the European Commission set a target of net-zero carbon emissions by 2050. There is qualified support among energy leaders to include nuclear energy to help create a carbon neutral continent and enable a just energy transition.

This paper describes a 1-D numerical model for the prediction of heat and mass transfer through an intumescent paint that is applied to an on-board high-pressure GH2 storage tank. The intumescent paint is treated as a composite system consisting of three general components decomposing in accordance with independent finite reaction rates. A moving mesh that is employed for a better prediction of the expansion process of the intumescent paint is based on the local changes of heat and mass. The numerical model is validated against experiments by Cagliostro et al. (1975). The overall model results are used to estimate effect of intumescent paint on fire resistance of carbon-fibre reinforced GH2 storage.

In super duplex stainless steels (SDSSs) both austenite and ferrite are susceptible to hydrogen embrittlement however there is a lack of understanding into the effect of hydrogen in each phase. In this study in neutron diffraction was applied on hydrogen-charged (H-charged) samples to investigate the hydrogen embrittlement behaviour in super duplex stainless steels. The result reveals that austenite maintains good plasticity during tensile testing whilst a loss of it is realised in ferrite. Fractography analysis reveals the diffusion of hydrogen induced a brittle-to-ductile transition from the sample surface towards the centre; hydrogen embrittlement vanishes as the specimen’s centre is approached while it is demonstrated to disappear first in austenite but not in ferrite. This transition can be predicted by applying a physics-based hydrogen embrittlement model which incorporates the effects of hydrogen concentration hydrogen diffusivity residual stress loading state and temperature. The present work demonstrates the dissimilar susceptibility of austenite and ferrite to hydrogen embrittlement providing a tool to describe it.

Europe has built up one of the best gas distribution infrastructures in the world. There’s one problem though. It distributes natural gas a fuel that we will hardly be able to use if we’re to reach our net zero targets. Can we use the infrastructure instead for clean hydrogen – either blended with natural gas as a stepping stone or with pure hydrogen in the future? In this episode we put aside discussion on the extent to which we should do this – and focus on whether or not we can do this and what’s involved in doing so.

Jon Slowe is joined by Eva Hennig Head of Department for EU Energy Policy at Thüga an alliance of German municipal energy companies (as well as chair of Eurogas’s distribution committee); Keith Owen Head of Systems Development and Energy Strategy at Northern Gas Networks in the UK; and Delta-EE expert Rob Castek.  

This White Paper has been commissioned by the UK Hydrogen and Fuel Cell (H2FC) SUPERGEN Hub to examine the roles and potential benefits of hydrogen and fuel cell technologies for heat provision in future low-carbon energy systems. The H2FC SUPERGEN Hub is an inclusive network encompassing the entire UK hydrogen and fuel cells research community with around 100 UK-based academics supported by key stakeholders from industry and government. It is funded by the UK EPSRC research council as part of the RCUK Energy Programme. This paper is the first of four that will be published over the lifetime of the Hub with the others examining: (i) low-carbon energy systems (including balancing renewable intermittency); (ii) low-carbon transport systems; and (iii) the provision of secure and affordable energy supplies for the future

• Hydrogen and fuel cells are part of the cost-optimal heating technology portfolio in long-term UK energy system scenarios.
• Fuel cell CHP is already being deployed commercially around the world.
• Hydrogen can be a zero-carbon alternative to natural gas. Most technologies that use natural gas can be adapted to use hydrogen and still provide the same level of service.
• Hydrogen and fuel cell technologies avoid some of the disadvantages of other low-carbon heating technologies.

Time is rapidly running out to make the crucial planning decisions and secure investment to keep the UK on track to deliver a reliable affordable and decarbonised energy system to meet future emissions regulation enshrined in the 2008 Climate Change Act according to a report published today by the Royal Academy of Engineering.

Prepared for the Prime Minister's Council for Science and Technology A critical time for UK energy policy details the actions needed now to create a secure and affordable low carbon energy system for 2030 and beyond.

The study looks at the future evolution of the UK’s energy system in the short to medium term. It considers how the system is expected to develop across a range of possible trajectories identified through modelling and scenarios.

The following actions for government are identified as a matter of urgency:

• enable local or regional whole-system large scale pilot projects to establish real-world examples of how the future system will work. These must move beyond  current single technology demonstrators and include all aspects of the energy systems along with consumer behaviour and financial mechanisms
• drive forward new capacity in the three main low carbon electricity generating technologies: nuclear carbon capture and storage (CCS) and offshore wind
• develop policies to accelerate demand reduction especially in domestic heating and introduce smarter demand management
• clarify and stabilise market mechanisms and incentives in order to give industry the confidence to invest.

New technologies could become unexpectedly significant – such as solar PV which has recently become much cheaper. But large scale deployment of novel technologies would take decades and the system cannot be planned on promises and aspirations alone. The Academy calls instead for a combination of known technologies to be scaled up to unprecedented levels and integrated in smarter ways.

The report notes that the addition of shale gas or tight oil is unlikely to have a major impact on the evolution of the UK's energy system as we already have secure and diverse supplies of hydrocarbons from multiple sources.

Dr David Clarke FREng who led the group that produced the report says: “Updating the UK energy system to meet the ‘trilemma’ of decarbonisation security and affordability is a massive undertaking. Meeting national targets affordably requires substantial decarbonisation of the electricity system by 2030 through a mix of nuclear power CCS and renewables with gas generation for balancing. Beyond 2030 we must then largely decarbonise heat and transport potentially through electrification but also using other options such as hydrogen and biofuels. We also need to adapt our transmission and distribution networks to become ‘smarter’”.

"Failure to plan the development of the whole energy system carefully will result at best in huge increases in the cost of delivery or at worst a failure to deliver. Substantial investment is needed and current investment capacity is fragile. For example in the last month projects like Carlton’s new Trafford CCGT plant have announced further financing delays and the hoped-for investment by Drax in the White Rose CCS demonstrator has been withdrawn. The UK has also dropped four places to 11th in EY’s renewable energy country attractiveness index.”

Link to document download on Royal Society Website

Hydrogen energy applications often require that systems are used indoors (e.g. industrial trucks for materials handling in a warehouse facility fuel cells located in a room or hydrogen stored and distributed from a gas cabinet). It may also be necessary or desirable to locate some hydrogen system components/equipment inside indoor or outdoor enclosures for security or safety reasons to isolate them from the end-user and the public or from weather conditions.<br/>Using of hydrogen in confined environments requires detailed assessments of hazards and associated risks including potential risk prevention and mitigation features. The release of hydrogen can potentially lead to the accumulation of hydrogen and the formation of a flammable hydrogen-air mixture or can result in jet-fires. Within Hyindoor European Project carried out for the EU Fuel Cells and Hydrogen Joint Undertaking safety design guidelines and engineering tools have been developed to prevent and mitigate hazardous consequences of hydrogen release in confined environments. Three main areas are considered: Hydrogen release conditions and accumulation vented deflagrations jet fires and including under-ventilated flame regimes (e.g. extinguishment or oscillating flames and steady burns). Potential RCS recommendations are also identified.

The paper describes a lumped-parameter model for vented deflagrations of localised and layered fuel air mixtures. Theoretical model background is described to allow insight into the model development with focus on lean mixtures and overpressures significantly below 0.1 MPa for protection of low strength equipment and buildings. Phenomena leading to combustion augmentation was accounted based on conclusions of recent CFD studies. Technique to treat layered mixtures with concentration gradient is demonstrated. The model is validated against 25 vented deflagration experiments with lean non-uniform and layered hydrogen-air mixtures performed in Health and Safety Laboratory (UK) and Karlsruhe Institute of Technology (Germany).

