Publications

Photoelectrochemical reforming of plastic waste offers an environmentally-benign and sustainable route for hydrogen generation. Nonetheless little attention was paid to develop electrocatalysts that can efficiently and selectively catalyze oxidative transformation of valueless plastic wastes into valued chemicals. Herein we report on facile electrosynthesis of nickel-phosphorus nanospheres (nanoNi-P) and their versatility in catalyzing hydrogen generation water oxidation and reforming of polyethylene terephthalate (PET). Notably composite of nanoNi-P with carbon nanotubes (CNT/nanoNi-P) requires −180 mV overpotential to drive hydrogen generation at -100 mA cm⁻². Besides CV-activated nanoNi-P (nanoNi-P(CV)) was shown to be capable of reforming PET into formate with high selectivity (Faradic efficiency= ∼100 %). Efficient and selective generation of hydrogen and formate from PET reforming is realized utilizing an Earth-abundant photoelectrochemical platform based on nanoNi-P(CV)-modified TiO2 nanorods photoanode and CNT/nanoNi-P cathode. This work paves a path for developing artificial leaf for simultaneous environmental mitigation and photosynthesis of renewable fuels and valued chemicals.

We report volumetric analysis techniques to analyze the transport properties of hydrogen dissolved in cylindrical-shaped polymers. The techniques utilize the volume measurement of the released hydrogen from rubber by gas collection in a graduated cylinder after charging sample with high-pressure hydrogen and subsequent decompression. We further improve the graduated cylinder with some modifications such as reading the electrical capacitance of the water level using electrodes and changing the sample loading position. From the measurement results the uptake (C∞) diffusion coefficient (D) and solubility (S) of hydrogen are quantified with an upgraded diffusion analysis program. These methods are applied to three cylindrical rubbers. Dual adsorption behaviors with increasing pressure are observed for all the samples. C∞ follows Henry’s law up to ~15 MPa whereas Langmuir model applies up to 90 MPa. D shows Knudsen and bulk diffusion behavior below and above pressure respectively. A COMSOL simulation is compared with experimental observations.

In the present work an Ir/CeO₂ catalyst was prepared by the deposition–precipitation method and tested in the decomposition of hydrazine hydrate to hydrogen which is very important in the development of hydrogen storage materials for fuel cells. The catalyst was characterised using different techniques i.e. X-ray photoelectron spectroscopy (XPS) transmission electron microscopy (TEM) scanning electron microscopy (SEM) equipped with X-ray detector (EDX) and inductively coupled plasma—mass spectroscopy (ICP-MS). The effect of reaction conditions on the activity and selectivity of the material was evaluated in this study modifying parameters such as temperature the mass of the catalyst stirring speed and concentration of base in order to find the optimal conditions of reaction which allow performing the test in a kinetically limited regime.

Durability is the most pressing issue preventing the efficient commercialization of polymer electrolyte membrane fuel cell (PEMFC) stationary and transportation applications. A big barrier to overcoming the durability limitations is gaining a better understanding of failure modes for user profiles. In addition durability test protocols for determining the lifetime of PEMFCs are important factors in the development of the technology. These methods are designed to gather enough data about the cell/stack to understand its efficiency and durability without causing it to fail. They also provide some indication of the cell/stack’s age in terms of changes in performance over time. Based on a study of the literature the fundamental factors influencing PEMFC long-term durability and the durability test protocols for both PEMFC stationary and transportation applications were discussed and outlined in depth in this review. This brief analysis should provide engineers and researchers with a fast overview as well as a useful toolbox for investigating PEMFC durability issues.

In situ neutron radiography experiments can provide information about diffusive processes and the kinetics of chemical reactions. The paper discusses requirements for such investigations. As examples of the zirconium alloy Zircaloy^-4 the hydrogen diffusion the hydrogen uptake during high-temperature oxidation in steam and the reaction in nitrogen/steam and air/steam atmospheres results of in situ neutron radiography investigations are reviewed and their benefit is discussed.

Hydrogen production from biomass pyrolysis is economically and technologically attractive from the perspectives of energy and the environment. The two-stage catalytic pyrolysis of pine sawdust for hydrogen-rich gas production is investigated using nano-NiO/Al2O3 as the catalyst at high temperatures. The influences of residence time (0–30 s) and catalytic temperature (500–800 ◦C) on pyrolysis performance are examined in the distribution of pyrolysis products gas composition and gas properties. The results show that increasing the residence time decreased the solid and liquid products but increased gas products. Longer residence times could promote tar cracking and gas-phase conversion reactions and improve the syngas yield H2/CO ratio and carbon conversion. The nano-NiO/A12O3 exhibits excellent catalytic activity for tar removal with a tar conversion rate of 93% at 800 ◦C. The high catalytic temperature could significantly improve H2 and CO yields by enhancing the decomposition of tar and gas-phase reactions between CO2 and CH4 . The increasing catalytic temperature increases the dry gas yield and carbon conversion but decreases the H2/CO ratio and low heating value.

Australia’s Technology Investment Roadmap is a strategy to accelerate development and commercialisation of low emissions technologies.

Annual low emissions statements are key milestones of the roadmap process. These statements prioritise low emissions technologies with potential to deliver the strongest economic and emissions reduction outcomes for Australia. They focus government investment on new and emerging technologies.

In this Statement

The first Low Emissions Technology Statement presents a vision of a prosperous Australia recognised as a global low emissions technology leader

• priority technologies and economic stretch goals
• Australia’s big technology challenges and opportunities
• Technology Investment Framework
• monitoring transparency and impact evaluation

To reduce loss of hydrogen in storage vessels with high energy-to-weight-ratio new materials especially polymers have to be developed as barrier materials. Very established methods for characterization of barrier materials with permeation measurements are the time-lag and flow rate method along with the differential pressure method which resembles the nature of hydrogen vessel systems very well. Long measurement durations are necessary to gain suitable measurement data for these evaluation methods and often restrictive conditions have to be fulfilled. For these reasons common models for hydrogen permeation through single-layer and multi-layer membranes as well as models for hydrogen gas properties were collected and reviewed. Using current computer power together with these models can reduce measurement time for characterization of the barrier properties of materials while additional information about the quality of the measurement results is obtained.

