- Home
- A-Z Publications
- Publications
Publications
The Trajectory of Hybrid and Hydrogen Technologies in North American Heavy Haul Operations
Jul 2021
Publication
The central aim of this paper is to provide an up-to-date snapshot of hybrid and hydrogen technology-related developments and activities in the North American heavy haul railway setting placed in the context of the transportation industry more broadly. An overview of relevant alternative propulsion technologies is provided including a discussion of applicability to the transportation sector in general and heavy haul freight rail specifically. This is followed by a discussion of current developments and research in alternative and blended fuels discussed again in both general and specific settings. Key factors and technical considerations for heavy haul applications are reviewed followed by a discussion of non-technical and human factors that motivate a move toward clean energy in North American Heavy Haul systems. Finally current project activities are described to provide a clear understanding of both the status and trajectory of hybrid and hydrogen technologies in the established context.
Estimation of Liquid Hydrogen Fuels in Aviation
Sep 2022
Publication
As the demand for alternative fuels to solve environmental problems increases worldwide due to the greenhouse gas problem this study predicted the demand for liquid hydrogen fuel in aviation to achieve ‘zero‐emission flight’. The liquid hydrogen fuel models of an aircraft and all aviation sectors were produced based on the prediction of aviation fleet growth through the classification of currently operated aircraft. Using these models the required amount of liquid hydrogen fuel and the total cost of liquid hydrogen were also calculated when various environmental regulations were satisfied. As a result it was found to be necessary to convert approximately 66% to 100% of all aircraft from existing aircraft to liquid hydrogen aircraft in 2050 according to regulations. The annual liquid hydrogen cost was 4.7–5.2 times higher in the beginning due to the high production cost but after 2030 it will be maintained at almost the same price and it was found that the cost was rather low compared to jet fuel.
CO2 Emissions of Battery Electric Vehicles and Hydrogen Fuel Cell Vehicles
Jun 2023
Publication
During the last few years electric and hydrogen vehicles have become an alternative to cars that use internal combustion engines. The number of electric and hydrogen vehicles sold has increased due to support from local governments and because car manufacturers will stop the production of internal combustion engines in the near future. The emissions of these vehicles while being driven are zero but they still have an impact on the environment due to their fuel. In this article an analysis of carbon dioxide (CO2 ) emissions for two types of vehicles: battery electric vehicles (BEVs) powered by electricity and fuel cell electric vehicles (FCEVs) powered by hydrogen is presented. The analysis considers different values for the mix of power generation and hydrogen production options in comparison to other studies. The CO2 emissions were calculated and compared for the two types of vehicles. The results show that the CO2 emissions of BEVs are lower when compared to FCEVs if the hydrogen is obtained from pollutant sources and is higher if the hydrogen is obtained from nuclear power and renewable energy sources. When compared to conventional combustion engine vehicles BEVs have lower CO2 emissions while the emissions of FCEVs are dependent on the hydrogen production method.
The Role of Hydrogen for Deep Decarbonization of Energy Systems: A Chilean Case Study
Mar 2023
Publication
In this paper we implement a long-term multi-sectoral energy planning model to evaluate the role of green hydrogen in the energy mix of Chile a country with a high renewable potential under stringent emission reduction objectives in 2050. Our results show that green hydrogen is a cost-effective and environmentally friendly route especially for hard-to-abate sectors such as interprovincial and freight transport. They also suggest a strong synergy of hydrogen with electricity generation from renewable sources. Our numerical simulations show that Chile should (i) start immediately to develop hydrogen production through electrolyzers all along the country (ii) keep investing in wind and solar generation capacities ensuring a low cost hydrogen production and reinforce the power transmission grid to allow nodal hydrogen production (iii) foster the use of electric mobility for cars and local buses and of hydrogen for long-haul trucks and interprovincial buses and (iv) develop seasonal hydrogen storage and hydrogen cells to be exploited for electricity supply especially for the most stringent emission reduction objectives.
Ammonia Decomposition in the Process Chain for a Renewable Hydrogen Supply
Jun 2022
Publication
This review article deals with the challenge to identify catalyst materials from literature studies for the ammonia decomposition reaction with potential for application in large-scale industrial processes. On the one hand the requirements on the catalyst are quite demanding. Of central importance are the conditions for the primary reaction that have to be met by the catalyst. Likewise the catalytic performance i.e. an ideally quantitative conversion and a high lifetime are critical as well as the consideration of requirements on the product properties in terms of pressure or by-products for potential follow-up processes in this case synthesis gas applications. On the other hand the evaluation of the multitude of literature studies poses difficulties due to significant varieties in catalytic testing protocols.
Hydrogen Leakage Simulation and Risk Analysis of Hydrogen Fueling Station in China
Sep 2022
Publication
Hydrogen is a renewable energy source with various features clean carbon-free high energy density which is being recognized internationally as a “future energy.” The US the EU Japan South Korea China and other countries or regions are gradually clarifying the development position of hydrogen. The rapid development of the hydrogen energy industry requires more hydrogenation infrastructure to meet the hydrogenation need of hydrogen fuel cell vehicles. Nevertheless due to the frequent occurrence of hydrogen infrastructure accidents their safety has become an obstacle to large-scale construction. This paper analyzed five sizes (diameters of 0.068 mm 0.215 mm 0.68 mm 2.15 mm and 6.8 mm) of hydrogen leakage in the hydrogen fueling station using Quantitative Risk Assessment (QRA) and HyRAM software. The results show that unignited leaks occur most frequently; leaks caused by flanges valves instruments compressors and filters occur more frequently; and the risk indicator of thermal radiation accident and structure collapse accident caused by over-pressure exceeds the Chinese individual acceptable risk standard and the risk indicator of a thermal radiation accident and head impact accident caused by overpressure is below the Chinese standard. On the other hand we simulated the consequences of hydrogen leak from the 45 MPa hydrogen storage vessels by the physic module of HyRAM and obtained the ranges of plume dispersion jet fire radiative heat flux and unconfined overpressure. We suggest targeted preventive measures and safety distance to provide references for hydrogen fueling stations’ safe construction and operation.
Hydrogen or Electric Drive—Inconvenient (Omitted) Aspects
May 2023
Publication
Currently hydrogen and electric drives used in various means of transport is a leading topic in many respects. This article discusses the most important aspects of the operation of vehicles with electric drives (passenger cars) and hydrogen drives. In both cases the official reason for using both drives is the possibility of independence from fossil fuel supplies especially oil. The desire for independence is mainly dictated by political considerations. This article discusses the acquisition of basic raw materials for the construction of lithium-ion batteries in electric cars as well as methods for obtaining hydrogen as a fuel. The widespread use of electric passenger cars requires the construction of a network of charging stations. This article shows that taking into account the entire production process of electric cars including lithium-ion batteries the argument that they are ecological cannot be used. Additionally it was indicated that there is no concept for the use of used accumulator batteries. If hydrogen drives are used in trains there is no need to build the traction network infrastructure and then continuously monitor its technical condition and perform the necessary repairs. Of course the necessary hydrogen tanks must be built but there must be similar tanks to store oil for diesel locomotives. This paper also deals with other possibilities of hydrogen application for transformational usage e.g. the use of combustion engines driven with liquid hydrogen. Unfortunately an optimistic approach to this issue does not allow for a critical view of the whole matter. In public discussion there is no room for scientific arguments and emotions to dominate.
Can Africa Serve Europe with Hydrogen Energy from Its Renewables?—Assessing the Economics of Shipping Hydrogen and Hydrogen Carriers to Europe from Different Parts of the Continent
Apr 2023
Publication
There exists no single optimal way for transporting hydrogen and other hydrogen carriers from one port to the other globally. Its delivery depends on several factors such as the quantity distance economics and the availability of the required infrastructure for its transportation. Europe has a strategy to invest in the production of green hydrogen in Africa to meet its needs. This study assessed the economic viability of shipping liquefied hydrogen (LH2 ) and hydrogen carriers to Germany from six African countries that have been identified as countries with great potential in the production of hydrogen. The results obtained suggest that the shipping of LH2 to Europe (Germany) will cost between 0.47 and 1.55 USD/kg H2 depending on the distance of travel for the ship. Similarly the transportation of hydrogen carriers could range from 0.19 to 0.55 USD/kg H2 for ammonia 0.25 to 0.77 USD/kg H2 for LNG 0.24 to 0.73 USD/kg H2 for methanol and 0.43 to 1.28 USD/kg H2 for liquid organic hydrogen carriers (LOHCs). Ammonia was found to be the ideal hydrogen carrier since it recorded the least transportation cost. A sensitivity analysis conducted indicates that an increase in the economic life by 5 years could averagely decrease the cost of LNG by some 13.9% NH3 by 13.2% methanol by 7.9% LOHC by 8.03% and LH2 by 12.41% under a constant distance of 6470 nautical miles. The study concludes with a suggestion that if both foreign and local participation in the development of the hydrogen market is increased in Africa the continent could supply LH2 and other hydrogen carriers to Europe at a cheaper price using clean fuel.
Life Cycle Assessment of Carbon Footprint in Public Transportation - A Case Study of Bus Route NO. 2 in Tainan City, Taiwan
Apr 2019
Publication
Human activities have exacerbated global greenhouse effects resulting in extreme climate changes that have caused disasters and food and water shortages in recent years. Transport activities are the one of the main causes of global greenhouse gas (GHG) emissions. Therefore policy makers must develop some strategies to reduce GHG emissions. One of the Taiwan’s transportation policies intended to reduce CO2 emissions is to replace all traditional diesel fuel urban buses with alternative energy buses. This paper uses a case study of bus route NO. 2 in Tainan City and follows the international standard ISO/TS 14067 and PAS2050 to measure the carbon footprints of different energy buses. The purpose is to measure the environmental benefits of alternative energy buses. The results of the bus carbon footprints from high to low were LNG buses 63.14g CO2e/pkm; traditional diesel buses 54.6g CO2e/pkm; liquefied petroleum gas buses 47.4g CO2e/pkm; plug-in electric buses 37.82g CO2e/pkm and hydrogen fuel cell bus es 29.17g CO2e/pkm respectively. It was also found that the use of hydrogen fuel cell buses would potentially reduce CO2e emissions in Tainan City by 1244081 tons which at this time is only city bus No. 2. If all the Taiwan city buses were switched to hydrogen fuel cell buses this would potentially reduce CO2e by 227832.39 tons. The effect of the reduction in carbon emissions from the use of hydrogen fuel cells buses in all Taiwanese urban areas is the equivalent of planting 22.78 million trees. It is thus suggested that the government use hydrogen fuel cell buses as the future of the country’s major alternative energy buses since they are the most environmentally friendly alternative to reducing CO2 emissions.
Identifying Informed Beliefs about Hydrogen Technologies Across the Energy Supply Chain
Apr 2023
Publication
Developing a thriving hydrogen industry will depend on public and community support. Past research mainly focusing on the acceptance of hydrogen fuelling stations and cars suggests that people generally support hydrogen energy technology (HET). Few studies have however considered how people think about other components of the hydrogen supply chain (i.e. technologies required to make store transport and use hydrogen). Moreover there has been limited research investigating how people interpret and develop beliefs about HET after being presented with technical information. This paper attempts to address these research gaps by presenting the findings from four face-to-face focus group discussions conducted in Australia. The findings suggest that people have differing views about HET which depends on the type of technology and these views influence levels of support. The study also revealed concerns about a range of other factors that have yet to be considered in hydrogen acceptance research (e.g. perceived water use efficiency and indirect benefits). The findings highlight the value of qualitative research for identifying salient beliefs that shape attitudes towards HET and provide recommendations for future research and how to effectively communicate with the public and communities about an emerging hydrogen industry.
Economic Assessment of Hydrogen Production in a Renewable Energy Community in Italy
Feb 2023
Publication
Renewable Energy Community (REC) is a new paradigm in European Union to produce transform share and sell renewables at a local consumer level also via e-fuel (i.e. hydrogen). This work investigates the economic feasibility of a hydrogen Power-to-Gas (PtG) system realized inside a REC using only excess renewable electricity not consumed by REC itself. A single centralized photovoltaic (PV) plant is directly connected to an electrolyser; a hydrogen compressor and two hydrogen storages at low and high pressure complete the PtG system. A scenario of a REC composed by 450 residential electric users (around 1000 people) has been analysed coupled with described PtG considering eight different sizes of PV plant. In the study Italian subsidies to REC shared energy are evaluated as incentives to hydrogen production. An optimal size of PtG components for each PV size is investigated at the limit of economical sustainability evaluating net present value (NPV) positive and near zero. Results show that for the considered REC it is possible to produce and sell up to around 3 tons per year of green hydrogen at most to the same lowest selling price declared currently in the Italian market (5 €/kg).
Review and Comparison of Worldwide Hydrogen Activities in the Rail Sector with Special Focus on On-board Storage and Refueling Technologies
Aug 2022
Publication
"This paper investigates hydrogen storage and refueling technologies that were used in rail vehicles over the past 20 years as well as planned activities as part of demonstration projects or feasibility studies. Presented are details of the currently available technology and its vehicle integration market availability as well as standardization and research and development activities. A total of 80 international studies corporate announcements as well as vehicle and refueling demonstration projects were evaluated with regard to storage and refueling technology pressure level hydrogen amount and installation concepts inside rolling stock. Furthermore current hydrogen storage systems of worldwide manufacturers were analyzed in terms of technical data.<br/>We found that large fleets of hydrogen-fueled passenger railcars are currently being commissioned or are about to enter service along with many more vehicles on order worldwide. 35 MPa compressed gaseous storage system technology currently dominates in implementation projects. In terms of hydrogen storage requirements for railcars sufficient energy content and range are not a major barrier at present (assuming enough installation space is available). For this reason also hydrogen refueling stations required for 35 MPa vehicle operation are currently being set up worldwide.<br/>A wide variety of hydrogen demonstration and retrofit projects are currently underway for freight locomotive applications around the world in addition to completed and ongoing feasibility studies. Up to now no prevailing hydrogen storage technology emerged especially because line-haul locomotives are required to carry significantly more energy than passenger trains. The 35 MPa compressed storage systems commonly used in passenger trains offer too little energy density for mainline locomotive operation - alternative storage technologies are not yet established. Energy tender solutions could be an option to increase hydrogen storage capacity here."
Energy-Economic Assessment of Islanded Microgrid with Wind Turbine, Photovoltaic Field, Wood Gasifier, Battery, and Hydrogen Energy Storage
Sep 2022
Publication
Island energy systems are becoming an important part of energy transformation due to the growing needs for the penetration of renewable energy. Among the possible systems a combination of different energy generation technologies is a viable option for local users as long as energy storage is implemented. The presented paper describes an energy-economic assessment of an island system with a photovoltaic field small wind turbine wood chip gasifier battery and hydrogen circuit with electrolyzer and fuel cell. The system is designed to satisfy the electrical energy demand of a tourist facility in two European localizations. The operation of the system is developed and dynamically simulated in the Transient System Simulation (TRNSYS) environment taking into account realistic user demand. The results show that in Gdansk Poland it is possible to satisfy 99% of user demand with renewable energy sources with excess energy equal to 31% while in Agkistro Greece a similar result is possible with 43% of excess energy. Despite the high initial costs it is possible to obtain Simple Pay Back periods of 12.5 and 22.5 years for Gdansk and Agkistro respectively. This result points out that under a high share of renewables in the energy demand of the user the profitability of the system is highly affected by the local cost of energy vectors. The achieved results show that the system is robust in providing energy to the users and that future development may lead to an operation based fully on renewables.