Achieving the UK's net zero target by 2050 will be a challenge. Hydrogen can make a substantial contribution but it needs investment and policy support to establish demand increase the scale of deployment and reduce costs. The Ten Point Plan for a Green Industrial Revolution confirms the government’s commitment to drive the growth of low carbon hydrogen in the UK through a range of measures. This includes publishing its hydrogen strategy and setting out revenue mechanisms to attract private investment as well as allocating further support for hydrogen production and hydrogen applications in heating.

We have created a bespoke model to help understand the cost of hydrogen in the UK across the value chain under different pathways. Our analysis highlights areas for cost reduction and identifies factors that could make hydrogen more attractive to investors.

You can read the full report on the Deloitte website at this link

In future energy supply systems hydrogen and electricity may be generated in decarbonized industrial clusters using a common infrastructure for natural gas supply electricity grid and transport and geological storage of CO_2. The novel contribution of this article consists of using sequential combustion in a steam methane reforming (SMR) hydrogen plant to allow for capital and operating cost reduction by using a single post-combustion carbon capture system for both the hydrogen process and the combined cycle gas turbine (CCGT) power plant plus appropriate integration for this new equipment combination. The concept would be widely applied to any post-combustion CO₂ capture process. A newly developed rigorous gPROMs model of two hydrogen production technologies covering a wide range of hydrogen production capacities thermodynamically integrated with commercially available gas turbine engines quantifies the step change in thermal efficiency and hydrogen production efficiency. It includes a generic post-combustion capture technology – a conventional 30%wt MEA process - to quantify the reduction in size of CO₂ absorber columns the most capital intensive part of solvent-based capture systems. For a conventional SMR located downstream of an H-class gas turbine engine followed by a three-pressure level HRSG and a capture plant with two absorbers the integrated system produces ca. 696400 Nm3/h of H₂ with a net power output of 651 MWe at a net thermal efficiency of 38.9%LHV. This corresponds to 34 MWe of additional power increasing efficiency by 4.9% points and makes one absorber redundant compared to the equivalent non-integrated system producing the same volume of H₂. For a dedicated gas heated reformer (GHR) located downstream of an aeroderivative gas turbine engine followed by a two-pressure level HRSG and a capture plant with one absorber the integrated system produces ca. 80750 Nm3/h of H₂ with a net power output of 73 MWe and a net thermal efficiency of 54.7%LHV. This corresponds to 13 MWe of additional power output increasing efficiency by 13.5% points and also makes one absorber redundant. The article also presents new insights for the design and operation of reformers integrated with gas turbines and with CO₂ capture.

Biofuels from biomass gasification are reviewed here and demonstrated to be an attractive option. Recent progress in gasification techniques and key generation pathways for biofuels production process design and integration and socio-environmental impacts of biofuel generation are discussed with the goal of investigating gasification-to-biofuels’ credentials as a sustainable and eco-friendly technology. The synthesis of important biofuels such as bio-methanol bio-ethanol and higher alcohols bio-dimethyl ether Fischer Tropsch fuels bio-methane bio-hydrogen and algae-based fuels is reviewed together with recent technologies catalysts and reactors. Significant thermodynamic studies for each biofuel are also examined. Syngas cleaning is demonstrated to be a critical issue for biofuel production and innovative pathways such as those employed by Choren Industrietechnik Germany and BioMCN the Netherlands are shown to allow efficient methanol generation. The conversion of syngas to FT transportation fuels such as gasoline and diesel over Co or Fe catalysts is reviewed and demonstrated to be a promising option for the future of biofuels. Bio-methane has emerged as a lucrative alternative for conventional transportation fuel with all the advantages of natural gas including a dense distribution trade and supply network. Routes to produce H2 are discussed though critical issues such as storage expensive production routes with low efficiencies remain. Algae-based fuels are in the research and development stage but are shown to have immense potential to become commercially important because of their capability to fix large amounts of CO₂ to rapidly grow in many environments and versatile end uses. However suitable process configurations resulting in optimal plant designs are crucial so detailed process integration is a powerful tool to optimize current and develop new processes. LCA and ethical issues are also discussed in brief. It is clear that the use of food crops as opposed to food wastes represents an area fraught with challenges which must be resolved on a case by case basis.

Many railway vehicles use diesel as their energy source but exhaust emissions and concerns about economical fuel supply demand alternatives. Railway electrification is not cost effective for some routes particularly low-traffic density regional lines. The journey of a regional diesel–electric train is simulated over the British route Birmingham Moor Street to Stratford-upon-Avon and return to establish a benchmark for the conceptual design of a hydrogen-powered and hydrogen-hybrid vehicle. A fuel cell power plant compressed hydrogen at 350 and 700 bar and metal-hydride storage are evaluated. All equipment required for the propulsion can be accommodated within the space of the original diesel– electric train while not compromising passenger-carrying capacity if 700 bar hydrogen tanks are employed. The hydrogen trains are designed to meet the benchmark journey time of 94 min and the operating range of a day without refuelling. An energy consumption reduction of 34% with the hydrogen-powered vehicle and a decrease of 55% with the hydrogen-hybrid train are achieved compared with the original diesel–electric. The well-to-wheel carbon dioxide emissions are lower for the conceptual trains: 55% decrease for the hydrogen-powered and 72% reduction for the hydrogen-hybrid assuming that the hydrogen is produced from natural gas.

Integrated energy systems have become an area of interest as with growing energy demand globally means of producing sustainable energy from flexible sources is key to meet future energy demands while keeping carbon emissions low. Hydrogen is a potential solution for providing flexibility in the future energy mix as it does not emit harmful gases when used as an energy source. In this paper an integrated energy system including hydrogen as an energy vector and hydrogen storage is studied. The system is used to assess the behaviour of a hydrogen production and storage system under different renewable energy generation profiles. Two case studies are considered: a high renewable energy generation scenario and a low renewable energy generation scenario. These provide an understanding of how different levels of renewable penetration may affect the operation of an electrolyser and a fuel cell against an electricity import/export pricing regime. The mathematical model of the system under study is represented using the energy hub approach with system optimisation through linear programming conducted via MATLAB to minimise the total operational cost. The work undertaken showcases the unique interactions the fuel cell has with the hydrogen storage system in terms of minimising grid electricity import and exporting stored hydrogen as electricity back to the grid when export prices are competitive.

This paper presents a study undertaken on a naturally aspirated direct injection diesel engine investigating the combustion and emission characteristics of CH₄-CO₂  and CH₄-CO₂ -H₂ mixtures. These aspirated gas mixtures were pilot-ignited by diesel fuel while the engine load was varied between 0 and 7 bar IMEP by only adjusting the flow rate of the aspirated mixtures. The in-cylinder gas composition was also investigated when combusting CH₄-CO₂ and CH₄-CO₂-H₂ mixtures at different engine loads with in cylinder samples collected using two different sampling arrangements. The results showed a longer ignition delay period and lower peak heat release rates when the proportion of CO₂ was increased in the aspirated mixture. Exhaust CO₂ emissions were observed to be higher for 60 CH₄:40CO₂ mixture but lower for the 80CH₄:20CO₂ mixture as compared to diesel fuel only combustion at all engine loads. Both exhaust and in-cylinder NO_x levels were observed to decrease when the proportion of CO₂ was increased; NO_x levels increased when the proportion of H₂ was increased in the aspirated mixture. In-cylinder NO_x levels were observed to be higher in the region between the sprays as compared to within the spray core attributable to higher gas temperatures reached post ignition in that region.