Wind and solar energies present a time and space disparity that generally leads to a mismatch between the demand and the supply. To harvest their maximum potentials one of the main challenges is the storage and transport of these energies. This challenge can be tackled by electrofuels such as hydrogen methane and methanol. They offer three main advantages: compatibility with existing distribution networks or technologies of conversion economical storage solution for high capacity and ability to couple sectors (i.e. electricity to transport to heat or to industry). However the level of contribution of electric-energy carriers is unknown. To assess their role in the future we used whole-energy system modelling (EnergyScope Typical Days) to study the case of Belgium in 2050. This model is multi-energy and multi-sector. It optimises the design of the overall system to minimise its costs and emissions. Such a model relies on many parameters (e.g. price of natural gas efficiency of heat pump) to represent as closely as possible the future energy system. However these parameters can be highly uncertain especially for long-term planning. Consequently this work uses the polynomial chaos expansion method to integrate a global sensitivity analysis in order to highlight the influence of the parameters on the total cost of the system. The outcome of this analysis points out that compared to the deterministic cost-optimum situation the system cost accounting for uncertainties becomes higher (+17%) and twice more uncertain at carbon neutrality and that electrofuels are a major contribution to the uncertainty (up to 53% in the variation of the costs) due to their importance in the energy system and their high uncertainties their higher price and uncertainty.

The UK is on course to become a global leader in hydrogen technology. Over £3bn is ready to be invested into hydrogen today. The pace of activity is rapid and the opportunities are vast.



Join us at our free to attend event where you will gain unique insights into how the Hydrogen industry is progressing together with exclusive access to future plans.

The dynamic and lively session will demonstrate the viability of hydrogen as a key component to achieve Net Zero.



Confirmed contributors include:

• National Grid Gas Transmission
• Cadent
• Chris Train Previous CEO Cadent
• DNV
• Worcester Bosch
• ITM Power
• Northern Gas Networks
• Decarbonising Heat in Buildings - New Research Findings from the Gas Distribution Networks

This paper discusses the numerical modeling of an automobile fuel cell system using a two-stage turbo-compressor for air supply. The numerical model incorporates essential input parameters for air and hydrogen flow. The model also performed mass and energy balances across different components such as pump fan heat-exchanger air compressor and keeps in consideration the pressure losses across flow pipes and various mechanical parts. The compressor design process initiates with numerical analysis of the preliminary design of a highly efficient two-stage turbo compressor with an expander as a single-stage compressor has several limitations in terms of efficiency and pressure ratio. The compressor’s design parameters were carefully studied and analyzed with respect to the highly efficient fuel cell stack (FCS) used in modern hydrogen vehicles. The model is solved to evaluate the overall performance of PEM FCS. The final compressor has a total pressure and temperature of 4.2 bar and 149.3°C whereas the required power is 20.08kW with 3.18kW power losses and having a combined efficiency of 70.8%. According to the FC model with and without expander the net-power outputs are 98.15kW and 88.27kW respectively and the maximum efficiencies are 65.1% and 59.1% respectively. Therefore it can be concluded that a two-stage turbo compressor with a turbo-expander can have significant effects on overall system power and efficiency. The model can be used to predict and optimize system performance for PEM FCS at different operating conditions.

Iridium-containing NaTaO₃ is produced using a one-step hydrothermal crystallisation from Ta₂O₅ and IrCl₃ in an aqueous solution of 10 M NaOH in 40 vol% H₂O₂ heated at 240 °C. Although a nominal replacement of 50% of Ta by Ir was attempted the amount of Ir included in the perovskite oxide was only up to 15 mol%. The materials are formed as crystalline powders comprising cube-shaped crystallites around 100 nm in edge length as seen by scanning transmission electron microscopy. Energy dispersive X-ray mapping shows an even dispersion of Ir through the crystallites. Profile fitting of powder X-ray diffraction (XRD) shows expanded unit cell volumes (orthorhombic space group Pbnm) compared to the parent NaTaO₃ while XANES spectroscopy at the Ir LIII-edge reveals that the highest Ir-content materials contain Ir⁴⁺. The inclusion of Ir⁴⁺ into the perovskite by replacement of Ta⁵⁺ implies the presence of charge-balancing defects and upon heat treatment the iridium is extruded from the perovskite at around 600 °C in air with the presence of metallic iridium seen by in situ powder XRD. The highest Ir-content material was loaded with Pt and examined for photocatalytic evolution of H₂ from aqueous methanol. Compared to the parent NaTaO₃ the Ir-substituted material shows a more than ten-fold enhancement of hydrogen yield with a significant proportion ascribed to visible light absorption.