Efficiency, Economic and Environmental Impact Assessment of a Newly Developed Rail Engine using Hydrogen and Other Sustainable Fuel Blends
Jan 2023
Publication
Locomotives still use antiqued engines such as internal combustion engines operated by fossil fuels which cause global warming due to their significant emissions. This paper continues investigating the newly hybridized locomotive engine containing a gas turbine system solid oxide fuel cell system energy saving system and on-board hydrogen production system. This new engine is operated using five fuel blends composed of five alternative fuels such as hydrogen methane methanol ethanol and dimethyl ether. The current investigation involves exergy analysis exergo-economic analysis and exergo-environmental analysis to assess the engine from three perspectives: efficiency/irreversibility cost and environmental impact. The study results show that the net power of this new engine is 4948.6 kW and it has an exergetic efficiency of 62.7% according to the fuel and product principle. This engine weighs about 9 tons and costs about $10.2M with a levelized cost rate of 147 $/h and 14.06 mPt/h of overall component-related environmental rate. The average overall specific fuel and product exergy costs are about 37 $/GJ and 60 $/GJ and the minimum values are 13.3 $/GJ and 21.8 $/GJ using methane and hydrogen blend respectively. Also the average overall specific fuel and product exergo-environmental impact are about 15 and 23 mPt/MJ respectively. The on-board hydrogen production has an average exergy cost of 274 $/GJ and an environmental impact of 52 mPt/MJ. Hydrogen blended with methane or methanol is found to be more economic and has less environmental impact.
A Review of the Role of Hydrogen in the Heat Decarbonization of Future Energy Systems: Insights and Perspectives
Apr 2024
Publication
Hydrogen is an emerging technology changing the context of heating with cleaner combustion than traditional fossil fuels. Studies indicate the potential to repurpose the existing natural gas infrastructure offering consumers a sustainable economically viable option in the future. The integration of hydrogen in combined heat and power systems could provide residential energy demand and reduce environmental emissions. However the widespread adoption of hydrogen will face several challenges such as carbon dioxide emissions from the current production methods and the need for infrastructure modification for transport and safety. Researchers indicated the viability of hydrogen in decarbonizing heat while some studies also challenged its long-term role in the future of heating. In this paper a comprehensive literature review is carried out by identifying the following key aspects which could impact the conclusion on the overall role of hydrogen in heat decarbonization: (i) a holistic view of the energy system considering factors such as renewable integration and system balancing; (ii) consumer-oriented approaches often overlook the broader benefits of hydrogen in emission reduction and grid stability; (iii) carbon capture and storage scalability is a key factor for large-scale production of low-emission blue hydrogen; (iv) technological improvements could increase the cost-effectiveness of hydrogen; (v) the role of hydrogen in enhancing resilience especially during extreme weather conditions raises the potential of hydrogen as a flexible asset in the energy infrastructure for future energy supply; and finally when considering the UK as a basis case (vi) incorporating factors such as the extensive gas network and unique climate conditions necessitates specific strategies.
Prospects of Fuel Cell Combined Heat and Power Systems
Aug 2020
Publication
Combined heat and power (CHP) in a single and integrated device is concurrent or synchronized production of many sources of usable power typically electric as well as thermal. Integrating combined heat and power systems in today’s energy market will address energy scarcity global warming as well as energy-saving problems. This review highlights the system design for fuel cell CHP technologies. Key among the components discussed was the type of fuel cell stack capable of generating the maximum performance of the entire system. The type of fuel processor used was also noted to influence the systemic performance coupled with its longevity. Other components equally discussed was the power electronics. The thermal and water management was also noted to have an effect on the overall efficiency of the system. Carbon dioxide emission reduction reduction of electricity cost and grid independence were some notable advantages associated with fueling cell combined heat and power systems. Despite these merits the high initial capital cost is a key factor impeding its commercialization. It is therefore imperative that future research activities are geared towards the development of novel and cheap materials for the development of the fuel cell which will transcend into a total reduction of the entire system. Similarly robust systemic designs should equally be an active research direction. Other types of fuel aside hydrogen should equally be explored. Proper risk assessment strategies and documentation will similarly expand and accelerate the commercialization of this novel technology. Finally public sensitization of the technology will also make its acceptance and possible competition with existing forms of energy generation feasible. The work in summary showed that proton exchange membrane fuel cell (PEM fuel cell) operated at a lower temperature-oriented cogeneration has good efficiency and is very reliable. The critical issue pertaining to these systems has to do with the complication associated with water treatment. This implies that the balance of the plant would be significantly affected; likewise the purity of the gas is crucial in the performance of the system. An alternative to these systems is the PEM fuel cell systems operated at higher temperatures.
Green Steel: Synergies between the Australian Iron Ore Industry and the Production of Green Industry
May 2023
Publication
Green steel produced using renewable energy and hydrogen presents a promising avenue to decarbonize steel manufacturing and expand the hydrogen industry. Australia endowed with abundant renewable resources and iron ore deposits is ideally placed to support this global effort. This paper's two-step analytical approach offers the first comprehensive assessment of Australia's potential to develop green steel as a value-added export commodity. The Economic Fairways modelling reveals a strong alignment between prospective hydrogen hubs and current and future iron ore operations enabling shared infrastructure development and first-mover advantages. By employing a site-based system optimization that integrates both wind and solar power sources the cost of producing green steel could decrease significantly to around AU$900 per tonne by 2030 and AU$750 per tonne by 2050. Moreover replacing 1% of global steel production would require 35 GW of well-optimized wind and solar photovoltaics 11 GW of hydrogen electrolysers and 1000 square kilometres of land. Sensitivity analysis further indicates that iron ore prices would exert a long-term influence on green steel prices. Overall this study highlights the opportunities and challenges facing the Australian iron ore industry in contributing to the decarbonization of the global steel sector underscoring the crucial role of government support in driving the growth and development of the green steel industry.
Study on Hydrogen in Ports and Industrial Coastal Areas - Report 1
Jan 2023
Publication
The study feeds into the work of the Global Hydrogen Ports Coalition launched at the latest Clean Energy Ministerial (CEM12). This important international initiative brings together ports from around the world to work together on hydrogen technologies. The planned study will be a comprehensive assessment of the hydrogen demand in ports and industrial coastal areas enabling the creation of a 'European Hydrogen Ports Roadmap'. It will also feature clear economic forecasts based on a variety of business models for the transition to renewable hydrogen in ports while presenting new case studies and project concepts. “The objective is to provide new directions for research and innovation guidance for regulation codes and standards and proposals on policy and regulation. The forthcoming study will also help create impetus for stakeholders to come together and take a long term perspective on the hydrogen transition in ports. Finally the study will be a centralized resource It will form a Europe wide hydrogen ports ' when combined with roadmaps and other materials created by individual ports.
Assessment of the Co-combustion Process of Ammonia with Hydrogen in a Research VCR Piston Engine
Oct 2022
Publication
The presented work concerns experimental research of a spark-ignition engine with variable compression ratio (VCR) adapted to dual-fuel operation in which co-combustion of ammonia with hydrogen was conducted and the energy share of hydrogen varied from 0% to 70%. The research was aimed at assessing the impact of the energy share of hydrogen co-combusted with ammonia on the performance stability and emissions of an engine operating at a compression ratio of 8 (CR 8) and 10 (CR 10). The operation of the engine powered by ammonia alone for both CR 8 and CR 10 is associated with either a complete lack of ignition in a significant number of cycles or with significantly delayed ignition and the related low value of the maximum pressure pmax. Increasing the energy share of hydrogen in the fuel to 12% allows to completely eliminate the instability of the ignition process in the combustible mixture which is confirmed by a decrease in the IMEP uniqueness and a much lower pmax dispersion. For 12% of the energy share of hydrogen co-combusted with ammonia the most favorable course of the combustion process was obtained the highest engine efficiency and the highest IMEP value were recorded. The conducted research shows that increasing the H2 share causes an increase in NO emissions for both analyzed compression ratios
Optimized Design and Control of an Off Grid solar PV/hydrogen Fuel Cell Power System for Green Buildings
Sep 2017
Publication
Modelling simulation optimization and control strategies are used in this study to design a stand-alone solar PV/Fuel Cell/Battery/Generator hybrid power system to serve the electrical load of a commercial building. The main objective is to design an off grid energy system to meet the desired electric load of the commercial building with high renewable fraction low emissions and low cost of energy. The goal is to manage the energy consumption of the building reduce the associate cost and to switch from grid-tied fossil fuel power system to an off grid renewable and cleaner power system. Energy audit was performed in this study to determine the energy consumption of the building. Hourly simulations modelling and optimization were performed to determine the performance and cost of the hybrid power configurations using different control strategies. The results show that the hybrid off grid solar PV/Fuel Cell/Generator/Battery/Inverter power system offers the best performance for the tested system architectures. From the total energy generated from the off grid hybrid power system 73% is produced from the solar PV 24% from the fuel cell and 3% from the backup Diesel generator. The produced power is used to meet all the AC load of the building without power shortage (<0.1%). The hybrid power system produces 18.2% excess power that can be used to serve the thermal load of the building. The proposed hybrid power system is sustainable economically viable and environmentally friendly: High renewable fraction (66.1%) low levelized cost of energy (92 $/MWh) and low carbon dioxide emissions (24 kg CO2/MWh) are achieved.
Energy System Changes in 1.5 °C, Well Below 2 °C and 2 °C Scenarios
Dec 2018
Publication
Meeting the Paris Agreement's goal to limit global warming to well below 2 °C and pursuing efforts towards 1.5 °C is likely to require more rapid and fundamental energy system changes than the previously-agreed 2 °C target. Here we assess over 200 integrated assessment model scenarios which achieve 2 °C and well-below 2 °C targets drawn from the IPCC's fifth assessment report database combined with a set of 1.5 °C scenarios produced in recent years. We specifically assess differences in a range of near-term indicators describing CO2 emissions reductions pathways changes in primary energy and final energy across the economy's major sectors in addition to more detailed metrics around the use of carbon capture and storage (CCS) negative emissions low-carbon electricity and hydrogen.
Techno-Economic Evaluation of Hydrogen-Based Cooking Solutions in Remote African Communities—The Case of Kenya
Apr 2023
Publication
Hydrogen has recently been proposed as a versatile energy carrier to contribute to archiving universal access to clean cooking. In hard-to-reach rural settings decentralized produced hydrogen may be utilized (i) as a clean fuel via direct combustion in pure gaseous form or blended with Liquid Petroleum Gas (LPG) or (ii) via power-to-hydrogen-to-power (P2H2P) to serve electric cooking (e-cooking) appliances. Here we present the first techno-economic evaluation of hydrogen-based cooking solutions. We apply mathematical optimization via energy system modeling to assess the minimal cost configuration of each respective energy system on technical and economic measures under present and future parameters. We further compare the potential costs of cooking for the end user with the costs of cooking with traditional fuels. Today P2H2P-based e-cooking and production of hydrogen for utilization via combustion integrated into the electricity supply system have almost equal energy system costs to simultaneously satisfy the cooking and electricity needs of the isolated rural Kenyan village studied. P2H2P-based e-cooking might become advantageous in the near future when improving the energy efficiency of e-cooking appliances. The economic efficiency of producing hydrogen for utilization by end users via combustion benefits from integrating the water electrolysis into the electricity supply system. More efficient and cheaper hydrogen technologies expected by 2050 may improve the economic performance of integrated hydrogen production and utilization via combustion to be competitive with P2H2P-based e-cooking. The monthly costs of cooking per household may be lower than the traditional use of firewood and charcoal even today when applying the current life-line tariff for the electricity consumed or utilizing hydrogen via combustion. Driven by likely future technological improvements and the expected increase in traditional and fossil fuel prices any hydrogen-based cooking pathway may be cheaper for end users than using charcoal and firewood by 2030 and LPG by 2040. The results suggest that providing clean cooking in rural villages could economically and environmentally benefit from utilizing hydrogen. However facing the complexity of clean cooking projects we emphasize the importance of embedding the results of our techno-economic analysis in holistic energy delivery models. We propose useful starting points for future aspects to be investigated in the discussion section including business and financing models.
Electrofuels from Excess Renewable Electricity at High Variable Renewable Shares: Cost, Greenhouse Gas Abatement, Carbon Use and Competition
Nov 2020
Publication
Increasing shares of variable renewable electricity (VRE) generation are necessary for achieving high renewable shares in all energy sectors. This results in increased excess renewable electricity (ERE) at times when supply exceeds demand. ERE can be utilized as a low-emission energy source for sector coupling through hydrogen production via electrolysis which can be used directly or combined with a carbon source to produce electrofuels. Such fuels are crucial for the transport sector where renewable alternatives are scarce. However while ERE increases with raising VRE shares carbon emissions decrease and may become a limited resource with several usage options including carbon storage (CCS). Here we perform a model based analysis for the German case until 2050 with a general analysis for regions with a high VRE reliance. Results indicate that ERE-based electrofuels could achieve a greenhouse gas (GHG) abatement of 74 MtCO2eq yearly (46% of current German transport emissions) by displacing fossil fuels at high fuel-cell electric vehicle (FCEV) shares at a cost of 250–320 V per tCO2eq. The capital expenditure of electrolysers was found not to be crucial for the cost despite low capacity factors due to variable ERE patterns. Carbon will likely become a limiting factor when aiming for stringent climate targets and renewable electricity-based hydrocarbon electrofuels replacing fossil fuels achieve up to 70% more GHG abatement than CCS. Given (1) an unsaturated demand for renewable hydrocarbon fuels (2) a saturated renewable hydrogen demand and (3) unused ERE capacities which would otherwise be curtailed we find that carbon is better used for renewable fuel production than being stored in terms of overall GHG abatement.
Everything About Hydrogen Podcast: Producing Hydrogen with Wind Energy
Sep 2022
Publication
On this episode of Everything About Hydrogen we are speaking with David Wellard Regulatory Affairs Manager at Orsted. Orsted is a global leader in renewable energy generation projects particularly when it comes to the rapidly expanding wind energy sector. Headquartered in Denmark the company has a global reach across multiple continents and technologies. David helps lead Orsted’s policy and regulatory engagement in the United Kingdom and beyond. We are excited to have him with us to discuss how Orsted is looking at and deploying hydrogen technologies and how they expect to utilized hydrogen in a decarbonized energy future.
The podcast can be found on their website.
The podcast can be found on their website.