Emissions from natural gas combustion and use are the largest source of greenhouse gas (GHG) emissions in the UK. The use of hydrogen in place of natural gas in principle offers a potential route to long term widespread decarbonisation of gas distribution networks as shown by the Leeds City Gate (‘H21’) study.1 The purpose of considering conversion to hydrogen is to deliver widespread carbon abatement across the UK at lower cost than alternative decarbonisation strategies.<br/>The Government is to finalise and publish the long-awaited ‘Clean Growth Plan’ along with an Industrial Strategy White Paper in Autumn 2017. Conversion from natural gas to hydrogen potentially on an incremental basis would likely represent a major opportunity for new industrial growth. This might be through the longer term stability or potential expansion of existing (newly decarbonised) energy intensive industry or through business opportunities and growth created from new technologies developed to facilitate the transition to hydrogen as the UK becomes a global leader and major exporter of equipment and skills. Job creation and the resulting gross value added (GVA) to the economy could therefore be significant in delivery of the goals of the Industrial Strategy Challenge Fund (ISCF).<br/>The core requirement is to supply low carbon hydrogen in bulk matching production to distribution network demand at an affordable cost. The H21 study concluded that to do so reliably hydrogen is best produced by reducing natural gas in steam methane reformers (SMRs) fitted with Carbon Capture and Storage (CCS). The study proposed that the considerable inter-seasonal and daily fluctuations in network demand can be managed by storing hydrogen in underground salt formations. It concluded that the SMRs with associated carbon dioxide (CO2) capture should be located near to where CO2 transport and storage infrastructure was likely to be created and noted that candidate locations for this are Teesside Humberside Grangemouth and the Liverpool-Manchester (L-M) area. Two of these Humberside and the L-M area are within the Cadent Gas Ltd (‘Cadent’) network and are also industrial ‘clusters’ with significant populations.<br/>The work reported here builds upon the approach proposed in the H21 project by focussing on defining ‘low carbon’ hydrogen supply and distribution systems in Humberside and the L-M area at a system scale sufficient to supply a large city.2 Both the Humber and L-M clusters are close to salt deposits which are suitable for both daily and inter-seasonal storage of hydrogen (for initial or expanded projects). Furthermore new large-scale gas Combined Cycle Gas Turbine (CCGT) plants widely assumed as likely anchor projects for CCS infrastructure have been consented in both cluster areas confirming that they are both strong candidates as locations for the first CCS clusters and hence as locations for a hydrogen supply system.

<br/>The decarbonisation of heating represents a transformative challenge for many countries. The UK’s net-zero greenhouse gas emissions target requires the removal of fossil fuel combustion from heating in just three decades. A greater understanding of policy processes linked to system transformations is expected to be of value for understanding systemic change; how policy makers perceive policy issues can impact on policy change with knock-on effects for energy system change. This article builds on the literature considering policy maker perceptions and focuses on the issue of UK heat policy. Using qualitative analysis we show that policy makers perceive heat decarbonisation as disruptive technological pathways are seen as deeply uncertain and heat decarbonisation appears to offer policy makers little ‘up-side’. Perceptions are bounded by uncertainty affected by concerns over negative impacts influenced by external influences and relate to ideas of continuity. Further research and evidence on optimal heat decarbonisation and an adaptive approach to governance could support policy makers to deliver policy commensurate with heat decarbonisation. However even with reduced uncertainty and more flexible governance the perceptions of disruption to consumers mean that transformative heat policy may remain unpopular for policy makers potentially putting greenhouse mitigation targets at risk of being missed.

"Hydrogen is expected to play a critical role in the move to a net-zero economy. However large-scale deployment is still in its infancy and there is still much to be done before we can blend hydrogen in large volumes into gas networks and ramp up the production that is required to meet demands of the energy transport and industry sectors. KTN Global Alliance will host two webinars to explore these challenges and opportunities in hydrogen blending on the 2nd and 3rd March 2021.



Exciting pilot projects are being conducted and explored in the UK Canada and US states such as California to determine the technical feasibility of blending hydrogen into existing natural gas systems. Whilst the deployment of hydrogen is in its early stages there is increasing interest around permitting significant percentage blends of hydrogen into gas networks which would enable the carbon intensity of gas supplies to be reduced creating a new demand for hydrogen and with the use of separation and purification technologies downstream support the transportation of pure hydrogen to markets.

Gaps in codes and standards need to be addressed to enable adoption and there may be opportunities for international collaboration and harmonisation to ensure that best practices are shared globally and to facilitate the growth of trade and export markets. There is an opportunity for the UK Canada and US three G7 countries to work together and show market making leadership in key enabling regulation for the new hydrogen economy.



Delivered by KTN Global Alliance on behalf of the British Consulate-General in Vancouver and the UK Science and Innovation Network in Canada and the US these two webinars will showcase hydrogen blending pilot projects in the UK Canada and California highlighting challenges and opportunities with regard to standards development for hydrogen blending and supporting further transatlantic collaboration in this area. The events also form part of the UK’s international engagement to build momentum towards a successful outcome at COP26 the UN climate summit that the UK will host in Glasgow in November 2021. The webinars will bring together experts from industry academia and policy from the UK Canada and California. Attendees will have an opportunity to ask questions and interact using Mentimeter."











Part 2 Highlights and Perspectives from Canada and California can be found here.

Cleavage of aromatic ether bonds through hydrogenolysis is one of the most promising routes for depolymerisation and transformation of lignin into value-added chemicals. Instead of using pressurized hydrogen gas as hydrogen source some reductive organic molecules such as methanol ethanol isopropanol as well as formates and formic acid can serve as hydrogen donor is the process called catalytic transfer hydrogenolysis. This is an emerging and promising research field but there are very few reports. In this paper a comprehensive review of the works is presented on catalytic transfer hydrogenolysis of lignin and lignin model compounds aiming to breakdown the aromatic ethers including α-O-4 β-O-4 and 4-O-5 linkages with focus on reaction mechanisms. The works are organised regarding to different hydrogen donors used to gain an in-depth understanding of the special role of various hydrogen donors in this process. Perspectives on current challenges and opportunities of future research to develop catalytic transfer hydrogenolysis as a competitive and unique strategy for lignin valorisation are also provided.

On this weeks episode the team are talking all things hydrogen in the Orkneys with Adele Lidderdale (Hydrogen Officer for Orkney Island Council) and Jon Clipsham (Hydrogen Manager EMEC). While the islands are best known for their exceptional wildlife whisky and cruise ships the Orkney islands have also emerged as a hub for the green hydrogen economy. Working alongside local government community groups research agencies and private sector partners the islands have deployed hydrogen solutions to heat a school power ferries in port move local council workers from A to B and in the future perhaps make Gin?! All this and more on the show.