Densified liquid hydrogen/liquid oxygen is a promising propulsion fuel in the future. In order to systematically demonstrate the benefits and challenges of densified liquid hydrogen/liquid oxygen a transient thermodynamical model considering the heat leakage temperature rise engine thrust pressurization pressure of the tank and wall thickness of tank is developed in the present paper and the performance of densified liquid hydrogen/liquid oxygen as propulsion fuel is further evaluated in actual application. For liquid hydrogen/liquid oxygen tanks at different structural dimensions the effects of many factors such as temperature rise during propellant ground parking lift of engine thrust mass reduction of the tank structure and extension of spacecraft in‐orbit time are analyzed to demonstrate the comprehensive performance of liquid hydrogen/liquid oxygen after densification. Meanwhile the problem of subcooling combination matching of liquid hydro‐ gen/liquid oxygen is proposed for the first time. Combining the fuel consumption and engine thrust lifting the subcooling combination matching of liquid hydrogen/liquid oxygen at different mixing ratios and constant mixing ratios are discussed respectively. The results show that the relative engine thrust enhances by 6.96% compared with the normal boiling point state in the condition of slush hydrogen with 50% solid content and enough liquid oxygen. The in‐orbit time of spacecraft can extend about 2–6.5 days and 24–95 days for slush hydrogen with 50% solid content and liquid oxygen in the triple point state in different cryogenic tanks respectively. Due to temperature rise during parking the existing adiabatic storage scheme and filling scheme for densification LH2 need to be redesigned and for densification LO2 are suitable. It is found that there is an optimal subcooling matching relation after densification of liquid hydrogen/liquid oxygen as propulsion fuel. In other words the subcooling temperature of liquid hydrogen/liquid oxygen is not the lower the bet‐ ter but the matching relationship between LH2 subcooling degree and LO2 subcooling degree needs to be considered at the same time. It is necessary that the LO2 was cooled to 69.2 K and 54.5 K when the LH2 of 13.9 K and SH2 with 45% was adopted respectively. This research provides theoretical support for the promotion and application of densification cryogenic propellants.

This work reports on H2 fuel generation from sewage water using Cu/CuO nanoporous (NP) electrodes. This is a novel concept for converting contaminated water into H2 fuel. The preparation of Cu/CuO NP was achieved using a simple thermal combustion process of Cu metallic foil at 550 ◦C for 1 h. The Cu/CuO surface consists of island-like structures with an inter-distance of 100 nm. Each island has a highly porous surface with a pore diameter of about 250 nm. X-ray diffraction (XRD) confirmed the formation of monoclinic Cu/CuO NP material with a crystallite size of 89 nm. The prepared Cu/CuO photoelectrode was applied for H2 generation from sewage water achieving an incident to photon conversion efficiency (IPCE) of 14.6%. Further the effects of light intensity and wavelength on the photoelectrode performance were assessed. The current density (Jph) value increased from 2.17 to 4.7 mA·cm−2 upon raising the light power density from 50 to 100 mW·cm−2 . Moreover the enthalpy (∆H*) and entropy (∆S*) values of Cu/CuO electrode were determined as 9.519 KJ mol−1 and 180.4 JK−1 ·mol−1 respectively. The results obtained in the present study are very promising for solving the problem of energy in far regions by converting sewage water to H2 fuel.

Managing the concentration of atmospheric CO₂ requires a multifaceted engineering strategy which remains a highly challenging task. Reducing atmospheric CO₂ (CO2R) by converting it to value-added chemicals in a carbon neutral footprint manner must be the ultimate goal. The latest progress in CO2R through either abiotic (artificial catalysts) or biotic (natural enzymes) processes is reviewed herein. Abiotic CO2R can be conducted in the aqueous phase that usually leads to the formation of a mixture of CO formic acid and hydrogen. By contrast a wide spectrum of hydrocarbon species is often observed by abiotic CO2R in the gaseous phase. On the other hand biotic CO2R is often conducted in the aqueous phase and a wide spectrum of value-added chemicals are obtained. Key to the success of the abiotic process is understanding the surface chemistry of catalysts which significantly governs the reactivity and selectivity of CO2R. However in biotic CO2R operation conditions and reactor design are crucial to reaching a neutral carbon footprint. Future research needs to look toward neutral or even negative carbon footprint CO2R processes. Having a deep insight into the scientific and technological aspect of both abiotic and biotic CO2R would advance in designing efficient catalysts and microalgae farming systems. Integrating the abiotic and biotic CO2R such as microbial fuel cells further diversifies the spectrum of CO2R.

Producing hydrogen from water using a redox mediator on solid electrocatalyst particles in a reactor offers several advantages over classical electrolysis in terms of safety membrane degradation purity and flexibility. Herein vanadium-mediated hydrogen evolution on a commercial and low-cost Mo2C electrocatalyst is studied through the development of a reaction kinetics model. Based on a proposed mechanistic reaction scheme we established a kinetic rate law dependent on the concentration of V2+ the state-of-charge of the vanadium electrolyte from a vanadium redox flow battery and the amount of available catalytic sites on solid Mo2C. Kinetic experiments in transient conditions reveals a first-order dependence on both the concentration of V2+ and the concentration of catalytic active sites and a power law with an exponential factor of 0.57 was measured on the molar ratio V2+/V3+ i.e. on the electrochemical driving force generated on the Mo2C particles. The kinetic rate law was validated by studying the rate of reaction in steady-state conditions using a specially developed rotating ring-disk device (RRD) methodology. The kinetic model was demonstrated to be a useful tool to predict the hydrogen production via the chemical oxidation of V2+ over Mo2C at low pH (> 1 M H2SO4). For a perspective the model was implemented in a semi-batch reactor. The simulations highlight the optimal state-of-charge (SOC) to carry out the reaction in an efficient way for a given demand in hydrogen.

The present work aims to identify critical materials in water electrolysers with potential future supply constraints. The expected rise in demand for green hydrogen as well as the respective implications on material availability are assessed by conducting a case study for Germany. Furthermore the recycling of end‐of‐life (EoL) electrolysers is evaluated concerning its potential in ensuring the sustainable supply of the considered materials. As critical materials bear the risk of raising production costs of electrolysers substantially this article examines the readiness of this technology for industrialisation from a material perspective. Except for titanium the indicators for each assessed material are scored with a moderate to high (platinum) or mostly high (iridium scandium and yttrium) supply risk. Hence the availability of these materials bears the risk of hampering the scale‐up of electrolysis capacity. Although conventional recycling pathways for platinum iridium and titanium already exist secondary material from EoL electrolysers will not reduce the dependence on primary resources significantly within the period under consideration—from 2020 until 2050. Notably the materials identified as critical are used in PEM and high temperature electrolysis whereas materials in alkaline electrolysis are not exposed to significant supply risks.