Power Balance Control and Dimensioning of a Hybrid Off-grid Energy system for a Nordic Climate Townhouse
Mar 2023
Publication
This paper investigates conversion of a Nordic oil-heated townhouse into carbon-neutral by different energy efficiency (EE) improvements and an off-grid system including solar photovoltaics (PV) wind power and battery and hydrogen energy storage systems (BESS and HESS). A heat-pump-based heating system including waste heat recovery (WHR) from the HESS and an off-grid electrical system are dimensioned for the building by applying models developed in MATLAB and Microsoft Excel to study the life cycle costs (LCC). The work uses a measured electrical load profile and the heat generation of the new heating system and the power generation are simulated by commercial software. It is shown that the EE improvements and WHR from the HESS have a positive effect on the dimensioning of the off-grid system and the LCC can be reduced by up to €2 million. With the EE improvements and WHR the component dimensioning can be reduced by 22%–41% and 13%–51% on average respectively. WHR can cover up to 57% of the building's annual heat demand and full-power dimensioning of the heat pump is not reasonable when WHR is applied. Wind power was found to be very relevant in the Nordic conditions reducing the LCC by 32%.
Configuration Optimization of Hydrogen-Based Multi-Microgrid Systems under Electricity Market Trading and Different Hydrogen Production Strategies
Apr 2023
Publication
Hydrogen-based multi-microgrid systems (HBMMSs) are beneficial for energy saving and emission reductions. However the optimal sizing of HBMMSs lacks a practical configuration optimization model and a reasonable solution method. To address these problems we designed a novel structure of HBMMSs that combines conventional energy renewable energy and a hydrogen energy subsystem. Then we established a bi-level multi-objective capacity optimization model while considering electricity market trading and different hydrogen production strategies. The objective of the inner model which is the minimum annual operation cost and the three objectives of the outer model which are the minimum total annual cost (TAC); the annual carbon emission (ACE); and the maximum self-sufficiency rate (SSR) are researched simultaneously. To solve the above optimization model a two-stage solution method which considers the conflicts between objectives and the objectivity of objective weights is proposed. Finally a case study is performed. The results show that when green hydrogen production strategies are adopted the three objectives of the best configuration optimization scheme are USD 404.987 million 1.106 million tons and 0.486 respectively.
The Potential Role of Flying Vehicles in Progressing the Energy Transition
Oct 2022
Publication
An energy transition is in progress around the globe notably led by an increase in the deployment of renewable energy and a shift toward less emissions-intense options notably in the transportation sector. This research investigates the potential role that new transportation options namely flying vehicles may play toward progressing the energy transition. As flying vehicles are a relatively new technology yet to penetrate the market it is also prudent to consider the ethical legal and social issues (ELSI) associated with their implementation alongside the potential energy and environmental impacts. Through a review of ELSI and energy and environmental literature we identify research gaps and identify how flying vehicles may impact upon the energy transition over time. Our research identifies several critical aspects of both ELSI and energy and environmental academia relevant to the future deployment of flying vehicles and describes a deployment timeline and the resultant societal outcomes. We find that flying vehicles could drive the energy transition and the hydrogen economy and that their widespread adoption could engender shared socio-environmental benefits. Our findings are relevant to transportation and environmental policymakers and identify critical considerations for the planned introduction of new shared transportation options to the market conducive to a sustainable energy transition.
Development and Testing of a 100 kW Fuel-flexible Micro Gas Turbine Running on 100% Hydrogen
Jun 2023
Publication
Hydrogen as a carbon-free energy carrier has emerged as a crucial component in the decarbonization of the energy system serving as both an energy storage option and fuel for dispatchable power generation to mitigate the intermittent nature of renewable energy sources. However the unique physical and combustion characteristics of hydrogen which differ from conventional gaseous fuels such as biogas and natural gas present new challenges that must be addressed. To fully integrate hydrogen as an energy carrier in the energy system the development of low-emission and highly reliable technologies capable of handling hydrogen combustion is imperative. This study presents a ground-breaking achievement - the first successful test of a micro gas turbine running on 100% hydrogen with NOx emissions below the standard limits. Furthermore the combustor of the micro gas turbine demonstrates exceptional fuel flexibility allowing for the use of various blends of hydrogen biogas and natural gas covering a wide range of heating values. In addition to a comprehensive presentation of the test rig and its instrumentation this paper illuminates the challenges of hydrogen combustion and offers real-world operational data from engine operation with 100% hydrogen and its blends with methane.
Hydrogen Combustion, Production, and Applications: A Review
May 2024
Publication
The demand for fossil fuels is rising rapidly leading to increased greenhouse gas emissions. Hydrogen has emerged as a promising clean energy alternative that could help meet future demands way sustainably especially if produced using renewable methods. For hydrogen to meaningfully contribute to energy transitions it needs more integration into sectors like transportation buildings and power that currently have minimal hydrogen usage. This requires developing extensive cross-sector hydrogen infrastructure. This review examines hydrogen combustion as a fuel by exploring and comparing production techniques enriching ammonia with hydrogen as a CO2-free option and hydrogen applications in engines. Additionally a techno-economic environmental risk analysis is discussed. Results showed steam methane reforming is the most established and cost-effective production method at $1.3–1.5/kg H2 and 70–85% efficiency but generates CO2. Biomass gasification costs $1.25–2.20/kg H2 and pyrolysis $1.77–2.05/kg H2 offering renewable options. However bio-photolysis currently has high costs of $1.42–2.13/kg H2 due to low conversion rates requiring large reactors. Blending H2/NH3 could enable carbon-free combustion aiding carbon neutrality pursuits but minimizing resultant NOx is crucial. Hydrogen’s wide uses from transportation to power underline its potential as a transformational energy carrier.
A Review of Hydrogen-based Hybrid Renewable Energy Systems: Simulation and Optimization with Artificial Intelligence
Nov 2021
Publication
With the massive use of traditional fossil fuels greenhouse gas emissions are increasing and environmental pollution is becoming an increasingly serious problem which led to an imminent energy transition. Therefore the development and application of renewable energy are particularly important. This paper reviews a wide range of issues associated with hybrid renewable energy systems (HRESs). The issues concerning system configurations energy storage options simulation and optimization with artificial intelligence are discussed in detail. Storage technology options are introduced for stand-alone (off-grid) and grid-connected (on-grid) HRESs. Different optimization methodologies including classical techniques intelligent techniques hybrid techniques and software tools for sizing system components are presented. Besides the artificial intelligence methods for optimizing the solar/wind HRESs are discussed in detail.
Minimizing Emissions from Grid-based Hydrogen Production in the United States
Jan 2023
Publication
Low-carbon hydrogen could be an important component of a net-zero carbon economy helping to mitigate emissions in a number of hard-to-abate sectors. The United States recently introduced an escalating production tax credit (PTC) to incentivize production of hydrogen meeting increasingly stringent embodied emissions thresholds. Hydrogen produced via electrolysis can qualify for the full subsidy under current federal accounting standards if the input electricity is generated by carbon-free resources but may fail to do so if emitting resources are present in the generation mix. While use of behind-the-meter carbon-free electricity inputs can guarantee compliance with this standard the PTC could also be structured to allow producers using grid-supplied electricity to qualify subject to certain clean energy procurement requirements. Herein we use electricity system capacity expansion modeling to quantitatively assess the impact of grid-connected electrolysis on the evolution of the power sector in the western United States through 2030 under multiple possible implementations of the clean hydrogen PTC. We find that subsidized grid-connected hydrogen production has the potential to induce additional emissions at effective rates worse than those of conventional fossil-based hydrogen production pathways. Emissions can be minimized by requiring grid-based hydrogen producers to match 100% of their electricity consumption on an hourly basis with physically deliverable ‘additional’ clean generation which ensures effective emissions rates equivalent to electrolysis exclusively supplied by behind-the-meter carbon-free generation. While these requirements cannot eliminate indirect emissions caused by competition for limited clean resources which we find to be a persistent result of large hydrogen production subsidies they consistently outperform alternative approaches relying on relaxed time matching or marginal emissions accounting. Added hydrogen production costs from enforcing an hourly matching requirement rather than no requirements are less than $1 kg−1 and can be near zero if clean firm electricity resources are available for procurement.
Green Hydrogen Futures: Tensions of Energy and Justice Within Sociotechnical Imaginaries
May 2024
Publication
As a reformist approach to low-carbon transitions green hydrogen is often promoted as an easy replacement for fossil fuels. This substitution narrative makes this technology compelling as it offers to reduce emissions while continuing the contemporary energy system. Using ‘sociotechnical imaginaries’ this paper explores the underlying political processes on what appears to be a mostly technical vision of green hydrogen. Analysis through expert interviews in Aotearoa New Zealand revealed two contrasting energy visions one emphasizing the technical role of green hydrogen in New Zealand's transition—the green hydrogen imaginary and the other which advocated for a future motivated by social change—the alternative energy imaginary. Comparing the tensions through a lens of hydrogen justice exposed the assumptions and exclusions present in the emerging green hydrogen imaginary. This paper argues that the technocratic business as usual approach of green hydrogen depoliticizes the social nature of energy and thus risks perpetuating inequalities and harms present in the current energy system. However these critiques also suggest that there is hope for green hydrogen to be reimagined in more ethical and just ways.
A Study on the Viability of Fuel Cells as an Alternative to Diesel Fuel Generators on Ships
Jul 2023
Publication
This study investigates methods for reducing air pollution in the shipping sector particularly in port areas. The study examines the use of fuel cells as an alternative to diesel generators. Environmental pollution at ports remains a critical issue so using fuel cells as an alternative to conventional energy systems warrants further research. This study compares commercial fuel cell types that can be used on a case study very large crude carrier (VLCC) vessel specifically although the technology is applicable to other vessels and requirements. Seven different fuel cell types were ranked based on five criteria to accomplish this. The proton-exchange membrane cell type was found to be the most suitable fuel cell type for the case study vessel. Based on the input fuel ammonia-based hydrogen storage has been identified as the most promising option along with using an ammonia reforming unit to produce pure hydrogen. Furthermore this study provides an integrated fuel cell module and highlights the economic environmental and maintenance aspects of implementing the proton-exchange membrane fuel cell module for this case study. It also calculates the required space as a crucial constraint of implementing fuel cell technology at sea.
Potential Economic Benefits of Carbon Dioxide (CO2) Reduction Due to Renewable Energy and Electrolytic Hydrogen Fuel Deployment Under Current and Long Term Forecasting of the Social Carbon Cost (SCC)
May 2019
Publication
The 2016 Paris Agreement (UNFCCC Authors 2015) is the latest of initiative to create an international consensus on action to reduce GHG emissions. However the challenge of meeting its targets lies mainly in the intimate relationship between GHG emissions and energy production which in turn links to industry and economic growth. The Middle East and North African region (MENA) particularly those nations rich oil and gas (O&G) resources depend on these as a main income source. Persuading the region to cut down on O&G production or reduce its GHG emissions is hugely challenging as it is so vital to its economic strength. In this paper an alternative option is established by creating an economic link between GHG emissions measured as their CO2 equivalent (CO2e) and the earning of profits through the concept of Social Carbon Cost (SCC). The case study is a small coastal city in Libya where 6% of electricity is assumed to be generated from renewable sources. At times when renewable energy (RE) output exceeds the demand for power the surplus is used for powering the production of hydrogen by electrolysis thus storing the energy and creating an emission-free fuel. Two scenarios are tested based on short and long term SCCs. In the short term scenario the amount of fossil fuel energy saved matches the renewable energy produced which equates to the same amount of curtailed O&G production. The O&G-producing region can earn profits in two ways: (1) by cutting down CO2 emissions as a result of a reduction in O&G production and (2) by replacing an amount of fossil fuel with electrolytically-produced hydrogen which creates no CO2 emissions. In the short term scenario the value of SCC saved is nearly 39% and in the long term scenario this rose to 83%.
Technology Transfer from Fuel Processing for Fuel Cells to Fuel Synthesis from Hydrogen and Carbon Dioxide
Aug 2023
Publication
Improving the energy efficiency of existing technologies such as the on-board power supply of trucks ships and aircraft is an important endeavor for reducing primary energy consumption. The approach consists of using fuel cell technology in conjunction with hydrogen production from liquid fuels. However the energy transition with the goal of complete climate-neutrality requires technological changes in the use of hydrogen produced from renewable energy via electrolysis. Synthetic fuels are an important building block for drive systems that will continue to require liquid energy carriers in the future due to their range. This study addresses the question of whether technical devices that were developed for the generation of hydrogen from liquid fuels for fuel cells to generate electricity are now suitable for the reverse process chain or can play an important role in it. The new process chain produces hydrogen from sustainable electricity combining it with carbon dioxide to create a synthetic liquid fuel.
Renewable Hydrogen: Modular Concepts from Production over Storage to the Consumer
Jan 2021
Publication
A simulation tool called HYDRA to optimize individual hydrogen infrastructure layouts is presented. The different electrolyzer technologies namely proton exchange membrane electrolysis anion exchange membrane electrolysis alkaline electrolysis and solid oxide electrolysis as well as hydrogen storage possibilities are described in more detail and evaluated. To illustrate the application opportunities of HYDRA three project examples are discussed. The examples include central and decentral applications while taking the usage of hydrogen into account.
Necessary and Sufficient Conditions for Deploying Hydrogen Homes: A Consumer-oriented Perspective
May 2024
Publication
As part of its efforts to secure a ‘net-zero society’ the UK government will take a strategic decision on the role of hydrogen in decarbonising homes within the next years. While scholars have recently advanced the social science research agenda on hydrogen technology acceptance studies are yet to engage with the prospective dynamics of adopting ‘hydrogen homes’. In response this study examines the perceived adoption potential of hydrogen heating and cooking technologies as evaluated through the eyes of consumer. Engaging with behavioural and market acceptance this research draws on data from a broadly nationally representative online survey to examine the influence of safety technological economic environmental and emotional factors on the domestic hydrogen transition in the UK context. The analysis follows a multi-stage empirical approach integrating findings from partial least squares structural equation and necessary condition analysis to crystallise insights on this emergent subject. At this juncture perceived adoption potential may hinge primarily on emotional environmental safety and to a lesser extent technological perspectives. However consumers have an expressed preference for hydrogen heating over hydrogen cooking with perceived boiler performance emerging as a necessary condition for enabling adoption potential. At the formative phase of the transition risks associated with energy insecurity and fuel poverty exceed concerns over purchasing and running costs. Nevertheless economic factors remain less critical during the pre-deployment phase of the innovation-decision process. Across the full sample simple slope analysis highlights the moderating effects of gender age and housing tenure. Moreover statistically significant differences from both a sufficiency- and necessity-based perspective are detected between male property owners aged 55+ and female mortgage owners 18–34 years old. By bridging the knowledge gap between social acceptance and adoption intention this contribution reinforces the need for consumer engagement in the hydrogen economy advocating for more fine-grained mixed-methods analyses of technology acceptance dynamics to support decarbonisation strategies.