The podcast can be found on their website

Together the pathways examined in the report paint a picture of the nationwide transformation getting underway in how we heat our homes and buildings. The report identifies that by 2050 gas used to heat buildings could fall by 75-95% electricity increase from a 10% share today to 30-80% and district heat increase from less than 2% to up to a 40% share. At the same time energy efficiency could help to lower bills and offset the expected growth in our heating needs from an expanding population and building stock. Across most pathways examined in the report mass deployment of low carbon heat solutions ramps up in the lead-in to 2030. Carbon Connect’s overarching recommendation is that the next decade should be spent preparing by developing a robust strategy for decarbonising heat in buildings whilst testing and scaling up delivery models. The report calls for the next Government to prioritise these preparations in the same way that preparing for power sector decarbonisation has been the overriding focus of energy policy in the past decade. The Future Heat Series brings together politicians policy and academic experts and industry leaders. Together this coalition of key figures is taking stock of evidence progressing the policy debate in an open and constructive forum and building consensus for prioritising and transforming heat. Pathways for Heat is the first part of the Future Heat Series and presents six recommendations and over twenty findings.

Hydrogen has been identified as a fuel of choice for providing clean energy for transport and other applications across the world and the development of materials to store hydrogen efficiently and safely is crucial to this endeavour. Hydrogen has the largest scattering interaction with neutrons of all the elements in the periodic table making neutron scattering ideal for studying hydrogen storage materials. Simultaneous characterisation of the structure and dynamics of these materials during hydrogen uptake is straightforward using neutron scattering techniques. These studies will help us to understand the fundamental properties of hydrogen storage in realistic conditions and hence design new hydrogen storage materials.

This independent cross-party report highlights the key role that political consensus can play in helping to reduce the costs of nuclear power in the UK as well as other low carbon technologies. This political consensus has never been more important than in this ‘defining decade’ for the power sector. The report highlights that an immediate challenge facing the UK’s new build programme is agreeing with the European Commission a regime for supporting new nuclear power. Changing the proposed support package would not be an impossible task if made necessary but maintaining broad political consensus and considering the implications of delay are also important. The State Aid process is an important opportunity for scrutiny with the report demonstrating that shareholders for Hinkley Point C could see bigger returns (19-21%) than those typically expected for PFI projects (12-15%). However it is too early to conclude on the value for money of the Hinkley Point C agreement. Both the negotiation process and the resulting investment contract are important but there has been little transparency over either so far and the negotiations were not competitive. The inquiry calls for more urgency and better coordination in seizing the opportunity to reuse the UK’s plutonium stockpile.



The UK’s stockpile of separated plutonium presents opportunities to tackle a number of national strategic priorities including implementing long term solutions for nuclear waste developing new technologies that could redefine the sector laying the ground for new nuclear power and pursuing nuclear non-proliferation.  Government has identified three ‘credible solutions’ for reuse and the report recommends that it now sets clearer criteria against which to assess options and identifies budgetary requirements to help expediate the process. The report also argues that Government should do more on new nuclear technologies that could redefine the sector – such as considering smaller reactors nuclear for industrial heat or hydrogen production and closed or thorium fuel cycles. The Government’s initial response to a review of nuclear R&D a year ago by the then Chief Scientific Advisor Sir John Beddington has been welcome and it needs to build on this. In particular the UK should capitalise upon its existing expertise and past experience to focus efforts where there is most strategic value. Nulcear waste. Having failed to date the Government must urgently revisit plans for finding a site to store nuclear waste underground for thousands of years. Implementing this is a crucial part of demonstrating that nuclear waste is a manageable challenge. Despite being rejected by Cumbria County Council the continuing strong support amongst communities in West Cumbria for hosting a site is a promising sign.



On affordability the report finds that it is not yet clear which electricity generation technologies will be cheapest in the 2020s and beyond. Coal and gas could get more expensive if fossil fuel and carbon prices rise whilst low carbon technologies could get cheaper as technology costs fall with more deployment. This is the main reason for adopting an ‘all of the above’ strategy including nuclear power until costs become clearer and there is broad consensus behind this general approach.  



On security of supply the inquiry says that deployment of nuclear power is likely to be influenced more by the economics of system balancing rather than technical system balancing challenges which can be met with greater deployment of existing balancing tools. The cost of maintaining system security is likely to mean that the UK maintains at least some baseload capacity such as nuclear power to limit system costs.



On sustainability the report finds that the environmental impacts of nuclear power are comparable to some generation technologies and favourable to others although the long lived nature of some radioactive nuclear waste and the dual use potential of nuclear technology for civil and military applications create unique sustainability challenges which the UK is a world leader in managing.



It is the final report of the Future Electricity Series an independent and cross party inquiry into the UK power sector sponsored by the Institution of Gas Engineers and Managers

We investigate the implications of conducting hydrogen-assisted fatigue crack growth experiments in a hydrogen gas environment (in-situ hydrogen charging) or in air (following exposure to hydrogen gas). The study is conducted on welded 42CrMo4 steel a primary candidate for the future hydrogen transport infrastructure allowing us to additionally gain insight into the differences in behavior between the base steel and the coarse grain heat affected zone. The results reveal significant differences between the two testing approaches and the two weld regions. The differences are particularly remarkable for the comparison of testing methodologies with fatigue crack growth rates being more than one order of magnitude higher over relevant loading regimes when the samples are tested in a hydrogen-containing environment relative to the pre-charged samples. Aided by finite element modelling and microscopy analysis these differences are discussed and rationalized. Independent of the testing approach the heat affected zone showed a higher susceptibility to hydrogen embrittlement. Similar microstructural behavior is observed for both testing approaches with the base metal exhibiting martensite lath decohesion while the heat affected zone experienced both martensite lath decohesion and intergranular fracture.

The report was formally launched on 2nd December in Parliament at a panel debate chaired by Lord Whitty and Oliver Colvile and featured representatives from Government and Industry. The report outlines the case for investment by businesses in the energy efficiency of their buildings and operations and highlights how this could help neutralise the threat to profitability posed by increasing energy bills energy price volatility and an increasing reliance on electricity in the commercial sector. The report highlights that business in the UK have the opportunity to not only reduce energy bills but increase their competitiveness and improve worker productivity through better designed buildings.

Policy for Heat: Transforming the System urges Government to implement an ambitious long-term decarbonisation strategy for the heat sector before it’s too late in new inquiry report. The report builds on the work of Part 1 in the Future Heat Series which compared recent decarbonisation pathways and analyses to identify and highlight key policy mechanisms and transitions that are needed in order to decarbonise heat for buildings by 2050. Chaired by Shadow Energy Minister Jonathan Reynolds MP and Conservative MP Rebecca Pow (and also previous MP and member of the Energy and Climate Change Select Committee Dan Byles MP until he stood down at the General Election) the report is written by cross-party think tank group Carbon Connect. The report was published in Parliament at a cross-party debate on Wednesday 14th October. Sponsored by Energy & Utilities Alliance (EUA) and the Institution of Gas Engineers and Managers (IGEM) the report is the second in a cross-party and independent inquiry series.  

A common sustainability issue arising in production systems is the efficient use of resources for providing goods or services. With the increased interest in a hydrogen (H2) economy the life-cycle environmental performance of H2 production has special significance for assisting in identifying opportunities to improve environmental performance and to guide challenging decisions and select between technology paths. Life cycle impact assessment methods are rapidly evolving to analyze multiple environmental impacts of the production of products or processes. This study marks the first step in developing process-based streamlined life cycle analysis (LCA) of several H2 production pathways combining life cycle impacts at the midpoint (17 problem-oriented) and endpoint (3 damage-oriented) levels using the state-of-the-art impact assessment method ReCiPe 2016. Steam reforming of natural gas coal gasification water electrolysis via proton exchange membrane fuel cell (PEM) solid oxide electrolyzer cell (SOEC) biomass gasification and reforming and dark fermentation of lignocellulosic biomass were analyzed. An innovative aspect is developed in this study is an analysis of water consumption associated with H2 production pathways by life-cycle stage to provide a better understanding of the life cycle water-related impacts on human health and natural environment. For water-related scope Water scarcity footprint (WSF) quantified using Available Water Remaining (AWARE) method was applied as a stand-alone indicator. The paper discusses the strengths and weaknesses of each production pathway identify the drivers of environmental impact quantify midpoint environmental impact and its influence on the endpoint environmental performance. The findings of this study could serve as a useful theoretical reference and practical basis to decision-makers of potential environmental impacts of H2 production systems.