Given the increase in population and energy demand worldwide alternative methods have been adopted for the production of hydrogen as a clean energy source. This energy offers an alternative energy source due to its high energy content and without emissions to the environment. In this bibliometric analysis of energy production using electrolysis and taking into account the different forms of energy production. In this analysis it was possible to evaluate the research trends based on the literature in the Scopus database during the years 2011–2021. The results showed a growing interest in hydrogen production from electrolysis and other mechanisms with China being the country with the highest number of publications and the United States TOP in citations. The trend shows that during the first four years of this study (2011–2014) the average number of publications was 74 articles per year from 2015 to 2021 where the growth is an average of 209 articles the journal that published the most on this topic is Applied Energy followed by Energy contributing with almost 33% in the research area. Lastly the keyword analysis identified six important research points for future discussions which we have termed clusters. The study concludes that new perspectives on clean hydrogen energy generation environmental impacts and social acceptance could contribute to the positive evolution of the hydrogen energy industry.

To inform our Sixth Carbon Budget advice the Climate Change Committee (CCC) asked the University of Leeds to undertake independent research to evaluate which policies (and combinations of policies) would enable industrial decarbonisation in line with the UK’s net zero target without inducing carbon leakage. The research focused on policies applicable to the manufacturing sector but with some consideration also given to the policies required to decarbonise the Fossil Fuel Production and Supply and Non-Road Mobile Machinery sectors. This report:

Sets out a comprehensive review of existing policies;

• Identifies future policy mechanisms that address key challenges in decarbonising industry;
• Explores how combinations of policies might work together strategically in the form of ‘policy packages’ and how these packages might evolve over the period to 2050;
• Evaluates a series of illustrative policy packages and considers any complementary policies required to minimise carbon leakage and deliver ‘just’ industrial decarbonisation.
• The findings were developed through a combination of literature review and extensive stakeholder engagement with industry government and academic experts. 

This supported the Sixth Carbon budget.

The paper can be downloaded from the CCC website

In order to inform the Quantified Risk Assessment (QRA) and procedures for the Winlaton trial the gas characteristics relating to the behaviour of the flammable gas have been reviewed for blended natural gas mixtures containing 20% mol/mol hydrogen (hereby referred to as “blend”) for normal operation and 50% mol/mol for fault conditions. This work builds on the findings of the previous HyDeploy gas characteristics report HyD-Rep04-V02-Characteristics.<br/>Click on the supplements tab to view the other documents from this report

Development of marine engines could largely benefit from the broader usage of methanol and hydrogen which are both potential energy carriers. Here numerical results are presented on tri-fuel (TF) ignition using large-eddy simulation (LES) and finite-rate chemistry. Zero-dimensional (0D) and three-dimensional (3D) simulations for n-dodecane spray ignition of methanol/hydrogen blends are performed. 0D results reveal the beneficial role of hydrogen addition in facilitating methanol ignition. Based on LES the following findings are reported: 1) Hydrogen promotes TF ignition significantly for molar blending ratios βX = [H₂]/([H₂]+[CH₃OH]) ≥0.8. 2) For βX = 0 unfavorable heat generation in ambient methanol is noted. We provide evidence that excessive hydrogen enrichment (βX ≥ 0.94) potentially avoids this behavior consistent with 0D results. 3) Ignition delay time is advanced by 23–26% with shorter spray vapor penetrations (10–15%) through hydrogen mass blending ratios 0.25/0.5/1.0. 4) Last adding hydrogen increases shares of lower and higher temperature chemistry modes to total heat release.

Our new independent report finds that hydrogen can play an important role in UK’s ambitious decarbonisation plan and boost its global industrial competitiveness.

Key insights from this new analysis include:

• New independent report from Aurora Energy Research shows that hydrogen can meet up to half of Great Britain’s (GB) final energy demand by 2050 providing an important pathway to reaching UK’s ambitious Net Zero targets.
• The report concludes that both blue hydrogen (produced from natural gas after reforming to remove carbon content) and green hydrogen (produced by using power to electrolyse water) are expected to play an important role providing up to 480TWh of hydrogen or c.45% of GB’s final energy demand by 2050.
• All Net Zero scenarios require substantial growth in low-carbon generation such as renewables and nuclear. Large-scale hydrogen adoption could help to integrate renewables into the power system by reducing the power sector requirement for flexibility during peak winter months and boosting revenues for clean power generators by c. £3bn per year by 2050.
• The rollout of hydrogen could accelerate green growth and enable the development of globally competitive low-carbon industrial clusters while utilising UK’s competitive advantage on carbon capture.
• In facilitating the identification of a cost-effective hydrogen pathway there are some low-regret options for Government to explore including the stimulation of hydrogen demand in key sectors the deployment of CCS in strategic locations and the standardisation of networks. These initiatives could form an important part of the UK Government’s post-COVID stimulus plan.

Read the full report on Aurora Energy Research Website

CCS is an emissions reduction technology critical to meeting global climate targets. The Global Status of CCS 2019 documents important milestones for CCS over the past 12 months its status across the world and the key opportunities and challenges it faces. We hope this report will be read and used by governments policy-makers academics media commentators and the millions of people who care about our climate.