Evaluating Hydrogen-based Electricity Generation using the Concept of Total Efficiency
Aug 2023
Publication
The popularity of hydrogen has been increasing globally as a promising sustainable energy source. However hydrogen needs to be produced and processed before it can be used in the energy sector. This paper uses total efficiency to evaluate the lifecycle of hydrogen-driven power generation. Total efficiency introduces the energy requirement of fuel preparation in conventional efficiency and is a reliable method to fairly compare different energy sources. Two case studies in Spain and Germany with nine scenarios each are defined to study different hydrogen-preparation routes. The scenarios include the main colors of hydrogen production (grey turquoise yellow and green) and different combinations of processing and transportation choices. In most cases the highest energy penalty in the overall preparation process of the fuel is linked to the production step. A large difference is found between fossil fuel-based hydrogen and green hydrogen derived from excess renewable energy with fossil fuel-based hydrogen resulting in significantly lower total efficiencies compared to green hydrogen. The use of natural gas as the primary source to generate hydrogen is found to be a critical factor affecting total efficiency particularly in cases where the gas must be transported from far away. This shows the value of using excess renewable energy in the production of hydrogen instead of grid power. Even in the most efficient scenario of green hydrogen studied total efficiency was found to be 7 % lower than the respective conventional efficiency that does not account for hydrogen generation. These results emphasize the importance of considering the impact of fuel preparation stages in comparative thermodynamic analyses and evaluations.
LCA of a Proton Exchange Membrane Fuel Cell Electric Vehicle Considering Different Power System Architectures
Sep 2023
Publication
Fuel cell electric vehicles are a promising solution for reducing the environmental impacts of the automotive sector; however there are still some key points to address in finding the most efficient and less impactful implementation of this technology. In this work three electrical architectures of fuel cell electric vehicles were modeled and compared in terms of the environmental impacts of their manufacturing and use phases. The three architectures differ in terms of the number and position of the DC/DC converters connecting the battery and the fuel cell to the electric motor. The life cycle assessment methodology was employed to compute and compare the impacts of the three vehicles. A model of the production of the main components of vehicles and fuel cell stacks as well as of the production of hydrogen fuel was constructed and the impacts were calculated using the program SimaPro. Eleven impact categories were considered when adopting the ReCiPe 2016 midpoint method and the EF (adapted) method was exploited for a final comparison. The results highlighted the importance of the converters and their influence on fuel consumption which was identified as the main factor in the comparison of the environmental impacts of the vehicle.
Integration of Air-cooled Multi-stack Polymer Electrolyte Fuel Cell Systems into Renewable Microgrids
May 2022
Publication
Currently there is a growing interest in increasing the power range of air-cooled fuel cells (ACFCs) as they are cheaper easier to use and maintain than water-cooled fuel cells (WCFCs). However air-cooled stacks are only available up to medium power (<10 kW). Therefore a good solution may be the development of ACFCs consisting of several stacks until the required power output is reached. This is the concept of air-cooled multi-stack fuel cell (AC-MSFC). The objective of this work is to develop a turnkey solution for the integration of AC-MSFCs in renewable microgrids specifically those with high-voltage DC (HVDC) bus. This is challenging because the AC-MSFCs must operate in the microgrid as a single ACFC with adjustable power depending on the number of stacks in operation. To achieve this the necessary power converter (ACFCs operate at low voltages so high conversion rates are required) and control loops must be developed. Unlike most designs in the literature the proposed solution is compact forming a system (AC-MSFCS) with a single input (hydrogen) and a single output (high voltage regulated power or voltage) that can be easily integrated into any microgrid and easily scalable depending on the power required. The developed AC-MSFCS integrates stacks balance of plant data acquisition and instrumentation power converters and local controllers. In addition a virtual instrument (VI)has been developed which connected to the energy management system (EMS) of the microgrid allows monitoring of the entire AC-MSFCS (operating temperature purging cell voltage monitoring for degradation evaluation stacks operating point control and alarm and event management) as well as serving as a user interface. This allows the EMS to know the degradation of each stack and to carry out energy distribution strategies or specific maintenance actions which improves efficiency lifespan and of course saves costs. The experimental results have been excellent in terms of the correct operation of the developed AC-MSFCS. Likewise the accumulated degradation of the stacks was quantified showing cells with a degradation of >80%. The excellent electrical and thermal performance of the developed power converter was also validated which allowed the correct and efficient supply of regulated power (average efficiency above 90%) to the HVDC bus according to the power setpoint defined by the EMS of the microgrid.
Hydrogen Energy and Fuel Cells: A Vision of our Future
Jan 2003
Publication
This report of the High Level Group for Hydrogen and Fuel Cell Technologies sets out a vision for these technologies in future sustainable energy systems - improving energy security of supply and air quality whilst mitigating climate change. The report recommends actions for developing world-class European hydrogen technologies and fostering their commercial exploitation.
Performance, Emissions, and Combustion Characteristics of a Hydrogen-Fueled Spark-Ignited Engine at Different Compression Ratios: Experimental and Numerical Investigation
Jul 2023
Publication
This paper investigates the performance of hydrogen-fueled spark-ignited single-cylinder Cooperative Fuel Research using experimental and numerical approaches. This study examines the effect of the air–fuel ratio on engine performance emissions and knock behaviour across different compression ratios. The results indicate that λ significantly affects both engine performance and emissions with a λ value of 2 yielding the highest efficiency and lowest emissions for all the tested compression ratios. Combustion analysis reveals normal combustion at λ ≥ 2 while knocking combustion occurs at λ < 2 irrespective of the tested compression ratios. The Livenwood–Wu integral approach was evaluated to assess the likelihood of end-gas autoignition based on fuel reactivity demonstrating that both normal and knocking combustion possibilities are consistent with experimental investigations. Combustion analysis at the ignition timing for maximum brake torque conditions demonstrates knock-free stable combustion up to λ = 3 with increased end-gas autoignition at lower λ values. To achieve knock-free combustion at those low λs the spark timings are significantly retarded to after top dead center crank angle position. Engine-out NOx emissions consistently increase in trend with a decrease in the air–fuel ratio of up to λ = 3 after which a distinct variation in NOx is observed with an increase in the compression ratio.
Natural Hydrogen the Fuel of the 21st Century
Jun 2019
Publication
Much has been learned about natural hydrogen (H2) seepages and accumulation but present knowledge of hydrogen behavior in the crust is so limited that it is not yet possible to consider exploitation of this resources. Hydrogen targeting requires a shift in the long-standing paradigms that drive oil and gas exploration. This paper describes the foundation of an integrated source-to-sink view of the hydrogen cycle and propose preliminary practical guidelines for hydrogen exploration.
A Control Strategy Study of a Renewable CCHP Energy System Integrated Hydrogen Production Unit - A Case Study of an Industrial Park in Jiangsu Province
Aug 2023
Publication
This paper describes a renewable energy system incorporating a hydrogen production unit to address the imbalance between energy supply and demand. The system utilizes renewable energy and hydrogen production energy to release energy to fill the power gap during peak demand power supply for demand peaking and valley filling. The system is optimized by analyzing marine predator behavioral logic and optimizing the system for maximum operational efficiency and best economic value. The results of the study show that after the optimized scheduling of the hydrogen production coupled renewable energy integrated energy system using the improved marine predator optimization algorithm the energy distribution of the whole energy system is good with the primary energy saving rate maintained at 24.75% the CO2 emission reduction rate maintained at 42.32% and the cost saving rate maintained at 0.78%. In addition this paper uses the Adaboost-BP prediction model to predictively analyze the system. The results show that as the price of natural gas increases the advantages of the combined hydrogen production renewable integrated energy system proposed in this paper become more obvious and the cumulative cost over three years is better than other related systems. These research results provide an important reference for the application and development of the system.
A Short Review on Ni Based Catalysts and Related Engineering Issues for Methane Steam Reforming
Mar 2020
Publication
Hydrogen is an important raw material in chemical industries and the steam reforming of light hydrocarbons (such as methane) is the most used process for its production. In this process the use of a catalyst is mandatory and if compared to precious metal-based catalysts Ni-based catalysts assure an acceptable high activity and a lower cost. The aim of a distributed hydrogen production for example through an on-site type hydrogen station is only reachable if a novel reforming system is developed with some unique properties that are not present in the large-scale reforming system. These properties include among the others (i) daily startup and shutdown (DSS) operation ability (ii) rapid response to load fluctuation (iii) compactness of device and (iv) excellent thermal exchange. In this sense the catalyst has an important role. There is vast amount of information in the literature regarding the performance of catalysts in methane steam reforming. In this short review an overview on the most recent advances in Ni based catalysts for methane steam reforming is given also regarding the use of innovative structured catalysts.
Genesis and Energy Significance of Natural Hydrogen
Jan 2023
Publication
H2 is clean energy and an important component of natural gas. Moreover it plays an irreplaceable role in improving the hydrocarbon generation rate of organic matter and activating ancient source rocks to generate hydrocarbon in Fischer-Tropsch (FT) synthesis and catalytic hydrogenation. Compared with hydrocarbon reservoir system a complete hydrogen (H2) accumulation system consists of H2 source,reservoirs and seal. In nature the four main sources of H2 are hydrolysis organic matter degradation the decomposition of substances such as methane and ammonia and deep mantle degassing. Because the complex tectonic activities the H2 produced in a geological environment is generally a mixture of various sources. Compared with the genetic mechanisms of H2 the migration and preservation of H2 especially the H2 trapping are rarely studied. A necessary condition for large-scale H2 accumulation is that the speed of H2 charge is much faster than diffusion loss. Dense cap rock and continuous H2 supply are favorable for H2 accumulation. Moreover H2O in the cap rock pores may provide favorable conditions for short-term H2 accumulation.
Phasing Out Steam Methane Reformers with Water Electrolysis in Producing Renewable Hydrogen and Ammonia: A Case Study Based on the Spanish Energy Markets
Jul 2023
Publication
Deploying renewable hydrogen presents a significant challenge in accessing off-takers who are willing to make long-term investments. To address this challenge current projects focus on large-scale deployment to replace the demand for non-renewable hydrogen particularly in ammonia synthesis for fertiliser production plants. The traditional process involving Steam Methane Reformers (SMR) connected to Haber-Bosch synthesis could potentially transition towards decarbonisation by gradually integrating water electrolysis. However the coexistence of these processes poses limitations in accommodating the integration of renewable hydrogen thereby creating operational challenges for industrial hubs. To tackle this issue this paper proposes an optimal dispatch model for producing green hydrogen and ammonia while considering the coexistence of different processes. Furthermore the objective is to analyse external factors that could determine the appropriate regulatory and pricing framework to facilitate the phase-out of SMR in favour of renewable hydrogen production. The paper presents a case study based in Spain utilising data from 2018 2022 and 2030 perspectives on the country's renewable resources gas and electricity wholesale markets pricing ranges and regulatory constraints to validate the model. The findings indicate that carbon emissions taxation and the availability and pricing of Power Purchase Agreements (PPAs) will play crucial roles in this transition - the carbon emission price required for total phasing out SMR with water electrolysis would be around 550 EUR/ton CO2.
Centralized Offshore Hydrogen Production from Wind Farms in the Baltic Sea Area—A Study Case for Poland
Aug 2023
Publication
In Poland hydrogen production should be carried out using renewable energy sources particularly wind energy (as this is the most efficient zero-emission technology available). According to hydrogen demand in Poland and to ensure stability as well as security of energy supply and also the realization of energy policy for the EU it is necessary to use offshore wind energy for direct hydrogen production. In this study a centralized offshore hydrogen production system in the Baltic Sea area was presented. The goal of our research was to explore the possibility of producing hydrogen using offshore wind energy. After analyzing wind conditions and calculating the capacity of the proposed wind farm a 600 MW offshore hydrogen platform was designed along with a pipeline to transport hydrogen to onshore storage facilities. Taking into account Poland’s Baltic Sea area wind conditions with capacity factor between 45 and 50% and having obtained results with highest monthly average output of 3508.85 t of hydrogen it should be assumed that green hydrogen production will reach profitability most quickly with electricity from offshore wind farms.
Study on Hydrogen Substitution in a Compressed Natural Gas Spark-ignition Passenger Car Engine
Jun 2023
Publication
Hydrogen substitution in applications fueled by compressed natural gas arises as a potential alternative to fossil fuels and it may be the key to an effective hydrogen economy transition. The reduction of greenhouse gas emissions especially carbon dioxide and unburned methane as hydrogen is used in transport and industry applications makes its use an attractive option for a sustainable future. The purpose of this research is to examine the gradual adoption of hydrogen as a fuel for light-duty transportation. Particularly the study focuses on evaluating the performance and emissions of a single-cylinder port fuel injection spark-ignition engine as hydrogen is progressively increased in the natural gas-based fuel blend. Results identify the optimal conditions for air dilution and engine operation parameters to achieve the best performance. They corroborate that the dilution rate has to be adjusted to control pollutant emissions as the percentage of hydrogen is increased. Moreover the study identifies the threshold for hydrogen substitution below which the reduction of carbon dioxide emissions due to efficiency gains is negligible compared to the reduction of the carbon content in the fuel blend. These findings will help reduce the environmental footprint of light-duty transportation not only in the long term but also in the short and medium terms.
Investigation of Performance of Anion Exchange Membrane (AEM) Electrolysis with Different Operating Conditions
Mar 2023
Publication
In this work the performance of anion exchange membrane (AEM) electrolysis is evaluated. A parametric study is conducted focusing on the effects of various operating parameters on the AEM efficiency. The following parameters—potassium hydroxide (KOH electrolyte concentration (0.5–2.0 M) electrolyte flow rate (1–9 mL/min) and operating temperature (30–60 ◦C)—were varied to understand their relationship to AEM performance. The performance of the electrolysis unit is measured by its hydrogen production and energy efficiency using the AEM electrolysis unit. Based on the findings the operating parameters greatly influence the performance of AEM electrolysis. The highest hydrogen production was achieved with the operational parameters of 2.0 M electrolyte concentration 60 ◦C operating temperature and 9 mL/min electrolyte flow at 2.38 V applied voltage. Hydrogen production of 61.13 mL/min was achieved with an energy consumption of 48.25 kW·h/kg and an energy efficiency of 69.64%.
A Review on Hydrogen Embrittlement and Risk-based Inspection of Hydrogen Technologies
May 2023
Publication
Hydrogen could gradually replace fossil fuels mitigating the human impact on the environment. However equipment exposed to hydrogen is subjected to damaging effects due to H2 absorption and permeation through metals. Hence inspection activities are necessary to preserve the physical integrity of the containment systems and the risk-based (RBI) methodology is considered the most beneficial approach. This review aims to provide relevant information regarding hydrogen embrittlement its effect on materials’ properties and the synergistic interplay of the factors influencing its occurrence. Moreover an overview of predictive maintenance strategies is presented focusing on the RBI methodology. A systematic review was carried out to identify examples of the application of RBI to equipment exposed to hydrogenated environments and to identify the most active research groups. In conclusion a significant lack of knowledge has been highlighted along with difficulties in applying the RBI methodology for equipment operating in a pure hydrogen environment.