To achieve the Net-Zero Emissions goal by 2050 a major upscale in green hydrogen needs to be achieved; this will also facilitate use of renewable electricity as a source of decarbonised fuel in hard-to-abate sectors such as industry and transport. Nearly 80% of the world’s offshore wind resource is in waters deeper than 60 m where bottom-fixed wind turbines are not feasible. This creates a significant opportunity to couple the high capacity factor floating offshore wind and green hydrogen. In this paper we consider dedicated large-scale floating offshore wind farms for hydrogen production with three coupling typologies; (i) centralised onshore electrolysis (ii) decentralised offshore electrolysis and (iii) centralised offshore electrolysis. The typology design is based on variables including for: electrolyser technology; floating wind platform; and energy transmission vector (electrical power or offshore hydrogen pipelines). Offshore hydrogen pipelines are assessed as economical for large and distant farms. The decentralised offshore typology employing a semi-submersible platform could accommodate a proton exchange membrane electrolyser on deck; this would negate the need for an additional separate structure or hydrogen export compression and enhance dynamic operational ability. It is flexible; if one electrolyser (or turbine) fails hydrogen production can easily continue on the other turbines. It also facilities flexibility in further expansion as it is very much a modular system. Alternatively less complexity is associated with the centralised offshore typology which may employ the electrolysis facility on a separate offshore platform and be associated with a farm of spar-buoy platforms in significant water depth locations.

Hydrogen can be used to enable decarbonisation of challenging applications such as provision of heat and as a fuel for heavy transport. The UK has set out a strategy for developing a new low carbon hydrogen sector by 2030. Underground storage will be a key component of any regional or national hydrogen network because of the variability of both supply and demand across different end-use applications. For storage of pure hydrogen salt caverns currently remain the only commercially proven subsurface storage technology implemented at scale. A new network of hydrogen storage caverns will therefore be required to service a low carbon hydrogen network. To facilitate planning for such systems this study presents a modelling approach used to evaluate the UK's theoretical hydrogen storage capacity in new salt caverns in bedded rock salt. The findings suggest an upper bound potential for hydrogen storage exceeding 64 million tonnes providing 2150 TWh of storage capacity distributed in three discrete salt basins in the UK. The modelled cavern capacity has been interrogated to identify the practical inter-seasonal storage capacity suitable for integration in a hydrogen transmission system. Depending on cavern spacing a peak load deliverability of between 957 and 1876 GW is technically possible with over 70% of the potential found in the East Yorkshire and Humber region. The range of geologic uncertainty affecting the estimates is approximately ±36%. In principle the peak domestic heating demand of approximately 170 GW across the UK can be met using the hydrogen withdrawn from caverns alone albeit in practice the storage potential is unevenly distributed. The analysis indicates that the availability of salt cavern storage potential does not present a limiting constraint for the development of a low-carbon hydrogen network in the UK. The general framework presented in this paper can be applied to other regions to estimate region-specific hydrogen storage potential in salt caverns.

The HyDeploy project has undertaken a programme of work to assess the effect of hydrogen addition on the safety and performance of gas appliances and installations. A representative set of eight appliances have been assessed in laboratory experiments with a range of test gases that explored high and low Wobbe Index and hydrogen concentrations up to 28.4 % mol/mol. These tests have demonstrated that the addition of hydrogen does not affect the key hazard areas of CO production light back flame out or the operation of flame failure devices. It was identified that for some designs of gas fire appliances the operation of the oxygen depletion sensors may be affected by the addition of hydrogen. Testing of the gas fires that are present at Keele University that use oxygen depletion sensors have been shown to operate satisfactorily.<br/>A comprehensive onsite survey programme at Keele University has assessed 95% of the installations (126 of 133) that will receive the hydrogen blended gas during the HyDeploy trial. Where access to properties was not possible then the information obtained revealed that the appliances were annually checked either through British Gas service contracts or as a result of being rental properties. The onsite testing programme assessed installations for gas tightness and appliance combustion safety and operation with normal line gas G20 reference gas and two hydrogen blended gases. The checks identified a small number instances were remedial work was required to correct poor condition or operation. Only one case was found to be immediately dangerous which was capped off until repair work was undertaken. CO and smoke alarms were fitted in approximately half of properties and alarms were provided as required to the occupants. Gas tightness tests identified leaks in three installations. Where installations are gas tight then analysis has shown that no additional leaks would occur with hydrogen blended gas. There were no issues identified with the combustion performance of those appliances that were operating correctly and results were in line with those obtained in the laboratory testing programme.<br/>The findings of the Appliance and Installation testing program have been used to define the input values into the HyDeploy quantified risk assessment (QRA) where Keele University specific operation is different to GB as a whole or where the findings show the addition of hydrogen will change the risk profile.<br/>Click on supplements to see the other documents from this report

Liquid hydrogen may have an important role in the storage and transportation of hydrogen energy. It may also provide the best option for some users of hydrogen energy notably the aviation sector. In the 1960’s liquid hydrogen spillages in open uncongested conditions sometimes produced violent condensed phase explosions as well as the familiar gas phase flash and sustained pool fire. Testing showed that burning mixtures of LH2 and solid oxygen/nitrogen readily transitioned to detonation for oxygen concentrations in the solid phase at or above 50%. Such explosive events have been observed in more recent research work on LH2 spillage and the pressure effects could be significant in some accident scenarios. There is a need to understand how solids are produced following spillage and what factors determine the level of oxygen enrichment. This paper describes the physical processes involved in the accumulation of solids during a horizontal discharge at ground level based on observations made in a recent HSE test that led to a condensed phase explosion. Areas where solids accumulated but remained in intimate contact with LH2 are identified. The paper also includes a thermodynamic and fluid mechanical analysis of the condensation process that includes the calculation of densities of mixtures of LH2 and air in different proportions. When the difference in flow speed between air and underlying LH2 is low a stable condensation layer can develop above the liquid where the temperature is just under the initial condensation point of air allowing sustained oxygen enrichment of condensate.

Many energy system optimization studies show that hydrogen may be an important part of an optimal decarbonisation mix but such analyses are unable to examine the uncertainties associated with breaking the ‘locked-in’ nature of incumbent systems. Uncertainties around technical learning rates; consumer behaviour; and the strategic interactions of governments automakers and fuel providers are particularly acute. System dynamics and agent-based models and studies of historical alternative fuel transitions have furthered our understanding of possible transition dynamics but these types of analysis exclude broader systemic issues concerning energy system evolution (e.g. supplies and prices of low-carbon energy) and the politics of transitions. This paper presents a hybrid approach to assessing hydrogen transitions in the UK by linking qualitative scenarios with quantitative energy systems modelling using the UK MARKAL model. Three possible transition pathways are explored each exploring different uncertainties and possible decision points with modelling used to inform and test key elements of each scenario. The scenarios draw on literature review and participatory input and the scenario structure is based on archetypal transition dynamics drawn from historical energy system transitions reflecting insights relating to innovation system development and resistance to change. Conclusions are drawn about appropriate policy responses.