The paper presents and discusses results of mechanical spectroscopy (MS) tests carried out on a Cr martensitic steel. The study regards the following topics: (i) embrittlement induced by Cr segregation; (ii) interaction of hydrogen with C–Cr associates; (iii) nucleation of Cr carbides. The MS technique permitted characterising of the specific role played by point defects in the investigated phenomena: (i) Cr segregation depends on C–Cr associates distribution in as-quenched material in particular a slow cooling rate (~150 K/min) from austenitic field involves an unstable distribution which leads to Cr concentration fluctuations after tempering at 973 K; (ii) hydrogen interacts with C–Cr associates and the phenomenon hinders hydrogen attack (HA) because hydrogen atoms bound by C–Cr associates are not able to diffuse towards grain boundaries and dislocation where CH4 bubbles may nucleate grow and merge to form the typical HA cracks; (iii) C–Cr associates take part in the nucleation mechanism of Cr7C3 carbides and specifically these carbides form by the aggregation of C–Cr associates with 1 Cr atom.

Interest in hydrogen as a carbon-neutral energy carrier is on the rise around the globe including in Europe. In particular power-to-gas as a technology to transform electricity to hydrogen is receiving ample attention. This article scrutinises current updates in the energy law framework of the EU to explain the legal pre-conditions for the various possible applications of power-to-gas technology. It highlights the influence of both electricity and gas legislation on conversion storage and transmission of hydrogen and demonstrates why ‘green’ hydrogen might come with certain legal privileges under the Renewable Energy Directive attached to it as opposed to the European Commission’s so-called ‘clean’ hydrogen. The article concludes by advocating for legal system integration in EU energy law namely merging the currently distinct EU electricity and gas law frameworks into one unified EU Energy Act.

The report analyses the technical impacts to end-users of natural gas in Australian distribution networks when up to 10% hydrogen (by volume) is mixed with natural gas.



The full report can be found at this link.

A new criterion for hydrogen-induced cracking (HIC) that includes both the embrittlement effect and the loading effect of hydrogen was obtained theoretically. The surface cohesive energy and plastic deformation energy are reduced by hydrogen atoms at the interface; thus the fracture toughness is reduced according to fracture mechanics theory. Both the pressure effect and the embrittlement effect mitigate the critical condition required for crack instability extension. During the crack instability expansion the hydrogen in the material can be divided into two categories: hydrogen atoms surrounding the crack and hydrogen molecules in the crack cavity. The loading effect of hydrogen was verified by experiments and the characterization methods for the stress intensity factor under hydrogen pressure in a linear elastic model and an elastoplastic model were analyzed using the finite-element simulation method. The hydrogen pressure due to the aggregation of hydrogen molecules inside the crack cavity regularly contributed to the stress intensity factor. The embrittlement of hydrogen was verified by electrolytic charging hydrogen experiments. According to the change in the atomic distribution during crack propagation in a molecular dynamics simulation the transition from ductile to brittle fracture and the reduction in the fracture toughness were due to the formation of crack tip dislocation regions suppressed by hydrogen. The HIC formation mechanism is both the driving force of crack propagation due to the hydrogen gas pressure and the resisting force reduced by hydrogen atoms.

Hydrogen Europe is the organisation representing the interests of the European hydrogen industry. It fully adheres to the European Union’s target of climate neutrality by 2050 and supports the European Commission’s objectives to develop and integrate more renewable energy sources into the European energy mix.<br/><br/>In December 2015 in Paris a global climate agreement was reached at the UN Climate Change Conference (COP 21). The Paris Agreement is seen as a historic and landmark instrument in climate action. However the agreement is lacking emphasis on international maritime transport and the role that this sector will need to play in contributing to the decarbonisation of the global economy and in striving for a clean planet for all.<br/><br/>Hydrogen hydrogen-based fuels (such as ammonia) and hydrogen technologies offer tremendous potential for the maritime sector<br/>and if properly harnessed can significantly contribute to the decarbonisation and also mitigate the air pollution of the worldwide fleet. Hydrogen Europe will be the catalyst in this process the decarbonisation and also mitigate the air pollution of the worldwide fleet. Hydrogen Europe will be the catalyst in this process.<br/><br/>The pathway towards hydrogen and hydrogenbased fuels for the maritime sector does not come without technological and commercial challenges let alone regulatory barriers.

The current evidential effect of carbon emissions has become a societal challenge and the need to transition to cleaner energy sources/technologies has attracted wide research attention. Technologies that utilize low-grade heat like the organic Rankine cycle (ORC) and Kalina cycle have been proposed as viable approaches for fossil reduction/carbon mitigation. The development of renewable energy-based multigeneration systems is another alternative solution to this global challenge. Hence it is important to monitor the development of multigeneration energy systems based on low-grade heat. In this study a review of the ORC’s application in multigeneration systems is presented to highlight the recent development in ORC integrality/application. Beyond this a new ORC-CPVT (concentrated photovoltaic/thermal) integrated multigeneration system is also modeled and analyzed using the thermodynamics approach. Since most CPVT systems integrate hot water production in the thermal stem the proposed multigeneration system is designed to utilize part of the thermal energy to generate electricity and hydrogen. Although the CPVT system can achieve high energetic and exergetic efficiencies while producing thermal energy and electricity these efficiencies are 47.9% and 37.88% respectively for the CPVT-ORC multigeneration configuration. However it is noteworthy that the electricity generation from the CPVT-ORC configuration in this study is increased by 16%. In addition the hot water cooling effect and hydrogen generated from the multigeneration system are 0.4363 L/s 161 kW and 1.515 L/s respectively. The environmental analysis of the system also shows that the carbon emissions reduction potential is enormous.

The objective of this project is to take into account the mechanical constraints formed by diffusion of hydrogen or tritium in watertight palladium alloy cathode. To know the origin of these it was necessary to discriminating the damaging effects encountered. Effectively hydrogen and isotope induce deformation embrittlement stress corrosion cracking and cathodic corrosion in different regions of cathode. Palladium can be alloyed with silver or yttrium to favourably increase diffusion and reduce these constraints. Effects of electrochemical factors temperature cathode structure adsorbed transient complex of palladium and porous material support are given to estimate and to limit possible damage.