A Web-based Decision Support System (DSS) for Hydrogen Refueling Station Location and Supply Chain Optimisation
Jun 2023
Publication
This study presents a novel web-based decision support system (DSS) that optimizes the locations of hydrogen refueling stations (HRSs) and hydrogen supply chains (HSCs). The system is developed with a design science approach that identifies key design requirements and features through interviews and literature reviews. Based on the findings a system architecture and data model were designed incorporating scenario management optimization model visualization and data management components. The DSS provides a two-stage solution model that links demand to HRSs and production facilities to HRSs. A prototype is demonstrated with a plan for 2025 and 2030 in the Republic of Korea where 450 to 660 stations were deployed nationwide and linked to production facilities. User evaluation confirmed the effectiveness of the DSS in solving optimization problems and its potential to assist the government and municipalities in planning hydrogen infrastructure.
The Use of Hydrogen for Traction in Freight Transport: Estimating the Reduction in Fuel Consumption and Emissions in a Regional Context
Jan 2023
Publication
The Italian National Recovery and Resilience Plan (NRRP) includes among other measures investments in hydrogen vehicle refuelling stations intending to promote the use of fuel cell electric vehicles (FCEVs) for long-haul freight transport. This paper evaluates the impact that this action could have on CO2 emissions and fuel consumption focusing on a case study of the Campania region. The proposed approach which can also be transferred to other geographical contexts requires the implementation of a freight road transport simulation model; this model is based on the construction of a supply model the estimation of road freight demand and an assignment procedure for computing traffic flows. This study covers the period from 2025 to 2040 according to the forecasts of the NRRP and some assumptions on the action effects; moreover it is assumed that hydrogen is entirely produced from renewable sources (green hydrogen). The key findings from three different scenarios show that savings between 423832 and 778538 tonnes of CO2 and between 144 and 264 million litres of diesel could be obtained.
A Comprehensive Survey of Alkaline Electrolyzer Modeling: Electrical Domain and Specific Electrolyte Conductivity
May 2022
Publication
Alkaline electrolyzers are the most widespread technology due to their maturity low cost and large capacity in generating hydrogen. However compared to proton exchange membrane (PEM) electrolyzers they request the use of potassium hydroxide (KOH) or sodium hydroxide (NaOH) since the electrolyte relies on a liquid solution. For this reason the performances of alkaline electrolyzers are governed by the electrolyte concentration and operating temperature. Due to the growing development of the water electrolysis process based on alkaline electrolyzers to generate green hydrogen from renewable energy sources the main purpose of this paper is to carry out a comprehensive survey on alkaline electrolyzers and more specifically about their electrical domain and specific electrolytic conductivity. Besides this survey will allow emphasizing the remaining key issues from the modeling point of view.
On-site Hydrogen Refuelling Station Techno-economic Model for a Fleet of Fuel Cell Buses
May 2024
Publication
Fuel cell electric buses (FCBs) have proven to be a technically viable solution for transportation owing to various advantages such as reliability simplicity better energy efficiency and quietness of operation. However largescale adoption of FCBs is hindered by the lack of extensive and structured infrastructure and the high cost of clean hydrogen. Many studies agree that one of the significant contributors to the lack of competitiveness of green hydrogen is the cost of electricity for its production followed by transportation costs. On the one hand to reduce the investment cost of the electrolyzer high operating hours should be achieved; on the other as the number of operating hours decreases the impact of the electricity costs declines. This paper presents an innovative algorithm for a scalable hydrogen refuelling station (HRS) capable of successfully matching and identifying the most cost-efficient levelized cost of hydrogen (LCOH) produced via electrolysis and connected to the grid based on the HRS components’ cost curves and the hourly average electricity price profile. The objective is to identify the least-cost range of LCOH by considering both the electric energy and the investment costs associated with a hydrogen demand given by different FCB sizes and electrolyzer rated powers. In addition sensitivity analyses have been conducted to quantify the technology cost margins and a cost comparison between the refuelling of an FCB fleet and the recharging infrastructure required for an equivalent fleet of Battery Electric Buse (BEB) has been performed. An LCOH of around 10.5 €/kg varying from 12 €/kg (2 FCB) to 10.2 €/kg (30 FCB) has been found for the best-optimized configurations. The final major conclusion of this paper is that FCB technology is currently not economically competitive. Still a cost contraction of the electric energy price and the electrolyzer capital investment would lead to a 50% decrease in the LCOH. Furthermore increasing renewable energies into the grid may shift the electricity cost curve resulting in higher prices when the BEB recharging demand is more significant. This impact in addition to the peak power load and longer recharging times might contribute to bridging the gap with FCBs.
Numerical Simulation of Hydrogen Diffusion in Cement Sheath of Wells Used for Underground Hydrogen Storage
Jul 2023
Publication
The negative environmental impact of carbon emissions from fossil fuels has promoted hydrogen utilization and storage in underground structures. Hydrogen leakage from storage structures through wells is a major concern due to the small hydrogen molecules that diffuse fast in the porous well cement sheath. The second-order parabolic partial differential equation describing the hydrogen diffusion in well cement was solved numerically using the finite difference method (FDM). The numerical model was verified with an analytical solution for an ideal case where the matrix and fluid have invariant properties. Sensitivity analyses with the model revealed several possibilities. Based on simulation studies and underlying assumptions such as non-dissolvable hydrogen gas in water present in the cement pore spaces constant hydrogen diffusion coefficient cement properties such as porosity and saturation etc. hydrogen should take about 7.5 days to fully penetrate a 35 cm cement sheath under expected well conditions. The relatively short duration for hydrogen breakthrough in the cement sheath is mainly due to the small molecule size and high hydrogen diffusivity. If the hydrogen reaches a vertical channel behind the casing a hydrogen leak from the well is soon expected. Also the simulation result reveals that hydrogen migration along the axial direction of the cement column from a storage reservoir to the top of a 50 m caprock is likely to occur in 500 years. Hydrogen diffusion into cement sheaths increases with increased cement porosity and diffusion coefficient and decreases with water saturation (and increases with hydrogen saturation). Hence cement with a low water-to-cement ratio to reduce water content and low cement porosity is desirable for completing hydrogen storage wells.
Optimal Scheduling of Power Systems with High Proportions of Renewable Energy Accounting for Operational Flexibility
Jul 2023
Publication
Yi Lin,
Wei Lin,
Wei Wu and
Zhenshan Zhu
The volatility and uncertainty of high-penetration renewable energy pose significant challenges to the stability of the power system. Current research often fails to consider the insufficient system flexibility during real-time scheduling. To address this issue this paper proposes a flexibility scheduling method for high-penetration renewable energy power systems that considers flexibility index constraints. Firstly a quantification method for flexibility resources and demands is introduced. Then considering the constraint of the flexibility margin index optimization scheduling strategies for different time scales including day-ahead scheduling and intra-day scheduling are developed with the objective of minimizing total operational costs. The intra-day optimization is divided into 15 min and 1 min time scales to meet the flexibility requirements of different time scales in the power system. Finally through simulation studies the proposed strategy is validated to enhance the system’s flexibility and economic performance. The daily operating costs are reduced by 3.1% and the wind curtailment rate is reduced by 4.7%. The proposed strategy not only considers the economic efficiency of day-ahead scheduling but also ensures a sufficient margin to cope with the uncertainty of intra-day renewable energy fluctuations.
An Economic and Greenhouse Gas Footprint Assessment of International Maritime Transportation of Hydrogen Using Liquid Organic Hydrogen Carriers
Apr 2023
Publication
The supply storage and (international) transport of green hydrogen (H2) are essential for the decarbonization of the energy sector. The goal of this study was to assess the final cost-price and carbon footprint of imported green H2 in the market via maritime shipping of liquid organic hydrogen carriers (LOHCs) including dibenzyl toluene-perhydro-dibenzyltoluene (DBTPDBT) and toluene-methylcyclohexane (TOL-MCH) systems. The study focused on logistic steps in intra-European supply chains in different scenarios of future production in Portugal and demand in the Netherlands and carbon tariffs between 2030 and 2050. The case study is based on a formally accepted agreement between Portugal and the Netherlands within the Strategic Forum on Important Projects of Common European Interest (IPCEI). Under the following assumptions the results show that LOHCs are a viable technical-economic solution with logistics costs from 2030 to 2050 varying between 0.30-0.37 €/kg-H2 for DBT-PDBT and 0.28-0.34 €/kg-H2 for TOL-MCH. The associated CO2 emissions of these international H2 supply chains are between 0.46 and 2.46 kg-CO2/GJ (LHV) and 0.55-2.95 kg-CO2/GJ (LHV) for DBT-PDBT and TOL-MCH respectively.
Modeling the Global Annual Carbon Footprint for the Transportation Sector and a Path to Sustainability
Jun 2023
Publication
The transportation industry’s transition to carbon neutrality is essential for addressing sustainability concerns. This study details a model for calculating the carbon footprint of the transportation sector as it progresses towards carbon neutrality. The model aims to support policymakers in estimating the potential impact of various decisions regarding transportation technology and infrastructure. It accounts for energy demand technological advancements and infrastructure upgrades as they relate to each transportation market: passenger vehicles commercial vehicles aircraft watercraft and trains. A technology roadmap underlies this model outlining anticipated advancements in batteries hydrogen storage biofuels renewable grid electricity and carbon capture and sequestration. By estimating the demand and the technologies that comprise each transportation market the model estimates carbon emissions. Results indicate that based on the technology roadmap carbon neutrality can be achieved by 2070 for the transportation sector. Furthermore the model found that carbon neutrality can still be achieved with slippage in the technology development schedule; however delays in infrastructure updates will delay carbon neutrality while resulting in a substantial increase in the cumulative carbon footprint of the transportation sector.
Impacts of Green Hydrogen for Steel, Ammonia, and Long-distance Transport on the Cost of Meeting Electricity, Heat, Cold, and Hydrogen Demand in 145 Countries Running on 100% Wind-water-solar
May 2023
Publication
As the world moves to clean renewable energy questions arise as to how best to produce and use hydrogen. Here we propose using hydrogen produced only by electrolysis with clean renewable electricity (green hydrogen). We then test the impact of producing such hydrogen intermittently versus continuously for steel and ammonia manufacturing and long-distance transport via fuel cells on the cost of matching electricity heat cold and hydrogen demand with supply and storage on grids worldwide. An estimated 79 32 and 91 Tg-H2/y of green hydrogen are needed in 2050 among 145 countries for steel ammonia and long-distance transport respectively. Producing and compressing such hydrogen for these processes may consume ~12.1% of the energy needed for end-use sectors in these countries after they transition to 100% wind-water-solar (WWS) in all such sectors. This is less than the energy needed for fossil fuels to power the same processes. Due to the variability of WWS electricity producing green hydrogen intermittently rather than continuously thus with electrolyzer use factors significantly below unity (0.2–0.65) may reduce overall energy costs with 100% WWS. This result is subject to model uncertainties but appears robust. In sum grid operators should incorporate intermittent green hydrogen production and use in planning.
Additive Manufacturing for Proton Exchange Membrane (PEM) Hydrogen Technologies: Merits, Challenges, and Prospects
Jul 2023
Publication
With the growing demand for green technologies hydrogen energy devices such as Proton Exchange Membrane (PEM) fuel cells and water electrolysers have received accelerated developments. However the materials and manufacturing cost of these technologies are still relatively expensive which impedes their widespread commercialization. Additive Manufacturing (AM) commonly termed 3D Printing (3DP) with its advanced capabilities could be a potential pathway to solve the fabrication challenges of PEM parts. Herein in this paper the research studies on the novel AM fabrication methods of PEM components are thoroughly reviewed and analysed. The key performance properties such as corrosion and hydrogen embrittlement resistance of the additively manufactured materials in the PEM working environment are discussed to emphasise their reliability for the PEM systems. Additionally the major challenges and required future developments of AM technologies to unlock their full potential for PEM fabrication are identified. This paper provides insights from the latest research developments on the significance of advanced manufacturing technologies in developing sustainable energy systems to address the global energy challenges and climate change effects.
Energy and Environmental Costs in Transitioning to Zero and Low Emission Trucks for the Australian Truck Fleet: An Industry Perspective
May 2024
Publication
Modernising Australia’s old truck fleet and adopting a more stringent standard to reduce emissions and air pollutants is a primary objective for the Australian truck sector. Various strategies worldwide have been introduced to cut emissions and pollutants in the truck sector such as a low-emission strategy supported by strict diesel standards and a zero-emission strategy to shift to battery-electric or hydrogen trucks. The paper focuses on emissions and local air pollutants of trucks under various transition scenarios at both the tailpipe and the wider supply chain including domestic power generation and hydrogen production. In contrast for diesel we focus on tailpipe outputs following fuel standards in Australia given diesel is imported other than in some limited refineries. We compare and recommend actions that government and truck operators may take in the near to longer term in transitioning to cleaner energy. We tested a number of scenarios using a decision support system incorporating all the latest information on costs and emissions for all truck classes using diesel electric or hydrogen. A key finding from our scenario tests is that the current electricity mix has high carbon emissions and air pollutants due to fossil fuel-fired sources for power generation. Without improvement in using renewable energy sources in the future transitioning to electric trucks implies more carbon emissions and air pollutants in the atmosphere from power plants even though electric trucks generate zero tailpipe emissions. The main motivation for switching to zero-emission trucks is energy cost savings. We urge the government to decide on a clear roadmap for the truck sector before the sector is in a position to take action to shift to low or zero-emission trucks without totally relying on the likely reduction of emission intensity in electricity and renewable energy production.
Sustainable Propulsion Alternatives in Regional Aviation: The Case of the Canary Islands
May 2023
Publication
Sustainability is one of the main challenges the aviation industry is currently facing. In a global context of energy transition towards cleaner and renewable sources the sector is developing technologies to fly more efficiently and mitigate its environmental impact. Innovative propulsion alternatives such as biofuels electric aircraft and hydrogen engines are already a reality or are close to becoming so. To assess their feasibility a study is conducted on specific routes and aircraft across different flight ranges. The analysis focuses on the Canary Islands an outermost region of the EU with high mobility and no comparable alternative means of transport. For three routes flight profiles are analyzed obtaining the fuel consumption and emissions generated by the conventional propulsion and later applying the sustainable alternatives. The results indicate optimistic perspectives with reductions in environmental impact ranging between 40% and 75% compared to the present.