A consortiumcomprising Cadent Gas Health and Safety Executive – Science Division ITMPower Keele University Northern Gas Networks and Progressive Energy is undertaking the second phase of the research project HyDeploy. The project the first two phase ofwhich are funded under the UK Network Innovation Competition scheme aims to demonstrate that natural gas containing levels of hydrogen beyond the upper limit set out in Schedule 3 of in the Gas Safety (Management) Regulations (GSMR) can be distributed and utilised safely and efficiently in the UK gas distribution networks.<br/>The first phase of the HyDeploy project concludes with a 10-month field trial in which hydrogen will be injected into part of a private gas distribution system owned and operated by Keele University.<br/>The second phase of the HyDeploy project (HyDeploy2) continues on from the work of the first phase and is scheduled to conclude with two 12-month field trials in which hydrogen will be injected into public gas networks owned and operated by Northern Gas Networks and Cadent Gas.<br/>Dave Lander Consulting Limited is providing technical support to the HyDeploy project and this report presents the results of Quantified Risk Assessment (QRA) for the proposed field trial of hydrogen injection into part of a gas distribution system owned and operated by Northern Gas Networks (NGN) near the town of Winlaton in Gateshead Tyne and Wear. The QRA is intended to support an application by NGN for exemption from the legal requirement to only convey gas that is compliant with the requirements of Schedule 3 of the GSMR. The QRA estimates the risk to persons within the trial area affected by the proposed injection. A similar QRA1 was developed for the original HyDeploy field trial at Keele University.<br/>Click on the supplement tab to see the other documents from this report

In order to inform the Quantified Risk Assessment (QRA) and procedures for the Winlaton trial the HyDeploy 2 project has undertaken a second programme of work focused on assessing the safe operation of gas appliances with hydrogen blended gas. This work extends the initial programme of work undertaken in HyDeploy 1 in 2018. Collectively these two projects provide an evidence base to support the project objective to demonstrate that there are no overarching safety concerns for the addition of up to 20 % mol/mol hydrogen to the GB natural gas distribution network.<br/>Click on the supplements tab to view the other documents from this report

The heating sector makes up 10% of the United Kingdom’s carbon footprint and residential homes account for a majority of demand. At present central heating from a natural gas-fired boiler is the most common system in the UK but low or zero-carbon hydrogen and renewable electricity are the two primary energy replacement options to reduce the carbon footprint. An important consideration is how using either energy source would affect heating costs. This assessment projects the costs for a typical single-family UK household and climate performance in 2050 using low-GHG or GHG-neutral hydrogen renewable electricity or a combination of both. The cost of using boilers or fuel cells in 2050 with two types of hydrogen are assessed: produced via steam-methane reforming (SMR) combined with carbon capture and storage (CCS) and electrolysis using zero-carbon renewable electricity. The costs of heat pumps the most promising heating technology for the direct use of renewable electricity are also assessed in two scenarios: a heat pump only and a hybrid heat pump with an auxiliary hydrogen boiler.

You can download this document from the International Council On Clean Transportation website linked here

Initial assessment of Scotland’s opportunity to produce green hydrogen from offshore wind

Summary of Key Findings

• Scotland has an abundant offshore wind resource that has the potential to be a vital component in our net zero transition. If used to produce green hydrogen offshore wind can help abate the emissions of historically challenging sectors such as heating transport and industry.
• The production of green hydrogen from offshore wind can help overcome Scotland’s grid constraints and unlock a massive clean power generation resource creating a clean fuel for Scottish industry and households and a highly valuable commodity to supply rapidly growing UK and European markets.
• The primary export markets for Scottish green hydrogen are expected to be in Northern Europe (Germany Netherlands & Belgium). Strong competition to supply these markets is expected to come from green hydrogen produced from solar energy in Southern Europe and North Africa.
• Falling wind and electrolyser costs will enable green hydrogen production to be cost-competitive in the key transport and heat sectors by 2032. Strategic investment in hydrogen transportation and storage is essential to unlocking the economic opportunity for Scotland.
• Xodus’ analysis supports a long-term outlook of LCoH falling towards £2/kg with an estimated reference cost of £2.3 /kg in 2032 for hydrogen delivered to shore.
• Scotland has extensive port and pipeline infrastructure that can be repurposed for hydrogen export to the rest of UK and to Europe. Pipelines from the ‘90s are optimal for this purpose as they are likely to retain acceptable mechanical integrity and have a metallurgy better suited to hydrogen service. A more detailed assessment of export options should be performed to provide a firm foundation for early commercial green hydrogen projects.
• There is considerable hydrogen supply chain overlap with elements of parallel sectors most notably the oil and gas offshore wind and subsea engineering sectors. Scotland already has a mature hydrocarbon supply chain which is engaged in supporting green hydrogen. However a steady pipeline of early projects supported by a clear financeable route to market will be needed to secure this supply chain capability through to widescale commercial deployment.
• There are gaps in the Scottish supply chain in the areas of design manufacture and maintenance of hydrogen production storage and transportation systems. Support including apprenticeships will be needed to develop indigenous skills and capabilities in these areas.
• The development of green hydrogen from offshore wind has the potential to create high value jobs a significant proportion which are likely to be in remote rural/coastal communities located close to offshore wind resources. These can serve as an avenue for workers to redeploy and develop skills learned from oil and gas in line with Just Transition principles.

The high environmental impacts of transport mean that there is an increasing interest in utilising low-carbon alternative energy carriers and powertrains within the sector. While electricity has been mooted as the energy carrier of choice for passenger vehicles as the mass and range of the vehicle increases electrification becomes more difficult. This paper reviews the shipping aviation and haulage sectors and a range of low-carbon energy carriers (electricity biofuels hydrogen and electro fuels) that can be used to decarbonise them. Energy carriers were assessed based on their energy density specific energy cost lifecycle greenhouse gas emissions and land-use. In terms of haulage current battery electric vehicles may be technically feasible however the specific energy of current battery technology reduces the payload capacity and range when compared to diesel. To alleviate these issues biomethane represents a mature technology with potential co-benefits while hydrogen is close to competitiveness but requires significant infrastructure. Energy density issues preclude the use of batteries in shipping which requires energy dense liquids or compressed gaseous fuels that allow for retrofits/current hull designs with methanol being particularly appropriate here. Future shipping may be achieved with ammonia or hydrogen but hull design will need to be changed significantly. Regulations and aircraft design mean that commercial aviation is dependant on drop-in jet fuels for the foreseeable future with power-to-liquid fuels being deemed the most suitable option due to the scales required. Fuel costs and a lack of refuelling infrastructure were identified as key barriers facing the uptake of alternatives with policy and financial incentives required to encourage the uptake of low-carbon fuels.

Hydrogen technologies have experienced cycles of excessive expectations followed by disillusion. Nonetheless a growing body of evidence suggests these technologies form an attractive option for the deep decarbonisation of global energy systems and that recent improvements in their cost and performance point towards economic viability as well. This paper is a comprehensive review of the potential role that hydrogen could play in the provision of electricity heat industry transport and energy storage in a low-carbon energy system and an assessment of the status of hydrogen in being able to fulfil that potential. The picture that emerges is one of qualified promise: hydrogen is well established in certain niches such as forklift trucks while mainstream applications are now forthcoming. Hydrogen vehicles are available commercially in several countries and 225 000 fuel cell home heating systems have been sold. This represents a step change from the situation of only five years ago. This review shows that challenges around cost and performance remain and considerable improvements are still required for hydrogen to become truly competitive. But such competitiveness in the medium-term future no longer seems an unrealistic prospect which fully justifies the growing interest and policy support for these technologies around the world.