Experimental tests of flat titanium samples at a temperature of 450 °C stretched with a constant force up to destruction were carried out. Titanium samples were hydrogenated in the Moscow Aviation Institute laboratory to a hydrogen content of 0.1 % 0.3 % and 0.6 % by weight of the specimen and then tested in the laboratory of Lomonosov Moscow State University. From the experiments the time to failure the localization time of the deformations and the stress distribution along the longitudinal coordinate of the sample over time were obtained. A metallographic study was conducted and the phase composition was investigated in Moscow Aviation Institute. The effect of hydrogen on long-term strength mechanical characteristics and phase composition has been elucidated.

A new assessment tool for evaluating decarbonization technologies that considers each technology’s sustainability security affordability readiness and impact for a specific country is proposed. This tool is applied to a set of decarbonization technologies for the power transport and industry sectors for the ten Southeast Asian countries that constitute ASEAN. This results in a list of the most promising decarbonization technologies as well as the remaining issues that need more research and development. This study reveals several common themes for ASEAN’s decarbonization. First carbon capture and storage (CCS) is a key technology for large-scale CO2 emission. Second for countries that rely heavily on coal for power generation switching to gas can halve their CO2 emission in the power sector and should be given high priority. Third hydropower and bioenergy both have high potential for the majority of ASEAN countries if their sustainability issues can be resolved satisfactorily. Fourth replacing conventional vehicles by electric vehicles is the overarching theme in the road transport sector but will result in increased demand for electricity. In the medium to long term the use of hydrogen for marine fuel and biofuels for aviation fuel are preferred solutions for the marine and aviation transport sectors. Fifth for the industry sector installing CCS in industrial plants should be given priority but replacing fossil fuels by blue hydrogen for high-temperature heating is the preferred long-term solution.

Australia’s gas infrastructure is currently subject to regulations that were designed for a natural-gas only network system. Future Fuels CRC has released a full report and database of regulations to share exactly how Australia’s current gas regulations can be modernised to enable hydrogen biomethane and other potential future fuels.

This research thoroughly assessed Australia’s current regulatory framework to identify the regulations that will require modernisation to facilitate the use of future fuels within Australia’s energy networks and align them with the goals of Australia’s National Hydrogen Strategy. This study builds on the initial work completed as part of Australia’s National Hydrogen Strategy and creates a comprehensive regulatory map of relevant legislation across the natural gas production and supply chain which may be impacted by the addition of future fuels such as hydrogen and biomethane.

The research was delivered by RMIT University of Sydney and GPA Engineering supported by our industry and government participants APA APGA ATCO AusNet Services ENA Energy Safe Victoria Jemena and the South Australian Government.

The study’s report summarises the key issues and the direction of possible solutions. The study also created a database that holds details of legislation by state and territory as well as Commonwealth legislation and applicable Australian standards. The database is designed to be readily updated as these regulations continue to evolve.  

The Australian energy industry and regulators benefit from this study by ensuring that any regulatory changes required for future fuels are identified early so that appropriate regulatory changes can be initiated and delivered. These changes will enable the many highly-regulated pilot projects happening across Australia to expand and develop under a modernised and effective regulatory environment.

You can find the full report on the Future Fuels CRC website here

Carbon capture and storage (CCS) refers to a set of technologies that may offer the potential for large-scale removal of CO₂ emissions from a range of processes – potentially including the generation of electricity and heat industrial processes and the production of hydrogen and synthetic fuels. CCS has both proponents and opponents. Like other emerging low carbon technologies CCS is not without risks or uncertainties and there are various challenges that would need to be overcome if it were to be widely deployed. Policy makers’ decisions as to whether to pursue CCS should be based on a judgement as to whether the risks and uncertainties associated with attempting to deploy CCS outweigh the risks of not having it available as part of a portfolio of mitigation options in future years.

The full report can be found on the Global CSS Institute website at this link

Hydrogen embrittlement (HE) is a critical issue that affects the reliability of hydrogenation reactors. The hydrogen diffusivity/trap characteristics of 2.25Cr-1Mo-0.25V steel are important parameters mainly used to study the HE mechanism of steel alloys. In this work the hydrogen diffusivity/trap characteristics of heat-treated (annealed) and untreated 2.25Cr-1Mo-0.25V steel were studied using an electrochemical permeation method. The microstructures of both 2.25Cr-1Mo-0.25V steels were investigated by metallurgical microscopy. The effect of cementite on the hydrogen diffusivity/trap mechanisms was studied using thermodynamics-based and Lennard–Jones potential theories. The results revealed that the cementite located at the grain boundaries and at the interfaces of lath ferrite served as a kind of hydrogen trap (i.e. an irreversible hydrogen trap). In addition hydrogen was transported from ferrite to cementite via up-hill diffusion thereby supporting the hypothesis of cementite acting as a hydrogen trap.

Proton conducting SmNiO₃ (SNO) thin films were grown on (001) LaAlO₃ substrates for systematically investigating the proton transport properties. X-ray Diffraction and Atomic Force Microscopy studies reveal that the as-grown SNO thin films have good single crystallinity and smooth surface morphology. The electrical conductivity measurements in air indicate a peak at 473 K in the temperature dependence of the resistance of the SNO films probably due to oxygen loss on heating. A Metal-Insulator-Transition occurs at 373 K for the films after annealing at 873 K in air. In a hydrogen atmosphere (3% H2/97% N₂) an anomalous peak in the resistance is found at 685 K on the first heating cycle. Electrochemical Impedance Spectroscopy studies as a function of temperature indicate that the SNO films have a high ionic conductivity (0.030 S/cm at 773 K) in a hydrogen atmosphere. The activation energy for proton conductivity was determined to be 0.23 eV at 473–773 K and 0.37 eV at 773–973 K respectively. These findings demonstrate that SNO thin films have good proton conductivity and are good candidate electrolytes for low temperature proton-conducting Solid Oxide Fuel Cells.