Exploring the Potential of Green Hydrogen Production and Application in the Antofagasta Region of Chile
Jun 2023
Publication
Green hydrogen is gaining increasing attention as a key component of the global energy transition towards a more sustainable industry. Chile with its vast renewable energy potential is well positioned to become a major producer and exporter of green hydrogen. In this context this paper explores the prospects for green hydrogen production and use in Chile. The perspectives presented in this study are primarily based on a compilation of government reports and data from the scientific literature which primarily offer a theoretical perspective on the efficiency and cost of hydrogen production. To address the need for experimental data an ongoing experimental project was initiated in March 2023. This project aims to assess the efficiency of hydrogen production and consumption in the Atacama Desert through the deployment of a mobile on-site laboratory for hydrogen generation. The facility is mainly composed by solar panels electrolyzers fuel cells and a battery bank and it moves through the Atacama Desert in Chile at different altitudes from the sea level to measure the efficiency of hydrogen generation through the energy approach. The challenges and opportunities in Chile for developing a robust green hydrogen economy are also analyzed. According to the results Chile has remarkable renewable energy resources particularly in solar and wind power that could be harnessed to produce green hydrogen. Chile has also established a supportive policy framework that promotes the development of renewable energy and the adoption of green hydrogen technologies. However there are challenges that need to be addressed such as the high capital costs of green hydrogen production and the need for supportive infrastructure. Despite these challenges we argue that Chile has the potential to become a leading producer and exporter of green hydrogen or derivatives such as ammonia or methanol. The country’s strategic location political stability and strong commitment to renewable energy provide a favorable environment for the development of a green hydrogen industry. The growing demand for clean energy and the increasing interest in decarbonization present significant opportunities for Chile to capitalize on its renewable energy resources and become a major player in the global green hydrogen market.
Evaluation of Hydrogen Transportation Networks - A Case Study on the German Energy System
May 2023
Publication
Not only due to the energy crisis European policymakers are exploring options to substitute natural gas with renewable hydrogen. A condition for the application of hydrogen is a functioning transportation infrastructure. However the most efficient transport of large hydrogen quantities is still unclear and deeper analyses are missing. A promising option is converting the existing gas infrastructure. This study presents a novel approach to develop hydrogen networks by applying the Steiner tree algorithm to derive candidates and evaluate their costs. This method uses the existing grid (brownfield) and is compared to a newly built grid (Greenfield). The goal is the technical and economic evaluation and comparison of hydrogen network candidates. The methodology is applied to the German gas grid and demand and supply scenarios covering the industry heavy-duty transport power and heating sector imports and domestic production. Five brownfield candidates are compared to a greenfield candidate. The candidates differ by network length and pipeline diameters to consider the transported volume of hydrogen. The economic evaluation concludes that most brownfield candidates’ cost is significantly lower than those of the greenfield candidate. The candidates can serve as starting points for flow simulations and policymakers can estimate the cost based on the results.
Investment Timing Analysis of Hydrogen-Refueling Stations and the Case of China: Independent or Co-Operative Investment?
Jun 2023
Publication
The investment in hydrogen-refueling stations (HRS) is key to the development of a hydrogen economy. This paper focuses on the decision-making for potential investors faced with the thought-provoking question of when the optimal timing to invest in HRS is. To fill the gap that exists due to the fact that few studies explain why HRS investment timing is critical we expound that earlier investment in HRS could induce the first mover advantages of the technology diffusion theory. Additionally differently from the previous research that only considered that HRS investment is just made by one individual firm we innovatively examine the HRS co-investment made by two different firms. Accordingly we compare these two optional investment modes and determine which is better considering either independent investment or co-operative investment. We then explore how the optimal HRS investment timing could be figured out under conditions of uncertainty with the real options approach. Given the Chinese HRS case under the condition of demand uncertainty the hydrogen demand required for triggering investment is viewed as the proxy for investment timing. Based on analytical and numerical results we conclude that one-firm independent investment is better than two-firm cooperative investment to develop HRS not only in terms of the earlier investment timing but also in terms of the attribute for dealing with the uncertainty. Finally we offer recommendations including stabilizing the hydrogen demand for decreasing uncertainty and accelerating firms’ innovation from both technological and strategic perspectives in order to ensure firms can make HRS investments on their own.
Resilience-oriented Operation of Microgrids in the Presence of Power-to-hydrogen Systems
Jul 2023
Publication
This study presents a novel framework for improving the resilience of microgrids based on the power-to-hydrogen concept and the ability of microgrids to operate independently (i.e. islanded mode). For this purpose a model is being developed for the resilient operation of microgrids in which the compressed hydrogen produced by power-to-hydrogen systems can either be used to generate electricity through fuel cells or sold to other industries. The model is a bi-objective optimization problem which minimizes the cost of operation and resilience by (i) reducing the active power exchange with the main grid (ii) reducing the ohmic power losses and (iii) increasing the amount of hydrogen stored in the tanks. A solution approach is also developed to deal with the complexity of the bi-objective model combining a goal programming approach and Generalized Benders Decomposition due to the mixed-integer nonlinear nature of the optimization problem. The results indicate that the resilience approach although increasing the operation cost does not lead to load shedding in the event of main grid failures. The study concludes that integrating distributed power-to-hydrogen systems results in significant benefits including emission reductions of up to 20 % and cost savings of up to 30 %. Additionally the integration of the decomposition method improves computational performance by 54 % compared to using commercial solvers within the GAMS software.
Current Development Status, Policy Support and Promotion Path of China’s Green Hydrogen Industries under the Target of Carbon Emission Peaking and Carbon Neutrality
Jun 2023
Publication
The green hydrogen industry highly efficient and safe is endowed with flexible production and low carbon emissions. It is conducive to building a low-carbon efficient and clean energy structure optimizing the energy industry system and promoting the strategic transformation of energy development and enhancing energy security. In order to achieve carbon emission peaking by 2030 and neutrality by 2060 (dual carbon goals) China is vigorously promoting the green hydrogen industry. Based on an analysis of the green hydrogen industry policies of the U.S. the EU and Japan this paper explores supporting policies issued by Chinese central and local authorities and examines the inherent advantages of China’s green hydrogen industry. After investigating and analyzing the basis for the development of the green hydrogen industry in China we conclude that China has enormous potential including abundant renewable energy resources as well as commercialization experience with renewable energy robust infrastructure and technological innovation capacity demand for large-scale applications of green hydrogen in traditional industries etc. Despite this China’s green hydrogen industry is still in its early stage and has encountered bottlenecks in its development including a lack of clarity on the strategic role and position of the green hydrogen industry low competitiveness of green hydrogen production heavy reliance on imports of PEMs perfluorosulfonic acid resins (PFSR) and other core components the development dilemma of the industry chain lack of installed capacity for green hydrogen production and complicated administrative permission etc. This article therefore proposes that an appropriate development road-map and integrated administration supervision systems including safety supervision will systematically promote the green hydrogen industry. Enhancing the core technology and equipment of green hydrogen and improving the green hydrogen industry chain will be an adequate way to reduce dependence on foreign technologies lowering the price of green hydrogen products through the scale effect and thus expanding the scope of application of green hydrogen. Financial support mechanisms such as providing tax breaks and project subsidies will encourage enterprises to carry out innovative technological research on and invest in the green hydrogen industry.
Renewable Marine Fuel Production for Decarbonised Maritime Shipping: Pathways, Policy Measures and Transition Dynamics
Jun 2023
Publication
This article investigates the potential of renewable and low-carbon fuel production for the maritime shipping sector using Sweden as a case in focus. Techno-economic modelling and socio-technical transition studies are combined to explore the conditions opportunities and barriers to decarbonising the maritime shipping industry. A set of scenarios have been developed considering demand assumptions and potential instruments such as carbon price energy tax and blending mandate. The study finds that there are opportunities for decarbonising the maritime shipping industry by using renewable marine fuels such as advanced biofuels (e.g. biomethanol) electrofuels (e.g. e-methanol) and hydrogen. Sweden has tremendous resource potential for bio-based and hydrogen-based renewable liquid fuel production. In the evaluated system boundary biomethanol presents the cheapest technology option while e-ammonia is the most expensive one. Green electricity plays an important role in the decarbonisation of the maritime sector. The results of the supply chain optimisation identify the location sites and technology in Sweden as well as the trade flows to bring the fuels to where the bunker facilities are potentially located. Biomethanol and hydrogen-based marine fuels are cost-effective at a carbon price beyond 100 €/tCO2 and 200 €/tCO2 respectively. Linking back to the socio-technical transition pathways the study finds that some shipping companies are in the process of transitioning towards using renewable marine fuels thereby enabling niche innovations to break through the carbon lock-in and eventually alter the socio-technical regime while other shipping companies are more resistant. Overall there is increasing pressure from (inter)national energy and climate policy-making to decarbonise the maritime shipping industry.
The Prospects of Hydrogen in Achieving Net Zero Emissions by 2050: A Critical Review
May 2023
Publication
Hydrogen (H2) usage was 90 metric tonnes (Mt) in 2020 almost entirely for industrial and refining uses and generated almost completely from fossil fuels leading to nearly 900 Mt of carbon dioxide emissions. However there has been significant growth of H2 in recent years. Electrolysers' total capacity which are required to generate H2 from electricity has multiplied in the past years reaching more than 300 MW through 2021. Approximately 350 projects reportedly under construction could push total capacity to 54 GW by the year 2030. Some other 40 projects totalling output of more than 35 GW are in the planning phase. If each of these projects is completed global H2 production from electrolysers could exceed 8 Mt by 2030. It's an opportunity to take advantage of H2S prospects to be a crucial component of a clean safe and cost-effective sustainable future. This paper assesses the situation regarding H2 at the moment and provides recommendations for its potential future advancement. The study reveals that clean H2 is experiencing significant unparalleled commercial and political force with the amount of laws and projects all over the globe growing quickly. The paper concludes that in order to make H2 more widely employed it is crucial to significantly increase innovations and reduce costs. The practical and implementable suggestions provided to industries and governments will allow them to fully capitalise on this growing momentum.
U.S. National Clean Hydrogen Strategy and Roadmap
Jun 2023
Publication
The U.S. National Clean Hydrogen Strategy and Roadmap explores opportunities for clean hydrogen to contribute to national decarbonization goals across multiple sectors of the economy. It provides a snapshot of hydrogen production transport storage and use in the United States today and presents a strategic framework for achieving large-scale production and use of clean hydrogen examining scenarios for 2030 2040 and 2050.
The Strategy and Roadmap also identifies needs for collaboration among federal government agencies industry academia national laboratories state local and Tribal communities environmental and justice communities labor unions and numerous stakeholder groups to accelerate progress and market liftoff. This roadmap establishes concrete targets market-driven metrics and tangible actions to measure success across sectors.
The Strategy and Roadmap responds to legislative language set forth in section 40314 of the Infrastructure Investment and Jobs Act (Public Law 117-58) also known as the Bipartisan Infrastructure Law (BIL). This document was posted for in draft form for public comment in September 2022 and the final version of the report was informed by stakeholder feedback further analysis on market liftoff as well as engagement across several federal agencies and the White House Climate Policy Office. There will also be future opportunities for stakeholder feedback as the report will be updated at least every three years as required by the BIL.
The report can be found on their website.
The Strategy and Roadmap also identifies needs for collaboration among federal government agencies industry academia national laboratories state local and Tribal communities environmental and justice communities labor unions and numerous stakeholder groups to accelerate progress and market liftoff. This roadmap establishes concrete targets market-driven metrics and tangible actions to measure success across sectors.
The Strategy and Roadmap responds to legislative language set forth in section 40314 of the Infrastructure Investment and Jobs Act (Public Law 117-58) also known as the Bipartisan Infrastructure Law (BIL). This document was posted for in draft form for public comment in September 2022 and the final version of the report was informed by stakeholder feedback further analysis on market liftoff as well as engagement across several federal agencies and the White House Climate Policy Office. There will also be future opportunities for stakeholder feedback as the report will be updated at least every three years as required by the BIL.
The report can be found on their website.
Impacts of Wind Conditions on Hydrogen Leakage During Refilling Hydrogen-powered Vehicles
Mar 2023
Publication
Although hydrogen leakage at hydrogen refueling stations has been a concern less effort has been devoted to hydrogen leakage during the refueling of hydrogen-powered vehicles. In this study hydrogen leakage and dilution from the hydrogen dispenser during the refueling of hydrogen-powered vehicles were numerically investigated under different wind configurations. The shape size and distribution of flammable gas clouds (FGC) during the leakage and dilution processes were analyzed. The results showed that the presence of hydrogen-powered vehicles resulted in irregular FGC shapes. Greater wind speeds (vwv) were associated with longer FGC propagation distances. At vwv =2 m/s and 10 m/s the FGC lengths at the end of the leakage were 7.9 m and 20.4 m respectively. Under downwind conditions higher wind speeds corresponded to lower FGC heights. The FGC height was larger under upwind conditions and was slightly affected by the magnitude of the wind speed. In the dilution process the existence of a region with a high hydrogen concentration led to the FGC volume first increasing and then gradually decreasing. Wind promoted the mixing of hydrogen and air accelerated FGC dilution inhibited hydrogen uplifting and augmented the horizontal movement of the FGC. At higher wind speeds the low-altitude FGC movements could induce potential safety hazards.
Analyzing the Future Potential of Defossilizing Industrial Specialty Glass Production with Hydrogen by LCA
Mar 2022
Publication
The glass industry is part of the energy-intensive industry with most of the energy needed to melt the raw materials. To produce glass temperatures between 1000 and 1600 °C are necessary. Presently mostly fossil natural gas is the dominant energy source. As direct electrification is not always possible in this paper a Life Cycle Assessment (LCA) for specialty glass production is conducted where the conventional fossil-based reference process is compared to a hydrogen-fired furnace. This hydrogen can be produced on-site in an water electrolyzer using not only the hydrogen for the combustion but also the produced oxygen. Hydrogen can be produced alternatively off-site in a large scale electrolyzer to facilitate economy of scale. For the transport and distribution of this hydrogen different options are available. A rather new option are liquid organic hydrogen carriers (LOHC) which bind the hydrogen in a chemical substance. However temperatures around 300 °C are necessary to separate the hydrogen from the LOHC after transport. At the glass trough waste heat is available at the required temperature level to facilitate the dehydrogenation. The comparison is completed by the production of off-site hydrogen transported to the glass trough as conventional liquefied hydrogen in cooling tanks by truck or in hydrogen pipelines. In this assessment to power the electrolyzers the national grid mix of Germany is used. A time frame from 2020 till 2050 and its changing energy system towards defossilisation is analyzed. Regarding climate change on-site hydrogen production causes the least impact for specialty glass production in 2050. However negative trade-offs for other environmental impact categories e.g. Metal depletion are recorded.
Energy Sustainability: A Pragmatic Approach and Illustrations
Mar 2009
Publication
Many factors to be appropriately addressed in moving towards energy sustainability are examined. These include harnessing sustainable energy sources utilizing sustainable energy carriers increasing efficiency reducing environmental impact and improving socioeconomic acceptability. The latter factor includes community involvement and social acceptability economic affordability and equity lifestyles land use and aesthetics. Numerous illustrations demonstrate measures consistent with the approach put forward and options for energy sustainability and the broader objective of sustainability. Energy sustainability is of great importance to overall sustainability given the pervasiveness of energy use its importance in economic development and living standards and its impact on the environment.