The Energy Technologies Institute (ETI) has developed an internationally peer-reviewed model of the UK’s national energy system extending across power heat transport and infrastructure. The Energy System Modelling Environment (ESME) is a policy neutral system-wide optimisation model. It models the key technology and engineering choices taking account of cost engineering spatial and temporal factors.

Key points:

• A system-wide perspective informed by modelling is highly relevant because complex energy systems are made more inter-dependent by emissions reduction objectives
• Efforts to cut emissions are substitutable across a national energy system encompassing power heat transport and infrastructure.
• Energy systems are subject to key decision points and it is important to make the right choices in major long lived investments
• Policy makers should place policy in a system-wide context.

The ETI’s current ESME-based analysis of the UK energy system shows that

• Decarbonisation can be achieved affordably (at around 0.6% of GDP) provided that the most cost effective technologies and strategies to reduce emissions are deployed
• A broad portfolio of technologies is needed to deliver emissions reductions with bio-energy and carbon capture and storage of particular system-wide importance

Policy makers can use energy system modelling to inform market and policy design increase understanding of pathways (including the impacts of ‘real world’ constraints and inertia in deploying technology) and identify key ‘contender’ technologies with particular system-wide value.

A model has been derived for the magnesium hydrogenation reaction at conditions close to equilibrium. The reaction mechanism involves an adsorption element where the model is an extension of the Langmuir adsorption model. The concept of site availability (σs) is introduced whereby it has the capability to reduce the reaction rate. To improve representation of σs an adaptable semi-empirical equation has been developed. Supplement to the surface reaction a rate equation has been derived considering resistance effects. It was found that close to equilibrium surface resistance dominated the reaction.

This paper presents the optimal design and operation of integrated wind-hydrogen-electricity networks using the general mixed integer linear programming energy network model STeMES (Samsatli and Samsatli 2015). The network comprises: wind turbines; electrolysers fuel cells compressors and expanders; pressurised vessels and underground storage for hydrogen storage; hydrogen pipelines and electricity overhead/underground transmission lines; and fuelling stations and distribution pipelines.<br/>The spatial distribution and temporal variability of energy demands and wind availability were considered in detail in the model. The suitable sites for wind turbines were identified using GIS by applying a total of 10 technical and environmental constraints (buffer distances from urban areas rivers roads airports woodland and so on) and used to determine the maximum number of new wind turbines that can be installed in each zone.<br/>The objective is the minimisation of the total cost of the network subject to satisfying all of the demands of the domestic transport sector in Great Britain. The model simultaneously determines the optimal number size and location of each technology whether to transmit the energy as electricity or hydrogen the structure of the transmission network the hourly operation of each technology and so on. The cost of distribution was estimated from the number of fuelling stations and length of the distribution pipelines which were determined from the demand density at the 1 km level.<br/>Results indicate that all of Britain's domestic transport demand can be met by on-shore wind through appropriately designed and operated hydrogen-electricity networks. Within the set of technologies considered the optimal solution is: to build a hydrogen pipeline network in the south of England and Wales; to supply the Midlands and Greater London with hydrogen from the pipeline network alone; to use Humbly Grove underground storage for seasonal storage and pressurised vessels at different locations for hourly balancing as well as seasonal storage; for Northern Wales Northern England and Scotland to be self-sufficient generating and storing all of the hydrogen locally. These results may change with the inclusion of more technologies such as electricity storage and electric vehicles.

Across Europe permitted blend levels of hydrogen blending into the gas grid are appreciably higher than that currently permitted in the UK up to 12% mol/mol compared with 0.1% mol/mol. Whilst there is some routine blending undertaking – typically power to gas applications three major projects have been undertaken to demonstrate operation of a gas distribution network at higher blend levels of hydrogen.<br/>A Dutch project was completed in 2011 which demonstrated successful operation into a network with new appliances at 20% mol/mol. A German project was completed in 2015 which demonstrated successful operation into an existing gas network with existing appliances at their permitted level of 10% mol/mol. In France an extensive programme is underway to inject hydrogen into a network at 20% mol/mol due to commence injection in 2018.<br/>Each of these projects undertook extensive pre-trial activities and operational data was collected during the Dutch and German trials. The programme of pre-trial work for the French project was particularly extensive and mirrored the work done by HyDeploy. This led to a permit being granted for the French project at 20% mol/mol with injection into the network imminent.<br/>The HyDeploy team has engaged with each of the project teams who have been very co-operative; this has enabled scientific sharing of best practice. In all cases the projects were successful. The participants in the Dutch project were particularly keen to have been able to undertake a similar trial to HyDeploy; a larger trial into existing appliances. However political changes in Holland have precluded that at this time such progress was not limited by technical findings from the work.<br/>A high level overview of the projects and the data provided is summarised in this report. More detailed information is referenced and covered in more detail where required in the appropriate individual topic reports supporting the Exemption.<br/>Click on supplements tab to view the other documents from this report

Hydrogen has been identified as a potential energy vector to decarbonise the transport and chemical sectors and achieve global greenhouse gas reduction targets. Despite ongoing efforts hydrogen technologies are often assessed focusing on their global warming potential while overlooking other impacts or at most including additional metrics that are not easily interpretable. Herein a wide range of alternative technologies have been assessed to determine the total cost of hydrogen production by coupling life-cycle assessments with an economic evaluation of the environmental externalities of production. By including monetised values of environmental impacts on human health ecosystem quality and resources on top of the levelised cost of hydrogen production an estimation of the “real” total cost of hydrogen was obtained to transparently rank the alternative technologies. The study herein covers steam methane reforming (SMR) coal and biomass gasification methane pyrolysis and electrolysis from renewable and nuclear technologies. Monetised externalities are found to represent a significant percentage of the total cost ultimately altering the standard ranking of technologies. SMR coupled with carbon capture and storage emerges as the cheapest option followed by methane pyrolysis and water electrolysis from wind and nuclear. The obtained results identify the “real” ranges for the cost of hydrogen compared to SMR (business as usual) by including environmental externalities thereby helping to pinpoint critical barriers for emerging and competing technologies to SMR.

Fuel cells as clean power sources are very attractive for the maritime sector which is committed to sustainability and reducing greenhouse gas and atmospheric pollutant emissions from ships. This paper presents a technological review on fuel cell power systems for maritime applications from the past two decades. The available fuels including hydrogen ammonia renewable methane and methanol for fuel cells under the context of sustainable maritime transportation and their pre-processing technologies are analyzed. Proton exchange membrane molten carbonate and solid oxide fuel cells are found to be the most promising options for maritime applications once energy efficiency power capacity and sensitivity to fuel impurities are considered. The types layouts and characteristics of fuel cell modules are summarized based on the existing applications in particular industrial or residential sectors. The various research and demonstration projects of fuel cell power systems in the maritime industry are reviewed and the challenges with regard to power capacity safety reliability durability operability and costs are analyzed. Currently power capacity costs and lifetime of the fuel cell stack are the primary barriers. Coupling with batteries modularization mass production and optimized operating and control strategies are all important pathways to improve the performance of fuel cell power systems.