In this study electrochemical measurements immersion tests and slow strain rate tensile (SSRT) tests were applied to investigate the electrochemical and stress corrosion cracking (SCC) behavior of X70 steel in simulated seawater with the interference of different alternating current (AC) densities. The results indicate that AC significantly strengthens the cathodic reaction especially the oxygen reduction reaction. Simultaneously hydrogen evolution reaction occurs when the limiting diffusion current density of oxygen reaches and thus icorr sharply increases with the increase in AC density. Additionally when AC is imposed the X70 steel exhibits higher SCC susceptibility in the simulated seawater and the susceptibility increases with the increasing AC density. The SCC mechanism is controlled by both anodic dissolution (AD) and hydrogen embrittlement (HE) with the interference of AC.

Deloitte was commissioned by the National Hydrogen Taskforce established by the COAG Energy Council to undertake an Australian and Global Growth Scenario Analysis. Deloitte analysed the current global hydrogen industry its development and growth potential and how Australia can position itself to best capitalise on the newly forming industry.



To conceptualise the possibilities for Australia Deloitte created scenarios to model the realm of possibilities for Australia out to 2050 focusing on identifying the scope and distribution of economic and environmental costs and benefits from Australian hydrogen industry development. This work will aid in analysing the opportunities and challenges to hydrogen industry development in Australia and the actions needed to overcome barriers to industry growth manage risks and best drive industry development.



The full report is available on the Deloitte website at this link

A flake is a crack that is induced by trapped hydrogen within steel. To study its formation mechanism previous studies mostly focused on the formation process and magnitude of hydrogen pressure in hydrogen traps such as cavities and cracks. However according to recent studies the hydrogen leads to the decline of the mechanical properties of steel which is known as hydrogen embrittlement is another reason for flake formation. In addition the phenomenon of stress induced hydrogen uphill diffusion should not be neglected. All of the three behaviors are at work simultaneously. In order to further explore the formation mechanism of flakes in steel the process of flake initiation and growth were studied with the following three coupling factors: trap hydrogen pressure hydrogen embrittlement and stress induced hydrogen re-distribution. The analysis model was established using the finite element method and a crack whose radius is 0.5 mm was set in its center. The cohesive method and Bilinear Traction Separate Law (BTSL) were used to address the coupling effect. The results show that trap hydrogen pressure is the main driving force for flake formation. After the high hydrogen pressure was generated around the trap a stress field formed. In addition the trap is the center of stress concentration. Then hydrogen is concentrated in a distribution around this trap and most of the steel mechanical properties are reduced. The trap size is a key factor for defining the critical hydrogen content for flake formation and propagation. However when the trap size exceeds the specified value the critical hydrogen content does not change any more. As for the crack whose radius is 0.5 mm the critical hydrogen content of Cr5VMo steel is 2.2 ppm which is much closer to the maximum safe hydrogen concentration of 2.0 ppm used in China. The work presented in this article increases our understanding of flake formation and propagation mechanisms in steel.

Low temperature methane steam reforming for hydrogen production using experimental developed Ni/Al2O3 catalysts is studied both experimentally and numerically. The catalytic activity measurements were performed at a temperature range of 500–700 ◦C with steam to carbon ratio (S/C) of 2 and 3 under atmospheric pressure conditions. A mathematical analysis to evaluate the reaction feasibility at all different conditions that have been applied by using chemical equilibrium with applications (CEA) software and in addition a mathematical model focused on the kinetics and the thermodynamics of the reforming reaction is introduced and applied using a commercial finite element analysis software (COMSOL Multiphysics 5.0). The experimental results were employed to validate the extracted simulation data based on the yields of the produced H2 CO2 and CO at different temperatures. A maximum hydrogen yield of 2.7 mol/mol-CH4 is achieved at 700 ◦C and S/C of 2 and 3. The stability of the 10%Ni/Al2O3 catalyst shows that the catalyst is prone to deactivation as supported by Thermogravimetric Analysis TGA results.

The Department for Business Energy and Industrial Strategy (BEIS) commissioned a study to research the capacity of the manufacturing supply chain to meet expected future demand for heat pumps. This report contains analysis of the existing supply chain including component parts and also assesses the risks to and opportunities for growth in domestic heat pump manufacture and export.<br/><br/>Alongside a literature review the findings in this report were supported by interviews with organisations involved in the manufacture of heat pumps and an online workshop held with a range of businesses throughout the supply chain.

Pipelines during their service life subjected to operational degradation i.e. their mechanical characteristics worsened with time. Pronounced texture of pipe steels associated with their manufacturing process revealed itself in an essential difference in impact toughness determined for specimens cut in mutually perpendicular directions with respect to the pipe axis. Higher KCV values for longitudinal specimens as compared with transverse ones were explained by the difference in a length of perlite grain strips separated by ferrite grains in specimens of different orientation. A role of hydrogen absorbed my metal during its operation in steel degradation was discussed.<br/>The main fractographic peculiarity for the operated steels comparing to the steels in the initial state is the appearance of delamination on the fracture surfaces which are oriented in the rolling direction. Correlation was found for the tested steels between fractographic sings of their embrittlement due to operational degradation and their loss of brittle fracture resistance. It is concluded that a decrease of impact toughness caused by long term operation of pipeline steels is definitely concerned with the amount of delamination on the fracture surfaces.

Rod-like molybdenum carbide (Mo₂C) microcrystals were obtained from the pyrolysis of Mo-containing organic-inorganic hybrid composite. We investigated the photocatalytic H₂ evolution activity of Mo₂C by constructing a Mo₂C-dye sensitizer photocatalyst system. A high quantum efficiency of 29.7% was obtained at 480 nm. Moreover Mo₂C catalyst can be easily recycled by simple filtration.