Oxy-fuel Combustion-based Blue Hydrogen Production with the Integration of Water Electrolysis
Jun 2023
Publication
Blue hydrogen is gaining attention as an intermediate step toward achieving eco-friendly green hydrogen production. However the general blue hydrogen production requires an energy-intensive process for carbon capture and storage resulting in low process efficiency. Additionally the hydrogen production processes steam methane reforming (SMR) and electrolysis emits waste heat and byproduct oxygen respectively. To solve these problems this study proposes an oxy-fuel combustion-based blue hydrogen production process that integrates fossil fuel-based hydrogen production and electrolysis processes. The proposed processes are SMR + SOEC and SMR + PEMEC whereas SMR solid oxide electrolysis cell (SOEC) and proton exchange membrane electrolysis cell (PEMEC) are also examined for comparison. In the proposed processes the oxygen produced by the electrolyzer is utilized for oxy-fuel combustion in the SMR process and the resulting flue gas containing CO2 and H2O is condensed to easily separate CO2. Additionally the waste heat from the SMR process is recovered to heat the feed water for the electrolyzer thereby maximizing the process efficiency. Techno-economic sensitivity and greenhouse gas (GHG) analyses were conducted to evaluate the efficiency and feasibility of the proposed processes. The results show that SMR + SOEC demonstrated the highest thermal efficiency (85.2%) and exergy efficiency (80.5%) exceeding the efficiency of the SMR process (78.4% and 70.4% for thermal and exergy efficiencies respectively). Furthermore the SMR + SOEC process showed the lowest levelized cost of hydrogen of 6.21 USD/kgH2. Lastly the SMR + SOEC demonstrated the lowest life cycle GHG emissions. In conclusion the proposed SMR + SOEC process is expected to be a suitable technology for the transition from gray to green hydrogen.
Characterization of the Hydrogen Combustion Process in a Scramjet Engine
May 2024
Publication
In this paper by using a large eddy simulation we study the combustion process in the HyShot II scramjet combustor. By conducting a detailed analysis of the mass-fraction distributions of the main species such as H2 H2O and the radicals OH and HO2 of the mass source terms of these main species and of the chemical source term of the energy equation we detect the regions where chemical reactions occur through a diffusion process and the regions where auto-ignition and premixed combustion may develop. The analysis indicates that the combustion process is mainly of diffusive type along a thin shear layer enveloping the hydrogen plume whereas there could be some auto-ignition and/or premixed combustion cores inside the plume.
The UK Hydrogen Innovation Opportunity
Apr 2024
Publication
The report considers the full end-to-end nature of the hydrogen economy to ensure there is a common understanding of the economic opportunity it could represent by 2050. Insights from across industry have brought clarity to both market and technology requirements identifying four focus areas that represent the greatest potential benefit for the UK. It highlights the steps needed to build the UK industrial capability and capacity to position the UK as a market leader. The UK Hydrogen Innovation Opportunity has been developed with and for industry with the first phase of industrial engagement involving over 250 businesses and 12 sector bodies. A second phase of industrial engagement will expand to a broader set of consulted stakeholder groups concluding with a report entitled Hydrogen Innovation: The Case for Action in summer 2024. This will seek to validate the proposed focus areas provide more detailed scope definition the size of the opportunity and outline the steps required to secure them for the UK.
Correlations between Component Size Green Hydrogen Demand and Breakeven Price for Energy Islands
Jun 2023
Publication
The topic of energy islands is currently a focal point in the push for the energy transition. An ambitious project in the North Sea aims to build an offshore wind-powered electrolyser for green hydrogen production. Power-to-X (PtX) is a process of converting renewable electricity into hydrogen-based energy carriers such as natural gas liquid fuels and chemicals. PtH2 represents a subset of PtX wherein hydrogen is the resultant green energy from the conversion process. Many uncertainties surround PtH2 plants affecting the economic success of the investment and making the price of hydrogen and the levelized cost of hydrogen (LCOH) of this technology uncompetitive. Several studies have analysed PtH2 layouts to identify the hydrogen price without considering how component capacities and external inputs affect the breakeven price. Unlike previous works this paper investigates component capacity dependencies under variables such as wind and hydrogen demand shape for dedicated/non-dedicated system layouts. To this end the techno-economic analysis finds the breakeven price optimising the components to reach the lowest selling price. Results show that the hydrogen price can reach 2.2 €/kg for a non-dedicated system for certain combinations of maximum demand and electrolyser capacity. Furthermore the LCOH analysis revealed that the offshore wind electrolyser system is currently uncompetitive with hydrogen production from carbon-based technologies but is competitive with renewable technologies. The sensitivity analysis reveals the green electricity price in the non-dedicated case for which a dedicated system has a lower optimum hydrogen price. The price limit for the dedicated case is 116 €/MWh.
Market-based Asset Valuation of Hydrogen Geological Storage
Jul 2023
Publication
Because of hydrogen's low energy density hydrogen storage is a critical component of the hydrogen economy particularly when large-scale and flexible hydrogen utilization is required. There is a sense of urgency to develop hydrogen geological storage projects to support large-scale yet flexible hydrogen utilization. This study aims to answer questions not yet resolved in the research literature discussing the valuation of hydrogen geological storage options for commercial development. This study establishes a net present value (NPV) evaluation framework for geological hydrogen storage that integrates the updated techno-economic analysis and market-based operations. The capital asset pricing model (CAPM) and the related finance theories are applied to determine the risk-adjusted discount rate in building the NPV evaluation framework. The NPV framework has been applied to two geological hydrogen storage projects a single-turn storage serving downstream transportation seasonal demand versus a multiturn storage as part of an integrated renewables-based hydrogen energy system providing peak electric load. From the NPV framework both projects have positive NPVs $46 560 632 and $12 457 546 respectively and International Rate of Return (IRR) values which are higher than the costs of capital. The NPV framework is also applied to the sensitivity analysis and shows that the hydrogen price spread between withdrawal and injection prices site development and well costs are the top three factors that impact both NPV and IRR the most for both projects. The established NPV framework can be used for project risk management by discovering the key cost drivers for the storage assets.
Technology Pathways, Efficiency Gains and Price Implications of Decarbonising Residential Heat in the UK
Jun 2023
Publication
The UK government’s plans to decarbonise residential heating will mean major changes to the energy system whatever the specific technology pathway chosen driving a range of impacts on users and suppliers. We use an energy system model (UK TIMES) to identify the potential energy system impacts of alternative pathways to low or zero carbon heating. We find that the speed of transitioning can affect the network investment requirements the overall energy use and emissions generated while the primary heating fuel shift will determine which sectors and networks require most investment. Crucially we identify that retail price differences between heating fuels in the UK particularly gas and electricity could erode or eliminate bill savings from switching to more efficient heating systems.
Experimental Comparison of Hydrogen Refueling with Directly Pressurized vs. Cascade Method
Aug 2023
Publication
This paper presents a comparative analysis of two hydrogen station configurations during the refueling process: the conventional “directly pressurized refueling process” and the innovative “cascade refueling process.” The objective of the cascade process is to refuel vehicles without the need for booster compressors. The experiments were conducted at the Hydrogen Research and Fueling Facility located at California State University Los Angeles. In the cascade refueling process the facility buffer tanks were utilized as high-pressure storage enabling the refueling operation. Three different scenarios were tested: one involving the cascade refueling process and two involving compressor-driven refueling processes. On average each refueling event delivered 1.6 kg of hydrogen. Although the cascade refueling process using the high-pressure buffer tanks did not achieve the pressure target it resulted in a notable improvement in the nozzle outlet temperature trend reducing it by approximately 8 ◦C. Moreover the overall hydrogen chiller load for the two directly pressurized refuelings was 66 Wh/kg and 62 Wh/kg respectively whereas the cascading process only required 55 Wh/kg. This represents a 20% and 12% reduction in energy consumption compared to the scenarios involving booster compressors during fueling. The observed refueling range of 150–350 bar showed that the cascade process consistently required 12–20% less energy for hydrogen chilling. Additionally the nozzle outlet temperature demonstrated an approximate 8 ◦C improvement within this pressure range. These findings indicate that further improvements can be expected in the high-pressure region specifically above 350 bar. This research suggests the potential for significant improvements in the high-pressure range emphasizing the viability of the cascade refueling process as a promising alternative to the direct compression approach.
Hydrogen Liquefaction: A Review of the Fundamental Physics, Engineering Practice and Future Opportunities
Apr 2022
Publication
Hydrogen is emerging as one of the most promising energy carriers for a decarbonised global energy system. Transportation and storage of hydrogen are critical to its large-scale adoption and to these ends liquid hydrogen is being widely considered. The liquefaction and storage processes must however be both safe and efficient for liquid hydrogen to be viable as an energy carrier. Identifying the most promising liquefaction processes and associated transport and storage technologies is therefore crucial; these need to be considered in terms of a range of interconnected parameters ranging from energy consumption and appropriate materials usage to considerations of unique liquid-hydrogen physics (in the form of ortho–para hydrogen conversion) and boil-off gas handling. This study presents the current state of liquid hydrogen technology across the entire value chain whilst detailing both the relevant underpinning science (e.g. the quantum behaviour of hydrogen at cryogenic temperatures) and current liquefaction process routes including relevant unit operation design and efficiency. Cognisant of the challenges associated with a projected hydrogen liquefaction plant capacity scale-up from the current 32 tonnes per day to greater than 100 tonnes per day to meet projected hydrogen demand this study also reflects on the next-generation of liquid-hydrogen technologies and the scientific research and development priorities needed to enable them.
Research of Energy Efficiency and Environmental Performance of Vehicle Power Plant Converted to Work on Alternative Fuels
Apr 2024
Publication
The use of alternative fuels remains an important factor in solving the problem of reducing harmful substances caused by vehicles and decarbonising transport. It is also important to ensure the energy efficiency of vehicle power plants when using different fuels at a sufficient level. The article presents the results of theoretical and experimental studies of the conversion of diesel engine to alternative fuels with hydrogen admixtures. Methanol is considered as an alternative fuel which is a cheaper alternative to commercial diesel fuel. The chemical essence of improving the calorific value of alternative methanol fuel was investigated. Studies showed that the energy effect of burning an alternative mixture with hydrogen additives exceeds the effect of burning the same amount of methanol fuel. The increase in combustion energy and engine power is achieved as a result of heat from efficient use of the engine exhaust gases and chemical conversion of methanol. An experimental installation was created to study the work of a converted diesel engine on hydrogen–methanol mixtures and thermochemical regeneration processes. Experimental studies of the energy and environmental parameters of diesel engine converted to work on an alternative fuel with hydrogen admixtures have shown that engine power increases by 10–14% and emissions of harmful substances decrease.
Anion Exchange Membrane Water Electrolyzer: Electrode Design, Lab-scaled Testing System and Performance Evaluation
Aug 2022
Publication
Green hydrogen produced by water electrolysis is one of the most promising technologies to realize the efficient utilization of intermittent renewable energy and the decarbonizing future. Among various electrolysis technologies the emerging anion-exchange membrane water electrolysis (AEMWE) shows the most potential for producing green hydrogen at a competitive price. In this review we demonstrate a comprehensive introduction to AEMWE including the advanced electrode design the lab-scaled testing system establishment and the electrochemical performance evaluation. Specifically recent progress in developing high activity transition metal-based powder electrocatalysts and self-supporting electrodes for AEMWE is summarized. To improve the synergistic transfer behaviors between electron charge water and gas inside the gas diffusion electrode (GDE) two optimizing strategies are concluded by regulating the pore structure and interfacial chemistry. Moreover we provide a detailed guideline for establishing the AEMWE testing system and selecting the electrolyzer components. The influences of the membrane electrode assembly (MEA) technologies and operation conditions on cell performance are also discussed. Besides diverse electrochemical methods to evaluate the activity and stability implement the failure analyses and realize the in-situ characterizations are elaborated. In end some perspectives about the optimization of interfacial environment and cost assessments have been proposed for the development of advanced and durable AEMWE.
A Theoretical Study on the Hydrogen Filling Process of the On-board Storage Cylinder in Hydrogen Refueling Station
May 2023
Publication
With the development of the hydrogen fuel automobile industry higher requirements are put forward for the construction of hydrogen energy infrastructure the matching of parameters and the control strategy of hydrogen filling rate in the hydrogen charging process of hydrogen refueling stations. At present the technological difficulty of hydrogen fueling is mainly reflected in the balanced treatment of reducing the temperature rise of hydrogen and shortening the filling time during the fast filling process. Vehicle hydrogen storage cylinder (VHSC) is one of the important components of hydrogen fuel cell vehicles. This study proposed a theoretical model for calculating the temperature rise in the VHSC during the high pressure refueling process and revealed the hydrogen temperature rise during refueling. A hydrogen temperature rise prediction model was constructed to elucidate the relationship between filling parameters and temperature rise. The filling process of VHSC was analyzed from the theoretical method. The theoretical analysis results were consistent with the simulation and experimental analysis results which provided a theoretical basis for the current hydrogen temperature control algorithm of the gas source in the hydrogen refueling station and then reduced the energy consumption required for hydrogen cooling in the hydrogen refueling station.
A Comprehensive Resilience Assessment Framework for Hydrogen Energy Infrastructure Development
Jun 2023
Publication
In recent years sustainable development has become a challenge for many societies due to natural or other disruptive events which have disrupted economic environmental and energy infrastructure growth. Developing hydrogen energy infrastructure is crucial for sustainable development because of its numerous benefits over conventional energy sources. However the complexity of hydrogen energy infrastructure including production utilization and storage stages requires accounting for potential vulnerabilities. Therefore resilience needs to be considered along with sustainable development. This paper proposes a decision-making framework to evaluate the resilience of hydrogen energy infrastructure by integrating resilience indicators and sustainability contributing factors. A holistic taxonomy of resilience performance is first developed followed by a qualitative resilience assessment framework using a novel Intuitionistic fuzzy Weighted Influence Nonlinear Gauge System (IFWINGS). The results highlighted that Regulation and legislation Government preparation and Crisis response budget are the most critical resilience indicators in the understudy hydrogen energy infrastructure. A comparative case study demonstrates the practicality capability and effectiveness of the proposed approach. The results suggest that the proposed model can be used for resilience assessment in other areas.
Perspectives and Prospects of Underground Hydrogen Storage and Natural Hydrogen
Jun 2022
Publication
Hydrogen is considered the fuel of the future due to its cleaner nature compared to methane and gasoline. Therefore renewable hydrogen production technologies and long-term affordable and safe storage have recently attracted significant research interest. However natural underground hydrogen production and storage have received scant attention in the literature despite its great potential. As such the associated formation mechanisms geological locations and future applications remain relatively under-explored thereby requiring further investigation. In this review the global natural hydrogen formation along with reaction mechanisms (i.e. metamorphic processes pyritization and serpentinization reactions) as well as the suitable geological locations (i.e. ophiolites organic-rich sediments fault zones igneous rocks crystalline basements salt bearing strata and hydrocarbon-bearing basins) are discussed. Moreover the underground hydrogen storage mechanisms are detailed and compared with underground natural gas and CO2 storage. Techno-economic analyses of large-scale underground hydrogen storage are presented along with the current challenges and future directions.