Low-carbon hydrogen has the potential to play a significant role in tackling climate change and poor air quality. This policy briefing considers how hydrogen could be produced at a useful scale to power vehicles heat homes and supply industrial processes.

Four groups of hydrogen production technologies are examined:

Thermochemical Routes to Hydrogen

These methods typically use heat and fossil fuels. Steam methane reforming is the dominant commercial technology and currently produces hydrogen on a large scale but is not currently low carbon. Carbon capture is therefore essential with this process. Innovative technology developments may also help and research is underway. Alternative thermal methods of creating hydrogen indicate biomass gasification has potential. Other techniques at a low technology readiness level include separation of hydrogen from hydrocarbons using microwaves.

Electrolytic Routes to Hydrogen

Electrolytic hydrogen production also known as electrolysis splits water into hydrogen and oxygen using electricity in an electrolysis cell. Electrolysis produces pure hydrogen which is ideal for low temperature fuel cells for example in electric vehicles. Commercial electrolysers are on the market and have been in use for many years. Further technology developments will enable new generation electrolysers to be commercially competitive when used at scale with fluctuating renewable energy sources.

Biological Routes to Hydrogen

Biological routes usually involve the conversion of biomass to hydrogen and other valuable end products using microbial processes. Methods such as anaerobic digestion are feasible now at a laboratory and small pilot scale. This technology may prove to have additional or greater impact and value as route for the production of high value chemicals within a biorefinery concept.

Solar to Fuels Routes to Hydrogen

A number of experimental techniques have been reported the most developed of which is ‘solar to fuels’ - a suite of technologies that typically split water into hydrogen and oxygen using solar energy. These methods have close parallels with the process of photosynthesis and are often referred to as ‘artificial photosynthesis’ processes. The research is promising though views are divided on its ultimate utility. Competition for space will always limit the scale up of solar to fuels.

The briefing concludes that steam methane reforming and electrolysis are the most likely technologies to be deployed to produce low-carbon hydrogen at volume in the near to mid-term providing that the challenges of high levels of carbon capture (for steam methane reforming) and cost reduction and renewable energy sources (for electrolysis) can be overcome.

Hydrogen has potential applications across our future energy systems due particularly to its relatively high energy weight ratio and because it is emission-free at the point of use. Hydrogen is also abundant and versatile in the sense that it could be produced from a variety of primary energy sources and chemical substances including water and used to deliver power in a variety of applications including fuel cell combined heat and power technologies. As a chemical feedstock hydrogen has been used for several decades and such expertise could be fed back into the relatively new areas of utilising hydrogen to meet growing energy demands.<br/>The UK interest in hydrogen is also growing with various industrial academic and governmental organisations investigating how hydrogen could be part of a diverse portfolio of options for a low carbon future. While hydrogen as an alternative fuel is yet to command mass-appeal in the UK energy market IGEM believes hydrogen is capable of allowing us to use the wide range of primary energy sources at our disposal in a much greener and sustainable way.<br/>IGEM also sees hydrogen playing a small but key role in the gas industry whereby excess renewable energy is used to generate hydrogen which is then injected into the gas grid for widespread distribution and consumption. Various studies suggest admixtures containing up to 10 – 50%v/v hydrogen could be safely administered into the existing natural gas infrastructure. However IGEM understands that this would currently not be permissible under the Gas Safety (Management) Regulations (GS(M)R) for gas conveyance here in the UK. Also proper assessments of the risks associated with adding hydrogen to natural gas streams will need to be performed so that such systems can be managed effectively.<br/>IGEM has also identified a need for standards that cover the safety requirements of hydrogen technologies particularly those pertaining to installations in commercial or domestic environments. IGEM also recommend that the technical measures used to determine separation distances for hydrogen installations particularly refuelling stations are re-assessed through a systematic identification and control of potential sources of ignition.<br/>Hydrogen has the potential to be a significant fuel of the future and part of a diverse portfolio of energy options capable of meeting growing energy needs. This report therefore seeks to demonstrate how hydrogen could be a potential option for energy storage and power generation in a diverse energy system. It also aims to inform the readers on the current state of hydrogen here in the UK and abroad. This report has been assembled for IGEM members interested bodies and the general public.

In the framework of the EU-funded project HyTunnel-CS an inter-comparison among partners CFD simulations  has  been  carried  out.  The simulations  are  based  on  experiments  conducted   within  the project by Pro-Science and involve hydrogen release inside a safety vessel testing different ventilation configurations. The different ventilation configurations that were tested are co-flow counter-flow and cross-flow.  In the  current  study  co-flow  and  counter-flow  tests   along  with  the  no  ventilation  test (m'  = S g/s  d = 4 mm ) are simulated with the aim to validate available and well-known CFD codes against  such  applications  and  to  provide   recommendations  on  modeling  strategies. Special  focus  is given on modeling the velocity field produced by the fan during the experiments. The computational results are compared with the experimental results and a discussion follows regarding the efficiency of each ventilation configuration.

Introduction of hydrogen into the UK gas main has been reviewed in terms of how materials within the Keele G3 gas distribution network (G3 GDN) on the Keele University network may be affected by contact with natural gas (NG):hydrogen blends up to a limit of 20 % mol/mol hydrogen.<br/>This work has formed part of the supporting evidence for a 1 year hydrogen blending trial on the Keele G3 GDN coordinated by the HyDeploy consortium (formed of representatives of Cadent Northern Gas Networks ITM Power Progressive Energy HSL and Keele University).<br/>A wide range of materials were identified and assessed via a combination of literature review and practical test programmes. No significant changes to material properties in terms of accelerated material degradation or predicted efficiency of gas confinement were identified which would cause concern for the year-long trial at Keele.<br/>It can be concluded that materials on the Keele G3 GDN should be acceptable to provide a safe operating network the HyDeploy demonstrator project up to a level of 20 % mol/mol hydrogen.<br/>Check the supplements tab for the other documents in this report

There is no inherent property of hydrogen that makes it unsuitable for metering at distribution or transmission pressures. Towns gas containing large percentages of hydrogen was used for many years in the UK and continues to be in use in Hong Kong and Singapore. Many manufacturers sell their ordinary mechanical gas meters as suitable for hydrogen in a laboratory or industrial situation; unfortunately lack of demand has meant that none of these meters seem to have certified under appropriate metering regulations for gaseous hydrogen (e.g. the Measuring Instruments Directive)<br/>Some of the more sophisticated modern inferential meters (e.g. thermal or ultrasonic) currently designed specifically for natural gas (or LPG if suitably calibrated) are likely to unsuitable for repurposing directly to hydrogen but none of the problems appear fundamental or insuperable. The largest potential hurdle probably surrounds the physical size of current meters. A hydrogen appliance will consume about 3.3 more hydrogen than natural gas (on a volumetric basis) and using traditional designs this would have been measured through a meter probably too large to fit within an existing meter box. Unless unsolved such an increase in size would add materially to any hydrogen re-purposing programme.<br/>The meter trade thus need to be challenged to come up with a hydrogen meter that is the same physical size as a natural gas meter on a power rating basis (i.e. in kW). Ultrasonic and thermal mass meters should be included in the necessary Research and Development programme.<br/>A meter test programme is suggested that will provide evidence to meter manufacturers that the metering of hydrogen is not inherently difficult and thus convince them to make the necessary investments and/or approach the GDNO’s for assistance with such a programme.