Atomic hydrogen produced by corrosion of a low-carbon steel in NaCl – Water solution may markedly affect its certain tensile mechanical and magnetic properties in a complex and peculiar manner. This influence was investigated by employing the intrinsic micromagnetic emission (ME)-response as well as tensile mechanical response of this ferromagnetic material and also by introduction a relevant measurement parameter of specific micromagnetic emission response. In this fashion it was shown that an increase in the hydrogen accumulation with corrosion time leads to an associated increase in the pervasive and embrittling influence expressed by a marked loss in ductility of the material. It was also shown that the competitive interplay of cumulative hydrogen applied stress and plastic strain-induced microstructural damage was related to a specific ME-response parameter by which an increased magnetic hardening tendency of material with corrosion time was established. In general embrittlement and magnetic hardening are parallel products of stress- assisted hydrogen accumulation where magnetic hardening process seems to be in a time processing advance of embrittlement one. The above findings allow to estimate that the magnetic properties are more susceptible to hydrogen effects than the mechanical ones.

We present a method that operates an electrolyzer to meet the demand of a hydrogen refueling station in a cost-effective manner by solving a model-based optimal control problem. To formulate the underlying problem we first conduct an experimental characterization of a Siemens SILYZER 100 polymer electrolyte membrane electrolyzer with 100 kW of rated power. We run experiments to determine the electrolyzer’s conversion efficiency and thermal dynamics as well as the overload-limiting algorithm used in the electrolyzer. The resulting detailed nonlinear models are used to design a real-time optimal controller which is then implemented on the actual system. Each minute the controller solves a deterministic receding-horizon problem which seeks to minimize the cost of satisfying a given hydrogen demand while using a storage tank to take advantage of time-varying electricity prices and photovoltaic inflow. We illustrate in simulation the significant cost reduction achieved by our method compared to others in the literature and then validate our method by demonstrating it in real-time operation on the actual system.

Renewable power-to-hydrogen (P2H) technology is one of the most promising solutions for fulfilling the increasing global demand for hydrogen and to buffer large-scale fluctuating renewable energies. The high-power high-current ac/dc converter plays a crucial role in P2H facilities transforming medium-voltage (MV) ac power to a large dc current to supply hydrogen electrolyzers. This work introduces the general requirements and overviews several power converter topologies for P2H systems. The performances of different topologies are evaluated and compared from multiple perspectives. Moreover the future trend of eliminating the line frequency transformer (LFT) is discussed. This work can provide guidance for future designing and implementing of power-electronics-based P2H systems.

The ever-increasing demand for energy coupled with dwindling fossil fuel resources make the establishment of a clean and sustainable energy system a compelling need. Hydrogen-based energy systems offer potential solutions. Although in the long-term the ultimate technological challenge is large-scale hydrogen production from renewable sources the pressing issue is how to store hydrogen efficiently on board hydrogen fuel-cell vehicles.

Minerals are essential components in many of today’s rapidly growing clean energy technologies – from wind turbines and electricity networks to electric vehicles. Demand for these minerals will grow quickly as clean energy transitions gather pace. This new World Energy Outlook Special Report provides the most comprehensive analysis to date of the complex links between these minerals and the prospects for a secure rapid transformation of the energy sector.



Alongside a wealth of detail on mineral demand prospects under different technology and policy assumptions it examines whether today’s mineral investments can meet the needs of a swiftly changing energy sector. It considers the task ahead to promote responsible and sustainable development of mineral resources and offers vital insights for policy makers including six key IEA recommendations for a new comprehensive approach to mineral security."





Link to International Energy Agency website

In the context of the current serious problems related to energy demand and climate change substantial progress has been made in developing a sustainable energy system. Electrochemical hydrogen–water conversion is an ideal energy system that can produce fuels via sustainable fossil-free pathways. However the energy conversion efficiency of two functioning technologies in this energy system—namely water electrolysis and the fuel cell—still has great scope for improvement. This review analyzes the energy dissipation of water electrolysis and the fuel cell in the hydrogen–water energy system and discusses the key barriers in the hydrogen- and oxygen-involving reactions that occur on the catalyst surface. By means of the scaling relations between reactive intermediates and their apparent catalytic performance this article summarizes the frameworks of the catalytic activity trends providing insights into the design of highly active electrocatalysts for the involved reactions. A series of structural engineering methodologies (including nanoarchitecture facet engineering polymorph engineering amorphization defect engineering element doping interface engineering and alloying) and their applications based on catalytic performance are then introduced with an emphasis on the rational guidance from previous theoretical and experimental studies. The key scientific problems in the electrochemical hydrogen–water conversion system are outlined and future directions are proposed for developing advanced catalysts for technologies with high energy-conversion efficiency.

The study on temper embrittlement and hydrogen embrittlement of a test block from a 3Cr1Mo1/4V hydrogenation reactor after ten years of service was carried out by small punch test (SPT) at different temperatures. The SPT fracture energy Esp (derived from integrating the load-displacement curve) divided by the maximum load (Fm) of SPT was used to fit the Esp/Fm versus-temperature curve to determine the energy transition temperature (Tsp) which corresponded to the ductile-brittle transition temperature of the Charpy impact test. The results indicated that the ratio of Esp/Fm could better represent the energy of transition in SPT compared with Esp. The ductile-to-brittle transition temperature of the four different types of materials was measured using the hydrogen charging test by SPT. These four types of materials included the base metal and the weld metal in the as-received state and the base metal and the weld metal in the de-embrittled state. The results showed that there was a degree of temper embrittlement in the base metal and the weld metal after ten years of service at 390 °C. The specimens became slightly more brittle but this was not obvious after hydrogen charging. Because the toughness of the material of the hydrogenation reactor was very good the flat samples of SPT could not characterize the energy transition temperature within the liquid nitrogen temperature. Additionally there was no synergetic effect of temper embrittlement and hydrogen embrittlement found in 3Cr1Mo1/4V steel.