The Effect of Explosions on the Protective Wall of a Containerized Hydrogen Fuel Cell System
Jun 2023
Publication
With the development of hydrogen energy containerized hydrogen fuel cell systems are being used in distributed energy-supply systems. Hydrogen pipelines and electronic equipment of fuel cell containers can trigger hydrogen-explosion accidents. In the present study Computational Fluid Dynamics (CFD) software was used to calculate the affected areas of hydrogen fuel cell container-explosion accidents with and without protective walls. The protective effects were studied for protective walls at various distances and heights. The results show that strategically placing protective walls can effectively block the propagation of shock waves and flames. However the protective wall has a limited effect on the reduction of overpressure and temperature behind the wall when the protective wall is insufficiently high. Reflected explosion shock waves and flames will cause damage to the area inside the wall when the protective wall is too close to the container. In this study a protective wall that is 5 m away from the container and 3 m high can effectively protect the area behind the wall and prevent damage to the container due to the reflection of shock waves and flame. This paper presents a suitable protective wall setting scheme for hydrogen fuel cell containers.
Linking Cost Decline and Demand Surge in the Hydrogen Market: A Case Study in China
Jun 2023
Publication
Hydrogen is crucial in achieving global energy transition and carbon neutrality goals. Existing market estimates typically presume linear or exponential growth but fail to consider how market demand responds to the declining cost of underlying technologies. To address this this study utilizes a learning curve model to project the cost of electrolyzers and its subsequent impact on hydrogen market aligning with a premise that the market demand is proportional to the cost of hydrogen. In a case study of China’s hydrogen market projecting from 2020 to 2060 we observed substantial differences in market evolution compared to exponential growth scenarios. Contrary to exponential growth scenarios China’s hydrogen market experiences faster growth during the 2020–2040 period rather than later. Such differences underscore the necessity for proactive strategic planning in emerging technology markets particularly for those experiencing rapid cost decline such as hydrogen. The framework can also be extended to other markets by using local data providing valuable insights to investors policymakers and developers engaged in the hydrogen market.
Preliminary Study for the Commercialization of a Electrochemical Hydrogen Compressor
Mar 2023
Publication
A global energy shift to a carbon‐neutral society requires clean energy. Hydrogen can accelerate the process of expanding clean and renewable energy sources. However conventional hydrogen compression and storage technology still suffers from inefficiencies high costs and safety concerns. An electrochemical hydrogen compressor (EHC) is a device similar in structure to a water electrolyzer. Its most significant advantage is that it can accomplish hydrogen separation and compression at the same time. With no mechanical motion and low energy consumption the EHC is the key to future hydrogen compression and purification technology breakthroughs. In this study the compression performance efficiency and other related parameters of EHC are investigated through experiments and simulation calculations. The experimental results show that under the same experimental conditions increasing the supply voltage and the pressure in the anode chamber can improve the reaction rate of EHC and balance the pressure difference between the cathode and anode. The presence of residual air in the anode can impede the interaction between hydrogen and the catalyst as well as the proton exchange membrane (PEM) resulting in a decrease in performance. In addition it was found that a single EHC has a better compression ratio and reaction rate than a double EHC. The experimental results were compatible with the theoretical calculations within less than a 7% deviation. Finally the conditions required to reach commercialization were evaluated using the theoretical model.
The Role of Liquid Hydrogen in Integrated Energy Systems - A Case Study for Germany
May 2023
Publication
Hydrogen (H2) is expected to be a key building block in future greenhouse gas neutral energy systems. This study investigates the role of liquid hydrogen (LH2) in a national greenhouse gas-neutral energy supply system for Germany in 2045. The integrated energy system model suite ETHOS is extended by LH2 demand profiles in the sectors aviation mobility and chemical industry and means of LH2 transportation via inland vessel rail and truck. This case study demonstrates that the type of hydrogen demand (liquid or gaseous) can strongly affect the cost-optimal design of the future energy system. When LH2 demand is introduced to the energy system LH2 import transportation and production grow in importance. This decreases the need for gaseous hydrogen (GH2) pipelines and affects the location of H2 production plants. When identifying no-regret measures it must be considered that the largest H2 consumers are the ones with the highest readiness to use LH2.
Green Hydrogen Based Power Generation Prospect for Sustainable Development of Bangladesh using PEMFC and Hydrogen Gas Turbine
Feb 2023
Publication
Bangladesh focuses on green energy sources to be a lesser dependent on imported fossil fuels and to reduce the GHG emission to decarbonize the energy sector. The integration of renewable energy technologies for green hydrogen production is promising for Bangladesh. Hybrid renewable plants at the coastline along the Bay of Bengal Kuakata Sandwip St. Martin Cox’sbazer and Chattogram for green hydrogen production is very promising to solve the power demand scarcity of Bangladesh. Hydrogen gas turbine and hydrogen fuel cell configured power plant performances are studied to observe the feasibility/prospect to the green energy transition. The Plant’s performances investigated based on specification of the plant’s units and verified by MATLAB SIMULINK software. Fuels blending (different percent of hydrogen with fossil fuel/NG) technique makes the hydrogen more feasible as turbine fuel. The net efficiency of the fuel cell-based combined cycle configuration (74%) is higher than that of the hydrogen gas turbine-based configuration (51.9%). Moreover analyses show that the increment of combined cycle gas turbine efficiency (+18.5%) is more than the combined cycle PEMFC configuration (+14%). Long-term storage of renewable energy in the salt cavern as green hydrogen can be a source of energy for emergency. A significant share of power can be generated by a numbers of green power plants at specified places in Bangladesh.
Hydrogen 4.0: A Cyber–Physical System for Renewable Hydrogen Energy Plants
May 2024
Publication
The demand for green hydrogen as an energy carrier is projected to exceed 350 million tons per year by 2050 driven by the need for sustainable distribution and storage of energy generated from sources. Despite its potential hydrogen production currently faces challenges related to cost efficiency compliance monitoring and safety. This work proposes Hydrogen 4.0 a cyber–physical approach that leverages Industry 4.0 technologies—including smart sensing analytics and the Internet of Things (IoT)—to address these issues in hydrogen energy plants. Such an approach has the potential to enhance efficiency safety and compliance through real-time data analysis predictive maintenance and optimised resource allocation ultimately facilitating the adoption of renewable green hydrogen. The following sections break down conventional hydrogen plants into functional blocks and discusses how Industry 4.0 technologies can be applied to each segment. The components benefits and application scenarios of Hydrogen 4.0 are discussed while how digitalisation technologies can contribute to the successful integration of sustainable energy solutions in the global energy sector is also addressed.
Uncertainty Quantification in Hydrogen Tank Exchange: Estimating Maintenance Costs for New Aircraft Concepts
Apr 2024
Publication
The increasing demand for sustainable air mobility has led to the development of innovative aircraft designs necessitating a balance between environmental responsibility and profitability. However despite technological advancements there is still limited understanding of the maintenance implications for hydrogen systems in aviation. The aim of this study is to estimate the maintenance costs of replacing the hydrogen storage system in an aircraft as part of its life cycle costs. To achieve this we compared conventional and hydrogenpowered aircraft. As there is insufficient data for new aircraft concepts typical probabilistic methods are not applicable. However by combining global sensitivity analysis with Dempster–Shafer Theory of Evidence and discrete event simulation it is possible to identify key uncertainties that impact maintenance costs and economic efficiency. This innovative framework offers an early estimate of maintenance costs under uncertainty enhancing understanding and assisting in decision-making when integrating hydrogen storage systems and new aviation technologies.
Carbon-negative Hydrogen: Exploring the Techno-economic Potential of Biomass Co-gasification with CO2 Capture
Sep 2021
Publication
The hydrogen economy is receiving increasing attention as a complement to electrification in the global energy transition. Clean hydrogen production is often viewed as a competition between natural gas reforming with CO2 capture and electrolysis using renewable electricity. However solid fuel gasification with CO2 capture presents another viable alternative especially when considering the potential of biomass to achieve negative CO2 emissions. This study investigates the techno-economic potential of hydrogen production from large-scale coal/ biomass co-gasification plants with CO2 capture. With a CO2 price of 50 €/ton the benchmark plant using commercially available technologies achieved an attractive hydrogen production cost of 1.78 €/kg with higher CO2 prices leading to considerable cost reductions. Advanced configurations employing hot gas clean-up membrane-assisted water-gas shift and more efficient gasification with slurry vaporization and a chemical quench reduced the hydrogen production cost to 1.50–1.62 €/kg with up to 100% CO2 capture. Without contingencies added to the pre-commercial technologies the lowest cost reduces to 1.43 €/kg. It was also possible to recover waste heat in the form of hot water at 120 ◦C for district heating potentially unlocking further cost reductions to 1.24 €/kg. In conclusion gasification of locally available solid fuels should be seriously considered next to natural gas and electrolysis for supplying the emerging hydrogen economy.
Comparative Exergy and Environmental Assessment of the Residual Biomass Gasification Routes for Hydrogen and Ammonia Production
Jul 2023
Publication
The need to reduce the dependency of chemicals on fossil fuels has recently motivated the adoption of renewable energies in those sectors. In addition due to a growing population the treatment and disposition of residual biomass from agricultural processes such as sugar cane and orange bagasse or even from human waste such as sewage sludge will be a challenge for the next generation. These residual biomasses can be an attractive alternative for the production of environmentally friendly fuels and make the economy more circular and efficient. However these raw materials have been hitherto widely used as fuel for boilers or disposed of in sanitary landfills losing their capacity to generate other by-products in addition to contributing to the emissions of gases that promote global warming. For this reason this work analyzes and optimizes the biomass-based routes of biochemical production (namely hydrogen and ammonia) using the gasification of residual biomasses. Moreover the capture of biogenic CO2 aims to reduce the environmental burden leading to negative emissions in the overall energy system. In this context the chemical plants were designed modeled and simulated using Aspen plus™ software. The energy integration and optimization were performed using the OSMOSE Lua Platform. The exergy destruction exergy efficiency and general balance of the CO2 emissions were evaluated. As a result the irreversibility generated by the gasification unit has a relevant influence on the exergy efficiency of the entire plant. On the other hand an overall negative emission balance of −5.95 kgCO2/kgH2 in the hydrogen production route and −1.615 kgCO2/kgNH3 in the ammonia production route can be achieved thus removing from the atmosphere 0.901 tCO2/tbiomass and 1.096 tCO2/tbiomass respectively.
A Green Route for Hydrogen Producton from Alkaline Thermal Treatment (ATT) of Biomass with Carbon Storage
Apr 2023
Publication
Hydrogen a green energy carrier is one of the most promising energy sources. However,it is currently mainly produced from depleting fossil fuels with high carbon emissions which has serious negative effects on the economy and environment. To address this issue sustainable hydrogen production from bio-energy with carbon capture and storage (HyBECCS) is an ideal technology to reduce global carbon emissions while meeting energy demand. This review presents an overview of the latest progress in alkaline thermal treatment (ATT) of biomass for hydrogen production with carbon storage especially focusing on the technical characteristics and related challenges from an industrial application perspective. Additionally the roles of alkali and catalyst in the ATT process are critically discussed and several aspects that have great influences on the ATT process such as biomass types reaction parameters and reactors are expounded. Finally the potential solutions to the general challenges and obstacles to the future industrial-scale application of ATT of biomass for hydrogen production are proposed.
Life Cycle Assessment of Electric Vehicles and Hydrogen Fuel Cell Vehicles Using the GREET Model—A Comparative Study
Apr 2021
Publication
Facing global warming and recent bans on the use of diesel in vehicles there is a growing need to develop vehicles powered by renewable energy sources to mitigate greenhouse gas and pollutant emissions. Among the various forms of non-fossil energy for vehicles hydrogen fuel is emerging as a promising way to combat global warming. To date most studies on vehicle carbon emissions have focused on diesel and electric vehicles (EVs). Emission assessment methodologies are usually developed for fast-moving consumer goods (FMCG) which are non-durable household goods such as packaged foods beverages and toiletries instead of vehicle products. There is an increase in the number of articles addressing the product carbon footprint (PCF) of hydrogen fuel cell vehicles in the recent years while relatively little research focuses on both vehicle PCF and fuel cycle. Zero-emission vehicles initiative has also brought the importance of investigating the emission throughout the fuel cycle of hydrogen fuel cell and its environmental impact. To address these gaps this study uses the life-cycle assessment (LCA) process of GREET (greenhouse gases regulated emissions and energy use in transportation) to compare the PCF of an EV (Tesla Model 3) and a hydrogen fuel cell car (Toyota MIRAI). According to the GREET results the fuel cycle contributes significantly to the PCF of both vehicles. The findings also reveal the need for greater transparency in the disclosure of relevant information on the PCF methodology adopted by vehicle manufacturers to enable comparison of their vehicles’ emissions. Future work will include examining the best practices of PCF reporting for vehicles powered by renewable energy sources as well as examining the carbon footprints of hydrogen production technologies based on different methodologies.
Hazard Identification of Hydrogen-Based Alternative Fuels Onboard Ships
Dec 2023
Publication
It is essential to use alternative fuels if we are to reach the emission reduction targets set by the IMO. Hydrogen carriers are classified as zero-emission while having a higher energy density (including packing factor) than pure hydrogen. They are often considered as safe alternative fuels. The exact definition of what safety entails is often lacking both for hydrogen carriers as well as for ship safety. The aim of this study is to review the safety of hydrogen carriers from two perspectives investigating potential connections between the chemical and maritime approaches to safety. This enables a reasoned consideration between safety aspects and other design drivers in ship design and operation. The hydrogen carriers AB NaBH4 KBH4 and two LOHCs (NEC and DBT) are taken into consideration together with a couple reference fuels (ammonia methanol and MDO). After the evaluation of chemical properties related to safety and the scope of the current IMO safety framework it can be concluded that safety remains a vague and non-explicit concept from both perspectives. Therefore further research is required to prove the safe application of hydrogen carriers onboard ships.
Process Path for Reducing Carbon Emissions from Steel Industry—Combined Electrification and Hydrogen Reduction
Jan 2024
Publication
This review focuses on the energy structure of iron and steel production and a feasible development path for carbon reduction. The process path and feasible development direction of carbon emission reduction in the iron and steel industry have been analyzed from the perspective of the carbon–electricity–hydrogen ternary relationship. Frontier technologies such as “hydrogen replacing carbon” are being developed worldwide. Combining the high efficiency of microwave electric-thermal conversion with the high efficiency and pollution-free advantages of hydrogen-reducing agents may drive future developments. In this review a process path for “microwave + hydrogen” synergistic metallurgy is proposed. The reduction of magnetite powder by H2 (CO) in a microwave field versus in a conventional field is compared. The driving effect of the microwave field is found to be significant and the synergistic reduction effect of microwaves with H2 is far greater than that of CO.
No more items...